DE69717819T2 - Homogen oxidierungskatalysator von grosser lebensdauer - Google Patents

Homogen oxidierungskatalysator von grosser lebensdauer

Info

Publication number
DE69717819T2
DE69717819T2 DE69717819T DE69717819T DE69717819T2 DE 69717819 T2 DE69717819 T2 DE 69717819T2 DE 69717819 T DE69717819 T DE 69717819T DE 69717819 T DE69717819 T DE 69717819T DE 69717819 T2 DE69717819 T2 DE 69717819T2
Authority
DE
Germany
Prior art keywords
oxidation catalyst
long life
homogeneous oxidation
homogeneous
life
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69717819T
Other languages
English (en)
Other versions
DE69717819D1 (de
Inventor
J Collins
W Gordon-Wylie
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Carnegie Mellon University
Original Assignee
Carnegie Mellon University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Carnegie Mellon University filed Critical Carnegie Mellon University
Publication of DE69717819D1 publication Critical patent/DE69717819D1/de
Application granted granted Critical
Publication of DE69717819T2 publication Critical patent/DE69717819T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
    • C07F15/002—Osmium compounds
    • C07F15/0026—Osmium compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B01J31/182—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine comprising aliphatic or saturated rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D257/00—Heterocyclic compounds containing rings having four nitrogen atoms as the only ring hetero atoms
    • C07D257/02—Heterocyclic compounds containing rings having four nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D257/00—Heterocyclic compounds containing rings having four nitrogen atoms as the only ring hetero atoms
    • C07D257/10—Heterocyclic compounds containing rings having four nitrogen atoms as the only ring hetero atoms condensed with carbocyclic rings or ring systems
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/16—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/17—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/18—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/64—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/66—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/74—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/825—Osmium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/828—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts
DE69717819T 1996-07-22 1997-07-21 Homogen oxidierungskatalysator von grosser lebensdauer Expired - Lifetime DE69717819T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/681,237 US5847120A (en) 1996-07-22 1996-07-22 Long-lived homogenous oxidation catalysts
PCT/US1997/012803 WO1998003263A1 (en) 1996-07-22 1997-07-21 Long-lived homogenous oxidation catalysts

Publications (2)

Publication Number Publication Date
DE69717819D1 DE69717819D1 (de) 2003-01-23
DE69717819T2 true DE69717819T2 (de) 2003-07-10

Family

ID=24734398

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69717819T Expired - Lifetime DE69717819T2 (de) 1996-07-22 1997-07-21 Homogen oxidierungskatalysator von grosser lebensdauer

Country Status (21)

Country Link
US (2) US5847120A (de)
EP (1) EP0914206B1 (de)
JP (2) JP2000515152A (de)
KR (1) KR100491450B1 (de)
CN (1) CN1121906C (de)
AP (1) AP919A (de)
AT (1) ATE229372T1 (de)
AU (1) AU729102B2 (de)
BR (1) BR9710513B1 (de)
CA (1) CA2261589C (de)
DE (1) DE69717819T2 (de)
DK (1) DK0914206T3 (de)
ES (1) ES2188969T3 (de)
HK (1) HK1020176A1 (de)
IL (1) IL128150A0 (de)
NO (1) NO326043B1 (de)
NZ (1) NZ333797A (de)
OA (1) OA10960A (de)
PL (1) PL187534B1 (de)
PT (1) PT914206E (de)
WO (1) WO1998003263A1 (de)

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US5876625A (en) * 1996-07-22 1999-03-02 Carnegie Mellon University Metal ligand containing bleaching compositions
US5847120A (en) * 1996-07-22 1998-12-08 Carnegie Mellon University Long-lived homogenous oxidation catalysts
AP9901723A0 (en) * 1997-06-20 1999-12-31 Univ Carnegie Mellon Homogeneous oxidation catalysis using metal complexes.
WO1999052631A1 (en) * 1998-04-15 1999-10-21 Shell Internationale Research Maatschappij B.V. CATALYST SYSTEM FOR α-OLEFIN OLIGOMERIZATION
US6861262B2 (en) * 2000-03-03 2005-03-01 Quest Diagnostics Investments Incorporated Composition and method for detecting an adulterant in an aqueous sample
GB0020846D0 (en) * 2000-08-23 2000-10-11 Unilever Plc Ligands for bleaching compositions and synthesis thereof
US6797196B2 (en) 2001-01-10 2004-09-28 Kao Corporation Bleaching formulation
BR0211875A (pt) * 2001-08-02 2004-09-21 Unilever Nv Composições compreendendo complexo de metal de tetraamido macrocìclico como catalisador de alvejamento
GB0118936D0 (en) * 2001-08-02 2001-09-26 Unilever Plc Improvements relating to colour-safe fabric treatment compositions
GB0205278D0 (en) * 2002-03-06 2002-04-17 Unilever Plc Composition comprising macrocyclic tetra-amido N-donor metal-ligand complex as bleaching catalyst
GB0205276D0 (en) * 2002-03-06 2002-04-17 Unilever Plc Bleaching composition
DE10227774A1 (de) * 2002-06-21 2004-01-08 Degussa Ag Verwendung von Übergangsmetallkomplexen mit stickstoffhaltigen mehrzähnigen Liganden als Bleichkatalysator und Bleichmittelzusammensetzung
US7060818B2 (en) * 2003-02-21 2006-06-13 Carnegie Mellon University Synthesis of macrocyclic tetraamido compounds and new metal insertion process
AU2006218395A1 (en) * 2005-03-03 2006-09-08 South Dakota Soybean Processors, Llc Novel polyols derived from a vegetable oil using an oxidation process
CN100412080C (zh) * 2005-04-06 2008-08-20 友达光电股份有限公司 有机金属络合物及包括它的有机发光二极管和显示器
CA2612643A1 (en) * 2005-06-21 2006-12-21 Crosslink Polymer Research Signal activated decontaminating coating
CA2632183A1 (en) 2005-08-25 2007-03-01 Philip R. Houle Treatment systems for delivery of sensitizer solutions
US8715489B2 (en) 2005-09-08 2014-05-06 Saudi Arabian Oil Company Process for oxidative conversion of organosulfur compounds in liquid hydrocarbon mixtures
US7744749B2 (en) * 2005-09-08 2010-06-29 Saudi Arabian Oil Company Diesel oil desulfurization by oxidation and extraction
US7959773B2 (en) * 2008-05-23 2011-06-14 Lumimove, Inc. Electroactivated film with electrocatalyst-enhanced carbon electrode
US8722881B2 (en) * 2009-10-13 2014-05-13 Board Of Trustees Of The University Of Arkansas Method of synthesis of tetradentate amide macrocycle ligand and its metal-complex
US20150342839A1 (en) 2010-04-21 2015-12-03 Oraceutica LLC Compositions and methods for whitening teeth
US8584757B2 (en) 2010-04-21 2013-11-19 Halliburton Energy Services, Inc. Method and composition for treating fluids before injection into subterranean zones
EP2561447A2 (de) 2010-04-21 2013-02-27 Discus Dental, LLC Verfahren zur gleichzeitigen reinigung und aufhellung der zähne
US8888489B2 (en) 2012-10-23 2014-11-18 Oraceutical Llc Method of simultaneously cleaning and whitening teeth
US9320580B2 (en) 2013-04-21 2016-04-26 Oraceutical Llc Hand-held tooth whitening instrument with applicator reservoir for whitening composition and methods of using same
EP3172569A1 (de) * 2014-07-25 2017-05-31 Selux Diagnostics Inc. Testverfahren einschliesslich dissoziierbaren nanopartikeln
US20180118590A1 (en) * 2015-04-24 2018-05-03 Auckland Uniservices Limited Oxidation method
AR104939A1 (es) 2015-06-10 2017-08-23 Chemsenti Ltd Método oxidativo para generar dióxido de cloro
AR104940A1 (es) 2015-06-10 2017-08-23 Chemsenti Ltd Método para generar dióxido de cloro
WO2017015145A2 (en) 2015-07-17 2017-01-26 SeLux Diagnostics, Inc. Dissociable transition-metal nanoparticles
WO2017053564A1 (en) 2015-09-25 2017-03-30 Carnegie Mellon University Far superior oxidation catalysts based on macrocyclic compounds
WO2017100442A1 (en) 2015-12-08 2017-06-15 SeLux Diagnostics, Inc. Nanoparticle amplifiers and uses thereof
ES2862345T3 (es) 2016-01-21 2021-10-07 Selux Diagnostics Inc Métodos rápidos para probar la susceptibilidad antimicrobiana
RU2653989C2 (ru) * 2016-04-26 2018-05-16 Федеральное Государственное Бюджетное Научное Учреждение Уфимский Федеральный Исследовательский Центр Российской Академии Наук (Уфиц Ран) Катализатор для получения 3-(3-фенилпроп-2-ин-1-ил)-1,3-оксазолидина
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US5847120A (en) * 1996-07-22 1998-12-08 Carnegie Mellon University Long-lived homogenous oxidation catalysts

Also Published As

Publication number Publication date
OA10960A (en) 2001-10-29
NO326043B1 (no) 2008-09-08
PL187534B1 (pl) 2004-07-30
KR20000067993A (ko) 2000-11-25
AP9901455A0 (en) 1999-03-31
NO990268L (no) 1999-03-22
JP2007016036A (ja) 2007-01-25
DK0914206T3 (da) 2003-04-07
EP0914206A1 (de) 1999-05-12
HK1020176A1 (en) 2000-03-31
IL128150A0 (en) 1999-11-30
PL331315A1 (en) 1999-07-05
PT914206E (pt) 2003-04-30
CA2261589A1 (en) 1998-01-29
DE69717819D1 (de) 2003-01-23
US6100394A (en) 2000-08-08
WO1998003263A1 (en) 1998-01-29
ATE229372T1 (de) 2002-12-15
AU729102B2 (en) 2001-01-25
US5847120A (en) 1998-12-08
EP0914206B1 (de) 2002-12-11
BR9710513A (pt) 2002-03-05
CN1121906C (zh) 2003-09-24
ES2188969T3 (es) 2003-07-01
BR9710513B1 (pt) 2010-10-19
CA2261589C (en) 2002-10-01
AP919A (en) 2000-12-29
KR100491450B1 (ko) 2005-05-25
AU4043697A (en) 1998-02-10
CN1230903A (zh) 1999-10-06
NO990268D0 (no) 1999-01-21
NZ333797A (en) 2000-06-23
JP2000515152A (ja) 2000-11-14

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