EP0294253A3 - Thermoplastic compositions, process for their preparation and their application in obtaining industrial objects - Google Patents

Thermoplastic compositions, process for their preparation and their application in obtaining industrial objects Download PDF

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Publication number
EP0294253A3
EP0294253A3 EP88401094A EP88401094A EP0294253A3 EP 0294253 A3 EP0294253 A3 EP 0294253A3 EP 88401094 A EP88401094 A EP 88401094A EP 88401094 A EP88401094 A EP 88401094A EP 0294253 A3 EP0294253 A3 EP 0294253A3
Authority
EP
European Patent Office
Prior art keywords
polymer
ethylene
weight
moles
initiator
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP88401094A
Other languages
French (fr)
Other versions
EP0294253A2 (en
EP0294253B1 (en
Inventor
Joel Audureau
Vincent Crenna
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SOFRAPO-COMMERCIALE
Original Assignee
Norsolor SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Norsolor SA filed Critical Norsolor SA
Publication of EP0294253A2 publication Critical patent/EP0294253A2/en
Publication of EP0294253A3 publication Critical patent/EP0294253A3/en
Application granted granted Critical
Publication of EP0294253B1 publication Critical patent/EP0294253B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/92—Measuring, controlling or regulating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/50—Partial depolymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/92704—Temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/78—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
    • B29C48/80—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling at the plasticising zone, e.g. by heating cylinders
    • B29C48/84—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling at the plasticising zone, e.g. by heating cylinders by heating or cooling the feeding screws
    • B29C48/845—Heating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/10—Copolymer characterised by the proportions of the comonomers expressed as molar percentages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/10—Chemical modification of a polymer including a reactive processing step which leads, inter alia, to morphological and/or rheological modifications, e.g. visbreaking
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L2023/40—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with compounds changing molecular weight
    • C08L2023/42—Depolymerisation, vis-breaking or degradation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins

Abstract

The compositions contain a) less than 90% and at least 2% by weight of at least one ethylene polymer (A), and optionally, at least one alpha -olefin having from 3 to 12 carbon atoms, said polymer containing at least 70% in moles of patterns derived from ethylene, and b) more than 10% and up to 98% by weight of at least one polymer (B) containing at least 85% in moles of patterns derived from at least one alpha -olefin having from 3 to 12 carbon atoms and at the most 15% in moles of patterns derived from ethylene, and are characterized in that the polymer (A) is a modified polymer of which the measured limit viscosity is comprised between 1.3 and 100 times its limit viscosity calculated from the distribution of molecular masses. The compositions are obtained by a process consisting in providing a polymer of ethylene and, optionally, of at least one alpha -olefin having from 3 to 12 carbon atoms in the presence, on the one hand, of at least one initiator of free radicals in a quantity comprised between 0.001 and 0.3 parts by weight of the initiator for one hundred parts by weight of said polymer at a temperature higher than the melting temperature of said polymer during a time at least equal to one tenth of the half life time of the initiator at the temperature considered, and, on the other hand, of at least one polymer (B). Application to the production of industrial articles by extrusion-blowing of sheaths or hollow bodies, extrusion of films by means of flat dies, roto-moulding, injection or coating.
EP88401094A 1987-05-07 1988-05-05 Thermoplastic compositions, process for their preparation and their application in obtaining industrial objects Expired - Lifetime EP0294253B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8706431 1987-05-07
FR8706431A FR2614897B1 (en) 1987-05-07 1987-05-07 THERMOPLASTIC COMPOSITIONS CONTAINING A MODIFIED ETHYLENE POLYMER AND A C3-C12 OLEFIN POLYMER, THEIR PREPARATION PROCESS AND THEIR APPLICATION FOR OBTAINING INDUSTRIAL ARTICLES

Publications (3)

Publication Number Publication Date
EP0294253A2 EP0294253A2 (en) 1988-12-07
EP0294253A3 true EP0294253A3 (en) 1988-12-14
EP0294253B1 EP0294253B1 (en) 1995-01-18

Family

ID=9350859

Family Applications (1)

Application Number Title Priority Date Filing Date
EP88401094A Expired - Lifetime EP0294253B1 (en) 1987-05-07 1988-05-05 Thermoplastic compositions, process for their preparation and their application in obtaining industrial objects

Country Status (19)

Country Link
US (2) US5218046A (en)
EP (1) EP0294253B1 (en)
JP (1) JP2684567B2 (en)
KR (1) KR960006152B1 (en)
CN (1) CN1020910C (en)
AT (1) ATE117341T1 (en)
AU (1) AU617321B2 (en)
BR (1) BR8807489A (en)
CA (1) CA1317057C (en)
DE (1) DE3852783T2 (en)
ES (1) ES2067482T3 (en)
FI (1) FI98522C (en)
FR (1) FR2614897B1 (en)
GR (1) GR3015780T3 (en)
IE (1) IE67277B1 (en)
IN (1) IN169031B (en)
NO (1) NO303229B1 (en)
PT (1) PT87434B (en)
WO (1) WO1988008865A1 (en)

Families Citing this family (24)

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Publication number Priority date Publication date Assignee Title
US4840996A (en) * 1987-11-30 1989-06-20 Quantum Chemical Corporation Polymeric composition
US5073598A (en) * 1989-06-21 1991-12-17 Mobil Oil Corporation Method for improving the processing characteristics of polyethylene blends
DE4202663A1 (en) * 1992-01-31 1993-08-05 Alkor Gmbh Plastics film based on propylene@] terpolymer blend - with VLDPE and/or hetero:phase polyolefin or propylene@] homo-or copolymer contg. elastomer with good flexibility and sealing property
US5639818A (en) * 1994-03-11 1997-06-17 Quantum Chemical Corporation Peroxide modified PP/PE blends with superior melt strength
BE1009007A3 (en) * 1994-12-27 1996-10-01 Dsm Nv Cross-linked polymer composition containing polypropylene and polyethene.
US5986000A (en) * 1995-05-22 1999-11-16 Playtex Products, Inc. Soft, flexible composition and method for making same
BE1009963A3 (en) * 1995-12-22 1997-11-04 Solvay COMPOSITIONS STATISTICS PROPYLENE COPOLYMERS, METHOD OF MAKING, AND CONTAINING SHEETS MULTI-sealable.
US6506842B1 (en) 1997-01-29 2003-01-14 Dupont Dow Elastomers L.L.C. Rheology-modified thermoplastic elastomer compositions and articles fabricated therefrom
EP0991716B1 (en) * 1997-06-25 2004-01-28 Eastman Chemical Company Monolayer film
US6153702A (en) * 1997-09-12 2000-11-28 Eastman Chemical Company Polymers, and novel compositions and films therefrom
US6197887B1 (en) 1997-09-12 2001-03-06 Eastman Chemical Company Compositions having particular utility as stretch wrap cling film
US6204335B1 (en) 1997-09-12 2001-03-20 Eastman Chemical Company Compositions of linear ultra low density polyethylene and propylene polymers and films therefrom
US6070394A (en) * 1997-09-12 2000-06-06 Eastman Chemical Company Lownoise stretch wrapping process
US6548600B2 (en) * 2000-09-22 2003-04-15 Dupont Dow Elastomers L.L.C. Thermoplastic elastomer compositions rheology-modified using peroxides and free radical coagents
JP4372539B2 (en) * 2001-06-15 2009-11-25 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ Method for cross-linking thermoplastic polyolefin elastomer composition
US7125924B2 (en) * 2002-09-17 2006-10-24 Basell Poliolefine Italia S.P.A. Highly filled soft polyolefin compositions
US7338994B2 (en) * 2002-10-01 2008-03-04 Dow Global Technologies Inc. Rheology-modified thermoplastic elastomer compositions for extruded profiles
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
CN101724110B (en) 2002-10-15 2013-03-27 埃克森美孚化学专利公司 Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
ITMI20030629A1 (en) * 2003-03-31 2004-10-01 Polimeri Europa Spa ELASTOMERIC COMPOSITION FOR THE INSULATION OF ELECTRIC CABLES.
ITMI20032550A1 (en) * 2003-12-22 2005-06-23 Polimeri Europa Spa NEROFUMO ELASTOMERIC COMPOUNDS
US7750086B2 (en) * 2006-02-27 2010-07-06 Equistar Chemicals, Lp Solid state modification of propylene polymers
JP5944926B2 (en) 2011-02-04 2016-07-05 ダウ グローバル テクノロジーズ エルエルシー Crosslinkable polyolefin composition for embossed skin material

Citations (3)

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Publication number Priority date Publication date Assignee Title
US4514534A (en) * 1984-04-13 1985-04-30 United States Steel Corporation Modified polypropylene for film
EP0191990A2 (en) * 1984-12-27 1986-08-27 Nippon Oil Co. Ltd. Crosslinked resin compositions
US4614764A (en) * 1985-03-06 1986-09-30 Mobil Oil Corporation Linear low density ethylene polymers blended with modified linear low density ethylene polymers

Family Cites Families (15)

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FR52557E (en) * 1942-10-09 1945-04-30 Licentia Gmbh Device for controlling current rectifiers with mechanical current interruption
JPS5839653B2 (en) * 1975-04-15 1983-08-31 チッソ株式会社 Ibisaiwari Sensei Ichijikuenshinbutsuno Seizouhouhou
JPS52121060A (en) * 1976-04-06 1977-10-12 Mitsui Toatsu Chem Inc Polyolefin compositions suitable for use in extrusion coating
FR2493855B1 (en) * 1980-11-13 1986-01-10 Naphtachimie Sa IMPROVED IMPACT RESISTANCE POLYPROPYLENE COMPOSITIONS
AT372890B (en) * 1981-10-16 1983-11-25 Ver Edelstahlwerke Ag REMOVAL DEVICE OF A HORIZONTAL CONTINUOUS CASTING SYSTEM
FR2519007B1 (en) * 1981-12-24 1985-12-27 Charbonnages Ste Chimique MODIFIED COPOLYMERS OF ETHYLENE AND AT LEAST ONE A-OLEFIN AND PROCESS FOR THEIR PREPARATION
US4375531A (en) * 1982-01-11 1983-03-01 Northern Petrochemical Company High impact visbroken polymeric blends
JPS58210969A (en) * 1982-05-31 1983-12-08 Nitto Electric Ind Co Ltd Water-soluble insulating coating
JPS58210949A (en) * 1982-06-02 1983-12-08 Showa Denko Kk Preparation of impact-resistant polypropylene composition
FR2529563B1 (en) * 1982-06-30 1986-01-24 Charbonnages Ste Chimique COMPOSITIONS OF POLYPROPYLENE AND ETHYLENE / A-OLEFIN COPOLYMERS AND THEIR APPLICATION IN THE MANUFACTURE OF SINGLE-ORIENTED YARNS
US4489034A (en) * 1982-08-25 1984-12-18 Shell Oil Company Thermoforming process using modified polymer blend
US4514543A (en) * 1983-10-03 1985-04-30 Atlantic Richfield Company Methylmethacrylate/phenylmaleimide copolymer and styrene/maleic anhydride copolymer
US4603173A (en) * 1985-02-27 1986-07-29 E. I. Du Pont De Nemours And Company Processing polyethylene resins
JPS62112644A (en) * 1985-11-11 1987-05-23 Nippon Petrochem Co Ltd Non-rigid polyolefin composition
FR2592051B1 (en) * 1985-12-24 1988-10-14 Charbonnages Ste Chimique COMPOSITIONS OF ETHYLENE POLYMERS, A PROCESS FOR THEIR PREPARATION AND THEIR APPLICATION FOR OBTAINING INDUSTRIAL ARTICLES

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4514534A (en) * 1984-04-13 1985-04-30 United States Steel Corporation Modified polypropylene for film
EP0191990A2 (en) * 1984-12-27 1986-08-27 Nippon Oil Co. Ltd. Crosslinked resin compositions
US4614764A (en) * 1985-03-06 1986-09-30 Mobil Oil Corporation Linear low density ethylene polymers blended with modified linear low density ethylene polymers

Also Published As

Publication number Publication date
PT87434A (en) 1989-05-31
JP2684567B2 (en) 1997-12-03
AU617321B2 (en) 1991-11-28
JPH03503422A (en) 1991-08-01
DE3852783T2 (en) 1995-07-20
NO303229B1 (en) 1998-06-15
EP0294253A2 (en) 1988-12-07
WO1988008865A1 (en) 1988-11-17
ES2067482T3 (en) 1995-04-01
FI895266A0 (en) 1989-11-06
EP0294253B1 (en) 1995-01-18
KR960006152B1 (en) 1996-05-09
IE881371L (en) 1988-11-07
CN1030432A (en) 1989-01-18
BR8807489A (en) 1990-05-22
DE3852783D1 (en) 1995-03-02
NO890065D0 (en) 1989-01-06
FR2614897B1 (en) 1991-12-20
IN169031B (en) 1991-08-24
CN1020910C (en) 1993-05-26
FI98522B (en) 1997-03-27
FR2614897A1 (en) 1988-11-10
KR890701688A (en) 1989-12-21
AU1724088A (en) 1988-12-06
US5334663A (en) 1994-08-02
US5218046A (en) 1993-06-08
GR3015780T3 (en) 1995-07-31
ATE117341T1 (en) 1995-02-15
PT87434B (en) 1992-08-31
CA1317057C (en) 1993-04-27
IE67277B1 (en) 1996-03-20
FI98522C (en) 1997-07-10
NO890065L (en) 1989-01-06

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