DE69943133D1 - Unter scherwirkung verflüssigbare ethylen/alpha-olefin/dien polymere und ihre herstellung - Google Patents

Unter scherwirkung verflüssigbare ethylen/alpha-olefin/dien polymere und ihre herstellung

Info

Publication number
DE69943133D1
DE69943133D1 DE69943133T DE69943133T DE69943133D1 DE 69943133 D1 DE69943133 D1 DE 69943133D1 DE 69943133 T DE69943133 T DE 69943133T DE 69943133 T DE69943133 T DE 69943133T DE 69943133 D1 DE69943133 D1 DE 69943133D1
Authority
DE
Germany
Prior art keywords
olefin
ethylene
coatable
dien
alpha
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69943133T
Other languages
English (en)
Inventor
Larry Duane Cady
Morgan Mark Hughes
Michael Kenneth Laughner
Larry Alan Meiske
Deepak Rasiklal Parikh
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
Original Assignee
Dow Global Technologies LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies LLC filed Critical Dow Global Technologies LLC
Application granted granted Critical
Publication of DE69943133D1 publication Critical patent/DE69943133D1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/44Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/903Monomer polymerized in presence of transition metal containing catalyst and hydrocarbon additive affecting polymer properties of catalyst activity
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts
DE69943133T 1998-11-02 1999-11-02 Unter scherwirkung verflüssigbare ethylen/alpha-olefin/dien polymere und ihre herstellung Expired - Lifetime DE69943133D1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10656998P 1998-11-02 1998-11-02
PCT/US1999/025637 WO2000026268A1 (en) 1998-11-02 1999-11-02 SHEAR THINNING ETHYLENE/α-OLEFIN INTERPOLYMERS AND THEIR PREPARATION

Publications (1)

Publication Number Publication Date
DE69943133D1 true DE69943133D1 (de) 2011-02-24

Family

ID=22312137

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69943133T Expired - Lifetime DE69943133D1 (de) 1998-11-02 1999-11-02 Unter scherwirkung verflüssigbare ethylen/alpha-olefin/dien polymere und ihre herstellung

Country Status (13)

Country Link
US (1) US7750104B2 (de)
EP (2) EP1159320B1 (de)
JP (3) JP5276757B2 (de)
KR (1) KR100623106B1 (de)
CN (1) CN1134467C (de)
AT (1) ATE495205T1 (de)
AU (1) AU1241600A (de)
BR (1) BR9915199B1 (de)
CA (1) CA2347501C (de)
DE (1) DE69943133D1 (de)
ES (2) ES2666708T3 (de)
MX (1) MXPA01004337A (de)
WO (1) WO2000026268A1 (de)

Families Citing this family (53)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003000740A2 (en) 2001-06-20 2003-01-03 Exxonmobil Chemical Patents Inc. Polyolefins made by catalyst comprising a noncoordinating anion and articles comprising them
US20040168757A1 (en) * 2001-06-21 2004-09-02 Jurg Vogt Monolithic belts containing ethylene-alpha-olefin copolymers
US7906586B2 (en) * 2003-12-09 2011-03-15 Dow Global Technologies Llc Thermoplastic olefinic compositions
US20050209403A1 (en) * 2003-12-09 2005-09-22 Walton Kim L Thermoplastic olefinic compositions
DE602005021222D1 (de) * 2004-06-28 2010-06-24 Dow Global Technologies Inc Haftverstärker für mehrschichtige laminate
WO2006124369A1 (en) * 2005-05-12 2006-11-23 Dow Global Technologies Inc. Thermoformed, extruded sheeting with reduced gloss
AU2006291074A1 (en) 2005-09-12 2007-03-22 Dow Global Technologies Llc Automotive parts prepared from ethylene/alpha -olefins compositions
BRPI0520599A2 (pt) 2005-10-07 2009-10-06 Pirelli & C Spa poste de serviço, material compósito termoplástico, e, processo para a produção de um poste de serviço
EP2004738A2 (de) * 2006-04-06 2008-12-24 Dow Global Technologies Inc. Dehnbare polyolefinzusammensetzungen und isolierte fahrzeugteile mit gedehnten polyolefinzusammensetzungen
AR060643A1 (es) * 2006-05-17 2008-07-02 Dow Global Technologies Inc Proceso de polimerizacion de solucion de polipropileno
WO2008057886A2 (en) * 2006-11-01 2008-05-15 Dow Global Technologies Inc. Polyurethane compositions and articles prepared therefrom, and methods for making the same
BRPI0719500B1 (pt) 2006-12-21 2023-10-10 Dow Global Technologies Inc Processo para preparar um interpolímero de olefina em multibloco funcionalizado e processo para preparar um interpolímero em multibloco funcionalizado com imida
JP5100342B2 (ja) * 2007-12-05 2012-12-19 三井化学株式会社 ゴム組成物およびその用途
WO2010059474A1 (en) * 2008-11-21 2010-05-27 Dow Global Technologies Inc. Medium voltage cable sheath comprising an olefin-based polymer
EP2449027B1 (de) 2009-07-02 2017-04-26 Dow Global Technologies LLC Tpo zusammensetzung, artikel und verfahren zu ihrer herstellung
JP5357643B2 (ja) * 2009-07-08 2013-12-04 三井化学株式会社 ゴム組成物およびその用途
EP2376346B3 (de) 2009-07-09 2016-01-13 Advanced Technology Materials, Inc. Aufbewahrungssystem mit starrer Innenauskleidung sowie Verfahren zur Ausgabe eines Fluidums
EP2454317B1 (de) 2009-07-14 2013-05-01 Dow Global Technologies LLC Vakuumthermogeformte, extrudierte folie mit verbesserter glanzreduktion
CN102666701B (zh) 2009-11-23 2016-01-20 陶氏环球技术有限责任公司 组合物、膜及其制备方法
BR112012028158B1 (pt) 2010-05-21 2020-04-07 Dow Global Technologies Llc composição termoplástica e artigo
CN102985476B (zh) 2010-05-27 2015-08-19 陶氏环球技术有限责任公司 聚合物组合物、其制备方法、以及由该组合物制备的制品
SG186718A1 (en) 2010-06-22 2013-02-28 Dow Global Technologies Llc Crosslinked compositions and articles prepared therefrom
IT1400743B1 (it) 2010-06-30 2013-07-02 Dow Global Technologies Inc Composizioni polimeriche
EP2643094A4 (de) 2010-11-23 2017-05-24 Advanced Technology Materials, Inc. Spender mit einem inneren behälter
WO2012078829A1 (en) 2010-12-10 2012-06-14 Dow Global Technologies Llc Films with improved coefficient of friction
ES2758356T3 (es) 2010-12-21 2020-05-05 Dow Global Technologies Llc Polímeros basados en olefinas y polimerizaciones en dispersión
EP2681124A4 (de) 2011-03-01 2015-05-27 Advanced Tech Materials Verschachtelte blasgeformte innere auskleidung und umverpackung sowie herstellungsverfahren dafür
JP5697747B2 (ja) 2011-05-18 2015-04-08 三井化学株式会社 プロピレン系共重合体、プロピレン系共重合体組成物、その成形体およびその発泡体、およびそれらの製造方法
KR101212637B1 (ko) * 2011-06-09 2012-12-14 에스케이종합화학 주식회사 신규한 사이클로펜타[b]플루오레닐 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법
BR112014006802B1 (pt) 2011-09-23 2020-11-24 Dow Global Technologies Llc composição e artigo
US9580587B2 (en) 2011-10-10 2017-02-28 Dow Global Technologies Llc Polymer compositions with improved retention of properties under mechanical and thermal stresses
MX357976B (es) 2011-12-13 2018-08-01 Dow Global Technologies Llc Composicion de interpolimero de etileno-propileno-dieno.
WO2013096418A1 (en) * 2011-12-19 2013-06-27 Dow Global Technologies Llc Ethylene-based polymers prepared by dispersion polymerization
ES2607135T3 (es) 2012-05-09 2017-03-29 Sasol Technology (Proprietary) Limited Separación de componentes de una corriente de hidrocarburo multi-componente
WO2014046777A1 (en) * 2012-09-20 2014-03-27 Exxonmobil Chemical Patents Inc. Modified polyethylene compositions for films
US8901238B2 (en) * 2012-10-09 2014-12-02 Lion Copolymer Geismar, Llc Sponge polymer with controlled long chain branching and broad molecular weight distribution
CN104812783B (zh) 2012-11-30 2021-07-16 陶氏环球技术有限责任公司 乙烯/α-烯烃/多烯基组合物
KR102038178B1 (ko) 2013-01-18 2019-10-29 다우 글로벌 테크놀로지스 엘엘씨 고분자량 폴리올레핀을 위한 중합 방법
KR101585206B1 (ko) * 2013-07-22 2016-01-13 주식회사 엘지화학 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법
KR101585204B1 (ko) 2013-06-28 2016-01-13 주식회사 엘지화학 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법
WO2014209084A1 (ko) 2013-06-28 2014-12-31 주식회사 엘지화학 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법
IN2015DN02232A (de) 2013-06-28 2015-08-21 Lg Chemical Ltd
US10184045B2 (en) 2014-02-24 2019-01-22 Dow Global Technologies Llc Thermoplastic polyolefin with reduced gloss for non-carpeted flooring
BR112018077402B1 (pt) 2016-06-30 2023-04-25 Dow Global Technologies Llc Composições à base de etileno/alfa-olefina/polieno
US11098144B2 (en) 2016-06-30 2021-08-24 Dow Global Technologies Llc Ethylene/alpha-olefin/polyene interpolymers and compositions containing the same
SG10202101314UA (en) 2016-08-12 2021-03-30 Dow Global Technologies Llc Propylene-based compositions comprising carbon fibers and a thermoplastic polyolefin elastomer
EP3672811A1 (de) 2017-08-24 2020-07-01 Dow Global Technologies LLC Ethylen/c5-c10-alpha-olefin-/polyen-interpolymere
BR112020003532B1 (pt) 2017-08-30 2023-05-09 Dow Global Technologies Llc Composição elastomérica, processo para produzir um assoalho sem carpete de veículo e assoalho sem carpete de caminhão ou automóvel
CN111868166A (zh) * 2018-02-14 2020-10-30 陶氏环球技术有限责任公司 具有改进的长期热老化性能的乙烯/α-烯烃互聚物组合物
EP3752554B1 (de) 2018-02-14 2023-05-31 Dow Global Technologies LLC Ethylen/alpha-olefin interpolymer-zusammensetzungen mit verbessertem widerstand bei hoher kontinuerlicher temperatur
EP3752559B1 (de) 2018-02-14 2023-08-30 Dow Global Technologies LLC Ethylen-/alpha-olefin-interpolymerzusammensetzungen mit verbessertem kontinuierlichen hochtemperaturwiderstand
KR20220123255A (ko) * 2019-12-27 2022-09-06 다우 글로벌 테크놀로지스 엘엘씨 에틸렌/부텐 다중블록 공중합체 및 이를 제조하는 방법
KR102572495B1 (ko) 2021-06-07 2023-09-01 (주) 화승소재 열가소성 가황물 및 이의 제조방법

Family Cites Families (111)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8003A (en) 1851-03-25 Improvement in scythe-tastenings
US304314A (en) 1884-09-02 Method of casting steel
US1305296A (en) 1919-06-03 Kwotss op bendebjng objects less visible against backgrounds
US547718A (en) 1895-10-08 Joseph fletcher
US545403A (en) 1895-08-27 Type weiting machine
US702475A (en) 1902-02-14 1902-06-17 William Powers Harrow.
US876268A (en) 1907-03-05 1908-01-07 Alfred J Diescher Apparatus for washing coal, ore, &c.
US1095893A (en) 1911-09-13 1914-05-05 Clarence P Landreth Process of and apparatus for treating water.
US2491396A (en) 1939-08-11 1949-12-13 Ernst J Seckel Adhesive thread and fabric
DE1276331B (de) 1963-11-21 1968-08-29 Gen Electric Verfahren zur Herstellung eines homogenen halbleitenden Einkristalls
US3706718A (en) 1971-05-10 1972-12-19 Uniroyal Inc Catalyst and method for making epdm having improved processability
GB1534003A (en) * 1975-04-11 1978-11-29 Sola Basic Ind Inc Electrical stress-relieving elastomeric material devices made therewith and method of making shielded electrical conductor terminations
US4177160A (en) 1975-08-08 1979-12-04 Montedison S.P.A. Catalytic components and catalysts for the polymerization of olefins
DZ520A1 (fr) 1982-03-24 2004-09-13 Union Carbide Corp Procédé perfectionné pour accroitre le rendement espace temps d'une réaction de polymérisation exothermique en lit fluidisé.
US4588790A (en) 1982-03-24 1986-05-13 Union Carbide Corporation Method for fluidized bed polymerization
US4543399A (en) 1982-03-24 1985-09-24 Union Carbide Corporation Fluidized bed reaction systems
JPS58191705A (ja) * 1982-05-06 1983-11-09 Mitsui Petrochem Ind Ltd エチレン共重合ゴム
JPS62502265A (ja) * 1985-02-21 1987-09-03 リサーチ ポリマーズ インターナショナル コーポレーション 自動車ペイント関連応用に受容的な熱可塑性物品
DE3524342A1 (de) * 1985-07-08 1987-01-15 Daimler Benz Ag Punktschweisszange fuer maschinellen einsatz
US5153157A (en) 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5096867A (en) 1990-06-04 1992-03-17 Exxon Chemical Patents Inc. Monocyclopentadienyl transition metal olefin polymerization catalysts
US5055438A (en) 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5229478A (en) 1988-06-16 1993-07-20 Exxon Chemical Patents Inc. Process for production of high molecular weight EPDM elastomers using a metallocene-alumoxane catalyst system
FR2634212B1 (fr) 1988-07-15 1991-04-19 Bp Chimie Sa Appareillage et procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5057475A (en) 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
FR2656314B1 (fr) 1989-12-22 1992-04-17 Bp Chemicals Snc Catalyseur a base de zirconium supporte sur du chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.
US5032562A (en) 1989-12-27 1991-07-16 Mobil Oil Corporation Catalyst composition and process for polymerizing polymers having multimodal molecular weight distribution
WO1991017194A1 (en) 1990-05-07 1991-11-14 Exxon Chemical Patents Inc. UNSATURATED α-OLEFIN COPOLYMERS AND METHOD FOR PREPARATION THEREOF
JP2545006B2 (ja) 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
US5272236A (en) * 1991-10-15 1993-12-21 The Dow Chemical Company Elastic substantially linear olefin polymers
JP3275211B2 (ja) 1991-05-20 2002-04-15 ザ ダウ ケミカル カンパニー 付加重合触媒の製造方法
US5721185A (en) 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5278272A (en) * 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
US6545088B1 (en) * 1991-12-30 2003-04-08 Dow Global Technologies Inc. Metallocene-catalyzed process for the manufacture of EP and EPDM polymers
US5436304A (en) 1992-03-19 1995-07-25 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
US5352749A (en) 1992-03-19 1994-10-04 Exxon Chemical Patents, Inc. Process for polymerizing monomers in fluidized beds
US5374696A (en) 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
US5296433A (en) 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
WO1994000500A1 (en) 1992-06-26 1994-01-06 Exxon Chemical Patents Inc. Solution phase polymerization process utilizing metallocene catalyst with production of olefin polymers
US5414040A (en) 1992-09-15 1995-05-09 The Dow Chemical Company Formulated ethylene/α-olefin elastomeric compounds
JPH08502303A (ja) 1992-09-29 1996-03-12 エクソン・ケミカル・パテンツ・インク 長鎖分岐ポリマー及び長鎖分岐ポリマーを製造する方法
US5604043A (en) 1993-09-20 1997-02-18 W.R. Grace & Co.-Conn. Heat shrinkable films containing single site catalyzed copolymers having long chain branching
US5326602A (en) * 1992-12-01 1994-07-05 Union Carbide Chemicals & Plastics Technology Corporation Polyethylene blends
US5332706A (en) 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
JPH06306121A (ja) * 1993-04-21 1994-11-01 Dow Chem Co:The 弾性で実質的に線状であるオレフィンポリマー
US5462999A (en) 1993-04-26 1995-10-31 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
EP0699212A1 (de) 1993-04-26 1996-03-06 Exxon Chemical Patents Inc. Polymerisation von monomeren im wirbelbett
CA2161448C (en) 1993-04-26 2003-10-14 Marc Louis Dechellis Process for polymerizing monomers in fluidized beds
EP0698044A1 (de) 1993-05-13 1996-02-28 Exxon Chemical Patents Inc. Polymerisationskatalysatorsysteme, ihre herstellung und ihre verwendung
ZA943399B (en) 1993-05-20 1995-11-17 Bp Chem Int Ltd Polymerisation process
FR2706330B1 (fr) 1993-06-15 1995-08-25 Conceptair Anstalt Dispositif polyvalent de pulvérisation et de fumigation de substance fluide vaporisable.
ES2096475T3 (es) 1993-06-24 1997-03-01 Dow Chemical Co Complejos de titanio (ii) o circonio (ii) y catalizadores de polimerizacion por adicion obtenidos a partir de los mismos.
US5470993A (en) 1993-06-24 1995-11-28 The Dow Chemical Company Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom
HU215173B (hu) 1993-09-17 1998-10-28 The Dow Chemical Company Eljárások olefinek gázfázisú polimerizálására
ES2157312T3 (es) 1993-11-08 2001-08-16 Univation Tech Llc Procedimiento para la polimerizacion o copolimerizacion de etileno.
WO1995014024A1 (fr) 1993-11-18 1995-05-26 Idemitsu Kosan Co., Ltd. Compose de metal de transition, catalyseur de polymerisation d'olefines et procede pour produire un polymere d'olefines en utilisant ce catalyseur
CA2138572C (en) 1993-12-21 1999-08-24 Univation Technologies Llc Production of polyolefins containing long chain branches by a gas phase process
JP3548619B2 (ja) * 1994-03-04 2004-07-28 アドバンスド エラストマー システムズ,エル.ピー. 半透明熱可塑性エラストマー
NL9400758A (nl) 1994-05-06 1995-12-01 Dsm Nv Werkwijze voor de bereiding van een hoogmoleculair polymeer uit etheen, alfa-olefine en eventueel dieen.
US5486632A (en) 1994-06-28 1996-01-23 The Dow Chemical Company Group 4 metal diene complexes and addition polymerization catalysts therefrom
US5461123A (en) 1994-07-14 1995-10-24 Union Carbide Chemicals & Plastics Technology Corporation Gas phase fluidized bed polyolefin polymerization process using sound waves
US5453471B1 (en) 1994-08-02 1999-02-09 Carbide Chemicals & Plastics T Gas phase polymerization process
US5527929A (en) 1994-08-02 1996-06-18 The Dow Chemical Company Zwitterionic biscyclopentadienyl complexes
RU2159779C2 (ru) * 1994-09-02 2000-11-27 Дзе Дау Кемикал Компани Термореактивные эластомеры
US5869591A (en) * 1994-09-02 1999-02-09 The Dow Chemical Company Thermoset interpolymers and foams
US5541349A (en) 1994-09-12 1996-07-30 The Dow Chemical Company Metal complexes containing partially delocalized II-bound groups and addition polymerization catalysts therefrom
US5625087A (en) 1994-09-12 1997-04-29 The Dow Chemical Company Silylium cationic polymerization activators for metallocene complexes
US5495036A (en) 1994-09-12 1996-02-27 The Dow Chemical Company Metal (III) complexes containing conjugated, non-aromatic anionic II-bound groups and addition polymerization catalysts therefrom
JP3468886B2 (ja) 1994-10-14 2003-11-17 丸善工業株式会社 発泡チューブラーフィルム、その製法および物品包装用袋
JP3560379B2 (ja) * 1995-02-28 2004-09-02 三菱化学株式会社 エチレン重合体およびその製造法
KR19990007827A (ko) 1995-04-19 1999-01-25 말콤디.킨 직쇄 폴리에틸렌으로의 장쇄 측쇄 도입
CA2178459A1 (en) 1995-06-07 1996-12-08 William Scott Lambert Low shrink force shrink film containing homogeneous substantially linear polymer having long chain branching
JP3483173B2 (ja) * 1995-06-29 2004-01-06 三井化学株式会社 オレフィン系熱可塑性エラストマー組成物
MY114719A (en) 1995-06-29 2002-12-31 Mitsui Chemicals Inc Olefin thermoplastic elastomer compositions
WO1997007252A1 (de) 1995-08-16 1997-02-27 Siemens Aktiengesellschaft Erzeugnis zur führung eines heissen, oxidierenden gases
US5670595A (en) * 1995-08-28 1997-09-23 Exxon Chemical Patents Inc. Diene modified polymers
CN1098857C (zh) 1995-10-27 2003-01-15 陶氏化学公司 含有取代茚基的金属配合物和烯烃聚合方法
US5786403A (en) 1996-03-04 1998-07-28 Mitsui Petrochemical Industries, Ltd. Foamable olefin thermoplastic elastomer compositions and foamed products thereof
JP2000517348A (ja) 1996-03-08 2000-12-26 デュポン ダウ エラストマーズ エルエルシー 粘度示数改善剤またはゲル化剤としての実質的に線状のエチレン/アルファ―オレフィンポリマー
US5958905A (en) 1996-03-26 1999-09-28 Texas Biotechnology Corporation Phosphoramidates, phosphinic amides and related compounds and the use thereof to modulate the activity of endothelin
WO1997038424A1 (en) * 1996-04-10 1997-10-16 The Dow Chemical Company Ethylene polymer composition for cable applications
JPH09316254A (ja) * 1996-05-27 1997-12-09 Arai Pump Mfg Co Ltd ローラ用ゴム組成物およびこれを用いた記録媒体搬送ローラ
SK15399A3 (en) 1996-08-08 2000-04-10 Dow Chemical Co 3-heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process
CN1245513A (zh) 1996-12-12 2000-02-23 陶氏化学公司 共聚体组合物及其平挤弹性膜
US5965756A (en) * 1996-12-19 1999-10-12 The Dow Chemical Company Fused ring substituted indenyl metal complexes and polymerization process
US6506842B1 (en) 1997-01-29 2003-01-14 Dupont Dow Elastomers L.L.C. Rheology-modified thermoplastic elastomer compositions and articles fabricated therefrom
JP2001511214A (ja) 1997-02-07 2001-08-07 エクソン・ケミカル・パテンツ・インク ビニル含有マクロマーの調製
KR100488833B1 (ko) * 1997-04-30 2005-05-11 듀폰 다우 엘라스토마스 엘. 엘. 씨. 에틸렌/알파-올레핀/디엔 공중합체 및 그의 제조 방법
AR012645A1 (es) * 1997-05-01 2000-11-08 Dow Global Technologies Inc Polimeros de alfa-olefinas preparados por polimerizacion en presencia de complejos de metales que contienen grupos indenilo
US6207754B1 (en) * 1997-05-29 2001-03-27 Exxon Chemical Patents, Inc. Low modulus thermoplastic olefin compositions
AU747745B2 (en) 1997-08-15 2002-05-23 Dow Chemical Company, The Films produced from substantially linear homogeneous olefin polymer compositions
CA2301836C (en) * 1997-08-27 2009-02-03 The Dow Chemical Company Rheology modification of elastomers
US6680361B1 (en) * 1998-11-02 2004-01-20 Dupont Dow Elastomers Llc Shear thinning ethylene/α-olefin interpolymers and their preparation
US6815062B2 (en) * 1999-06-21 2004-11-09 Pirelli Cavi E Sistemi S.P.A. Cable, in particular for electric energy transportation or distribution, and an insulating composition used therein
US6369176B1 (en) * 1999-08-19 2002-04-09 Dupont Dow Elastomers Llc Process for preparing in a single reactor polymer blends having a broad molecular weight distribution
US6372847B1 (en) * 2000-05-10 2002-04-16 Exxon Mobil Chemical Patents, Inc. Polyolefin compositions having improved low temperature toughness
JP4723732B2 (ja) * 2000-07-12 2011-07-13 セイコーインスツル株式会社 脈検出装置及び超音波診断装置
US6498214B2 (en) * 2000-08-22 2002-12-24 Dupont Dow Elastomers L.L.C. Soft touch TPO compositions comprising polypropylene and low crystalline ethylene copolymers
US6548600B2 (en) * 2000-09-22 2003-04-15 Dupont Dow Elastomers L.L.C. Thermoplastic elastomer compositions rheology-modified using peroxides and free radical coagents
WO2003082971A2 (en) 2002-03-22 2003-10-09 Dow Global Technologies Inc. Thermoplastic vulcanizate composition and method of making same
US7338994B2 (en) * 2002-10-01 2008-03-04 Dow Global Technologies Inc. Rheology-modified thermoplastic elastomer compositions for extruded profiles
US20050209403A1 (en) 2003-12-09 2005-09-22 Walton Kim L Thermoplastic olefinic compositions
US7906586B2 (en) 2003-12-09 2011-03-15 Dow Global Technologies Llc Thermoplastic olefinic compositions
AU2006213822B2 (en) 2005-02-09 2011-05-26 Covidien Lp Synthetic sealants
US7592362B2 (en) 2006-01-19 2009-09-22 Pfizer Limited Substituted imidazoles
US8170830B2 (en) 2006-08-22 2012-05-01 Jacobs James P Method and system for providing tolerance to interference and obstructions of line of sight
JP2009049520A (ja) 2007-08-14 2009-03-05 Fuji Xerox Co Ltd 画像処理装置及びシステム
US7904770B2 (en) 2008-09-09 2011-03-08 Qualcomm Incorporated Testing circuit split between tiers of through silicon stacking chips

Also Published As

Publication number Publication date
BR9915199A (pt) 2001-12-04
EP1159320A1 (de) 2001-12-05
CA2347501A1 (en) 2000-05-11
JP5276757B2 (ja) 2013-08-28
JP2014145082A (ja) 2014-08-14
US20070203314A1 (en) 2007-08-30
EP2277928A1 (de) 2011-01-26
CN1134467C (zh) 2004-01-14
CN1332755A (zh) 2002-01-23
ES2356612T3 (es) 2011-04-11
AU1241600A (en) 2000-05-22
JP6039906B2 (ja) 2016-12-07
JP6117143B2 (ja) 2017-04-19
JP2012136706A (ja) 2012-07-19
US7750104B2 (en) 2010-07-06
EP2277928B1 (de) 2018-02-21
JP2002528610A (ja) 2002-09-03
KR100623106B1 (ko) 2006-09-13
EP1159320B1 (de) 2011-01-12
MXPA01004337A (es) 2002-04-24
KR20010080925A (ko) 2001-08-25
BR9915199B1 (pt) 2010-09-08
ATE495205T1 (de) 2011-01-15
CA2347501C (en) 2010-03-23
WO2000026268A1 (en) 2000-05-11
ES2666708T3 (es) 2018-05-07

Similar Documents

Publication Publication Date Title
DE69943133D1 (de) Unter scherwirkung verflüssigbare ethylen/alpha-olefin/dien polymere und ihre herstellung
AU7845000A (en) Catalyst compositions and method of polymerization therewith
MX9501383A (es) Metalocenos que contienen fluorenilo para utilizarse en polimerizacion de olefinas.
CA2387900A1 (en) A method for preparing a supported catalyst system and its use in a polymerization process
EP0839823A3 (de) Metallocene
CA2387877A1 (en) Catalyst systems and their use in a polymerization process
NO952217L (no) Etylenselektive metallocener med höy aktivitet
BR0013335B1 (pt) mistura polimérica baseada em etileno, e artigo
TW200628503A (en) Supported metallocene catalyst and method of preparing ethylene-based copolymer using the same
EP0666267A3 (de) Organometall-Fluorenylverbindungen deren Herstellung und deren Verwendung
DE69712652D1 (de) Metallocen-Alumoxan-Trägerkatalysator für die Herstellung von Polyethylen mit breiter monomodaler Molekulargewichtsverteilung
CA2146208A1 (en) Polymerisation process
ES2144146T3 (es) Procedimiento para producir polimeros y copolimeros de etileno de distribucion de peso molecular bimodal.
MXPA00006074A (es) Catalizadores de niquel diimina con metilalumoxano como cocatalizador, metodo de polimerizacion de olefinas con los mismos y polimeros producidos.
WO2004060930A3 (en) Processes for transitioning between metallocene and ziegler-natta polymerization catalysts
MY127666A (en) Substituted indenyl containing metal complexes and olefin polymerization process
BR9714089A (pt) Pelìculas estáveis e respiráveis com aperfeiçoadoestiramento e método de fabricação destas
ATE300549T1 (de) Verbrückte metallocene, herstellung und verwendung als olefinpolymerisationskatalysator
DK1082356T3 (da) Kontrol af molekylvægten ved polymerisation af olefiner
TW428001B (en) Catalysts for the polymerization of alpha-olefins
ATE293643T1 (de) Propen dien copolymerisate
EP0598628A3 (de) Olefinpolymerisationkatalysator, Verfahren für Olefinpolymerisation unter Verwendung desselben, Ethylen/Alpha-Olefin-Copolymere, Pfropfmodifizierte Ethylen/Alpha-Olefin-Copolymere und Äthylen-Copolymer-Zusammensetzung.
ATE276321T1 (de) Pigmentkonzentrate und verfahren zu ihrer herstellung
DE69914012D1 (de) Katalysatorsysteme für die Polymerisation und Copolymerisation von Alpha-Olefinen
ATE257491T1 (de) Herstellung von härtbaren polymeren

Legal Events

Date Code Title Description
8327 Change in the person/name/address of the patent owner

Owner name: DOW GLOBAL TECHNOLOGIES LLC, MIDLAND, MICH., US