US1321062A - Gas-detector. - Google Patents
Gas-detector. Download PDFInfo
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- US1321062A US1321062A US26875118A US26875118A US1321062A US 1321062 A US1321062 A US 1321062A US 26875118 A US26875118 A US 26875118A US 26875118 A US26875118 A US 26875118A US 1321062 A US1321062 A US 1321062A
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- gases
- gas
- tube
- hoolamite
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/0004—Gaseous mixtures, e.g. polluted air
- G01N33/0009—General constructional details of gas analysers, e.g. portable test equipment
- G01N33/0027—General constructional details of gas analysers, e.g. portable test equipment concerning the detector
- G01N33/0036—Specially adapted to detect a particular component
- G01N33/004—Specially adapted to detect a particular component for CO, CO2
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/16—Phosphorus containing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/17—Nitrogen containing
- Y10T436/173845—Amine and quaternary ammonium
- Y10T436/175383—Ammonia
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/20—Oxygen containing
- Y10T436/204998—Inorganic carbon compounds
- Y10T436/205831—Carbon monoxide only
Definitions
- This invention relates to methods of and means for detecting oxdizable gases such as carbon monoxid, ars'in, phosphin, ammonia, and many others, and also relates specifically to methods of and means for detecting small quantities of carbon monoxid.
- One of the objects of the invention is to provide a compact and self-contained unit for the detection of the above gases, one that can be used for the detection of harmful gases in mines, industrial plants, etc.
- the invention consists in making use of a very sensitive form of the material described and claimed by us in application Serial No. 268,750, filed concurrently herewith, in such manner as to permit the observation of the color change characteristic of the material and in such manner as to allow the material to undergo this change only in the presence of a particular gas.
- Detectors prepared in accordance with the present invention are shown in the accompanying drawings in which the figures show two types of prepared units for the detection of carbon monoxid, Figure 1 showing the arrangement of the materials in a single tube and Fig. 2 showing a similar arrangement of materials but having the several materials in separate and detachable tubes, so that any one of them may be removed and a fresh one substituted when it is considered necessary.
- hoolamite a material which, for want of a better name, has been named hoolamite.
- the composition of the material varies somewhat according to the purpose for which it is to be used, but only in the proportions of the several constituents.
- the nal product is a mixture or compound, or both, of oxids of iodin, oxids of sulfur, and water. There may be added to this a small amount of iodin and a solid supporting substance,
- solid supporting material may be pumice or asbestos 'but it should be understood that any suitable material may be used in the place of these.
- fuming sulfuric acid and iodc anhydrid are used in proportions varying from a small amount of one in a relatively large amount of the other to a relatively large amount of the first with a small amount of the second.
- the most advantageous mixtures for most purposes lie in the range of from 3 to 1v of the acid to l to 10 of the iodic anhydrid,
- the particular proportlons to be chosen will depend upon the use. For example, in respirators, it is desirable to use a composition having not too great a proportion of fuming sulfuric acid because of the tendency to give oil' sulfuric anhydrid. For other purposes it may be that a small amount of sulfuric anhydrid in the gas after treatment will not be objectionable and in such cases a greater proportion of the acid my be used with an increase in the sensitiveness of the composition.
- the latter may be thoroughly mixed dry with the pumice and the fuming sulfurid acid then added and the whole mixed until uniform.
- the iodio anhydrid may be prepared for reaction by saturating the granular or fragmentary carrier with iodio acid in water, evaporating to dryness, and continuing the heating to dehydrate the acid, leaving iodio anhydrid on the carrier. This is then mixed with the fuming sulfuric acid as before indicated.
- the material prepared in the manner dicated in the above mentioned application may be modied as to its sensitiveness by the varia-tion of the amounts of the constituents, as indicated in the description.
- the oxidizing absorbent is repared by thorough mixing of iodic anhy .rid and strong fuming sulfuric acid with orwlthout the addition of a carrying material, such as asbestos ory pumice, depending upon whether the constituents are so proportioned as to produce a liquid or a solid product.
- a carrying material such as asbestos ory pumice
- a liquid product is desirable, but, in most cases, if the product is a liquid, it must be absorbed in-such a carrier as above mentioned in order that gases may be suiti ably' contacted therewith, such as by passing them through it.
- Material prepared in this method reacts In choosingv proportions of the constituents for the purposeofmaking a' detector which will make the color change more pronounced, .e., the material should be suliciently White to enable one to easily perceive the green tinge caused by a small amountof oxidizable gas..
- a more specific application of the material is its use in the detection and approximate estimation of the carbon monoxid, present in gas mixtures.
- This use may be carried out by preparing a tube containing a layer of active charcoal or other suitable absorbent and a layer of the oxidizing absorbent material and passing gases through the tube in such manner that they pass through the charcoal first and in measuring the amount passed.
- the charcoal will absorb from the gases substantially all of the oxidizable gases except carbon monoxidtand hydrogen and. the latter will not react With 'the material. As the color change of the material is un'rform and gradual, the extent of the change will indicate how much carbon monoxid has been acted upon.
- Fig, 1 The device shown in Fig, 1 is one not intended to be renewed after once having been exhausted. That of Fig. 2 is one in which the several parts may be detached and fresh elements substituted therefor. y
- A is a glass tube having a reduced portion at one end and having packed ite in the following fashion: First, there 1s ⁇ a small amount of granular pumice B or equivalent materlal, such as glass wool or .therein charcoal, a drier, and the hoolamsealed ofi".
- Fig. 2 the several elements of the detector are made detachable, a form more convenient for some purposes.
- This form of the detector consists of a small glass tube of the hoolamite H, one end of which may be thrust through the stopper Kwhich its in the end of the tube F containing the granular active charcoal M.
- This charcoal is suitably retained in position in the tube by the porous plugs N and the spring L.
- the delivery end of the bulb O' adapted to force air or other suspected gas through the tube and the materials.
- a means for detecting and estimatin carbon monoxid in gas mixtures comprising a layer of active charcoal, a layer of hoolamite, means for passing the gases through the layers in the order named, and means permitting the observationof the change in color of the hoolamite.
- a means for detecting the presence of oxidizable gases in mixtures of gases comprising a layer of a drying material and .a
- a means for detecting and estimating carbon monoxid in gas mixtures comprising a glass tube containing a layer of active charcoal and a layer of hoolamite and means for passing the gases through the tube and layers in order named.
- a means for detecting the presence of oxidizable gasesin mixtures of gases comprising a glass tube containing a layer of drying material and a layer of hoolamite and means for passing the gas mixture through the tube and layers in the order named;
- Means lfor detecting the presence of oxidizable gases in gas mixtures comprising a tubular element wherein are arranged layers of hoolamite, a drier, and a selective absorbent in such fashion as to permit passing the gas mixture therethrough in the reverse of the order named.
- Means for detecting the presence of carbon monoxid in gas mixtures comprising a separat@J container for bodies of granular active charcoal and a drier, means whereby the gas mixtureJY may be passed through the said materials in series, and means containing a body of hoolamite so arranged as to allow the passage therethrough of the gas mixture previously passed through the drier and charcoal.
- Process of detecting the presence of carbon monoxid in gas mixtures which comprises passing the mixture through an absorbent capable of removing therefrom other oxidizable gases than carbon monoxid and then passing the residual gases through a body of hoolamite, the presence of carbon monoxid being shown by the change of the color of the hoolamite.
- Process of detecting the presence of oxidizable gases in gas mixtures which comprises passing the said mixtures through a drier and then through a body of hoolamite, the presence ofl the oxidizable gases in the mixture being indicated by a change of color of the hoolamite.
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Food Science & Technology (AREA)
- Combustion & Propulsion (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
Description
A. B. LAMB AND c. R. HOOVER.
GAS DETECTOR.
APPLICATION FILED DEC.
' Patented Nov sTATEs PATENT oEEIcE.
B. LAMB, 'OF UNITED STATES ARMY, AND CHARLES R. HOOVER, 0F
MVIDDLETOWN, CONNECTICUT.
Gas-numeros. l
Speoication ot Letters Patent.
Patented Nov. 4t, tfg.
To all 'whom t may concern:
Be it known that we, Lieut. Col., and CHAnLEs -R. HoovER, civilian, Chemical Warfare Service, U. S. Army, citizens of the United States, and residing at 'Washingtom D. C., and Middletown, Connecticut, respectively, have invented certain new and useful Improvements in Gas-Detectors, of which the following is a specification.
This invention relates to methods of and means for detecting oxdizable gases such as carbon monoxid, ars'in, phosphin, ammonia, and many others, and also relates specifically to methods of and means for detecting small quantities of carbon monoxid.
One of the objects of the invention is to provide a compact and self-contained unit for the detection of the above gases, one that can be used for the detection of harmful gases in mines, industrial plants, etc.
The invention consists in making use of a very sensitive form of the material described and claimed by us in application Serial No. 268,750, filed concurrently herewith, in such manner as to permit the observation of the color change characteristic of the material and in such manner as to allow the material to undergo this change only in the presence of a particular gas.
Detectors prepared in accordance with the present invention are shown in the accompanying drawings in which the figures show two types of prepared units for the detection of carbon monoxid, Figure 1 showing the arrangement of the materials in a single tube and Fig. 2 showing a similar arrangement of materials but having the several materials in separate and detachable tubes, so that any one of them may be removed and a fresh one substituted when it is considered necessary.
In the codepending application above referred to, there are described processes of making a material which, for want of a better name, has been named hoolamite. The composition of the material varies somewhat according to the purpose for which it is to be used, but only in the proportions of the several constituents. The nal product is a mixture or compound, or both, of oxids of iodin, oxids of sulfur, and water. There may be added to this a small amount of iodin and a solid supporting substance,
ARTHUR B. LAMB,
solid supporting material may be pumice or asbestos 'but it should be understood that any suitable material may be used in the place of these.
In the preparation of the new product, fuming sulfuric acid and iodc anhydrid are used in proportions varying from a small amount of one in a relatively large amount of the other to a relatively large amount of the first with a small amount of the second. The most advantageous mixtures for most purposes, however, lie in the range of from 3 to 1v of the acid to l to 10 of the iodic anhydrid, The particular proportlons to be chosen will depend upon the use. For example, in respirators, it is desirable to use a composition having not too great a proportion of fuming sulfuric acid because of the tendency to give oil' sulfuric anhydrid. For other purposes it may be that a small amount of sulfuric anhydrid in the gas after treatment will not be objectionable and in such cases a greater proportion of the acid my be used with an increase in the sensitiveness of the composition.
In these processes involving the use of pumice as a carrier it has been found to be an advantage to heat the pumice immediately before mixing, as this allows a better mixing and produces a somewhat better product.
Instead of first mixing the acid and umice with the subsequent addition o the iodic anhydrid, the latter may be thoroughly mixed dry with the pumice and the fuming sulfurid acid then added and the whole mixed until uniform.
Further, instead of proceeding in the manner indicated in the last paragraph, the iodio anhydrid may be prepared for reaction by saturating the granular or fragmentary carrier with iodio acid in water, evaporating to dryness, and continuing the heating to dehydrate the acid, leaving iodio anhydrid on the carrier. This is then mixed with the fuming sulfuric acid as before indicated.
In case a solid product without a support is desired, about equal parts of iodio anhydrid and fuming sulfuric acid are allowed to interact at a slightly elevated temperature or allowed to stand in contact for a few depending upon the use of the product. The
vdays until a. hard uniform product is obtained. This is then broken in pieces ofthose cases where a larg? proportion of fuming sulfuric acid has een used and when acting as an oxidizing agent undergoes a color change from White to green to brown. This color change is not permanent but dis.- appears on standing and the material may be repeatedly reused until the iodic ox1d has been entirely reduced. It is strongly corrosive and therefore should be kept in containers of glass, porcelain, etc. t
The material prepared in the manner dicated in the above mentioned application may be modied as to its sensitiveness by the varia-tion of the amounts of the constituents, as indicated in the description.
In general, the oxidizing absorbent is repared by thorough mixing of iodic anhy .rid and strong fuming sulfuric acid with orwlthout the addition of a carrying material, such as asbestos ory pumice, depending upon whether the constituents are so proportioned as to produce a liquid or a solid product. In some cases a liquid product is desirable, but, in most cases, if the product is a liquid, it must be absorbed in-such a carrier as above mentioned in order that gases may be suiti ably' contacted therewith, such as by passing them through it.
In making up a product to be used in detecting small amounts of oxidizable gases mixed with large quantities ofv diluting gases,it is necessary to so proportion the constituents as to give a very sensitive product. This is done by increasing the proportion of the fuming sulfuric acid, as, within certain limits, the greater the proportion of the fuming sulfuric acid, the more sensitive the product.
As a specific example ofthe preparation of a product which is suitable for use in the detection of, e. y., carbon monoxid, the following method is given:
30 parts4 of pumice stone, freed from organic matter and water byy ignition, and passing through a 2O mesh but retained by a 40 mesh screen, are treated with 50 parts of fuming sulfuric acid, sulfur trioxid and after thorough mixing, 10 parts of iodic anhydridare added and thoroughly mixed. The product isa white granular solid.
In order to increase the lsensitiveness it 1s sometimes advanta eous to add a small proportion of iodin, grom .25 to 2% being sufficient.
Material prepared in this method reacts In choosingv proportions of the constituents for the purposeofmaking a' detector which will make the color change more pronounced, .e., the material should be suliciently White to enable one to easily perceive the green tinge caused by a small amountof oxidizable gas..
.In using the above material for the detection of oxidizable gases it is only necessary to pack someI of the material in a glass tube and pass the gases therethrough, whereupon the presence of the oxidizable gases will cause the characteristic color change to green and if in sufficient quantity, to
brown. It is better, however, when making use of the material, to protect it from the moisture usually present and this may bel done 'by placing in the tube on either side of the material, a drier such as pumice in which has been absorbed sulfuric acid.
A more specific application of the material is its use in the detection and approximate estimation of the carbon monoxid, present in gas mixtures. This use may be carried out by preparing a tube containing a layer of active charcoal or other suitable absorbent and a layer of the oxidizing absorbent material and passing gases through the tube in such manner that they pass through the charcoal first and in measuring the amount passed. The charcoal will absorb from the gases substantially all of the oxidizable gases except carbon monoxidtand hydrogen and. the latter will not react With 'the material. As the color change of the material is un'rform and gradual, the extent of the change will indicate how much carbon monoxid has been acted upon.
It is, of course, evident that tubes containing the several substances mentioned may be previously prepared andused singly or togethervas indicated above. y
In the drawings there are shown two 'suitable arrangements of apparatus which may be used for the detection and approximate estimation of carbon monoxid.
The device shown in Fig, 1 is one not intended to be renewed after once having been exhausted. That of Fig. 2 is one in which the several parts may be detached and fresh elements substituted therefor. y
In Fig. 1, A is a glass tube having a reduced portion at one end and having packed ite in the following fashion: First, there 1s`a small amount of granular pumice B or equivalent materlal, such as glass wool or .therein charcoal, a drier, and the hoolamsealed ofi".
asbestos. This pumice or other material is used for the purpose of retaining the granular charcoal C which is used for the purpose of absorbing other oxidizable gases than carbon monoxid. Next in order in the tube is the layer of drier D which is preferably though not necessarily sulfuric acid absorbed by granules of pumice. In the reduced portion of the tube there is placed the hoolamite in granular form E and the ends of the tube In using the tube of material thus pre-` pared, it is only necessary to break oif the tips of the tube and` force the-suspected gas mixture through the tube and materials in the order above indicated. If the gas contains carbon monoxid, the color ofv the hoolamite changes in the characteristic manner.
In Fig. 2 the several elements of the detector are made detachable, a form more convenient for some purposes. This form of the detector consists of a small glass tube of the hoolamite H, one end of which may be thrust through the stopper Kwhich its in the end of the tube F containing the granular active charcoal M. This charcoal is suitably retained in position in the tube by the porous plugs N and the spring L. In the other end of the tube- F is inserted the delivery end of the bulb O' adapted to force air or other suspected gas through the tube and the materials.
It is to be understood that the invention is not to be limited to the specific examples herein given as it is obvious that these may be varied without departing from the spirit v of the invention as defined inthe accompanying claims. i
Claims:
1.v A means for detecting and estimatin carbon monoxid in gas mixtures, comprising a layer of active charcoal, a layer of hoolamite, means for passing the gases through the layers in the order named, and means permitting the observationof the change in color of the hoolamite.
2. A means for detecting the presence of oxidizable gases in mixtures of gases, comprising a layer of a drying material and .a
layer of hoolamite and means for permitting the observation of the color change in the hoolamite.
3.Y A means for detecting and estimating carbon monoxid in gas mixtures, comprising a glass tube containing a layer of active charcoal and a layer of hoolamite and means for passing the gases through the tube and layers in order named.
4. A means for detecting the presence of oxidizable gasesin mixtures of gases, comprising a glass tube containing a layer of drying material and a layer of hoolamite and means for passing the gas mixture through the tube and layers in the order named;
5. Means lfor detecting the presence of oxidizable gases in gas mixtures, comprising a tubular element wherein are arranged layers of hoolamite, a drier, and a selective absorbent in such fashion as to permit passing the gas mixture therethrough in the reverse of the order named.
6. Means for detecting the presence of carbon monoxid in gas mixtures, comprising a separat@J container for bodies of granular active charcoal and a drier, means whereby the gas mixtureJY may be passed through the said materials in series, and means containing a body of hoolamite so arranged as to allow the passage therethrough of the gas mixture previously passed through the drier and charcoal.
7. Process of detecting the presence of carbon monoxid in gas mixtures which comprises passing the mixture through an absorbent capable of removing therefrom other oxidizable gases than carbon monoxid and then passing the residual gases through a body of hoolamite, the presence of carbon monoxid being shown by the change of the color of the hoolamite.
8. Process of detecting the presence of oxidizable gases in gas mixtures, which comprises passing the said mixtures through a drier and then through a body of hoolamite, the presence ofl the oxidizable gases in the mixture being indicated by a change of color of the hoolamite.
ARTHUR B. LAMB. CHARLES R. HOOVER.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US26875118A US1321062A (en) | 1918-12-28 | 1918-12-28 | Gas-detector. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US26875118A US1321062A (en) | 1918-12-28 | 1918-12-28 | Gas-detector. |
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US1321062A true US1321062A (en) | 1919-11-04 |
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US26875118A Expired - Lifetime US1321062A (en) | 1918-12-28 | 1918-12-28 | Gas-detector. |
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Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE741932C (en) * | 1940-01-17 | 1943-11-19 | Auergesellschaft Ag | Detector tubes for gas detectors |
DE742910C (en) * | 1933-05-25 | 1943-12-14 | Draegerwerk Heinr U Bernh Drae | Method for the detection of small amounts of gas or steam in air or other gases |
US2429694A (en) * | 1944-03-29 | 1947-10-28 | Little Inc A | Method and equipment for indicating the water content of a gas |
US2483108A (en) * | 1947-06-19 | 1949-09-27 | Silverman Leslie | Determination of chromium compounds in gaseous atmospheres |
US2487077A (en) * | 1943-12-28 | 1949-11-08 | Us Commerce | Colorimetric gas detection |
US2534229A (en) * | 1945-03-15 | 1950-12-19 | Homer W Carhart | Method and apparatus for detecting hydrogen cyanide |
US2552477A (en) * | 1946-06-05 | 1951-05-08 | Cole James Webb | Temperature time integrator |
US2569895A (en) * | 1943-07-12 | 1951-10-02 | Main-Smith John David | Detection of carbon monoxide by palladous sulfite and/or palladosulfites |
DE858150C (en) * | 1941-09-25 | 1952-12-04 | Draegerwerk Ag | Process for adjusting reaction masses consisting of silica-iodine pentoxide-sulfur trioxide mixtures for carbon dioxide test tubes by means of iodine |
US2850359A (en) * | 1956-09-07 | 1958-09-02 | Worthington Biochem Corp | Testing unit and method of testing for glucose |
US2888331A (en) * | 1954-12-27 | 1959-05-26 | Virginia C Carpenter | Testing device |
US3022141A (en) * | 1959-04-29 | 1962-02-20 | Dragerwerks Heinr & Bernh Drag | Small testing tubes having three or more separately arranged reagents or reagent layers |
US3113842A (en) * | 1961-10-20 | 1963-12-10 | Corning Glass Works | Gas detection apparatus |
US3956940A (en) * | 1975-05-05 | 1976-05-18 | Guild Lloyd V | Sampling of fluid |
US3997296A (en) * | 1975-02-06 | 1976-12-14 | Spex Industries Inc. | Primary standards |
US4077776A (en) * | 1976-06-18 | 1978-03-07 | Dragerwerk Aktiengesellschaft | Gas and gas-carried suspended matter indicator tube having fixing elements for reagent carriers |
US4079622A (en) * | 1975-05-21 | 1978-03-21 | Snamprogetti S.P.A. | Apparatus for determining the smoke density of flue gases of gas and fuel oil |
US4692309A (en) * | 1985-09-05 | 1987-09-08 | Dragerwerk Ag | Diffusion sample collector for gaseous media |
US4731333A (en) * | 1985-06-25 | 1988-03-15 | Japan Pionics., Ltd. | Method for detecting gaseous hydrides |
US6217827B1 (en) * | 1999-03-25 | 2001-04-17 | Zellweger Analytics, Inc. | Hydride gas detecting tape |
-
1918
- 1918-12-28 US US26875118A patent/US1321062A/en not_active Expired - Lifetime
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE742910C (en) * | 1933-05-25 | 1943-12-14 | Draegerwerk Heinr U Bernh Drae | Method for the detection of small amounts of gas or steam in air or other gases |
DE741932C (en) * | 1940-01-17 | 1943-11-19 | Auergesellschaft Ag | Detector tubes for gas detectors |
DE858150C (en) * | 1941-09-25 | 1952-12-04 | Draegerwerk Ag | Process for adjusting reaction masses consisting of silica-iodine pentoxide-sulfur trioxide mixtures for carbon dioxide test tubes by means of iodine |
US2569895A (en) * | 1943-07-12 | 1951-10-02 | Main-Smith John David | Detection of carbon monoxide by palladous sulfite and/or palladosulfites |
US2487077A (en) * | 1943-12-28 | 1949-11-08 | Us Commerce | Colorimetric gas detection |
US2429694A (en) * | 1944-03-29 | 1947-10-28 | Little Inc A | Method and equipment for indicating the water content of a gas |
US2534229A (en) * | 1945-03-15 | 1950-12-19 | Homer W Carhart | Method and apparatus for detecting hydrogen cyanide |
US2552477A (en) * | 1946-06-05 | 1951-05-08 | Cole James Webb | Temperature time integrator |
US2483108A (en) * | 1947-06-19 | 1949-09-27 | Silverman Leslie | Determination of chromium compounds in gaseous atmospheres |
US2888331A (en) * | 1954-12-27 | 1959-05-26 | Virginia C Carpenter | Testing device |
US2850359A (en) * | 1956-09-07 | 1958-09-02 | Worthington Biochem Corp | Testing unit and method of testing for glucose |
US3022141A (en) * | 1959-04-29 | 1962-02-20 | Dragerwerks Heinr & Bernh Drag | Small testing tubes having three or more separately arranged reagents or reagent layers |
US3113842A (en) * | 1961-10-20 | 1963-12-10 | Corning Glass Works | Gas detection apparatus |
US3997296A (en) * | 1975-02-06 | 1976-12-14 | Spex Industries Inc. | Primary standards |
US3956940A (en) * | 1975-05-05 | 1976-05-18 | Guild Lloyd V | Sampling of fluid |
US4079622A (en) * | 1975-05-21 | 1978-03-21 | Snamprogetti S.P.A. | Apparatus for determining the smoke density of flue gases of gas and fuel oil |
US4077776A (en) * | 1976-06-18 | 1978-03-07 | Dragerwerk Aktiengesellschaft | Gas and gas-carried suspended matter indicator tube having fixing elements for reagent carriers |
US4731333A (en) * | 1985-06-25 | 1988-03-15 | Japan Pionics., Ltd. | Method for detecting gaseous hydrides |
US4692309A (en) * | 1985-09-05 | 1987-09-08 | Dragerwerk Ag | Diffusion sample collector for gaseous media |
US6217827B1 (en) * | 1999-03-25 | 2001-04-17 | Zellweger Analytics, Inc. | Hydride gas detecting tape |
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