EP0071723A2 - Coated abrasive - Google Patents
Coated abrasive Download PDFInfo
- Publication number
- EP0071723A2 EP0071723A2 EP82105371A EP82105371A EP0071723A2 EP 0071723 A2 EP0071723 A2 EP 0071723A2 EP 82105371 A EP82105371 A EP 82105371A EP 82105371 A EP82105371 A EP 82105371A EP 0071723 A2 EP0071723 A2 EP 0071723A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- adhesive
- adhesive bond
- coated abrasive
- amino
- bond material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
- B24D3/34—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties
- B24D3/342—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties incorporated in the bonding agent
- B24D3/344—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties incorporated in the bonding agent the bonding agent being organic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
- B24D3/001—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as supporting member
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
- B24D3/02—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
- B24D3/20—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially organic
- B24D3/28—Resins or natural or synthetic macromolecular compounds
Definitions
- the present invention relates to coated abrasives which consist of flexible backings to which are adhered a plurality of abrasive grit particles on at least one side.
- Coated abrasives are used primarily for the shaping, dimensioning, or surface finish alteration of other material objects known generally as workpieces. Small particles of material removed from the workpieces and/or shed from the coated abrasives during working are collectively called "swarf". In many cases, the swarf tends to wholly or partially adhere to the surface of the coated abrasive, eventually loading or clogging its abrasive surfaces and rendering it unsuited for further use.
- This invention relates particularly to coated abrasives which are specially resistant to such failure by loading.
- U.S. Patent 3,043,673 teaches the use of oxy- containing compounds either in a third coat or in the conventional sizing coat of a coated abrasive, together with an exceptionally high ratio of binder adhesive to grain, as an effective means for increasing the resistance of coated abrasives to loading in the finishing of leather and similar materials.
- the oxy compounds specified in this patent are all neutral organic compounds not expected to ionize in water solution.
- U.S. Patent 3,089,763 teaches the use of polyoxyalkylene compounds in the size of coated abrasives, and one of the objects stated is to reduce loading.
- the teaching of this U.S. Patent is restricted to sizing compositions in which the principal constituent is an amine catalyzed phenolic resin.
- loading resistance can be imparted to otherwise conventional coated abrasives with size coats containing glue or amino resins by the incorporation into the size of small amounts of specific chemical compounds and mixtures as hereinafter described.
- These additives are total or partial alkyl esters of phosphoric acid, amine salts of partial esters of phosphoric acid, and quarternary ammonium salts with at least one long alkyl or substituted long alkyl group. Typical examples would be the triethanolamine salt of mono- or di- decylphosphate or stearamidopropyl-S-hydroxyethylammonium nitrate.
- Grits can be synthetic fused alumina, silicon carbide, garnet, zirconia alumina, emery, flint, or other materials, and maker adhesives can be film- forming starches, animal hide glue, amino resins, etc.
- the additives investigated which had detectable effect in reducing loading when used in the size coat are listed in Table. 1. These additives were most effective when used with amino resins such as urea-formaldehyde or melamine-formaldehydeo Such amino resins could be mixed in up to equal parts by weight with phenol-formaldehyde resins, one amino resin could be mixed with others, and any of the resins or mixtures could be filled with finely divided solids such as calcium sulfate, walnut shell flour, or any of the other well-known fillers used in the manufacture of coated abrasives. Suitable types of naturally derived glue can also be used as the size, although the product performance with glue sizes will normally not be as effective as with resin size, as is true in the absence of the additives disclosed hereo
- Still other conventionally known materials such as pigments or dyes, diluents for reducing viscosity, antifoam agents, etc. may be used together with the additives of this invention when needed or desired. No adverse interactions between such materials and the additives of this invention have been noted.
- a particularly important class of conventional components in amino resin adhesive formulations are the oxyamines useful for craze resistance as taught by Duke in U.S. Patent 2,983,593, the entire specification of which is hereby incorporated herein by reference. Use of adhesive compositions as taught by Duke, in combination with the additives of my invention, is preferred.
- Zelec NE which is neutral as supplied, could be added directly to a conventional formulation such as Example III of the Duke patent, after all the other ingredients listed there are mixed together.
- Zelec NK which is acidic, should first be neutralized, conveniently with 2-amino-2-methylpropanol, in a separate container, and the neutralized mixture then added to such a conventional formulation after all other ingredients had been added. All preceding and subsequent stages of manufacture of the coated abrasive may be carried out in a conventional manner.
- the minimum amount of additive to give a useful loading resistance effect was found to be that corresponding to a mass of 0.74 grams per square meter.
- An amount more than 10% by weight of the total sizing adhesive used is generally not desirable, because of probable decrease in the heat-distortion resistance of the sizing adhesive, with resultant danger of reduction of grinding effectiveness.
- the workable range is from 0.74 to 13.3 grams per square meter of additive, and the preferred range is from 1.2 to 3.5 grams per square meter. This can be conveniently achieved in most cases by using the additive at a level of 3-5% by weight of the resin or glue used.
- Size height levels for products coated with sizes containing the additives taught herein should generally conform to those for conventional products which are not to receive an additional third coatingo In any case, suitable levels can easily be determined if necessary by those skilled in the art of manufacturing coated abrasives.
- Table 2 illustrates examples of specific products prepared according to the methods of this invention
- organyl is used to include any chemical group which could be formed by the breaking of one valence bond in an organic compound.
- organyl includes the groups normally designated as alkyl, alkenyl, alkynyl, aryl such as phenyl, and combinations of and substitutions on the other simple groups, as well as a wide variety of others.
- long organyl refers to an organyl group which comprises at least eight carbon atoms bonded linearly to each other. The linear bonding may include double or triple as well as single carbon-carbon bonds.
- layer in the description of a body of adhesive material is to be considered to include any substantially continuous body of material of substantially uniform composition, with a projected area covering substantially all of the area of an abrasive backing. Because of the presence of abrasive grit particles in a coated abrasive, the layers of adhesive used in the construction thereof are expected to have very irregular outer surfaces rather than the smooth parallel surfaces normally suggested by the word layer in ordinary usageo As an example, the maker and sizer adhesive coats noted above in the brief description of the normal manufacturing process for a coated abrasive would constitute layers in the finished product, as would any separate coat of metallic soap intended to confer loading resistance.
- composition of an adhesive layer is intended to include any natural surface enrichment of a surface active material incorporated into the adhesive layer when it is applied in liquid form. Also, substantial continuity of an adhesive is not violated by the presence of normal flex cracks in a coated abrasive.
Abstract
- (a) animal giue, or a cured amino resin, or a mixture thereof in an amount of at least 40% by weight of the total adhesive bond material, exclusive of any filler; and
- (b) at least 0.74 grams per square meter of an additive which is
- (1) a mono-, di-, and tri-organyl ester of orthophosphoric acid,
- (2) a salt of a mono-, di-, and tri-organyl ester of orthophosphoric acid with an amine,
- (3) a tetraorganyiammonium sait, or
- (4) a soluble mixture thereof. Best results are obtained with a sizer adhesive of amino resin containing phosphate esters or their amine salts as additive.
Description
- The present invention relates to coated abrasives which consist of flexible backings to which are adhered a plurality of abrasive grit particles on at least one side. Coated abrasives are used primarily for the shaping, dimensioning, or surface finish alteration of other material objects known generally as workpieces. Small particles of material removed from the workpieces and/or shed from the coated abrasives during working are collectively called "swarf". In many cases, the swarf tends to wholly or partially adhere to the surface of the coated abrasive, eventually loading or clogging its abrasive surfaces and rendering it unsuited for further use. This invention relates particularly to coated abrasives which are specially resistant to such failure by loading.
- A common commercial practice for the preparation of coated abrasives which resist loading in the sanding of paints, primers, wood sealer coats, and a wide variety of other finishing compositions used on workpieces is essentially that described in U.S. Patent 2,768,886. This patent describes the preparation of coated abrasives which have a final grit- side surface coating of unfused metallic soaps applied preferably from dispersion of such soap in a volatile liquid. The application of this metallic soap is done as a separate coating step in addition to the normal making and sizing coating steps which are customarily used for achieving adherence of the abrasive grits to the backing. In some cases, it may be possible to prepare products with adequate properties without using a sizing adhesive. The need for an additional coating operation compared with most other coated abrasives imposes labor and material costs which it would obviously be advantageous to avoid.
- Since the publication of the above patent, there have been several other patents directed to other types of "third" coatings (i.e., coatings in addition to the two normal making and sizing ones) which would achieve loading- resistant coated abrasives. Examples include polyvinylacetate as disclosed in Canadian Patent 931,767, polytetrafluoroethene and mixtures thereof as disclosed in U.S. Patent 3,042,508, and mixtures of thermosetting resins, elastomers, and metallic soaps as disclosed in U.S. Patent 3,619,150.
- U.S. Patent 3,043,673 teaches the use of oxy- containing compounds either in a third coat or in the conventional sizing coat of a coated abrasive, together with an exceptionally high ratio of binder adhesive to grain, as an effective means for increasing the resistance of coated abrasives to loading in the finishing of leather and similar materials. The oxy compounds specified in this patent are all neutral organic compounds not expected to ionize in water solution. U.S. Patent 3,089,763 teaches the use of polyoxyalkylene compounds in the size of coated abrasives, and one of the objects stated is to reduce loading. However, the teaching of this U.S. Patent is restricted to sizing compositions in which the principal constituent is an amine catalyzed phenolic resin.
- It is a primary object of this invention to provide coated abrasives which are as resistant to loading as products with metallic soap third coats but which do not require an actual third coatingo Other objects will be apparent from the description below.
- It has been found that loading resistance can be imparted to otherwise conventional coated abrasives with size coats containing glue or amino resins by the incorporation into the size of small amounts of specific chemical compounds and mixtures as hereinafter described. These additives are total or partial alkyl esters of phosphoric acid, amine salts of partial esters of phosphoric acid, and quarternary ammonium salts with at least one long alkyl or substituted long alkyl group. Typical examples would be the triethanolamine salt of mono- or di- decylphosphate or stearamidopropyl-S-hydroxyethylammonium nitrate.
- In the studies which led to this invention, use was made of conventional coated abrasive backings, maker adhesives, and abrasive grits. The invention is applicable to any such products containing any such constituents, including the full range of grit sizes of normal commercial practice, comprising at least those with numerical designations of size from 12 to 600 as defined by the ANSI standard B74.18-1977. As is known to those skilled in the art, suitable constituents include but are not limited to papers of weights varying from 50 to 300 grams per square meter (gm/m2), suitably prepared (finished) cloth of a wide variety of types, and vulcanized fiber. Grits can be synthetic fused alumina, silicon carbide, garnet, zirconia alumina, emery, flint, or other materials, and maker adhesives can be film- forming starches, animal hide glue, amino resins, etc.
- The additives investigated which had detectable effect in reducing loading when used in the size coat are listed in Table. 1. These additives were most effective when used with amino resins such as urea-formaldehyde or melamine-formaldehydeo Such amino resins could be mixed in up to equal parts by weight with phenol-formaldehyde resins, one amino resin could be mixed with others, and any of the resins or mixtures could be filled with finely divided solids such as calcium sulfate, walnut shell flour, or any of the other well-known fillers used in the manufacture of coated abrasives. Suitable types of naturally derived glue can also be used as the size, although the product performance with glue sizes will normally not be as effective as with resin size, as is true in the absence of the additives disclosed hereo
- Still other conventionally known materials, such as pigments or dyes, diluents for reducing viscosity, antifoam agents, etc. may be used together with the additives of this invention when needed or desired. No adverse interactions between such materials and the additives of this invention have been noted. A particularly important class of conventional components in amino resin adhesive formulations are the oxyamines useful for craze resistance as taught by Duke in U.S. Patent 2,983,593, the entire specification of which is hereby incorporated herein by reference. Use of adhesive compositions as taught by Duke, in combination with the additives of my invention, is preferred.
- It should be noted that some of the additives shown in Table 1 are acidic and thus capable of catalyzing the cure of amino resins. However, such a practice would incur risk of shortened pot life of the amino resin, compared to use of the catalysts taught by Duke. Thus it is usually preferable in practicing my invention to neutralize the additive, if it is acidic, with a suitable amine or ammonium hydroxide before adding it to an amino resin adhesive formulation. When this is done, the resin adhesive with my additive can be cured with the same time and temperature program as is useful for the same resin without the additive. It is convenient to use one of the oxyamines taught by Duke to neutralize the additive of my invention if needed.
- For example, Zelec NE, which is neutral as supplied, could be added directly to a conventional formulation such as Example III of the Duke patent, after all the other ingredients listed there are mixed together. On the other hand, Zelec NK, which is acidic, should first be neutralized, conveniently with 2-amino-2-methylpropanol, in a separate container, and the neutralized mixture then added to such a conventional formulation after all other ingredients had been added. All preceding and subsequent stages of manufacture of the coated abrasive may be carried out in a conventional manner.
- The minimum amount of additive to give a useful loading resistance effect was found to be that corresponding to a mass of 0.74 grams per square meter. An amount more than 10% by weight of the total sizing adhesive used is generally not desirable, because of probable decrease in the heat-distortion resistance of the sizing adhesive, with resultant danger of reduction of grinding effectiveness. In general, the workable range is from 0.74 to 13.3 grams per square meter of additive, and the preferred range is from 1.2 to 3.5 grams per square meter. This can be conveniently achieved in most cases by using the additive at a level of 3-5% by weight of the resin or glue used.
- The additives listed in Table 1 all mixed readily with amino resins or glue suspensions to give liquid mixtures which were uniform as far as could be noted visually, although in some cases there was a hazy or milky appearance to the mixture, indicative of dispersion rather than true solution, There was no direct evidence during processing of any tendency of the adhesive mixtures containing the additives to develop inhomogeneities under normal conditions of coating, drying, or cure. However, it is expected from the chemical nature of the preferable additives, which contain both ionic bonds and at least one long organic chain in each molecule, that such additives may effectively reduce the surface tension of most liquid adhesives into which they are mixed. If such reduction in surface tension actually occurs, the well-known Gibbs equation for such surface active species predicts that the surface active component(s) will spontaneously distribute themselves at equilibrium so as to form a surface layer enriched in the surface active component. This spontaneous concentration of additive in the surface layer may explain why the minimum amount of additive required to obtain a detectable increase in loading resistance was found to be related to the area of the coated abrasive product rather than to the volume of adhesive.
- Size height levels for products coated with sizes containing the additives taught herein should generally conform to those for conventional products which are not to receive an additional third coatingo In any case, suitable levels can easily be determined if necessary by those skilled in the art of manufacturing coated abrasives.
- Table 2 illustrates examples of specific products prepared according to the methods of this invention
- The group of the four additives listed in Table 1 as Group A all appeared to be approximately equal in their ability to induce loading-resistance when added to amino resin sizes. Products with these additives in the size coat were tested in sanding of a wide variety of paints, metal primers, enamels, lacquers, varnishes, etc. and tound in general to have longer useful lives than previous standard commercial products made for sanding such workpieces. (Such commercial products normally have a third coating containing primarily zinc stearate or some other similar metallic soap.) The other additives shown in Table 1 are listed in groups of decreasing effectiveness in imparting loading-resistance to the size adhesives.
- In this specification and in the claims below, the term "organyl" is used to include any chemical group which could be formed by the breaking of one valence bond in an organic compound. Thus organyl includes the groups normally designated as alkyl, alkenyl, alkynyl, aryl such as phenyl, and combinations of and substitutions on the other simple groups, as well as a wide variety of others. The term "long organyl" refers to an organyl group which comprises at least eight carbon atoms bonded linearly to each other. The linear bonding may include double or triple as well as single carbon-carbon bonds. The term "layer" in the description of a body of adhesive material is to be considered to include any substantially continuous body of material of substantially uniform composition, with a projected area covering substantially all of the area of an abrasive backing. Because of the presence of abrasive grit particles in a coated abrasive, the layers of adhesive used in the construction thereof are expected to have very irregular outer surfaces rather than the smooth parallel surfaces normally suggested by the word layer in ordinary usageo As an example, the maker and sizer adhesive coats noted above in the brief description of the normal manufacturing process for a coated abrasive would constitute layers in the finished product, as would any separate coat of metallic soap intended to confer loading resistance. It should be further noted that substantial uniformity of composition of an adhesive layer is intended to include any natural surface enrichment of a surface active material incorporated into the adhesive layer when it is applied in liquid form. Also, substantial continuity of an adhesive is not violated by the presence of normal flex cracks in a coated abrasive.
-
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT82105371T ATE28813T1 (en) | 1981-08-10 | 1982-06-18 | COATED ABRASIVE. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US29120581A | 1981-08-10 | 1981-08-10 | |
US291205 | 1981-08-10 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0071723A2 true EP0071723A2 (en) | 1983-02-16 |
EP0071723A3 EP0071723A3 (en) | 1984-09-05 |
EP0071723B1 EP0071723B1 (en) | 1987-08-12 |
Family
ID=23119334
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP82105371A Expired EP0071723B1 (en) | 1981-08-10 | 1982-06-18 | Coated abrasive |
Country Status (12)
Country | Link |
---|---|
EP (1) | EP0071723B1 (en) |
JP (1) | JPS5851078A (en) |
AT (1) | ATE28813T1 (en) |
AU (1) | AU557187B2 (en) |
BR (1) | BR8204145A (en) |
CA (1) | CA1192050A (en) |
DD (1) | DD202255A5 (en) |
DE (2) | DE3276931D1 (en) |
ES (1) | ES513995A0 (en) |
MX (1) | MX160757A (en) |
YU (1) | YU154482A (en) |
ZA (1) | ZA824334B (en) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0398580A1 (en) * | 1989-05-15 | 1990-11-22 | Minnesota Mining And Manufacturing Company | Abrasive article with conductive, doped, conjugated, polymer, supersize coat and method of making same |
EP0408943A1 (en) * | 1989-06-29 | 1991-01-23 | Norton Company | Coated abrasives with anti-static supersize coat |
EP0414346A1 (en) * | 1989-06-23 | 1991-02-27 | Minnesota Mining And Manufacturing Company | Coated abrasive article overcoated with loading resistant top layer |
WO1997014535A1 (en) * | 1995-10-20 | 1997-04-24 | Minnesota Mining And Manufacturing Company | Abrasive article containing an inorganic metal orthophosphate |
WO1997042006A1 (en) * | 1996-05-08 | 1997-11-13 | Minnesota Mining And Manufacturing Company | Antiloading components for abrasive articles |
US5702811A (en) * | 1995-10-20 | 1997-12-30 | Ho; Kwok-Lun | High performance abrasive articles containing abrasive grains and nonabrasive composite grains |
US5738695A (en) * | 1995-10-20 | 1998-04-14 | Minnesota Mining And Manufacturing Company | Abrasive article containing an inorganic phosphate |
WO1998058769A1 (en) * | 1997-06-24 | 1998-12-30 | Minnesota Mining And Manufacturing Company | Abrasive articles including and antiloading composition |
US6039775A (en) * | 1997-11-03 | 2000-03-21 | 3M Innovative Properties Company | Abrasive article containing a grinding aid and method of making the same |
US6270543B1 (en) | 1997-10-02 | 2001-08-07 | 3M Innovative Properties Company | Abrasive article containing an inorganic metal orthophosphate |
CN1092095C (en) * | 1996-05-08 | 2002-10-09 | 明尼苏达矿业和制造公司 | Abrasive article comprising antiloading component |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111843867B (en) * | 2020-08-07 | 2022-02-22 | 惠州市瑞丰研磨材料有限公司 | Sand coating device for sand paper production |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE494833A (en) * | ||||
US1591001A (en) * | 1925-05-12 | 1926-06-29 | Us Sand Paper Company | Sheet abrasive material |
DE818863C (en) * | 1942-10-06 | 1951-10-29 | Behr Manning Corp | Sandpaper and emery cloth |
US2983593A (en) * | 1959-03-02 | 1961-05-09 | Norton Co | Adhesive compositions and products |
DE1646824A1 (en) * | 1967-12-28 | 1969-09-18 | Norddeutsche Schleifmittel Ind | Abrasives |
DE2226744A1 (en) * | 1972-06-02 | 1973-12-20 | Ver Schmirgel & Maschf | Grinding wheel compsn - with substrate having varying bonding thickne |
FR2330504A1 (en) * | 1975-11-10 | 1977-06-03 | Durrschmidt Ets G | Grinding tools contg. filler imparting limited flexure - for grinding workpieces and for imparting very high surface finish |
DE2720829A1 (en) * | 1977-05-09 | 1978-11-23 | Carl Hilzinger Thum Fa | Plasticised polyvinyl acetate emulsion binder impregnant - used in mfr. of flexible fibrous buffing wheel |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US298359A (en) * | 1884-05-13 | Paint-brush | ||
US3043673A (en) * | 1958-11-17 | 1962-07-10 | Minnesota Mining & Mfg | Fill-resistant flexible abrasive sheet |
US3089763A (en) * | 1959-04-15 | 1963-05-14 | Norton Co | Coated abrasives |
JPS5115858B2 (en) * | 1972-04-17 | 1976-05-20 |
-
1982
- 1982-05-21 CA CA000403506A patent/CA1192050A/en not_active Expired
- 1982-06-18 EP EP82105371A patent/EP0071723B1/en not_active Expired
- 1982-06-18 AT AT82105371T patent/ATE28813T1/en not_active IP Right Cessation
- 1982-06-18 DE DE8282105371T patent/DE3276931D1/en not_active Expired
- 1982-06-18 ZA ZA824334A patent/ZA824334B/en unknown
- 1982-06-18 DE DE198282105371T patent/DE71723T1/en active Pending
- 1982-06-21 AU AU85056/82A patent/AU557187B2/en not_active Ceased
- 1982-06-28 JP JP57110075A patent/JPS5851078A/en active Granted
- 1982-07-07 MX MX193484A patent/MX160757A/en unknown
- 1982-07-15 YU YU01544/82A patent/YU154482A/en unknown
- 1982-07-15 ES ES513995A patent/ES513995A0/en active Granted
- 1982-07-16 DD DD82241726A patent/DD202255A5/en unknown
- 1982-07-16 BR BR8204145A patent/BR8204145A/en unknown
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE494833A (en) * | ||||
US1591001A (en) * | 1925-05-12 | 1926-06-29 | Us Sand Paper Company | Sheet abrasive material |
DE818863C (en) * | 1942-10-06 | 1951-10-29 | Behr Manning Corp | Sandpaper and emery cloth |
US2983593A (en) * | 1959-03-02 | 1961-05-09 | Norton Co | Adhesive compositions and products |
DE1646824A1 (en) * | 1967-12-28 | 1969-09-18 | Norddeutsche Schleifmittel Ind | Abrasives |
DE2226744A1 (en) * | 1972-06-02 | 1973-12-20 | Ver Schmirgel & Maschf | Grinding wheel compsn - with substrate having varying bonding thickne |
FR2330504A1 (en) * | 1975-11-10 | 1977-06-03 | Durrschmidt Ets G | Grinding tools contg. filler imparting limited flexure - for grinding workpieces and for imparting very high surface finish |
DE2720829A1 (en) * | 1977-05-09 | 1978-11-23 | Carl Hilzinger Thum Fa | Plasticised polyvinyl acetate emulsion binder impregnant - used in mfr. of flexible fibrous buffing wheel |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0398580A1 (en) * | 1989-05-15 | 1990-11-22 | Minnesota Mining And Manufacturing Company | Abrasive article with conductive, doped, conjugated, polymer, supersize coat and method of making same |
EP0414346A1 (en) * | 1989-06-23 | 1991-02-27 | Minnesota Mining And Manufacturing Company | Coated abrasive article overcoated with loading resistant top layer |
EP0408943A1 (en) * | 1989-06-29 | 1991-01-23 | Norton Company | Coated abrasives with anti-static supersize coat |
US5738695A (en) * | 1995-10-20 | 1998-04-14 | Minnesota Mining And Manufacturing Company | Abrasive article containing an inorganic phosphate |
US5702811A (en) * | 1995-10-20 | 1997-12-30 | Ho; Kwok-Lun | High performance abrasive articles containing abrasive grains and nonabrasive composite grains |
WO1997014535A1 (en) * | 1995-10-20 | 1997-04-24 | Minnesota Mining And Manufacturing Company | Abrasive article containing an inorganic metal orthophosphate |
US5840090A (en) * | 1995-10-20 | 1998-11-24 | Minnesota Mining And Manufacturing | High performance abrasive articles containing abrasive grains and nonabrasive composite grains |
US5961674A (en) * | 1995-10-20 | 1999-10-05 | 3M Innovative Properties Company | Abrasive article containing an inorganic metal orthophosphate |
WO1997042006A1 (en) * | 1996-05-08 | 1997-11-13 | Minnesota Mining And Manufacturing Company | Antiloading components for abrasive articles |
CN1066996C (en) * | 1996-05-08 | 2001-06-13 | 美国3M公司 | Antiloading components for abrasive articles |
CN1092095C (en) * | 1996-05-08 | 2002-10-09 | 明尼苏达矿业和制造公司 | Abrasive article comprising antiloading component |
WO1998058769A1 (en) * | 1997-06-24 | 1998-12-30 | Minnesota Mining And Manufacturing Company | Abrasive articles including and antiloading composition |
US6270543B1 (en) | 1997-10-02 | 2001-08-07 | 3M Innovative Properties Company | Abrasive article containing an inorganic metal orthophosphate |
US6039775A (en) * | 1997-11-03 | 2000-03-21 | 3M Innovative Properties Company | Abrasive article containing a grinding aid and method of making the same |
Also Published As
Publication number | Publication date |
---|---|
CA1192050A (en) | 1985-08-20 |
DE3276931D1 (en) | 1987-09-17 |
DE71723T1 (en) | 1983-09-29 |
JPS5851078A (en) | 1983-03-25 |
DD202255A5 (en) | 1983-09-07 |
EP0071723A3 (en) | 1984-09-05 |
ES8402609A1 (en) | 1984-02-01 |
ATE28813T1 (en) | 1987-08-15 |
AU557187B2 (en) | 1986-12-11 |
JPH0355271B2 (en) | 1991-08-22 |
MX160757A (en) | 1990-05-09 |
ES513995A0 (en) | 1984-02-01 |
EP0071723B1 (en) | 1987-08-12 |
ZA824334B (en) | 1983-04-27 |
BR8204145A (en) | 1983-07-12 |
AU8505682A (en) | 1983-02-17 |
YU154482A (en) | 1985-10-31 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4396403A (en) | Loading resistant coated abrasive | |
EP0071723B1 (en) | Coated abrasive | |
AU2008302173B2 (en) | Phenolic resin formulation and coatings for abrasive products | |
US8979957B2 (en) | Melamine methylol for abrasive products | |
US5011512A (en) | Coated abrasive products employing nonabrasive diluent grains | |
CN103282395A (en) | Low free formaldehyde phenolic resins for abrasive products | |
EP0660850B1 (en) | Coated abrasives made using coatable urea-aldehyde compositions containing a cocatalyst, and methods of making coated abrasives | |
US3321287A (en) | Method of impregnating lubricant into abrasive wheels | |
US3360391A (en) | Process for the production of corrosion resistant and highly wearresistant coated surface and the coated surface | |
CN101613570B (en) | Colored gorgeous texture floor coating and construction method thereof | |
US2893854A (en) | Coated abrasive article and method of manufacture | |
US3205054A (en) | Abrasive coated material | |
US2706936A (en) | Anti-skid surface covering | |
CN209579263U (en) | A kind of precise numerical control grinder abrasive band water proof abrasive cloth | |
JPH0464308B2 (en) | ||
US2205438A (en) | Adhesive abrasive composition | |
US1576122A (en) | Abrasive article | |
CN107639553A (en) | A kind of high abrasion folding molding sand paper and its forming technique | |
US3387955A (en) | Abrasive coated products | |
US1963339A (en) | Air vulcanizable rubber compound and method of manufacture | |
CN1839037B (en) | Time released curing system | |
US20050070646A1 (en) | Time released curing system | |
CN107584435A (en) | A kind of high adhesion force sand paper and its forming technique |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Designated state(s): AT CH DE FR GB IT LI SE |
|
EL | Fr: translation of claims filed | ||
DET | De: translation of patent claims | ||
PUAL | Search report despatched |
Free format text: ORIGINAL CODE: 0009013 |
|
AK | Designated contracting states |
Designated state(s): AT CH DE FR GB IT LI SE |
|
17P | Request for examination filed |
Effective date: 19850131 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT CH DE FR GB IT LI SE |
|
REF | Corresponds to: |
Ref document number: 28813 Country of ref document: AT Date of ref document: 19870815 Kind code of ref document: T |
|
ITF | It: translation for a ep patent filed |
Owner name: ING. C. GREGORJ S.P.A. |
|
REF | Corresponds to: |
Ref document number: 3276931 Country of ref document: DE Date of ref document: 19870917 |
|
ET | Fr: translation filed | ||
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed | ||
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: CH Payment date: 19890509 Year of fee payment: 8 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 19890519 Year of fee payment: 8 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: SE Payment date: 19890522 Year of fee payment: 8 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 19890531 Year of fee payment: 8 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: AT Payment date: 19890601 Year of fee payment: 8 |
|
ITTA | It: last paid annual fee | ||
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Effective date: 19900618 Ref country code: AT Effective date: 19900618 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Effective date: 19900619 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Effective date: 19900630 Ref country code: CH Effective date: 19900630 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee | ||
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DE Effective date: 19910301 |
|
EUG | Se: european patent has lapsed |
Ref document number: 82105371.7 Effective date: 19910206 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20010531 Year of fee payment: 20 |