DE69941191D1 - Verfahren zur Gasphasenpolymerisation - Google Patents

Verfahren zur Gasphasenpolymerisation

Info

Publication number
DE69941191D1
DE69941191D1 DE69941191T DE69941191T DE69941191D1 DE 69941191 D1 DE69941191 D1 DE 69941191D1 DE 69941191 T DE69941191 T DE 69941191T DE 69941191 T DE69941191 T DE 69941191T DE 69941191 D1 DE69941191 D1 DE 69941191D1
Authority
DE
Germany
Prior art keywords
gas
phase polymerization
polymerization
phase
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69941191T
Other languages
English (en)
Inventor
Agapios Kyriacos Agapiou
Chi-I Kuo
David Micheal Glowczwski
Steven Kent Ackerman
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Univation Technologies LLC
Original Assignee
Univation Technologies LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univation Technologies LLC filed Critical Univation Technologies LLC
Application granted granted Critical
Publication of DE69941191D1 publication Critical patent/DE69941191D1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/02—Anti-static agent incorporated into the catalyst
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts
DE69941191T 1998-07-10 1999-06-23 Verfahren zur Gasphasenpolymerisation Expired - Lifetime DE69941191D1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/113,216 US7354880B2 (en) 1998-07-10 1998-07-10 Catalyst composition and methods for its preparation and use in a polymerization process
PCT/US1999/014214 WO2000002931A1 (en) 1998-07-10 1999-06-23 A catalyst composition and methods for its preparation and use in a polymerization process

Publications (1)

Publication Number Publication Date
DE69941191D1 true DE69941191D1 (de) 2009-09-10

Family

ID=22348220

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69941191T Expired - Lifetime DE69941191D1 (de) 1998-07-10 1999-06-23 Verfahren zur Gasphasenpolymerisation

Country Status (24)

Country Link
US (7) US7354880B2 (de)
EP (2) EP1102798B1 (de)
JP (3) JP2002520427A (de)
KR (2) KR20010083089A (de)
CN (2) CN1166700C (de)
AR (2) AR019758A1 (de)
AU (2) AU762896B2 (de)
BR (2) BR9911988A (de)
CA (2) CA2333239C (de)
DE (1) DE69941191D1 (de)
EG (2) EG22216A (de)
ES (1) ES2331341T3 (de)
ID (2) ID26870A (de)
IL (2) IL139554A0 (de)
MY (1) MY135520A (de)
NO (2) NO20010155L (de)
PL (2) PL345417A1 (de)
RU (1) RU2233291C2 (de)
SA (1) SA99200422B1 (de)
SK (2) SK192001A3 (de)
TR (2) TR200100006T2 (de)
TW (1) TWI239962B (de)
WO (2) WO2000002930A1 (de)
ZA (2) ZA200006608B (de)

Families Citing this family (140)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8497330B2 (en) * 1997-12-08 2013-07-30 Univation Technologies, Llc Methods for polymerization using spray dried and slurried catalyst
US7354880B2 (en) * 1998-07-10 2008-04-08 Univation Technologies, Llc Catalyst composition and methods for its preparation and use in a polymerization process
US6559088B1 (en) * 1999-02-22 2003-05-06 Fina Technology, Inc. Ziegler-Natta catalyst with amine for polymerization
JP4376485B2 (ja) * 1999-12-15 2009-12-02 ユニベーション・テクノロジーズ・エルエルシー 重合方法
US6482903B1 (en) 1999-12-15 2002-11-19 Univation Technologies, Llc Method for preparing a supported catalyst system and its use in a polymerization process
US6593267B2 (en) * 2000-12-18 2003-07-15 Univation Technologies, Llc Method for preparing a supported catalyst system and its use in a polymerization process
JP2002265507A (ja) * 2001-03-09 2002-09-18 Sumitomo Chem Co Ltd オレフィンの気相流動床式重合反応におけるシーティング防止
CN1276018C (zh) 2001-06-22 2006-09-20 埃克森美孚化学专利公司 作为抗冲改性剂的茂金属生产的极低密聚乙烯或线型低密度聚乙烯
EP1308464A1 (de) * 2001-10-19 2003-05-07 BP Chemicals S.N.C. Verfahren zur Gasphasen-(Co)polymerisation von Olefinen in einem Fliessbettreaktor
US20030113255A1 (en) * 2001-11-27 2003-06-19 Wayne Harlan Activated alumina and method of producing same
FR2833191B1 (fr) * 2001-12-10 2004-08-20 Inst Francais Du Petrole Composition catalytique et procede ameliores pour l'oligomerisation de l'ethylene, en particulier en hexene-1
US6864205B2 (en) * 2001-12-18 2005-03-08 Univation Technologies, Llc Heterocyclic-amide catalyst compositions for the polymerization of olefins
US7199255B2 (en) * 2001-12-18 2007-04-03 Univation Technologies, Llc Imino-amide catalysts for olefin polymerization
US7001863B2 (en) * 2001-12-18 2006-02-21 Univation Technologies, Llc Monoamide based catalyst compositions for the polymerization of olefins
US6703338B2 (en) 2002-06-28 2004-03-09 Univation Technologies, Llc Polymerization catalyst activators, method of preparing, and their use in polymerization processes
EP1556424B1 (de) * 2002-10-09 2006-03-22 Exxonmobil Chemical Patents Inc. Verfahren zur injektion von katalysator in einen polymerizationsreaktor
AU2003278856A1 (en) * 2002-10-09 2004-05-04 Exxonmobil Chemical Patents Inc. Methods of feed purification for olefin polymerization
AU2003270801A1 (en) 2002-10-09 2004-05-04 Exxonmobil Chemical Patents Inc. Methods of delivering catalyst systems for propylene polymerization
US6884749B2 (en) 2002-10-17 2005-04-26 Equistar Chemicals L.P. Supported catalysts which reduce sheeting in olefin polymerization, process for the preparation and the use thereof
CN100549037C (zh) * 2002-12-17 2009-10-14 英诺文尼欧洲有限公司 烯烃聚合载体催化剂
US7172987B2 (en) 2002-12-31 2007-02-06 Univation Technologies, Llc Bimetallic catalyst, method of polymerization and bimodal polyolefins therefrom
JP4742221B2 (ja) * 2003-03-21 2011-08-10 ダウ グローバル テクノロジーズ エルエルシー モルホロジー制御オレフィン重合プロセス
CN1212196C (zh) * 2003-04-25 2005-07-27 中山大学 无机插层纳米催化剂及其制备方法
JP5095909B2 (ja) * 2003-06-24 2012-12-12 ローム・アンド・ハース・エレクトロニック・マテリアルズ，エル．エル．シー． 触媒組成物および析出方法
US6870010B1 (en) 2003-12-01 2005-03-22 Univation Technologies, Llc Low haze high strength polyethylene compositions
US7244795B2 (en) * 2003-12-08 2007-07-17 Univation Technologies, Llc Polymerization process using metallocene catalyst systems
US20050148742A1 (en) * 2004-01-02 2005-07-07 Hagerty Robert O. Method for controlling sheeting in gas phase reactors
US20070073012A1 (en) * 2005-09-28 2007-03-29 Pannell Richard B Method for seed bed treatment before a polymerization reaction
US20050182210A1 (en) 2004-02-17 2005-08-18 Natarajan Muruganandam De-foaming spray dried catalyst slurries
BR122018006665B1 (pt) 2004-08-09 2019-04-02 Union Carbide Chemicals & Plastics Technology Llc Método para preparar uma composição de procatalisador ziegler-natta e processo para preparar um polímero
KR101195320B1 (ko) * 2004-08-09 2012-10-29 다우 글로벌 테크놀로지스 엘엘씨 중합체를 제조하기 위한 지지된비스(하이드록시아릴아릴옥시) 촉매
US20110166305A1 (en) * 2004-08-09 2011-07-07 Jorgensen Robert J Robust Spray-Dried Ziegler-Natta Procatalyst and Polymerization Process Employing Same
US7193017B2 (en) * 2004-08-13 2007-03-20 Univation Technologies, Llc High strength biomodal polyethylene compositions
JP4928723B2 (ja) * 2004-10-12 2012-05-09 日本ポリエチレン株式会社 電線被覆用又は絶縁用樹脂組成物
US7473750B2 (en) * 2004-12-07 2009-01-06 Fina Technology, Inc. Random copolymers and formulations useful for thermoforming and blow molding applications
US7067451B1 (en) * 2004-12-17 2006-06-27 Fina Technology, Inc. Soluble magnesium complexes useful for the production of polyolefin catalysts and catalysts prepared therewith
US7312279B2 (en) * 2005-02-07 2007-12-25 Univation Technologies, Llc Polyethylene blend compositions
US7220806B2 (en) * 2005-04-29 2007-05-22 Fina Technology, Inc. Process for increasing ethylene incorporation into random copolymers
US20060247394A1 (en) * 2005-04-29 2006-11-02 Fina Technology, Inc. Process for increasing ethylene incorporation into random copolymers
US7081285B1 (en) 2005-04-29 2006-07-25 Fina Technology, Inc. Polyethylene useful for blown films and blow molding
US7645834B2 (en) * 2005-04-29 2010-01-12 Fina Technologies, Inc. Catalyst system for production of polyolefins
US7282546B2 (en) * 2005-06-22 2007-10-16 Fina Technology, Inc. Cocatalysts for reduction of production problems in metallocene-catalyzed polymerizations
US7323526B2 (en) * 2005-07-29 2008-01-29 Univation Technologies, Llc Supported metallocene-alkyl catalyst composition
EP1803747A1 (de) * 2005-12-30 2007-07-04 Borealis Technology Oy Oberflächemodifizierte Polymerisationskatalysatoren zur Herstellung von Polyolefinfilmen mit niedrigem Gelgehalt
JP5249785B2 (ja) * 2006-01-27 2013-07-31 ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア 生体模倣足場材
US20080220042A1 (en) * 2006-01-27 2008-09-11 The Regents Of The University Of California Biomolecule-linked biomimetic scaffolds
US20070299222A1 (en) 2006-04-04 2007-12-27 Fina Technology, Inc. Transition metal catalysts and formation thereof
US7683002B2 (en) 2006-04-04 2010-03-23 Fina Technology, Inc. Transition metal catalyst and formation thereof
US20070235896A1 (en) * 2006-04-06 2007-10-11 Fina Technology, Inc. High shrink high modulus biaxially oriented films
US20090186996A1 (en) 2006-05-05 2009-07-23 Boone Harold W Hafnium complexes of carbazolyl substituted imidazole ligands
US20080051538A1 (en) * 2006-07-11 2008-02-28 Fina Technology, Inc. Bimodal pipe resin and products made therefrom
US7449529B2 (en) * 2006-07-11 2008-11-11 Fina Technology, Inc. Bimodal blow molding resin and products made therefrom
US7893181B2 (en) * 2006-07-11 2011-02-22 Fina Technology, Inc. Bimodal film resin and products made therefrom
US7514510B2 (en) * 2006-07-25 2009-04-07 Fina Technology, Inc. Fluorenyl catalyst compositions and olefin polymerization process
US7470759B2 (en) * 2006-07-31 2008-12-30 Fina Technology, Inc. Isotactic-atactic polypropylene and methods of making same
WO2008018976A1 (en) * 2006-08-04 2008-02-14 Univation Technologies, Llc Method of maintaining heat transfer capacity in a polymerization reaction system
US20080061468A1 (en) * 2006-09-07 2008-03-13 Frank Li Fiber processing of high ethylene level propylene-ethylene random copolymers by use of nucleators
US7538167B2 (en) * 2006-10-23 2009-05-26 Fina Technology, Inc. Syndiotactic polypropylene and methods of preparing same
US20080114130A1 (en) * 2006-11-10 2008-05-15 John Ashbaugh Resin composition for production of high tenacity slit film, monofilaments and fibers
CA2664910A1 (en) 2006-12-15 2008-07-03 Fina Technology, Inc. Polypropylene blown film
KR20090094003A (ko) * 2006-12-29 2009-09-02 피나 테크놀러지, 인코포레이티드 폴리프로필렌 필름 등급 수지를 제조하기 위해 ｎ-부틸메틸디메톡시실란을 사용하는 숙시네이트 함유 중합 촉매 시스템
EP2118152B1 (de) 2007-03-06 2016-08-17 Univation Technologies, LLC Verfahren zur anbringung von lösungskatalysatoren auf reaktoroberflächen
RU2444531C2 (ru) * 2007-03-06 2012-03-10 Юнивейшн Текнолоджиз, Ллк Способы и устройства для полимеризации
DE602007013538D1 (de) † 2007-05-25 2011-05-12 Borealis Tech Oy Herstellungsverfahren für ein Alpha-Olefin-Polymerharz
EP2183286B1 (de) * 2007-08-16 2012-12-12 Univation Technologies, LLC Kontinuitätsadditive und ihre verwendung bei polymerisationsverfahren
WO2009048625A1 (en) * 2007-10-11 2009-04-16 Univation Technologies, Llc Continuity additives and their use in polymerization processes
TW200932762A (en) 2007-10-22 2009-08-01 Univation Tech Llc Polyethylene compositions having improved properties
EP2112175A1 (de) 2008-04-16 2009-10-28 ExxonMobil Chemical Patents Inc. Aktivator für Metallocene, der einen oder mehrere halogensubstituierte heterocyklische Liganden enthält, die an ein Alumoxan koordiniert sind
BRPI0819552A2 (pt) * 2007-12-31 2015-05-19 Dow Global Technologies Inc Processo para produzir um polímero a base de olefina
RU2486952C2 (ru) 2008-01-07 2013-07-10 Юнивейшн Текнолоджиз, Ллк Системы подачи катализатора и способы их применения
US8859084B2 (en) * 2008-01-29 2014-10-14 Fina Technology, Inc. Modifiers for oriented polypropylene
US8003741B2 (en) 2008-02-07 2011-08-23 Fina Technology, Inc. Ziegler-Natta catalyst
US20090202770A1 (en) * 2008-02-08 2009-08-13 Fengkui Li Polypropylene/polyisobutylene blends and films prepared from same
WO2009139851A1 (en) * 2008-05-15 2009-11-19 Univation Technologies, Llc Polyolefin compositions and methods of processing the same using metal salts
US7740070B2 (en) * 2008-06-16 2010-06-22 Halliburton Energy Services, Inc. Wellbore servicing compositions comprising a density segregation inhibiting composite and methods of making and using same
US8759446B2 (en) 2008-06-30 2014-06-24 Fina Technology, Inc. Compatibilized polypropylene and polylactic acid blends and methods of making and using same
US8268913B2 (en) * 2008-06-30 2012-09-18 Fina Technology, Inc. Polymeric blends and methods of using same
US8545971B2 (en) * 2008-06-30 2013-10-01 Fina Technology, Inc. Polymeric compositions comprising polylactic acid and methods of making and using same
US9334342B2 (en) 2008-10-01 2016-05-10 Fina Technology, Inc. Polypropylene for reduced plate out in polymer article production processes
US8247588B2 (en) 2008-10-03 2012-08-21 Univation Technologies, Llc Catalyst and compositions and methods of making and using the same
US20100087602A1 (en) * 2008-10-08 2010-04-08 Fina Technology, Inc. Long chain branched polypropylene for cast film applications
WO2010071798A1 (en) 2008-12-18 2010-06-24 Univation Technologies, Llc Method for seed bed treatment for a polymerization reaction
RU2527945C2 (ru) 2009-01-08 2014-09-10 Юнивейшн Текнолоджиз, Ллк Добавка для процессов полимеризации полиолефинов
US9090000B2 (en) 2009-03-26 2015-07-28 Fina Technology, Inc. Injection stretch blow molded articles and random copolymers for use therein
US8653198B2 (en) 2009-03-26 2014-02-18 Fina Technology, Inc. Method for the preparation of a heterophasic copolymer and uses thereof
US20100247887A1 (en) 2009-03-26 2010-09-30 Fina Technology, Inc. Polyolefin films for in-mold labels
US8957167B2 (en) 2009-07-28 2015-02-17 Univation Technologies, Llc Polymerization process using a supported constrained geometry catalyst
US9174384B2 (en) 2009-09-01 2015-11-03 Fina Technology, Inc. Multilayer polypropylene films and methods of making and using same
KR101769276B1 (ko) * 2009-09-11 2017-08-18 바셀 폴리올레핀 이탈리아 에스.알.엘 올레핀의 기체상 중합 방법
US20110065846A1 (en) * 2009-09-11 2011-03-17 Abel Grosjean Olefin polymerisation process
US20110076598A1 (en) * 2009-09-30 2011-03-31 Academia Sinica Corrin compound fuel cell catalysts
US8592535B2 (en) 2010-01-11 2013-11-26 Fina Technology, Inc. Ziegler-natta catalyst systems and polymers formed therefrom
EA019933B1 (ru) * 2010-03-04 2014-07-30 Тотал Ресерч Энд Текнолоджи Фелюи Модифицированные носители катализатора
US10351640B2 (en) 2010-04-22 2019-07-16 Fina Technology, Inc. Formation of Ziegler-Natta catalyst using non-blended components
US8278403B2 (en) 2010-07-08 2012-10-02 Fina Technology, Inc. Multi-component catalyst systems and polymerization processes for forming broad composition distribution polymers
US20120046429A1 (en) 2010-08-23 2012-02-23 Fina Technology, Inc. Sequential Formation of Ziegler-Natta Catalyst Using Non-blended Components
ES2571737T3 (es) * 2010-11-30 2016-05-26 Univation Tech Llc Procedimientos para la polimerización de olefinas con sales metálicas de carboxilato extraídas
ES2543432T3 (es) 2010-11-30 2015-08-19 Univation Technologies, Llc Composición de catalizador con características de flujo mejoradas y métodos de producir y utilizar la misma
RU2577324C2 (ru) * 2010-12-22 2016-03-20 Юнивейшн Текнолоджиз, Ллк Добавка для способов полимеризации полиолефина
US10711077B2 (en) 2011-02-07 2020-07-14 Fina Technology, Inc. Ziegler-natta catalyst composition with controlled morphology
US8586192B2 (en) 2011-02-15 2013-11-19 Fina Technology, Inc. Compatibilized polymeric compositions comprising polyolefin-polylactic acid copolymers and methods of making the same
US9382347B2 (en) 2011-02-16 2016-07-05 Fina Technology Inc Ziegler-Natta catalysts doped with non-group IV metal chlorides
US8628718B2 (en) 2011-02-18 2014-01-14 Fina Technology, Inc. Modified polylactic acid, polymeric blends and methods of making the same
CA2734167C (en) 2011-03-15 2018-03-27 Nova Chemicals Corporation Polyethylene film
US8685879B2 (en) * 2011-04-29 2014-04-01 Basf Corporation Emulsion process for improved large spherical polypropylene catalysts
CA2749835C (en) 2011-08-23 2018-08-21 Nova Chemicals Corporation Feeding highly active phosphinimine catalysts to a gas phase reactor
US20130059968A1 (en) * 2011-09-06 2013-03-07 Fei-Lin Yang Plastic composition
CA2760264C (en) 2011-12-05 2018-08-21 Nova Chemicals Corporation Passivated supports for use with olefin polymerization catalysts
US8580893B2 (en) 2011-12-22 2013-11-12 Fina Technology, Inc. Methods for improving multimodal polyethylene and films produced therefrom
CA2798855C (en) 2012-06-21 2021-01-26 Nova Chemicals Corporation Ethylene copolymers having reverse comonomer incorporation
US9115233B2 (en) 2012-06-21 2015-08-25 Nova Chemicals (International) S.A. Ethylene copolymer compositions, film and polymerization processes
CA2797620C (en) 2012-12-03 2019-08-27 Nova Chemicals Corporation Controlling resin properties in a gas phase polymerization process
CA2800056A1 (en) 2012-12-24 2014-06-24 Nova Chemicals Corporation Polyethylene blend compositions
BR112015018250B1 (pt) 2013-01-30 2021-02-23 Univation Technologies, Llc processo para produzir uma composição catalisadora e processo de polimerização
KR101584350B1 (ko) * 2013-04-08 2016-01-13 한화케미칼 주식회사 대전 방지제를 포함하는 메탈로센 촉매 시스템 및 이를 이용한 폴리올레핀의 제조 방법
US9073029B2 (en) 2013-09-25 2015-07-07 Chevron Phillips Chemical Company Lp System and method for deterring fouling in a polymerization reactor
US9206293B2 (en) 2014-01-31 2015-12-08 Fina Technology, Inc. Polyethyene and articles produced therefrom
CN106459248B (zh) * 2014-04-02 2020-03-03 尤尼威蒂恩技术有限责任公司 催化剂组合物、制备方法及在聚合工艺中的用途
EP3126404B1 (de) 2014-04-02 2019-08-21 Univation Technologies, LLC Kontinuitätszusammensetzungen und verwendung davon in olefinpolymerisationsverfahren
EP3154937A4 (de) 2014-06-11 2018-01-17 Fina Technology, Inc. Chlorbeständige polyolethylenzusammensetzungen und daraus hergestellte artikel
US9650448B2 (en) 2014-06-13 2017-05-16 Fina Technology, Inc. Formation of a Ziegler-Natta catalyst
US9624321B2 (en) 2014-06-13 2017-04-18 Fina Technology, Inc. Formation of a Ziegler-Natta catalyst
CA2871463A1 (en) 2014-11-19 2016-05-19 Nova Chemicals Corporation Passivated supports: catalyst, process and product
EP3223942A2 (de) * 2014-11-24 2017-10-04 Univation Technologies, LLC Katalysatorzusammensetzungen auf chrombasis zur olefinpolymerisierung
CA2874344C (en) 2014-12-15 2021-08-31 Nova Chemicals Corporation Spheroidal catalyst for olefin polymerization
CA2891693C (en) 2015-05-21 2022-01-11 Nova Chemicals Corporation Controlling the placement of comonomer in an ethylene copolymer
CA2892552C (en) 2015-05-26 2022-02-15 Victoria Ker Process for polymerization in a fluidized bed reactor
CA2892882C (en) 2015-05-27 2022-03-22 Nova Chemicals Corporation Ethylene/1-butene copolymers with enhanced resin processability
FR3045414B1 (fr) * 2015-12-18 2019-12-27 IFP Energies Nouvelles Nouvelle composition catalytique a base de nickel et de ligand de type phosphine et d'une base de lewis et son utilisation dans un procede d'oligomerisation des olefines
MX2019004273A (es) 2016-10-28 2019-08-05 Fina Technology Uso de agentes para reducir la cristalinidad en polipropileno para aplicaciones de bopp.
WO2020056119A1 (en) 2018-09-14 2020-03-19 Fina Technology, Inc. Polyethylene and controlled rheology polypropylene polymer blends and methods of use
EP3873949A1 (de) 2018-11-01 2021-09-08 ExxonMobil Chemical Patents Inc. Abänderungen eines schlammtrimmkatalysatorzuführers
KR102285140B1 (ko) * 2018-12-03 2021-08-02 한화솔루션 주식회사 올레핀 중합용 촉매의 제조방법
KR102287064B1 (ko) * 2018-12-11 2021-08-05 한화솔루션 주식회사 올레핀 중합용 촉매의 제조방법
WO2020172306A1 (en) 2019-02-20 2020-08-27 Fina Technology, Inc. Polymer compositions with low warpage
US20210138446A1 (en) * 2019-11-12 2021-05-13 Exxonmobil Research And Engineering Company Particulate compositions having low fines content
CN114901391A (zh) * 2019-11-26 2022-08-12 埃克森美孚化学专利公司 生产负载型催化剂的系统和方法
EP4073131A1 (de) 2019-12-11 2022-10-19 ExxonMobil Chemical Patents Inc. Niedrigaromatische polyolefine
RU2737084C1 (ru) * 2020-02-26 2020-11-24 Михаил Эхильевич Шмулевский Способ получения катализатора для полимеризации стирола
US20220340723A1 (en) 2021-04-26 2022-10-27 Fina Technology, Inc. Thin Single-Site Catalyzed Polymer Sheets

Family Cites Families (66)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3082198A (en) 1958-08-25 1963-03-19 Goodrich Gulf Chem Inc Process for polymerizing ethylene in the process of aluminum alkyl, titanium tetrachloride, and carboxylic acid
GB1124750A (en) 1965-03-17 1968-08-21 Borden Co Improvements in the recovery of acetylene
NL161467C (nl) * 1970-12-02 1980-02-15 Stamicarbon Werkwijze voor het polymeriseren van etheen.
JPS5038158B2 (de) 1972-01-22 1975-12-08
GB1443074A (en) * 1974-01-14 1976-07-21 Ici Ltd Olefin polymerisation process
US3995097A (en) 1975-09-15 1976-11-30 Phillips Petroleum Company Prevention of fouling in polymerization reactors
CA1125268A (en) 1978-04-14 1982-06-08 Exxon Research And Engineering Company Trialkyl aluminum cocatalyst
US4310439A (en) 1979-03-07 1982-01-12 Exxon Research & Engineering Co. Novel trialkyl aluminum cocatalyst
DE2911241A1 (de) 1979-03-22 1980-10-02 Basf Ag Alkoxylierte fettsaeuren, verfahren zu deren herstellung und ihre anwendung als loesungsvermittler
US4513095A (en) 1980-11-24 1985-04-23 National Distillers And Chemical Corporation Intermetallic compounds of polymeric transition metal oxide alkoxides and catalytic use thereof
US4610974A (en) 1980-11-24 1986-09-09 National Distillers And Chemical Corporation Intermetallic compounds of Lewis base bridged transition metal-reducing metal complexes and catalytic use thereof
US4792592A (en) * 1981-03-26 1988-12-20 Union Carbide Corporation Process for reducing sheeting during polymerization of alpha-olefins
US4876320A (en) 1981-03-26 1989-10-24 Union Carbide Chemicals And Plastics Company Inc. Process for reducing sheeting during polymerization of alpha-olefins
US4532311A (en) 1981-03-26 1985-07-30 Union Carbide Corporation Process for reducing sheeting during polymerization of alpha-olefins
AT377625B (de) 1981-06-29 1985-04-10 Georges A Cournoyer Vorrichtung zum lehren von musiktonleitern und -intervallen
JPS5819308A (ja) 1981-07-28 1983-02-04 Sumitomo Chem Co Ltd 触媒の脱活性化処理方法
US4425464A (en) 1982-05-20 1984-01-10 The Dow Chemical Company Neutralizing polyethylene catalyst residues
JPS58222103A (ja) * 1982-06-18 1983-12-23 Toa Nenryo Kogyo Kk オレフイン重合用触媒成分の製造方法
JPS58222104A (ja) * 1982-06-21 1983-12-23 Toa Nenryo Kogyo Kk オレフイン重合用触媒成分
GB8302885D0 (en) * 1983-02-02 1983-03-09 Ici Plc Catalyst
US4564647A (en) 1983-11-14 1986-01-14 Idemitsu Kosan Company Limited Process for the production of polyethylene compositions
EP0374619A1 (de) 1983-11-14 1990-06-27 Idemitsu Kosan Company Limited Verfahren zur Herstellung von Zusammensetzungen auf Polyethylenbasis
US4634744A (en) 1985-01-09 1987-01-06 Chemplex Company Method of catalyst deactivation
US4855370A (en) * 1986-10-01 1989-08-08 Union Carbide Corporation Method for reducing sheeting during polymerization of alpha-olefins
US5026795A (en) * 1987-02-24 1991-06-25 Phillips Petroleum Co Process for preventing fouling in a gas phase polymerization reactor
US4803251A (en) * 1987-11-04 1989-02-07 Union Carbide Corporation Method for reducing sheeting during polymerization of alpha-olefins
FR2646426B2 (fr) * 1988-09-13 1991-08-16 Bp Chemicals Sa Procede et appareillage de polymerisation d'alpha-olefine en phase gazeuse en presence d'un agent ralentisseur d'activite
DE3833445A1 (de) * 1988-10-01 1990-04-05 Basf Ag Vermeidung von farbigen verunreinigungen bei der herstellung von ultrahochmolekularen ethylenpolymerisaten mittels eines titan enthaltenden katalysatorsystems
DE3833444A1 (de) 1988-10-01 1990-04-05 Basf Ag Vermeidung von farbigen verunreinigungen bei der herstellung von ultrahochmolekularen ethylenpolymerisaten mittels eines titan enthaltenden katalysatorsystems
EP0376145B1 (de) * 1988-12-26 1994-03-23 Tosoh Corporation Verfahren zur Herstellung von stereoregularem Polyolefin
DE4008732A1 (de) 1990-03-19 1991-09-26 Basf Ag Uebergangsmetall-katalysatorkomponente fuer ein ziegler-katalysatorsystem und dessen verwendung
FR2660926B1 (fr) * 1990-04-11 1992-07-31 Bp Chemicals Snc Prepolymere d'alpha-olefine contenant un metal de transition et procede de polymerisation d'alpha-olefine en phase gazeuse mettant en óoeuvre le prepolymere.
JPH0445110A (ja) 1990-06-12 1992-02-14 Japan Synthetic Rubber Co Ltd エチレン系共重合体の製造方法
US5218052A (en) * 1991-02-04 1993-06-08 Amoco Corporation Olefin polymerization and copolymerization process
TW248565B (de) 1991-08-14 1995-06-01 Mitsui Petroleum Chemicals Industry Co
US5126414A (en) * 1991-10-11 1992-06-30 Mobil Oil Corporation Control of oligomer level in low pressure polyethylene reactor systems
CA2124187C (en) * 1991-11-25 2001-08-07 Howard William Turner Polyonic transition metal catalyst composition
IT1262933B (it) * 1992-01-31 1996-07-22 Montecatini Tecnologie Srl Processo per la polimerizzazione in fase gas di alfa-olefine
US5459217A (en) 1993-04-09 1995-10-17 Mitsui Petrochemical Industries, Ltd. Ethylene/alpha-olefin copolymer
US5332706A (en) * 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
CN1087326C (zh) 1993-05-13 2002-07-10 埃克森美孚化学专利公司 乙烯共聚物制备的薄膜及其制备方法
US5422386A (en) 1993-08-30 1995-06-06 Quantum Chemical Corporation Process to simultaneously reactor-fill polyolefins and compatibilize fillers with polyolefins
US5391657A (en) * 1993-09-27 1995-02-21 Union Carbide Chemicals & Plastics Technology Corporaton Method for reducing sheeting and static charges during polymerization of ethylene polymers
FI96867C (fi) * 1993-12-27 1996-09-10 Borealis Polymers Oy Leijupetireaktori
IT1274016B (it) * 1994-02-21 1997-07-14 Spherilene Srl Processo per la polimerizzazione in fase gas delle a-olefine
DE69525679T2 (de) 1994-05-18 2002-11-07 Mitsubishi Chem Corp Katalysator zur Polymerisation eines Olefins und Verfahren zum Polymerisieren des Olefins
US5473020A (en) * 1994-06-30 1995-12-05 Phillips Petroleum Company Polymer bound ligands, polymer bound metallocenes, catalyst systems, preparation, and use
US5461123A (en) * 1994-07-14 1995-10-24 Union Carbide Chemicals & Plastics Technology Corporation Gas phase fluidized bed polyolefin polymerization process using sound waves
IT1273660B (it) * 1994-07-20 1997-07-09 Spherilene Srl Procedimento per la preparazione di polimeri amorfi del propilene
US5643847A (en) * 1994-08-03 1997-07-01 Exxon Chemical Patents Inc. Supported ionic catalyst composition
US5763543A (en) * 1994-09-14 1998-06-09 Exxon Chemical Patents Inc. Olefin polymerization process with little or no scavenger present
DE4446907A1 (de) 1994-12-27 1996-07-04 Basf Ag Verfahren zur Herstellung eines Hydrierkatalysators
JPH08198905A (ja) * 1995-01-25 1996-08-06 Mitsui Petrochem Ind Ltd オレフィンの気相重合法
FI104827B (fi) 1995-04-12 2000-04-14 Borealis Polymers Oy Menetelmä likaantumisen ja kerrostumisen estämiseksi kaasufaasireaktoreissa
US5654454A (en) 1995-05-30 1997-08-05 Phillips Petroleum Company Metallocene preparation and use
US5661095A (en) * 1995-06-06 1997-08-26 Quantum Chemical Corporation Olefin polymerization catalyst component supported on a copolymer of an olefin and an unsaturated silane
JP3654456B2 (ja) * 1995-09-12 2005-06-02 三井化学株式会社 オレフィンの気相重合方法
US5723399A (en) 1995-09-14 1998-03-03 Showa Denko K.K. Ethylenic polymerization catalyst
EP0768319A1 (de) 1995-09-29 1997-04-16 Nippon Oil Co. Ltd. Verfahren zur Herstellung von Polyolefinen
DE19615953A1 (de) 1996-04-22 1997-10-23 Basf Ag Verfahren zur Herstellung von Polymerisaten von Alk-1-enen in Gegenwart eines geträgerten Metallocenkatalysatorsystems und eines Antistatikums
DE19617229A1 (de) 1996-04-30 1997-11-06 Basf Ag Verfahren zur Herstellung von niedermolekularen Ethylenpolymerisaten im Hochdruck
US5693727A (en) 1996-06-06 1997-12-02 Union Carbide Chemicals & Plastics Technology Corporation Method for feeding a liquid catalyst to a fluidized bed polymerization reactor
JP2000511959A (ja) 1996-06-11 2000-09-12 ビーエーエスエフ アクチェンゲゼルシャフト 担体として無機酸化物を有するメタロセン触媒組成物
BR9806848A (pt) * 1997-11-06 2000-03-14 Toho Titanium Co Ltd Componente de catalizador sólido para a polimerização de olefinas, e, catalisador para a polimerização de olefinas.
US6069109A (en) * 1998-07-01 2000-05-30 Union Carbide Chemicals & Plastics Technology Corporation Process for the production of half-sandwich transition metal based catalyst precursors
US7354880B2 (en) * 1998-07-10 2008-04-08 Univation Technologies, Llc Catalyst composition and methods for its preparation and use in a polymerization process

Also Published As

Publication number Publication date
TWI239962B (en) 2005-09-21
SK202001A3 (en) 2001-10-08
BR9911988A (pt) 2001-03-27
IL139553A0 (en) 2002-02-10
US20080214385A1 (en) 2008-09-04
AR019757A1 (es) 2002-03-13
BR9912025A (pt) 2001-04-03
CN1133661C (zh) 2004-01-07
ES2331341T3 (es) 2009-12-29
EP1123322A1 (de) 2001-08-16
WO2000002931A1 (en) 2000-01-20
EG22259A (en) 2002-11-30
KR20010083089A (ko) 2001-08-31
JP2002520428A (ja) 2002-07-09
AR019758A1 (es) 2002-03-13
JP4929066B2 (ja) 2012-05-09
US7354880B2 (en) 2008-04-08
JP2002520427A (ja) 2002-07-09
IL139554A0 (en) 2002-02-10
US20020026018A1 (en) 2002-02-28
SK192001A3 (en) 2001-08-06
KR20010083088A (ko) 2001-08-31
US6391819B1 (en) 2002-05-21
PL345390A1 (en) 2001-12-17
NO20010155L (no) 2001-02-28
ID26807A (id) 2001-02-08
NO20010156D0 (no) 2001-01-09
ID26870A (id) 2001-02-15
EG22216A (en) 2002-10-31
NO20010155D0 (no) 2001-01-09
EP1102798A1 (de) 2001-05-30
CA2333239A1 (en) 2000-01-20
SA99200422B1 (ar) 2006-06-21
WO2000002930A1 (en) 2000-01-20
US20020028742A1 (en) 2002-03-07
NO20010156L (no) 2001-03-05
MY135520A (en) 2008-05-30
EP1102798B1 (de) 2009-07-29
US6472342B2 (en) 2002-10-29
TR200100010T2 (tr) 2001-06-21
CN1307598A (zh) 2001-08-08
PL345417A1 (en) 2001-12-17
KR100470577B1 (ko) 2005-03-08
US6608153B2 (en) 2003-08-19
CN1166700C (zh) 2004-09-15
ZA200006608B (en) 2002-02-14
CA2332324A1 (en) 2000-01-20
US20020004448A1 (en) 2002-01-10
JP2007291404A (ja) 2007-11-08
AU4710799A (en) 2000-02-01
AU752470B2 (en) 2002-09-19
US20020123579A1 (en) 2002-09-05
RU2233291C2 (ru) 2004-07-27
TR200100006T2 (tr) 2001-07-23
ZA200006609B (en) 2002-02-14
CA2333239C (en) 2009-07-21
AU4710099A (en) 2000-02-01
US6306984B1 (en) 2001-10-23
AU762896B2 (en) 2003-07-10
CN1307597A (zh) 2001-08-08
US6300436B1 (en) 2001-10-09

Similar Documents

Publication Publication Date Title
DE69941191D1 (de) Verfahren zur Gasphasenpolymerisation
DE69907785D1 (de) Mehrstufiges Verfahren zur Olefinpolymerisation
DE69937681D1 (de) Verfahren zur radikalischen polymerisation
DE69624844T2 (de) Verfahren zur Olefinpolymerisation
DE69921593D1 (de) Verfahren zur Kälteversorgung
DE69910557D1 (de) Verfahren zur reinigung von aminonitrilen
DE60037724D1 (de) Verfahren zur chlor-herstellung
DE50015014D1 (de) Verfahren zur Hydroformylierung von Olefinen
DE60029182D1 (de) Verfahren zur eindeutigen Abstandsschätzung
DE69515241D1 (de) Verfahren zur Emulsions-Polymerisation
DE69939253D1 (de) Verfahren zur veränderung von polymeroberflächen zur besseren benetzbarkeit
DE69914995D1 (de) Verfahren zur schnellen Vorhangbeschichtung
DE60013154D1 (de) Verfahren zur Emulsionspolymerisation
DE50000893D1 (de) Verfahren zur veredelung
DE69902063T2 (de) Verfahren zur Katalysatorherstellung
DE69807473D1 (de) Kontinuierliches verfahren zur herstellung von propylenpolymeren
DE19983354T1 (de) Verfahren zur Hydroformylierung
DE59805982D1 (de) Verfahren zur signalverarbeitung
ATE206392T1 (de) Verfahren zur alkylierug von gehinderten sulfonamiden
DE69601540D1 (de) Verfahren zur oxychlorierung
DE60024037T2 (de) Verfahren zur Verbesserung NHRP
DE69929184D1 (de) Verfahren zur sputterbeschichtung
DE69609963D1 (de) Verfahren zur iodierung
DE69823210D1 (de) Verfahren zur Olefinpolymerisation
DE60019408D1 (de) Verfahren zur Modifizierung von Polymerisaten

Legal Events

Date Code Title Description
8364 No opposition during term of opposition