US1078686A - Process for the production of hydrogen. - Google Patents
Process for the production of hydrogen. Download PDFInfo
- Publication number
- US1078686A US1078686A US664809A US1911664809A US1078686A US 1078686 A US1078686 A US 1078686A US 664809 A US664809 A US 664809A US 1911664809 A US1911664809 A US 1911664809A US 1078686 A US1078686 A US 1078686A
- Authority
- US
- United States
- Prior art keywords
- hydrogen
- retort
- gas
- production
- steam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/08—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents with metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Definitions
- This invention relates to the well-known method of produemg hydrogen in which a metal is alternately oxidize ess in consequence of't e steam admitted to the-retort during the oxidation stage coming 3 into contact with the reducing gas admitted during the previous reduction sta e and with "the :su fur carbon,etc., associat with and into the retort bysald gas, the
- the object of my invention is to avoid this disadvantage nd to this end it consists in a method of carrying the process into effect according to which-the whole of thereducing gas, as well as -the sulfur carbon and other impurities associated with said gas may be I got rid of between the two phases of theprocess.
- the invention is carried into practice as follows. The process being continuous it by steam and 1,6 deoxidized by a reducing gas. In practice 3 it has hitherto been found impossible to obtain a sufliciently pure roduct by this. procserial No. 664,809.
Description
' introduced NITED STATES PATENT OFFICE.
HOWARD LANE. or BIRMINGHAM, ENGLAND, as'srenoa TCINTERNATIONALE wassnnsrorr axrmnensnnnscmrr, or rnanxronr-on-rnn-mam, GERMANY, A
CORPORATION OF GERMANY.
PROCESS FOR THE PRODUCTION OF HYDROGEN.
Specification of Letters Patent.
Patented Nov. 18, 1913.
NoDrawing. Original application filed June 16, 1910, Serial No. 572,411. Divided and this application filed December 9, 1911.
i the county of Warwick, England, have invented certain new and useful. Improvements in a Process for the Production of Hydrogen, of which the following is a specificatlon.
This application is a division of my application for patent for the same inventionfiled the 16th June 1910 Serial No. 57 2,411.
This invention relates to the well-known method of produemg hydrogen in which a metal is alternately oxidize ess in consequence of't e steam admitted to the-retort during the oxidation stage coming 3 into contact with the reducing gas admitted during the previous reduction sta e and with "the :su fur carbon,etc., associat with and into the retort bysald gas, the
- result of which contact being the formation 7 of sulfuretedhydro en, sulfurous acid, carbon d1ox1d etc., an consequent contamination of hydrogen produced'by the action of the steam.. p
The object of my invention is to avoid this disadvantage nd to this end it consists in a method of carrying the process into effect according to which-the whole of thereducing gas, as well as -the sulfur carbon and other impurities associated with said gas may be I got rid of between the two phases of theprocess. I The invention is carried into practice as follows. The process being continuous it by steam and 1,6 deoxidized by a reducing gas. In practice 3 it has hitherto been found impossible to obtain a sufliciently pure roduct by this. procserial No. 664,809.
will be assumed that the metal has just beenoxidized durin' the hydro en producing phase. The sul ur, carbon an other impunties left by the preceding reduction phase are thereupon got rid of by admitting air under pressure to the retort and the products of combustion being discharged into the atmosphere. The admission of air to the retort and the dischargeof the products of combustion are then out 01f a'nd reducin gas admitted and passed through and out o the retort to a gas-washing and regenerating apparatus. When the reduction stage has been completed the admission of the reducing gas to the retort and its dischargev from the retort to the gas washing and regenerating apparatus 1s then cut off and steam admitted. As a certain proportion of reducing gas will then be present impure hydrogen will be produced and this is al-' lowed to escape to waste, until the product is found to be sufiiciently pure. Thereupon the outlet to the atmosphere is closed and the hydrogen passed into a storage tank. Claim.
The process of producing hydrogen in a heated retort, which consists in deoxidizing a metal oxid within said retort by means of a reducing gas, in then oxidizing the deoxidized metal by means of steam, and in then introducing a blast of oxygen in the form of air'into the retort and then again deox1d1zducing gas as described.
p HOWARD LANE. Witnesses:
H. D. Jameson, 0. J. WORTH:
ing the oxidized metal by means of the re-
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US664809A US1078686A (en) | 1910-07-16 | 1911-12-09 | Process for the production of hydrogen. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US57241110A US1028366A (en) | 1910-07-16 | 1910-07-16 | Apparatus for producing hydrogen gas. |
US664809A US1078686A (en) | 1910-07-16 | 1911-12-09 | Process for the production of hydrogen. |
Publications (1)
Publication Number | Publication Date |
---|---|
US1078686A true US1078686A (en) | 1913-11-18 |
Family
ID=3146920
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US664809A Expired - Lifetime US1078686A (en) | 1910-07-16 | 1911-12-09 | Process for the production of hydrogen. |
Country Status (1)
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US (1) | US1078686A (en) |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20090000194A1 (en) * | 2006-01-12 | 2009-01-01 | Liang-Shih Fan | Systems and Methods of Converting Fuel |
US9371227B2 (en) | 2009-09-08 | 2016-06-21 | Ohio State Innovation Foundation | Integration of reforming/water splitting and electrochemical systems for power generation with integrated carbon capture |
US9376318B2 (en) | 2008-09-26 | 2016-06-28 | The Ohio State University | Conversion of carbonaceous fuels into carbon free energy carriers |
US9518236B2 (en) | 2009-09-08 | 2016-12-13 | The Ohio State University Research Foundation | Synthetic fuels and chemicals production with in-situ CO2 capture |
US9616403B2 (en) | 2013-03-14 | 2017-04-11 | Ohio State Innovation Foundation | Systems and methods for converting carbonaceous fuels |
US9777920B2 (en) | 2011-05-11 | 2017-10-03 | Ohio State Innovation Foundation | Oxygen carrying materials |
US9903584B2 (en) | 2011-05-11 | 2018-02-27 | Ohio State Innovation Foundation | Systems for converting fuel |
US10010847B2 (en) | 2010-11-08 | 2018-07-03 | Ohio State Innovation Foundation | Circulating fluidized bed with moving bed downcomers and gas sealing between reactors |
US10022693B2 (en) | 2014-02-27 | 2018-07-17 | Ohio State Innovation Foundation | Systems and methods for partial or complete oxidation of fuels |
US10144640B2 (en) | 2013-02-05 | 2018-12-04 | Ohio State Innovation Foundation | Methods for fuel conversion |
US10549236B2 (en) | 2018-01-29 | 2020-02-04 | Ohio State Innovation Foundation | Systems, methods and materials for NOx decomposition with metal oxide materials |
US11090624B2 (en) | 2017-07-31 | 2021-08-17 | Ohio State Innovation Foundation | Reactor system with unequal reactor assembly operating pressures |
US11111143B2 (en) | 2016-04-12 | 2021-09-07 | Ohio State Innovation Foundation | Chemical looping syngas production from carbonaceous fuels |
US11413574B2 (en) | 2018-08-09 | 2022-08-16 | Ohio State Innovation Foundation | Systems, methods and materials for hydrogen sulfide conversion |
US11453626B2 (en) | 2019-04-09 | 2022-09-27 | Ohio State Innovation Foundation | Alkene generation using metal sulfide particles |
-
1911
- 1911-12-09 US US664809A patent/US1078686A/en not_active Expired - Lifetime
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20090000194A1 (en) * | 2006-01-12 | 2009-01-01 | Liang-Shih Fan | Systems and Methods of Converting Fuel |
US9376318B2 (en) | 2008-09-26 | 2016-06-28 | The Ohio State University | Conversion of carbonaceous fuels into carbon free energy carriers |
US9371227B2 (en) | 2009-09-08 | 2016-06-21 | Ohio State Innovation Foundation | Integration of reforming/water splitting and electrochemical systems for power generation with integrated carbon capture |
US9518236B2 (en) | 2009-09-08 | 2016-12-13 | The Ohio State University Research Foundation | Synthetic fuels and chemicals production with in-situ CO2 capture |
US10865346B2 (en) | 2009-09-08 | 2020-12-15 | Ohio State Innovation Foundation | Synthetic fuels and chemicals production with in-situ CO2 capture |
US10253266B2 (en) | 2009-09-08 | 2019-04-09 | Ohio State Innovation Foundation | Synthetic fuels and chemicals production with in-situ CO2 capture |
US10010847B2 (en) | 2010-11-08 | 2018-07-03 | Ohio State Innovation Foundation | Circulating fluidized bed with moving bed downcomers and gas sealing between reactors |
US9777920B2 (en) | 2011-05-11 | 2017-10-03 | Ohio State Innovation Foundation | Oxygen carrying materials |
US10502414B2 (en) | 2011-05-11 | 2019-12-10 | Ohio State Innovation Foundation | Oxygen carrying materials |
US9903584B2 (en) | 2011-05-11 | 2018-02-27 | Ohio State Innovation Foundation | Systems for converting fuel |
US10144640B2 (en) | 2013-02-05 | 2018-12-04 | Ohio State Innovation Foundation | Methods for fuel conversion |
US10501318B2 (en) | 2013-02-05 | 2019-12-10 | Ohio State Innovation Foundation | Methods for fuel conversion |
US9616403B2 (en) | 2013-03-14 | 2017-04-11 | Ohio State Innovation Foundation | Systems and methods for converting carbonaceous fuels |
US10022693B2 (en) | 2014-02-27 | 2018-07-17 | Ohio State Innovation Foundation | Systems and methods for partial or complete oxidation of fuels |
US11111143B2 (en) | 2016-04-12 | 2021-09-07 | Ohio State Innovation Foundation | Chemical looping syngas production from carbonaceous fuels |
US11090624B2 (en) | 2017-07-31 | 2021-08-17 | Ohio State Innovation Foundation | Reactor system with unequal reactor assembly operating pressures |
US10549236B2 (en) | 2018-01-29 | 2020-02-04 | Ohio State Innovation Foundation | Systems, methods and materials for NOx decomposition with metal oxide materials |
US11413574B2 (en) | 2018-08-09 | 2022-08-16 | Ohio State Innovation Foundation | Systems, methods and materials for hydrogen sulfide conversion |
US11826700B2 (en) | 2018-08-09 | 2023-11-28 | Ohio State Innovation Foundation | Systems, methods and materials for hydrogen sulfide conversion |
US11453626B2 (en) | 2019-04-09 | 2022-09-27 | Ohio State Innovation Foundation | Alkene generation using metal sulfide particles |
US11767275B2 (en) | 2019-04-09 | 2023-09-26 | Ohio State Innovation Foundation | Alkene generation using metal sulfide particles |
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