EP0543022A4 - Process for producing styrenic polymer and catalyst therefor - Google Patents

Process for producing styrenic polymer and catalyst therefor

Info

Publication number
EP0543022A4
EP0543022A4 EP19920911400 EP92911400A EP0543022A4 EP 0543022 A4 EP0543022 A4 EP 0543022A4 EP 19920911400 EP19920911400 EP 19920911400 EP 92911400 A EP92911400 A EP 92911400A EP 0543022 A4 EP0543022 A4 EP 0543022A4
Authority
EP
European Patent Office
Prior art keywords
styrenic polymer
catalyst
highly syndiotactic
catalyst therefor
producing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP19920911400
Other versions
EP0543022B1 (en
EP0543022A1 (en
Inventor
Shoji Naganuma
Masami Watanabe
Norio Tomotsu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Idemitsu Kosan Co Ltd
Original Assignee
Idemitsu Kosan Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Idemitsu Kosan Co Ltd filed Critical Idemitsu Kosan Co Ltd
Publication of EP0543022A1 publication Critical patent/EP0543022A1/en
Publication of EP0543022A4 publication Critical patent/EP0543022A4/en
Application granted granted Critical
Publication of EP0543022B1 publication Critical patent/EP0543022B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Abstract

A catalyst comprising a transition metal compound, such as pentamethylcyclopentadienyltitaniumtrimethyl, and a coordination compound formed between a quaternary ammonium salt and an anion comprising two or more groups bonded to a metal atom, such as O-cyano-N-methylpyridinium tetra(pentafluorophenyl)borate, and another catalyst comprising the above catalyst and an alkylating agent, such as triisobutylaluminum, suitable for the production of a highly syndiotactic styrenic polymer. A process for producing a highly syndiotactic styrenic polymer by polymerizing a styrenic monomer in the presence of the above catalyst. It is thereby possible to produce a highly syndiotactic styrenic polymer efficiently without the necessity for using expensive aluminoxane in a large amount.
EP92911400A 1991-06-12 1992-06-09 Process for producing styrenic polymer and catalyst therefor Expired - Lifetime EP0543022B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP3139955A JPH04366109A (en) 1991-06-12 1991-06-12 Preparation of styrene polymer and catalyst therefor
JP139955/91 1991-06-12
PCT/JP1992/000736 WO1992022589A1 (en) 1991-06-12 1992-06-09 Process for producing styrenic polymer and catalyst therefor

Publications (3)

Publication Number Publication Date
EP0543022A1 EP0543022A1 (en) 1993-05-26
EP0543022A4 true EP0543022A4 (en) 1994-11-23
EP0543022B1 EP0543022B1 (en) 1998-02-04

Family

ID=15257566

Family Applications (1)

Application Number Title Priority Date Filing Date
EP92911400A Expired - Lifetime EP0543022B1 (en) 1991-06-12 1992-06-09 Process for producing styrenic polymer and catalyst therefor

Country Status (6)

Country Link
US (1) US5391661A (en)
EP (1) EP0543022B1 (en)
JP (1) JPH04366109A (en)
AT (1) ATE163018T1 (en)
DE (1) DE69224353T2 (en)
WO (1) WO1992022589A1 (en)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05331228A (en) * 1971-11-18 1993-12-14 Idemitsu Kosan Co Ltd Production of polyolefin
US5384299A (en) * 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
EP0698619B1 (en) * 1993-03-31 2001-11-07 Idemitsu Kosan Company Limited Catalyst for producing vinyl polymer and process for producing vinylaromatic polymer
JPH0733812A (en) * 1993-07-02 1995-02-03 Idemitsu Kosan Co Ltd Catalyst for styrene polymerization and production of styrene polymer thereby
JP3216748B2 (en) * 1993-07-23 2001-10-09 出光興産株式会社 Catalyst for producing aromatic vinyl compound polymer composition and method for producing aromatic vinyl compound polymer composition using the same
US5428120A (en) * 1993-10-08 1995-06-27 The Dow Chemical Company Process for preparation of syndiotactic vinylidene aromatic polymers using chain transfer agent
US5594080A (en) 1994-03-24 1997-01-14 Leland Stanford, Jr. University Thermoplastic elastomeric olefin polymers, method of production and catalysts therefor
US5721183A (en) * 1995-03-10 1998-02-24 The Dow Chemical Company Catalyst system comprising amine or phosphine adducts of tris(organyl)borane compounds
DE19509785A1 (en) * 1995-03-17 1996-09-19 Basf Ag Process for the preparation of polymers of vinyl aromatic compounds under pressure in the presence of volatile hydrocarbons
AU717137B2 (en) * 1995-11-24 2000-03-16 Ciba Specialty Chemicals Holding Inc. Borate coinitiators for photopolymerization
US5856256A (en) * 1996-02-20 1999-01-05 Northwestern University Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations
US6291695B1 (en) 1996-02-20 2001-09-18 Northwestern University Organo-Lewis acids of enhanced utility, uses thereof, and products based thereon
US6274752B1 (en) 1996-02-20 2001-08-14 Northwestern University Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations
US5854166A (en) * 1996-08-19 1998-12-29 Northwestern University Synthesis and use of (perfluoroaryl) fluoro-aluminate anion
US6262200B1 (en) 1996-08-19 2001-07-17 Northwestern University (Polyfluoroaryl)fluoroanions of aluminum, gallium, and indium of enhanced utility, uses thereof, and products based thereon
US6130302A (en) 1996-08-19 2000-10-10 Northwestern University Synthesis and use of (polyfluoroaryl)fluoroanions of aluminum, gallium and indium
US5895771A (en) * 1997-06-05 1999-04-20 Akzo Nobel Nv Fluorinated alkoxy and/or aryloxy aluminates as cocatalysts for metallocene-catalyzed olefin polymerizations
US6670299B1 (en) * 1999-07-03 2003-12-30 Northwestern University Cyclopentadienyl-containing low-valent early transition metal olefin polymerization catalysts
MXPA02005642A (en) * 1999-12-09 2002-09-02 Exxon Chemical Patents Inc Olefin polymerization cocatalysts derived from group 15 compounds and processes using them.
US6489480B2 (en) 1999-12-09 2002-12-03 Exxonmobil Chemical Patents Inc. Group-15 cationic compounds for olefin polymerization catalysts
US6822057B2 (en) 1999-12-09 2004-11-23 Exxon Mobil Chemical Patents Inc. Olefin polymerization catalysts derived from Group-15 cationic compounds and processes using them
US6538081B2 (en) * 2000-12-18 2003-03-25 Univation Tech Llc Polymerization process
US7759489B2 (en) * 2006-01-27 2010-07-20 Idemitsu Kosan Co., Ltd. Transition metal complex compound and organic electroluminescence device using the compound
KR20200086295A (en) * 2017-12-01 2020-07-16 이데미쓰 고산 가부시키가이샤 Method for producing styrene resin and molded styrene resin

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02255646A (en) * 1989-03-29 1990-10-16 Nippon Paint Co Ltd New benzylammonium salt
EP0421659A2 (en) * 1989-09-29 1991-04-10 The Dow Chemical Company Process for preparation of syndiotactic vinyl aromatic polymers

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3418303A (en) * 1964-09-16 1968-12-24 Du Pont Coordination catalyst system and polymerization process
US3459825A (en) * 1967-10-26 1969-08-05 Sun Oil Co Catalyst and process for dimerization of olefins
JP2531583B2 (en) * 1987-01-28 1996-09-04 出光興産株式会社 Styrene-based copolymer and method for producing the same
JPS62187708A (en) * 1985-11-11 1987-08-17 Idemitsu Kosan Co Ltd Production of styrene polymer
JPH085929B2 (en) * 1987-01-22 1996-01-24 出光興産株式会社 Method for producing styrenic polymer
US5153157A (en) * 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
US5066741A (en) * 1990-03-22 1991-11-19 The Dow Chemical Company Process for preparation of syndiotactic vinyl aromatic polymers
US5066740A (en) * 1989-12-26 1991-11-19 The B. F. Goodrich Company Pyridinium metathesis catalysts for cycloolefin polymerization
US5171919A (en) * 1990-10-17 1992-12-15 Idemitsu Kosan Co., Ltd. Process for producing propylene based oligomers

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02255646A (en) * 1989-03-29 1990-10-16 Nippon Paint Co Ltd New benzylammonium salt
EP0421659A2 (en) * 1989-09-29 1991-04-10 The Dow Chemical Company Process for preparation of syndiotactic vinyl aromatic polymers

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN vol. 15, no. 1 (C - 0793) 7 January 1991 (1991-01-07) *

Also Published As

Publication number Publication date
EP0543022B1 (en) 1998-02-04
WO1992022589A1 (en) 1992-12-23
ATE163018T1 (en) 1998-02-15
US5391661A (en) 1995-02-21
DE69224353D1 (en) 1998-03-12
EP0543022A1 (en) 1993-05-26
JPH04366109A (en) 1992-12-18
DE69224353T2 (en) 1998-06-10

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