EP0294942B2

EP0294942B2 - Solid catalyst for polymerizing an olefin

Info

Publication number: EP0294942B2
Application number: EP88304301A
Authority: EP
Inventors: Toshiyuki Tsutsui; Ken Yoshitsugu; Akinori Toyota; Norio Kashiwa
Original assignee: Mitsui Chemicals Inc
Current assignee: Mitsui Chemicals Inc
Priority date: 1987-05-13
Filing date: 1988-05-12
Publication date: 2002-05-08
Anticipated expiration: 2008-05-12
Also published as: CN1013581B; ATE108460T1; KR880013990A; DE3850616T3; DE3850616D1; CA1314536C; CN88103902A; JPS63280703A; JP2538595B2; EP0294942B1; KR920001319B1; DE3850616T2; EP0294942A1; US5126301A

Abstract

A solid catalyst for polymerizing an olefin is prepared from an organometallic compound, a fine-particle carrier, an aluminoxane, a compound of group IVB transition metal in periodic table, and an olefin polymer produced in a preliminary polymerization. The catalyst has a high polymerization activity and is capable of producing an olefin polymer having a narrow molecular-weight distribution. When the catalyst is used for producing an olefin copolymer, the resulting copolymer has both narrow molecular-weight distribution and composition distribution.

Description

The present invention relates to process for preparing a solid catalyst for polymerizing an olefin.
α-olefin polymers, particularly ethylene polymer and ethylene-α-olefin copolymer have generally been prepared by a known process wherein ethylene is polymerized, or ethylene and an α-olefin are copolymerized under the presence of a titanium-based catalyst comprising a titanium compound and an organoaluminum compound or a vanadium-based catalyst comprising a vanadium compound and an organoaluminum compound.
A new series of Ziegler catalysts comprising a zirconium compound and an aluminoxane have also been recently proposed for polymerization of an olefin.
Japanese Patent Application Kokai No. 58-19309 describes a process for polymerizing ethylene and at least one C_{3-12 α}-olefin at a temperature of from -50 to 200°C under the presence of a catalyst comprising a transition metal-containing compound represented by the formula: (cyclopentadienyl)₂ MeRHal wherein R is selected from cyclopentadienyl, C_1-8 alkyl, and halogen. Me is a transition metal, and Hal is a halogen,
a linear aluminoxane represented by the formula: Al₂OR₄(Al(R)-O)_n wherein R is methyl or ethyl, and n is a number of 4 to 20, and
a cyclic aluminoxane represented by the formula:
wherein R and n are as defined above. There is also described that ethylene should be polymerized under the presence of a small amount, that is up to 10% by weight of an α-olefin having a somewhat longer chain or a mixture thereof to adjust a density of the resulting polyethylene.
Japanese Patent Application Kokal No. 59-95292 describes processes for preparing a linear aluminoxane represented by the formula:
wherein n is a number of 2 to 40 and R is a C_1-8 alkyl, and a cyclic aluminoxane represented by the formula:
wherein n and R are as described above. There is also disclosed that at least 25 million grams of polyethylene may be produced per 1 g of transition metal per hour when an olefin is polymerized under the presence of a mixture of, for example, methylaluminoxane prepared as described above and a bis-(cyclopentadienyl) compound containing titanium or zirconium.
Japanese Patent Application Kokai 60-35005 discloses a process for preparing an olefin-polymerization catalyst comprising effecting a reaction between a magnesium compound and an aluminoxane compound represented by the formula:
wherein R¹ is a C_1-10 alkyl radical, and R⁰ may represent R¹ or, taken together, form -O-; chlorinating the reaction product; and treating the product with Ti, V, Zr, or Cr-containing compound to produce an olefin-polymerizing catalyst. There is also disclosed that said catalyst is particularly preferable for copolymerizing ethylene with a C_3-12 α-olefin.
Japanese Patent Application Kokai No. 60-35006 discloses a catalyst system for polymers blended in a reactor which comprises a combination of (a) a mono-, di- or tri-cyclopentadienyl compound of at least two different transition metals, or a derivative thereof, and (b) an alumoxane (aluminoxane). Example 1 of this application discloses that a polyethylene having a number average molecular weight of 15,300, a weight average molecular weight of 36,400, and propylene content of 3.4% may be prepared by polymerizing ethylene and propylene by using bis(pentamethylcyclopentadietnyl)zirconium dimethyl and an alumoxane as catalyst. Example 2 discloses that a blend of polyethylene and ethylene-propylene copolymer having a number average molecular weight of 2,000, a weight average molecular weight of 8,300, and propylene content of 7.1 mol% comprising toluene-soluble portion having a number average molecular weight of 2,200, a weight average molecular weight of 11,900, and propylene content of 30 mol% and toluene-insoluble portion having a number average molecular weight of 3,000, a weight average molecular weight of 7,400, and propylene content of 4.8 mol% may be prepared by polymerizing ethylene and propylene by using bis(pentamethylcyclopentadienyl)zirconium dichloride, bis(methylcyclopentadienyl)zirconium dichloride, and an alumoxane as catalyst. Example 3 discloses a blend of LLDPE and ethylene-propylene copolymer comprising a soluble portion having a molecular weight distribution (Mw/Mn) of 4.57 and propylene content of 20.6 mol%, and an insoluble portion having a molecular weight distribution of 3.04 and propylene content of 2.9 mol%.
Japanese Patent Application Kokai No 60-35007 describes a process for polymerizing ethylene either alone or together with an α-olefin having at least 3 carbon atoms under the presence of a catalyst containing a metallocene and a cyclic alumoxane represented by the formula:
wherein R is a C_1-5 alkyl radical and n is an integer of 1 to 20, or a linear alumoxane represented by the formula:
wherein R and n are as described above. The polymer prepared by such a process has a weight average molecular weight of 500 to 1,400,000 and a molecular-weight distribution of 1.5 to 4.0.
Japanese Patent Application Kokai No. 60-35008 discloses that a polyethylene or an ethylene-C_3-10 α-olefin copolymer having a wide molecular-weight distribution may be prepared by using a catalyst system containing at least two metallocenes and an aluminoxane. There is also disclosed that said copolymer has a molecular-weight distribution (Mw/Mn) of 2 to 50.
The catalysts comprising a transition metal compound and an aluminoxane as proposed in the above-mentioned patent applications are provided with a significantly superior polymerization activity compared to the conventional catalyst systems prepared from a transition metal compound and an organoaluminum compound. These catalysts, however, are mostly soluble in the reaction system, and frequently require adoption of solution polymerization system.
On the other hand, attempts have been made to polymerize an olefin in dispersion or gas-phase polymerization systems by using catalysts wherein one or both of said transition metal compound and said aluminoxane are supported on a porous carrier of an inorganic oxide such as silica, silica-alumina, and alumina.
For example, aforementioned Japanese Patent Application Kokai Nos. 60-35006, 60-35007 and 60-35008 disclose that the transition metal compound and the aluminoxane supported on a carrier such as silica, slica-alumina, and alumina can also be used as catalysts.
Japanese Patent Application Kokai Nos. 60-106808 and 60-106809 disclose a process for preparing a composition comprising a polyethylene-based polymer and a filler which involves preliminarily contacting a high-activity catalyst component containing titanium and/or zirconium which is soluble in a hydrocarbon solvent with a filler, and then polymerizing ethylene or copolymeriaing ethylene and an α-olefin under the presence of the thus treated catalyst component, an organoaluminum compound, and a filler which has an affinity for a polyolefin.
Japanese Patent Application Kokai No. 61-31404 discloses a process for polymerizing ethylene or copolymerizing ethylene and an α-olefin under the presence of a mixed catalyst comprising a transition metal compound and a product obtained by reacting a trialkylaluminum and water under the presence of silicon dioxide or aluminum oxide.
Japanese Patent Application Kokai No. 61-276805 discloses a process for polymerizing an olefin under the presence of a catalyst comprising a reaction mixture between an inorganic oxide containing surface hydroxyl radical such as silica and a reaction mixture obtained by reacting a zirconium compound and an aluminoxane with a trialkylaluminum.
Japanese Patent Application Kokai Nos. 61-108610 and 61-296008 disclose a process for polymerizing an olefin under the presence of a catalyst comprising a transition metal compound such as a metallocene and an aluminoxane supported on a carrier such as an inorganic oxide.
However, when an olefin is polymerized or copolymerized in a dispersion or gas-phase polymerization system by utilizing the carrier-supported solid catalyst components as mentioned above, polymerization activity is markedly reduced and the properties inherent to the catalyst comprising the transition metal compound catalyst component and the aluminoxane catalyst component are not fully exerted. Powder properties such as bulk density of the thus prepared polymer were also insufficient. Moreover, the above-mentioned catalysts are attended by a practical problem that a large amount of expensive aluminoxane is required to achieve high polymerization activity, and the polymerization activity is low when a small amount of aluminoxane is used.
EP-A-0279863 discloses a catalyst for polymerization of α-olefins, which catalyst is formed by using a solid catalyst comprising
(A) a solid catalyst component composed of a compound of a transition metal of Group IVB of the periodic table supported on a carrier, and
(B) an aluminoxane.
EP-A-0120734 discloses a process for the preparation of a solid catalyst suitable for polymerizing olefins. The catalyst comprises a transition metal compound selected from Ti, V, Zr and Cr, a porous solid support, an organometallic compound of a group I to III metal and a polyolefin produced in a prepolymerization.
It has now been found that adoption of a particular carrier-supported solid catalyst component may enable production of a catalyst having a high polymerization activity even when a small amount of expensive aluminoxane is used. It has also been found that such catalysts are capable of producing an olefin polymer having excellent powder properties and narrow molecular-weight distribution or an olefin copolymer having both a narrow molecular-weight distribution and composition distribution when applied to the copolymerization of two or more olefins, particularly ethylene and another α-olefin.
According to the present invention, there is provided a process for preparing a solid catalyst for polymerizing an olefin or copolymerizing olefins the process comprising pretreating a fine particle carrier with an organoaluminium compound and an aluminoxane, and conducting preliminary olefin polymerisation in the presence of a transition metal compound and the pretreated fine particle carrier, wherein the organoaluminium compound is a trialkylaluminium comprising a branched alkyl radical, dialkylaluminium hydride comprising a branched alkyl radical or alkylaluminium alkoxide comprising a branched alkyl radical or a tricycloalkylaluminium or triarylaluminium compound and the transition metal compound is a zirconium compound of the formula (III), R¹ _kR² _lR³ _mR⁴ _nZr wherein R¹ is an optionally substituted cyclopentadienyl radical selected from cyclopentadienyl, methylcyclopentadienyl, ethylcyclopentadienyl, dimethylcyclopentadienyl, pentamethylcyclopentadienyl, indenyl and tetrahydroindenyl, R², R³ and R⁴ are independently; an optionally substituted cyclopentadienyl radical selected from cyclopentadienyl, methylcyclopentadienyl, ethylcyclopentadienyl, dimethylcyclopentadienyl, pentamethylcyclopentadienyl, indenyl and tetrahydroindenyl, aryl, alkyl, cycloalkyl, aralkyl, halogen, hydrogen, OR^a, SR^b, NR^c ₂ or PR^d ₂, wherein R^a, R^b, R^c and R^d are independently alkyl, cycloalkyl, aryl, aralkyl or silyl, with the proviso that R^c and R^d may together form a ring; k is at least 1; and the sum of k, I, m and n equals 4; and
wherein R¹ and R² may be bonded by an intervening ethylene group when R² is an optionally substituted cyclopentadienyl radical;
or a titanium compound selected from
bis(cyclopentadienyl)titanium monochloride monohydride,
bis(cyclopentadienyl)methyltitanium hydride,
bis(cyclopentadienyl)phenyltitanium chloride,
bis(cyclopentadienyl)benzyltitanium chloride,
bis(cyclopentadienyl)titanium dichloride,
bis(cyclopentadienyl)titanium dibenzyl,
bis(cyclopentadienyl)ethoxytitanium chloride,
bis(cyclopentadienyl)butoxytitanium chloride,
bis(cyclopentadienyl)methyltitanium ethoxide,
bis(cyclopentadienyl)phenoxytitanium chloride,
bis(cyclopentadienyl)trimethylsiloxytitanium chloride,
bis(cyclopentadienyl)thiophenyltitanium chloride,
bis(cyclopentadienyl)bis(dimethylamide)titanium
bis(cyclopentadienyl)diethoxytitanium,
ethylenebis(indenyl)titanium dichloride, and
ethylenebis(4,5,6,7-tetrahydro-1-indenyl)titanium dichloride;
or a hafnium compound selected from
bis(cyclopentadienyl)hafnium monochloride monohydride,
bis(cyclopentadienyl)ethylhafnium hydride,
bis(cyclopentadienyl)phenylhafnium chloride,
bis(cyclopentadienyl)hafnium dichloride,
bis(cyclopentadienyl)hafnium dibenzyl,
bis(cyclopentadienyl)ethoxyhafnium chloride,
bis(cyclopentadienyl)butoxyhafnium chloride,
bis(cyclopentadienyl)methylhafnium ethoxide,
bis(cyclopentadienyl)phenoxyhafnium chloride,
bis(cyclopentadienyl)thiophenylhafnium chloride,
bis(cyclopentadienyl)bis(diethylamide)hafnium,
ethylenebis(indenyl)hafnium dichloride, and
ethylenebis(4,5,6,7-tetrahydro-1-indenyl)hafnium dichloride.
The solid catalyst, however, may additionally contain optional components such as an electron donor.
The term polymerization used herein may include not only homopolymerization but also copolymerization. Similarly, the term polymer may include both homopolymer and copolymer.
The fine particle carrier is an inorganic or organic fine-particle carrier, having an average particle diameter generally in the range of from 1 to 300 µm, and preferably from 10 to 200 µm.
Suitably, the carrier is an inorganic oxide, most suitably SiO₂, Al₂O₃, MgO, ZrO₂, TiO₂, or a mixture thereof. Among these, a carrier primarily comprising at least an oxide selected from SiO₂, Al₂O₃, and MgO is preferably employed. The inorganic oxide carrier is calcined generally at 150 to 1000°C, preferably 200 to 800°C for 2 to 20 hours prior to its use.
The carrier may comprise an organic polymer and have an average particle diameter from 1 to 300 µm. The organic polymer is suitably a polyolefin such as polyethylene, polypropylene, poly-1-butene, poly-4-methyl-1-pentene, or a polystyrene. When the organoaluminium compound used to prepare the catalyst of the invention contains a branched alkyl radical, it suitably is an isoalkyl radical. The organoaluminium compound may also contain an n-alkyl group. Examples of trialkylaluminiums are triisopropylaluminium, triisobutylaluminium, tri(2-methylbutyl)aluminium, tri(3-methylbutyl)aluminium, tri(2-methylpentyl)aluminium, tri(3-methylpentyl)aluminium, tri(4-methylpentyl)aluminium, tri(2-methylhexyl)aluminium, tri(3-methylhexyl)-aluminium and tri(2-ethylhexyl)aluminium. Tricycloalkyl aluminiums are exemplified by tricyclohexyl aluminium. Triaryl aluminiums are exemplified by triphenylaluminium and tritolylaluminium. Dialkylaluminium hydrides are exemplified by diisobutylaluminium hydride. Alkylaluminium alkoxides are exemplified by isobutylaluminium methoxide, isobutylaluminium ethoxide and isobutylaluminium isopropoxide. Aluminoxanes prepared by reacting the above-mentioned organoaluminium compounds with water may be employed.
The aluminoxane constituting the olefin-polymerizing catalyst may be represented by the general formulae [I] or [II]:

wherein R is a C_1-20, preferably a C_1-4 hydrocarbon radical, and m has a value of 2 to 50, preferably 4 to 40, and most preferably 6 to 30. The hydrocarbon radicals represented by R include methyl, ethyl, propyl, isopropyl, isopropenyl, n-butyl, sec-butyl, tert-butyl, pentyl, hexyl, octyl, decyl, dodecyl, tridecyl, tetradecyl, hexadecyl, octadecyl, eicocyl, cyclohexyl, cyclooctyl, phenyl, ethylphenyl, etc. Among these, methyl, ethyl, and isobutyl are preferred, and methyl is most preferred. The aluminoxane component may also contain a halogenated aluminoxane wherein R in general formula [I] or [II] is a halogen atom such as chlorine or bromine, with the proviso that the halogen content is up to 40% by weight, and preferably up to 30% by weight.
The aluminoxane represented by the general formula [I] or [II] may be prepared by conventional known processes including:
(1) a process comprising preparing a hydrocarbon medium suspension of a compound containing absorbed water such as water-containing silica and water-containing alumina, or a salt containing water of crystallization such as hydrated magnesium chloride, hydrated copper sulfate, hydrated aluminum sulfate, hydrated nickel sulfate, and hydrated cerous chloride; and adding a trialkylaluminum into said suspension for reaction; and
(2) a process wherein water is directly reacted with a trialkylaluminum in a medium such as benzene, toluene, ethylether, and tetrahydrofuran.
Among these processes, process (1) is more preferable. A small amount of organometallic component may also be contained in the aluminoxane. For example, an organometallic compound such as a halogen-containing organoaluminum compound and organomagnesium compound may also be present with the trialkylaluminum.
The transition metal compound is preferably a titanium or zirconium compound, and more preferably is a zirconium compound.
A zirconium compound contains a cycloalkadienyl radical, which may be cyclopentadienyl, methylcyclopentadienyl, ethylcyclopentadienyl, dimethylcyclopentadienyl, pentamethylcyclopentadienyl, indenyl or tetrahydroindenyl. A zirconium compound of formula (III) also contains other radicals which are exemplified below. Examples of alkyl radicals include methyl, ethyl, propyl, isopropyl, butyl, hexyl, octyl, 2-ethylhexyl, decyl and oleil. Examples of aryl radicals include phenyl and tolyl. Examples of aralkyl radicals include benzyl and neophyl. Examples of cycloalkyl radicals include cyclopentyl, cyclohexyl, cyclooctyl, norbonyl, bicyclononyl and alkyl-substituted radicals thereof. Examples of silyl radicals include trimethylsilyl, triethylsilyl, phenyldimethylsilyl and triphenylsilyl. Unsaturated aliphatic radicals such as vinyl, allyl, propenyl, isopropenyl and 1-butenyl, and unsaturated cycloaliphatic radicals such as cyclohexenyl may also be employed. Examples of halogen atoms include fluorine, chlorine and bromine. Examples of lower alkylene radicals include methylene, ethylene, propylene and butylene.
Examples of the zirconium compounds include:
bis(cyclopentadienyl)zirconium monochloride monohydride;
bis(cyclopentadienyl)zirconium monobromide monohydride:
bis(cyclopentadienyl)methylzirconium hydride;
bis(cyclopentadienyl)ethylzirconium hydride;
bis(cyclopentadienyl)cyclohexylzirconium hydride;
bis(cyclopentadienyl)phenylzirconium hydride;
bis(cyclopentadienyl)benzylzirconium hydride;
bis(cyclopentadienyl)neopentylzirconium hydride;
bis(methylcyclopentadienyl)zirconium monochloride monohydride;
bis(indenyl)zirconium monochloride monohydride;
bis(cyclopentadienyl)zirconium dichloride;
bis(cyclopentadienyl)zirconium dibromide;
bis(cyclopentadienyl)methylzirconium monochloride;
bis(cyclopentadienyl)ethylzirconium monochloride;
bis(cyclopentadienyl)cyclohexylzirconium monochloride;
bis(cyclopentadienyl)phenylzirconium monochloride;
bis(cyclopentadienyl)benzylzirconium monochloride:
bis(methylcyclopentadienyl)zirconium dichloride:
bis(indenyl)zirconium dichloride;
bis(indenyl)zirconium dibromide;
bis(cyclopentadienyl)zirconium diphenyl;
bis(cyclopentadienyl)zirconium dibenzyl;
bis(cyclopentadienyl)methoxyzirconium chloride;
bis(cyclopentadienyl)ethoxyzirconium chloride:
bis(cyclopentadienyl)butoxyzirconium chloride;
bis(cyclopentadienyl)-2-ethylhexoxyzirconium chloride;
bis(cyclopentadienyl)methylzirconium ethoxide;
bis(cyclopentadienyl)methylzirconium butoxide;
bis(cyclopentadienyl)ethylzirconium ethoxide;
bis(cyclopentadienyl)phenylzirconium ethoxide;
bis(cyclopentadienyl)benzylzirconium ethoxide;
bis(methylcyclopentadienyl)ethoxyzirconium chloride;
bis(indenyl)ethoxyzirconium chloride;
bis(cyclopentadienyl)ethoxyzirconium;
bis(cyclopentadienyl)butoxyzirconium;
bis(cyclopentadienyl)-2-ethylhexoxyzirconium;
bis(cyclopentadienyl)phenoxyzirconium chloride;
bis(cyclopentadienyl)cyclohexoxyzirconium chloride;
bis(cyclopentadienyl)phenylmethoxyzirconium chloride;
bis(cyclopentadienyl)methylzirconium phenylmethoxide;
bis(cyclopentadienyl)trimethylsiloxyzirconium chloride;
bis(cyclopentadienyl)triphenylsiloxyzirconium chloride;
bis(cyclopentadienyl)thiophenylzirconium chloride;
bis(cyclopentadienyl)thioethylzirconium chloride;
bis(cyclopentadienyl)bis(dimethylamide)zirconium;
bis(cyclopentadienyl)diethylamidezirconium chloride;
ethylenebis(indenyl)ethoxyzirconium chloride;
ethylenebis(4,5,6,7-tetrahydro-1-indenyl)ethoxyzirconium chloride;
ethylenebis(indenyl)dimethylzirconium;
ethylenebis(indenyl)diethylzirconium;
ethylenebis(indenyl)diphenylzirconium;
ethylenebis(indenyl)dibenzylzirconium;
ethylenebis(indenyl)methylzirconium monobromide;
ethylenebis(indenyl)ethylzirconium monochloride;
ethylenebis(indenyl)benzylzirconium monochloride;
ethylenebis(indenyl)methylzirconium monochloride;
ethylenebis(indenyl)zirconium dichloride;
ethylenebis(indenyl)zirconium dibromide;
ethylenebis(4,5,6,7-tetrahydro-1-indenyl)dimethylzirconium;
ethylenebis(4,5,6,7-tetrahydro-1-indenyl)methylzirconium monochloride;
ethylenebis(4,5,6,7-tetrahydro-1-indenyl)zirconium dichloride;
ethylenebis(4,5,6,7-tetrahydro-1-indenyl)zirconium dibromide;
ethylenebis(indenyl)zirconium dimethoxide;
ethylenebis(indenyl)zirconium diethoxide;
ethylenebis(indenyl)methoxyzirconium chloride;
ethylenebis(indenyl)ethoxyzirconium chloride;
ethylenebis(indenyl)methylzirconium ethoxide;
ethylene bis(4,5,6,7-tetrahydro-1-indenyl)zirconium dimethoxide;
ethylenebis(4,5,6,7-tetrahydro-1-indenyl)zirconium ethoxide;
ethylenebis(4,5,6,7-tetrahydro-1-indenyl)methoxyzirconium chloride;
ethylenebis(4,5,6,7-tetrahydro-1-indenyl)ethoxyzirconium chloride;
ethylenebis(4,5,6,7-tetrahydro-1-indenyl)methylzirconium ethoxide.
Preferred zirconium compounds are:
bis(cyclopentadienyl)zirconium dichloride,
bis(cyclopentadienyl)zirconium dibromide,
bis(methylcyclopentadienyl)zirconium dichloride,
ethylenebis(indenyl)zirconium dichloride,
ethylenebis(indenyl)zirconium dibromide.
The olefin polymer produced in the preliminary polymerization may be polymer or a copolymer of ethylene, propylene, 1-butene, 1-hexene, 4-methyl-1-pentene, 1-octene, 1-decene, 1-dodecene, 1-tetradecene, 1-hexadecene, 1-octadecene or 1-eicocene. Among these, ethylene polymer and a copolymer of ethylene and a C_3-10 α-olefin are preferred.
The electron donor which may optionally be contained as a component of the olefin-polymerizing solid catalyst may typically be selected from carboxylic acids, esters, ethers, ketones, aldehydes, alcohols, phenols, acid amides, oxygen-containing compounds such as those containing metal-O-C bond, the metal being aluminium, silicon, nitriles, amines and phosphines. The sum of the aluminium atoms constituting the organoaluminium compound and the aluminoxane may be from 0.01 to 3 gram atoms, preferably from 0.05 to 2 gram atoms, and most preferably from 0.1 to 1 gram atoms per 100 g of the fine-particle carrier. The content of the transition metal compound calculated as transition metal atom may be from 3 x 10^-4 to 3 x 10^-1 gram atoms, preferably from 5 x 10^-4 to 5 x 10^-2 gram atoms, and most preferably from 1 x 10-³ to 1 x 10^-2 gram atoms per 100 g of the fine-particle carrier. The content of the α-olefin polymer prepared by the preliminary polymerization may be from 5 to 1 x 10⁴ g, preferably from 10 to 5 x 10³ g, and most preferably from 20 to 3 x 10³ g per 100 g of the fine-particle carrier. The solid catalyst may optionally contain from 0 to 1 mole, preferably from 0.1 to 0.6 mole of the electron donor per 1 gram atom of the transition metal atom (M). In the olefin-polymerizing solid catalyst, the gram atom ratio of the sum of the aluminium atoms (M₁) constituting the organoaluminium compound and the aluminium atoms (M₂) constituting the aluminoxane to the transition metal atoms (M), namely, (M₁ + M₂)/M may be in the range of from 15 to 500, preferably from 20 to 200, more preferably 25 to 150, and most preferably from 30 to 100.
The catalyst may be prepared by a process comprising mixing the organoaluminium compound the aluminoxane and the fine-particle carrier, in any order, adding the transition metal compound to the mixture thus produced and preliminarily polymerising the olefin in the presence of the mixture and transition metal compound. Processes for preparing the fine-particle carrier pretreated with the organoaluminum compound and the aluminoxane include:
(1) treating the carrier with the organaluminum compound, and further treating the carrier with the aluminoxane;
(2) simultaneously treating the carrier with the organoaluminum compound and the aluminoxane; and
(3) treating the carrier with the aluminoxane, and further treating the carrier with the organoaluminum compound. Among these processes, process (1) is preferable since this process is capable of producing an olefin-polymerizing solid catalyst exhibiting a particularly superior polymerization activity. In these processes, the fine-particle carrier is treated by utilizing a solution of the organaluminum compound, a solution of a mixture of the organoaluminum compound and the aluminoxane, or a solution of the aluminoxane. In the solution of the organoaluminum compound, the concentration of the compound is generally 0.05 to 3 gram atoms/liter, and preferably 0.1 to 1 gram atom/liter calculated as aluminum atom. In the solution of a mixture of the organoaluminum compound and the aluminoxane, concentration of the organoaluminum compound is generally 0.01 to 2 gram atoms/liter, and preferably 0.05 to 0.5 gram atoms/liter calculated as aluminum atom, and concentration of the aluminoxane is generally 0.02 to 2 gram atoms/liter, and preferably 0.1 to 1 gram atom/liter calculated as aluminum atom. In the solution of the aluminoxane, the concentration of the aluminoxane is generally 0.1 to 3 gram atoms/liter, and preferably 0.2 to 2 gram atoms/liter calculated as aluminum atom. In the reaction of said treatment, the organoaluminum compound is employed generally from 0.01 to 5 gram atoms, and preferably from 0.05 to 3 gram atoms calculated as organoaluminum atom per 100 g of the fine-particle carrier, and the aluminoxane is employed generally from 0.05 to 10 gram atoms, and preferably from 0.1 to 5 gram atoms calculated as aluminum atom per 100 g of the fine-particle carrier. In these processes, the temperature of the reaction system is generally from -50°C to 110°C, and preferably from 0°C to 80°C in the case of treating with the solution of the organoaluminum compound; generally from -50°C to 110°C, and preferably from 0°C to 90°C in the case of treating with the solution of a mixture of the organoaluminum compound and the aluminoxane; and generally from -50°C to 110°C, and preferably from 0°C to 90°C in the case of treating with the aluminoxane solution. In any of these processes, the time required for the treatment is generally from 1 minute to 2 hours.In any of these processes, said contact treatments are carried out with the fine-particle carrier suspended in an inert solvent. For example, the fine-particle carrier may be suspended in the inert solvent, the contact treatment may then be effected by adding the solution of the organoaluminum compound. the solution of a mixture of the organoaluminum compound and the aluminoxane, or the aluminoxane solution into the suspension.In the above-described treatments, the proportion of the organoaluminum compound and the aluminoxane supported on the fine-particle carrier may be selected depending on the above-specified treating conditions such that the final olefin-polymerizing solid catalyst may comprise the catalyst components at predetermined contents.In the above-described treatments, the solution of the organoaluminum compound. the solution of a mixture of the organoaluminum compound and the aluminoxane, and the aluminoxane solution may typically comprise a solvent, for example, an aliphatic hydrocarbon such as pentane, hexane, heptane, octane, decane, dodecane, keroseine or gas oil; an alicyclic hydrocarbon such as cyclohexane, cyclooctane or cyclodecane; or an aromatic hydrocarbon such as benezene, toluene, ethylbenezene, xylene or cumene.In treating the fine-particle carrier with the aluminoxane by such a process as above-described (1), (2) and (3), the aluminoxane to be supported on the fine-particle carrier may preferably be precipitated by contacting the aluminoxane solution with a solvent to which the aluminoxane is insoluble or hardly soluble in order to obtain an olefin-polymerizing solid catalyst having a superior polymerization activity. Illustrative aluminoxane treatments of the fine-particle carrier include the processes (4), (5), (6), and (7) as described below.
(4) An aluminoxane supported on a fine-particle carrier may be prepared by preparing a suspension of the fine-particle carrier or the fine-particle carrier pretreated with the organoaluminum compound dispersed in a solvent used for dissolving aluminoxane, contacting the aluminoxane or the aluminoxane solution with said suspension, and contacting said suspension with a solvent in which the aluminoxane is either insoluble or hardly soluble. Specifically, the aluminoxane supported by the fine-particle carrier may be prepared by preparing a suspension comprising the solvent used for dissolving the aluminoxane and the fine-particle carrier or the fine-particle carrier pretreated with the organoaluminum compound; contacting said suspension with the aluminoxane or the aluminoxane solution to generate a suspension containing both the aluminoxane and the fine-particle carrier; and adding the solvent to which the aluminoxane is either insoluble or hardly soluble to said suspension to precipitate the aluminoxane onto the fine-particle carrier. The aluminoxane may also be precipitated by adding said suspension containing both the aluminoxane and the fine-particle carrier to the solvent to which the aluminoxane is either insoluble or hardly soluble. The aluminoxane precipitation may further be promoted by evaporating off the solvent capable of dissolving the aluminoxane from said mixed suspension.The proportion of the solvent in which the aluminoxane is, either insoluble or hardly soluble may generally be in the range of from 10 to 10,000 parts by weight, and preferably from 100 to 1,000 parts by weight based on 100 parts by weight of the aluminoxane-dissolving solvent present in the suspension of the fine-particle carrier. The contact treatment is generally carried out with agitation at a temperature of from -50°C to 110°C, preferably from 0°C to 90°C, and more preferably from 0°C to 80°C.The aluminoxane solution is prepared at least from the aluminoxane and the solvent capable of dissolving the aluminoxane which will be exemplified later. The aluminoxane solution may be obtained by simply mixing both compounds, or by mixing both compounds under heating. The solvent included in the aluminoxane solution may generally be from 0.1 to 50 liters, preferably from 0.2 to 10 liters, and more preferably from 0.3 to 2 liters per 1 gram atom of aluminum in the aluminoxane.
(5) An aluminoxane-supported fine-particle carrier may also be prepared by preparing a suspension of the fine-particle carrier or the fine-particle carrier pretreated with the organoaluminum compound dispersed in the aluminoxane solution, and contacting the suspension with the solvent in which the aluminoxane is either insoluble or hardly soluble. Specifically, the aluminoxane supported by the fine-particle carrier may be prepared by preparing a suspension comprising the aluminoxane solution and the fine-particle carrier or the fine-particle carrier pretreated with the organoaluminum compound; and adding the solvent in which the aluminoxane is either insoluble or hardly soluble to the suspension to precipitate the aluminoxane onto he fine-particle carrier The aluminoxane may also be precipitated by adding said suspension comprising the aluminoxane solution and the carrier to the solvent to which the aluminoxane is either insoluble or hardly soluble. The aluminoxane precipitation may further be promoted by evaporating off the solvent used for dissolving the aluminoxane from said mixed suspension.In the above-described treatment, the proportion of the solvent in which the aluminoxane is either insoluble or hardly soluble may generally be in the range of from 10 to 10,000 parts by weight, and preferably from 100 to 1,000 parts by weight based on 100 parts by weight of the aluminoxane solution. The contact treatment is generally carried out with agitation at a temperature of from -50°C to 110°C, preferably from 0°C to 90°C, and more preferably from 0°C to 80°C.
(6) An aluminoxane supported by a fine-particle carrier may be prepared by preparing a suspension of the fine-particle carrier or the fine-particle carrier pretreated with the organoaluminum compound dispersed in the solvent in which the aluminoxane is either insoluble or hardly soluble, and contacting the aluminoxane solution with the suspension.
Specifically, the aluminoxane-supported fine-particle carrier may be prepared by preparing a suspension of the fine-particle carrier or the fine-particle carrier pretreated with the organoaluminum compound dispersed in the solvent in which the aluminoxane is either insoluble or hardly soluble, and adding the aluminoxane solution to the suspension to precipitate the aluminoxane onto the fine-particle carrier. The aluminoxane may also be precipitated by adding said suspension comprising the solvent to which the aluminoxane is either insoluble or hardly soluble and the fine-particle carrier to the aluminoxane solution. The aluminoxane precipitation may further be promoted by evaporating off the solvent used for dissolving the aluminoxane from said mixed suspension.
The suspension and the aluminoxane solution may generally be contacted with agitation at a temperature of from -50°C to 110°C, preferably from 0°C to 90°C, and more preferably from 0°C to 80°C. The proportion of the aluminoxane solution may generally be in the range of from 1 to 1,000 parts by weight, and preferably from 10 to 100 parts by weight based on 100 parts by weight of the suspension.
The aluminoxane solution is prepared at least from the aluminoxane and the solvent capable of dissolving the aluminoxane which will be exemplified later. The aluminoxane solution may be obtained by simply mixing both compounds, or by mixing both compounds under heating. The solvent included in the aluminoxane solution may generally be from 0.1 to 50 liters, preferably from 0.2 to 10 liters, and more preferably from 0.3 to 2 liters per 1 gram atom of aluminum in the aluminoxane.
The solvents which are capable of dissolving the aluminoxane include aromatic hydrocarbons such as benzene, toluene, ethylbenzene, propylbenzene, butylbenzene, xylene and chlorobenzene. The solvents in which the aluminoxane is either insoluble or hardly soluble include linear and branched aliphatic hydrocarbons such as pentane, hexane, decane, dodecane and kerosin, and alicyclic hydrocarbons such as cyclohexane, norbornane and ethylcyclohexane. The solvent in which the aluminoxane is either insoluble or hardly soluble may preferably have a higher boiling point than the solvent used for dissolving the aluminoxane.
The olefin-polymerizing solid catalyst is prepared by subjecting the fine-particle carrier treated with the organoaluminum compound and the aluminoxane according to such a process as above-mentioned (4), (5) or (6) to a contact treatment with the transition metal and the preliminary polymerization. For example, the olefin-polymerizing solid catalyst may be prepared by contacting the suspension of the fine-particle carrier treated with the organoaluminum compound and the aluminoxane with the transition metal compound, and then introducing the olefin into the suspension for the preliminary polymerization. The transition metal compound is supported on the carrier by the preliminary polymerization.
In contacting the fine-particle carrier treated with the organoaluminum compound and the aluminoxnane with the transition metal compounds, the amount of the transition metal compound used may range from 2 x 10^-4 to 5 x 10^-2 gram atoms, and preferably 1 x 10^-3 to 1 x 10^-2 gram atoms per 100 g of the fine-particle carrier. The temperature during the contact treatment may generally be from -50°C to 150°C, and preferably from 0 to 100°C.
The preliminary polymerization is carried out in an inert hydrocarbon medium. In the preliminary polymerization treatment, the concentration of the transition metal compound is generally 1 x 10^-4 to 5 x 10^-2 gram atoms/liter, and preferably 5 x 10^-4 to 1 x 10^-2 gram atoms/liter. The inert hydrocarbon medium used for the preliminary polymerization may typically be the solvents constituting said solution of the organoaluminum compound or the aluminoxane. Among these solvents, aliphatic hydrocarbons such as hexane, heptane, octane and decane, and alicyclic solvents such as cyclohexane and cyclooctane are preferred.
The preliminary polymerization may generally be carried out at a temperature of from -20°C to 70 °C, preferably from -10°C to 60°C, and most preferably from 0°C to 50°C.
The olefin-polymerizing solid catalyst may be obtained by removing solvent-soluble catalyst components by a filtration or decantation after the preliminary polymerization.
The amounts of the catalyst components such as the transition metal compound, the organoaluminum compound, the aluminoxane, and the olefin polymer produced by the preliminary polymerization supported on the fine-particle carrier in the preparation of the olefin-polymerizing catalyst are selected depending on the above-specified preparation conditions such that the content of each of the catalyst components in the final catalyst is within the predetermined range.
The catalyst is effective for producing an olefin polymer, particularly ethylene polymer and an ethylene-α-olefin copolymer. Examples of the olefins which can be polymerized by the catalyst of the present invention include C_2-20 α-olefins, such as ethylene, propylene, 1-butene, 1-hexene, 4-methyl-1-pentene, 1-octene, 1-decene, 1-dodecene, 1-tetradecene, 1-hexadecene, 1-octadecene and 1-eicocene. The catalyst is particularly suitable for polymerizing ethylene, or copolymerizing a C_3-10 α-olefin with ethylene.
In an olefin polymerizaion employing a catalyst according to the present invention, olefins are polymerized by a gas-phase polymerization or a slurry polymerization. In slurry polymerization, either an inert hydrocarbon or the olefin itself may be used as a solvent.
Illustrative hydrocarbon media are aliphatic hydrocarbons such as butane, isobutane, pentane, hexane, octane, decane, dodecane, hexadecane and octadecane; alicyclic hydrocarbons such as cyclopentane, methylcyclopentane, cyclohexane and cyclooctane; and petroleum cuts such as kerosine and gas oil.
Slurry polymerization utilizing the catalyst may generally be carried out at a temperature of from -50°C to 120°C, and preferably from 0°C to 100°C.
Gas-phase polymerization utilizing the catalyst may generally be carried out at a temperature in the range of from 0°C to 120°C, and preferably from 20°C to 100°C.
The amount of the transition metal compound used in slurry polymerization or gas-phase polymerization utilizing the catalyst may generally be in the range of 10^-8 to 10^-2 gram atoms/liter, and preferably 10^-7 to 10^-3 gram atoms/liter as a concentration of the transition metal atom in the polymerization system.
An additional aluminoxane or organoaluminum compound having a general formula: R^h _pRⁱ _qAlX_3-p-q may optionally be employed in the practice of the above-described olefin polymerization. R^h is a C_1-10 hydrocarbon, preferably a C_1-6 alkyl, alkenyl, cycloalkyl, or aryl radical, Rⁱ is a C_1-6 alkoxy, or aryloxy radical, X is a halogen atom, p is 3 ≧ p > 0, and q is 2 ≧ q ≧ 0.
The olefin polymerization may generally be carried out at a pressure of standard atmospheric pressure to 9.8 x 10⁶ Pa (100 kg/cm²), and preferably from 1.96 x 10⁵ to 4.9 x 10⁶ Pa (2 to 50 kg/cm²). The polymerization may be carried out by a batch method, semi-continuous method or continuous method.
Further, the polymerization may be carried out in two or more steps corresponding to different reaction conditions.
When the slurry polymerization or the gas-phase polymerization, particularly the gas-phase polymerization is carried out for polymerizing an olefin, particularly for polymerizing ethylene or copolymerizing ethylene and an α-olefin by using the olefin-polymerizing solid catalyst the resulting polymer does not deposit on the reactor wall. Moreover, the resulting polymer has excellent powder properties and narrow molecular-weight distribution. In the case of copolymerizing two or more olefins, the resulting polymer has both narrow molecular-weight distribution and composition distribution. Even when a significantly smaller amount of aluminoxane compared to conventional processes is used, the catalyst may still be able to produce high-molecular weight polymers with high activity.
In the following Examples and Comparative Examples, the melt flow rate (MFR) is measured at a temperature of 190°C and under a load of 2.16 kg, and the value of Mw/Mn is measured as described hereinafter according to the process described in Takeuchi et al., "Gel Permeation Chromatography", Maruzen K.K., Tokyo, 1976.
(1) Using a polystyrene having a known molecular weight (a monodisperse polystyrene manufactured by Toyo Soda Mfg. K.K.) as a standard, a molecular weight M and gel permeation chromatograph (GPC) counts are measured to plot a calibration curve between the molecular weight M and the elution volume (EV). The concentration at this stage is 0.02 % by weight.
(2) A GPC chromatogram of the sample was depicted by measuring on GPC. The number average molecular weight Mn and the weight average molecular weight Mw calculated as polystyrene are determined from the calibration curve plotted in (1) to find out the value of Mw/Mn. Samples were prepared and measured on GPC as described below.

Sample preparation

(a) The sample and o-dichlorobenzene solvent are added to an Erlenmeyer flask so that the concentration of the sample is 0.1 % by weight.
(b) The Erlenmeyer flask is heated to 140°C and agitated for 30 minutes to dissolve the sample.
(c) The solution is applied to GPC.

Measurement on GPC

The following conditions were used.
(a) equipment: 150C-ALC/GPC manufactured by Waters Co.
(b) column: GMH type manufactured by Toyo Soda Mfg. K.K.)
(c) Sample volume: 400 µl
(d) temperature: 140°C
(e) flow rate: 1 ml/min.
The amount of n-decane-soluble portion in the copolymer was measured by adding about 3 g of the copolymer into 450 ml of n-decane, dissolving the copolymer at 145°C, gradually cooling the solution to 23°C, removing n-decane-insoluble portion by filtering the solution, and recovering the n-decane-soluble portion from the filtrate. The amount of the n-decane-soluble portion is indicative of the composition distribution, and a smaller soluble portion indicates a narrower composition distribution.

Example 1

Preparation of aluminoxane

A 400 ml flask was fully purged with nitrogen and charged with 37 g of Al₂(SO₄)₃.14H₂O and 125 ml of toluene, and cooled to 0°C. To this solution, 500 mmol of trimethylaluminum diluted with 125 ml of toluene was added dropwise. The solution was then heated to 35°C, and reacted at this temperature for 10 hours. After the reaction, solid was removed by filtration, and toluene was removed from the filtrate. 11 g of white solid aluminoxane was obtained. The molecular weight determined by cryoscopy in benzene was 810, and the value of m in formulae [I] and [II] was 12.

Preparation of solid catalyst (zirconium catalyst)

A 100 ml flask was fully purged with nitrogen, and charged with 2.7 g of silica (F-952 manufactured by Fuji Devison K.K.) which had been calcined at 700°C for 6 hours and 15 ml of toluene to produce a suspension. To the suspension. 13.5 ml of toluene solution of triisobutylaluminum (Al. 1 mol/ℓ) was added, and agitated at 23°C for 30 minutes. Subsequently, 18 ml of toluene solution of the aluminoxane (Al, 1.25 mol/ℓ) was added and agitated at 23 ° C for another 10 minutes. To this solution, 30 ml of n-decane was added, and toluene was removed at a temperature of 50°C and at a reduced pressure of 267 Pa (2 mmHg). The removal of toluene required 85 minutes. To the thus obtained fine-particle solid suspended in n-decane, 4.5 ml of toluene solution of bis(cyclopentadienyl)zirconium dichloride (Zr, 0.04 mol/ℓ) was added, and toluene was again removed at a temperature of 50°C and at a reduced pressure of 267 Pa (2 mmHg). The toluene removal required 45 minutes. To said suspension, an additional 100 ml n-decane was added, and ethylene gas at atmospheric pressure was continuously introduced thereto to effect a preliminary polymerization at 35°C for 2 hours. Subsequently, n-decane was removed by filtration, and the reaction mixture was washed three times with hexane at 60 ° C. As a result of such a procedure, a catalyst containing 5.0 x 10^-3 gram atoms of Zr, 0.55 gram atoms of Al, and 280 g of polyethylene per 100 g of silica was obtained.

Polymerization

A stainless autoclave having an internal volume of 2 liters was fully purged with nitrogen and charged with 250 g of sodium chloride (special grade, manufactured by Wako Pharmaceutical K.K.), which was then dried at a temperature of 90 ° C at a reduced pressure for 1 hour. The reaction system was cooled to 75 ° C, and 0.015 mg atom calculated as zirconium atom of said solid catalyst was added. 50 ml of hydrogen was introduced, ethylene was introduced at 75°C to start polymerization, and a total pressure was set at 7.84 x 10⁵ Pa-g (8 kg/cm²-G). The polymerization was continued at 80°C for 1 hour while the total pressure was kept at 7.84 x 10⁵ Pa-G (8 kg/cm²) by feeding ethylene. After completion of the polymerization, sodium chloride was removed by washing with water, and the remaining polymer was washed with hexane and dried at a temperature of 80°C and at a reduced pressure for overnight.
There was obtained 154 g of a spherical polymer having MFR of 0.008 g/min (0.08 g/10 min), Mw/Mn of 2.61, and bulk density of 0.38 g/cm³. The polymer had an average particle diameter of 280 µm. Deposition of the polymer onto the autoclave wall was not recognized.

Examples 2 to 11, 13, and 14

The procedure of Example 1 was repeated except that the zirconium catalysts were prepared under the conditions as specified in Table 1.
Polymerization was carried out in an exactly the same manner as Example 1. The results are shown in Table 2.

Example 12

The procedure of Example 1 was repeated except that a mixed gas of ethylene and propylene (propylene, 3 mol%) was employed and the catalyst was prepared under the conditions as specified in Table 1.
Polymerization was carried out in a similar manner as Example 1 except for that 0.01 mg atom calculated as zirconium atom of the solid catalyst was employed.
The results are shown in Tables 1 and 2.

Example 15

The procedure of Example 2 was repeated except that 10 ml of 1-hexene was added, 0.01 mg atom calculated as zirconium atom of catalyst was employed, and polymerization was carried out for 30 minutes without adding hydrogen. There was obtained 60 g of a spherical polymer having MFR of 0.058 g/min (0.58 g/10 min), Mw/Mn of 2.49, bulk density of 0.35 g/cm³, density of 0.931 g/cm³, and content of the decane-soluble portion at room temperature of 0.11% by weight. The polymer had an average particle diameter of 230 µm. Deposition of the polymer onto the autoclave wall was not recognized.

Example 16

The catalyst preparation procedure of Example 2 was repeated except for that silica (Microbeads manufactured by Fuji Devison K.K., specific surface area, 73 m²/g, particle diameter, 30 to 70 µm) was employed as a fine-particle carrier. The resulting catalyst had 3.7 x 10^-3 gram atom of Zr, 0.40 gram atom of Al, and 350 g of polyethylene per 100 g of silica.
Polymerization was carried out in an exactly same manner as Example 2 by using the thus prepared catalyst. There was obtained 101 g of spherical polymer having MFR of 0.013 g/min (0.13 g/10 min). Mw/Mn of 2.52, and bulk density of 0.45 g/cm³ and particle diameter of 320 µm.
Deposition of the polymer onto the autoclave wall was not recognized.

Example 17

Preparation of solid catalyst (zirconium catalyst)

A 100 ml flask was fully purged with nitrogen, and charged with 3.0 g of silica used in Example 1 and 15 ml of n-decane to produce a suspension. To the suspension, 10 ml of decane solution of triisobutylaluminum (Al, 1 mol/l) was added, and agitated at 23°C for 30 minutes. Subsequently, 21 ml of the aluminoxane suspension in decane (Al, 1.2 mol/l) was added and agitated at 23°C for another 10 minutes. 5 ml toluene solution of bis(cyclopentadienyl)zirconium dichloride (Zr, 0.04 mol/l) was added, and toluene was removed at a temperature of 50°C and at a reduced pressure of 267 Pa (2 mmHg). The toluene removal required 30 minutes. To said suspension, an additional 100 ml n-decane was added, and ethylene gas at atmospheric pressure was continuously introduced thereto to effect a preliminary polymerization at 35°C for 2 hours. The procedure of Example 1 was subsequently repeated and a catalyst containing 3.4 x 10^-3 gram atoms of Zr, 0.35 gram atoms of Al, and 650 g of polyethylene per 100 g of silica was obtained.

Polymerization

The procedure of Example 1 was exactly repeated. There was obtained 134 g of a spherical polymer having MFR of 0.10 g/10 min., Mw/Mn of 2.66, and bulk density of 0.40 g/cm³. The polymer had an average particle diameter of 330 µm.
Deposition of the polymer onto the autoclave wall was not recognized.

Comparative Example 1

Preparation of solid catalyst (zirconium catalyst)

The procedure of Example 15 was repeated except for that triisobutylaluminum was not used. There was obtained a catalyst containing 6.7 x 10^-3 gram atoms of Zr, 0.32 gram atoms of Al, and 15 g of polyethylene per 100 g of silica.

Polymerization

The procedure of Example 15 was exactly repeated. The polymer obtained was only 3 g.

Comparative Example 2

The procedure of Example 2 was repeated except for that no alummoxane was used in the procedure of the preparation of solid catalyst. The resulting catalyst did not exhibit any polymerization activity.

Claims

A process for preparing a solid catalyst for polymerising an olefin or copolymerising olefins, the process comprising
pretreating a fine particle carrier with an organoaluminum compound and an aluminoxane, and
conducting preliminary olefin polymerisation in the presence of a transition metal compound and the pretreated fine particle carrier,
wherein the organoaluminum compound is a trialkylaluminum comprising a branched alkyl radical, a dialkylaluminum hydride comprising a branched alkyl radical or an alkyaluminum alkoxide comprising a branched alkyl radical, a tricycloalkylaluminum or a triarylaluminum compound, and
the transition metal compound is a zirconium compound of formula (III) R¹ _kR² _lR³ _mR⁴ _nZr wherein R¹ is an optionally substituted cyclopentadienyl radical selected from cyclopentadienyl, methylcyclopentadienyl, ethylcyclopentadienyl, dimethylcyclopentadienyl, pentamethylcyclopentadienyl, indenyl and tetrahydroindenyl, R², R³ and R⁴ are independently optionally substituted cyclopentadienyl radical selected from cyclopentadienyl, methylcyclopentadienyl, ethylcyclopentadienyl, dimethylcyclopentadienyl, pentamethylcyclopentadienyl, indenyl and tetrahydroindenyl, aryl, alkyl, cycloalkyl, aralkyl, halogen, hydrogen, OR^a, SR^b, NR^c ₂ or PR^d ₂, wherein R^a, R^b, R^c and R^d are independently alkyl, cycloalkyl, aryl, aralkyl or silyl, with the proviso that R^c and R^d may together form a ring; k is at least 1; and the sum of k, I, m and n equals 4; and
wherein R¹ and R² may be bonded by an intervening ethylene group when R² is an optionally substituted cyclopentadienyl radical;
or a titanium compound selected from
bis(cyclopentadienyl)titanium monochloride monohydride,
bis(cyclopentadienyl)methyltitanium hydride,
bis(cyclopentadienyl)phenyltitanium chloride,
bis(cyclopentadienyl)benzyltitanium chloride,
bis(cyclopentadienyl)titanium dichloride,
bis(cyclopentadienyl)titanium dibenzyl,
bis(cyclopentadienyl)ethoxytitanium chloride,
bis(cyclopentadienyl)butoxytitanium chloride,
bis(cyclopentadienyl)methyltitanium ethoxide,
bis(cyclopentadienyl)phenoxytitanium chloride,
bis(cyclopentadienyl)trimethylsiloxytitanium chloride,
bis(cyclopentadienyl)thiophenyltitanium chloride,
bis(cyclopentadienyl)bis(dimethylamide)titanium,
bis(cyclopentadienyl)diethoxytitanium,
ethylenebis(indenyl)titanium dichloride, and
ethylenebis(4,5,6,7-tetrahydro-1-indenyl)titanium dichloride;
or a hafnium compound selected from
bis(cyclopentadienyl)hafnium monochloride monohydride,
bis(cyclopentadienyl)ethylhafnium hydride,
bis(cyclopentadienyl)phenylhafnium chloride,
bis(cyclopentadienyl)hafnium dichloride,
bis(cyclopentadienyl)hafnium dibenzyl,
bis(cyclopentadienyl)ethoxyhafnium chloride,
bis(cyclopentadienyl)butoxyhafnium chloride,
bis(cyclopentadienyl)methylhafnium ethoxide,
bis(cyclopentadienyl)phenoxyhafnium chloride,
bis(cyclopentadienyl)thiophenylhafnium chloride,
bis(cyclopentadienyl)bis(diethylamide)hafnium,
ethylenebis(indenyl)hafnium dichloride, and
ethylenebis(4,5,6,7-tetrahydro-1-indenyl)hafnium dichloride.
A process according to claim 1 wherein the preliminary polymerisation is carried out in the presence of an inert hydrocarbon medium.
A process according to claim 1 or 2 wherein the fine-particle carrier comprises an inorganic oxide having an average particle diameter from 1 to 300 µm.
A process according to claim 3 wherein the carrier comprises at least one oxide selected from the group consisting of SiO₂, Al₂O₃, and MgO.
A process according to claim 1 or 2 wherein the fine-particle carrier comprises an organic polymer and has an average particle diameter from 1 to 300 µm.
A process according to claim 5 wherein the carrier comprises a polyolefin.
A process according to any one of the preceding claims wherein the aluminoxane comprises a compound represented by the formula [I] or [II]:

wherein R is a C_1-20 hydrocarbon radical and m is from 2 to 50.
A process according to any one of the preceding claims wherein the transition metal compound is:

bis(cyclopentadienyl)zirconium dichloride,

bis(cyclopentadienyl)zirconium dibromide,

bis(methylcyclopentadienyl)zirconium dichloride,

ethylenebis(indenyl)zirconium dichloride,

ethylenebis(indenyl)zirconium dibromide.
A process of polymerising an olefin or co-polymerising olefins which process comprises producing a catalyst according to any one of the preceding claims and conducting the polymerisation of at least one olefin in the presence of the catalyst.