DE69506906D1 - Polymere mit langkettigen verweigungen und ihre herstellung - Google Patents
Polymere mit langkettigen verweigungen und ihre herstellungInfo
- Publication number
- DE69506906D1 DE69506906D1 DE69506906T DE69506906T DE69506906D1 DE 69506906 D1 DE69506906 D1 DE 69506906D1 DE 69506906 T DE69506906 T DE 69506906T DE 69506906 T DE69506906 T DE 69506906T DE 69506906 D1 DE69506906 D1 DE 69506906D1
- Authority
- DE
- Germany
- Prior art keywords
- polymers
- production
- long
- chain branches
- branches
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Revoked
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/328,187 US6300451B1 (en) | 1994-10-24 | 1994-10-24 | Long-chain branched polymers and their production |
PCT/US1995/013643 WO1996012744A1 (en) | 1994-10-24 | 1995-10-24 | Long-chain branched polymers and their production |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69506906D1 true DE69506906D1 (de) | 1999-02-04 |
DE69506906T2 DE69506906T2 (de) | 1999-05-27 |
Family
ID=23279893
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69506906T Revoked DE69506906T2 (de) | 1994-10-24 | 1995-10-24 | Polymere mit langkettigen verweigungen und ihre herstellung |
Country Status (13)
Country | Link |
---|---|
US (1) | US6300451B1 (de) |
EP (1) | EP0788521B1 (de) |
JP (1) | JPH10512600A (de) |
KR (1) | KR100358857B1 (de) |
CN (2) | CN1091774C (de) |
AU (1) | AU694812B2 (de) |
BR (1) | BR9509427A (de) |
CA (1) | CA2202402C (de) |
DE (1) | DE69506906T2 (de) |
ES (1) | ES2128786T3 (de) |
RU (1) | RU2165437C2 (de) |
TW (1) | TW422857B (de) |
WO (1) | WO1996012744A1 (de) |
Families Citing this family (92)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5792534A (en) * | 1994-10-21 | 1998-08-11 | The Dow Chemical Company | Polyolefin film exhibiting heat resistivity, low hexane extractives and controlled modulus |
WO1997001586A1 (en) * | 1995-06-29 | 1997-01-16 | Dsm N.V. | Elastomeric copolymer |
CA2190678A1 (en) | 1995-11-22 | 1997-05-23 | Robert Joseph Noel Bernier | Process for preparing elastomeric compounds from granular elastomers and polymers and articles manufactured therefrom |
US5814714A (en) * | 1995-11-30 | 1998-09-29 | The Dow Chemical Company | Mono-olefin/polyene interpolymers, method of preparation, compositions containing the same, and articles made thereof |
EP0784062A3 (de) * | 1995-12-15 | 1998-04-22 | Union Carbide Chemicals & Plastics Technology Corporation | Verfahren zur Herstellung von Polyolefinen mit langkettigen Verzweigungen |
BR9810350B1 (pt) * | 1997-06-27 | 2012-02-22 | processo para a preparação de copolìmeros elastoméricos e copolìmeros elastoméricos | |
NL1006421C2 (nl) * | 1997-06-27 | 1998-12-29 | Dsm Nv | Elastomeer copolymeer. |
KR100564506B1 (ko) * | 1998-02-17 | 2006-03-29 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 에틸렌 공중합 방법 |
US6294631B1 (en) * | 1998-12-15 | 2001-09-25 | Exxonmobil Chemical Patents Inc. | Hyperbranched polymers by coordination polymerization |
US6281316B1 (en) | 1999-03-22 | 2001-08-28 | Union Carbide Chemicals & Plastics Technology Corporation | Enhanced crosslinking terpolymer |
CA2372056A1 (en) * | 1999-05-14 | 2000-11-23 | Morgan Mark Hughes | Highly crystalline eaodm interpolymers |
US7041617B2 (en) | 2004-01-09 | 2006-05-09 | Chevron Phillips Chemical Company, L.P. | Catalyst compositions and polyolefins for extrusion coating applications |
US6509431B1 (en) * | 2000-01-18 | 2003-01-21 | Exxonmobil Oil Corporation | Terpolymers |
US6806336B2 (en) * | 2002-06-19 | 2004-10-19 | Exxonmobil Chemical Patents Inc. | Process for polymerizing ethylene, higher alpha-olefin comonomer and dienes, especially vinyl norbornene; polymers made using such processes; and articles made from such polymers |
EP1539841B1 (de) * | 2002-09-20 | 2012-08-01 | ExxonMobil Chemical Patents Inc. | Herstellung von polymeren unter überkritischen bedingungen |
US8008412B2 (en) | 2002-09-20 | 2011-08-30 | Exxonmobil Chemical Patents Inc. | Polymer production at supersolution conditions |
US7807769B2 (en) | 2002-09-20 | 2010-10-05 | Exxonmobil Chemical Patents Inc. | Isotactic polypropylene produced from supercritical polymerization process |
EP1558655B1 (de) | 2002-10-15 | 2012-08-29 | ExxonMobil Chemical Patents Inc. | Katalysatorsystem zur olefinpolymerisation bestehend aus mehreren katalysatoren und damit hergestellte polymere |
US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
WO2004065435A1 (ja) * | 2003-01-23 | 2004-08-05 | Mitsui Chemicals, Inc. | エチレン・α-オレフィン・非共役ポリエン共重合体の製造方法およびエチレン・α-オレフィン・非共役ポリエン共重合体 |
US20050209403A1 (en) * | 2003-12-09 | 2005-09-22 | Walton Kim L | Thermoplastic olefinic compositions |
US7906586B2 (en) * | 2003-12-09 | 2011-03-15 | Dow Global Technologies Llc | Thermoplastic olefinic compositions |
US7119153B2 (en) | 2004-01-21 | 2006-10-10 | Jensen Michael D | Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength |
JP4988568B2 (ja) * | 2004-07-08 | 2012-08-01 | エクソンモービル・ケミカル・パテンツ・インク | オレフィン重合触媒系およびその使用方法 |
US7741420B2 (en) | 2004-07-14 | 2010-06-22 | Exxonmobil Chemical Patents Inc. | Polymer production at supercritical conditions |
US8101697B2 (en) * | 2005-02-01 | 2012-01-24 | Bridgestone Corporation | Multi-functionalized high-trans elastomeric polymers |
EP1882014B1 (de) * | 2005-05-12 | 2009-03-11 | Dow Global Technologies Inc. | Thermogeformte und extrudierte folie mit reduziertem glanz |
ES2370416T5 (es) * | 2005-05-20 | 2016-04-25 | Bridgestone Corporation | Método para preparar polímeros de bajo peso molecular |
US8288480B2 (en) | 2005-06-22 | 2012-10-16 | Exxonmobil Chemical Patents Inc. | In-reactor polymer blends |
DE602006013848D1 (de) | 2005-09-12 | 2010-06-02 | Dow Global Technologies Inc | Ethylen-/alpha-olefinverbindungen, daraus hergestellte artikel und herstellungsverfahren dafür |
US8557938B2 (en) | 2005-11-10 | 2013-10-15 | Arkema Inc. | Branched fluoropolymers |
US7517939B2 (en) | 2006-02-02 | 2009-04-14 | Chevron Phillips Chemical Company, Lp | Polymerization catalysts for producing high molecular weight polymers with low levels of long chain branching |
US7619047B2 (en) | 2006-02-22 | 2009-11-17 | Chevron Phillips Chemical Company, Lp | Dual metallocene catalysts for polymerization of bimodal polymers |
US7576163B2 (en) * | 2006-03-31 | 2009-08-18 | Chevron Phillips Chemical Company, Lp | Polymerization catalysts for producing polymers with low levels of long chain branching |
BRPI0716697A2 (pt) | 2006-11-01 | 2014-02-25 | Dow Global Technologies Inc | Composição, artigo, estrutura laminada, artigo moldao, dispersão, artigo moldado, dispersão, artigo por injeção, peça automotiva e adesivo |
US8242237B2 (en) * | 2006-12-20 | 2012-08-14 | Exxonmobil Chemical Patents Inc. | Phase separator and monomer recycle for supercritical polymerization process |
US8143352B2 (en) * | 2006-12-20 | 2012-03-27 | Exxonmobil Research And Engineering Company | Process for fluid phase in-line blending of polymers |
CN104927184B (zh) * | 2006-12-21 | 2019-06-14 | 陶氏环球技术有限责任公司 | 填充的热塑性聚烯烃组合物、制备其的方法和由其制得的制品 |
US8080610B2 (en) | 2007-03-06 | 2011-12-20 | Exxonmobil Research And Engineering Company | Monomer recycle process for fluid phase in-line blending of polymers |
WO2008140280A2 (en) * | 2007-05-16 | 2008-11-20 | Lg Chem, Ltd. | Long chain-branched ethylene-alpha olefin copolymer |
JP2010529253A (ja) | 2007-06-04 | 2010-08-26 | エクソンモービル・ケミカル・パテンツ・インク | 非常に均一なプロピレンの溶液重合法 |
WO2009035850A1 (en) * | 2007-09-07 | 2009-03-19 | Dow Global Technologies Inc. | Filled tpo compositions with good low temperature ductility |
WO2009035579A1 (en) * | 2007-09-13 | 2009-03-19 | Exxonmobil Research And Engineering Company | In-line blending of plasticizers with a base polymer |
WO2009035580A1 (en) * | 2007-09-13 | 2009-03-19 | Exxonmobil Research And Engineering Company | In-line process for producing plasticized polymers and plasticized polymer blends |
WO2009064692A1 (en) | 2007-11-14 | 2009-05-22 | Dow Global Technologies Inc. | Articles and methods of making the same |
CN101945940B (zh) * | 2007-12-20 | 2014-04-09 | 埃克森美孚研究工程公司 | 聚丙烯乙烯-丙烯共聚物共混物和生产它的在线方法 |
US7910679B2 (en) * | 2007-12-20 | 2011-03-22 | Exxonmobil Research And Engineering Company | Bulk homogeneous polymerization process for ethylene propylene copolymers |
WO2009082463A1 (en) * | 2007-12-20 | 2009-07-02 | Exxonmobil Research And Engineering Company | In-line process to produce pellet-stable polyolefins |
US8318875B2 (en) | 2008-01-18 | 2012-11-27 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization and polypropylenes made therefrom |
US8524793B2 (en) | 2008-06-18 | 2013-09-03 | Dow Global Technologies, Llc | Interpolymer compositions of ethylene, α-olefin and nonconjugated polyene, methods of making the same, and foam and articles prepared from the same |
BRPI1007676A2 (pt) * | 2009-05-08 | 2020-10-13 | 3M Innovative Properties Company | métodos para hidratação, kits para tratamento bucal e método para hidratação dos tecidos bucais |
JP5512812B2 (ja) | 2009-07-15 | 2014-06-04 | ダウ グローバル テクノロジーズ エルエルシー | ポリマー組成物、その製造方法及びそれから製造される物品 |
CN102666596B (zh) | 2009-10-14 | 2014-04-02 | 株式会社普利司通 | 环状和无环二烯共聚物的制备方法及橡胶组合物 |
US9458310B2 (en) | 2009-10-16 | 2016-10-04 | Exxonmobil Chemical Patents Inc. | Modified polyethylene film compositions |
US9580533B2 (en) * | 2011-09-23 | 2017-02-28 | Exxonmobil Chemical Patents Inc. | Modified polyethylene compositions |
US9321911B2 (en) | 2011-09-23 | 2016-04-26 | Exxonmobil Chemical Patents Inc. | Modified polyethylene compositions for cast film |
US20160272798A1 (en) * | 2011-09-23 | 2016-09-22 | Exxonmobil Chemical Patents Inc. | Modified Polyethylene Compositions with Enhanced Melt Strength |
US20130216812A1 (en) * | 2011-09-23 | 2013-08-22 | Exxonmobil Chemical Patents Inc. | Modified Polyethylene Compositions with Enhanced Melt Strength |
US9340664B2 (en) | 2011-09-23 | 2016-05-17 | Exxonmobil Chemical Patents Inc. | Modified polyethylene compositions for blown film |
US8629217B2 (en) | 2011-11-22 | 2014-01-14 | Exxonmobil Chemical Patents Inc. | Modified polyethylene blown film compositions having excellent bubble stability |
US10836853B2 (en) | 2012-09-20 | 2020-11-17 | Exxonmobil Chemical Patents Inc. | Crack-resistant polyethylene compositions |
US10822479B2 (en) * | 2012-09-20 | 2020-11-03 | Exxonmobil Chemical Patents Inc. | Foamed polyethylene compositions |
US8901238B2 (en) | 2012-10-09 | 2014-12-02 | Lion Copolymer Geismar, Llc | Sponge polymer with controlled long chain branching and broad molecular weight distribution |
US9139726B2 (en) | 2012-10-09 | 2015-09-22 | Lion Copolymer Geismar, Llc | Process for making an ethylene elastomer with long chain branching for use in anti-vibration applications |
US9139727B2 (en) | 2012-10-09 | 2015-09-22 | Lion Copolymer Geismar, Llc | Low damping high strength polymer with long chain branching for use in anti-vibration applications |
US8937139B2 (en) | 2012-10-25 | 2015-01-20 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
US8895679B2 (en) | 2012-10-25 | 2014-11-25 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
WO2014088827A1 (en) | 2012-12-05 | 2014-06-12 | Exxonmobil Chemical Patents Inc. | Hdpe modified polyethylene blown film compositions having excellent bubble stability |
US9034991B2 (en) | 2013-01-29 | 2015-05-19 | Chevron Phillips Chemical Company Lp | Polymer compositions and methods of making and using same |
US8877672B2 (en) | 2013-01-29 | 2014-11-04 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
CN103304743B (zh) * | 2013-06-24 | 2015-04-29 | 苏州新区佳合塑胶有限公司 | 一种含有4-甲基-1-戊烯的阻燃耐热塑胶 |
CN103304742B (zh) * | 2013-06-24 | 2015-04-15 | 苏州新区佳合塑胶有限公司 | 一种含有1,3-环己二烯的阻燃耐热塑胶 |
JP6439280B2 (ja) * | 2013-08-09 | 2018-12-19 | 三菱ケミカル株式会社 | 熱可塑性エラストマー組成物の製造方法 |
CN105980471B (zh) | 2014-02-24 | 2019-08-20 | 陶氏环球技术有限责任公司 | 用于未铺地毯的地板的具有降低的光泽度的热塑性聚烯烃 |
US10077344B2 (en) | 2014-05-29 | 2018-09-18 | Exxonmobil Chemical Patents Inc. | Polyethylene films and production of such films |
WO2015183577A1 (en) | 2014-05-29 | 2015-12-03 | Exxonmobil Chemical Patents Inc. | Cyclic-diene additives in polyethylene films and enhanced film orientation balance in production thereof |
US10125247B2 (en) | 2014-05-29 | 2018-11-13 | Exxonmobil Chemical Patents Inc. | Polyethylene compositions |
WO2017201304A1 (en) | 2016-05-20 | 2017-11-23 | Chevron Phillips Chemical Company Lp | Low pressure process for preparing low-density polyethylene |
KR20190036557A (ko) | 2016-08-12 | 2019-04-04 | 다우 글로벌 테크놀로지스 엘엘씨 | 탄소 섬유 및 열가소성 폴리올레핀 탄성중합체를 포함하는 프로필렌계 조성물 |
US9574035B1 (en) | 2016-08-12 | 2017-02-21 | Lion Copolymer Geismar, Llc | Process for making high molecular weight tetrapolymer and articles produced therefrom |
US9574034B1 (en) | 2016-08-12 | 2017-02-21 | Lion Copolymer Geismar, Llc | Process for making high molecular weight tetrapolymer and articles produced therefrom |
US9574033B1 (en) | 2016-08-12 | 2017-02-21 | Lion Copolymer Geismar, Llc | Process for continuously making high molecular weight tetrapolymer for use in anti-vibration applications |
WO2018182943A1 (en) | 2017-03-29 | 2018-10-04 | Exxonmobil Chemical Patents Inc. | Polyethylene compositions |
US10550252B2 (en) | 2017-04-20 | 2020-02-04 | Chevron Phillips Chemical Company Lp | Bimodal PE resins with improved melt strength |
US11041035B2 (en) | 2018-03-08 | 2021-06-22 | Exxonmobil Chemical Patents Inc. | Process to produce long-chain branched polyolefins using dienes |
US11479625B2 (en) | 2018-03-08 | 2022-10-25 | Exxonmobil Chemical Patents Inc. | Ethylene-propylene branched copolymers as viscosity modifiers with enhanced fuel economy |
SG11202102966RA (en) * | 2018-09-28 | 2021-04-29 | Dow Global Technologies Llc | Tetra-functional long-chain branched ethylene-based polymers |
US10961331B2 (en) | 2018-12-19 | 2021-03-30 | Chevron Phillips Chemical Company Lp | Ethylene homopolymers with a reverse short chain branch distribution |
US20220213246A1 (en) * | 2019-03-29 | 2022-07-07 | Dow Global Technologies Llc | Process of polymerizing tri-functional long-chain branched olefin |
EP3947482A1 (de) * | 2019-03-29 | 2022-02-09 | Dow Global Technologies LLC | Verfahren zur polymerisierung von trifunktionalem langkettigem verzweigtem olefin |
EP3947484A1 (de) * | 2019-03-29 | 2022-02-09 | Dow Global Technologies LLC | Trifunktionelles langkettiges verzweigtes polyolefin |
WO2023101936A1 (en) | 2021-11-30 | 2023-06-08 | Dow Global Technologies Llc | Soft thermoplastic olefins and products made therefrom |
Family Cites Families (42)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3624056A (en) * | 1965-09-28 | 1971-11-30 | Goodrich Co B F | Olefin interpolymers prepared with a catalyst system of a titanium compound, alkyl aryl halide and diaryl magnesium |
CA849081A (en) | 1967-03-02 | 1970-08-11 | Du Pont Of Canada Limited | PRODUCTION OF ETHYLENE/.alpha.-OLEFIN COPOLYMERS OF IMPROVED PHYSICAL PROPERTIES |
DE1770036C3 (de) | 1967-03-24 | 1980-04-24 | Du Pont | Verfahren zur Herstellung eines mit Schwefel härtbaren elastomeren Mischpolymerisats und seine Verwendung |
NL6817611A (de) * | 1967-12-15 | 1969-06-17 | ||
US3472829A (en) | 1968-06-10 | 1969-10-14 | Exxon Research Engineering Co | Process for broadening the molecular weight distribution in polymers |
CA980498A (en) | 1971-04-16 | 1975-12-23 | Du Pont Of Canada Limited | Ethylene polymers with long chain branching |
US3821143A (en) | 1973-03-22 | 1974-06-28 | Du Pont | Hot melt adhesive composition containing a branched elastomeric copolymer |
DE3007725A1 (de) | 1980-02-29 | 1981-09-17 | Hansjörg Prof. Dr. 2000 Hamburg Sinn | Verfahren zur herstellung von polyethylen, polypropylen und copolymeren |
AU9008382A (en) | 1981-11-03 | 1983-05-12 | Baker, R.W. | Ratchet tool |
US5324800A (en) | 1983-06-06 | 1994-06-28 | Exxon Chemical Patents Inc. | Process and catalyst for polyolefin density and molecular weight control |
US4882406A (en) | 1983-06-15 | 1989-11-21 | Exxon Research & Engineering Company | Nodular copolymers formed of alpha-olefin copolymers coupled by non-conjugated dienes |
FR2562546B1 (fr) | 1984-04-09 | 1987-01-23 | Bp Chimie Sa | Procede de traitement de polyethylene de basse densite lineaire destine a la fabrication par extrusion de corps creux, tubes et gaines |
US5191052A (en) * | 1985-06-21 | 1993-03-02 | Exxon Chemical Patents Inc. | Copolymers of ethylene and 1,3-butadiene |
IN172494B (de) | 1986-12-19 | 1993-09-04 | Exxon Chemical Patents Inc | |
US4668834B1 (en) | 1985-10-16 | 1996-05-07 | Uniroyal Chem Co Inc | Low molecular weight ethylene-alphaolefin copolymer intermediates |
EP0230753B1 (de) | 1985-12-16 | 1991-10-23 | Exxon Research And Engineering Company | Kopolymer-Zusammensetzungen mit enger Molekulargewichtsverteilung und Verfahren zu deren Herstellung |
US5084534A (en) * | 1987-06-04 | 1992-01-28 | Exxon Chemical Patents, Inc. | High pressure, high temperature polymerization of ethylene |
IN172282B (de) | 1986-12-19 | 1993-05-29 | Exxon Chemical Patents Inc | |
IL84641A (en) | 1986-12-19 | 1992-05-25 | Exxon Chemical Patents Inc | Unsaturated ethylene polymers |
CA1327673C (en) | 1988-06-16 | 1994-03-08 | Sigmund Floyd | Process for production of high molecular weight epdm elastomers using a metallocene-alumoxane catalyst system |
US5229478A (en) | 1988-06-16 | 1993-07-20 | Exxon Chemical Patents Inc. | Process for production of high molecular weight EPDM elastomers using a metallocene-alumoxane catalyst system |
US5218071A (en) | 1988-12-26 | 1993-06-08 | Mitsui Petrochemical Industries, Ltd. | Ethylene random copolymers |
JP2883641B2 (ja) | 1989-08-11 | 1999-04-19 | 三井化学株式会社 | ポリウレタン樹脂 |
NZ235032A (en) | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
EP0446013B1 (de) | 1990-03-06 | 1996-07-03 | Tosoh Corporation | Polyäthylen und Verfahren zur Herstellung |
GB2244276A (en) | 1990-05-21 | 1991-11-27 | Ici Plc | Amorphous polyolefins |
US5272236A (en) | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
US5096743A (en) | 1990-11-09 | 1992-03-17 | E. I. Du Pont De Nemours And Company | Process for making roofing membrane of epdm elastomer and ethylene-containing polymer |
GB9103527D0 (en) | 1991-02-20 | 1991-04-10 | Exxon Chemical Patents Inc | Hp catalyst killer |
NL9101536A (nl) | 1991-09-11 | 1993-04-01 | Dsm Nv | Katalysator en werkwijze voor de bereiding van een amorf copolymeer van etheen. |
US5278272A (en) | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
IT1252069B (it) | 1991-11-25 | 1995-05-29 | Enichem Elastomers | Processo per la preparazione di copolimeri elastomerici dell'etilene |
DE69309726T2 (de) | 1992-01-23 | 1997-08-21 | Mitsui Petrochemical Ind | Ethylen/Alpha-Olefin/7-Methyl-1,6-Octadien Copolymerisat-Kautschuk und Zusammensetzungen desselben |
JPH08501325A (ja) | 1992-06-18 | 1996-02-13 | スペリレーネ エッセ.アール.エッレ. | エチレン系ポリマーの製造法 |
WO1994000500A1 (en) | 1992-06-26 | 1994-01-06 | Exxon Chemical Patents Inc. | Solution phase polymerization process utilizing metallocene catalyst with production of olefin polymers |
EP0662980A1 (de) | 1992-09-29 | 1995-07-19 | Exxon Chemical Patents Inc. | Polymere mit langen seitenketten, und ein verfahren zur herstellung von polymeren mit langen seitenketten |
WO1994013175A1 (en) * | 1992-12-16 | 1994-06-23 | Paul Solomon | Door comprising recessed cabinet |
CA2110654C (en) | 1992-12-17 | 2006-03-21 | Albert Rossi | Dilute process for the polymerization of ethylene/alpha-olefin copolymer using metallocene catalyst systems |
US5410003A (en) * | 1994-03-31 | 1995-04-25 | Union Carbide Chemicals & Plastics Technology Corporation | Process for production of homogeneous polyethylenes |
US5552489A (en) * | 1994-07-22 | 1996-09-03 | Exxon Chemical Patents Inc. | Tackifiers and a process to obtain tackifiers |
JPH1054010A (ja) | 1997-06-06 | 1998-02-24 | Ohbayashi Corp | 鋼管・コンクリート複合構造橋脚 |
-
1994
- 1994-10-24 US US08/328,187 patent/US6300451B1/en not_active Expired - Fee Related
-
1995
- 1995-10-24 JP JP8514092A patent/JPH10512600A/ja active Pending
- 1995-10-24 KR KR1019970702672A patent/KR100358857B1/ko not_active IP Right Cessation
- 1995-10-24 RU RU97108600/04A patent/RU2165437C2/ru not_active IP Right Cessation
- 1995-10-24 EP EP95938287A patent/EP0788521B1/de not_active Revoked
- 1995-10-24 CN CN95195850A patent/CN1091774C/zh not_active Expired - Fee Related
- 1995-10-24 CA CA002202402A patent/CA2202402C/en not_active Expired - Fee Related
- 1995-10-24 ES ES95938287T patent/ES2128786T3/es not_active Expired - Lifetime
- 1995-10-24 AU AU38970/95A patent/AU694812B2/en not_active Ceased
- 1995-10-24 DE DE69506906T patent/DE69506906T2/de not_active Revoked
- 1995-10-24 WO PCT/US1995/013643 patent/WO1996012744A1/en not_active Application Discontinuation
- 1995-10-24 BR BR9509427A patent/BR9509427A/pt not_active IP Right Cessation
-
1996
- 1996-04-26 TW TW085105107A patent/TW422857B/zh not_active IP Right Cessation
-
2001
- 2001-09-06 CN CNB011328118A patent/CN1204157C/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
RU2165437C2 (ru) | 2001-04-20 |
MX9702954A (es) | 1998-07-31 |
AU694812B2 (en) | 1998-07-30 |
KR100358857B1 (ko) | 2003-02-07 |
AU3897095A (en) | 1996-05-15 |
WO1996012744A1 (en) | 1996-05-02 |
EP0788521A1 (de) | 1997-08-13 |
CN1204157C (zh) | 2005-06-01 |
TW422857B (en) | 2001-02-21 |
CN1341672A (zh) | 2002-03-27 |
CN1161700A (zh) | 1997-10-08 |
DE69506906T2 (de) | 1999-05-27 |
JPH10512600A (ja) | 1998-12-02 |
BR9509427A (pt) | 1998-01-06 |
CN1091774C (zh) | 2002-10-02 |
ES2128786T3 (es) | 1999-05-16 |
CA2202402A1 (en) | 1996-05-02 |
KR970707184A (ko) | 1997-12-01 |
CA2202402C (en) | 2006-10-17 |
US6300451B1 (en) | 2001-10-09 |
EP0788521B1 (de) | 1998-12-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE69506906T2 (de) | Polymere mit langkettigen verweigungen und ihre herstellung | |
DE69405859D1 (de) | Fluorhaltige polymere, ihre herstellung und ihre verwendung | |
DE69529026D1 (de) | Trehalose, ihre Herstellung und ihre Verwendung | |
DE69503139D1 (de) | Schuhwerk und dessen herstellung | |
ATE239693T1 (de) | 3,3-diarylpropylamine , ihre verwendung und herstellung | |
ATE430734T1 (de) | Isochinoline und deren herstellung | |
DE69015788T2 (de) | Thermistor und dessen herstellung. | |
DE59703980D1 (de) | Reaktivfarbstoffe, ihre Herstellung und Verwendung | |
DE69709548T2 (de) | Sternförmige polymere mit definiertem siloxankern und polyisobutylenzweigen und syntheseverfahren | |
DE59800590D1 (de) | Polymere organosiliciumverbindungen, deren herstellung und verwendung | |
DE69827144D1 (de) | Neue blockpolymere und deren herstellung | |
DE69532131D1 (de) | Heizvorrichtung und ihre herstellung | |
DE69314784D1 (de) | Flourierte polymere, ihre herstellung und verwendung | |
DE69510223T2 (de) | Herstellung von 2-chlor-2-hydrohexafluorpropan und ihre azeotropen mit hf | |
DE59409541D1 (de) | Bicyclen-derivate, ihre herstellung und verwendung | |
DE59303537D1 (de) | Reaktivfarbstoffe, deren Herstellung und Verwendung | |
DE69421172D1 (de) | Synthetises detergensstueck und herstellung davon | |
DE69317265D1 (de) | Konstruktionselement und dessen herstellung | |
DE59304510D1 (de) | Reaktivfarbstoffe, deren Herstellung und Verwendung | |
DE59509446D1 (de) | Reaktivfarbstoffe, deren Herstellung und Verwendung | |
DE59409438D1 (de) | Reaktivfarbstoffe, deren Herstellung und Verwendung | |
DE69031606T2 (de) | Kern-Schale-Polymer, Herstellung und dessen Verwendung | |
DE69507338D1 (de) | Fluor-enthaltende polymere und deren herstellung | |
DE59606806D1 (de) | Polymerholz-formkörper, ihre herstellung und verwendung | |
DE69406686D1 (de) | Esteramid-Copolymere und ihre Herstellung |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
8363 | Opposition against the patent | ||
8331 | Complete revocation |