DE69701676D1 - Verbesserte vliesstoffe - Google Patents

Verbesserte vliesstoffe

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Publication number
DE69701676D1
DE69701676D1 DE69701676T DE69701676T DE69701676D1 DE 69701676 D1 DE69701676 D1 DE 69701676D1 DE 69701676 T DE69701676 T DE 69701676T DE 69701676 T DE69701676 T DE 69701676T DE 69701676 D1 DE69701676 D1 DE 69701676D1
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Germany
Prior art keywords
catalyst components
relates
catalyst
designed distribution
supported
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DE69701676T
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English (en)
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DE69701676T2 (de
Inventor
C Richeson
Allen Stahl
J Mcalpin
N Speca
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ExxonMobil Chemical Patents Inc
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Exxon Chemical Patents Inc
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    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/16Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
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    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
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    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
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    • B01J31/22Organic complexes
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    • B01J31/2295Cyclic compounds, e.g. cyclopentadienyls
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    • C08F4/61922Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/61927Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
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    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts
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Families Citing this family (53)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6583227B2 (en) 1996-09-04 2003-06-24 Exxonmobil Chemical Patents Inc. Propylene polymers for films
CN1115360C (zh) * 1996-09-04 2003-07-23 埃克森美孚化学专利公司 改进的用于取向薄膜的丙烯聚合物
US6576306B2 (en) 1996-09-04 2003-06-10 Exxonmobil Chemical Patents Inc. Propylene polymers for films
US5847059A (en) * 1996-12-20 1998-12-08 Fina Technology, Inc. Catalyst yield from supported metallocene catalysts
US6143683A (en) * 1997-04-09 2000-11-07 Fina Technology, Inc. Metallocene catalyst and catalyst system for polymerizing an olefin having at least 3 carbon atoms
JP2002508025A (ja) * 1997-07-08 2002-03-12 ビーピー ケミカルズ リミテッド 支持重合触媒
AU9206998A (en) * 1997-08-29 1999-03-16 Kimberly-Clark Worldwide, Inc. Meltblown nonwoven web and process for making the same
DE19738051A1 (de) * 1997-09-01 1999-03-04 Targor Gmbh Spritzgieß-Artikel aus Metallocen-Polypropylen
DE19805329A1 (de) 1998-02-11 1999-08-12 Basf Ag Spritzstreckgeblasene Behälter aus Olefinpolymerisaten
AU755053B2 (en) * 1998-05-06 2002-12-05 Huntsman Polymers Corporation Polymerizations using adjuvant catalyst
WO1999057164A1 (en) * 1998-05-06 1999-11-11 Huntsman Polymers Corporation Polymerizations using adjuvant catalyst
US7041750B1 (en) * 1999-12-16 2006-05-09 Basell Polyolefine Gmbh Process and apparatus for making supported catalyst systems for olefin polymerization
US7041617B2 (en) * 2004-01-09 2006-05-09 Chevron Phillips Chemical Company, L.P. Catalyst compositions and polyolefins for extrusion coating applications
US6875719B2 (en) * 2000-04-27 2005-04-05 Industrial Technology Research Institute Catalyst composition for preparing olefin polymers
EP1301277A2 (de) 2000-07-17 2003-04-16 Honeywell International Inc. Trägerkatalysatorsysteme
US6734265B1 (en) * 2000-10-06 2004-05-11 Univation Technologies, Llc. Linear low density polyethylenes with high melt strength and high melt index ratio
US6884747B2 (en) * 2000-10-06 2005-04-26 Univation Technologies, Llc Linear low density polyethylenes with high melt strength and high melt index ratio
KR100447931B1 (ko) * 2001-10-24 2004-09-08 한국화학연구원 초발수성 유/무기 복합막
US8058371B2 (en) 2002-09-20 2011-11-15 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization
US8008412B2 (en) 2002-09-20 2011-08-30 Exxonmobil Chemical Patents Inc. Polymer production at supersolution conditions
KR100579843B1 (ko) * 2003-04-01 2006-05-12 주식회사 엘지화학 혼성 담지 메탈로센 촉매 및 그의 제조방법과 이를 이용한폴리올레핀의 제조방법
GB0329348D0 (en) * 2003-12-18 2004-01-21 Bp Chem Int Ltd Polymerisation process
US7119153B2 (en) * 2004-01-21 2006-10-10 Jensen Michael D Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength
US20050187418A1 (en) * 2004-02-19 2005-08-25 Small Brooke L. Olefin oligomerization
US20070043181A1 (en) * 2005-08-19 2007-02-22 Knudsen Ronald D Methods of preparation of an olefin oligomerization catalyst
US7384886B2 (en) * 2004-02-20 2008-06-10 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
US9550841B2 (en) 2004-02-20 2017-01-24 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
US20050187098A1 (en) * 2004-02-20 2005-08-25 Knudsen Ronald D. Methods of preparation of an olefin oligomerization catalyst
DE102004020525A1 (de) * 2004-04-26 2005-11-10 Basell Polyolefine Gmbh Katalysatorsystem zur Olefinpolymerisation, dessen Herstellung und Verwendung
WO2006065844A2 (en) 2004-12-16 2006-06-22 Exxonmobil Chemical Patents Inc. Process for producing substituted metallocene compounds for olefin polymerization
US7763562B2 (en) 2005-12-14 2010-07-27 Exxonmobil Chemical Patents Inc. Heteroatom bridged metallocene compounds for olefin polymerization
US7538168B2 (en) 2005-12-14 2009-05-26 Exxonmobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
US7550544B2 (en) 2005-12-14 2009-06-23 Exxonmobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
US7868197B2 (en) 2005-12-14 2011-01-11 Exxonmobil Chemical Patents Inc. Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization
US7667064B2 (en) 2005-12-14 2010-02-23 Exxonmobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
US8242237B2 (en) 2006-12-20 2012-08-14 Exxonmobil Chemical Patents Inc. Phase separator and monomer recycle for supercritical polymerization process
EP2215129A2 (de) * 2007-08-27 2010-08-11 Borealis Technology OY Katalysatoren
EP2058337A1 (de) * 2007-11-06 2009-05-13 Total Petrochemicals Research Feluy Verfahren zur Herstellung von Polyethylen in einem Doppelschleifenreaktor mit einer Mischung von Bis-indenyl und Bis-tetraindenyl Katalysatorkomponenten
US7902415B2 (en) * 2007-12-21 2011-03-08 Chevron Phillips Chemical Company Lp Processes for dimerizing or isomerizing olefins
US8318875B2 (en) 2008-01-18 2012-11-27 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization and polypropylenes made therefrom
US7812104B2 (en) 2008-01-18 2010-10-12 Exxonmobil Chemical Patents Inc. Production of propylene-based polymers
KR100996336B1 (ko) 2008-08-26 2010-11-24 삼성토탈 주식회사 폴리올레핀 중합용 촉매의 제조방법
WO2010024268A1 (ja) 2008-09-01 2010-03-04 三井化学株式会社 長繊維不織布
EP2663400A4 (de) 2011-01-14 2014-07-30 Grace W R & Co Verfahren zur herstellung eines modifizierten metallocenkatalysators, in diesem verfahren hergestellter katalysator und verwendung davon
KR101339550B1 (ko) * 2011-11-24 2013-12-10 삼성토탈 주식회사 올레핀 중합 및 공중합용 촉매 및 이를 사용하는 올레핀 중합 또는 공중합 방법
US9586872B2 (en) 2011-12-30 2017-03-07 Chevron Phillips Chemical Company Lp Olefin oligomerization methods
KR101827523B1 (ko) * 2012-03-06 2018-03-22 에스케이이노베이션 주식회사 혼성 담지 메탈로센 촉매, 이의 제조방법 및 이를 이용한 폴리올레핀의 제조방법
KR101639356B1 (ko) * 2014-09-18 2016-07-14 엔브이에이치코리아(주) 자동차용 흡차음재
KR101761394B1 (ko) * 2014-09-30 2017-07-25 주식회사 엘지화학 섬유 제조용 폴리올레핀 중합체의 제조방법
KR101790672B1 (ko) 2015-08-24 2017-10-26 주식회사 엘지화학 전이 금속 화합물, 이를 포함하는 촉매 조성물 및 이를 이용한 올레핀 중합체의 제조 방법
KR101791231B1 (ko) 2015-12-23 2017-10-27 주식회사 엘지화학 장섬유 강화용 올레핀 중합체의 제조 방법 및 장섬유
KR102317015B1 (ko) 2017-11-08 2021-10-26 주식회사 엘지화학 부직포용 호모 폴리프로필렌 수지 및 그의 제조 방법
CN114008084B (zh) * 2019-11-01 2024-04-12 株式会社Lg化学 生产茂金属负载型催化剂的方法和茂金属负载型催化剂

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE177759T1 (de) * 1986-09-24 1999-04-15 Mitsui Chemicals Inc Verfahren zur olefinpolymerisation
IL85097A (en) * 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
JPH0742301B2 (ja) * 1987-02-14 1995-05-10 三井石油化学工業株式会社 微粒子状アルミノオキサン、その製法およびその用途
US5064797A (en) * 1987-04-03 1991-11-12 Phillips Petroleum Company Process for producing polyolefins and polyolefin catalysts
US4975403A (en) * 1987-09-11 1990-12-04 Fina Technology, Inc. Catalyst systems for producing polyolefins having a broad molecular weight distribution
ES2064322T3 (es) * 1987-09-11 1995-02-01 Fina Technology Sistemas de catalisis para la produccion de poliolefinas cubriendo una gama amplia de pesos moleculares.
US5763549A (en) * 1989-10-10 1998-06-09 Fina Technology, Inc. Cationic metallocene catalysts based on organoaluminum anions
DE69018376T3 (de) * 1989-10-30 2002-05-16 Fina Technology Herstellung von Metallocenkatalysatoren für Olefinpolymerisation.
AU643255B2 (en) * 1990-01-02 1993-11-11 Exxon Chemical Patents Inc. Supported ionic metallocene catalysts for olefin polymerization
KR0123370B1 (ko) * 1990-06-22 1997-11-12 벤 씨, 카덴헤드 올레핀 중합을 위한 알루미늄-비함유 모노사이클로 펜타디에닐 메탈로센 촉매
EP0841349B1 (de) * 1990-07-24 2002-06-12 Mitsui Chemicals, Inc. Katalysator für die alpha-Olefinpolymerisation und Herstellung von Poly-alpha-olefinen
US5189192A (en) * 1991-01-16 1993-02-23 The Dow Chemical Company Process for preparing addition polymerization catalysts via metal center oxidation
CA2068939C (en) * 1991-05-20 1996-04-09 Takashi Ueda Olefin polymerization catalyst and olefin polymerization
ATE132168T1 (de) * 1991-05-27 1996-01-15 Hoechst Ag Verfahren zur herstellung von syndiotaktischen polyolefinen mit breiter molmassenverteilung
DE69219206T2 (de) * 1991-05-31 1997-08-28 Mitsui Petrochemical Ind Fester Katalysatorbestandteil, Katalysator und Verfahren für Olefinpolymerisation
US5721185A (en) * 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
TW300901B (de) * 1991-08-26 1997-03-21 Hoechst Ag
ES2093166T3 (es) * 1991-11-30 1996-12-16 Hoechst Ag Metalocenos con derivados de indenilo condensados con benzo como ligandos, procedimiento para su preparacion y su utilizacion como catalizadores.
US5182244A (en) * 1991-12-19 1993-01-26 Phillips Petroleum Company Transition metal/rare earth catalyst and olefin polymerization process
US5329032A (en) * 1992-03-18 1994-07-12 Akzo Chemicals Inc. Polymethylaluminoxane of enhanced solution stability
US5434115A (en) * 1992-05-22 1995-07-18 Tosoh Corporation Process for producing olefin polymer
TW294669B (de) * 1992-06-27 1997-01-01 Hoechst Ag
CA2141814A1 (en) * 1992-08-05 1994-02-17 David Jonathan Upton Supported ionic transition metal catalysts for olefin polymerization
US5939346A (en) * 1992-11-02 1999-08-17 Akzo Nobel N.V. Catalyst system comprising an aryloxyaluminoxane containing an electron withdrawing group
US5332706A (en) * 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
AU7521794A (en) * 1993-08-06 1995-02-28 Exxon Chemical Patents Inc. Polymerization catalysts, their production and use
DE4330667A1 (de) * 1993-09-10 1995-03-16 Basf Ag Verfahren zur Herstellung von mehrphasigen Homo- oder Copolymerisaten von C¶2¶-C¶1¶¶0¶-Alk-1-enen in einer Reaktionszone
DE4333128A1 (de) * 1993-09-29 1995-03-30 Hoechst Ag Verfahren zur Herstellung von Polyolefinen
FI96866C (fi) * 1993-11-05 1996-09-10 Borealis As Tuettu olefiinipolymerointikatalyytti, sen valmistus ja käyttö
CN1112370C (zh) * 1994-06-24 2003-06-25 埃克森美孚化学专利公司 聚合催化剂体系、它们的制备和用途

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CA2245645C (en) 2005-08-23
CN1211994A (zh) 1999-03-24
CN1211998A (zh) 1999-03-24
ES2144849T3 (es) 2000-06-16
EP0882073A1 (de) 1998-12-09
CA2241942C (en) 2005-04-26
EP0882078B1 (de) 2000-04-12
CN1246340C (zh) 2006-03-22
KR100479961B1 (ko) 2005-05-16
ES2146088T3 (es) 2000-07-16
KR19990087169A (ko) 1999-12-15
EP0882078A1 (de) 1998-12-09
DE69701627D1 (de) 2000-05-11
WO1997031035A1 (en) 1997-08-28
ATE191488T1 (de) 2000-04-15
AU710785B2 (en) 1999-09-30
EP0882073B1 (de) 2000-04-05
WO1997031040A1 (en) 1997-08-28
DE69701627T2 (de) 2000-10-26
CA2245645A1 (en) 1997-08-28
KR19990087170A (ko) 1999-12-15
JP4234199B2 (ja) 2009-03-04
CA2241942A1 (en) 1997-08-28
JP2001500574A (ja) 2001-01-16
JP2001508472A (ja) 2001-06-26
DE69701676T2 (de) 2000-08-10
AU2054897A (en) 1997-09-10

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