US1230095A - Paper. - Google Patents

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Publication number
US1230095A
US1230095A US7760216A US1230095A US 1230095 A US1230095 A US 1230095A US 7760216 A US7760216 A US 7760216A US 1230095 A US1230095 A US 1230095A
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US
United States
Prior art keywords
paper
silica
web
coating
uncombined
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Expired - Lifetime
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James E Baum Jr
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Individual
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Individual
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Priority to US7760216 priority Critical patent/US1230095A/en
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Publication of US1230095A publication Critical patent/US1230095A/en
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Expired - Lifetime legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/56Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/58Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31725Of polyamide
    • Y10T428/31768Natural source-type polyamide [e.g., casein, gelatin, etc.]
    • Y10T428/31772Next to cellulosic
    • Y10T428/31775Paper

Definitions

  • the object of my invention is to provide ,an improved paper having its surface coated or otherwise formed with a special compound which will enable the calendered paper to have a very smooth, dead or flat finish making it beautiful in texture, capable of receiving printed impressions from half-tone Work of the finest mesh, and restful to the eyes when employed in books and reading matter generally.
  • the paper stock in the beaters is loaded with'the filler which is beaten up and incorporated with the paper stock being treated before it is fed to the paper mill proper.
  • the loading material in these cases has usually been sulfate of lime and kaolin and sometimes infusorial earth, but the finished paper in these cases as in the other, receives more or less gloss when passed through the calendering rolls.
  • the surface of the calendered paper may be of a smooth dead or flat finish, capable of receiving perfect imprints from the finest half-tone engravings and imparting the most artistic effect to the printed matter.
  • the paper web may be coated with my imings and dryings may be done before any calenderlng. So far as these steps are concerned, any of the usual procedures may be followed and conducted with the machinery and appliances in common use.
  • the coating material or compound consists essentially of silica in such fine subdivision as to be air-floated, water-floated or impalpable and hence substantially free from grit, associated with suflicient water and animal size or, casein to give a creamy liquid consistency which may be easily applied to the traveling web of paper. This is usually applied by the present methods in use when using the kaolin compounds, and hence no de ailed description of the apparatus will be necessary.
  • the paper web After the paper web has been coated on oneside, it is conveyed through the drying room in loops by traveling bars,as customary; and when dried, the web is passed through the .calendering rolls.
  • the coating is only upon one surface of the web, but if both sides of the paper are to be coated, then, before or after the calendering operation, the dried paper web is returned and subjected to a coating operation on its other side, or the operation may be continued with a second set of coating and drying apparatus. After the second coating, -the paper web is subjected to the calendering operation and is then ready for the market.
  • the coating compound will give a very white finish, but this may be varied to suit any color or tint desiredby incorporating into the creamy liquid the coloring matter desired. It is also evident that a colored sand, such as contains oxid of iron, might be used to provide a pale yellow or ocher tint,and in such case no additional coloring matter than the iron present need be added.
  • I may mix any desired quantities of-kaolin or other powdered material suitable for coating, with the powder-e silica and thereby obtain varying degrees of finely powdered uncombined'silica' may be employed with the sizing in the paper stool; before being fed to the fourdrinier of the paper making machine, in which case the silica will constitute a loading or give body to the fiber of the stock; and if the loading is in sufficient quantity, the calendered paper so made may be employed without the additional surface coating above described.
  • my invention 'comprehends the incorporation with the paper of the silica powder held in place by a suitable sizeor binder, whether this is accomplished simply as a coating or incorporated into the body as loading and applied to the paper stock in the beating engine, or otherwise, preliminary to the formation of the web.
  • paper in sheet or web form having a. coating of uncombined silica in a state of impalpable 40 impalpable powder mixed with clay in such proportions as to impart a moderate degree of gloss and a very smooth surface.
  • paper having its fiber associated with impalpable powder, of uncombined silica, and calendered to a smooth surface.
  • paper in sheets or web form having its surface provided with an impalpable powder of uncombined silica held in place by size, and calendered to a smooth surface.

Description

r FFIQE,
JAMES E. BAUM, JR., OF CHICAGO, ILLINbIS.
Patented June 19, 1917.
PAPER.
1,230,095 Specification of Letters Patent. No Drawing. Application filed February 11, 1916. Serial No. 77,602.
To all whom it may concern:
Be it known that I, JAMES E. BAUM, J r., a citizen of the United States, and resident of Chicago, county of Cook and State of Illinois,'have invented an Improvement in Paper, of which the following is a specification.
The object of my invention is to provide ,an improved paper having its surface coated or otherwise formed with a special compound which will enable the calendered paper to have a very smooth, dead or flat finish making it beautiful in texture, capable of receiving printed impressions from half-tone Work of the finest mesh, and restful to the eyes when employed in books and reading matter generally.
Heretofore, it has been customary to coat the paper with a filler or loading of kaolin, known as pipe clay and china clay, the same being essentially silicate of alumina. In practice, these substances have been dissolved in Water'and with animal sizing or casein to the consistence of a creamy liquid, with or without coloring matter and applied to the surface or surfaces of the paper and, after drying, subjected to cal'endering to give finish. Such papers, while having a fine finish, have a very high luster or gloss and hence are more or less objectionable for many uses.
In some cases the paper stock in the beaters is loaded with'the filler which is beaten up and incorporated with the paper stock being treated before it is fed to the paper mill proper. The loading material in these cases has usually been sulfate of lime and kaolin and sometimes infusorial earth, but the finished paper in these cases as in the other, receives more or less gloss when passed through the calendering rolls.
I have found that, if the paper web is coated or loaded with relatively pure silica, (that is, uncombined and hence differing from silicates) such as produced as an impalpable powder from pulverized white sand or quartz (which may be produced in a tube mill), associated with a suitable binder or size, the surface of the calendered paper may be of a smooth dead or flat finish, capable of receiving perfect imprints from the finest half-tone engravings and imparting the most artistic effect to the printed matter.
In carrying my lnvention into practice, the paper web may be coated with my imings and dryings may be done before any calenderlng. So far as these steps are concerned, any of the usual procedures may be followed and conducted with the machinery and appliances in common use.
The coating material or compound consists essentially of silica in such fine subdivision as to be air-floated, water-floated or impalpable and hence substantially free from grit, associated with suflicient water and animal size or, casein to give a creamy liquid consistency which may be easily applied to the traveling web of paper. This is usually applied by the present methods in use when using the kaolin compounds, and hence no de ailed description of the apparatus will be necessary.
After the paper web has been coated on oneside, it is conveyed through the drying room in loops by traveling bars,as customary; and when dried, the web is passed through the .calendering rolls.
In some cases the coating is only upon one surface of the web, but if both sides of the paper are to be coated, then, before or after the calendering operation, the dried paper web is returned and subjected to a coating operation on its other side, or the operation may be continued with a second set of coating and drying apparatus. After the second coating, -the paper web is subjected to the calendering operation and is then ready for the market.
If white sand (uncombined) is employed in the preparation of the silica powder, the coating compound will give a very white finish, but this may be varied to suit any color or tint desiredby incorporating into the creamy liquid the coloring matter desired. It is also evident that a colored sand, such as contains oxid of iron, might be used to provide a pale yellow or ocher tint,and in such case no additional coloring matter than the iron present need be added.
this respect. I may mix any desired quantities of-kaolin or other powdered material suitable for coating, with the powder-e silica and thereby obtain varying degrees of finely powdered uncombined'silica' may be employed with the sizing in the paper stool; before being fed to the fourdrinier of the paper making machine, in which case the silica will constitute a loading or give body to the fiber of the stock; and if the loading is in sufficient quantity, the calendered paper so made may be employed without the additional surface coating above described. Broadly considered, my invention 'comprehends the incorporation with the paper of the silica powder held in place by a suitable sizeor binder, whether this is accomplished simply as a coating or incorporated into the body as loading and applied to the paper stock in the beating engine, or otherwise, preliminary to the formation of the web.
Having now described my invention, what I claim as new and desire to secure by Letters Patent, is
1. As an article of manufacture, paper in sheet or web form having a. coating of uncombined silica in a state of impalpable 40 impalpable powder mixed with clay in such proportions as to impart a moderate degree of gloss and a very smooth surface.
4:. As an article of manufacture, paper in sheet or web form coated with a compound composed essentially of uncombined silica in a state of impalpable powder mixed with a coloring matter and suflicient size to act as a binder between the materials and with the fiber and form a very smooth surface.
5. As an article of manufacture, paper having its fiber associated with impalpable powder, of uncombined silica, and calendered to a smooth surface.
6. As an article of manufacture, paper in sheets or web form having its surface provided with an impalpable powder of uncombined silica held in place by size, and calendered to a smooth surface.
In testimony of which invention, I here unto set my hand.-
JAMES E. BAUM, JR.
Witnesses:
R. M. HUNTER, FLORENCE DEACON.
US7760216 1916-02-11 1916-02-11 Paper. Expired - Lifetime US1230095A (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2433515A (en) * 1945-04-18 1947-12-30 H P Andrews Paper Company Method of making photographic paper
US2485724A (en) * 1945-12-21 1949-10-25 Pittsburgh Corning Corp Method of making lightweight cellular materials
DE955110C (en) * 1952-06-28 1956-12-27 Gen Aniline & Film Corp Blueprint material for the diazotype process and process for its production
DE1002623B (en) * 1951-07-18 1957-02-14 Gen Aniline & Film Corp Process for the production of diazotype material
DE965674C (en) * 1947-10-30 1957-06-13 Gen Aniline & Film Corp Diazotype material
US3022213A (en) * 1958-02-13 1962-02-20 Michigan Res Lab Inc Conductive web and method of making same
US3373070A (en) * 1964-05-01 1968-03-12 Gen Electric Laminates
US3720514A (en) * 1969-07-17 1973-03-13 Xerox Corp Electrophotographic paper having an inorganic colloidal oxide coating
US3787235A (en) * 1970-07-06 1974-01-22 Xerox Corp Method of electrophotographic sensitive paper
USRE30233E (en) * 1971-05-28 1980-03-18 The Mead Corporation Multiple layer decorated paper, laminate prepared therefrom and process

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2433515A (en) * 1945-04-18 1947-12-30 H P Andrews Paper Company Method of making photographic paper
US2485724A (en) * 1945-12-21 1949-10-25 Pittsburgh Corning Corp Method of making lightweight cellular materials
DE965674C (en) * 1947-10-30 1957-06-13 Gen Aniline & Film Corp Diazotype material
DE1002623B (en) * 1951-07-18 1957-02-14 Gen Aniline & Film Corp Process for the production of diazotype material
DE955110C (en) * 1952-06-28 1956-12-27 Gen Aniline & Film Corp Blueprint material for the diazotype process and process for its production
US3022213A (en) * 1958-02-13 1962-02-20 Michigan Res Lab Inc Conductive web and method of making same
US3373070A (en) * 1964-05-01 1968-03-12 Gen Electric Laminates
US3720514A (en) * 1969-07-17 1973-03-13 Xerox Corp Electrophotographic paper having an inorganic colloidal oxide coating
US3787235A (en) * 1970-07-06 1974-01-22 Xerox Corp Method of electrophotographic sensitive paper
USRE30233E (en) * 1971-05-28 1980-03-18 The Mead Corporation Multiple layer decorated paper, laminate prepared therefrom and process

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