EP0097149A1 - Process for increasing the water discharge of water delivering drilled wells - Google Patents
Process for increasing the water discharge of water delivering drilled wellsInfo
- Publication number
- EP0097149A1 EP0097149A1 EP82900127A EP82900127A EP0097149A1 EP 0097149 A1 EP0097149 A1 EP 0097149A1 EP 82900127 A EP82900127 A EP 82900127A EP 82900127 A EP82900127 A EP 82900127A EP 0097149 A1 EP0097149 A1 EP 0097149A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- acid
- well
- water
- dissociation constant
- hours
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 238000000034 method Methods 0.000 title claims abstract description 22
- 239000002253 acid Substances 0.000 claims abstract description 16
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims abstract description 12
- 150000007513 acids Chemical class 0.000 claims abstract description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000010494 dissociation reaction Methods 0.000 claims abstract description 9
- 230000005593 dissociations Effects 0.000 claims abstract description 9
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims abstract description 6
- 235000017557 sodium bicarbonate Nutrition 0.000 claims abstract description 6
- 239000005708 Sodium hypochlorite Substances 0.000 claims abstract description 4
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims abstract description 4
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000011975 tartaric acid Substances 0.000 claims abstract description 4
- 235000002906 tartaric acid Nutrition 0.000 claims abstract description 4
- VGTPKLINSHNZRD-UHFFFAOYSA-N oxoborinic acid Chemical compound OB=O VGTPKLINSHNZRD-UHFFFAOYSA-N 0.000 claims abstract description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 12
- 230000002000 scavenging effect Effects 0.000 claims description 11
- 238000011010 flushing procedure Methods 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 6
- XDVOLDOITVSJGL-UHFFFAOYSA-N 3,7-dihydroxy-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound O1B(O)OB2OB(O)OB1O2 XDVOLDOITVSJGL-UHFFFAOYSA-N 0.000 abstract description 4
- 238000001914 filtration Methods 0.000 abstract description 4
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 abstract description 2
- 230000006835 compression Effects 0.000 abstract description 2
- 238000007906 compression Methods 0.000 abstract description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 14
- 230000000694 effects Effects 0.000 description 8
- 238000005086 pumping Methods 0.000 description 8
- 229960000443 hydrochloric acid Drugs 0.000 description 7
- 235000011167 hydrochloric acid Nutrition 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 230000000149 penetrating effect Effects 0.000 description 4
- 230000035699 permeability Effects 0.000 description 4
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 2
- 230000000254 damaging effect Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 241001503485 Mammuthus Species 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- CEALXSHFPPCRNM-UHFFFAOYSA-L disodium;carboxylato carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OC([O-])=O CEALXSHFPPCRNM-UHFFFAOYSA-L 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 150000002506 iron compounds Chemical class 0.000 description 1
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D29/00—Filters with filtering elements stationary during filtration, e.g. pressure or suction filters, not covered by groups B01D24/00 - B01D27/00; Filtering elements therefor
- B01D29/62—Regenerating the filter material in the filter
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/52—Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning
- C09K8/528—Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning inorganic depositions, e.g. sulfates or carbonates
Definitions
- the invention relates to a process for increasing the water discharge of water delivering drilled wells in case of the decrease of the water discharge with wells having been exploited for a longer period, furtheron in case of new wells having been deepened with mud, for restoring i.e. increasing the water permeability of the original rocks by reducing the well-resistance, by using a chemical treatment.
- the water discharge of the water delivering drilled wells depends in addition to the layer conditions on the mode of the well formation, the age of the well, the methods of water production and on the quality of water.
- Themode of well formation includes the structural solutions to be applied, e.g. the piping, the arrangement and construction of the filter, as well as the drilling methods and pumping with the purpose of cleaning being utmost important from the point of view of water discharge.
- the pumping serving for purification may decisively influence the quality of well formation, which can be characterized numerically by the wellresistance.
- the components of well-resistance a re the following: the dam effect, i.e.
- the changed resistance of the zone around the well the layer resistance, the filter resistance, the resistance resulting from the instrustation, the resistance-surplus of a more or less turbulent stream - compared to the linear stream - at higher flow velocities and at least the flow resistance of the piping in the well.
- the increase of the water discharge can be achieved by the considerable decrease of the dam effect - the more, by converting it into an effect with a different sign (achieving a lower resistance in the zone around the well, than the original one), by the reduction of the resistance resulting from incrustation and indirectly by the reduction of the resistance-surplus of the turbulent stream.
- detrimental effects of the mud can be eliminated by removing the mud increasing the layer resistance with a high efficiency from the infiltered zone and by increasing the original water permeability of the confining zone.
- Incrustation i.e. clogging is caused by the deposition of different compounds; said compounds contain mainly iron and calcium in form of carbonates, oxydes, hydroxydes, sulfates and silicates. Due to biological effects, e.g. as a consequence of the activity of iron- and manganese bacteria organic compounds may also deposit.
- the rate of incrustation is increasing in dependence of the age of the well, at the same time the mode of operation and the quality of water are also considerably influencing the rate of incrustation.
- the so-called “ochre-formation” is of the largest extent, accordingly, it is to be considered as the most dangerous phenomenon; in course of this process iron compounds, mainly ferric(III)hydroxyde are segregated.
- hydrochloric acid is highly damaging all the fittings made of iron.
- Improvement of wells with a reduced water discharge is mostly performed by using hydrochloric acid (Technical Directives of the Office of Water conserveancy, 136/4-73/4.2).
- the layer purification with hydrochloric acid is causing corrosional damages in the metal parts and in case of glassf ⁇ bre reinforced synthetic casing pipes the risk is extraordinarily high and may lead to the early ageing of the well.
- the advantageous effect of the weak acids may be explained probably by the fact that said acids dissolve far slower the carbonates and oxydes, than the hydrochloric acid, accordingly, they are penetrating far deeper into the zones confining the filter.
- the slower dissolution is accompanied by a less vigorous gas formation, as a consequence, the danger of layer collapse is also less.
- the weak acids having been used in course of the process according to the invention do not destruct the material of the filter and the pipes, the mechanical properties of the glassfibre-reinforced synthetic pipes are not deteriorated either.
- the treatment having the character of an alkaline reaction i.e. using the sodium hypochlorite and/or sodium bicarbonate solutions after the treatment with the acids is highly increasing the efficiency of the process according to the invention, in the majority of cases a productivity far excessing the original one could be achieved.
- Example 1 The well having been started in 1938 with an initial water discharge of 180 1/min (MALEV well II), with no yield at the start of the process, was subjected to a frad.it ⁇ onal treatment for 48 hours by using a Mammoth-pump and a compressor. As a result of the treatment a water discharge of 120 1/minute could be obtained. Thereafter, through the pipe penetrating to the filter concentrated acidic acid in a quantity of 1o kg was introduced Into the well; in the following operational phase, through the closed well-head, air pressure of 3 to 5 bar was produced for four hours by means of a compressor; after a pressure-free period lasting an hour, a pressure of 7 bar and of the duration of six hours was applied onto the well.
- MALEV well II initial water discharge of 180 1/min
- the concentrated aquaeous solution of 15 Kg tartaric acid was introduced through the pipe penetrating to the filter. After a dwelling period of 24 hours and compressing, flushing by means of a scavenging pump was performed, thereafter the solution of sodium bicarbonate (5 kg sodium bicarbonate have been diluted with 4o litres water) was introduced into the filter zone. After a dwelling period of six hours scavenging was performed. After the chemical treatment the water discharge of the well amounted to 1750 1/m ⁇ nute, being by 25 % higher, than the original yield.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Cleaning By Liquid Or Steam (AREA)
Abstract
Procédé d'augmentation du débit d'eau de puits produisant de l'eau, caractérisé en ce que dans la section de filtration du puits des acides faibles sont introduits lesquels ont une constante de dissociation inférieure à Kd = 10-3. Après une période de résidence de longue durée, de préférence de 10 à 48 heures, ainsi qu'une période de compression, la chasse s'effectue à l'aide d'une pompe à refoulement. Ensuite, la solution de bicarbonate de sodium et/ou d'hypochlorite de sodium est introduite dans la section filtrante. Après une période de résidence longue, de préférence d'1 à 36 heures, la chasse s'effectue à l'aide de la pompe à refoulement. De l'acide acétique, de l'acide tartarique, de l'acide cytrique, de l'acide métaborique et/ou de l'acide tétraborique peuvent être utilisés comme acides faibles ayant une constante de dissociation inférieure à Kd = 10-3.Method for increasing the flow rate of water producing wells, characterized in that weak acids are introduced into the filtration section of the well which have a dissociation constant lower than Kd = 10-3. After a long period of residence, preferably 10 to 48 hours, as well as a period of compression, hunting is carried out using a discharge pump. Then, the solution of sodium bicarbonate and / or sodium hypochlorite is introduced into the filtering section. After a long period of residence, preferably 1 to 36 hours, hunting is carried out using the discharge pump. Acetic acid, tartaric acid, cytric acid, metaboric acid and / or tetraboric acid can be used as weak acids having a dissociation constant less than Kd = 10-3.
Description
Process for increasing the water discharge of water delivering drilled wells
Technical field
The invention relates to a process for increasing the water discharge of water delivering drilled wells in case of the decrease of the water discharge with wells having been exploited for a longer period, furtheron in case of new wells having been deepened with mud, for restoring i.e. increasing the water permeability of the original rocks by reducing the well-resistance, by using a chemical treatment.
Background art
As it is a well known fact, the water discharge of the water delivering drilled wells depends in addition to the layer conditions on the mode of the well formation, the age of the well, the methods of water production and on the quality of water.
Themode of well formation includes the structural solutions to be applied, e.g. the piping, the arrangement and construction of the filter, as well as the drilling methods and pumping with the purpose of cleaning being utmost important from the point of view of water discharge. The pumping serving for purification may decisively influence the quality of well formation, which can be characterized numerically by the wellresistance. As it is known, the components of well-resistance a re the following: the dam effect, i.e. the changed resistance of the zone around the well, the layer resistance, the filter
resistance, the resistance resulting from the instrustation, the resistance-surplus of a more or less turbulent stream - compared to the linear stream - at higher flow velocities and at least the flow resistance of the piping in the well.
By the application of the process according to the invention the increase of the water discharge can be achieved by the considerable decrease of the dam effect - the more, by converting it into an effect with a different sign (achieving a lower resistance in the zone around the well, than the original one), by the reduction of the resistance resulting from incrustation and indirectly by the reduction of the resistance-surplus of the turbulent stream.
In course of well formation the optimal development of the zone around the well is of utmost importance. This represents an especially difficult task, when flush-dril I Ing is applied, since the mud is penetrating into the zone around the well in a depth of 10 to 50 cm and reduces water permeability of the confining zone. Water permeability may be considerably decreased, it may even reach the fhousandth-fenthousandth of the original value.
In accordance with the invention detrimental effects of the mud can be eliminated by removing the mud increasing the layer resistance with a high efficiency from the infiltered zone and by increasing the original water permeability of the confining zone.
It is a fact of common knowledge, that the resistance of the zone around the filter can be reduced by pumping, for this purpose the so-called Mammoth pump or a compressor is used. The pumping method in itself
is rarely yielding satisfactory results and in particular it used to be unsuccessful, when the infiltrate contains bentonϊte. In the majority of cases the reason for the insufficient effect of pumping is, that the pressure drop in the well is not entirely breaking up the conglomerated mud layer in the clogged zone around the filter, but only on certain places. The water streaming along the lowest resistance in the initially small channels having been formed in such a manner - is forming more and more larger ducts resulting finally in the collapse of the layer. In this case the whole cleaning process is to be repeated.
Incrustation, i.e. clogging is caused by the deposition of different compounds; said compounds contain mainly iron and calcium in form of carbonates, oxydes, hydroxydes, sulfates and silicates. Due to biological effects, e.g. as a consequence of the activity of iron- and manganese bacteria organic compounds may also deposit. The rate of incrustation is increasing in dependence of the age of the well, at the same time the mode of operation and the quality of water are also considerably influencing the rate of incrustation. The so-called "ochre-formation" is of the largest extent, accordingly, it is to be considered as the most dangerous phenomenon; in course of this process iron compounds, mainly ferric(III)hydroxyde are segregated. According to our experiences, the intensity of draw-off is playing an important role in ochre-formation. The partial or total turbulence arising with higher flow velocities considerably increases the rate of ochre-formation, while with wells being out of operation ochre-formation usually could not be observed.
In order to be able to eliminate the layer purification by means of pumping, mostly a treatment with hydro-chloric acid has been used (E. Bieske: Handbuch des Brunnenbaus, Berlin, 1965). Hydrochloric acid dissolves the oxydes and carbonates and elution of the ferrous and calciferous deposits in form of chlorides from the filter zone becomes possible. However, treatment with hydrochloric acid may be disadvantageous in several cases, e.g. where the relatively rapid and strong dissolving effect may result in the collapse of layers, in addition to this, due to its metal dissolving effect, hydrochloric acid is highly damaging all the fittings made of iron. In spite of the known damaging effects, Improvement of wells with a reduced water discharge is mostly performed by using hydrochloric acid (Technical Directives of the Office of Water Conservancy, 136/4-73/4.2). The layer purification with hydrochloric acid is causing corrosional damages in the metal parts and in case of glassfϊbre reinforced synthetic casing pipes the risk is extraordinarily high and may lead to the early ageing of the well.
Disclosure of Invention In course of our examinations aiming the elimination of the disadvantageous features of the known processes serving for the increase of the water discharge of drilled wells, we have found, that the water discharge of the drilled wells can be increased with a surprisingly good result - with a yield mostly surpassing the original one - by introducing weak acids into the filtering section, the dissociation constant of which is less, than Kd = l0-3 and after a longer dwelling period, expediently 1o to 48 hours and compression, flushing by means of a scavenging
pump is performed. Thereafter, the solution of sodium dicarbonate and/or sodium hypochlorite is introduced into the filtering section. After a longer dwelling period, expediently lasting 1 to 36 hours, repeated flushing is performed by means of the scaveng ing pump.
The weak acids to be used in course of the process according to the invention, having a dissociation constant less than Kd = 10-3 are the following: acetic acid, citric acid, tartaric acid, metaboric acid and tetraboric acid, all are giving excellent results (Lengyel, Proszt, Szarvas: General and Organic Chemis-try, Budapest, 1960, pp. 198-201). Very weak acids, as e.g. orthobor icaci d, require a dwelling period of several days for yielding proper results.
The advantageous effect of the weak acids may be explained probably by the fact that said acids dissolve far slower the carbonates and oxydes, than the hydrochloric acid, accordingly, they are penetrating far deeper into the zones confining the filter. The slower dissolution is accompanied by a less vigorous gas formation, as a consequence, the danger of layer collapse is also less.
The weak acids having been used in course of the process according to the invention do not destruct the material of the filter and the pipes, the mechanical properties of the glassfibre-reinforced synthetic pipes are not deteriorated either.
According to our experiences, the treatment having the character of an alkaline reaction, i.e. using the sodium hypochlorite and/or sodium
bicarbonate solutions after the treatment with the acids is highly increasing the efficiency of the process according to the invention, in the majority of cases a productivity far excessing the original one could be achieved.
Best Mode of Carrying out the Invention
The process according to the invention will be explained in details by the way of examples.
Example 1 The well having been started in 1938 with an initial water discharge of 180 1/min (MALEV well II), with no yield at the start of the process, was subjected to a frad.itϊonal treatment for 48 hours by using a Mammoth-pump and a compressor. As a result of the treatment a water discharge of 120 1/minute could be obtained. Thereafter, through the pipe penetrating to the filter concentrated acidic acid in a quantity of 1o kg was introduced Into the well; in the following operational phase, through the closed well-head, air pressure of 3 to 5 bar was produced for four hours by means of a compressor; after a pressure-free period lasting an hour, a pressure of 7 bar and of the duration of six hours was applied onto the well. After having scavenged the well with the pump for an hour, loo litres of commercially available hypo-solution were introduced into the well; after a dwelling period of eight hours cleaning was performed by means of the scavenging pump. After a treatment with chemicals the water discharge of the well could be incresed to 900 1/mϊnutes, amounting to the fivefold of the original yield and to the seven and half-fold of the value having been obtained by the traditional pumping process.
Example 2
Into the well having been started in 1938, with an original water discharge of 1400 1 /minute, the concentrated aquaeous solution of 15 Kg tartaric acid was introduced through the pipe penetrating to the filter. After a dwelling period of 24 hours and compressing, flushing by means of a scavenging pump was performed, thereafter the solution of sodium bicarbonate (5 kg sodium bicarbonate have been diluted with 4o litres water) was introduced into the filter zone. After a dwelling period of six hours scavenging was performed. After the chemical treatment the water discharge of the well amounted to 1750 1/mϊnute, being by 25 % higher, than the original yield.
Example 3
Into a 40 years old well of the depth of 300 m with no water discharge at all, into the filter zone the solution of citric acid (30 kg citric acid have been dissolved in 200 I water) introduced. After a dwelling period of 36 hours and compressing, flushing was performed by means of a scavenging pump and 100 liters commercially available hypo- -solution were introduced into the well. After a dwelling period of eight hours, scavenging pumping was performed. As a consequence of the chemical treatment the water discharge amounted to 600 1/minute, equalling about to the double of the original yield.
Example 4
Into a well of the depth of 150 m, having been deepened with mud and with a water discharge of 190 1/minute, following the traditional treatment,
the solution of tetraboric acid (1 kg tetraboric acid has been dissolved in 20 I warm water) was introduced into the well. After a dwelling time of 48 hours and compressing, flushing by means of the scavenging pump was performed, thereafter 5 kg sodium bicarbonate having been dissolved in 40 I water were introduced into the filter zone. After two hours of compressing and the following cleaning with the scavenging pump the water discharge amounted to 280 1/mϊnute, equalling to nearly one and a half of the water discharge having been measured prior to the chemical treatment.
Claims
1. Process for increasing the water discharge of water delivering drilled wells by using a chemical treatment, c h a r a c t e r i z e d in that into the filter section of the well weak acids are introduced, the dissociation constant of which is less, than Kd = l0-3 and after a dwelling period of longer duration, expediently 1o to 48 hours, as well as compressing, flushing is performed by means of a scavenging pump, thereafter the soluion of sodium bicarbonate and/or sodium hypochlorite is introduced into the filter section; after a dwelling time of longer duration, expediently 1 to 36 hours, flushing is performed by means of a scavenging pump.
2. Process as claimed in claim 1, c h a r a c t e r i z e d in that as a weak acid with a dissociation constant being less than Kd = l0-3 acetic acid is used.
3. Process as claimed in claim 1, c h a r a c t e r i z e d in that as a weak acid with a dissociation constant being less than Kd = l0-3 tartaric acid is used,
4. Process as claimed in claim 1, c h a r a c t e r i z e d in that as a weak acid with a dissociation constant being less than Kd = l0-3 citric acid is used.
5. Process as claimed in claim 1, c h a r a c t e r i z e d in that as a weak acid with a dissociation constant being less than Kd = l0-3 metaboric acid and/or tetraboric acidis used .
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/HU1981/000049 WO1983002296A1 (en) | 1981-12-23 | 1981-12-23 | Process for increasing the water discharge of water delivering drilled wells |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0097149A1 true EP0097149A1 (en) | 1984-01-04 |
| EP0097149A4 EP0097149A4 (en) | 1985-06-06 |
Family
ID=10980426
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19820900127 Withdrawn EP0097149A4 (en) | 1981-12-23 | 1981-12-23 | Process for increasing the water discharge of water delivering drilled wells. |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4541488A (en) |
| EP (1) | EP0097149A4 (en) |
| JP (1) | JPS59500323A (en) |
| BR (1) | BR8109052A (en) |
| WO (1) | WO1983002296A1 (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4778006A (en) * | 1987-05-04 | 1988-10-18 | Derowitsch Richard W | Process for removing carbonate from wells |
| US5203834A (en) * | 1990-12-21 | 1993-04-20 | Union Oil Company Of California | Foamed gels having selective permeability |
| US5145012A (en) * | 1990-12-21 | 1992-09-08 | Union Oil Company Of California | Method for selectively reducing subterranean water permeability |
| US5268112A (en) * | 1990-12-21 | 1993-12-07 | Union Oil Company Of California | Gel-forming composition |
| US5291950A (en) * | 1992-08-27 | 1994-03-08 | Petrosakh U.S.A. | Method of well treatment |
| GB9308884D0 (en) * | 1993-04-29 | 1993-06-16 | Archaeus Tech Group | Acidising oil reservoirs |
| US10068484B2 (en) * | 2017-01-23 | 2018-09-04 | Garden Technologies Llc | Parking assisting device |
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|---|---|---|---|---|
| US2425415A (en) * | 1945-12-05 | 1947-08-12 | Pure Oil Co | Acidizing earth bores |
| US3122503A (en) * | 1961-03-20 | 1964-02-25 | Dow Chemical Co | Dispersing clayey deposits |
| US3441085A (en) * | 1967-09-07 | 1969-04-29 | Exxon Production Research Co | Method for acid treating carbonate formations |
| US3556221A (en) * | 1969-01-06 | 1971-01-19 | Marathon Oil Co | Well stimulation process |
| US4325433A (en) * | 1980-06-27 | 1982-04-20 | University Of Southern California | Pre-caustic flood treatment |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1984668A (en) * | 1934-03-10 | 1934-12-18 | Alfred W Knight | Method of cleaning the walls of mudded bore-holes |
| US2045899A (en) * | 1935-04-30 | 1936-06-30 | Texas Co | Method of increasing production from wells |
| US2059459A (en) * | 1936-06-05 | 1936-11-03 | Walter J Hund | Method of treating wells with acids |
| US2852077A (en) * | 1955-04-27 | 1958-09-16 | Nat Aluminate Corp | Process of improving and maintaining the water permeability of geological formations |
| US2933137A (en) * | 1957-04-10 | 1960-04-19 | Ranney Method Water Supplies I | Plastic well screen and wells utilizing the screens and method of operation |
| US2978026A (en) * | 1958-01-07 | 1961-04-04 | California Research Corp | Well wash fluid |
| US3307630A (en) * | 1964-06-12 | 1967-03-07 | Shell Oil Co | Acidizing oil formations |
| US3482636A (en) * | 1967-04-06 | 1969-12-09 | Dow Chemical Co | Method of lessening the inhibitory effects to fluid flow due to the presence of solid organic substances in a subterranean formation |
-
1981
- 1981-12-23 EP EP19820900127 patent/EP0097149A4/en not_active Withdrawn
- 1981-12-23 WO PCT/HU1981/000049 patent/WO1983002296A1/en not_active Application Discontinuation
- 1981-12-23 BR BR8109052A patent/BR8109052A/en unknown
- 1981-12-23 JP JP57500209A patent/JPS59500323A/en active Pending
- 1981-12-26 US US06/552,135 patent/US4541488A/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2425415A (en) * | 1945-12-05 | 1947-08-12 | Pure Oil Co | Acidizing earth bores |
| US3122503A (en) * | 1961-03-20 | 1964-02-25 | Dow Chemical Co | Dispersing clayey deposits |
| US3441085A (en) * | 1967-09-07 | 1969-04-29 | Exxon Production Research Co | Method for acid treating carbonate formations |
| US3556221A (en) * | 1969-01-06 | 1971-01-19 | Marathon Oil Co | Well stimulation process |
| US4325433A (en) * | 1980-06-27 | 1982-04-20 | University Of Southern California | Pre-caustic flood treatment |
Non-Patent Citations (1)
| Title |
|---|
| See also references of WO8302296A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0097149A4 (en) | 1985-06-06 |
| JPS59500323A (en) | 1984-03-01 |
| WO1983002296A1 (en) | 1983-07-07 |
| BR8109052A (en) | 1983-11-22 |
| US4541488A (en) | 1985-09-17 |
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