DE69820251D1 - Verfahren zur herstellung von isotaktischen polypropylenen in kondensierter phase mit titanocenen - Google Patents
Verfahren zur herstellung von isotaktischen polypropylenen in kondensierter phase mit titanocenenInfo
- Publication number
- DE69820251D1 DE69820251D1 DE69820251T DE69820251T DE69820251D1 DE 69820251 D1 DE69820251 D1 DE 69820251D1 DE 69820251 T DE69820251 T DE 69820251T DE 69820251 T DE69820251 T DE 69820251T DE 69820251 D1 DE69820251 D1 DE 69820251D1
- Authority
- DE
- Germany
- Prior art keywords
- titanocenes
- isotactic polypropylene
- condensed phase
- producing isotactic
- producing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US850594 | 1986-04-11 | ||
US08/850,594 US6160072A (en) | 1997-05-02 | 1997-05-02 | Process for polymerizing tactioselective polyolefins in condensed phase using titanocenes |
PCT/EP1998/002534 WO1998050440A1 (en) | 1997-05-02 | 1998-04-29 | Process for producing tactioselective polyolefins in condensed phase using titanocenes |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69820251D1 true DE69820251D1 (de) | 2004-01-15 |
DE69820251T2 DE69820251T2 (de) | 2004-09-09 |
Family
ID=25308588
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69820251T Expired - Fee Related DE69820251T2 (de) | 1997-05-02 | 1998-04-29 | Verfahren zur herstellung von isotaktischen polypropylenen in kondensierter phase mit titanocenen |
Country Status (6)
Country | Link |
---|---|
US (1) | US6160072A (de) |
EP (1) | EP0979247B1 (de) |
JP (1) | JP2001525863A (de) |
DE (1) | DE69820251T2 (de) |
ES (1) | ES2210762T3 (de) |
WO (1) | WO1998050440A1 (de) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1332966C (zh) * | 2000-06-30 | 2007-08-22 | 埃克森美孚化学专利公司 | 桥接双(茚基)金属茂化合物 |
JP2002145932A (ja) * | 2000-11-13 | 2002-05-22 | Basell Technology Co Bv | 低アイソタクティックかつ比較的高融点のポリプロピレン |
US8058371B2 (en) | 2002-09-20 | 2011-11-15 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization |
US8008412B2 (en) | 2002-09-20 | 2011-08-30 | Exxonmobil Chemical Patents Inc. | Polymer production at supersolution conditions |
CN1326888C (zh) * | 2002-09-20 | 2007-07-18 | 埃克森美孚化学专利公司 | 在超临界条件生产聚合物的方法 |
EP1765841B1 (de) * | 2004-07-08 | 2008-10-08 | Exxonmobil Chemical Patents Inc. | Katalysator system für die olefinpolymerisation und verfahren zu seiner verwendung |
US8143352B2 (en) * | 2006-12-20 | 2012-03-27 | Exxonmobil Research And Engineering Company | Process for fluid phase in-line blending of polymers |
US8242237B2 (en) | 2006-12-20 | 2012-08-14 | Exxonmobil Chemical Patents Inc. | Phase separator and monomer recycle for supercritical polymerization process |
US8080610B2 (en) | 2007-03-06 | 2011-12-20 | Exxonmobil Research And Engineering Company | Monomer recycle process for fluid phase in-line blending of polymers |
WO2009020720A1 (en) * | 2007-08-06 | 2009-02-12 | Advance Elastomer Systems, L.P. | Peroxide-cured thermoplastic vulcanizates prepared with ultrahigh molecular weight plastics |
CN101855249B (zh) * | 2007-09-13 | 2013-02-13 | 埃克森美孚研究工程公司 | 在线生产增塑聚合物和增塑聚合物共混物的方法 |
EP2201042B1 (de) * | 2007-09-13 | 2012-06-27 | ExxonMobil Research and Engineering Company | In-line-mischen von weichmachern mit einem basispolymer |
US7994237B2 (en) * | 2007-12-20 | 2011-08-09 | Exxonmobil Research And Engineering Company | In-line process to produce pellet-stable polyolefins |
CN103254513B (zh) * | 2007-12-20 | 2015-08-26 | 埃克森美孚研究工程公司 | 全同立构聚丙烯和乙烯-丙烯共聚物的共混物 |
US7910679B2 (en) | 2007-12-20 | 2011-03-22 | Exxonmobil Research And Engineering Company | Bulk homogeneous polymerization process for ethylene propylene copolymers |
US8318875B2 (en) | 2008-01-18 | 2012-11-27 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization and polypropylenes made therefrom |
JP5315773B2 (ja) * | 2008-04-24 | 2013-10-16 | 住友化学株式会社 | プロピレン系樹脂組成物 |
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SU801482A1 (ru) * | 1979-05-24 | 1981-10-07 | Ордена Ленина Институт Геохимии И Аналитической Химии Им. В.И.Вернадского | Способ получени летучих бета-дикетонатов металлов |
JPS5950246B2 (ja) * | 1979-10-16 | 1984-12-07 | 三井化学株式会社 | 成形用オレフイン共重合体の製法 |
FR2488259B1 (fr) * | 1980-08-08 | 1986-08-08 | Centre Nat Rech Scient | Nouveaux complexes allyliques du nickel, procedes pour les preparer et utilisation de ces complexes comme catalyseurs d'oligomerisation ou de polymerisation |
JPS5754126A (en) * | 1980-09-19 | 1982-03-31 | Hokko Chem Ind Co Ltd | Novel preparation of olefin compound |
US4530914A (en) * | 1983-06-06 | 1985-07-23 | Exxon Research & Engineering Co. | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
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US5122583A (en) * | 1987-02-02 | 1992-06-16 | Fina Technology, Inc. | Efficiency of a pre-polymerized catalyst |
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JP2538588B2 (ja) * | 1987-04-03 | 1996-09-25 | 三井石油化学工業株式会社 | オレフイン重合用固体触媒の製法 |
JPS63270313A (ja) * | 1987-04-30 | 1988-11-08 | Mitsubishi Metal Corp | 希土類金属酸化物の膜と粉末を形成するための組成物 |
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US5225500A (en) * | 1988-07-15 | 1993-07-06 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
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DE59107926D1 (de) * | 1990-11-12 | 1996-07-18 | Hoechst Ag | Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren |
DE4039451A1 (de) * | 1990-12-11 | 1992-06-17 | Hoechst Ag | Metallocene mit bicyclischen cyclopentadienderivaten als liganden, verfahren zu ihrer herstellung und ihre verwendung als katalysatoren |
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US5391789A (en) * | 1991-08-08 | 1995-02-21 | Hoechst Aktiengesellschaft | Bridged, chiral metallocenes, processes for their preparation and their use as catalysts |
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US5710222A (en) * | 1992-06-22 | 1998-01-20 | Fina Technology, Inc. | Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems |
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WO1995033776A1 (en) * | 1994-06-07 | 1995-12-14 | Specs And Biospecs B.V. | Novel organo-metallic compounds, methods for preparing same, and a method for the polymerization of unsaturated hydrocarbons using said organo-metallic compounds as catalysts, as well as novel semi-products and catalyst preparations |
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-
1997
- 1997-05-02 US US08/850,594 patent/US6160072A/en not_active Expired - Fee Related
-
1998
- 1998-04-29 EP EP98924243A patent/EP0979247B1/de not_active Expired - Lifetime
- 1998-04-29 ES ES98924243T patent/ES2210762T3/es not_active Expired - Lifetime
- 1998-04-29 DE DE69820251T patent/DE69820251T2/de not_active Expired - Fee Related
- 1998-04-29 JP JP54770298A patent/JP2001525863A/ja not_active Withdrawn
- 1998-04-29 WO PCT/EP1998/002534 patent/WO1998050440A1/en active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
JP2001525863A (ja) | 2001-12-11 |
EP0979247B1 (de) | 2003-12-03 |
WO1998050440A1 (en) | 1998-11-12 |
ES2210762T3 (es) | 2004-07-01 |
US6160072A (en) | 2000-12-12 |
DE69820251T2 (de) | 2004-09-09 |
EP0979247A1 (de) | 2000-02-16 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition | ||
8339 | Ceased/non-payment of the annual fee |