EP0151952A1 - Insulated piston for internal combustion engines - Google Patents
Insulated piston for internal combustion engines Download PDFInfo
- Publication number
- EP0151952A1 EP0151952A1 EP85100435A EP85100435A EP0151952A1 EP 0151952 A1 EP0151952 A1 EP 0151952A1 EP 85100435 A EP85100435 A EP 85100435A EP 85100435 A EP85100435 A EP 85100435A EP 0151952 A1 EP0151952 A1 EP 0151952A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- piston
- combustion chamber
- ceramic material
- metal
- heat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002485 combustion reaction Methods 0.000 title claims abstract description 33
- 229910010293 ceramic material Inorganic materials 0.000 claims abstract description 22
- 229910052751 metal Inorganic materials 0.000 claims abstract description 10
- 239000002184 metal Substances 0.000 claims abstract description 10
- 239000011248 coating agent Substances 0.000 claims abstract description 7
- 238000000576 coating method Methods 0.000 claims abstract description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 11
- 229910045601 alloy Inorganic materials 0.000 claims description 6
- 239000000956 alloy Substances 0.000 claims description 6
- 229910000551 Silumin Inorganic materials 0.000 claims description 4
- 238000005266 casting Methods 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 229910000505 Al2TiO5 Inorganic materials 0.000 claims description 2
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 2
- 229910006501 ZrSiO Inorganic materials 0.000 claims description 2
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 claims description 2
- 238000001513 hot isostatic pressing Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 229910052863 mullite Inorganic materials 0.000 claims description 2
- AABBHSMFGKYLKE-SNAWJCMRSA-N propan-2-yl (e)-but-2-enoate Chemical compound C\C=C\C(=O)OC(C)C AABBHSMFGKYLKE-SNAWJCMRSA-N 0.000 claims description 2
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 2
- 229910001060 Gray iron Inorganic materials 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 229910002077 partially stabilized zirconia Inorganic materials 0.000 claims 1
- 239000000919 ceramic Substances 0.000 description 6
- 239000000446 fuel Substances 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 238000003825 pressing Methods 0.000 description 3
- 229910021364 Al-Si alloy Inorganic materials 0.000 description 2
- 229910000640 Fe alloy Inorganic materials 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- 239000002775 capsule Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229910018125 Al-Si Inorganic materials 0.000 description 1
- 229910018520 Al—Si Inorganic materials 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- WPPDFTBPZNZZRP-UHFFFAOYSA-N aluminum copper Chemical compound [Al].[Cu] WPPDFTBPZNZZRP-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B77/00—Component parts, details or accessories, not otherwise provided for
- F02B77/02—Surface coverings of combustion-gas-swept parts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F7/00—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
- B22F7/06—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite workpieces or articles from parts, e.g. to form tipped tools
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02F—CYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
- F02F3/00—Pistons
- F02F3/10—Pistons having surface coverings
- F02F3/12—Pistons having surface coverings on piston heads
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02F—CYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
- F02F7/00—Casings, e.g. crankcases or frames
- F02F7/0085—Materials for constructing engines or their parts
- F02F7/0087—Ceramic materials
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05C—INDEXING SCHEME RELATING TO MATERIALS, MATERIAL PROPERTIES OR MATERIAL CHARACTERISTICS FOR MACHINES, ENGINES OR PUMPS OTHER THAN NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES
- F05C2201/00—Metals
- F05C2201/02—Light metals
- F05C2201/021—Aluminium
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05C—INDEXING SCHEME RELATING TO MATERIALS, MATERIAL PROPERTIES OR MATERIAL CHARACTERISTICS FOR MACHINES, ENGINES OR PUMPS OTHER THAN NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES
- F05C2203/00—Non-metallic inorganic materials
- F05C2203/08—Ceramics; Oxides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49229—Prime mover or fluid pump making
- Y10T29/49249—Piston making
- Y10T29/49256—Piston making with assembly or composite article making
- Y10T29/49258—Piston making with assembly or composite article making with thermal barrier or heat flow provision
Definitions
- Ceramic materials are now known which would be outstandingly suitable as thermal insulators of piston crowns with a thermal conductivity ⁇ of ⁇ 2 to 3 W / m ° K, but those piston crowns or piston chamber cavities insulated with ceramic have hitherto remained unknown. The reason for this can be seen in the difficulties associated with the application of ceramic material to the metallic piston. So far it was not possible to create a connection between ceramic parts and the piston material, e.g. B. the preferred silumin (Al-Gußle Alloy with 10 to 25% Si), which has the mechanical strength required under the temperatures or temperature differences prevailing in the internal combustion engine.
- the object of the invention is therefore to provide a piston for internal combustion engines, the bottom or the combustion chamber bowl of which is provided with a firmly adhering, heat-insulating coating made of ceramic material.
- a ceramic body can be connected to the usual metallic piston materials perfectly and with great strength if the ceramic body has a surface of metallic or metal-ceramic material on the side to be connected to the piston material.
- the object outlined above is achieved by creating a piston for internal combustion engines, which is characterized in that the Kolberdoden or its combustion chamber trough is provided with a heat-insulating coating, which on its side facing the combustion chamber consists entirely of ceramic material and on its side facing the piston crown or its combustion chamber trough has a metallic or metal-ceramic material fused to the piston metal, the side of the coating facing the piston crown or its combustion chamber trough having a connection firmly bolted to the piston metal
- the ceramic material of the covering preferably has a conductivity value ⁇ of ⁇ 2 to 3 W / m ° K in order to achieve particularly effective thermal insulation.
- the metallic component of the metal-ceramic material of the heat-insulating covering consists of or preferably contains iron or iron alloys, while cast aluminum alloys can advantageously be used as the piston material.
- the silunin mentioned above can be used, but other Al casting alloys can also be used.
- such other Al casting alloys are eutectic Al-Si alloys with 11 to 13 Si and minor additions of Cu, Ni and Mg; hypereutectic Al-Si alloys with about 17 to 25% Si and minor additions of Cu, Ni and Mg; and aluminum-copper alloys Al Cu 4 with Ni and Mg additives.
- This pouring takes place in such a way that the pressing body is inserted into the piston mold and poured in with the piston material.
- a "surface-shaped body” is to be understood here as a structure whose length and width dimensions are many times larger than its depth measurement, so that the structure is comparable to the shape of a mat or a carpet, for example - in the preferred use of iron or iron alloys as a metal or metal-ceramic component of the hot-isostatically pressed laminated body and an Al casting alloy as piston material then formed during pouring of the molten Kolbenme t alls to the pressing body, the Al-Fin process analog (US Patent 2,455,457) , intermetallic Fe-Al compounds, which ensure a particularly strong mechanical connection between the piston metal and the heat-insulating coating. "also under Ver Using other piston metals and metal-ceramic materials, bond strengths between the piston and the ceramic covering can be achieved, which are in any case superior to the bond strengths achieved so far.
- the hot isostatic pressing of the porous laminate generally takes place at temperatures of about 1000 to 1450, preferably from about 1200 to 1350 and in particular at 1300 ° C.
- the pressures to be used are usually in the range from about 1000 to 1500, preferably in the range from about 1200 to 1300, bar.
- a combustion bowl insert made of Zr0 2 was provided with a suitable mandrel on the inside. Then carbonyl iron powder was applied on the outside using a molybdenum capsule. The sample thus prepared and encapsulated was then placed in a hot isostatic press. The HIPEN itself was carried out at temperatures between 1200 and 1300 ° C, at pressures between 1000 and 1500 bar, the pressing time was 1-2 hours. The composite combustion chamber bowl produced in this way was poured into silumin and showed very good adhesive strength, this connection strength corresponding to the strength of the piston material.
- a pre-shaped combustion bowl insert made of ZrO 2 was provided with a suitable mandrel on the inside. On the outside, a mixture of carbonyl iron powder and Zr0 2 powder, with a carbonyl iron powder content of 10 - 90%, was applied using a molybdenum capsule. After insertion in the
- Example 1 The hot isostatic press was pressed as in Example 1. This composite combustion bowl was also cast in silumin and showed very good connection strength, which is equivalent to the strength of the piston material.
Abstract
Kolben für Verbrennungskraftmaschinen der auf dem Kolbenboden bzw, in dessen Brennraummulde einen wärmeisolierenden Belagtraigt welcher auf seiner dem Verbrennungsraum zugewandten Seite vollständig aus keramischem Material besteht und auf seiner dem Kolbenboden bzw. dessen Brennraummulde zugewandten Seite einen mit dem Kolbenmetall verschmolzenen, metallischen bzw. metallkeramischen Stoff aufweist.Piston for internal combustion engines which on the piston crown or in the combustion chamber cavity has a heat-insulating coating which, on its side facing the combustion chamber, consists entirely of ceramic material and on its side facing the piston crown or its combustion chamber cavity has a metallic or metal-ceramic material fused to the piston metal .
Description
Die weltweit gestiegenen Kosten der Kraftstoffe für Verbrennungsmotoren haben zu intensiven Bemühungen der Kraftstoffersparnis geführt. Eine der Möglichkeiten von Brennstoffeinsparungen besteht in der thermischen Isolierung des Verbrennungsraumes, d. h. der Zylinderwandungen, des Zylinderkopfes, insbesondere aber des Kolbenbodens, über den ein wesentlicher Teil der Wärme abfließt.The worldwide increase in the cost of fuels for internal combustion engines has led to intensive efforts to save fuel. One of the ways to save fuel is to thermally isolate the combustion chamber, i.e. H. the cylinder walls, the cylinder head, but in particular the piston crown, through which a substantial part of the heat flows away.
Nun sind zwar keramische Stoffe bekannt, welche mit Wärmeleitfähigkeitsuerter λ von <2 bis 3 W/m °K als thermische Isolatoren von Kolbenböden hervorragend geeignet wären, doch sind solche mit Keramik isolierten Kolbenböden bzw. Kolbenbrennraummulden bisher unbekannt geblieben. Der Grund hierfür ist in den Schwierigkeiten zu sehen, welche mit dem Aufbringen keramischen Materials auf den metallischen Kolben verbunden sind. So war es bisher ni:ht möglich, eine Verbindung zwischen Keramikteilen und dem Kolbenwerkstoff, z. B. dem hierfür bevorzugten Silumin (Al-Gußlegierung mit 10 bis 25% Si), herzustellen welche die unter den im Verbrennungsmotor herrschenden Temperaturen bzw. Temperaturunterschieden erforderliche mechanische Festigkeit besitzt.Ceramic materials are now known which would be outstandingly suitable as thermal insulators of piston crowns with a thermal conductivity λ of <2 to 3 W / m ° K, but those piston crowns or piston chamber cavities insulated with ceramic have hitherto remained unknown. The reason for this can be seen in the difficulties associated with the application of ceramic material to the metallic piston. So far it was not possible to create a connection between ceramic parts and the piston material, e.g. B. the preferred silumin (Al-Gußle Alloy with 10 to 25% Si), which has the mechanical strength required under the temperatures or temperature differences prevailing in the internal combustion engine.
Aufgabe der Erfindung ist es daher, einen Kolben für Verbrennungsmotoren zu schaffen, dessen Boden bzw. dessen Brennraummulde mit einem festhaftenden wärmeisolierenden Belag aus keramischen Material versehen ist.The object of the invention is therefore to provide a piston for internal combustion engines, the bottom or the combustion chamber bowl of which is provided with a firmly adhering, heat-insulating coating made of ceramic material.
Nunmehr wurde überraschenderweise gefunden, daß sich ein keramischer Körper mit den üblichen metallischen kolbenwerkstoffen einwandfrei und mit großer Festigkeit verbinden läßt, wenn der keramische Körper auf der mit den Kolbenwerkstoff zu verbindenden Seite eine Oberfläche aus metallischem bzw. metallkeramischen Material aufweist. Durch Aufgießen geschmolzenen Kolbenmetalls auf eine solche Oberfläche läßt sich eine bisher nicht gekannte B ndefestigkeit zwischen wärmeisolierendem keramischem Materia und Kolbenwerkstoff erreichen.It has now surprisingly been found that a ceramic body can be connected to the usual metallic piston materials perfectly and with great strength if the ceramic body has a surface of metallic or metal-ceramic material on the side to be connected to the piston material. By pouring molten piston metal onto such a surface, a previously unknown bond strength between heat-insulating ceramic material and piston material can be achieved.
Somit wird die oben umrissene Aufgabe gelöst durcen die Schaffung eines Kolbens für Verbrennungskraftmasch nen, welcher dadurch gekennzeichnet.ist, daß der Kolberdoden bzw. dessen Brennraummulde mit einem wärmeisoliererden Belag versehen ist, welcher auf seiner dem Verbrenrungsraum zugewandten Seite vollständig aus keramischen Material besteht und auf seiner dem Kolbenboden bzw. dessen.Brennraummulde zugewandten Seite einen mit den Kolbenmetall verschmolzenen, metallischen bzw. metallkeramischei Stoff aufweist, wobei die dem Kolbenboden bzw. dessen Brennraummulde zugewandte Seite des Belages eine mit der Kolbenmetall fest verschnolzene Verbindung aufweisThus, the object outlined above is achieved by creating a piston for internal combustion engines, which is characterized in that the Kolberdoden or its combustion chamber trough is provided with a heat-insulating coating, which on its side facing the combustion chamber consists entirely of ceramic material and on its side facing the piston crown or its combustion chamber trough has a metallic or metal-ceramic material fused to the piston metal, the side of the coating facing the piston crown or its combustion chamber trough having a connection firmly bolted to the piston metal
Vorzugsweise besitzt das keramische Material des Belages einen Leitfähigkeitswert λ von <2 bis 3 W/m °K, um eine besonders wirksame Wärmedämmung zu erzielen. Bevorzugt verwendbare keramische Stoffe sind ZrSiO4, Aluminiumtitanat, Siliciumnitrid, das unter der Bezeichnung "Mullit" bekannte synthetische Al-Si-Mischoxyd der Formel 3Al2O3.2SiO2, sowie ein teilmodifiziertes Zr02, welches als "PSZ" (=partial stabilized zirconoxide) bekannt ist und Ca0 und/oder MgO als Stabilisatoren aufweist.The ceramic material of the covering preferably has a conductivity value λ of <2 to 3 W / m ° K in order to achieve particularly effective thermal insulation. Ceramic materials that can be used with preference are ZrSiO 4 , aluminum titanate, silicon nitride, the synthetic Al-Si mixed oxide of the formula 3Al 2 O 3 .2SiO 2 known under the name "Mullite", and a partially modified Zr0 2 , which is called "PSZ" (= partial stabilized zirconium oxide) is known and has Ca0 and / or MgO as stabilizers.
Die metallische Komponente des metallkeramischen Stoffes des wärmeisolierenden Belages besteht aus bzw. enthält vorzugsweise Eisen oder Eisenlegierungen, während als Kolbenwerkstoff Al-Gußlegierungen mit Vorteil anwendbar sind. Als solche kommen das bereits oben erwähnte Silunin in Frage, aber es können auch andere Al-Gußlegierungen verwendet werden. Beispiele solcher anderer Al - Gußlegierungen sind eutektische Al-Si-Legierungen mit 11 bis 13 Si und kleineren Zusätzen von Cu, Ni und Mg; übereutektische Al-Si-Legierungen mit etwa 17 bis 25% Si und kleineren Zusätzen von Cu, Ni und Mg; und Aluminium-Kupferlegierungen Al Cu 4 mit Ni- und Mg-Zusätzen.The metallic component of the metal-ceramic material of the heat-insulating covering consists of or preferably contains iron or iron alloys, while cast aluminum alloys can advantageously be used as the piston material. As such, the silunin mentioned above can be used, but other Al casting alloys can also be used. Examples of such other Al casting alloys are eutectic Al-Si alloys with 11 to 13 Si and minor additions of Cu, Ni and Mg; hypereutectic Al-Si alloys with about 17 to 25% Si and minor additions of Cu, Ni and Mg; and aluminum-copper alloys Al Cu 4 with Ni and Mg additives.
Der erfindungsgemäße Kolben mit wärmeisolierendem Belag des Kolbenbodens bzw. seiner Brennraummulde kann hergestellt werden, indem man
- a) einen als wärmeisolierenden Belag vorgesehenen, flächenhaft ausgebildeten Körper, welcher
- i) in seiner äu3eren Gestalt der Form des Kolbenbodens bzw. seiner Brennraummulde angeglichen ist,
- ii) auf seiner dem Verbrennungsraun der Verbrennungskraftmaschine zugewandten Seite aus einer oder mehreren Schichten vollständig keramischen Materials besteht und
- iii) auf seiner dem Kolbenboden bzw. dessen Brennraummulde zugewandten Seite eine oder mehrere Schichten metallischer bzw. metallkeramischer Stoffe trägt,
heißisostatisch verpreßt und dann - b) das geschmolzene Kolbenmetall auf den erhaltenen Preßkörper aufgießt.
- a) a surface-shaped body provided as a heat-insulating covering, which
- i) its outer shape is adapted to the shape of the piston crown or its combustion chamber bowl,
- ii) on its side facing the combustion chamber of the internal combustion engine consists of one or more layers of completely ceramic material and
- iii) carries one or more layers of metallic or metal-ceramic materials on its side facing the piston crown or its combustion chamber trough,
hot isostatically pressed and then - b) pouring the molten piston metal onto the obtained compact.
Dieses Aufgießen erfolgt in der Weise, daß man den Preßkörper in die Kolbenform einsetzt und mit dem Kolbennaterial eingie3t.This pouring takes place in such a way that the pressing body is inserted into the piston mold and poured in with the piston material.
Unter einen "flächenhaft ausgebildeten Körper" ist hier ein Gebilde zu verstehen, dessen Längen- und Breitenabmessungen um ein Vielfaches größer sind als seine Tiefenabnessung, so daß das Gebilde etwa mit der Form einer Matte oder eines Teppichs vergleichbar ist.-Bei der bevorzugten Verwendung von Eisen bzw. Eisenlegierungen als metallische bzw. metallkeramische Komponente des heißisostatisch verpreßten Schichtkörpers und einer Al-Gußlegierung als Kolbenwerkstoff bilden sich dann beim Aufgießen des geschmolzenen Kolbenmetalls auf den Preßkörper, analog dem Al-Fin-Verfahren (USA-Patentschrift 2 455 457), intermetallische Fe-Al-Verbindungen, welche eine besonders feste mechanische Verbindung zwischen Kolbenmetall und wärmeisolierendem belag gewährleisten. "ber auch unter Verwendung anderer Kolbenmetalle und metallkeramischer Stoffe lassen sich Bindefestigkeiten zwischen Kolben und keramischem Belag erzielen, welche den bisher erzielten Bindefestigkeiten in jedem Falle überlegen sind.A "surface-shaped body" is to be understood here as a structure whose length and width dimensions are many times larger than its depth measurement, so that the structure is comparable to the shape of a mat or a carpet, for example - in the preferred use of iron or iron alloys as a metal or metal-ceramic component of the hot-isostatically pressed laminated body and an Al casting alloy as piston material then formed during pouring of the molten Kolbenme t alls to the pressing body, the Al-Fin process analog (US Patent 2,455,457) , intermetallic Fe-Al compounds, which ensure a particularly strong mechanical connection between the piston metal and the heat-insulating coating. "also under Ver Using other piston metals and metal-ceramic materials, bond strengths between the piston and the ceramic covering can be achieved, which are in any case superior to the bond strengths achieved so far.
Das heißisostatische Verpressen des porösen Schichtkörpers erfolgt im allgemeinen bei Temperaturen von etwa 1000 bis 1450, vorzugsweise von etwa 1200 bis 1350 und insbesondere bei 1300 °C. Die dabei anzuwendenden Drücke liegen gewöhnlich im Bereich von etwa 1000 bis 1500, vorzugsweise in Bereich von etwa 1200 bis 1300 bar.The hot isostatic pressing of the porous laminate generally takes place at temperatures of about 1000 to 1450, preferably from about 1200 to 1350 and in particular at 1300 ° C. The pressures to be used are usually in the range from about 1000 to 1500, preferably in the range from about 1200 to 1300, bar.
Die Erfindung sei nunmehr durch die nachfolgenden Beispiele näher erläutert:The invention will now be explained in more detail by the following examples:
Ein Brennraummuldeneinsatz aus Zr02 wurde innseitig mit einem passenden Dorn versehen. Danach wurde außenseitig mittels einer Molybdänkapsel Carbonyleisenpulver aufgebracht. Die so präparierte und gekapselte Probe wurde dann in eine heißisostatische Presse eingesetzt. Das HIPEN selbst erfolgte bei Temperaturen zwischen 1200 und 1300 °C, bei Drücken zwischen 1000 und 1500 bar, die Preßzeit betrug 1 - 2 Stunden. Die so hergestellte Verbundbrennraummulde wurde in Silumin eingegossen und zeigte sehr gute Haftfestigkeit, wobei diese Verbindungsfestigkeit der Festigkeit des Kolbenwerkstoffes entspricht.A combustion bowl insert made of Zr0 2 was provided with a suitable mandrel on the inside. Then carbonyl iron powder was applied on the outside using a molybdenum capsule. The sample thus prepared and encapsulated was then placed in a hot isostatic press. The HIPEN itself was carried out at temperatures between 1200 and 1300 ° C, at pressures between 1000 and 1500 bar, the pressing time was 1-2 hours. The composite combustion chamber bowl produced in this way was poured into silumin and showed very good adhesive strength, this connection strength corresponding to the strength of the piston material.
Ein vorgeformter Brennraummuldeneinsatz aus ZrO2 wurde innseitig mit einem passenden Dorn versehen. Außenseitig wurde mittels einer Molybdänkapsel ein Gemisch aus Carbonyleisenpulver und Zr02-Pulver, bei einen Carbonyleisenpulvergehalt von 10 - 90%, aufgebracht. Nach Einsetzen in dieA pre-shaped combustion bowl insert made of ZrO 2 was provided with a suitable mandrel on the inside. On the outside, a mixture of carbonyl iron powder and Zr0 2 powder, with a carbonyl iron powder content of 10 - 90%, was applied using a molybdenum capsule. After insertion in the
heißisostatische Presse erfolgte das Pressen wie in Beispiel 1. Auch diese Verbundbrennraummulde wurde in Silumin eingegossen und zeigte sehr gute Verbindfestigkeit, die der Festigkeit des Kolbenwerkstoffes gleichkommt.The hot isostatic press was pressed as in Example 1. This composite combustion bowl was also cast in silumin and showed very good connection strength, which is equivalent to the strength of the piston material.
Claims (8)
heißisostatisch verpreßt und dann
hot isostatically pressed and then
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19843404121 DE3404121A1 (en) | 1984-02-07 | 1984-02-07 | HEAT-INSULATING PISTON FOR INTERNAL COMBUSTION ENGINES |
DE3404121 | 1984-02-07 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0151952A1 true EP0151952A1 (en) | 1985-08-21 |
EP0151952B1 EP0151952B1 (en) | 1989-03-29 |
Family
ID=6226914
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP85100435A Expired EP0151952B1 (en) | 1984-02-07 | 1985-01-17 | Insulated piston for internal combustion engines |
Country Status (4)
Country | Link |
---|---|
US (1) | US4651630A (en) |
EP (1) | EP0151952B1 (en) |
JP (1) | JPS60187740A (en) |
DE (2) | DE3404121A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013155131A3 (en) * | 2012-04-12 | 2014-01-16 | Rel, Inc. | Thermal isolation for casting articles |
EP3608532A1 (en) * | 2014-01-24 | 2020-02-12 | Volkswagen AG | Piston for an engine |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4706550A (en) * | 1986-01-09 | 1987-11-17 | The United States Of America As Represented By The Secretary Of The Navy | Metal matrix composite piston head and method of fabrication |
GB8622538D0 (en) * | 1986-09-18 | 1986-10-22 | Ae Plc | Pistons |
US4890663A (en) * | 1987-05-21 | 1990-01-02 | Interatom Gmbh | Method for producing a ceramic-coated metallic component |
GB8714287D0 (en) * | 1987-06-18 | 1987-07-22 | Ae Plc | Pistons |
US5282411A (en) * | 1989-08-10 | 1994-02-01 | Isuzu Motors Limited | Heat-insulating piston with middle section of less dense but same material |
WO1993024672A1 (en) * | 1992-05-29 | 1993-12-09 | United Technologies Corporation | Ceramic thermal barrier coating for rapid thermal cycling applications |
US5305726A (en) * | 1992-09-30 | 1994-04-26 | United Technologies Corporation | Ceramic composite coating material |
US5253625A (en) * | 1992-10-07 | 1993-10-19 | Brunswick Corporation | Internal combustion engine having a hypereutectic aluminum-silicon block and aluminum-copper pistons |
DE102004056519B4 (en) * | 2004-11-24 | 2017-07-13 | Mahle Gmbh | Method for producing a piston for an internal combustion engine |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2455457A (en) * | 1941-10-24 | 1948-12-07 | Fairchild Engine & Airplane | Coated metal article |
DE869570C (en) * | 1948-10-01 | 1954-03-08 | Maschf Augsburg Nuernberg Ag | Pistons for internal combustion engines |
US4055451A (en) * | 1973-08-31 | 1977-10-25 | Alan Gray Cockbain | Composite materials |
US4075364A (en) * | 1976-04-15 | 1978-02-21 | Brunswick Corporation | Porous ceramic seals and method of making same |
DE2749227A1 (en) * | 1976-11-05 | 1978-05-11 | Pechiney Aluminium | A PISTON MADE OF AN ALUMINUM ALLOY WITH A SURFACE TREATED TO ACHIEVE NO SEIZING IN CONTACT WITH A CYLINDER WITH THE INNER WALL MADE OF AN ALUMINUM ALLOY AND A PROCESS FOR THE PRODUCTION OF THIS |
EP0079151A1 (en) * | 1981-10-27 | 1983-05-18 | Advanced Technology Inc. | Ceramic, cermet or metal composites |
US4404262A (en) * | 1981-08-03 | 1983-09-13 | International Harvester Co. | Composite metallic and refractory article and method of manufacturing the article |
EP0111989B1 (en) * | 1982-12-03 | 1987-08-19 | Ngk Insulators, Ltd. | An engine part having a ceramics member and a metallic member joined together |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2297460A (en) * | 1939-07-14 | 1942-09-29 | Dietrich Friedrich Richard | Piston for combustion power engines |
FR902440A (en) * | 1944-03-06 | 1945-08-30 | Central D Entpr S Off | Flexible paving for flat roofs |
US3977459A (en) * | 1973-09-07 | 1976-08-31 | Gruber & Kaja | Casting a shaped aluminum part on a work piece |
US4530884A (en) * | 1976-04-05 | 1985-07-23 | Brunswick Corporation | Ceramic-metal laminate |
DE2639294C2 (en) * | 1976-09-01 | 1982-05-13 | Mahle Gmbh, 7000 Stuttgart | Pressed aluminum piston for internal combustion engines with inserts made of a different material |
US4152816A (en) * | 1977-06-06 | 1979-05-08 | General Motors Corporation | Method of manufacturing a hybrid turbine rotor |
JPS6018621B2 (en) * | 1981-05-21 | 1985-05-11 | 日本碍子株式会社 | engine parts |
JPS606910B2 (en) * | 1981-12-09 | 1985-02-21 | 日本碍子株式会社 | metal-ceramics joint |
FR2522647A1 (en) * | 1982-03-05 | 1983-09-09 | Rolls Royce | METALLOCERAMIC COMPOSITE PIECE AND PROCESS FOR PRODUCING THE SAME |
US4546048A (en) * | 1984-03-23 | 1985-10-08 | Dana Corporation | Composite thermal shield for engine components |
-
1984
- 1984-02-07 DE DE19843404121 patent/DE3404121A1/en not_active Withdrawn
-
1985
- 1985-01-17 DE DE8585100435T patent/DE3569144D1/en not_active Expired
- 1985-01-17 EP EP85100435A patent/EP0151952B1/en not_active Expired
- 1985-01-22 US US06/693,285 patent/US4651630A/en not_active Expired - Fee Related
- 1985-02-04 JP JP60019805A patent/JPS60187740A/en active Pending
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2455457A (en) * | 1941-10-24 | 1948-12-07 | Fairchild Engine & Airplane | Coated metal article |
DE869570C (en) * | 1948-10-01 | 1954-03-08 | Maschf Augsburg Nuernberg Ag | Pistons for internal combustion engines |
US4055451A (en) * | 1973-08-31 | 1977-10-25 | Alan Gray Cockbain | Composite materials |
US4075364A (en) * | 1976-04-15 | 1978-02-21 | Brunswick Corporation | Porous ceramic seals and method of making same |
DE2749227A1 (en) * | 1976-11-05 | 1978-05-11 | Pechiney Aluminium | A PISTON MADE OF AN ALUMINUM ALLOY WITH A SURFACE TREATED TO ACHIEVE NO SEIZING IN CONTACT WITH A CYLINDER WITH THE INNER WALL MADE OF AN ALUMINUM ALLOY AND A PROCESS FOR THE PRODUCTION OF THIS |
US4404262A (en) * | 1981-08-03 | 1983-09-13 | International Harvester Co. | Composite metallic and refractory article and method of manufacturing the article |
EP0079151A1 (en) * | 1981-10-27 | 1983-05-18 | Advanced Technology Inc. | Ceramic, cermet or metal composites |
EP0111989B1 (en) * | 1982-12-03 | 1987-08-19 | Ngk Insulators, Ltd. | An engine part having a ceramics member and a metallic member joined together |
Non-Patent Citations (3)
Title |
---|
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, Band 66, Nr. 7, Juli 1983, Columbus, Ohio, USA; K. SUGANUMA et al. "New method for solid-state bonding between ceramics and metals", Seiten C117, C118 * |
MOTORTECHNISCHE ZEITSCHRIFT, Band 44, Nr. 6, Juni 1983, Schwäbisch Gmünd; P. WALZER et al. "Hochtemperaturkeramik für Verbrennungskraftmaschinen", Seiten 225-229 * |
PATENT ABSTRACTS OF JAPAN, Band 7, Nr. 92, 16. April 1983, Seite (M-208) (1237); & JP-A-58 015 742 (NIPPON KOKAN), 29-01-1983 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013155131A3 (en) * | 2012-04-12 | 2014-01-16 | Rel, Inc. | Thermal isolation for casting articles |
US10179364B2 (en) | 2012-04-12 | 2019-01-15 | Rel, Inc. | Thermal isolation for casting articles |
US10434568B2 (en) | 2012-04-12 | 2019-10-08 | Loukus Technologies, Inc. | Thermal isolation spray for casting articles |
EP3608532A1 (en) * | 2014-01-24 | 2020-02-12 | Volkswagen AG | Piston for an engine |
Also Published As
Publication number | Publication date |
---|---|
DE3404121A1 (en) | 1985-08-08 |
EP0151952B1 (en) | 1989-03-29 |
DE3569144D1 (en) | 1989-05-03 |
JPS60187740A (en) | 1985-09-25 |
US4651630A (en) | 1987-03-24 |
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