EP0586323A1 - Detergent composition and method for its preparation - Google Patents
Detergent composition and method for its preparation Download PDFInfo
- Publication number
- EP0586323A1 EP0586323A1 EP93500108A EP93500108A EP0586323A1 EP 0586323 A1 EP0586323 A1 EP 0586323A1 EP 93500108 A EP93500108 A EP 93500108A EP 93500108 A EP93500108 A EP 93500108A EP 0586323 A1 EP0586323 A1 EP 0586323A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- detergent composition
- compounds represented
- preferebly
- present
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
Definitions
- the present invention relates to novel liquid detergent compositions which are biodegradable, non-toxic, and non-irritant, while improves its detergency, foam stability and colour protection in case of heavy and light duty detergent.
- These detergent compositions are particulary useful to formulate shampoos, body shampoos, washing up, all purpose cleaners, heavy and light duty detergents.
- the present invention relates to cleanning formulations comprising a specific nonionic compound.
- the present invention relates to a method for preparing the above mentioned nonionic.
- detergent compositions involve a combination of anionic, amphoteric and/or nonionic surfactants, in order to get better properties according to final product in terms of irritation, detergency and foam profile.
- the nonionics employed in the detergent compositions were conventionally ethoxylated nonylphenols, C 12 - 18 alcohols ethoxylated with approximately 12 moles of ethylene oxides, lately C 12-15 alcohols ethoxylated with 2 to 9 moles of ethylene oxides and EO/OP derivatives.
- Japanese Patent Laid-Open No. 52-22007, and Japanese Patent Publication No. 83037356 disclose the use of middle alcohol ethoxylated of formula R,O(C 2 H 4 0)nH, wherein R 1 is straight chain or branched alkyl radicals and n is 1-12 on average in detergent compositions.
- European Patent No. 80749 discloses the use of ethoxylated alkyl phenols in detergent compositions.
- US Patent 4908150 discloses the use of polyethylene glycol ether of a glycerol ester compositions.
- Japanese Patent Laid-Open No. 55-133495 discloses the use of a polyoxyethylene hardened castor oil or fatty acid ester, thereof, polyoxyethylene glyceryl etherfatty acid ester, polyoxyethylene trimethylol propane fatty acid ester and polyoxyethylene alkyletherdiester of N-lauroylglutamic acid etc, in detergent compositions.
- US Patent 4247425 discloses the use of alkoxylated partial glycerol esters of a detergent grade fatty acid in light duty detergent compositions.
- EP Patent 0007120 discloses an emulsifying system, to be used in a handwashing composition, mainly consisting of mono and diglycerides of higher natural fatty acids and ethoxylated glycerine esterified by fatty acids.
- US Patent 4897214 discloses the use of monoesters of fatty acids with polyoxyethylene hexitan derivatives in skin cleaning preparations.
- WO Patent 92/00945 discloses the use of octadienyl glycerin ethers with polyoxyethylene.
- UK Patent 21973308 discloses the use of polyoxyalkylene alkyl- or alkenyl ethers and polyoxyalkylene glycerol fatty acid esters in detergent compositions.
- the present inventors have carried out research on the developement of a detergent composition, which will exhibit the outstanding biodegradable, non-toxic, non-irritant performance, foam stability and better dye inhibition transfer maintaining and even improving detergency.
- the present invention relates to a detergent compositions comprising the compound represented by the formula (I), where the mono/di/tri-ester proportion is 46-90/9-30/1-15 wherein:
- Ratio (I)/(II) may have a value between 3 to 0,33 preferebly 1.3 to 0,75.
- the compound mixture of the formula (I) + (II) in the present invention can be obtained by conventional method for preparating it.
- the compound can be obtained by following the reaction processes.
- Triglyceride which can be used in process (A) includes natural fat and oil as well as a synthetic triglyceride.
- the fat and oil include vegetable oil such as coconut oil, palm oil, soybean oil; and animal fat and oil such as beef tallow, bone oil; aquatic animal fat and oil; hardened oils and semihardened oil thereof.
- the compound of the formula (I)+(II) can be incorporated in an amount of from 0.2% to 40%, preferebly from 3% to 20% by weight based on the whole of the detergent composition.
- compositions containing the nonionic of the present invention provide a more superior colour care than usual ethoxylated alcohol.
- the nonionic from the present invention performs better than alcohol ethoxylated preventing dye transfer.
- polyvinylpirrolidone typically dye- tranfer inhibitor.
- the especific amount to be saved will depend on the effect of other components, that means, on formulation design. It seems to the applicant that a synergistic effect exists between the non ionic of present invention and PVP.
- test 1 and 2 were corroborated using a 5 people panel, who evaluate the results according to a scale.
- compositions containing the nonionic of the present invention prevent better the colour transfer even in HDL where the ph is neutral and no optical brighters are used. (Note that HDL were used as colour save detergents before appearing the new segment of colour saving H.D.P.D..
- compositions containing Levenol shows a better detergency and fat dispersion, allowing the supresion of nitrogen derivatives (alkanol amide and amine oxide) and also the complete substitution of ethoxylated alcohol. Other key point is the partial substitution of betaine.
- the nonionic of the present invention gives also a creamy foam compared to other compositions.
Abstract
wherein :
- - "B" represents "H" or the group represented by
provided that R represents alkyl or alkenyl group having C6-22. R' represents H or CH3, and each of n, m and 1 independently represents an integer from 0 to 40 ; being m+n+1 =2-100 preferebly 9-19.
Description
- The present invention relates to novel liquid detergent compositions which are biodegradable, non-toxic, and non-irritant, while improves its detergency, foam stability and colour protection in case of heavy and light duty detergent. These detergent compositions are particulary useful to formulate shampoos, body shampoos, washing up, all purpose cleaners, heavy and light duty detergents.
- In fact, the present invention relates to cleanning formulations comprising a specific nonionic compound.
- In addition to that, the present invention relates to a method for preparing the above mentioned nonionic.
- Description of Prior Art.
- Most of detergent compositions involve a combination of anionic, amphoteric and/or nonionic surfactants, in order to get better properties according to final product in terms of irritation, detergency and foam profile.
- One of the current problems in the whole field of chemicals is the question of ecotoxicity and the duality cleanliness/damage, that is how to get a good performance without interact seriously with the surface (fabrics or skin).
- The nonionics employed in the detergent compositions were conventionally ethoxylated nonylphenols, C12-18 alcohols ethoxylated with approximately 12 moles of ethylene oxides, lately C12-15 alcohols ethoxylated with 2 to 9 moles of ethylene oxides and EO/OP derivatives.
- For instance:
- Japanese Patent Laid-Open No. 55-86894, discloses the use of a secondary Ce-i4 alcohols ethoxylated with 4-15 moles of ethylene oxides on average.
- Japanese Patent Laid-Open No. 52-22007, and Japanese Patent Publication No. 83037356, disclose the use of middle alcohol ethoxylated of formula R,O(C2H40)nH, wherein R1 is straight chain or branched alkyl radicals and n is 1-12 on average in detergent compositions.
- European Patent No. 80749, discloses the use of ethoxylated alkyl phenols in detergent compositions.
- US Patent 4908150, discloses the use of polyethylene glycol ether of a glycerol ester compositions.
- Japanese Patent Laid-Open No. 55-133495, discloses the use of a polyoxyethylene hardened castor oil or fatty acid ester, thereof, polyoxyethylene glyceryl etherfatty acid ester, polyoxyethylene trimethylol propane fatty acid ester and polyoxyethylene alkyletherdiester of N-lauroylglutamic acid etc, in detergent compositions.
- However, use of such nonionics deteriorates detergency ability of detergent formulation. Also in case of heavy and light duty liquids detergents tends to cause dye transfer, especially upon repeated laundering. In addition to the above mentioned points, current nonionics cause skin and eye irritation, and values of fish toxicity, daphnia inmobilization and algae are not acceptable under the present environmental requirements.
- Others patents describes the use of specific non-ionic compounds, different from the usual ones, in particular applications and/or conditions.
- US Patent 4247425, discloses the use of alkoxylated partial glycerol esters of a detergent grade fatty acid in light duty detergent compositions.
- EP Patent 0007120, discloses an emulsifying system, to be used in a handwashing composition, mainly consisting of mono and diglycerides of higher natural fatty acids and ethoxylated glycerine esterified by fatty acids.
- US Patent 4897214, discloses the use of monoesters of fatty acids with polyoxyethylene hexitan derivatives in skin cleaning preparations.
- WO Patent 92/00945, discloses the use of octadienyl glycerin ethers with polyoxyethylene.
- UK Patent 2197338, discloses the use of polyoxyalkylene alkyl- or alkenyl ethers and polyoxyalkylene glycerol fatty acid esters in detergent compositions.
- In none of disclosures mentioned above it is taught a nonionic like the one described in the present invention.
- The present inventors have carried out research on the developement of a detergent composition, which will exhibit the outstanding biodegradable, non-toxic, non-irritant performance, foam stability and better dye inhibition transfer maintaining and even improving detergency.
- It was unexpectedly found that the above mentioned requeriments can be met when the specified nonionic compound is incorporated into detergent composition.
- This finding has led to the present invention.
-
- - "B" represents "H" or the group represented by
provided that R represents alkyl or alkenyl group having C6-22. Consider that at least one of "B" is an ester group. - - "n","m" and "I" may have a value between 0 and 40 provided that (n+m+l) = 2 - 100 preferebly 9 - 19. - R' represents H or CH3 respectively and the compound represented by the formula (II)
wherein: - - "n","m" and "I" may have a value between 0 and 40 provided that (n+m+l) = 2 - 100 preferebly 9 - 19.
- - R' represents H or CH3 respectively.
- Being the high content of ethoxylated monoester in compound (I) and ratio (I)/(II) the key parameters to get the above mentioned properties.
- Ratio (I)/(II) may have a value between 3 to 0,33 preferebly 1.3 to 0,75.
- The compound mixture of the formula (I) + (II) in the present invention can be obtained by conventional method for preparating it.
- For example the compound can be obtained by following the reaction processes.
- (A) The interesterification reaction between triglyceride and glycerine, in a molar ratio in the proportion of 0.1-10/1, preferebly 0.15-3.5 (in presence of alkaline catalyst), and the reaction with alkylene oxide C2-3 or viceversa will lead to a mono- di- and triglyceride mixture (I) and (I)/(II) ratio of specific composition and structure, due to migration and exchange phenomena, with an HLB higher than 2.
- (B) The reaction of glycerine with alkylene oxide C2-3, in presence of alkaline catalysts and the later reaction with fatty acid in a molar ratio in the proportion of 0.1-10/1, preferebly 0,7-3.5/1 in presence of acidic or alkaline catalysts will lead to a mono- di- and triglyceride mixture of a specific composition and structure, due to migration and exchange phenomena, with an HLB higher than 2.
- Triglyceride which can be used in process (A) includes natural fat and oil as well as a synthetic triglyceride.
- The fat and oil include vegetable oil such as coconut oil, palm oil, soybean oil; and animal fat and oil such as beef tallow, bone oil; aquatic animal fat and oil; hardened oils and semihardened oil thereof.
- In the present invention the compound of the formula (I)+(II) can be incorporated in an amount of from 0.2% to 40%, preferebly from 3% to 20% by weight based on the whole of the detergent composition.
- The reason why the present invention exhibits the outstanding biodegradable, non-toxic and non-irritant performance without deteriorating its detergeny is not certain, but it seems to applicant that good performance of the present composition comes partially from the fact that existence of fatty acid groups facilitates its biodegradability and its very low skin irritation, oral toxicity, fish toxicity, algae and daphnia inmobilization compared with conventional nonionics.
- Furthermore incorporation of the formula of the new nonionic described in the patent, considerably improves its foam profile, anti dye transfer and perfume solubilization properties compared with conventional formulations, due to EO monoglyceride high ratio and the synergistic effect between (I) and (II).
- The surface active agents like anionic, other nonionic, amphoteric etc and the rest of additive useful in the practice of this invention depends a great deal on kind of final product to be formulated. At the same time they are standard items of commerce so they will be not further comments upon herein.
- The present invention is described in detail by way of the following examples. The present invention, however, is not limited to these examples.
- The compound ( (1)+(11) ) is obtained, for instance by means of the following process:
- Step (c).
- Step (d).
- wherein:
- - "B" represents "H" or the group represented by
- - "R" represents a coco alkyl chain.
- -(I)/(II) ratio is 1.
- 500 g (0.76 moles) of coco TRG, 210.7 g (2.29 moles) of glycerine 99% and 1.2 g of KOH 85% as catalyst are placed in a 3 kg flask properly equipped. System is purged several times with N2, vacuum stripping till 110°C, and continued heating to 140°C. When temperature reaches 140°C the reactor is pressurized to 2-3 kg/cm2 with ethylene oxide added until a total of 2013 gr (45.7 moles).
- After the final charge of ethylene oxide the reaction mixture is allowed to react for about 1/2 hour; cooled and discharged from reactor. A product like ( (I) + (II) ) is obtained.
- The compound ((I)+(II)) is obtained, for instance by means of the following process:
- Step (e).
- Step (f).
- wherein:
- "B" represents "H" or the group represented by
and I+m+n = 10. - R' represents CH3.
- R means tallow alkyl chain.
- Ratio (I)/(II) = 1.3
- 14.3 g (0.1554 moles) of glycerine 99% and 1.2 g of KOH 85% as catalyst are placed in a 250 gr flask properly equipped. System is purged several times with N2, vacuum stripping till 110°C, and continued heating to 140°C. When temperature reaches 140°C the reactor is pressurized to 2-3 kg/cm2with ethylene oxide added until a total of 67,9 gr (1.54 moles). After the final charge of ethylene oxide, the reaction mixture is allowed to react for about 1/2 hour; 52.3 gr (0.15 mol) of a methyl ester of fatty acid derived from tallow, is added and mixed for 45 minutes. Finally product is cooled and discharged from reactor. Thus a compound (I) + (II) is obtained.
- "B" represents "H" or the group represented by
- Detergent ability was evaluated on detergent compositions appearing in table 1.
- All variables considered, that is, temperature, water hardness and soil type the nonionic described in this patent shows in the worst of cases equivalent eficiency in terms of detergency.
- However, on the other hand, compositions containing the nonionic of the present invention provide a more superior colour care than usual ethoxylated alcohol.
- The following test have been conducted at 30°C.
- After 15 washings, differences appeared in terms of colour transfer.
-
- The lower delta E, the better composition is able to prevent dye transfer. Therefore can be concluded from the above results that the nonionic from the present invention performs better than alcohol ethoxylated preventing dye transfer. In addition to that it is possible to save some amount of polyvinylpirrolidone (typical dye- tranfer inhibitor). The especific amount to be saved will depend on the effect of other components, that means, on formulation design. It seems to the applicant that a synergistic effect exists between the non ionic of present invention and PVP.
- References:
- Yellow: Solar Yellow 3LG 160%
- Blue: Solar Blue 2GLN 350%
- After 3 washings, differences appeared in terms of colour transfer.
-
-
- Following the same test conditions than explained above for HDPD, (adapting the dosage according to the composition) the following results were obtained:
- - Good enough detergency in all cases.
- - Colour appearance results are shown in table 3.
-
- Compositions containing Levenol shows a better detergency and fat dispersion, allowing the supresion of nitrogen derivatives (alkanol amide and amine oxide) and also the complete substitution of ethoxylated alcohol. Other key point is the partial substitution of betaine. The nonionic of the present invention gives also a creamy foam compared to other compositions.
-
- From the comparison of the above compositions, can be inferred the mild effect of the nonionic of the present invention.
Claims (4)
Wherein:
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP93500108A EP0586323B2 (en) | 1992-07-20 | 1993-07-20 | Detergent composition and method for its preparation |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP92500092 | 1992-07-20 | ||
EP92500092 | 1992-07-20 | ||
EP93500108A EP0586323B2 (en) | 1992-07-20 | 1993-07-20 | Detergent composition and method for its preparation |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0586323A1 true EP0586323A1 (en) | 1994-03-09 |
EP0586323B1 EP0586323B1 (en) | 1996-04-10 |
EP0586323B2 EP0586323B2 (en) | 2005-11-02 |
Family
ID=8211823
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP93500108A Expired - Lifetime EP0586323B2 (en) | 1992-07-20 | 1993-07-20 | Detergent composition and method for its preparation |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0586323B2 (en) |
AT (1) | ATE136579T1 (en) |
DE (1) | DE69302151T3 (en) |
ES (1) | ES2088254T5 (en) |
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WO1995014765A1 (en) * | 1993-11-22 | 1995-06-01 | Colgate-Palmolive Company | Microemulsion all purpose liquid cleaning compositions |
EP0668346A1 (en) * | 1994-02-07 | 1995-08-23 | Colgate-Palmolive Company | Microemulsion all purpose liquid cleaning compositions |
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EP0684302A1 (en) * | 1994-05-28 | 1995-11-29 | Th. Goldschmidt AG | Aqueous free-flowing lustre concentrates |
US5476614A (en) * | 1995-01-17 | 1995-12-19 | Colgate Palmolive Co. | High foaming nonionic surfactant based liquid detergent |
WO1996022347A1 (en) * | 1995-01-17 | 1996-07-25 | Colgate-Palmolive Company | Light duty liquid cleaning compositions |
US5549840A (en) * | 1993-08-04 | 1996-08-27 | Colgate-Palmolive Co. | Cleaning composition in microemulsion, liquid crystal or aqueous solution form comprising mixture of partially esterified, full esterified and non-esterified ethoxylated polyhydric alcohols |
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WO1996029389A1 (en) * | 1995-03-17 | 1996-09-26 | Henkel Kommanditgesellschaft Auf Aktien | Process for manufacturing a powder washing or cleaning agent |
US5593958A (en) * | 1995-02-06 | 1997-01-14 | Colgate-Palmolive Co. | Cleaning composition in microemulsion, crystal or aqueous solution form based on ethoxylated polyhydric alcohols and option esters's thereof |
US5599785A (en) * | 1993-08-04 | 1997-02-04 | Colgate-Palmolive Co. | Cleaning composition in microemulsion or liquid crystal form comprising mixture of partially esterified, fully esterified and non-esterified polyhydric alchohols |
US5716925A (en) * | 1993-08-04 | 1998-02-10 | Colgate Palmolive Co. | Microemulsion all purpose liquid cleaning compositions comprising partially esterified, fully esterified and non-esterified polyhydric alcohol and grease release agent |
US5731281A (en) * | 1993-08-04 | 1998-03-24 | Colgate-Palmolive Company | Microemulsion liquid crystal cleaning compositions comprising esterified and non-esterfied ethoxylated glycerol mixture and sulfoxy anionic surfactant |
US5741760A (en) * | 1993-08-04 | 1998-04-21 | Colgate-Palmolive Company | Aqueous cleaning composition which may be in microemulsion form comprising polyalkylene oxide-polydimethyl siloxane |
US5759983A (en) * | 1993-08-04 | 1998-06-02 | Colgate-Palmolive Co. | Aqueous cleaning composition which may be in microemulsion form comprising polyalkylene oxide -polydimethyl siloxane and ethoxylated secondary alcohol |
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US5776880A (en) * | 1993-08-04 | 1998-07-07 | Colgate-Palmolive Co. | Aqueous cleaning compositions which may be in microemulsion form comprising ethoxylated secondary alcohol cosurfactant |
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US5854193A (en) * | 1993-08-04 | 1998-12-29 | Colgate Palmolive Company | Microemulsion/all purpose liquid cleaning composition based on EO-PO nonionic surfactant |
WO1998059031A1 (en) * | 1997-06-23 | 1998-12-30 | Colgate-Palmolive Company | Microemulsion all purpose liquid cleaning compositions |
US5861367A (en) * | 1993-08-04 | 1999-01-19 | Colgate Palmolive Company | Cleaning and disinfecting composition in microemulsion/liquid crystal form comprising aldehyde and mixture of partially esterified, fully esterified and non-esterified polyhydric alcohols |
WO1999006507A1 (en) * | 1997-08-01 | 1999-02-11 | Colgate-Palmolive Company | All purpose liquid cleaning compositions |
WO1999028424A1 (en) * | 1997-12-03 | 1999-06-10 | Colgate-Palmolive Company | All purpose liquid cleaning compositions |
US6017868A (en) * | 1993-08-04 | 2000-01-25 | Colgate Palmolive Company | Microemulsion all purpose liquid cleaning composition based on EO-PO nonionic surfactant |
EP1045021A1 (en) * | 1999-04-13 | 2000-10-18 | Kao Corporation, S.A. | Composition comprising a mixture of alkoxylated mono-, di- and triglycerides and glycerine |
EP0707059A3 (en) * | 1994-10-14 | 2001-04-18 | Kao Corporation | Liquid softener composition, use thereof and process for preparing a quaternary ammonium salt |
GR1003582B (en) * | 1993-08-04 | 2001-05-22 | Colgate-Palmolive Company | Microemulsion all purpose liquid cleaning compositions. |
US6544938B1 (en) | 2001-10-02 | 2003-04-08 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Soap bar comprising high levels of specific alkoxylated triglycerides which provide enhanced sensory properties and process well |
ES2185497A1 (en) * | 2001-07-30 | 2003-04-16 | Kao Corp Sa | Aqueous narceous concentrate compositions comprising ethoxylated glycerides |
EP1600532A1 (en) * | 2004-05-26 | 2005-11-30 | Dr. Th. Böhme KG Chem. Fabrik GmbH & Co. | Hydrophilizing agent for polyolefin- and/or polyester-containing materials |
ES2293825A1 (en) * | 2006-06-07 | 2008-03-16 | Kao Corporacion, S.A. | Composition which contains a mixture of mono-, di-, and triglycerides and glycerine |
EP2202219A1 (en) | 2008-12-24 | 2010-06-30 | Kao Corporation, S.A. | Mixture of amides and cosmetic compositions comprising said mixture |
EP2497844A1 (en) | 2011-03-10 | 2012-09-12 | Kao Corporation, S.A. | Quaternary ammonium esters (Esterquats) containing composition for inhibiting corrosion of metal surface |
WO2013024363A1 (en) * | 2011-08-17 | 2013-02-21 | Dow Global Technologies Llc | Biorenewable biodegradable surfactants |
EP2666848A1 (en) | 2012-05-22 | 2013-11-27 | Kao Corporation, S.A. | Dilutable surfactant composition |
WO2015040362A1 (en) * | 2013-09-19 | 2015-03-26 | Croda International Plc | A stain treatment additive |
WO2018085064A1 (en) | 2016-11-04 | 2018-05-11 | Huntsman Petrochemical Llc | Estolides of vegetable oil alkoxylates and methods of making and using |
WO2018111746A1 (en) * | 2016-12-15 | 2018-06-21 | Huntsman Petrochemical Llc | Vegetable oil-based alkoxylates and methods of making and using such |
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1993
- 1993-07-20 DE DE69302151T patent/DE69302151T3/en not_active Expired - Lifetime
- 1993-07-20 AT AT93500108T patent/ATE136579T1/en active
- 1993-07-20 ES ES93500108T patent/ES2088254T5/en not_active Expired - Lifetime
- 1993-07-20 EP EP93500108A patent/EP0586323B2/en not_active Expired - Lifetime
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Also Published As
Publication number | Publication date |
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EP0586323B1 (en) | 1996-04-10 |
ATE136579T1 (en) | 1996-04-15 |
ES2088254T5 (en) | 2006-04-16 |
DE69302151T3 (en) | 2006-06-14 |
ES2088254T3 (en) | 1996-08-01 |
EP0586323B2 (en) | 2005-11-02 |
DE69302151D1 (en) | 1996-05-15 |
DE69302151T2 (en) | 1996-12-05 |
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