DE69606892T2 - Alkyllithiumverbindungen, welche zyklische Amine enthalten und ihre Verwendung in Polymerisationsreaktionen - Google Patents
Alkyllithiumverbindungen, welche zyklische Amine enthalten und ihre Verwendung in PolymerisationsreaktionenInfo
- Publication number
- DE69606892T2 DE69606892T2 DE69606892T DE69606892T DE69606892T2 DE 69606892 T2 DE69606892 T2 DE 69606892T2 DE 69606892 T DE69606892 T DE 69606892T DE 69606892 T DE69606892 T DE 69606892T DE 69606892 T2 DE69606892 T2 DE 69606892T2
- Authority
- DE
- Germany
- Prior art keywords
- compounds containing
- containing cyclic
- cyclic amines
- polymerization reactions
- alkyl lithium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- -1 Alkyl lithium compounds Chemical class 0.000 title 1
- 238000006116 polymerization reaction Methods 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic System
- C07F1/02—Lithium compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polymerization Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/382,477 US5496940A (en) | 1995-02-01 | 1995-02-01 | Alkyllithium compounds containing cyclic amines and their use in polymerization |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69606892D1 DE69606892D1 (de) | 2000-04-13 |
| DE69606892T2 true DE69606892T2 (de) | 2000-06-29 |
Family
ID=23509127
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69606892T Expired - Fee Related DE69606892T2 (de) | 1995-02-01 | 1996-01-29 | Alkyllithiumverbindungen, welche zyklische Amine enthalten und ihre Verwendung in Polymerisationsreaktionen |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US5496940A (de) |
| EP (1) | EP0725069B1 (de) |
| JP (1) | JP4157170B2 (de) |
| CA (1) | CA2168499A1 (de) |
| DE (1) | DE69606892T2 (de) |
| ES (1) | ES2143674T3 (de) |
Families Citing this family (96)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6080835A (en) | 1995-02-01 | 2000-06-27 | Bridgestone Corporation | Aminoalkyllithium compounds containing cyclic amines and polymers therefrom |
| US6717014B1 (en) | 1996-06-28 | 2004-04-06 | Fmc Corporation | Processes for preparing haloamines and tertiary aminoalkylorganometallic compounds |
| US5728782A (en) * | 1996-12-06 | 1998-03-17 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase anionic polymerization of dienes and vinyl-substituted aromatic compounds |
| US5786441A (en) * | 1996-12-31 | 1998-07-28 | Bridgestone Corporation | Polymers, elastomeric compounds and products thereof, derived from novel amine compounds containing side-chain organolithium moieties |
| US5852189A (en) * | 1996-12-31 | 1998-12-22 | Bridgestone Corporation | Tertiaryaminoalkyllithium initiators and the preparation thereof |
| US5912343A (en) * | 1996-12-31 | 1999-06-15 | Bridgestone Corporation | Tertiary amines containing side-chain organolithium structures and method for the preparation thereof |
| US5736617A (en) * | 1996-12-31 | 1998-04-07 | Bridgestone Corporation | Polymers, elastomeric compounds, and products thereof, terminated with novel amine compounds containing side-chain organohalide reactive moieties |
| US5916961A (en) * | 1997-07-11 | 1999-06-29 | Bridgestone Corporation | Amine-initiated elastomers having hysteresis reducing interaction with silica |
| US5866650A (en) * | 1997-07-11 | 1999-02-02 | Bridgestone Corporation | Composition of cyclic amine-initiated elastomers and amorphous silica and process for the production thereof |
| US5935893A (en) * | 1997-08-01 | 1999-08-10 | Bridgestone Corporation | Aliphatic solutions of aminoalkyllithium compounds |
| US6184338B1 (en) | 1997-08-27 | 2001-02-06 | Fmc Corporation | Anionic polymerization initiators containing tertiary amine functionality, their chain extended analogues, and processes for using the same |
| US6605564B1 (en) * | 1997-11-14 | 2003-08-12 | Fmc Corporation | Compositions providing improved functionalization of terminal anions and processes for improved functionalization of terminal anions |
| US6545103B2 (en) | 1997-11-14 | 2003-04-08 | Fmc Corporation | Compositions providing improved functionalization of terminal anions and processes for improved functionalization of terminal anions |
| US7056979B1 (en) * | 1998-06-12 | 2006-06-06 | Bridgestone Corporation | Reaction product derived from amine-functionalized elastomers and maleated polyolefins |
| US6121474A (en) * | 1999-02-24 | 2000-09-19 | Fmc Corporation | Amine anionic polymerization initiators and functionalized polymers derived therefrom |
| US6610859B1 (en) * | 1999-02-24 | 2003-08-26 | Fmc Corporation | Protected aminofunctionalized polymerization initiators and methods of making and using same |
| US6451935B1 (en) | 2000-05-10 | 2002-09-17 | Bridgestone Corporation | Highly functionalized polymers and a process for making the same |
| US6313210B1 (en) | 2000-07-31 | 2001-11-06 | Bridgestone Coporation | Silica-reinforced rubber compounds containing moisture stabilized polymers |
| US6943250B2 (en) | 2001-03-06 | 2005-09-13 | Fmc Corporation | Protected aminofunctionalized polymerization initiators and methods of making and using same |
| US20030069366A1 (en) * | 2001-09-17 | 2003-04-10 | Letchford Robert J. | Urethane oligomers of heterotelechelic amine functional polyolefins |
| JP4763285B2 (ja) * | 2002-07-11 | 2011-08-31 | 株式会社ブリヂストン | 官能化陰イオン性重合開始剤の調製 |
| WO2004020475A1 (en) * | 2002-08-30 | 2004-03-11 | Bridgestone Corporation | Functionalized polymers and improved vulcanizates therefrom |
| EP2266993B1 (de) | 2002-10-30 | 2017-06-14 | Bridgestone Corporation | Verwendung von schwefelhaltigen initiatoren zur anionischen polymerisation von monomeren |
| US7671139B1 (en) | 2004-06-18 | 2010-03-02 | Bridgestone Corporation | Functionalized polymers and tires made therefrom |
| KR20070058554A (ko) * | 2004-10-02 | 2007-06-08 | 화이어스톤 폴리머스, 엘엘씨 | 아스팔트 조성물 및 아스팔트 콘크리트에 사용되는 중합체 |
| US7335712B2 (en) * | 2005-04-21 | 2008-02-26 | Bridgestone Corporation | Process of producing a siloxy-functionalized polymer |
| US20060264590A1 (en) * | 2005-05-20 | 2006-11-23 | Bridgestone Corporation | Anionic polymerization initiators and polymers therefrom |
| US7868110B2 (en) * | 2005-05-20 | 2011-01-11 | Bridgestone Corporation | Anionic polymerization initiators and polymers therefrom |
| US7875671B2 (en) | 2006-08-03 | 2011-01-25 | Bridgestone Corporation | Process for preparing filler-dispersed polymeric compositions |
| KR101457981B1 (ko) * | 2006-10-06 | 2014-11-05 | 가부시키가이샤 브리지스톤 | 분지화 중합체 및 그의 합성 방법 및 용도 |
| ZA200711159B (en) | 2006-12-28 | 2009-03-25 | Bridgestone Corp | Amine-containing alkoxysilyl-functionalized polymers |
| US8053621B2 (en) * | 2006-12-29 | 2011-11-08 | Bridgestone Corporation | Solvent treatment methods and polymerization processes employing the treatment methods |
| US8580874B2 (en) | 2007-04-20 | 2013-11-12 | Firestone Polymers, Llc | Polymer-modified asphalt compositions |
| US8063165B2 (en) | 2007-06-18 | 2011-11-22 | Bridgestone Corporation | Functional polymers prepared with sulfur-containing initiators |
| US7829624B2 (en) | 2007-06-29 | 2010-11-09 | Bridgestone Corporation | One-pot synthesis of nanoparticles and liquid polymer for rubber applications |
| US8314189B2 (en) | 2007-10-12 | 2012-11-20 | Bridgestone Corporation | Polymers functionalized with heterocyclic nitrile compounds |
| US20090326176A1 (en) * | 2007-12-28 | 2009-12-31 | Yuan-Yong Yan | Novel multifunctional initiators for anionic polymerization and polymers therefrom |
| ES2530797T3 (es) * | 2008-03-15 | 2015-03-05 | Bridgestone Corp | Polímeros funcionalizados e iniciadores para su fabricación |
| WO2009148932A1 (en) * | 2008-06-06 | 2009-12-10 | Dow Global Technologies Inc. | Modified elastomeric polymers |
| US9732178B1 (en) | 2008-07-24 | 2017-08-15 | Bridgestone Corporation | Block copolymers including high vinyl segments |
| FR2946048B1 (fr) * | 2009-06-02 | 2012-12-28 | Michelin Soc Tech | Systeme catalytique pour la polymerisation de dienes conjugues,procede de polymerisation et polymere fonctionnel obtenu |
| KR101752934B1 (ko) | 2009-06-30 | 2017-07-03 | 가부시키가이샤 브리지스톤 | 음이온 중합 개시제 및 방법 |
| US8338544B2 (en) | 2009-12-21 | 2012-12-25 | Bridgestone Corporation | Polymers functionalized with polyoxime compounds and methods for their manufacture |
| EP2516478B1 (de) | 2009-12-21 | 2014-06-11 | Styron Europe GmbH | Modifizierte polymerzusammensetzungen |
| ES2439669T3 (es) | 2009-12-21 | 2014-01-24 | Styron Europe Gmbh | Composiciones poliméricas modificadas |
| PL2516410T3 (pl) | 2009-12-22 | 2014-10-31 | Bridgestone Corp | Udoskonalona kompozycja modyfikatora winylu oraz procesy zastosowania takiej kompozycji |
| WO2011082098A1 (en) | 2009-12-30 | 2011-07-07 | The Rockefeller University | Lysine and arginine methyltransferase inhibitors for treating cancer |
| EP2519548B1 (de) | 2009-12-31 | 2020-04-01 | Bridgestone Corporation | Aminosilaninitiatoren und daraus hergestellte funktionalisierte polymere |
| RU2564352C2 (ru) | 2010-01-22 | 2015-09-27 | Бриджстоун Корпорейшн | Полимеры, функционализованные нитрильными соединениями, имеющими защищенную аминогруппу |
| US9051455B2 (en) | 2010-05-31 | 2015-06-09 | Bridgestone Corporation | Hydroxyl group-containing methylstyrene and polymers incorporating same |
| WO2012041804A2 (en) | 2010-09-30 | 2012-04-05 | Styron Europe Gmbh | Polymer compositions |
| US8748531B2 (en) | 2010-12-10 | 2014-06-10 | Bridgestone Corporation | Polymers functionalized with oxime compounds containing an acyl group |
| US8962745B2 (en) | 2010-12-27 | 2015-02-24 | Bridgestone Corporation | Functionalized polymers and vulcanizates with reduced hysteretic loss |
| JP5740487B2 (ja) | 2010-12-30 | 2015-06-24 | 株式会社ブリヂストン | アミノシラン開始剤及びそれを用いた官能化ポリマー |
| EP2670759B1 (de) | 2011-02-05 | 2018-04-18 | Bridgestone Corporation | Lanthanidkomplexkatalysator und polymerisationsverfahren damit |
| US9403919B2 (en) | 2011-03-29 | 2016-08-02 | Bridgestone Corporation | Polymers functionalized with a carboxylic or thiocarboxylic ester containing a silylated amino group |
| EP2751142B1 (de) | 2011-08-31 | 2015-12-09 | Bridgestone Corporation | Funktionalisierte polymere mit lactonen oder thiolaktonen mit einer geschützten aminogruppe |
| US9000070B2 (en) | 2011-10-19 | 2015-04-07 | Bridgestone Corporation | Mixing of telechelic rubber formulations |
| KR101956957B1 (ko) | 2011-11-18 | 2019-03-11 | 가부시키가이샤 브리지스톤 | 폴리디엔을 생산하는 방법 및 감소된 저온 유동을 갖는 폴리디엔 공중합체 |
| CN104093751B (zh) | 2011-12-09 | 2017-05-31 | 株式会社普利司通 | 制备具有减少的冷流的聚二烯和聚二烯共聚物的方法 |
| TWI585115B (zh) | 2011-12-15 | 2017-06-01 | 普利司通股份有限公司 | 經穩定之多價陰離子聚合反應引發劑及其製備方法 |
| US8685513B1 (en) | 2012-02-29 | 2014-04-01 | Carolyn M. Dry | Inflatable articles comprising a self-repairing laminate |
| US9694629B1 (en) | 2012-02-29 | 2017-07-04 | Carolyn Dry | Self-repairing inflatable articles incorporating an integrated self-repair system |
| SG11201407010RA (en) | 2012-05-01 | 2014-11-27 | Bridgestone Corp | Polydienes and diene copolymers having organophosphine functionality |
| EP2662392A1 (de) | 2012-05-09 | 2013-11-13 | LANXESS Deutschland GmbH | Allylaminhaltige, carbinolterminierte Polymere |
| EP2662406A1 (de) | 2012-05-09 | 2013-11-13 | LANXESS Deutschland GmbH | Aminhaltige, carbinolterminierte Polymere |
| US9469706B2 (en) | 2012-06-08 | 2016-10-18 | Bridgestone Corporation | Polymers functionalized with unsaturated heterocycles containing a protected amino group |
| WO2014052957A1 (en) | 2012-09-30 | 2014-04-03 | Bridgestone Corporation | Organometallic catalyst complex and polymerization method employing same |
| US9540502B2 (en) | 2012-11-09 | 2017-01-10 | Bridgestone Corporation | Uses of biobased styrene |
| US9663637B2 (en) | 2012-12-31 | 2017-05-30 | Bridgestone Corporation | Polymers functionalized with unsaturated heterocycles containing an azolinyl group |
| US9127092B2 (en) | 2012-12-31 | 2015-09-08 | Bridgestone Corporation | Method for producing polydienes and polydiene copolymers with reduced cold flow |
| WO2014107447A1 (en) | 2013-01-02 | 2014-07-10 | Bridgestone Corporation | Functionalized polymers |
| CN105209268B (zh) | 2013-03-15 | 2018-05-04 | 株式会社普利司通 | 经杂环亚胺官能化的聚合物 |
| EP2796485A1 (de) | 2013-04-24 | 2014-10-29 | LANXESS Deutschland GmbH | Cold Flow reduzierte Polymere mit gutem Verarbeitungsverhalten |
| EP2796471A1 (de) | 2013-04-24 | 2014-10-29 | LANXESS Deutschland GmbH | Silanhaltige carboxyterminierte Polymere |
| KR102456909B1 (ko) | 2013-10-02 | 2022-10-21 | 가부시키가이샤 브리지스톤 | 시아노 기를 함유하는 이민 화합물로 작용화된 중합체 |
| EP2865540A1 (de) | 2013-10-24 | 2015-04-29 | LANXESS Deutschland GmbH | Kautschukzusammensetzung |
| EP3080167A2 (de) | 2013-12-12 | 2016-10-19 | Firestone Polymers, LLC | Verfahren zur herstellung von polymeren zusammensetzungen mit funktionalisierten polymeren |
| US10030083B2 (en) | 2014-05-15 | 2018-07-24 | Bridgestone Corporation | Polymers functionalized with protected oxime compounds containing a cyano group |
| CN110283280B (zh) | 2014-05-31 | 2022-11-04 | 株式会社普利司通 | 金属络合物催化剂、采用金属络合物催化剂的聚合方法及其聚合物产品 |
| JP6734269B2 (ja) | 2014-10-07 | 2020-08-05 | 株式会社ブリヂストン | 低減されたコールドフローを有するポリジエン及びポリジエン共重合体を生成するための方法 |
| EP3053934A1 (de) | 2015-02-06 | 2016-08-10 | LANXESS Deutschland GmbH | Heteroatomhaltige modifizierte Dienpolymere |
| US10077323B2 (en) | 2015-07-24 | 2018-09-18 | Bridgestone Corporation | Polymers functionalized with imine compounds containing a protected thiol group |
| JP6866348B2 (ja) | 2015-07-29 | 2021-04-28 | 株式会社ブリヂストン | 官能化されたポリマーの調製方法、関連の官能化化合物、及びその調製 |
| RU2018110688A (ru) | 2015-08-28 | 2019-09-30 | Арланксео Дойчланд Гмбх | Реагенты десульфуризации с увеличенной эффективностью |
| EP3135712A1 (de) | 2015-08-28 | 2017-03-01 | ARLANXEO Deutschland GmbH | Erhöhte effizienz zur entschwefelung von reagenzien |
| US10519266B2 (en) | 2015-09-23 | 2019-12-31 | Bridgestone Corporation | Polydienes and diene copolymers using 1,1-bis(hydrocarbylthio)hydrocarbyl-1-ene compounds |
| WO2017087087A1 (en) | 2015-11-16 | 2017-05-26 | Bridgestone Corporation | Functional initiator for anionic polymerization |
| EP3366709A1 (de) | 2017-02-24 | 2018-08-29 | ARLANXEO Deutschland GmbH | In-chain-phosphin- und -phosphoniumhaltige dienpolymere |
| JP7096686B2 (ja) * | 2017-03-30 | 2022-07-06 | 住友化学株式会社 | アミノ基を有する有機リチウム化合物およびその中間体の製造方法、並びに有機リチウム化合物を用いた共役ジエン系重合体の製造方法 |
| KR102179487B1 (ko) * | 2017-12-05 | 2020-11-16 | 주식회사 엘지화학 | 변성 공액디엔계 중합체 및 이를 포함하는 고무 조성물 |
| EP3724246B1 (de) | 2017-12-14 | 2023-05-31 | Bridgestone Corporation | Gekoppelte polymerprodukte, verfahren zur herstellung und zusammensetzungen damit |
| JP7019818B2 (ja) | 2017-12-15 | 2022-02-15 | 株式会社ブリヂストン | 官能化ポリマー、官能化ポリマーの調製プロセス、及び官能化ポリマーを含有するゴム組成物 |
| US20220251246A1 (en) | 2019-07-16 | 2022-08-11 | Arlanxeo Deutschland Gmbh | Carboxyterminated diene rubbers |
| BR112022000726A2 (pt) | 2019-07-16 | 2022-03-08 | Arlanxeo Deutschland Gmbh | Borrachas de dieno terminado em 1-amino-3-(oxialquilalcoxissilil)-2-propanol |
| JP2024501217A (ja) | 2020-12-18 | 2024-01-11 | 株式会社ブリヂストン | バガス含有グアユールゴムとシランとを組み合わせたゴム組成物及び関連する方法 |
Family Cites Families (65)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE138070C (de) * | ||||
| US2849432A (en) * | 1956-02-06 | 1958-08-26 | Firestone Tire & Rubber Co | Polymerization of diolefines |
| US3317918A (en) * | 1956-08-21 | 1967-05-02 | Firestone Tire & Rubber Co | Butadiene polymers prepared with a lithium based catalyst characterized by having at least 29 percent of the butadiene as cis-1, 4 |
| NL252687A (de) * | 1959-06-30 | |||
| US3178398A (en) * | 1960-10-24 | 1965-04-13 | Phillips Petroleum Co | Production and curing of polymers containing terminally reactive nitrogen |
| US3109871A (en) * | 1960-12-27 | 1963-11-05 | Phillips Petroleum Co | Production and curing of polyfunctional terminally reactive polymers |
| US3177190A (en) * | 1961-06-14 | 1965-04-06 | Phillips Petroleum Co | Preparing and curing compositions of terminally reactive polymers |
| US3290277A (en) * | 1963-05-20 | 1966-12-06 | Shell Oil Co | Amino-containing block polymers of ethylene and alpha-alkyl styrene |
| US3326881A (en) * | 1963-10-11 | 1967-06-20 | Phillips Petroleum Co | Polymerization of vinylidene-containing monomers with an initiator consisting of an alkali metal derivative of a functional halogen-substituted aromatic compound |
| US3331821A (en) * | 1963-11-14 | 1967-07-18 | Phillips Petroleum Co | Catalyst composition and process of preparing conjugated diene polymers utilizing same |
| DE1300240B (de) * | 1964-01-22 | 1969-07-31 | Bayer Ag | Verfahren zur Herstellung von Polymerisaten konjugierter Diolefine |
| US3439049A (en) * | 1964-05-11 | 1969-04-15 | Phillips Petroleum Co | Organolithium polymerization initiator |
| US3393182A (en) * | 1965-02-23 | 1968-07-16 | Phillips Petroleum Co | Prevention of cold flow in polymers of conjugated dienes |
| US4085265A (en) * | 1972-08-25 | 1978-04-18 | Nippon Oil Company, Limited | Process for isomerization of lower polymers of butadiene |
| JPS5633410B2 (de) * | 1972-11-15 | 1981-08-04 | ||
| DE2355941A1 (de) * | 1973-11-09 | 1975-05-15 | Bayer Ag | Polymerisation und copolymerisation von dienen |
| US4026865A (en) * | 1974-07-01 | 1977-05-31 | Phillips Petroleum Company | Preparation of organometal terminated polymers |
| DD138070A1 (de) * | 1974-09-20 | 1979-10-10 | Peter Knoth | Verfahren zur polymerisation von konjugierten dienen zu"lebenden"polymeren |
| US4015061A (en) * | 1975-02-14 | 1977-03-29 | The Firestone Tire & Rubber Company | Protected amino-functional initiators and amino-terminated polymers and their production |
| US4112103A (en) * | 1976-04-15 | 1978-09-05 | Parke, Davis & Company | Antiarrhythmic (+,-)-cis-α-[3-(2,6-dimethyl-1-piperidinyl)propyl]-α-phenyl-2-pyridinemethanols |
| US4316001A (en) * | 1976-05-26 | 1982-02-16 | Societe Nationale Des Poudres Et Explosifs | Anionic polymerization of heterocyclic monomers with alkali metal amide hydroxylated compound initiator |
| JPS5465788A (en) * | 1977-11-07 | 1979-05-26 | Denki Kagaku Kogyo Kk | Preparation of copolymer |
| US4247418A (en) * | 1979-10-18 | 1981-01-27 | The Firestone Tire & Rubber Company | Polymerization catalyst and process for polymerizing dienes therewith |
| JPS5773030A (en) * | 1980-09-20 | 1982-05-07 | Bridgestone Corp | Rubber composition for tire |
| US4381810A (en) * | 1981-05-22 | 1983-05-03 | The Goodyear Tire & Rubber Company | Tire with dual tread compound |
| JPS58154703A (ja) * | 1982-03-09 | 1983-09-14 | Daicel Chem Ind Ltd | 光学活性な高分子の合成方法 |
| JPS58162604A (ja) * | 1982-03-19 | 1983-09-27 | Nippon Zeon Co Ltd | ジエン系重合体ゴムの改質方法 |
| US4414372A (en) * | 1982-06-17 | 1983-11-08 | E. I. Du Pont De Nemours & Co. | Process for preparing living polymers |
| US4476240A (en) * | 1982-07-01 | 1984-10-09 | The Firestone Tire & Rubber Company | Catalyst system containing an anionic initiator based on lithium and phosphine oxide modifier |
| JPS59140240A (ja) * | 1983-01-31 | 1984-08-11 | Japan Synthetic Rubber Co Ltd | ゴム組成物 |
| US4429091A (en) * | 1983-03-09 | 1984-01-31 | The Firestone Tire & Rubber Company | Oligomeric oxolanyl alkanes as modifiers for polymerization of dienes using lithium-based initiators |
| JPS59164308A (ja) * | 1983-03-09 | 1984-09-17 | Asahi Chem Ind Co Ltd | ポリエチレンの製造方法 |
| CA1217122A (en) * | 1983-06-01 | 1987-01-27 | John Timar | Pneumatic tire inner liner having puncture sealing characteristics |
| FR2567135B1 (fr) * | 1984-07-03 | 1989-01-13 | Asahi Chemical Ind | Polymere ou copolymere de butadiene et procede de preparation |
| US4616069A (en) * | 1984-10-26 | 1986-10-07 | Nippon Zeon Co., Ltd. | Process for making diene polymer rubbers |
| JPS61103901A (ja) * | 1984-10-26 | 1986-05-22 | Nippon Zeon Co Ltd | ジエン系共重合体ゴムの製造方法 |
| JPS61225202A (ja) * | 1985-03-29 | 1986-10-07 | Nippon Zeon Co Ltd | ゴムの変性方法 |
| IT1206738B (it) * | 1985-07-01 | 1989-05-03 | Eniricerche Spa | Metodo per la terminazione di polimeri viventi ottenuti per polimerizzazione anionica di monomeri dienici e/o vinilaromatici e composti adatti allo scopo. |
| IT1186746B (it) * | 1985-07-01 | 1987-12-16 | Eniricerche Spa | Metodo per la terminazione di polimeri viventi e composti adatti allo scopo |
| IT1186743B (it) * | 1985-07-01 | 1987-12-16 | Eniricerche Spa | Metodo per la terminazione di polimeri ottenuti per polimerizzazione anionica di monomeri dienici e/o vinilaromatici e composti adatti allo scopo |
| EP0473206B1 (de) * | 1985-10-11 | 1999-06-23 | Asahi Kasei Kogyo Kabushiki Kaisha | Endmodifizierte Blockcopolymere enthaltende Zusammensetzungen |
| US4835209A (en) * | 1986-01-10 | 1989-05-30 | Asahi Kasei Kogyo Kabushiki Kaisha | Rubber for tire treads and compositions thereof |
| US4647634A (en) * | 1986-03-10 | 1987-03-03 | The Goodyear Tire & Rubber Company | Randomizers for use in solution polymerizations |
| DD247455A1 (de) * | 1986-03-31 | 1987-07-08 | Buna Chem Werke Veb | Verfahren zur herstellung von polymeren mit funktionellen endgruppen |
| DE3611421A1 (de) * | 1986-04-05 | 1987-10-08 | Basf Ag | Polymerisate mit aminogruppen, deren herstellung und verwendung |
| US4736003A (en) * | 1986-04-07 | 1988-04-05 | E. I. Du Pont De Nemours And Company | Enhanced livingness of polymerization using silylated oxyanions |
| US4843120A (en) * | 1986-09-29 | 1989-06-27 | The Goodyear Tire & Rubber Company | Rubber composition |
| DE3639569A1 (de) * | 1986-11-20 | 1988-06-01 | Basf Ag | Am kettenende funktionalisierte polymere und verfahren zu ihrer herstellung |
| US4845165A (en) * | 1987-03-13 | 1989-07-04 | The Goodyear Tire & Rubber Company | Anionic diene polymerization process with branching |
| CA1303264C (en) * | 1987-05-11 | 1992-06-09 | Hiroyoshi Takao | Modified diene polymer rubbers |
| JPH0778151B2 (ja) * | 1987-07-17 | 1995-08-23 | 日本合成ゴム株式会社 | ゴム組成物 |
| JPH0798880B2 (ja) * | 1987-09-11 | 1995-10-25 | 株式会社ブリヂストン | 空気入りタイヤ |
| US4935471A (en) * | 1987-10-15 | 1990-06-19 | The Goodyear Tire & Rubber Company | Capped polydienes |
| CA1322750C (en) * | 1987-12-17 | 1993-10-05 | Mitsui Toatsu Chemicals, Inc. | Preparation process of unsaturated carboxylic acid amide |
| US5149457A (en) * | 1989-06-30 | 1992-09-22 | Cyprus Foote Mineral Company | Stable mixed lithium amide reagent compositions |
| US5066729A (en) * | 1990-04-09 | 1991-11-19 | Bridgestone/Firestone, Inc. | Diene polymers and copolymers terminated by reaction with n-alkyl and n-aryl imines |
| US5153159A (en) * | 1990-04-09 | 1992-10-06 | Bridgestone/Firestone, Inc. | Elastomers and products having reduced hysteresis |
| US5173209A (en) * | 1990-05-10 | 1992-12-22 | Cyprus Foote Mineral Company | Stable lithium cycloalkylimides |
| US5112929A (en) * | 1991-04-05 | 1992-05-12 | Bridgestone Corporation | Oxolanyl cyclic acetals as anionic polymerization modifiers |
| US5292790A (en) * | 1991-07-31 | 1994-03-08 | Bridgestone Corporation | Conjugated diene series rubber compositions |
| US5238893A (en) * | 1991-12-30 | 1993-08-24 | Bridgestone Corporation | Method of preparing an anionic polymerization initiator |
| US5332810A (en) * | 1992-10-02 | 1994-07-26 | Bridgestone Corporation | Solubilized anionic polymerization initiator and preparation thereof |
| US5329005A (en) * | 1992-10-02 | 1994-07-12 | Bridgestone Corporation | Soluble anionic polymerization initiators and preparation thereof |
| US5393721A (en) * | 1992-10-16 | 1995-02-28 | Bridgestone Corporation | Anionic polymerization initiators and reduced hysteresis products therefom |
| US5527753A (en) * | 1994-12-13 | 1996-06-18 | Fmc Corporation | Functionalized amine initiators for anionic polymerization |
-
1995
- 1995-02-01 US US08/382,477 patent/US5496940A/en not_active Expired - Lifetime
-
1996
- 1996-01-29 ES ES96101195T patent/ES2143674T3/es not_active Expired - Lifetime
- 1996-01-29 EP EP96101195A patent/EP0725069B1/de not_active Expired - Lifetime
- 1996-01-29 DE DE69606892T patent/DE69606892T2/de not_active Expired - Fee Related
- 1996-01-30 JP JP03420896A patent/JP4157170B2/ja not_active Expired - Fee Related
- 1996-01-31 CA CA002168499A patent/CA2168499A1/en not_active Abandoned
- 1996-02-23 US US08/606,388 patent/US5792820A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0725069A1 (de) | 1996-08-07 |
| EP0725069B1 (de) | 2000-03-08 |
| US5792820A (en) | 1998-08-11 |
| JP4157170B2 (ja) | 2008-09-24 |
| DE69606892D1 (de) | 2000-04-13 |
| US5496940A (en) | 1996-03-05 |
| CA2168499A1 (en) | 1996-08-02 |
| JPH08245638A (ja) | 1996-09-24 |
| ES2143674T3 (es) | 2000-05-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69606892T2 (de) | Alkyllithiumverbindungen, welche zyklische Amine enthalten und ihre Verwendung in Polymerisationsreaktionen | |
| DE69606893D1 (de) | Aminoalkyllithiumverbindungen, welche zyklische Amine enthalten und damit hergestellte Polymere | |
| DE69003397T2 (de) | Cyclische Aminverbindungen und ihre Verwendung. | |
| ZA958034B (en) | Monomeric and polymeric cyclic amine and n-halamine compounds | |
| DE69919865D1 (de) | Wegwerfpackung zum spenden von flüssigkeiten und verfahren zu deren herstellung | |
| DE69006290T2 (de) | N-Substituierte Benzyloxyiminderivate, Verfahren zu deren Herstellung und deren Verwendung. | |
| NO933248D0 (no) | Cykliske urinstoffderivater, legemidler inneholdende disse forbindelser, og fremgangsm}te for deres fremstilling | |
| PH23981A (en) | Arylalkyl heterocyclic amines,n-substituted by aryloxyalkyl groups used in a method for allergy | |
| DE69417322D1 (de) | Elektronisches Gerät, Batteriepack und Ladegerät für den Batteriepack | |
| DE69830851D1 (de) | Chemischer indikator und dessen verwendung | |
| DE69317768T2 (de) | Vollaromatische flüssigkristalline polymere, die ionische monomereinheiten enthalten und verbundstoffe daraus | |
| DE59801279D1 (de) | Vorrichtung zum Herstellen von Packungen | |
| DE69427270D1 (de) | Pyrimidin Derivate, Verfahren zu deren Herstellung und ihre Verwendung als herbizides Mittel | |
| DE69415159T2 (de) | Succinamid-derivate, verfahren zu ihrer herstellung und ihre verwendung als gelatinase- und collagenase- inhibitoren | |
| DE69600800T2 (de) | Träger und Packung | |
| DE3682071D1 (de) | Saegeverfahren und anordnung zu dessen verwendung. | |
| DE59603287D1 (de) | 1-fluor-5,6,7,8-tetrahydroisochinolin-derivate und ihre verwendung in flüssigkristallinen mischungen | |
| DE59603787D1 (de) | 1-fluor-6,7-dihydro-5h-isochinolin-8-on-derivate und ihre verwendung in flüssigkristallinen mischungen | |
| DE4497133T1 (de) | Batteriepack und Verfahren zum Herstellen davon | |
| DE59401442D1 (de) | Wasser-in-Öl-Polymeremulsionen, Verfahren zu ihrer Herstellung und ihre Verwendung | |
| DE59810046D1 (de) | Vorrichtung zum Handhaben oder Herstellen von Packungen | |
| DE69318181D1 (de) | Papierblock, streifen und verfahren zu deren herstellung | |
| DE59506861D1 (de) | Schwefelorganische Goldverbindungen, Verfahren zu ihrer Herstellung und Verwendung derselben | |
| DE29717551U1 (de) | Beutelgebinde, Beutelgebindesortiment und Produktpalette von Beuteln | |
| DE68923442T2 (de) | N-substituierte Acylaminosäure-Verbindungen, Verfahren zu deren Herstellung und deren Verwendung. |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |