EP1954785A4 - Selective naphtha hydrodesulfurization with high temperature mercaptan decomposition - Google Patents

Selective naphtha hydrodesulfurization with high temperature mercaptan decomposition

Info

Publication number
EP1954785A4
EP1954785A4 EP06827807A EP06827807A EP1954785A4 EP 1954785 A4 EP1954785 A4 EP 1954785A4 EP 06827807 A EP06827807 A EP 06827807A EP 06827807 A EP06827807 A EP 06827807A EP 1954785 A4 EP1954785 A4 EP 1954785A4
Authority
EP
European Patent Office
Prior art keywords
high temperature
naphtha hydrodesulfurization
mercaptan decomposition
selective naphtha
temperature mercaptan
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP06827807A
Other languages
German (de)
French (fr)
Other versions
EP1954785A1 (en
Inventor
John Peter Greeley
Edward Stanley Ellis
Thomas Risher Halbert
William Joseph Tracy Iii
Jeffrey M Dysard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
ExxonMobil Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Research and Engineering Co filed Critical ExxonMobil Research and Engineering Co
Publication of EP1954785A1 publication Critical patent/EP1954785A1/en
Publication of EP1954785A4 publication Critical patent/EP1954785A4/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
    • C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1044—Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/207—Acid gases, e.g. H2S, COS, SO2, HCN
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/301—Boiling range
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4006—Temperature
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4012—Pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/80—Additives
    • C10G2300/805—Water
    • C10G2300/807—Steam
EP06827807A 2005-11-23 2006-11-14 Selective naphtha hydrodesulfurization with high temperature mercaptan decomposition Withdrawn EP1954785A4 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/286,580 US20070114156A1 (en) 2005-11-23 2005-11-23 Selective naphtha hydrodesulfurization with high temperature mercaptan decomposition
PCT/US2006/044231 WO2007061701A1 (en) 2005-11-23 2006-11-14 Selective naphtha hydrodesulfurization with high temperature mercaptan decomposition

Publications (2)

Publication Number Publication Date
EP1954785A1 EP1954785A1 (en) 2008-08-13
EP1954785A4 true EP1954785A4 (en) 2011-06-22

Family

ID=38052405

Family Applications (1)

Application Number Title Priority Date Filing Date
EP06827807A Withdrawn EP1954785A4 (en) 2005-11-23 2006-11-14 Selective naphtha hydrodesulfurization with high temperature mercaptan decomposition

Country Status (7)

Country Link
US (1) US20070114156A1 (en)
EP (1) EP1954785A4 (en)
JP (1) JP5396084B2 (en)
CN (1) CN101313053B (en)
BR (1) BRPI0618818A2 (en)
CA (1) CA2630340C (en)
WO (1) WO2007061701A1 (en)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BRPI0601787B1 (en) * 2006-05-17 2016-06-07 Petroleo Brasileiro Sa selective naphtha hydrodesulfurization process
US8753504B2 (en) * 2011-04-28 2014-06-17 Battelle Memorial Institute Systems and processes for removing elemental sulfur compounds from desulfurized fuels
US8828218B2 (en) * 2011-10-31 2014-09-09 Exxonmobil Research And Engineering Company Pretreatment of FCC naphthas and selective hydrotreating
FR3020376B1 (en) * 2014-04-28 2017-10-20 Ifp Energies Now PROCESS FOR PRODUCING LOW TEMPERATURE GASOLINE IN SULFUR AND MARCAPTANS
EP2816094B1 (en) 2013-06-19 2020-04-29 IFP Energies nouvelles Method for producing gasoline with low sulphur and mercaptan content
FR3007416B1 (en) * 2013-06-19 2018-03-23 IFP Energies Nouvelles PROCESS FOR PRODUCING LOW SULFUR AND MERCAPTAN GASOLINE
CN105579135B (en) * 2013-10-11 2018-12-21 克斯莫石油株式会社 Hydrotreating catalyst, the manufacturing method of the hydrotreating catalyst of heavy hydrocarbon oil and the hydrotreating method of heavy hydrocarbon oil of heavy hydrocarbon oil
US10144883B2 (en) 2013-11-14 2018-12-04 Uop Llc Apparatuses and methods for desulfurization of naphtha
US9850435B2 (en) 2014-08-26 2017-12-26 Exxonmobil Research And Engineering Company Hydroprocessing with drum blanketing gas compositional control
CN105602618B (en) * 2014-11-19 2017-08-25 中国海洋石油总公司 A kind of method of gasoline selective hydrodesulfurizationmodification
CN105363481A (en) * 2015-11-20 2016-03-02 洛阳金达石化有限责任公司 Preparation method of ultra low aromatic hydrocarbon white oil hydrofining catalyst
FR3049955B1 (en) 2016-04-08 2018-04-06 IFP Energies Nouvelles PROCESS FOR TREATING A GASOLINE
FR3057578B1 (en) 2016-10-19 2018-11-16 IFP Energies Nouvelles PROCESS FOR HYDRODESULFURING OLEFINIC ESSENCE
SG11201906393TA (en) 2017-02-21 2019-09-27 Exxonmobil Res & Eng Co Desulfurization of a naphtha boiling range feed
FR3099173B1 (en) 2019-07-23 2021-07-09 Ifp Energies Now PROCESS FOR THE PRODUCTION OF A GASOLINE WITH LOW SULFUR AND MERCAPTANS
FR3099174B1 (en) 2019-07-23 2021-11-12 Ifp Energies Now PROCESS FOR THE PRODUCTION OF A GASOLINE WITH LOW SULFUR AND MERCAPTANS
FR3099175B1 (en) 2019-07-23 2021-07-16 Ifp Energies Now PROCESS FOR THE PRODUCTION OF A GASOLINE WITH LOW SULFUR AND MERCAPTANS
FR3099172B1 (en) 2019-07-23 2021-07-16 Ifp Energies Now PROCESS FOR TREATING A GASOLINE BY SEPARATION IN THREE CUTS
FR3104602A1 (en) 2019-12-17 2021-06-18 IFP Energies Nouvelles Finishing hydrodesulfurization process in the presence of a catalyst obtained by the molten salt route
FR3108333B1 (en) 2020-03-20 2022-03-11 Ifp Energies Now PROCESS FOR THE PRODUCTION OF A GASOLINE WITH LOW SULFUR AND MERCAPTANS CONTENT
FR3130831A1 (en) 2021-12-20 2023-06-23 IFP Energies Nouvelles Process for producing a low sulfur light gasoline cut
FR3130834A1 (en) 2021-12-20 2023-06-23 IFP Energies Nouvelles Process for treating a gasoline containing sulfur compounds

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3349027A (en) * 1965-02-08 1967-10-24 Gulf Research Development Co Multi-stage hydrodesulfurization process
US4132632A (en) * 1978-03-31 1979-01-02 Standard Oil Company (Indiana) Selective hydrodesulfurization of cracked naphtha
EP0755995A1 (en) * 1995-07-26 1997-01-29 Mitsubishi Oil Co., Ltd. Process for desulfurizing catalytically cracked gasoline
US5846406A (en) * 1996-03-22 1998-12-08 Texaco Inc Selective hydrodesulfurization of cracked naphtha using novel manganese oxide octahedral molecular sieve supported catalysts
WO2001079391A1 (en) * 2000-04-18 2001-10-25 Exxonmobil Research And Engineering Company Selective hydroprocessing and mercaptan removal
WO2005033930A2 (en) * 2003-10-02 2005-04-14 Exxonmobil Research And Engineering Company Process for upgrading naphtha
US20050252831A1 (en) * 2004-05-14 2005-11-17 Dysard Jeffrey M Process for removing sulfur from naphtha

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5597476A (en) * 1995-08-28 1997-01-28 Chemical Research & Licensing Company Gasoline desulfurization process
US6231753B1 (en) * 1996-02-02 2001-05-15 Exxon Research And Engineering Company Two stage deep naphtha desulfurization with reduced mercaptan formation
US6387249B1 (en) * 1999-12-22 2002-05-14 Exxonmobil Research And Engineering Company High temperature depressurization for naphtha mercaptan removal
JP4681794B2 (en) * 1999-12-22 2011-05-11 エクソンモービル リサーチ アンド エンジニアリング カンパニー High temperature decompression for removal of naphthamercaptan
US6495030B1 (en) * 2000-10-03 2002-12-17 Catalytic Distillation Technologies Process for the desulfurization of FCC naphtha
US6913688B2 (en) * 2001-11-30 2005-07-05 Exxonmobil Research And Engineering Company Multi-stage hydrodesulfurization of cracked naphtha streams with interstage fractionation
US7297251B2 (en) * 2002-05-21 2007-11-20 Exxonmobil Research And Engineering Company Multi-stage hydrodesulfurization of cracked naphtha streams with a stacked bed reactor

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3349027A (en) * 1965-02-08 1967-10-24 Gulf Research Development Co Multi-stage hydrodesulfurization process
US4132632A (en) * 1978-03-31 1979-01-02 Standard Oil Company (Indiana) Selective hydrodesulfurization of cracked naphtha
EP0755995A1 (en) * 1995-07-26 1997-01-29 Mitsubishi Oil Co., Ltd. Process for desulfurizing catalytically cracked gasoline
US5906730A (en) * 1995-07-26 1999-05-25 Mitsubishi Oil Co., Ltd. Process for desulfurizing catalytically cracked gasoline
US5846406A (en) * 1996-03-22 1998-12-08 Texaco Inc Selective hydrodesulfurization of cracked naphtha using novel manganese oxide octahedral molecular sieve supported catalysts
WO2001079391A1 (en) * 2000-04-18 2001-10-25 Exxonmobil Research And Engineering Company Selective hydroprocessing and mercaptan removal
WO2005033930A2 (en) * 2003-10-02 2005-04-14 Exxonmobil Research And Engineering Company Process for upgrading naphtha
US20050252831A1 (en) * 2004-05-14 2005-11-17 Dysard Jeffrey M Process for removing sulfur from naphtha

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO2007061701A1 *

Also Published As

Publication number Publication date
WO2007061701A1 (en) 2007-05-31
EP1954785A1 (en) 2008-08-13
CN101313053B (en) 2012-01-25
CN101313053A (en) 2008-11-26
JP2009517499A (en) 2009-04-30
BRPI0618818A2 (en) 2016-09-13
US20070114156A1 (en) 2007-05-24
CA2630340C (en) 2015-12-22
CA2630340A1 (en) 2007-05-31
JP5396084B2 (en) 2014-01-22

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