DE69321879T2 - Kationische Metallocenkatalysatoren auf Basis von Triphenylcarbeniumaluminium - Google Patents

Kationische Metallocenkatalysatoren auf Basis von Triphenylcarbeniumaluminium

Info

Publication number
DE69321879T2
DE69321879T2 DE69321879T DE69321879T DE69321879T2 DE 69321879 T2 DE69321879 T2 DE 69321879T2 DE 69321879 T DE69321879 T DE 69321879T DE 69321879 T DE69321879 T DE 69321879T DE 69321879 T2 DE69321879 T2 DE 69321879T2
Authority
DE
Germany
Prior art keywords
triphenylcarbenium
aluminum
metallocene catalysts
catalysts based
cationic metallocene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69321879T
Other languages
English (en)
Other versions
DE69321879D1 (de
Inventor
Michael J Elder
John A Ewen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fina Technology Inc
Original Assignee
Fina Technology Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fina Technology Inc filed Critical Fina Technology Inc
Publication of DE69321879D1 publication Critical patent/DE69321879D1/de
Application granted granted Critical
Publication of DE69321879T2 publication Critical patent/DE69321879T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/61927—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63908—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
DE69321879T 1992-06-04 1993-06-04 Kationische Metallocenkatalysatoren auf Basis von Triphenylcarbeniumaluminium Expired - Lifetime DE69321879T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/893,522 US5763549A (en) 1989-10-10 1992-06-04 Cationic metallocene catalysts based on organoaluminum anions

Publications (2)

Publication Number Publication Date
DE69321879D1 DE69321879D1 (de) 1998-12-10
DE69321879T2 true DE69321879T2 (de) 1999-06-10

Family

ID=25401710

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69321879T Expired - Lifetime DE69321879T2 (de) 1992-06-04 1993-06-04 Kationische Metallocenkatalysatoren auf Basis von Triphenylcarbeniumaluminium

Country Status (5)

Country Link
US (2) US5763549A (de)
EP (1) EP0573403B1 (de)
JP (1) JP3446059B2 (de)
DE (1) DE69321879T2 (de)
ES (1) ES2124777T3 (de)

Families Citing this family (153)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5384299A (en) * 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US6291389B1 (en) 1994-04-28 2001-09-18 Exxonmobil Chemical Patents Inc. Cationic polymerization catalysts
US6008307A (en) * 1994-04-28 1999-12-28 Exxon Chemical Patents Inc Process for producing olefin polymers using cationic catalysts
US6143686A (en) * 1994-08-03 2000-11-07 Exxon Chemical Patents, Inc. Supported ionic catalyst compositions
CZ28597A3 (en) * 1994-08-03 1997-07-16 Exxon Chemical Patents Inc Ionic catalytic supported composition
US5856256A (en) * 1996-02-20 1999-01-05 Northwestern University Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations
US6291695B1 (en) 1996-02-20 2001-09-18 Northwestern University Organo-Lewis acids of enhanced utility, uses thereof, and products based thereon
US6274752B1 (en) 1996-02-20 2001-08-14 Northwestern University Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations
US5786291A (en) * 1996-02-23 1998-07-28 Exxon Chemical Patents, Inc. Engineered catalyst systems and methods for their production and use
US5811379A (en) 1996-06-17 1998-09-22 Exxon Chemical Patents Inc. Polymers derived from olefins useful as lubricant and fuel oil additives, processes for preparation of such polymers and additives and use thereof (PT-1267)
US6066603A (en) * 1996-06-17 2000-05-23 Exxon Chemical Patents Inc. Polar monomer containing copolymers derived from olefins useful as lubricant and useful as lubricant and fuel oil additivies process for preparation of such copolymers and additives and use thereof
AU718884B2 (en) 1996-06-17 2000-04-20 Exxon Chemical Patents Inc. Mixed transition metal catalyst systems for olefin polymerization
US5854166A (en) * 1996-08-19 1998-12-29 Northwestern University Synthesis and use of (perfluoroaryl) fluoro-aluminate anion
US6262200B1 (en) 1996-08-19 2001-07-17 Northwestern University (Polyfluoroaryl)fluoroanions of aluminum, gallium, and indium of enhanced utility, uses thereof, and products based thereon
US6130302A (en) * 1996-08-19 2000-10-10 Northwestern University Synthesis and use of (polyfluoroaryl)fluoroanions of aluminum, gallium and indium
US6180736B1 (en) 1996-12-20 2001-01-30 Exxon Chemical Patents Inc High activity metallocene polymerization process
DE19703478A1 (de) 1997-01-31 1998-08-06 Hoechst Ag Verfahren zur Herstellung eines Matallocen-Katalysatorsystems
BR9806952A (pt) 1997-02-07 2000-03-21 Exxon Chemical Patents Inc Preparação de macrÈmeros contendo vinila.
JP2001511215A (ja) 1997-02-07 2001-08-07 エクソン・ケミカル・パテンツ・インク ポリエチレンマクロマーを組み入れるプロピレンポリマー
US5895771A (en) * 1997-06-05 1999-04-20 Akzo Nobel Nv Fluorinated alkoxy and/or aryloxy aluminates as cocatalysts for metallocene-catalyzed olefin polymerizations
US6172015B1 (en) 1997-07-21 2001-01-09 Exxon Chemical Patents, Inc Polar monomer containing copolymers derived from olefins useful as lubricant and fuel oil additives, processes for preparation of such copolymers and additives and use thereof
US7026404B2 (en) 1997-08-12 2006-04-11 Exxonmobil Chemical Patents Inc. Articles made from blends made from propylene ethylene polymers
US6635715B1 (en) 1997-08-12 2003-10-21 Sudhin Datta Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers
US6921794B2 (en) 1997-08-12 2005-07-26 Exxonmobil Chemical Patents Inc. Blends made from propylene ethylene polymers
US6100224A (en) * 1997-10-01 2000-08-08 Exxon Chemical Patents Inc Copolymers of ethylene α-olefin macromers and dicarboxylic monomers and derivatives thereof, useful as additives in lubricating oils and in fuels
US6184327B1 (en) 1997-12-10 2001-02-06 Exxon Chemical Patents, Inc. Elastomeric propylene polymers
US6197910B1 (en) 1997-12-10 2001-03-06 Exxon Chemical Patents, Inc. Propylene polymers incorporating macromers
US6117962A (en) * 1997-12-10 2000-09-12 Exxon Chemical Patents Inc. Vinyl-containing stereospecific polypropylene macromers
US6784269B2 (en) 1998-05-13 2004-08-31 Exxonmobil Chemical Patents Inc. Polypropylene compositions methods of making the same
EP1078009B1 (de) 1998-05-13 2004-06-16 ExxonMobil Chemical Patents Inc. Propylenhomopolymere und herstellungsverfahren
WO1999064476A1 (en) 1998-06-12 1999-12-16 Univation Technologies Llc Olefin polymerization process using activated lewis acid-base complexes
KR100581789B1 (ko) 1998-07-01 2006-05-23 엑손모빌 케미칼 패턴츠 인코포레이티드 프로필렌의 결정성 중합체 및 결정화가능한 중합체를포함하는 탄성 블렌드 조성물
CA2330775A1 (en) 1998-07-16 2000-01-27 Univation Technologies Llc Aluminum-based lewis acid cocatalysts for olefin polymerization
WO2000009515A1 (en) * 1998-08-11 2000-02-24 The Dow Chemical Company Catalyst activator composition
EP1104430B1 (de) * 1998-08-11 2002-12-18 Dow Global Technologies Inc. Ansa gruppe-4-metall bis(.mu.-aluminium) -substituierte metallocene
DE69901451T2 (de) * 1998-08-11 2002-12-12 Dow Chemical Co Ansa bis(.mu.-aluminium)-substituierte gruppe-4-metallkomplexe
BR9913647B1 (pt) 1998-08-26 2008-11-18 polipropileno ramificado e processo para produzir o mesmo.
US6403773B1 (en) 1998-09-30 2002-06-11 Exxon Mobil Chemical Patents Inc. Cationic group 3 catalyst system
IT1304181B1 (it) * 1998-12-17 2001-03-08 Enichem Spa Composizione attivante di complessi metallocenici nella catalisi deiprocessi di (co)polimerizzazione delle olefine.
JP2000351813A (ja) 1999-04-09 2000-12-19 Mitsui Chemicals Inc エチレン・α−オレフィン共重合体およびその製造方法ならびにその用途
US6174930B1 (en) 1999-04-16 2001-01-16 Exxon Chemical Patents, Inc. Foamable polypropylene polymer
US6339134B1 (en) 1999-05-06 2002-01-15 Univation Technologies, Llc Polymerization process for producing easier processing polymers
US6479598B1 (en) 1999-07-20 2002-11-12 Exxonmobil Chemical Patents Inc. Petroleum resins and their production with BF3 catalyst
DE19935592A1 (de) 1999-08-02 2001-02-08 Elenac Gmbh Imidochromverbindungen in Katalysatorsystemen für die Olefinpolymerisation
ES2228600T3 (es) 1999-08-13 2005-04-16 Basell Polyolefine Gmbh Copolimeros de etileno con alfa-olefinas con 3 a 9 atomos de carbono.
US6403743B1 (en) 1999-09-14 2002-06-11 Exxonmobil Chemical Patents Inc. Petroleum resins and their production with supported catalyst
US6300439B1 (en) 1999-11-08 2001-10-09 Univation Technologies, Llc Group 15 containing transition metal catalyst compounds, catalyst systems and their use in a polymerization process
US6274684B1 (en) 1999-10-22 2001-08-14 Univation Technologies, Llc Catalyst composition, method of polymerization, and polymer therefrom
ES2210015T3 (es) 1999-11-04 2004-07-01 Exxonmobil Chemical Patents Inc. Espumas de copolimero de propileno y su uso.
US6667274B1 (en) 1999-12-30 2003-12-23 Phillips Petroleum Company Polymerization catalysts
DE10022497A1 (de) 2000-05-09 2001-11-15 Bayer Ag Copolymerisation konjugierter Diene mit nichtkonjugierten Olefinen mittels Katalysatoren der Seltenen Erden
EP1303543A1 (de) * 2000-07-17 2003-04-23 Univation Technologies LLC Katalysatorsystem und seine verwendung in einem polymerisationsverfahren
US6495484B1 (en) 2000-08-28 2002-12-17 Univation Technologies, Llc Catalyst system and its use in a polymerization process
GC0000293A (en) * 2000-10-10 2006-11-01 Saudi Basic Ind Corp Catalyst composition and process for olfin polymerization and copolymerization using supported metallocene catalyst systems
CA2332203A1 (en) * 2001-01-24 2002-07-24 Bayer Inc. Process for making high molecular weight isobutylene polymers
ATE485319T1 (de) 2001-04-12 2010-11-15 Exxonmobil Chem Patents Inc Verfahren zur polymerisation von propylen und ethylen in lösung
DE10127926A1 (de) 2001-06-08 2002-12-12 Bayer Ag 1,3-disubstituierte Indenkomplexe
US6660679B2 (en) 2001-06-18 2003-12-09 Univation Technologies, Llc Catalyst system and its use in a polymerization process
WO2003002583A2 (en) 2001-06-29 2003-01-09 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
US6916892B2 (en) 2001-12-03 2005-07-12 Fina Technology, Inc. Method for transitioning between Ziegler-Natta and metallocene catalysts in a bulk loop reactor for the production of polypropylene
CA2368724C (en) * 2002-01-21 2011-06-14 Bayer Inc. Process for preparing isobutylene-based polymers
US7943700B2 (en) 2002-10-01 2011-05-17 Exxonmobil Chemical Patents Inc. Enhanced ESCR of HDPE resins
ES2394304T3 (es) 2002-10-15 2013-01-30 Exxonmobil Chemical Patents, Inc. Sistema de múltiples catalizadores para la polimerización de olefinas y polímeros producidos a partir de éstos
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US20040102311A1 (en) 2002-11-21 2004-05-27 Abbas Razavi Bridged metallocene catalyst component, method of making, polyolefin catalyst having C1, C2, or Cs symmetry, methods of making, methods of polymerizing, olefins and products made thereof
US7195806B2 (en) 2003-01-17 2007-03-27 Fina Technology, Inc. High gloss polyethylene articles
US6953764B2 (en) 2003-05-02 2005-10-11 Dow Global Technologies Inc. High activity olefin polymerization catalyst and process
US7803865B2 (en) 2003-08-25 2010-09-28 Dow Global Technologies Inc. Aqueous dispersion, its production method, and its use
US8946329B2 (en) 2003-08-25 2015-02-03 Dow Global Technologies Llc Coating compositions
TW200517426A (en) 2003-08-25 2005-06-01 Dow Global Technologies Inc Aqueous dispersion, its production method, and its use
US8779053B2 (en) 2003-08-25 2014-07-15 Dow Global Technologies Llc Coating compositions
US8722787B2 (en) 2003-08-25 2014-05-13 Dow Global Technologies Llc Coating composition and articles made therefrom
US7763676B2 (en) 2003-08-25 2010-07-27 Dow Global Technologies Inc. Aqueous polymer dispersions and products from those dispersions
US8349929B2 (en) 2003-08-25 2013-01-08 Dow Global Technologies Llc Coating composition and articles made therefrom
US8357749B2 (en) 2003-08-25 2013-01-22 Dow Global Technologies Llc Coating composition and articles made therefrom
US8158711B2 (en) 2003-08-25 2012-04-17 Dow Global Technologies Llc Aqueous dispersion, its production method, and its use
US9169406B2 (en) 2003-08-25 2015-10-27 Dow Global Technologies Llc Coating compositions
US7947776B2 (en) 2003-08-25 2011-05-24 Dow Global Technologies Llc Aqueous dispersion, its production method, and its use
US7034157B2 (en) * 2003-10-23 2006-04-25 Fina Technology, Inc. Catalyst components, process for their preparation and their use as catalyst components in polymerization of olefins
US7579416B2 (en) * 2003-12-23 2009-08-25 Basell Polyolefine Gmbh Catalyst system for olefin polymerization
US7211536B2 (en) * 2004-10-22 2007-05-01 Fina Technology, Inc. Supported metallocene catalysts and their use in producing stereospecific polymers
EP1805229A1 (de) 2004-10-28 2007-07-11 Dow Gloval Technologies Inc. Verfahren zur steuerung eines polymerisierungsreaktors
WO2006049699A1 (en) 2004-10-29 2006-05-11 Exxonmobil Chemical Patents Inc Catalyst compound containing divalent tridentate ligand
US7588706B2 (en) 2004-12-16 2009-09-15 Exxonmobil Chemical Patents Inc. Multi-layer films with improved properties
KR20070087670A (ko) 2004-12-21 2007-08-28 다우 글로벌 테크놀로지스 인크. 폴리프로필렌-기재의 접착제 조성물
US7053163B1 (en) 2005-02-22 2006-05-30 Fina Technology, Inc. Controlled comonomer distribution along a reactor for copolymer production
US20070080483A1 (en) * 2005-10-07 2007-04-12 Mitsui Chemicals, Inc. Process for producing injection molded product
US20070225423A1 (en) * 2005-10-07 2007-09-27 Mitsui Chemicals, Inc. Process for producing blow molded product by blow molding
US7605208B2 (en) 2005-10-31 2009-10-20 Mitsui Chemicals, Inc. Process for producing thermoplastic resin composition
EP1803747A1 (de) 2005-12-30 2007-07-04 Borealis Technology Oy Oberflächemodifizierte Polymerisationskatalysatoren zur Herstellung von Polyolefinfilmen mit niedrigem Gelgehalt
CN102786619B (zh) 2006-05-17 2015-01-07 陶氏环球技术有限责任公司 乙烯/α-烯烃/二烯溶液聚合法
US7985804B2 (en) 2006-11-06 2011-07-26 Exxonmobil Chemical Patents Inc. Rubber toughened compositions, articles, films, and methods of making the same
US8143352B2 (en) 2006-12-20 2012-03-27 Exxonmobil Research And Engineering Company Process for fluid phase in-line blending of polymers
JP5507263B2 (ja) 2007-03-07 2014-05-28 ダウ グローバル テクノロジーズ エルエルシー 固定化されている担持された遷移金属錯体
TW200932762A (en) 2007-10-22 2009-08-01 Univation Tech Llc Polyethylene compositions having improved properties
US7906588B2 (en) 2007-10-26 2011-03-15 Exxonmobil Chemical Patents Inc. Soft heterogeneous isotactic polypropylene compositions
TW200936619A (en) 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
WO2009067337A1 (en) 2007-11-19 2009-05-28 Dow Global Technologies Inc. Long chain branched propylene-alpha-olefin copolymers
US9938400B2 (en) 2008-04-23 2018-04-10 Exxonmobil Chemical Patents Inc. Propylene copolymers in soft thermoplastic blends
US8242198B2 (en) 2008-06-09 2012-08-14 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions
US8664129B2 (en) 2008-11-14 2014-03-04 Exxonmobil Chemical Patents Inc. Extensible nonwoven facing layer for elastic multilayer fabrics
US9168718B2 (en) 2009-04-21 2015-10-27 Exxonmobil Chemical Patents Inc. Method for producing temperature resistant nonwovens
US10161063B2 (en) 2008-09-30 2018-12-25 Exxonmobil Chemical Patents Inc. Polyolefin-based elastic meltblown fabrics
US9498932B2 (en) 2008-09-30 2016-11-22 Exxonmobil Chemical Patents Inc. Multi-layered meltblown composite and methods for making same
WO2010074815A1 (en) 2008-12-15 2010-07-01 Exxonmobil Chemical Patents Inc. Thermoplastic olefin compositions
MX2011009060A (es) 2009-02-27 2011-11-18 Exxonmobil Chem Patents Inc Laminados no tejidos in situ, de capas multiples, y metodo de producir los mismos.
US8378042B2 (en) 2009-04-28 2013-02-19 Exxonmobil Chemical Patents Inc. Finishing process for amorphous polymers
US9127151B2 (en) 2009-04-28 2015-09-08 Exxonmobil Chemical Patents Inc. Polymer compositions having improved properties as viscosity index improvers and use thereof in lubricating oils
US20120028865A1 (en) 2010-07-28 2012-02-02 Sudhin Datta Viscosity Modifiers Comprising Blends of Ethylene-Based Copolymers
IN2012DN02445A (de) 2009-10-02 2015-08-21 Exxonmobil Chem Patents Inc
BR112012009098B1 (pt) 2009-10-19 2018-05-22 Sasol Technology PTY Oligomerização de compostos olefínicos com formação reduzida de polímero
US8668975B2 (en) 2009-11-24 2014-03-11 Exxonmobil Chemical Patents Inc. Fabric with discrete elastic and plastic regions and method for making same
WO2011090861A1 (en) 2010-01-22 2011-07-28 Exxonmobil Chemical Patents Inc. Lubricating oil compositions and method for making them
CN102725319B (zh) 2010-01-27 2014-10-15 埃克森美孚化学专利公司 共聚物、其组合物及制造它们的方法
BR112012022809A2 (pt) 2010-03-12 2018-05-15 Exxonmobil Chemical Patents Inc construções de laminado soprado por fusão elástico e métodos para fazer as mesmas
SG186165A1 (en) 2010-07-28 2013-01-30 Exxonmobil Chem Patents Inc Viscosity modifiers comprising blends of ethylene-based copolymers
SG186167A1 (en) 2010-07-28 2013-01-30 Exxonmobil Chem Patents Inc Ethylene based copolymer compositions as viscosity modifiers and methods for making them
KR101442434B1 (ko) 2010-07-28 2014-09-17 엑손모빌 케미칼 패턴츠 인코포레이티드 에틸렌계 공중합체의 블렌드를 포함하는 점도 개질제
EP2688922A4 (de) 2011-03-25 2015-03-04 Exxonmobil Chem Patents Inc Durch alkenmetathese hergestellte amphiphile blockpolymere
JP5826913B2 (ja) 2011-03-25 2015-12-02 エクソンモービル ケミカル パテンツ インコーポレイテッド ビニル末端高級オレフィンポリマー及びその製造方法
US8658556B2 (en) 2011-06-08 2014-02-25 Exxonmobil Chemical Patents Inc. Catalyst systems comprising multiple non-coordinating anion activators and methods for polymerization therewith
US10316176B2 (en) 2012-02-03 2019-06-11 Exxonmobil Chemical Patents Inc. Polymer compositions and methods of making them
US9139794B2 (en) 2012-02-03 2015-09-22 Exxonmobil Chemical Patents Inc. Process for the production of polymeric compositions useful as oil modifiers
WO2013115912A1 (en) 2012-02-03 2013-08-08 Exxonmobil Chemical Patents Inc. Process for the production of polymeric compositions useful as oil modifiers
KR102177644B1 (ko) 2012-12-28 2020-11-11 다우 글로벌 테크놀로지스 엘엘씨 코팅 조성물 및 그로부터 제조된 물품
KR102146702B1 (ko) 2012-12-28 2020-08-21 다우 글로벌 테크놀로지스 엘엘씨 코팅 조성물
KR102038178B1 (ko) 2013-01-18 2019-10-29 다우 글로벌 테크놀로지스 엘엘씨 고분자량 폴리올레핀을 위한 중합 방법
US10548367B2 (en) 2013-01-29 2020-02-04 Exxonmobil Chemical Patents Inc. Footwear sole comprising a propylene-based elastomer, footwear comprising said sole, and methods of making them
WO2015056787A1 (ja) 2013-10-18 2015-04-23 三井化学株式会社 エチレン・α－オレフィン共重合体を含有する接着剤
EP3106475B1 (de) 2014-02-13 2019-08-28 Mitsui Chemicals, Inc. Verfahren zur herstellung von ethylen-/alpha-olefin-copolymeren
KR101909799B1 (ko) 2014-02-28 2018-10-18 미쓰이 가가쿠 가부시키가이샤 가교체와 그의 제조 방법 및 용도, 및 에틸렌계 공중합체
EP3124506B1 (de) 2014-03-28 2022-06-22 Mitsui Chemicals, Inc. Olefinharz und verfahren zur herstellung davon
WO2015147215A1 (ja) 2014-03-28 2015-10-01 三井化学株式会社 エチレン／α－オレフィン共重合体および潤滑油
CN106795449B (zh) 2014-09-10 2020-08-07 三井化学株式会社 润滑油组合物
WO2016039416A1 (ja) 2014-09-11 2016-03-17 三井化学株式会社 １－ブテン由来の構成単位を含むオレフィン（共）重合体の製造方法
EP3218426B1 (de) 2014-11-12 2022-03-30 ExxonMobil Chemical Patents Inc. Reinigung eines weichmachers und verwendung davon in polymerherstellungsverfahren und -anlage
US9670346B2 (en) 2014-12-09 2017-06-06 Mitsui Chemicals, Inc. Propylene-based resin composition
JP6439039B2 (ja) 2015-03-20 2018-12-19 三井化学株式会社 熱可塑性エラストマー組成物、その用途、その製造方法、エチレン・α−オレフィン・非共役ポリエン共重合体およびその用途
US10647626B2 (en) 2016-07-12 2020-05-12 Chevron Phillips Chemical Company Lp Decene oligomers
JP6710780B2 (ja) 2016-12-27 2020-06-17 三井化学株式会社 潤滑油組成物、潤滑油用粘度調整剤、および潤滑油用添加剤組成物
CN110072981B (zh) 2017-01-16 2022-02-25 三井化学株式会社 汽车齿轮用润滑油组合物
WO2019027524A1 (en) 2017-08-02 2019-02-07 Exxonmobil Chemical Patents Inc. MULTILAYER FILMS AND METHODS OF MANUFACTURE
US11905348B2 (en) 2018-03-20 2024-02-20 Mitsui Chemicals, Inc. Ethylene/alpha-olefin/non-conjugated polyene copolymer, method for producing the same, and use thereof
US11447584B2 (en) 2018-03-30 2022-09-20 Dow Global Technologies Llc Olefin polymerization activators
EP3774937A1 (de) 2018-03-30 2021-02-17 Dow Global Technologies LLC Hochlösliches alkylsubstituiertes carbeniumborat als co-katalysatoren für olefinpolymerisationen
WO2019190925A1 (en) 2018-03-30 2019-10-03 Dow Global Technologies Llc Binuclear olefin polymerization activators
US11447586B2 (en) 2018-03-30 2022-09-20 Dow Global Technologies Llc Olefin polymerization activators
CN112437790A (zh) 2018-06-13 2021-03-02 埃克森美孚化学专利公司 聚烯烃共混物组合物
WO2020056119A1 (en) 2018-09-14 2020-03-19 Fina Technology, Inc. Polyethylene and controlled rheology polypropylene polymer blends and methods of use
WO2020172306A1 (en) 2019-02-20 2020-08-27 Fina Technology, Inc. Polymer compositions with low warpage
US11873462B2 (en) 2019-08-29 2024-01-16 Mitsui Chemicals, Inc. Lubricating oil composition
US20220340723A1 (en) 2021-04-26 2022-10-27 Fina Technology, Inc. Thin Single-Site Catalyzed Polymer Sheets

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
IL85097A (en) * 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US4794096A (en) * 1987-04-03 1988-12-27 Fina Technology, Inc. Hafnium metallocene catalyst for the polymerization of olefins
US4975403A (en) * 1987-09-11 1990-12-04 Fina Technology, Inc. Catalyst systems for producing polyolefins having a broad molecular weight distribution
US5155080A (en) * 1988-07-15 1992-10-13 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
US5162278A (en) * 1988-07-15 1992-11-10 Fina Technology, Inc. Non-bridged syndiospecific metallocene catalysts and polymerization process
US4892851A (en) * 1988-07-15 1990-01-09 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
EP0423100A3 (en) * 1989-10-10 1991-08-07 Fina Technology, Inc. Process and catalyst for producing syndiotactic polymers
DE69018376T3 (de) * 1989-10-30 2002-05-16 Fina Technology Herstellung von Metallocenkatalysatoren für Olefinpolymerisation.
CA2066247C (en) * 1990-07-24 1998-09-15 Ryuichi Sugimoto Polymerization catalyst for .alpha.-olefin and method for preparing poly-.alpha.-olefin by using it
WO1992009640A1 (en) * 1990-11-30 1992-06-11 Idemitsu Kosan Co., Ltd. Process for producing olefinic polymer
JP2888648B2 (ja) * 1990-12-28 1999-05-10 出光興産株式会社 スチレン系重合体の製造方法及びその触媒
JP3194438B2 (ja) * 1992-01-08 2001-07-30 出光興産株式会社 スチレン系重合体の製造方法及びその触媒
KR100292158B1 (ko) * 1992-08-04 2001-06-01 가지와라 야스시 올레핀중합용 촉매 및 올레핀의 중합방법

Also Published As

Publication number Publication date
DE69321879D1 (de) 1998-12-10
EP0573403B1 (de) 1998-11-04
ES2124777T3 (es) 1999-02-16
EP0573403A3 (en) 1994-08-17
EP0573403A2 (de) 1993-12-08
US5763549A (en) 1998-06-09
JPH06220119A (ja) 1994-08-09
JP3446059B2 (ja) 2003-09-16
US5807939A (en) 1998-09-15

Similar Documents

Publication Publication Date Title
DE69321879T2 (de) Kationische Metallocenkatalysatoren auf Basis von Triphenylcarbeniumaluminium
DE69326463T2 (de) Olefinpolymerisationskatalysatoren auf basis von uebergangsmetallen
DE69503070D1 (de) Auf borabenzol basierter olefinpolymerisationskatalysator
BR9510288A (pt) Catalisadores de polimerização de azametaloceno
DE59409647D1 (de) Trägerkatalysatoren
DE69735068D1 (de) Heterocyclische Metallocne und Polymerisationskatalysatoren
DE9404954U1 (de) Katalysator
DE69534409D1 (de) Derivate auf Basis von Polyvinylpyridin
DE69518324D1 (de) Hochaktive polyäthylenkatalysatoren
DE69514803T2 (de) Olefinpolymerisationskatalysator
NO933427L (no) Etylenpolymerisasjonsprosess
DE69326256T2 (de) Hochaktive polyethylenkatalysatoren
NO891345D0 (no) Ziegler-natta-katalysator.
DE69301547T2 (de) Elektrisch heizbarer katalytischer Umwandler
DE59501207D1 (de) Geträgerte Metallocen-Katalysatorsysteme
DE59506210D1 (de) Geträgerte Metallocen-Katalysatorsysteme
DE69520449T2 (de) Olefinpolymerisationskatalysator
DE9313593U1 (de) Katalysatoranordnung
DE59804442D1 (de) Katalysatoren auf basis von fulven-metallkomplexen
DE59304643D1 (de) Kationische Triazatrimethinfarbstoffe
DE69306117T2 (de) Epoxydierungskatalysator
DE59807157D1 (de) Katalysatorsystem auf Basis von Monoazadien-Metallkomplexen
DK0665985T3 (da) Platin-rhodium-jern-katalysator
DE69325857T2 (de) Olefinpolymerisation, Katalysator und Vorprodukt
DE69309967T2 (de) Diarylcarbinol metathesekatalysatoren

Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8328 Change in the person/name/address of the agent

Representative=s name: ACKMANN MENGES PATENT- UND RECHTSANWAELTE, 80469 M

R082 Change of representative

Ref document number: 573403

Country of ref document: EP

Representative=s name: SCHUMACHER & WILLSAU PATENTANWALTSGESELLSCHAFT, DE