DE69419326D1 - Katalysatorzusammensetzungen und Verfahren zur Herstellung von Polyolefinen - Google Patents

Katalysatorzusammensetzungen und Verfahren zur Herstellung von Polyolefinen

Info

Publication number
DE69419326D1
DE69419326D1 DE69419326T DE69419326T DE69419326D1 DE 69419326 D1 DE69419326 D1 DE 69419326D1 DE 69419326 T DE69419326 T DE 69419326T DE 69419326 T DE69419326 T DE 69419326T DE 69419326 D1 DE69419326 D1 DE 69419326D1
Authority
DE
Germany
Prior art keywords
catalyst compositions
processes
making polyolefins
complexes
polyolefins
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69419326T
Other languages
English (en)
Other versions
DE69419326T2 (de
Inventor
John Paul Mcnally
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP Chemicals Ltd
Original Assignee
BP Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP Chemicals Ltd filed Critical BP Chemicals Ltd
Application granted granted Critical
Publication of DE69419326D1 publication Critical patent/DE69419326D1/de
Publication of DE69419326T2 publication Critical patent/DE69419326T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts
DE69419326T 1993-01-19 1994-01-07 Katalysatorzusammensetzungen und Verfahren zur Herstellung von Polyolefinen Expired - Fee Related DE69419326T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB939300934A GB9300934D0 (en) 1993-01-19 1993-01-19 Metallocene complexes

Publications (2)

Publication Number Publication Date
DE69419326D1 true DE69419326D1 (de) 1999-08-12
DE69419326T2 DE69419326T2 (de) 1999-11-04

Family

ID=10728908

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69419326T Expired - Fee Related DE69419326T2 (de) 1993-01-19 1994-01-07 Katalysatorzusammensetzungen und Verfahren zur Herstellung von Polyolefinen

Country Status (13)

Country Link
US (2) US5814574A (de)
EP (1) EP0608054B1 (de)
JP (1) JP3481285B2 (de)
KR (1) KR100299701B1 (de)
CN (1) CN1087303C (de)
AT (1) ATE181930T1 (de)
CA (1) CA2113601A1 (de)
DE (1) DE69419326T2 (de)
ES (1) ES2135539T3 (de)
FI (1) FI940266A (de)
GB (1) GB9300934D0 (de)
GR (1) GR3030725T3 (de)
NO (1) NO308133B1 (de)

Families Citing this family (64)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996013529A1 (en) * 1994-10-31 1996-05-09 Dsm N.V. Catalyst composition and process for the polymerization of an olefin
DE69521984T2 (de) 1994-11-22 2002-04-04 Atofina Res Seneffe Verbrückte metallocene zur verwendung in katalysatorsystemen für die polymerisierung von olefinen
DE19517851A1 (de) * 1995-05-16 1996-11-21 Hoechst Ag Organometallverbindung
AT403376B (de) * 1995-07-03 1998-01-26 Danubia Petrochem Polymere Metallocene mit silylsubstituierten brücken und deren einsatz für die olefinpolymerisation
CN1200739A (zh) * 1995-10-27 1998-12-02 陶氏化学公司 易载持的金属配合物
US6066588A (en) * 1995-11-22 2000-05-23 Fina Research, S.A. Bridged metallocenes catalyst for polymerization of olefins
DE19602543A1 (de) 1996-01-25 1997-07-31 Basf Ag Verfahren zur Herstellung von Polymerisaten von C¶2¶- bis C¶1¶¶0¶-Alkenen in Gegenwart von Metallocenkomplexen mit kationisch funktionalisierten Cyclopentadienylliganden
US6759499B1 (en) 1996-07-16 2004-07-06 Exxonmobil Chemical Patents Inc. Olefin polymerization process with alkyl-substituted metallocenes
EP0878486B1 (de) * 1997-02-21 2006-01-25 Council of Scientific and Industrial Research Verfahren zur Herstellung eines geträgerten Metallocen-Katalysators
US6268447B1 (en) 1998-12-18 2001-07-31 Univation Technologies, L.L.C. Olefin polymerization catalyst
US6103657A (en) 1997-07-02 2000-08-15 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
GB9722447D0 (en) * 1997-10-23 1997-12-24 Borealis As Process
CN1098867C (zh) * 1998-01-14 2003-01-15 中国石油化工集团公司 淤浆法全密度聚乙烯高效催化剂
KR100358225B1 (ko) 1998-04-09 2003-01-24 주식회사 엘지화학 조촉매의 재순환이 가능한 메탈로센 촉매 중합 방법
KR100380018B1 (ko) 1998-04-09 2003-10-04 주식회사 엘지화학 메탈로센담지촉매및이를이용한올레핀중합방법
US6303719B1 (en) 1998-12-18 2001-10-16 Univation Technologies Olefin polymerization catalyst system
DE19903695A1 (de) * 1999-02-01 2000-08-03 Elenac Gmbh Verfahren zur Herstellung von Polyolefinen mit breiter Molekulargewichtsverteilung
DE19903783A1 (de) * 1999-02-01 2000-08-03 Elenac Gmbh Verfahren zur Herstellung von Polyolefinen mit breiter Molekulargewichtsverteilung
KR100354290B1 (ko) * 1999-06-22 2002-09-28 주식회사 엘지화학 담지 메탈로센 촉매 및 이를 이용한 올레핀 중합
US7247595B2 (en) * 1999-06-22 2007-07-24 Lg Chem, Ltd. Supported metallocene catalyst and olefin polymerization using the same
US7041618B2 (en) * 1999-06-22 2006-05-09 Lg Chemical Ltd. Supported metallocene catalyst and olefin polymerization using the same
US6548442B1 (en) 1999-12-03 2003-04-15 Phillips Petroleum Company Organometal compound catalyst
US6846943B2 (en) 2000-05-23 2005-01-25 Chisso Corporation Metallocene compound, olefin polymerization catalyst containing the compound, and method for producing an olefin polymer by use of the catalyst
US6723675B1 (en) * 2000-05-25 2004-04-20 Univation Technologies, Llc Catalyst for the production of olefin polymers
ATE340800T1 (de) * 2001-10-26 2006-10-15 Epichem Ltd Vorlaeuferverbindungen für chemische dampfphasenabscheidung
EP1495038B1 (de) * 2002-04-12 2008-07-23 Dow Global Technologies Inc. Azaborolylkomplexe mit metallen der gruppe 4, katalysatoren und verfahren zur olefinepolymerisation
KR101113341B1 (ko) 2002-10-15 2012-09-27 엑손모빌 케미칼 패턴츠 인코포레이티드 올레핀 중합용 다중 촉매 시스템 및 이로부터 제조된중합체
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
EP1611169B1 (de) 2003-03-21 2010-06-02 Dow Global Technologies Inc. Verfahren zur herstellung von polyolefinen mit kontrollierter morphologie
KR100690345B1 (ko) * 2004-09-03 2007-03-09 주식회사 엘지화학 담지 메탈로센 촉매, 그 제조방법 및 이를 이용한폴리올레핀의 제조방법
AU2005316788B2 (en) 2004-12-17 2012-04-05 Dow Global Technologies Llc Rheology modified polyethylene compositions
GB2432363B (en) * 2005-11-16 2010-06-23 Epichem Ltd Hafnocene and zirconocene precursors, and use thereof in atomic layer deposition
EP1803747A1 (de) 2005-12-30 2007-07-04 Borealis Technology Oy Oberflächemodifizierte Polymerisationskatalysatoren zur Herstellung von Polyolefinfilmen mit niedrigem Gelgehalt
JP5575470B2 (ja) 2006-05-02 2014-08-20 ダウ グローバル テクノロジーズ エルエルシー 高密度ポリエチレン組成物、それを作製する方法、それから作製されるワイヤおよびケーブル用ジャケット、ならびにそのようなワイヤおよびケーブル用ジャケットを作製する方法
US7456244B2 (en) * 2006-05-23 2008-11-25 Dow Global Technologies High-density polyethylene compositions and method of making the same
US7956207B2 (en) * 2006-09-28 2011-06-07 Praxair Technology, Inc. Heteroleptic organometallic compounds
CN101490163A (zh) * 2007-05-02 2009-07-22 陶氏环球技术公司 高密度聚乙烯组合物、其制备方法、由其制得的注塑制品以及该制品的制备方法
US7981517B2 (en) * 2007-08-28 2011-07-19 Dow Global Technologies Inc. Bituminous compositions and methods of making and using same
RU2515900C2 (ru) 2008-12-18 2014-05-20 Юнивейшн Текнолоджиз, Ллк Способ обработки зародышевого слоя реакции полимеризации
WO2010088265A1 (en) 2009-01-30 2010-08-05 Dow Global Technologies Inc. High-density polyethylene compositions, method of producing the same, closure devices made therefrom, and method of making such closure devices
US8530593B2 (en) 2009-10-28 2013-09-10 Exxonmobil Chemical Patents Inc. Catalyst compounds and use thereof
EP2493933A4 (de) * 2009-10-28 2013-06-12 Exxonmobil Chem Patents Inc Katalysatorverbindungen und ihre verwendung
EP2493935A4 (de) * 2009-10-28 2013-06-26 Exxonmobil Chem Patents Inc Katalysatorverbindungen und ihre verwendung
CN102666597A (zh) * 2009-10-28 2012-09-12 埃克森美孚化学专利公司 催化剂化合物和它们的用途
WO2011056423A2 (en) * 2009-10-28 2011-05-12 Exxonmobil Chemical Patents Inc. Catalyst compounds and use thereof
CN104918947A (zh) 2012-12-28 2015-09-16 尤尼威蒂恩技术有限责任公司 将铝氧烷的生产整合到催化剂生产中的方法
KR102135226B1 (ko) 2013-01-14 2020-07-20 유니베이션 테크놀로지즈, 엘엘씨 증가된 생산성을 갖는 촉매 시스템의 제조 방법
KR102006096B1 (ko) 2015-05-08 2019-07-31 엑손모빌 케미칼 패턴츠 인코포레이티드 중합 방법
WO2018063767A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018063765A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018063764A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018118155A1 (en) 2016-12-20 2018-06-28 Exxonmobil Chemical Patents Inc. Polymerization process
US11591417B2 (en) 2017-12-13 2023-02-28 Exxonmobil Chemical Patents Inc. Deactivation methods for active components from gas phase polyolefin polymerization processes
WO2019173030A1 (en) 2018-03-08 2019-09-12 Exxonmobil Chemical Patents Inc. Methods of preparing and monitoring a seed bed for polymerization reactor startup
EP3788082A1 (de) 2018-05-02 2021-03-10 ExxonMobil Chemical Patents Inc. Verfahren zur aufskalierung von einer pilotanlage zu einer grösseren produktionsanlage
WO2019213227A1 (en) 2018-05-02 2019-11-07 Exxonmobil Chemical Patents Inc. Methods for scale-up from a pilot plant to a larger production facility
WO2020014138A1 (en) 2018-07-09 2020-01-16 Exxonmobil Chemical Patents Inc. Polyethylene cast films and methods for making the same
EP3826833A1 (de) 2018-07-26 2021-06-02 ExxonMobil Chemical Patents Inc. Mehrlagige schaumstofffolien und verfahren zur herstellung davon
WO2020102380A1 (en) 2018-11-13 2020-05-22 Exxonmobil Chemical Patents Inc. Polyethylene blends and films
US20220025135A1 (en) 2018-11-13 2022-01-27 Exxonmobil Chemical Patents Inc. Polyethylene Films
WO2020163079A1 (en) 2019-02-06 2020-08-13 Exxonmobil Chemical Patents Inc. Films and backsheets for hygiene articles
WO2021126458A1 (en) 2019-12-17 2021-06-24 Exxonmobil Chemical Patents Inc. Films made of polyethylene blends for improved sealing performance and mechanical properties
WO2021183337A1 (en) 2020-03-12 2021-09-16 Exxonmobil Chemical Patents Inc. Films made of polyethylene blends for improved bending stiffness and high md tear resistance
EP4330294A1 (de) 2021-04-30 2024-03-06 ExxonMobil Chemical Patents Inc. Verfahren zum übergang zwischen verschiedenen polymerisationskatalysatoren in einem polymerisationsreaktor

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2583307B1 (fr) * 1985-06-14 1993-07-02 Atochem Support a base de silice et de chlorure de magnesium, son procede de fabrication, catalyseurs obtenus a partir de ce support.
WO1988008432A1 (en) * 1987-04-20 1988-11-03 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst and process for polymerizing olefin
JP2538595B2 (ja) * 1987-05-13 1996-09-25 三井石油化学工業株式会社 オレフイン重合用固体触媒
GB8716950D0 (en) * 1987-07-17 1987-08-26 Ici Plc Polymers & catalyst components
US5026798A (en) * 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US5227440A (en) * 1989-09-13 1993-07-13 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing Group IVB transition metal complexes with MAO: supported catalysts for olefin polymerization
US5057475A (en) * 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5266544A (en) * 1989-12-29 1993-11-30 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst and process for the polymerization of olefins
JP2826362B2 (ja) * 1990-02-13 1998-11-18 三井化学株式会社 オレフィン重合用固体触媒の製造方法、オレフィン重合用固体触媒およびオレフィンの重合方法
EP0485821B1 (de) * 1990-11-12 1996-06-12 Hoechst Aktiengesellschaft Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
US5349100A (en) * 1991-01-02 1994-09-20 Exxon Chemical Patents Inc. Chiral metallocene compounds and preparation thereof by creation of a chiral center by enantioselective hydride transfer
EP0496193B1 (de) * 1991-01-12 1998-05-13 TARGOR GmbH Metallocen(co)polymere, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren; Metallocene hierfür.
US5189192A (en) * 1991-01-16 1993-02-23 The Dow Chemical Company Process for preparing addition polymerization catalysts via metal center oxidation
JPH07501845A (ja) * 1991-12-13 1995-02-23 エクソン・ケミカル・パテンツ・インク エチレンとより長いアルファーオレフィンのコポリマー

Also Published As

Publication number Publication date
DE69419326T2 (de) 1999-11-04
ATE181930T1 (de) 1999-07-15
JPH06239916A (ja) 1994-08-30
KR940018401A (ko) 1994-08-16
US5814574A (en) 1998-09-29
FI940266A0 (fi) 1994-01-19
CA2113601A1 (en) 1994-07-20
FI940266A (fi) 1994-07-20
CN1087303C (zh) 2002-07-10
NO940172L (no) 1994-07-20
NO308133B1 (no) 2000-07-31
CN1092081A (zh) 1994-09-14
JP3481285B2 (ja) 2003-12-22
EP0608054A2 (de) 1994-07-27
US5767209A (en) 1998-06-16
ES2135539T3 (es) 1999-11-01
KR100299701B1 (ko) 2001-10-22
GB9300934D0 (en) 1993-03-10
GR3030725T3 (en) 1999-11-30
EP0608054B1 (de) 1999-07-07
EP0608054A3 (de) 1994-11-30
NO940172D0 (no) 1994-01-18

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