DE69413904T2 - Olefinpolymerisationskatalysatoren und Methoden zur Olefinpolymerisation - Google Patents

Olefinpolymerisationskatalysatoren und Methoden zur Olefinpolymerisation

Info

Publication number
DE69413904T2
DE69413904T2 DE69413904T DE69413904T DE69413904T2 DE 69413904 T2 DE69413904 T2 DE 69413904T2 DE 69413904 T DE69413904 T DE 69413904T DE 69413904 T DE69413904 T DE 69413904T DE 69413904 T2 DE69413904 T2 DE 69413904T2
Authority
DE
Germany
Prior art keywords
olefin polymerization
methods
catalysts
polymerization catalysts
olefin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69413904T
Other languages
English (en)
Other versions
DE69413904D1 (de
Inventor
Toshiyuki Tsutsui
Ken Yoshitsugu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Chemicals Inc
Original Assignee
Mitsui Chemicals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP19861093A external-priority patent/JP3465310B2/ja
Priority claimed from JP19860993A external-priority patent/JP3465309B2/ja
Application filed by Mitsui Chemicals Inc filed Critical Mitsui Chemicals Inc
Application granted granted Critical
Publication of DE69413904D1 publication Critical patent/DE69413904D1/de
Publication of DE69413904T2 publication Critical patent/DE69413904T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
DE69413904T 1993-08-10 1994-08-10 Olefinpolymerisationskatalysatoren und Methoden zur Olefinpolymerisation Expired - Fee Related DE69413904T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP19861093A JP3465310B2 (ja) 1993-08-10 1993-08-10 オレフィン重合触媒の調製方法、オレフィン重合触媒およびオレフィンの重合方法
JP19860993A JP3465309B2 (ja) 1993-08-10 1993-08-10 オレフィン重合触媒の調製方法、オレフィン重合触媒およびオレフィンの重合方法

Publications (2)

Publication Number Publication Date
DE69413904D1 DE69413904D1 (de) 1998-11-19
DE69413904T2 true DE69413904T2 (de) 1999-04-08

Family

ID=26511079

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69413904T Expired - Fee Related DE69413904T2 (de) 1993-08-10 1994-08-10 Olefinpolymerisationskatalysatoren und Methoden zur Olefinpolymerisation

Country Status (6)

Country Link
US (2) US5539069A (de)
EP (1) EP0638595B1 (de)
KR (1) KR100312700B1 (de)
CN (1) CN1048502C (de)
CA (1) CA2129794A1 (de)
DE (1) DE69413904T2 (de)

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US5585184A (en) * 1994-09-29 1996-12-17 Union Carbide Chemicals & Plastics Technology Corporation Colorable non-sticky resin core-shell particles
DE69510812T2 (de) * 1994-10-13 2000-04-20 Exxon Chemical Patents Inc Verfahren zur herstellung von polymerisationskatalysatorsystemen und ihre verwendung
US6140432A (en) * 1995-07-13 2000-10-31 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
EP0785956B1 (de) * 1994-10-13 1999-04-28 Exxon Chemical Patents Inc. Polymerisation Katalysatorsysteme, ihre Herstellung und ihre Verwendung
EP0754706B1 (de) * 1995-07-08 1998-08-05 PCD-Polymere Gesellschaft m.b.H. Trägerkatalysator für die Polymerisation und seine Verwendung für die Olefinpolymerisation
EP0757995A1 (de) * 1995-07-08 1997-02-12 PCD-Polymere Gesellschaft m.b.H. Geträgerter Polymerisationkatalysator und dessen Verwendung für die Olefinpolymerisation
SG64939A1 (en) * 1995-07-17 2002-02-19 Mitsui Chemicals Inc Olefin polymerization catalyst, process for preparing olefin polymer, and olefin polymer
US5635437A (en) * 1995-07-28 1997-06-03 Exxon Chemicals Patents, Inc. Method for preparing metallocene catalyst systems
AU1295397A (en) * 1995-12-29 1997-07-28 Exxon Chemical Patents Inc. Slurry polymerization process
KR100466733B1 (ko) * 1996-07-23 2005-01-24 다우 글로벌 테크놀로지스 인크. 13족 화합물을 포함하는 올레핀 중합 촉매 조성물
US5756611A (en) * 1997-02-21 1998-05-26 Lyondell Petrochemical Company α-olefin polymerization catalysts
US6159889A (en) * 1997-12-09 2000-12-12 Union Carbide Chemicals & Plastics Technology Corporation Unbridged monocyclopentadienyl metal complex catalyst and a process for polyolefin production
US6127302A (en) * 1997-12-09 2000-10-03 Union Carbide Chemicals & Plastics Technology Corporation Unbridged monocyclopentadienyl metal complex catalyst and a process for polyolefin production
WO2000004057A1 (en) * 1998-07-17 2000-01-27 Bp Chemicals Limited Method for preparing an activator for the polymerisation of olefins
US6180735B1 (en) * 1998-12-17 2001-01-30 Univation Technologies Catalyst composition and methods for its preparation and use in a polymerization process
US6339134B1 (en) 1999-05-06 2002-01-15 Univation Technologies, Llc Polymerization process for producing easier processing polymers
US6281306B1 (en) 1999-12-16 2001-08-28 Univation Technologies, Llc Method of polymerization
US6713573B2 (en) 2000-11-30 2004-03-30 Univation Technologies, Llc Catalyst modifiers and their use in the polymerization of olefin(s)
GB0220681D0 (en) 2002-09-05 2002-10-16 Borealis Tech Oy Process
ES2394304T3 (es) 2002-10-15 2013-01-30 Exxonmobil Chemical Patents, Inc. Sistema de múltiples catalizadores para la polimerización de olefinas y polímeros producidos a partir de éstos
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
JP4742221B2 (ja) 2003-03-21 2011-08-10 ダウ グローバル テクノロジーズ エルエルシー モルホロジー制御オレフィン重合プロセス
US6710005B1 (en) * 2003-04-10 2004-03-23 Equistar Chemicals, Lp Aluminoxane modification
US6844402B1 (en) 2003-12-11 2005-01-18 Equistar Chemicals, Lp Preparation of olefin-acrylic copolymers with late transition metal catalysts
US6903169B1 (en) 2003-12-30 2005-06-07 Equistar Chemicals, Lp LTMC polymerization of unsaturated monomers
US7985811B2 (en) 2004-01-02 2011-07-26 Univation Technologies, Llc Method for controlling sheeting in gas phase reactors
US20070073012A1 (en) 2005-09-28 2007-03-29 Pannell Richard B Method for seed bed treatment before a polymerization reaction
US7125939B2 (en) * 2004-08-30 2006-10-24 Equistar Chemicals, Lp Olefin polymerization with polymer bound single-site catalysts
EP1803747A1 (de) 2005-12-30 2007-07-04 Borealis Technology Oy Oberflächemodifizierte Polymerisationskatalysatoren zur Herstellung von Polyolefinfilmen mit niedrigem Gelgehalt
TW200932762A (en) 2007-10-22 2009-08-01 Univation Tech Llc Polyethylene compositions having improved properties
RU2479593C2 (ru) 2007-12-18 2013-04-20 Юнивейшн Текнолоджиз, Ллк Способ регулирования активности бимодального катализатора в процессе полимеризации
EP3224287B1 (de) 2014-11-25 2019-05-01 Univation Technologies, LLC Verfahren zur steuerung des polyolefinschmelzindex
KR101689456B1 (ko) * 2015-01-23 2016-12-23 한화토탈 주식회사 에틸렌계 공중합체 및 이의 제조
KR102428722B1 (ko) * 2020-01-17 2022-08-04 주식회사 디에스엔프라 와이어 하네스용 전선 구조체
WO2022232760A1 (en) 2021-04-30 2022-11-03 Exxonmobil Chemical Patents Inc. Processes for transitioning between different polymerization catalysts in a polymerization reactor
CN115894745B (zh) * 2021-09-30 2023-09-12 中国石油化工股份有限公司 催化剂组合物、烯烃聚合方法和应用
KR20230134862A (ko) * 2022-03-15 2023-09-22 엘에스전선 주식회사 손실 저감 케이블

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Also Published As

Publication number Publication date
US5539069A (en) 1996-07-23
KR950005853A (ko) 1995-03-20
CA2129794A1 (en) 1995-02-11
US5543377A (en) 1996-08-06
CN1100429A (zh) 1995-03-22
EP0638595B1 (de) 1998-10-14
EP0638595A3 (de) 1995-04-26
KR100312700B1 (ko) 2001-12-28
CN1048502C (zh) 2000-01-19
EP0638595A2 (de) 1995-02-15
DE69413904D1 (de) 1998-11-19

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