DE69825119D1 - Verfahren zur Entfernung der Stickoxide aus den Abgasen mittels selektiver katalytischer Reduktion mit Ammoniak ohne Stickstoffprotoxidbildung - Google Patents

Verfahren zur Entfernung der Stickoxide aus den Abgasen mittels selektiver katalytischer Reduktion mit Ammoniak ohne Stickstoffprotoxidbildung

Info

Publication number: DE69825119D1
Authority: DE; Germany
Prior art keywords: zeolite; tetrahedra; equal; copper; faujasite
Prior art date: 1997-11-04
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

DE69825119T

Other languages

English (en)

Other versions

DE69825119T2 (de

Inventor

Bernard Coq

Gerard Delahay

Francois Fajulas

Stephane Kieger

Bernard Neveu

Jean-Bernard Peudpiece

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

GPN, COURBEVOIE, FR

Original Assignee

Grande Paroisse SA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1997-11-04

Filing date

1998-10-27

Publication date

2004-08-26

1998-10-27 Application filed by Grande Paroisse SA filed Critical Grande Paroisse SA

2004-08-26 Application granted granted Critical

2004-08-26 Publication of DE69825119D1 publication Critical patent/DE69825119D1/de

2005-08-11 Publication of DE69825119T2 publication Critical patent/DE69825119T2/de

2018-10-28 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 title abstract 8
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 title abstract 4
GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 title abstract 2
229910021529 ammonia Inorganic materials 0.000 title abstract 2
238000010531 catalytic reduction reaction Methods 0.000 title abstract 2
230000015572 biosynthetic process Effects 0.000 title 1
239000007789 gas Substances 0.000 title 1
238000000034 method Methods 0.000 title 1
229910021536 Zeolite Inorganic materials 0.000 abstract 6
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 6
239000010457 zeolite Substances 0.000 abstract 6
239000010949 copper Substances 0.000 abstract 5
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 4
229910052802 copper Inorganic materials 0.000 abstract 4
239000012013 faujasite Substances 0.000 abstract 4
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 3
238000001354 calcination Methods 0.000 abstract 3
239000001257 hydrogen Substances 0.000 abstract 3
229910052739 hydrogen Inorganic materials 0.000 abstract 3
239000003054 catalyst Substances 0.000 abstract 2
229910001387 inorganic aluminate Inorganic materials 0.000 abstract 2
229910052909 inorganic silicate Inorganic materials 0.000 abstract 2
238000005342 ion exchange Methods 0.000 abstract 2
150000002500 ions Chemical class 0.000 abstract 2
229910021644 lanthanide ion Inorganic materials 0.000 abstract 2
229910052751 metal Inorganic materials 0.000 abstract 2
229910052782 aluminium Inorganic materials 0.000 abstract 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
150000001879 copper Chemical class 0.000 abstract 1
238000004519 manufacturing process Methods 0.000 abstract 1
239000002184 metal Substances 0.000 abstract 1
239000000203 mixture Substances 0.000 abstract 1
239000012266 salt solution Substances 0.000 abstract 1
229910052710 silicon Inorganic materials 0.000 abstract 1
239000010703 silicon Substances 0.000 abstract 1
239000007787 solid Substances 0.000 abstract 1
239000000243 solution Substances 0.000 abstract 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
- B01D53/8628—Processes characterised by a specific catalyst
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
- B01J29/072—Iron group metals or copper
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
- B01J29/14—Iron group metals or copper
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20761—Copper
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/10—Capture or disposal of greenhouse gases of nitrous oxide (N2O)

DE69825119T 1997-11-04 1998-10-27 Verfahren zur Entfernung der Stickoxide aus den Abgasen mittels selektiver katalytischer Reduktion mit Ammoniak ohne Stickstoffprotoxidbildung Expired - Lifetime DE69825119T2 (de)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
FR9713861		1997-11-04
FR9713861A FR2770418B1 (fr)	1997-11-04	1997-11-04	Procede pour l'elimination dans le gaz des oxydes d'azote nox par reduction catalytique selective (scr) a l'ammoniac sur catalyseurs zeolitiques ne provoquant pas la formation de protoxyde d'azote

Publications (2)

Publication Number	Publication Date
DE69825119D1 true DE69825119D1 (de)	2004-08-26
DE69825119T2 DE69825119T2 (de)	2005-08-11

Family

ID=9513020

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DE69825119T Expired - Lifetime DE69825119T2 (de)	1997-11-04	1998-10-27	Verfahren zur Entfernung der Stickoxide aus den Abgasen mittels selektiver katalytischer Reduktion mit Ammoniak ohne Stickstoffprotoxidbildung

Country Status (7)

Country	Link
US (1)	US6221324B1 (de)
EP (1)	EP0914866B1 (de)
AT (1)	ATE271420T1 (de)
DE (1)	DE69825119T2 (de)
DK (1)	DK0914866T3 (de)
ES (1)	ES2226084T3 (de)
FR (1)	FR2770418B1 (de)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2789911B1 (fr) *	1999-02-18	2001-05-04	Grande Paroisse Sa	Procede pour abattre simultanement les oxydes nitriques et le protoxyde d'azote dans les gaz qui en contiennent
AU5130500A (en) *	1999-05-21	2000-12-12	Zeochem Llc	Molecular sieve adsorbent-catalyst for sulfur compound contaminated gas and liquid streams and process for its use
FR2804675B1 (fr) *	2000-02-08	2002-06-14	Ceca Sa	Procede pour l'elimination dans les gaz des oxydes d'azote nox par reduction catalytique selective (scr) a l'ammoniac sur catalyseurs zeolitiques agglomeres ne provoquant pas la formation de protoxyde d'azote
US20030073566A1 (en) *	2001-10-11	2003-04-17	Marshall Christopher L.	Novel catalyst for selective NOx reduction using hydrocarbons
DE10226461A1 (de)	2002-06-13	2004-01-22	Uhde Gmbh	Verfahren und Vorrichtung zur Verringerung des Gehaltes an NOx und N2O in Gasen
US6993900B2 (en)	2002-10-21	2006-02-07	Ford Global Technologies, Llc	Exhaust gas aftertreatment systems
US7093427B2 (en)	2002-11-21	2006-08-22	Ford Global Technologies, Llc	Exhaust gas aftertreatment systems
US6862879B2 (en)	2002-11-21	2005-03-08	Ford Global Technologies, Llc	Diesel aftertreatment system
US6892530B2 (en)	2002-11-21	2005-05-17	Ford Global Technologies, Llc	Exhaust gas aftertreatment systems
US6928806B2 (en) *	2002-11-21	2005-08-16	Ford Global Technologies, Llc	Exhaust gas aftertreatment systems
US6981368B2 (en) *	2002-11-21	2006-01-03	Ford Global Technologies, Llc	Exhaust gas aftertreatment systems
US6834498B2 (en) *	2002-11-21	2004-12-28	Ford Global Technologies, Llc	Diesel aftertreatment systems
US6895747B2 (en)	2002-11-21	2005-05-24	Ford Global Technologies, Llc	Diesel aftertreatment systems
US6823663B2 (en)	2002-11-21	2004-11-30	Ford Global Technologies, Llc	Exhaust gas aftertreatment systems
US7255842B1 (en)	2003-09-22	2007-08-14	United States Of America Department Of Energy	Multi-component removal in flue gas by aqua ammonia
RU2008128363A (ru) *	2005-12-14	2010-01-20	Басф Каталистс Ллк (Us)	ЦЕОЛИТНЫЙ КАТАЛИЗАТОР С УЛУЧШЕННЫМ ВОССТАНОВЛЕНИЕМ NOх В SCR
US9090525B2 (en)	2009-12-11	2015-07-28	Exxonmobil Research And Engineering Company	Process and system to convert methanol to light olefin, gasoline and distillate
DE102010022775A1 (de)	2010-06-04	2011-12-08	Uhde Gmbh	Verfahren und Vorrichtung zur Beseitigung von NOx und N2O
EP2593222B1 (de)	2010-07-15	2015-12-16	Basf Se	Kupfer-enthaltendes zsm-34-, off- und/oder eri-zeolith-material für selektive nox-reduzierung
EP2463028A1 (de)	2010-12-11	2012-06-13	Umicore Ag & Co. Kg	Verfahren zur Herstellung von metalldotierten Zeoliten und Zeotypen sowie dessen Anwendung zur katalytischen Entfernung von Stickstoffoxiden
EP2465606A1 (de) *	2010-12-16	2012-06-20	Umicore Ag & Co. Kg	Zeolith-basierter Katalysator mit verbesserter katalytischer Aktivität zur Reduktion von Stickoxiden
DE102011011881A1 (de)	2011-02-21	2012-08-23	Thyssenkrupp Uhde Gmbh	Verfahren zur Beseitigung von N2O und NOX aus dem Prozess zur Salpetersäureherstellung
DE102011014007A1 (de) *	2011-03-15	2012-09-20	Linde Aktiengesellschaft	Verfahren und Anlage zur Rauchgasentstickung
DE102011121188A1 (de)	2011-12-16	2013-06-20	Thyssen Krupp Uhde Gmbh	Vorrichtung und Verfahren zur Beseitigung von NOx und N20
US8821818B1 (en)	2013-03-15	2014-09-02	Three D Stack, LLC	Cleaning stack gas
AU2014233522B2 (en)	2013-03-15	2017-10-12	3D Clean Coal Emissions Stack, Llc	Cleaning stack gas
US9919269B2 (en)	2013-03-15	2018-03-20	3D Clean Coal Emissions Stack Llc	Clean coal stack
RU2577381C2 (ru) *	2014-05-13	2016-03-20	Федеральное государственное автономное образовательное учреждение высшего профессионального образования "Национальный исследовательский ядерный университет "МИФИ" (НИЯУ МИФИ)	Способ получения алюмосиликатных адсорбентов
CN108349830A (zh)	2015-10-28	2018-07-31	埃克森美孚研究工程公司	用于将含有含氧物的原料转化成汽油和馏分油的方法和装置
CA3024092A1 (en)	2016-05-14	2017-11-23	3 D Clean Coal Emissions Stack, Llc	Clean gas stack
US11851386B2 (en) *	2021-10-15	2023-12-26	Exelus, Inc.	Solid-acid catalyzed paraffin alkylation with rare earth-modified molecular sieve adsorbents

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5850777B2 (ja) *	1975-03-28	1983-11-12	トウアネンリヨウコウギヨウカブシキガイシヤ	チツソサンカブツノカンゲンヨウシヨクバイ
JPH0674135B2 (ja) *	1989-02-07	1994-09-21	重質油対策技術研究組合	新規な鉄含有アルミノシリケート
US5207893A (en)	1989-02-07	1993-05-04	Research Association For Residual Oil Processing	Hydrocracking process employing a novel iron-containing aluminosilicate
FR2649622B1 (fr)	1989-07-12	1993-12-24	Paroisse Ste Chimique Grande	Composition catalytique a base de zeolithe y, utilisable dans le traitement d'effluents oxygenes contenant des nox, sa preparation et son application
CA2024154C (en)	1989-08-31	1995-02-14	Senshi Kasahara	Catalyst for reducing nitrogen oxides from exhaust gas
US5234876A (en) *	1992-10-20	1993-08-10	Corning Incorporated	Thermally stable chromium-exchanged zeolites and method of making same
DE4413359A1 (de) *	1994-04-18	1995-10-19	Ftu Gmbh Forschung Und Tech En	Mittel und Verfahren zur Reinigung von Gasen und Abgasen von NOx

1997
- 1997-11-04 FR FR9713861A patent/FR2770418B1/fr not_active Expired - Fee Related
1998
- 1998-10-27 AT AT98402666T patent/ATE271420T1/de not_active IP Right Cessation
- 1998-10-27 EP EP98402666A patent/EP0914866B1/de not_active Expired - Lifetime
- 1998-10-27 DE DE69825119T patent/DE69825119T2/de not_active Expired - Lifetime
- 1998-10-27 ES ES98402666T patent/ES2226084T3/es not_active Expired - Lifetime
- 1998-10-27 DK DK98402666T patent/DK0914866T3/da active
- 1998-10-30 US US09/182,649 patent/US6221324B1/en not_active Expired - Fee Related

Also Published As

Publication number	Publication date
DK0914866T3 (da)	2004-11-22
US6221324B1 (en)	2001-04-24
FR2770418A1 (fr)	1999-05-07
ATE271420T1 (de)	2004-08-15
DE69825119T2 (de)	2005-08-11
FR2770418B1 (fr)	1999-12-03
EP0914866B1 (de)	2004-07-21
ES2226084T3 (es)	2005-03-16
EP0914866A1 (de)	1999-05-12

Legal Events

Date	Code	Title	Description
2006-05-11	8364	No opposition during term of opposition
2010-08-26	8327	Change in the person/name/address of the patent owner	Owner name: GPN, COURBEVOIE, FR

Publication	Publication Date	Title
DE69825119D1 (de)	2004-08-26	Verfahren zur Entfernung der Stickoxide aus den Abgasen mittels selektiver katalytischer Reduktion mit Ammoniak ohne Stickstoffprotoxidbildung
CN106163659B (zh)	2019-05-10	在低温下通过固态离子交换来生产金属交换的沸石的方法
JP3086015B2 (ja)	2000-09-11	排気ガス浄化用触媒
JPH01266854A (ja)	1989-10-24	排気ガス浄化用触媒の製造方法
CA2112190C (en)	2000-02-22	Process for removing nitrogen oxides from oxygen rich exhaust gas
EP3097054A1 (de)	2016-11-30	Bimetall-ausgetauschter zeolith-beta aus organotemplate-freier synthese und verwendung davon in der selektiven katalytischen nox-reduktion
CN109985660A (zh)	2019-07-09	一种一步法合成铁基分子筛催化剂的方法及其应用
US5374409A (en)	1994-12-20	Purifying gases with an alkali metal and transition metal containing zeolite
EP0888817A1 (de)	1999-01-07	Prozess zur produktion eines katalysators zur abgasreinigung
US5059569A (en)	1991-10-22	Process and catalyst for selective reduction of nitrogen oxides
CN101687187B (zh)	2013-07-10	用于含盐酸的废气的废气催化剂
Jiang et al.	2018	On the mechanism of ammonia SCR over Cu-and Fe-containing zeolite catalysts
JP2928853B2 (ja)	1999-08-03	窒素酸化物接触分解触媒及び接触分解方法
EP0491358B1 (de)	1996-03-13	Katalysator zur Reinigung von Abgasen
KR101795404B1 (ko)	2017-11-08	촉매 및 촉매의 제조 방법
JPH03127629A (ja)	1991-05-30	窒素酸化物の直接接触分解触媒
JPS63119850A (ja)	1988-05-24	燃焼排ガス浄化用触媒
JPH03101837A (ja)	1991-04-26	窒素酸化物の分解触媒の製造方法
Jabłońska et al.	2024	Disclosing the Enhanced NH3-SCR-DeNOx Activity of Cu-containing Zeolite Y Prepared with 15-Crown-5
Littlejohn et al.	1982	A Kinetic Study of Reactions Involving Ferrous Nitrosyl Complexes
KR100321471B1 (ko)	2002-07-31	질소산화물(NOx)정화용촉매의제조방법
JPH0824662A (ja)	1996-01-30	亜酸化窒素分解触媒
JPH0194946A (ja)	1989-04-13	高活性窒素酸化物分解触媒及び窒素酸化物の接触分解方法
Halasz et al.	1997	Decomposition of no over Cu-ZSM-5 prepared by solid-state ion exchange
JPH02251248A (ja)	1990-10-09	窒素酸化物の分解触媒