EP2782980A4 - Improved metal passivator/trap for fcc processes - Google Patents

Improved metal passivator/trap for fcc processes

Info

Publication number
EP2782980A4
EP2782980A4 EP11876225.1A EP11876225A EP2782980A4 EP 2782980 A4 EP2782980 A4 EP 2782980A4 EP 11876225 A EP11876225 A EP 11876225A EP 2782980 A4 EP2782980 A4 EP 2782980A4
Authority
EP
European Patent Office
Prior art keywords
trap
metal passivator
improved metal
fcc processes
fcc
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP11876225.1A
Other languages
German (de)
French (fr)
Other versions
EP2782980A1 (en
Inventor
Bram W Hoffer
David M Stockwell
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Corp
Original Assignee
BASF Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF Corp filed Critical BASF Corp
Publication of EP2782980A1 publication Critical patent/EP2782980A1/en
Publication of EP2782980A4 publication Critical patent/EP2782980A4/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
    • C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/843—Arsenic, antimony or bismuth
    • B01J23/8435—Antimony
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0211—Impregnation using a colloidal suspension
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/12—Oxidising
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/205—Metal content
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/28—Propane and butane
EP11876225.1A 2011-11-21 2011-11-21 Improved metal passivator/trap for fcc processes Withdrawn EP2782980A4 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US2011/061648 WO2013077836A1 (en) 2011-11-21 2011-11-21 Improved metal passivator/trap for fcc processes

Publications (2)

Publication Number Publication Date
EP2782980A1 EP2782980A1 (en) 2014-10-01
EP2782980A4 true EP2782980A4 (en) 2015-11-11

Family

ID=48470149

Family Applications (1)

Application Number Title Priority Date Filing Date
EP11876225.1A Withdrawn EP2782980A4 (en) 2011-11-21 2011-11-21 Improved metal passivator/trap for fcc processes

Country Status (9)

Country Link
EP (1) EP2782980A4 (en)
JP (1) JP5982496B2 (en)
KR (1) KR20140096134A (en)
CN (1) CN104066819B (en)
BR (1) BR112014012163A2 (en)
CA (1) CA2856493A1 (en)
RU (1) RU2603964C2 (en)
WO (1) WO2013077836A1 (en)
ZA (1) ZA201404460B (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9441167B2 (en) * 2013-12-19 2016-09-13 Basf Corporation Boron oxide in FCC processes
US9895680B2 (en) * 2013-12-19 2018-02-20 Basf Corporation FCC catalyst compositions containing boron oxide
CN106475155B (en) * 2015-08-28 2019-09-20 江苏科创石化有限公司 A kind of matal deactivator and preparation method thereof
CN109126898A (en) * 2018-09-26 2019-01-04 宜兴汉光高新石化有限公司 It is a kind of to be passivated various metals simultaneously, improve light oil and the passivator of total liquid recovery and preparation method thereof
CN110339865B (en) * 2019-07-29 2020-06-02 华东理工大学 Catalytic cracking anti-metal thickening agent and preparation method thereof
CN114602484B (en) * 2020-12-03 2023-10-10 中国石油化工股份有限公司 Preparation method of hydrogenation carbon residue removal catalyst

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2380073A1 (en) * 1977-02-11 1978-09-08 Phillips Petroleum Co PROCESS FOR INHIBITING THE HARMFUL EFFECTS OF METALS ON A CRACKING CATALYST AND NEW PRODUCTS THUS OBTAINED
US4178267A (en) * 1976-03-29 1979-12-11 Phillips Petroleum Company Passivating metals on cracking catalysts
US4372841A (en) * 1979-12-31 1983-02-08 Exxon Research And Engineering Co. Process for reducing coke formation in heavy feed catalytic cracking
US4935121A (en) * 1989-06-22 1990-06-19 Phillips Petroleum Company Reactivation of metal-contaminated cracking catalysts
US5037786A (en) * 1990-04-04 1991-08-06 Phillips Petroleum Company Metals passivation-zeolite containing cracking catalysts

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK160995C (en) * 1977-10-25 1991-11-04 Phillips Petroleum Co POLLUTION DISABLED CRACKING CATALYST, ITS APPLICATION AND MEDICINE FOR ITS PREPARATION
US4321129A (en) * 1978-09-12 1982-03-23 Phillips Petroleum Company Cracking process employing catalyst having combination of antimony and tin
US4370220A (en) * 1979-12-31 1983-01-25 Exxon Research And Engineering Co. Process for reducing coke formation in heavy feed catalytic cracking
US4335021A (en) * 1980-02-04 1982-06-15 Phillips Petroleum Company Catalyst regeneration
JPS57202381A (en) * 1981-06-05 1982-12-11 Exxon Research Engineering Co Method of reducing coke production on catalysis of heavy supply
US4576709A (en) * 1982-09-02 1986-03-18 Ashland Oil, Inc. Catalytic upgrading of reduced crudes and residual oils with a coke selective catalyst
JPS60258288A (en) * 1984-06-01 1985-12-20 ガルフ・リサ−チ・エンド・デベロツプメント・コンパニ− Catalytic decomposition
US4889617A (en) * 1986-03-24 1989-12-26 Chevron Research Company Method of suppressing sodium poisoning of cracking catalysts during fluid catalytic cracking
US4784752A (en) * 1987-05-05 1988-11-15 Chevron Research Company Method for suppressing the poisoning effects of contaminant metals on cracking catalysts in fluid catalytic cracking
GB2245001A (en) * 1990-06-11 1991-12-18 Unilever Plc Catalyst compositions containing metal ion-exchanged zeolites
US5401384A (en) * 1993-12-17 1995-03-28 Inteven, S.A. Antimony and tin containing compound, use of such a compound as a passivating agent, and process for preparing such a compound
US6110357A (en) * 1994-09-28 2000-08-29 Phillips Petroleum Company Passivated catalysts for cracking process
JP2695121B2 (en) * 1994-12-16 1997-12-24 インテヴェップ，エス．エイ． Compound containing antimony and tin and method for producing the same
CN1122703C (en) * 1998-12-29 2003-10-01 中国石油化工集团公司 Assistant for catalytic cracking of hydrocarbon and its usage
RU2283177C2 (en) * 2001-08-14 2006-09-10 Петролеум Энерджи Сентер Catalyst for fluidized-bed catalytic cracking of heavy hydrocarbons and fluidized-bed catalytic cracking process
CN100540141C (en) * 2005-09-28 2009-09-16 华东理工大学 Catalytic cracking metal passivant and preparation method thereof
US7678735B2 (en) * 2005-11-28 2010-03-16 Engelhard Corporation FCC additive for partial and full burn NOx control

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4178267A (en) * 1976-03-29 1979-12-11 Phillips Petroleum Company Passivating metals on cracking catalysts
FR2380073A1 (en) * 1977-02-11 1978-09-08 Phillips Petroleum Co PROCESS FOR INHIBITING THE HARMFUL EFFECTS OF METALS ON A CRACKING CATALYST AND NEW PRODUCTS THUS OBTAINED
US4372841A (en) * 1979-12-31 1983-02-08 Exxon Research And Engineering Co. Process for reducing coke formation in heavy feed catalytic cracking
US4935121A (en) * 1989-06-22 1990-06-19 Phillips Petroleum Company Reactivation of metal-contaminated cracking catalysts
US5037786A (en) * 1990-04-04 1991-08-06 Phillips Petroleum Company Metals passivation-zeolite containing cracking catalysts

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO2013077836A1 *

Also Published As

Publication number Publication date
BR112014012163A2 (en) 2017-05-30
CN104066819B (en) 2016-12-07
RU2603964C2 (en) 2016-12-10
JP5982496B2 (en) 2016-08-31
WO2013077836A1 (en) 2013-05-30
EP2782980A1 (en) 2014-10-01
CA2856493A1 (en) 2013-05-30
CN104066819A (en) 2014-09-24
KR20140096134A (en) 2014-08-04
JP2015504473A (en) 2015-02-12
RU2014125128A (en) 2015-12-27
ZA201404460B (en) 2015-12-23

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Inventor name: HOFFER, BRAM, W.

Inventor name: STOCKWELL, DAVID, M.

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Effective date: 20151008

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