DE69520592T2 - Isomerisierung von xylen in zwei betten - Google Patents
Isomerisierung von xylen in zwei bettenInfo
- Publication number
- DE69520592T2 DE69520592T2 DE69520592T DE69520592T DE69520592T2 DE 69520592 T2 DE69520592 T2 DE 69520592T2 DE 69520592 T DE69520592 T DE 69520592T DE 69520592 T DE69520592 T DE 69520592T DE 69520592 T2 DE69520592 T2 DE 69520592T2
- Authority
- DE
- Germany
- Prior art keywords
- isomerization
- beds
- xylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/02—Monocyclic hydrocarbons
- C07C15/067—C8H10 hydrocarbons
- C07C15/08—Xylenes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
- B01J29/44—Noble metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/02—Monocyclic hydrocarbons
- C07C15/067—C8H10 hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
- C07C4/08—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule
- C07C4/12—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene
- C07C4/14—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene splitting taking place at an aromatic-aliphatic bond
- C07C4/18—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
- C07C5/2708—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with crystalline alumino-silicates, e.g. molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/12—After treatment, characterised by the effect to be obtained to alter the outside of the crystallites, e.g. selectivation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/342,322 US5516956A (en) | 1994-11-18 | 1994-11-18 | Dual bed xylene isomerization |
PCT/US1995/016006 WO1996016005A1 (en) | 1994-11-18 | 1995-11-16 | Dual bed xylene isomerization |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69520592D1 DE69520592D1 (de) | 2001-05-10 |
DE69520592T2 true DE69520592T2 (de) | 2001-07-12 |
Family
ID=23341323
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69520592T Expired - Fee Related DE69520592T2 (de) | 1994-11-18 | 1995-11-16 | Isomerisierung von xylen in zwei betten |
Country Status (8)
Country | Link |
---|---|
US (1) | US5516956A (de) |
EP (1) | EP0792251B1 (de) |
JP (1) | JP3857311B2 (de) |
KR (1) | KR100369429B1 (de) |
CA (1) | CA2203365C (de) |
DE (1) | DE69520592T2 (de) |
ES (1) | ES2155538T3 (de) |
WO (1) | WO1996016005A1 (de) |
Families Citing this family (45)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5698756A (en) * | 1993-05-28 | 1997-12-16 | Mobil Oil Corporation | Toluene alkylation with ethylene to produce para-ethyloluene |
US5476823A (en) * | 1993-05-28 | 1995-12-19 | Mobil Oil Corp. | Method of preparation of ex situ selectivated zeolite catalysts for enhanced shape selective applications and method to increase the activity thereof |
US5659098A (en) * | 1993-05-28 | 1997-08-19 | Beck; Jeffrey S. | High conversion touluene disproportionation with ex situ selectivated zeolite catalysts |
US5689027A (en) * | 1994-11-18 | 1997-11-18 | Mobil Oil Corporation | Selective ethylbenzene conversion |
US5705726A (en) * | 1994-11-18 | 1998-01-06 | Mobil Oil Corporation | Xylene isomerization on separate reactors |
US5625104A (en) * | 1995-06-06 | 1997-04-29 | Mobil Oil Corporation | Alkali metal ion exchanged selectivated zeolite catalyst |
IN192640B (de) * | 1995-03-06 | 2004-05-08 | Toray Industries | |
US5849968A (en) * | 1995-06-06 | 1998-12-15 | Mobil Oil Corporation | Hydrocarbon conversion process with alkaline earth metal ion exchanged selectivated zeolite catalyst |
AU714275B2 (en) * | 1996-01-25 | 1999-12-23 | Exxon Research And Engineering Company | Separation process in which a membrane is used |
ID18446A (id) * | 1996-05-29 | 1998-04-09 | Exxon Chemical Patents Inc | Proses untuk isomerisasi hidrokarbon-hidrokarbon alkilaromatik |
ZA974712B (en) * | 1996-05-29 | 1998-11-17 | Exxon Chemical Patents Inc | Zeolite catalyst and use for hydrocarbon conversion |
US5877379A (en) * | 1996-08-19 | 1999-03-02 | Phillips Petroleum Company | Olefin conversion process involving coke suppressor impregnated catalyst |
US5968343A (en) * | 1997-05-05 | 1999-10-19 | Phillips Petroleum Company | Hydrocarbon conversion catalyst composition and processes therefor and therewith |
US5905051A (en) * | 1997-06-04 | 1999-05-18 | Wu; An-Hsiang | Hydrotreating catalyst composition and processes therefor and therewith |
US6207871B1 (en) | 1997-12-19 | 2001-03-27 | Mobil Oil Corporation | High-purity meta-xylene production process |
US6028238A (en) * | 1998-04-14 | 2000-02-22 | Mobil Oil Corporation | Xylene isomerization |
US5998688A (en) * | 1998-08-25 | 1999-12-07 | Mobil Oil Corporation | Xylene isomerization process using toluene co-feed |
US5977420A (en) * | 1998-08-25 | 1999-11-02 | Mobil Oil Corporation | Dual-loop xylene isomerization process |
US6709570B1 (en) | 1999-09-27 | 2004-03-23 | Shell Oil Company | Method for preparing a catalyst |
US7122496B2 (en) * | 2003-05-01 | 2006-10-17 | Bp Corporation North America Inc. | Para-xylene selective adsorbent compositions and methods |
US7271305B2 (en) * | 2003-05-01 | 2007-09-18 | Bp Corporation North America Inc. | Method of obtaining para-xylene |
US7067052B2 (en) * | 2003-07-01 | 2006-06-27 | Exxonmobil Chemical Patents Inc. | Process for the production of reformate having reduced ethylbenzene content |
US7247762B2 (en) * | 2003-09-12 | 2007-07-24 | Exxonmobil Chemical Patents Inc. | Process for xylene isomerization and ethylbenzene conversion |
US7271118B2 (en) * | 2004-07-29 | 2007-09-18 | Exxonmobil Chemical Patents Inc. | Xylenes isomerization catalyst system and use thereof |
EP2027917A1 (de) * | 2007-07-31 | 2009-02-25 | Shell Internationale Researchmaatschappij B.V. | Katalysatorzusammensetzung sowie ihre Herstellung und Verwendung |
US20100004493A1 (en) * | 2008-07-02 | 2010-01-07 | Porter John R | Integrated Process |
US8575055B2 (en) * | 2010-03-30 | 2013-11-05 | Uop Llc | Surface-modified zeolites and methods for preparing the same |
KR101844763B1 (ko) * | 2010-04-19 | 2018-04-03 | 쉘 인터내셔날 리써취 마트샤피지 비.브이. | 촉매 지지체의 제조 방법 |
WO2012058108A2 (en) * | 2010-10-29 | 2012-05-03 | Exxonmobil Chemical Patents Inc. | Process for the production of paraxylene |
CA2842809C (en) | 2011-08-31 | 2016-06-07 | Chunshe Cao | Production of paraxylene |
US9260360B2 (en) | 2012-12-05 | 2016-02-16 | Exxonmobil Chemical Patents Inc. | Manufacturing process |
BR112015030289A2 (pt) * | 2013-06-13 | 2017-07-25 | Exxonmobil Chemical Patents Inc | seletivação de coque de compensação in-situ de catalisador de desproporcionamento de tolueno |
WO2016003611A1 (en) | 2014-06-30 | 2016-01-07 | Exxonmobil Chemical Patents Inc. | Process for the production of para-xyxlene |
US9469579B2 (en) | 2014-06-30 | 2016-10-18 | Exxonmobil Chemical Patents Inc. | Process for the production of xylenes |
WO2016003613A2 (en) | 2014-06-30 | 2016-01-07 | Exxonmobil Chemical Patents Inc. | Process for the production of xylenes |
WO2016003612A1 (en) | 2014-06-30 | 2016-01-07 | Exxonmobil Chemical Patents Inc. | Processes for the production of para-xylene |
WO2016025077A1 (en) | 2014-08-15 | 2016-02-18 | Exxonmobil Chemical Patents Inc. | Aromatics production process |
US9708233B2 (en) * | 2014-08-15 | 2017-07-18 | Exxonmobil Chemical Patents Inc. | Aromatics production process |
WO2017075214A1 (en) * | 2015-10-28 | 2017-05-04 | Bp Corporation Nurth America Inc. | Improved catalyst for ethylbenzene conversion in a xylene isomerrization process |
WO2017105617A1 (en) | 2015-12-15 | 2017-06-22 | Exxonmobil Chemical Patents Inc. | Process for xylenes isomerization |
US9809509B2 (en) | 2015-12-15 | 2017-11-07 | Exxonmobil Chemical Patents Inc. | Process for xylenes isomerization |
SG11201811750SA (en) * | 2016-07-13 | 2019-01-30 | Shell Int Research | Catalyst composition comprising con-type zeolite and zsm-5-type zeolite, preparation and process using such composition |
SG11201901911TA (en) * | 2016-10-06 | 2019-04-29 | Shell Int Research | Alkylaromatic conversion catalyst |
WO2021048693A1 (en) * | 2019-09-10 | 2021-03-18 | Sabic Global Technologies B.V. | Aromatization catalyst with improved isomerization, reactor configurations and use thereof |
US10927057B1 (en) * | 2020-01-06 | 2021-02-23 | Uop Llc | Two bed liquid phase isomerization process |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4090981A (en) * | 1976-09-23 | 1978-05-23 | Mobile Oil Corporation | Catalyst for selective production of para dialkyl substituted benzenes |
US4117026A (en) * | 1976-05-12 | 1978-09-26 | Mobil Oil Corporation | Selective production of para dialkyl substituted benzenes |
US4163028A (en) * | 1977-07-22 | 1979-07-31 | Mobil Oil Corporation | Xylene isomerization |
USRE31782E (en) * | 1978-06-09 | 1984-12-25 | Mobil Oil Corporation | Xylene isomerization |
US4312790A (en) * | 1980-04-14 | 1982-01-26 | Mobil Oil Corporation | Aromatics processing catalysts |
US4560820A (en) * | 1981-04-13 | 1985-12-24 | Chevron Research Company | Alkylaromatic dealkylation |
US4477583A (en) * | 1983-06-09 | 1984-10-16 | Mobil Oil Corporation | Silica-modified catalyst and use for selective production of para-dialkyl substituted benzenes |
US4465886A (en) * | 1983-06-09 | 1984-08-14 | Mobil Oil Corporation | Silica-modified catalyst and use for selective production of para-dialkyl substituted benzenes |
US4582815A (en) * | 1984-07-06 | 1986-04-15 | Mobil Oil Corporation | Extrusion of silica-rich solids |
US4783568A (en) * | 1985-09-13 | 1988-11-08 | Uop Inc. | Xylene producing process having staged catalytic conversion of ethylbenzene |
US4899011A (en) * | 1986-01-15 | 1990-02-06 | Mobil Oil Corporation | Xylene isomerization process to exhaustively convert ethylbenzene and non-aromatics |
US5053374A (en) * | 1987-05-01 | 1991-10-01 | Mobil Oil Corporation | Method for preparing a zeolite catalyst bound with a refractory oxide of low acidity |
US5004855A (en) * | 1987-08-25 | 1991-04-02 | Toray Industries, Inc. | Process for conversion of ethylbenzene in C8 aromatic hydrocarbon mixture |
US4950835A (en) * | 1989-10-24 | 1990-08-21 | Taiwan Styrene Monomer Corporation | Novel silicon-modified catalyst Si/HZSM-5, it's preparation, and a process for synthesizing high purity p-dialkyl benzene from monoalkyl benzene by using said catalyst |
US5321183A (en) * | 1992-03-12 | 1994-06-14 | Mobil Oil Corp. | Process for the regioselective conversion of aromatics to para-disubstituted benzenes |
US5365003A (en) * | 1993-02-25 | 1994-11-15 | Mobil Oil Corp. | Shape selective conversion of hydrocarbons over extrusion-modified molecular sieve |
US5349114A (en) * | 1993-04-05 | 1994-09-20 | Mobil Oil Corp. | Shape selective hydrocarbon conversions over modified catalyst |
US5371312A (en) * | 1993-04-05 | 1994-12-06 | Mobil Oil Corp. | Shape selective hydrocarbon conversions over modified catalyst |
US5382737A (en) * | 1993-05-28 | 1995-01-17 | Mobil Oil Corp. | Selective ethylbenzene disproportionation process (SEBDP) with ex situ selectivated zeolite catalysts |
US5367099A (en) * | 1993-05-28 | 1994-11-22 | Mobil Oil Corp. | Selective toluene disproportionation process (STDP) with ex situ selectivated zeolite catalyst |
US5365004A (en) * | 1993-05-28 | 1994-11-15 | Mobil Oil Corp. | Selective toluene disproportionation process (STDP) with ex situ selectivated zeolite catalysts |
-
1994
- 1994-11-18 US US08/342,322 patent/US5516956A/en not_active Expired - Lifetime
-
1995
- 1995-11-16 WO PCT/US1995/016006 patent/WO1996016005A1/en active IP Right Grant
- 1995-11-16 DE DE69520592T patent/DE69520592T2/de not_active Expired - Fee Related
- 1995-11-16 CA CA002203365A patent/CA2203365C/en not_active Expired - Lifetime
- 1995-11-16 JP JP51711796A patent/JP3857311B2/ja not_active Expired - Lifetime
- 1995-11-16 ES ES95941529T patent/ES2155538T3/es not_active Expired - Lifetime
- 1995-11-16 EP EP95941529A patent/EP0792251B1/de not_active Expired - Lifetime
- 1995-11-16 KR KR1019970703266A patent/KR100369429B1/ko not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
EP0792251B1 (de) | 2001-04-04 |
ES2155538T3 (es) | 2001-05-16 |
EP0792251A1 (de) | 1997-09-03 |
KR970707062A (ko) | 1997-12-01 |
WO1996016005A1 (en) | 1996-05-30 |
CA2203365A1 (en) | 1996-05-30 |
CA2203365C (en) | 2007-06-26 |
KR100369429B1 (ko) | 2003-04-10 |
JPH10509720A (ja) | 1998-09-22 |
US5516956A (en) | 1996-05-14 |
JP3857311B2 (ja) | 2006-12-13 |
EP0792251A4 (de) | 1997-11-19 |
DE69520592D1 (de) | 2001-05-10 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition | ||
8339 | Ceased/non-payment of the annual fee |