DE69409690T2 - Katalysatorbestandteil für Alpha-olefinpolymerisation und Verfahren zur Herstellung von Alpha-olefinpolymere unter Anwendung derselben - Google Patents

Katalysatorbestandteil für Alpha-olefinpolymerisation und Verfahren zur Herstellung von Alpha-olefinpolymere unter Anwendung derselben

Info

Publication number
DE69409690T2
DE69409690T2 DE69409690T DE69409690T DE69409690T2 DE 69409690 T2 DE69409690 T2 DE 69409690T2 DE 69409690 T DE69409690 T DE 69409690T DE 69409690 T DE69409690 T DE 69409690T DE 69409690 T2 DE69409690 T2 DE 69409690T2
Authority
DE
Germany
Prior art keywords
alpha
olefin
same
catalyst component
producing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69409690T
Other languages
English (en)
Other versions
DE69409690D1 (de
Inventor
Toshihiko Sugano
Toru Wada
Tomohiko Takahama
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical Corp
Original Assignee
Mitsubishi Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Chemical Corp filed Critical Mitsubishi Chemical Corp
Application granted granted Critical
Publication of DE69409690D1 publication Critical patent/DE69409690D1/de
Publication of DE69409690T2 publication Critical patent/DE69409690T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
DE69409690T 1993-02-19 1994-02-18 Katalysatorbestandteil für Alpha-olefinpolymerisation und Verfahren zur Herstellung von Alpha-olefinpolymere unter Anwendung derselben Expired - Fee Related DE69409690T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP03093193A JP3293927B2 (ja) 1993-02-19 1993-02-19 α‐オレフィン重合用触媒成分およびそれを用いたα‐オレフィン重合体の製造法

Publications (2)

Publication Number Publication Date
DE69409690D1 DE69409690D1 (de) 1998-05-28
DE69409690T2 true DE69409690T2 (de) 1998-08-20

Family

ID=12317430

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69409690T Expired - Fee Related DE69409690T2 (de) 1993-02-19 1994-02-18 Katalysatorbestandteil für Alpha-olefinpolymerisation und Verfahren zur Herstellung von Alpha-olefinpolymere unter Anwendung derselben

Country Status (4)

Country Link
US (1) US5489659A (de)
EP (1) EP0611773B1 (de)
JP (1) JP3293927B2 (de)
DE (1) DE69409690T2 (de)

Families Citing this family (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6265338B1 (en) * 1989-09-13 2001-07-24 Exxon Chemical Patents, Inc. Monocyclopentadienyl titanium metal compounds for ethylene-α-olefin copolymer production catalysts
JP3241079B2 (ja) * 1992-02-24 2001-12-25 株式会社日立製作所 ディジタル位相同期回路
EP1209165B1 (de) * 1993-06-07 2006-04-19 Mitsui Chemicals, Inc. Propylenelastomere
JP3338190B2 (ja) * 1994-08-17 2002-10-28 三菱化学株式会社 α‐オレフィン重合用触媒成分およびそれを用いたα‐オレフィン重合体の製造法
DE19517851A1 (de) * 1995-05-16 1996-11-21 Hoechst Ag Organometallverbindung
KR19990028461A (ko) * 1995-06-28 1999-04-15 알베르투스 빌헬무스 요아네스 ㅔ스트라텐 유기금속 화합물을 포함한 촉매 조성물
DE19527047A1 (de) * 1995-07-25 1997-01-30 Danubia Petrochem Deutschland Metallocene mit silylsubstituierten Brücken und deren Einsatz für die Olefinpolymerisation
US5756609A (en) * 1995-10-19 1998-05-26 Amoco Corporation Homogeneous metallocene-based olefin polymerization system with increased activity
WO1997020872A1 (en) * 1995-12-07 1997-06-12 Exxon Chemical Patents Inc. Tackifiers and a process to obtain tackifiers
RU2178422C2 (ru) * 1996-03-27 2002-01-20 Дзе Дау Кемикал Компани Активатор катализаторов полимеризации олефинов, каталитическая система и способ полимеризации
DE19644039A1 (de) * 1996-10-31 1998-05-07 Hoechst Ag Metallocene
EP0846696B1 (de) 1996-12-09 2003-06-18 Mitsubishi Chemical Corporation Katalysator für Alpha-Olefinpolymerisation
IT1290856B1 (it) * 1996-12-19 1998-12-14 Enichem Spa Metalloceni, loro preparazione ed uso nella polimerizzazione di alfa-olefine
US6451938B1 (en) 1997-02-25 2002-09-17 Exxon Mobil Chemical Patents Inc. Polymerization catalyst system comprising heterocyclic fused cyclopentadienide ligands
US6030918A (en) * 1997-06-25 2000-02-29 The Regents Of The University Of California Gallium based low-interaction anions
NL1012219C2 (nl) * 1998-06-19 2000-04-13 Ciba Sc Holding Ag Werkwijze voor de polymersitie van overzadigde polyalkylpiperidinen.
US6664208B1 (en) 1999-09-07 2003-12-16 Sumitomo Chemical Company, Limited Modified aluminum oxy compound, polymerization catalyst and process for producing olefin polymer and alkenyl aromatic hydrocarbon polymer
US6194527B1 (en) * 1999-09-22 2001-02-27 Equistar Chemicals, L.P. Process for making polyolefins
DE60006146T2 (de) 1999-11-04 2004-09-30 Exxonmobil Chemical Patents Inc., Baytown Propylencopolymerschäume und deren verwendung
US6444833B1 (en) 1999-12-15 2002-09-03 Basell Technology Company Bv Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins
WO2001046278A2 (en) 1999-12-21 2001-06-28 Exxon Chemical Patents Inc. Adhesive alpha-olefin inter-polymers
US6806327B2 (en) 2000-06-30 2004-10-19 Dow Global Technologies Inc. Substituted polycyclic, fused ring compounds, metal complexes and polymerization process
DE60138708D1 (de) 2000-06-30 2009-06-25 Dow Global Technologies Inc Polyzyklische, kondensierte ringverbindungen, meta
FR2813079B1 (fr) * 2000-08-18 2003-07-25 Atofina Ligands avec au moins un substituant fluorosilicone pour la preparation de metallocenes
US8008412B2 (en) * 2002-09-20 2011-08-30 Exxonmobil Chemical Patents Inc. Polymer production at supersolution conditions
US20080153997A1 (en) * 2006-12-20 2008-06-26 Exxonmobil Research And Engineering Polymer production at supercritical conditions
US7195806B2 (en) 2003-01-17 2007-03-27 Fina Technology, Inc. High gloss polyethylene articles
DE102004027332A1 (de) * 2004-06-04 2005-12-22 Basell Polyolefine Gmbh Übergangsmetallverbindung, Ligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
US7709670B2 (en) * 2004-12-16 2010-05-04 Exxonmobil Chemical Patents Inc. Process for producing substituted metallocene compounds for olefin polymerization
US7550544B2 (en) 2005-12-14 2009-06-23 Exxonmobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
US7868197B2 (en) 2005-12-14 2011-01-11 Exxonmobil Chemical Patents Inc. Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization
US7667064B2 (en) * 2005-12-14 2010-02-23 Exxonmobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
US7538168B2 (en) 2005-12-14 2009-05-26 Exxonmobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
US7763562B2 (en) * 2005-12-14 2010-07-27 Exxonmobil Chemical Patents Inc. Heteroatom bridged metallocene compounds for olefin polymerization
US8242237B2 (en) 2006-12-20 2012-08-14 Exxonmobil Chemical Patents Inc. Phase separator and monomer recycle for supercritical polymerization process
ES2446294T3 (es) * 2007-06-04 2014-03-07 Exxonmobil Chemical Patents Inc. Polimerización de propileno en un sistema homogéneo en condiciones de superdisolución
US8318875B2 (en) * 2008-01-18 2012-11-27 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization and polypropylenes made therefrom
US7812104B2 (en) * 2008-01-18 2010-10-12 Exxonmobil Chemical Patents Inc. Production of propylene-based polymers
EP3042990B1 (de) 2010-11-16 2017-05-10 Adeka Corporation Verfahren zur stabilisierung von polymer für ein langzeitverfahren zur herstellung von vliesstoff und verfahren zur herstellung einer elastomerzusammensetzung
JPWO2012117823A1 (ja) 2011-03-02 2014-07-07 株式会社Adeka ラミネートフィルムおよび塗装部材用樹脂組成物の製造方法
EP2573091A1 (de) 2011-09-23 2013-03-27 Lummus Novolen Technology Gmbh Verfahren zur Wiedergewinnung freier Liganden aus ihren jeweiligen Metallocenkomplexen
JP2013199551A (ja) 2012-03-23 2013-10-03 Adeka Corp 家電材料用及び自動車内装材料用オレフィン樹脂組成物の製造方法
WO2015060257A1 (ja) 2013-10-21 2015-04-30 株式会社Adeka 安定化されたポリマーの製造方法
US20200087495A1 (en) 2018-09-14 2020-03-19 Fina Technology, Inc. Polyethylene and controlled rheology polypropylene polymer blends and methods of use
MX2021006769A (es) 2019-02-20 2021-07-15 Fina Technology Composiciones de polimero con baja distorsion.
WO2022232123A1 (en) 2021-04-26 2022-11-03 Fina Technology, Inc. Thin single-site catalyzed polymer sheets

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5120867A (en) * 1988-03-21 1992-06-09 Welborn Jr Howard C Silicon-bridged transition metal compounds
DE3840772A1 (de) * 1988-12-03 1990-06-07 Hoechst Ag Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente
JP2893743B2 (ja) * 1989-08-10 1999-05-24 三菱化学株式会社 α―オレフイン重合体の製造
DE4039451A1 (de) * 1990-12-11 1992-06-17 Hoechst Ag Metallocene mit bicyclischen cyclopentadienderivaten als liganden, verfahren zu ihrer herstellung und ihre verwendung als katalysatoren
JP3402473B2 (ja) * 1991-08-20 2003-05-06 日本ポリケム株式会社 オレフィン重合用触媒
DE4211086A1 (de) * 1992-04-03 1993-10-07 Basf Ag Katalysatorsysteme zur Polymerisation von C¶2¶- bis C¶1¶¶0¶-Alk-1-enen

Also Published As

Publication number Publication date
JPH06239915A (ja) 1994-08-30
JP3293927B2 (ja) 2002-06-17
EP0611773B1 (de) 1998-04-22
US5489659A (en) 1996-02-06
EP0611773A3 (de) 1994-11-09
EP0611773A2 (de) 1994-08-24
DE69409690D1 (de) 1998-05-28

Similar Documents

Publication Publication Date Title
DE69409690D1 (de) Katalysatorbestandteil für Alpha-olefinpolymerisation und Verfahren zur Herstellung von Alpha-olefinpolymere unter Anwendung derselben
DE69418742T2 (de) Katalysatorbestandteil für alpha-Olefinpolymerisation und Verfahren zur Herstellung von alpha-Olefinpolymeren unter Anwendung derselben
DE69500979D1 (de) Katalysatorbestandteil für alpha-Olefinpolymerisation und Verfahren zur Herstellung von alpha-Olefinpolymeren unter Anwendung desselben
DE69603811T2 (de) Träger für Olefinpolymerisationkatalysator, Olefinpolymerisationkatalysator und Verfahren zur Herstellung von Olefinpolymeren
DE69520332T2 (de) Katalysator zur Polymerisation von Olefinen und Verfahren zur Herstellung von Polyolefinen unter dessen Verwendung
DE69600892T2 (de) Katalysatoren für Olefinpolymerisation und Verfahren zur Herstellung von damit erhaltenen Olefinpolymeren
DE69502361T2 (de) Katalysatorbestandteil für Alpha-Olefinpolymerisation und Verfahren zur Herstellung von Alpha-Olefinpolymeren unter Anwendung desselben
DE69404257T2 (de) Verfahren zur Herstellung von alpha-Olefinpolymeren
DE69714830D1 (de) Olefinpolymerisationskatalysatore und Verfahren zur Herstellung von Olefinpolymeren
DE69502312D1 (de) Ethylenpolymer und Verfahren zur Herstellung desselben
DE69605372D1 (de) Katalysatorbestandteil für Olefinpolymerisation, Katalysator für Olefinpolymerisation, und Verfahren zur Herstellung von Olefinpolymeren
DE69326560D1 (de) Polymerisationskatalysator und verfahren zur herstellung von polymeren unter dessen verwendung
DE69426665D1 (de) Katalysator für die Herstellung von vinylaromatischem Polymer und Verfahren zur Herstellung von vinylaromatischem Polymer unter Anwendung desselben
DE69504237T2 (de) Titankatalysator-Feststoff für Olefinpolymerisation, Verfahren zur Herstellung desselben, Olefinpolymerisationskatalysator und Verfahren zur Olefinpolymerisation
DE69407522D1 (de) Katalysator zur Polymerisation von Olefin und Verfahren zur Herstellung von Polyolefin
DE69533310D1 (de) Verfahren zur herstellung von ethylenpolymer und ethylenpolymer
DE69621373T2 (de) Verfahren zur Herstellung von Alpha-Olefin-Polymerisationskatalysatoren und Verfahren zur Herstellung eines Alpha-Olefin-Polymers
DE69702434D1 (de) Olefinpolymerisationskatalysator und Verfahren zur Herstellung von Polyolefinen unter Verwendung desselben
DE69605845T2 (de) Olefinpolymerisationkatalysator und Verfahren zur Herstellung von Polyolefinen unter Verwendung desselben
DE69908452D1 (de) Katalysator für Olefinpolymerisation und Verfahren zur Herstellung von Olefinpolymer unter Verwendung desselben
DE69601760T2 (de) Katalysator für die Olefinpolymerisation und Verfahren zur Herstellung von Olefinpolymeren unter Verwendung desselben
DE69528689T2 (de) Olefinpolymerisationskatalysator und Verfahren zur Herstellung von Polyolefinen
DE69605349T2 (de) Olefinpolymerisationkatalysator und Verfahren zur Herstellung von Polyolefinen
DE69612214D1 (de) Polymerisationskatalysator und verfahren zur herstellung von polymeren
DE69509051T2 (de) 1,1,2,2-Tetramethylpropylperoxyester und Verfahren zur Herstellung von Vinylpolymeren

Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee