DE69600667T2 - Verfahren sowie katalysator zur behandlung von kohlenwasserstoffen - Google Patents
Verfahren sowie katalysator zur behandlung von kohlenwasserstoffenInfo
- Publication number
- DE69600667T2 DE69600667T2 DE69600667T DE69600667T DE69600667T2 DE 69600667 T2 DE69600667 T2 DE 69600667T2 DE 69600667 T DE69600667 T DE 69600667T DE 69600667 T DE69600667 T DE 69600667T DE 69600667 T2 DE69600667 T2 DE 69600667T2
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- core
- treating hydrocarbons
- surface layer
- ratio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 title 1
- 229930195733 hydrocarbon Natural products 0.000 title 1
- 150000002430 hydrocarbons Chemical class 0.000 title 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- 229910052710 silicon Inorganic materials 0.000 abstract 2
- 239000010703 silicon Substances 0.000 abstract 2
- 239000002344 surface layer Substances 0.000 abstract 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 abstract 1
- 229910021536 Zeolite Inorganic materials 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052733 gallium Inorganic materials 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 239000002808 molecular sieve Substances 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 238000006384 oligomerization reaction Methods 0.000 abstract 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 abstract 1
- 239000010457 zeolite Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/12—Catalytic processes with crystalline alumino-silicates or with catalysts comprising molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
-
- B01J35/19—
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/80—Mixtures of different zeolites
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB9502342.0A GB9502342D0 (en) | 1995-02-07 | 1995-02-07 | Hydrocarbon treatment and catalyst therefor |
PCT/EP1996/000395 WO1996024567A1 (en) | 1995-02-07 | 1996-01-29 | Hydrocarbon treatment and catalyst therefor |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69600667D1 DE69600667D1 (de) | 1998-10-22 |
DE69600667T2 true DE69600667T2 (de) | 1999-04-08 |
Family
ID=10769201
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69600667T Expired - Lifetime DE69600667T2 (de) | 1995-02-07 | 1996-01-29 | Verfahren sowie katalysator zur behandlung von kohlenwasserstoffen |
Country Status (13)
Country | Link |
---|---|
US (2) | US6013851A (de) |
EP (1) | EP0808298B1 (de) |
JP (1) | JP3937241B2 (de) |
KR (1) | KR100360734B1 (de) |
CN (2) | CN1072187C (de) |
AT (1) | ATE171155T1 (de) |
AU (1) | AU697790B2 (de) |
CA (1) | CA2211043C (de) |
DE (1) | DE69600667T2 (de) |
ES (1) | ES2122782T3 (de) |
GB (1) | GB9502342D0 (de) |
WO (1) | WO1996024567A1 (de) |
ZA (1) | ZA96891B (de) |
Families Citing this family (61)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999028031A1 (en) | 1997-12-03 | 1999-06-10 | Exxon Chemical Patents Inc. | Catalyst comprising a zeolite partially coated with a second zeolite, its use for hydrocarbon conversion |
US6177381B1 (en) | 1998-11-03 | 2001-01-23 | Uop Llc | Layered catalyst composition and processes for preparing and using the composition |
WO2001074970A2 (en) | 2000-04-03 | 2001-10-11 | Chevron U.S.A. Inc. | Improved conversion of syngas to distillate fuels |
GB0010433D0 (en) * | 2000-04-28 | 2000-06-14 | Exxon Chemical Patents Inc | Alkene oligomerization process |
US7112711B2 (en) | 2000-04-28 | 2006-09-26 | Exxonmobil Chemical Patents Inc. | Alkene oligomerization process |
US6521198B2 (en) * | 2000-05-17 | 2003-02-18 | The Regents Of The University Of California | Metal surfaces coated with molecular sieve for corrosion resistance |
US6515033B2 (en) | 2001-05-11 | 2003-02-04 | Chevron U.S.A. Inc. | Methods for optimizing fischer-tropsch synthesis hydrocarbons in the distillate fuel range |
AU2003218439A1 (en) * | 2002-03-29 | 2003-10-13 | Exxonmobil Chemical Patents Inc. | Process for olefin oligomerization |
AU2003222120A1 (en) * | 2002-03-29 | 2003-10-13 | Exxonmobil Chemical Patents Inc. | Oxon process |
EP1494983A1 (de) * | 2002-03-29 | 2005-01-12 | ExxonMobil Chemical Patents, Inc. a Corporation of the State of Delaware | Oligomerisierung von olefinen |
US7081553B2 (en) * | 2002-03-29 | 2006-07-25 | Exxonmobil Chemical Patents Inc. | Cobalt flash process |
FR2843049B1 (fr) * | 2002-08-01 | 2005-03-25 | Inst Francais Du Petrole | Adsorbant non homogene et son utilisation dans des procedes de separation diffusionnelle |
EP1697287B1 (de) | 2003-12-18 | 2015-08-26 | ExxonMobil Chemical Patents Inc. | Verbesserungen auf dem gebiet der hydrierung |
WO2005058787A1 (en) | 2003-12-18 | 2005-06-30 | Exxonmobil Chemical Patents Inc. | Improvements in or relating to hydroformylation |
ATE517074T1 (de) * | 2003-12-18 | 2011-08-15 | Exxonmobil Chem Patents Inc | Verbesserungen in oder in bezug auf katalytisierten reaktionen |
US7442365B1 (en) | 2004-06-14 | 2008-10-28 | Uop Llc | Process for preparing molecular sieve beads |
US7320782B1 (en) * | 2004-06-14 | 2008-01-22 | Uop Llc | Process for preparing a layered molecular sieve composition |
PL1616839T3 (pl) * | 2004-07-16 | 2014-03-31 | Uop Llc | Sposób syntetyzowania sit molekularnych |
GB0512377D0 (en) | 2005-06-17 | 2005-07-27 | Exxonmobil Chem Patents Inc | Oligomerisation of olefins with zeolite catalyst |
US8278235B2 (en) * | 2007-06-20 | 2012-10-02 | Basf Corporation | Structurally enhanced cracking catalysts |
US9108181B2 (en) * | 2007-06-20 | 2015-08-18 | Basf Corporation | Structurally enhanced cracking catalysts |
EP2067528A1 (de) | 2007-11-29 | 2009-06-10 | Uop Llc | Verfahren zur Herstellung einer schichtförmigen Molekularsieb-Zusammensetzung |
US8193402B2 (en) | 2007-12-03 | 2012-06-05 | Gevo, Inc. | Renewable compositions |
EP2225351A4 (de) | 2007-12-03 | 2016-11-09 | Gevo Inc | Erneuerbare zusammensetzungen |
CN101314135B (zh) * | 2008-06-27 | 2011-05-11 | 吉林大学 | 水热或溶剂热体系制备双催化中心分子筛核壳材料的方法 |
US8476350B2 (en) * | 2008-12-24 | 2013-07-02 | Exxonmobil Research And Engineering Company | Triglyceride plasticizer and process of making |
EP2513153A1 (de) | 2009-12-15 | 2012-10-24 | ExxonMobil Chemical Patents Inc. | Temperaturregelung eines oligomerisationsverfahrens und reaktor |
US8771815B2 (en) | 2009-12-17 | 2014-07-08 | Exxonmobil Research And Engineering Company | Process for making triglyceride plasticizer |
SG182407A1 (en) | 2010-01-08 | 2012-08-30 | Gevo Inc | Integrated methods of preparing renewable chemicals |
WO2011140560A1 (en) | 2010-05-07 | 2011-11-10 | Gevo, Inc. | Renewable jet fuel blendstock from isobutanol |
WO2012033562A1 (en) | 2010-09-07 | 2012-03-15 | Exxonmobil Chemical Patents Inc. | Extrudates including zeolite catalysts and their use in oligomerization processes |
US8742187B2 (en) | 2011-04-19 | 2014-06-03 | Gevo, Inc. | Variations on prins-like chemistry to produce 2,5-dimethylhexadiene from isobutanol |
US9505685B2 (en) | 2011-07-25 | 2016-11-29 | Exxonmobil Chemical Patents Inc. | Olefin oligomerization process |
WO2013013886A2 (en) | 2011-07-25 | 2013-01-31 | Exxonmobil Chemical Patents Inc. | Olefin oligomerization process |
US9573861B2 (en) | 2011-07-25 | 2017-02-21 | Exxonmobil Chemical Patents Inc. | Olefin oligomerization process |
WO2013013884A2 (en) | 2011-07-25 | 2013-01-31 | Exxonmobil Chemical Patents Inc. | Process for nitrile removal from hydrocarbon feeds |
WO2013013885A2 (en) | 2011-07-25 | 2013-01-31 | Exxonmobil Chemical Patents Inc. | Integrated nitrile poison adsorption and desorption system |
KR20130017165A (ko) * | 2011-08-10 | 2013-02-20 | 서강대학교산학협력단 | 제올라이트 코어/실리카 제올라이트 쉘 복합체, 그의 제조 방법 및 그의 촉매적 용도 |
EP2797854B9 (de) | 2011-12-30 | 2017-08-30 | K+S KALI GmbH | Zusammensetzung einer magnesiumsulfat-harnstoff-verbindung |
CA3092028C (en) | 2012-01-13 | 2022-08-30 | Lummus Technology Llc | Process for separating hydrocarbon compounds |
US9670113B2 (en) | 2012-07-09 | 2017-06-06 | Siluria Technologies, Inc. | Natural gas processing and systems |
WO2014089479A1 (en) | 2012-12-07 | 2014-06-12 | Siluria Technologies, Inc. | Integrated processes and systems for conversion of methane to multiple higher hydrocarbon products |
DE102012025141A1 (de) | 2012-12-21 | 2014-06-26 | K+S Aktiengesellschaft | Zusammensetzung einer Magnesium-Harnstoff-Verbindung |
US10047020B2 (en) | 2013-11-27 | 2018-08-14 | Siluria Technologies, Inc. | Reactors and systems for oxidative coupling of methane |
CA3123783A1 (en) | 2014-01-08 | 2015-07-16 | Lummus Technology Llc | Ethylene-to-liquids systems and methods |
CA3225180A1 (en) | 2014-01-09 | 2015-07-16 | Lummus Technology Llc | Oxidative coupling of methane implementations for olefin production |
US10377682B2 (en) | 2014-01-09 | 2019-08-13 | Siluria Technologies, Inc. | Reactors and systems for oxidative coupling of methane |
US9334204B1 (en) | 2015-03-17 | 2016-05-10 | Siluria Technologies, Inc. | Efficient oxidative coupling of methane processes and systems |
US10793490B2 (en) | 2015-03-17 | 2020-10-06 | Lummus Technology Llc | Oxidative coupling of methane methods and systems |
RU2017131237A (ru) | 2015-03-20 | 2019-04-22 | Эксонмобил Кемикэл Пейтентс Инк. | Способ превращения содержащего олефин углеводородного сырья в продукт реакции олигомеризации или гидрированный продукт реакции олигомеризации |
US20160289143A1 (en) | 2015-04-01 | 2016-10-06 | Siluria Technologies, Inc. | Advanced oxidative coupling of methane |
US20160312134A1 (en) * | 2015-04-24 | 2016-10-27 | Uop Llc | Process for the production of jet-range hydrocarbons |
US9328297B1 (en) | 2015-06-16 | 2016-05-03 | Siluria Technologies, Inc. | Ethylene-to-liquids systems and methods |
EP3786138A1 (de) | 2015-10-16 | 2021-03-03 | Lummus Technology LLC | Oxidative kupplung von methan |
WO2017180910A1 (en) | 2016-04-13 | 2017-10-19 | Siluria Technologies, Inc. | Oxidative coupling of methane for olefin production |
WO2018118105A1 (en) | 2016-12-19 | 2018-06-28 | Siluria Technologies, Inc. | Methods and systems for performing chemical separations |
DE102017104877A1 (de) | 2017-03-08 | 2018-09-13 | K+S Aktiengesellschaft | Magnesiumsulfat-Granulate auf Basis von synthetischem Magnesiumsulfat |
DE102017104876A1 (de) | 2017-03-08 | 2018-09-13 | K+S Aktiengesellschaft | Verwendung von Magnesiumsulfat-Granulaten |
ES2960342T3 (es) | 2017-05-23 | 2024-03-04 | Lummus Technology Inc | Integración de procedimientos de acoplamiento oxidativo del metano |
EP3649097A4 (de) | 2017-07-07 | 2021-03-24 | Lummus Technology LLC | Systeme und verfahren zur oxidativen kopplung von methan |
CN109908944B (zh) * | 2019-04-12 | 2020-09-15 | 西南化工研究设计院有限公司 | 一种丙烯齐聚制备壬烯和十二烯的催化剂及其制备方法 |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4203869A (en) * | 1976-09-24 | 1980-05-20 | Mobil Oil Corporation | ZSM-5 Containing aluminum-free shells on its surface |
US4394362A (en) * | 1981-04-28 | 1983-07-19 | Chevron Research Company | Crystalline silicate particle having an aluminum-containing outer shell |
EP0118632A1 (de) * | 1983-03-14 | 1984-09-19 | Mobil Oil Corporation | Kristalline Stoffe und Verfahren zu ihrer Herstellung |
US4975401A (en) | 1983-05-02 | 1990-12-04 | Mobil Oil Corporation | ZSM-5/ZSM-12 catalyst mixture for cracking alkylbenzenes |
US4575416A (en) | 1984-07-16 | 1986-03-11 | Mobil Oil Corporation | Hydrodewaxing with mixed zeolite catalysts |
FR2600557B1 (fr) * | 1986-06-24 | 1993-03-19 | Elf France | Systemes zeolitiques binaires, leur synthese et leur utilisation |
AU613954B2 (en) | 1987-10-07 | 1991-08-15 | Mobil Oil Corporation | Olefin oligomerization |
US4788374A (en) * | 1987-12-23 | 1988-11-29 | Mobil Oil Corporation | Zeolite catalysis |
DE3914817C2 (de) | 1989-05-05 | 1995-09-07 | Huels Chemische Werke Ag | Verfahren zur Oligomerisierung von Olefinen |
GB9114390D0 (en) | 1991-07-03 | 1991-08-21 | Shell Int Research | Hydrocarbon conversion process and catalyst composition |
JP2800499B2 (ja) * | 1991-09-18 | 1998-09-21 | 日産自動車株式会社 | 炭化水素吸着材 |
US5250484A (en) | 1991-11-26 | 1993-10-05 | Mobil Oil Corporation | Surface modified porous acidic crystalline catalyst |
AU671463B2 (en) | 1992-06-05 | 1996-08-29 | Exxon Chemical Patents Inc. | ZSM-22 zeolite |
US5284989A (en) | 1992-11-04 | 1994-02-08 | Mobil Oil Corporation | Olefin oligomerization with surface modified zeolite catalyst |
SG48109A1 (en) * | 1993-04-23 | 1998-04-17 | Exxon Chemical Ltd | Molecular sieve layers and processes for their manufacture |
CA2182994A1 (en) * | 1994-02-22 | 1995-08-24 | Exxonmobil Chemical Patents, Inc. | Oligomerization and catalysts therefor |
DE19619138C2 (de) * | 1996-05-11 | 2002-04-18 | Degussa | Verfahren zur Herstellung von vinylierten Silicium-organischen Verbindungen |
-
1995
- 1995-02-07 GB GBGB9502342.0A patent/GB9502342D0/en active Pending
-
1996
- 1996-01-29 DE DE69600667T patent/DE69600667T2/de not_active Expired - Lifetime
- 1996-01-29 AT AT96901339T patent/ATE171155T1/de not_active IP Right Cessation
- 1996-01-29 US US08/875,749 patent/US6013851A/en not_active Expired - Lifetime
- 1996-01-29 JP JP52394896A patent/JP3937241B2/ja not_active Expired - Fee Related
- 1996-01-29 ES ES96901339T patent/ES2122782T3/es not_active Expired - Lifetime
- 1996-01-29 WO PCT/EP1996/000395 patent/WO1996024567A1/en active IP Right Grant
- 1996-01-29 CN CN96191820A patent/CN1072187C/zh not_active Expired - Fee Related
- 1996-01-29 AU AU45395/96A patent/AU697790B2/en not_active Ceased
- 1996-01-29 EP EP96901339A patent/EP0808298B1/de not_active Expired - Lifetime
- 1996-01-29 KR KR1019970705388A patent/KR100360734B1/ko not_active IP Right Cessation
- 1996-01-29 CA CA002211043A patent/CA2211043C/en not_active Expired - Fee Related
- 1996-02-05 ZA ZA96891A patent/ZA96891B/xx unknown
-
1999
- 1999-11-08 US US09/436,485 patent/US6300536B1/en not_active Expired - Fee Related
- 1999-11-30 CN CN99124400A patent/CN1277951A/zh active Pending
Also Published As
Publication number | Publication date |
---|---|
CN1173858A (zh) | 1998-02-18 |
JPH10513459A (ja) | 1998-12-22 |
US6013851A (en) | 2000-01-11 |
CA2211043C (en) | 2001-03-20 |
CA2211043A1 (en) | 1996-08-15 |
DE69600667D1 (de) | 1998-10-22 |
EP0808298B1 (de) | 1998-09-16 |
US6300536B1 (en) | 2001-10-09 |
ATE171155T1 (de) | 1998-10-15 |
GB9502342D0 (en) | 1995-03-29 |
JP3937241B2 (ja) | 2007-06-27 |
EP0808298A1 (de) | 1997-11-26 |
CN1277951A (zh) | 2000-12-27 |
AU4539596A (en) | 1996-08-27 |
AU697790B2 (en) | 1998-10-15 |
CN1072187C (zh) | 2001-10-03 |
WO1996024567A1 (en) | 1996-08-15 |
KR19980701991A (ko) | 1998-06-25 |
KR100360734B1 (ko) | 2003-02-07 |
ES2122782T3 (es) | 1998-12-16 |
ZA96891B (en) | 1996-07-16 |
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