DE69911128D1 - Olefinpolymerisationskatalysator und Verfahren zur Herstellung von Olefinpolymeren - Google Patents

Olefinpolymerisationskatalysator und Verfahren zur Herstellung von Olefinpolymeren

Info

Publication number
DE69911128D1
DE69911128D1 DE69911128T DE69911128T DE69911128D1 DE 69911128 D1 DE69911128 D1 DE 69911128D1 DE 69911128 T DE69911128 T DE 69911128T DE 69911128 T DE69911128 T DE 69911128T DE 69911128 D1 DE69911128 D1 DE 69911128D1
Authority
DE
Germany
Prior art keywords
olefin
polymerization catalyst
making
polymers
olefin polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69911128T
Other languages
English (en)
Other versions
DE69911128T2 (de
Inventor
Katsumi Hirakawa
Yumito Uehara
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Japan Polychem Corp
Original Assignee
Japan Polychem Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Japan Polychem Corp filed Critical Japan Polychem Corp
Application granted granted Critical
Publication of DE69911128D1 publication Critical patent/DE69911128D1/de
Publication of DE69911128T2 publication Critical patent/DE69911128T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
DE69911128T 1998-07-21 1999-07-21 Olefinpolymerisationskatalysator und Verfahren zur Herstellung von Olefinpolymeren Expired - Fee Related DE69911128T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP20503298 1998-07-21
JP20503298 1998-07-21

Publications (2)

Publication Number Publication Date
DE69911128D1 true DE69911128D1 (de) 2003-10-16
DE69911128T2 DE69911128T2 (de) 2004-07-08

Family

ID=16500321

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69911128T Expired - Fee Related DE69911128T2 (de) 1998-07-21 1999-07-21 Olefinpolymerisationskatalysator und Verfahren zur Herstellung von Olefinpolymeren

Country Status (3)

Country Link
US (1) US6376416B1 (de)
EP (1) EP0974601B1 (de)
DE (1) DE69911128T2 (de)

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US6420298B1 (en) * 1999-08-31 2002-07-16 Exxonmobil Oil Corporation Metallocene catalyst compositions, processes for making polyolefin resins using such catalyst compositions, and products produced thereby
AU1330701A (en) * 1999-10-07 2001-05-10 Dow Chemical Company, The Silica gel composition and method for making
EP1101777A1 (de) * 1999-11-22 2001-05-23 UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION (a Delaware corporation) Metallmischkatalysatoren
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
KR101113341B1 (ko) 2002-10-15 2012-09-27 엑손모빌 케미칼 패턴츠 인코포레이티드 올레핀 중합용 다중 촉매 시스템 및 이로부터 제조된중합체
US7223822B2 (en) * 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
US7550528B2 (en) * 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
US7741417B2 (en) * 2004-01-07 2010-06-22 Exxonmobil Chemical Patents Inc. Preparation of polymerization catalyst activators utilizing indole-modified silica supports
US7220695B2 (en) * 2004-01-07 2007-05-22 Exxonmobil Chemical Patents Inc. Supported activator
EP1650230A1 (de) * 2004-10-21 2006-04-26 Total Petrochemicals Research Feluy Polyolefine hergestellt durch Ziegler -Natta und Metallocene Katalysator in einem einzigen Reaktor
US8022005B2 (en) 2007-11-08 2011-09-20 Exxonmobil Chemical Patents Inc. Halogen substituted heterocyclic heteroatom containing ligands-alumoxane activation of metallocenes
US8685879B2 (en) * 2011-04-29 2014-04-01 Basf Corporation Emulsion process for improved large spherical polypropylene catalysts
CN103351443B (zh) * 2013-07-16 2016-02-10 华东理工大学 一种负载型烯烃聚合催化剂及其制备方法与应用
US9321854B2 (en) 2013-10-29 2016-04-26 Exxonmobil Chemical Patents Inc. Aluminum alkyl with C5 cyclic and pendent olefin polymerization catalyst
US10351647B2 (en) 2015-05-29 2019-07-16 Exxonmobil Chemical Patents Inc. Polymerization process using bridged metallocene compounds supported on organoaluminum treated layered silicate supports
US10618988B2 (en) 2015-08-31 2020-04-14 Exxonmobil Chemical Patents Inc. Branched propylene polymers produced via use of vinyl transfer agents and processes for production thereof
US11041029B2 (en) 2015-08-31 2021-06-22 Exxonmobil Chemical Patents Inc. Aluminum alkyls with pendant olefins for polyolefin reactions
CN107921424A (zh) 2015-08-31 2018-04-17 埃克森美孚化学专利公司 粘土上的具有悬垂烯烃的烷基铝
US10059788B2 (en) 2016-04-29 2018-08-28 Exxonmobil Chemical Patents Inc. Organoaluminum activators on clays
US10562987B2 (en) 2016-06-30 2020-02-18 Exxonmobil Chemical Patents Inc. Polymers produced via use of quinolinyldiamido transition metal complexes and vinyl transfer agents
US10626200B2 (en) 2017-02-28 2020-04-21 Exxonmobil Chemical Patents Inc. Branched EPDM polymers produced via use of vinyl transfer agents and processes for production thereof
US10676551B2 (en) 2017-03-01 2020-06-09 Exxonmobil Chemical Patents Inc. Branched ethylene copolymers produced via use of vinyl transfer agents and processes for production thereof

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US4937299A (en) * 1983-06-06 1990-06-26 Exxon Research & Engineering Company Process and catalyst for producing reactor blend polyolefins
US4530914A (en) * 1983-06-06 1985-07-23 Exxon Research & Engineering Co. Process and catalyst for producing polyethylene having a broad molecular weight distribution
US4701432A (en) * 1985-11-15 1987-10-20 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4659685A (en) * 1986-03-17 1987-04-21 The Dow Chemical Company Heterogeneous organometallic catalysts containing a supported titanium compound and at least one other supported organometallic compound
US4939217A (en) * 1987-04-03 1990-07-03 Phillips Petroleum Company Process for producing polyolefins and polyolefin catalysts
US4975403A (en) * 1987-09-11 1990-12-04 Fina Technology, Inc. Catalyst systems for producing polyolefins having a broad molecular weight distribution
US5032562A (en) * 1989-12-27 1991-07-16 Mobil Oil Corporation Catalyst composition and process for polymerizing polymers having multimodal molecular weight distribution
JPH05105718A (ja) 1989-12-27 1993-04-27 Mobil Oil Corp 多モードの分子量分布を有するポリマーの重合触媒組成物および方法
JP2953520B2 (ja) 1989-12-29 1999-09-27 三井化学株式会社 オレフィン重合用触媒およびオレフィンの重合方法
US5145818A (en) * 1989-12-29 1992-09-08 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst and process for the polymerization of olefins
TW198726B (de) * 1989-12-29 1993-01-21 Mitsui Petroleum Chemicals Ind
US5266544A (en) * 1989-12-29 1993-11-30 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst and process for the polymerization of olefins
TW218884B (de) * 1991-05-01 1994-01-11 Mitsubishi Kakoki Kk
US5693583A (en) * 1991-06-10 1997-12-02 Mobil Oil Corporation High activity polyethylene catalysts which produce bimodal or trimodal product molecular weight distributions
JP3274509B2 (ja) * 1992-10-29 2002-04-15 三菱化学株式会社 オレフィン重合用触媒及びオレフィン重合体の製造方法
JP3274511B2 (ja) * 1992-10-30 2002-04-15 三菱化学株式会社 オレフィン重合用触媒及びオレフィン重合体の製造方法
US5804524A (en) * 1993-04-28 1998-09-08 Fina Technology, Inc. Process for a isotactic/syndiotactic polymer blend in a single reactor
JP3203903B2 (ja) 1993-09-02 2001-09-04 住友金属工業株式会社 半導体装置
US5614456A (en) * 1993-11-15 1997-03-25 Mobil Oil Corporation Catalyst for bimodal molecular weight distribution ethylene polymers and copolymers
EP0658576B1 (de) * 1993-12-17 1998-07-29 Tosoh Corporation Olefinpolymerisationkatalysator und Verfahren zur Olefinpolymerisation
EP0683180B1 (de) * 1994-05-18 2002-03-06 Mitsubishi Chemical Corporation Katalysator zur Polymerisation eines Olefins und Verfahren zum Polymerisieren des Olefins
IT1270070B (it) * 1994-07-08 1997-04-28 Spherilene Srl Componenti e catalizzatori per la polimerizzazione di olefine
US5529965A (en) * 1994-10-28 1996-06-25 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
AU3505497A (en) * 1996-07-15 1998-02-09 Mobil Oil Corporation Comonomer pretreated bimetallic catalyst for blow molding and film applications
JP3629113B2 (ja) * 1996-12-24 2005-03-16 三菱化学株式会社 オレフィンの多段階重合方法
US6051525A (en) * 1997-07-14 2000-04-18 Mobil Corporation Catalyst for the manufacture of polyethylene with a broad or bimodal molecular weight distribution
US6001766A (en) * 1997-12-24 1999-12-14 Mobil Oil Corporation Bimetallic catalysts for ethylene polymerization reactions activated with paraffin-soluble alkylalumoxanes

Also Published As

Publication number Publication date
EP0974601A2 (de) 2000-01-26
EP0974601B1 (de) 2003-09-10
DE69911128T2 (de) 2004-07-08
EP0974601A3 (de) 2000-05-17
US6376416B1 (en) 2002-04-23

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8339 Ceased/non-payment of the annual fee