DE69821528D1 - Katalysatorzusammensetzungen mit gesteigertem leistungsvermögen - Google Patents
Katalysatorzusammensetzungen mit gesteigertem leistungsvermögenInfo
- Publication number
- DE69821528D1 DE69821528D1 DE69821528T DE69821528T DE69821528D1 DE 69821528 D1 DE69821528 D1 DE 69821528D1 DE 69821528 T DE69821528 T DE 69821528T DE 69821528 T DE69821528 T DE 69821528T DE 69821528 D1 DE69821528 D1 DE 69821528D1
- Authority
- DE
- Germany
- Prior art keywords
- catalyst compositions
- increased performance
- performance
- increased
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US986824 | 1992-12-08 | ||
US98682497A | 1997-12-08 | 1997-12-08 | |
PCT/US1998/023517 WO1999029738A1 (en) | 1997-12-08 | 1998-11-03 | Catalyst compositions of enhanced productivity |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69821528D1 true DE69821528D1 (de) | 2004-03-11 |
DE69821528T2 DE69821528T2 (de) | 2004-07-01 |
Family
ID=25532784
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69821528T Expired - Fee Related DE69821528T2 (de) | 1997-12-08 | 1998-11-03 | Katalysatorzusammensetzungen mit gesteigertem leistungsvermögen |
Country Status (7)
Country | Link |
---|---|
US (3) | US6521728B1 (de) |
EP (1) | EP1037931B1 (de) |
JP (1) | JP2001525458A (de) |
CA (1) | CA2313244A1 (de) |
DE (1) | DE69821528T2 (de) |
ES (1) | ES2214750T3 (de) |
WO (1) | WO1999029738A1 (de) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6551955B1 (en) * | 1997-12-08 | 2003-04-22 | Albemarle Corporation | Particulate group 4 metallocene-aluminoxane catalyst compositions devoid of preformed support, and their preparation and their use |
US6677265B1 (en) * | 1997-12-08 | 2004-01-13 | Albemarle Corporation | Process of producing self-supported catalysts |
WO2001098381A2 (en) * | 2000-06-16 | 2001-12-27 | Albemarle Corporation | Polymerization process using self-supported catalysts |
IT1320128B1 (it) * | 2000-12-21 | 2003-11-18 | Enichem Spa | Complessi allilmetallocenici e loro uso nella catalisi dei processi di(co)polimerizzazione delle alfa-olefine. |
US6534609B2 (en) | 2001-03-13 | 2003-03-18 | Chevron Phillips Chemical Company Lp | Method for making and using a metallocene catalyst system |
GB0118010D0 (en) | 2001-07-24 | 2001-09-19 | Borealis Tech Oy | Catalysts |
EP1323747A1 (de) * | 2001-12-19 | 2003-07-02 | Borealis Technology Oy | Herstellung von Katalysatoren für die Olefinpolymerisation |
US6992034B2 (en) * | 2003-07-10 | 2006-01-31 | Formosa Plastics Corporation, U.S.A. | Catalyst component for olefin polymerization |
US7244795B2 (en) * | 2003-12-08 | 2007-07-17 | Univation Technologies, Llc | Polymerization process using metallocene catalyst systems |
ES2366651T3 (es) * | 2004-12-31 | 2011-10-24 | Borealis Technology Oy | Procedimiento para preparar un catalizador sólido para la polimerización de olefinas. |
EP1832338A1 (de) * | 2006-03-07 | 2007-09-12 | Total Petrochemicals Research Feluy | Verfahren und Vorrichtung zur Bestimmung der Aktivität eines Katalysators |
EP1847551A1 (de) * | 2006-04-18 | 2007-10-24 | Borealis Technology Oy | Verfahren zur Herstellung von Polypropylen |
EP1847555A1 (de) * | 2006-04-18 | 2007-10-24 | Borealis Technology Oy | Mehrfach verzweigtes Polypropylen |
EP1847552A1 (de) * | 2006-04-18 | 2007-10-24 | Borealis Technology Oy | Katalysatorsystem |
BR112014016325A8 (pt) | 2011-12-28 | 2017-07-04 | Ineos Europe Ag | processo de polimerização |
CN111132988B (zh) | 2017-09-28 | 2023-06-20 | 尤尼威蒂恩技术有限责任公司 | 环状有机化合物和茂金属的合成 |
KR102343937B1 (ko) | 2017-12-26 | 2021-12-27 | 주식회사 엘지화학 | 메탈로센 담지 촉매 및 이를 이용한 폴리프로필렌의 제조 방법 |
Family Cites Families (50)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3127133A1 (de) * | 1981-07-09 | 1983-01-27 | Hoechst Ag, 6000 Frankfurt | Verfahren zur herstellung von polyolefinen und deren copolymerisaten |
US4701432A (en) | 1985-11-15 | 1987-10-20 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
US5124418A (en) | 1985-11-15 | 1992-06-23 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
US4752597A (en) | 1985-12-12 | 1988-06-21 | Exxon Chemical Patents Inc. | New polymerization catalyst |
US4791180A (en) | 1985-12-12 | 1988-12-13 | Exxon Chemical Patents Inc. | New polymerization catalyst |
JP2618384B2 (ja) | 1986-12-27 | 1997-06-11 | 三井石油化学工業株式会社 | オレフイン重合用固体触媒およびその製法 |
US5198401A (en) | 1987-01-30 | 1993-03-30 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
US5153157A (en) | 1987-01-30 | 1992-10-06 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
US4767735A (en) | 1987-02-02 | 1988-08-30 | Cosden Technology, Inc. | Catalyst pretreatment process |
US4939217A (en) | 1987-04-03 | 1990-07-03 | Phillips Petroleum Company | Process for producing polyolefins and polyolefin catalysts |
JP2538595B2 (ja) | 1987-05-13 | 1996-09-25 | 三井石油化学工業株式会社 | オレフイン重合用固体触媒 |
US4975403A (en) | 1987-09-11 | 1990-12-04 | Fina Technology, Inc. | Catalyst systems for producing polyolefins having a broad molecular weight distribution |
US4978730A (en) | 1987-12-24 | 1990-12-18 | Idemitsu Kosan Company Limited | Process for producing styrene-based polymers and catalyst for use therein |
US5017714A (en) | 1988-03-21 | 1991-05-21 | Exxon Chemical Patents Inc. | Silicon-bridged transition metal compounds |
US5120867A (en) | 1988-03-21 | 1992-06-09 | Welborn Jr Howard C | Silicon-bridged transition metal compounds |
US5229478A (en) | 1988-06-16 | 1993-07-20 | Exxon Chemical Patents Inc. | Process for production of high molecular weight EPDM elastomers using a metallocene-alumoxane catalyst system |
US5001205A (en) | 1988-06-16 | 1991-03-19 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst |
US4871705A (en) | 1988-06-16 | 1989-10-03 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst |
US4892851A (en) | 1988-07-15 | 1990-01-09 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
DE3840772A1 (de) | 1988-12-03 | 1990-06-07 | Hoechst Ag | Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente |
US5227440A (en) | 1989-09-13 | 1993-07-13 | Exxon Chemical Patents Inc. | Mono-Cp heteroatom containing Group IVB transition metal complexes with MAO: supported catalysts for olefin polymerization |
KR100186779B1 (ko) | 1989-10-30 | 1999-05-15 | 제이. 씨. 디트 레이트 | 메탈로센 촉매반응을 이용하여 조절된 형태학적 특성을 갖는 폴리올레핀 플러프를 제조하는 방법 |
FR2656314B1 (fr) | 1989-12-22 | 1992-04-17 | Bp Chemicals Snc | Catalyseur a base de zirconium supporte sur du chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines. |
EP0485821B1 (de) | 1990-11-12 | 1996-06-12 | Hoechst Aktiengesellschaft | Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren |
DE59104869D1 (de) | 1990-11-12 | 1995-04-13 | Hoechst Ag | 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation. |
US5169818A (en) | 1991-01-12 | 1992-12-08 | Hoechst Aktiengesellschaft | Metallocene (co)polymers, process for their preparation and their use as catalysts |
US5466766A (en) | 1991-05-09 | 1995-11-14 | Phillips Petroleum Company | Metallocenes and processes therefor and therewith |
EP0516458B2 (de) | 1991-05-31 | 2007-12-19 | Mitsui Chemicals, Inc. | Fester Katalysatorbestandteil, Katalysator und Verfahren für Olefinpolymerisation |
DE69210480T2 (de) | 1991-06-27 | 1996-11-28 | Nippon Oil Co Ltd | Katalysatorbestandteil für die Olefinpolymerisation |
US5308815A (en) | 1991-07-26 | 1994-05-03 | Ethyl Corporation | Heterogeneous methylaluminoxane catalyst system |
US5308817A (en) | 1992-05-18 | 1994-05-03 | Fina Technology, Inc. | Metallocene catalyst component with good catalyst efficiency after aging |
US5240894A (en) | 1992-05-18 | 1993-08-31 | Exxon Chemical Patents Inc. | Method for making and using a supported metallocene catalyst system |
EP0586168B1 (de) | 1992-09-04 | 2000-07-05 | BP Chemicals Limited | Katalysatorzusammensetzungen und Verfahren zur Herstellung von Polyolefinen |
ES2148204T3 (es) * | 1992-09-04 | 2000-10-16 | Bp Chem Int Ltd | Composiciones cataliticas y procedimiento para la preparacion de poliolefinas. |
US5486585A (en) | 1993-08-26 | 1996-01-23 | Exxon Chemical Patents Inc. | Amidosilyldiyl bridged catalysts and method of polymerization using said catalysts. |
DE69422462T2 (de) | 1993-09-20 | 2000-05-31 | Albemarle Corp | Aluminoxanen mit einer erhöhten katalytischen Aktivität |
EP0654476B1 (de) | 1993-11-24 | 2001-01-24 | TARGOR GmbH | Metallocene, Verfahren zu ihrer Herstellung und ihrer Verwendung als Katalysatoren |
US5648310A (en) | 1993-12-23 | 1997-07-15 | Union Carbide Chemicals & Plastics Technology Corporation | Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture |
CA2180180C (en) | 1994-01-11 | 2006-03-14 | Jeffrey Harold Butler | Alumoxanes and catalysts comprising alumoxanes |
IT1269931B (it) | 1994-03-29 | 1997-04-16 | Spherilene Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
US5498581A (en) * | 1994-06-01 | 1996-03-12 | Phillips Petroleum Company | Method for making and using a supported metallocene catalyst system |
US5473020A (en) | 1994-06-30 | 1995-12-05 | Phillips Petroleum Company | Polymer bound ligands, polymer bound metallocenes, catalyst systems, preparation, and use |
US5770755A (en) | 1994-11-15 | 1998-06-23 | Phillips Petroleum Company | Process to prepare polymeric metallocenes |
IT1275452B (it) | 1995-06-30 | 1997-08-07 | Enichem Elastomers | Procedimento per la preparazione di copolimeri etilene-propilene |
US5610115A (en) | 1995-07-20 | 1997-03-11 | Samsung General Chemicals Co., Ltd. | Organic carrier supported metallocene catalyst for olefin polymerization |
US5739368A (en) | 1996-05-10 | 1998-04-14 | Albemarle Corporation | Use of heat treated alumoxanes in preparing supported catalysts |
US5726264A (en) | 1996-06-14 | 1998-03-10 | Phillips Petroleum Company | Processes to produce metallocene compounds and polymerization processes therewith |
DE19644040A1 (de) | 1996-10-31 | 1998-05-07 | Hoechst Ag | Verfahren zur Hydrierung von Metallocenen |
US5854363A (en) | 1997-01-08 | 1998-12-29 | Phillips Petroleum Company | (Omega-alkenyl) (cyclopentacarbyl) metallocene compounds |
WO1998052686A1 (en) | 1997-05-22 | 1998-11-26 | Phillips Petroleum Company | Method for making and using a prepolymerized olefin polymerization catalyst |
-
1998
- 1998-11-03 DE DE69821528T patent/DE69821528T2/de not_active Expired - Fee Related
- 1998-11-03 WO PCT/US1998/023517 patent/WO1999029738A1/en active IP Right Grant
- 1998-11-03 EP EP98956575A patent/EP1037931B1/de not_active Expired - Lifetime
- 1998-11-03 JP JP2000524326A patent/JP2001525458A/ja not_active Withdrawn
- 1998-11-03 CA CA002313244A patent/CA2313244A1/en not_active Abandoned
- 1998-11-03 ES ES98956575T patent/ES2214750T3/es not_active Expired - Lifetime
-
2000
- 2000-05-16 US US09/571,480 patent/US6521728B1/en not_active Expired - Fee Related
- 2000-05-16 US US09/571,542 patent/US6294496B1/en not_active Expired - Fee Related
-
2002
- 2002-12-18 US US10/323,171 patent/US6746981B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US6746981B2 (en) | 2004-06-08 |
US6294496B1 (en) | 2001-09-25 |
ES2214750T3 (es) | 2004-09-16 |
EP1037931B1 (de) | 2004-02-04 |
CA2313244A1 (en) | 1999-06-17 |
JP2001525458A (ja) | 2001-12-11 |
DE69821528T2 (de) | 2004-07-01 |
EP1037931A1 (de) | 2000-09-27 |
WO1999029738A1 (en) | 1999-06-17 |
US6521728B1 (en) | 2003-02-18 |
US20030105253A1 (en) | 2003-06-05 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition | ||
8339 | Ceased/non-payment of the annual fee |