US20010047790A1 - Internal combustion engine installation in a motor vehicle - Google Patents

Internal combustion engine installation in a motor vehicle Download PDF

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Publication number
US20010047790A1
US20010047790A1 US09/681,701 US68170101A US2001047790A1 US 20010047790 A1 US20010047790 A1 US 20010047790A1 US 68170101 A US68170101 A US 68170101A US 2001047790 A1 US2001047790 A1 US 2001047790A1
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Prior art keywords
heating device
hydrocarbon
engine
absorbing element
internal combustion
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US09/681,701
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US6408815B2 (en
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Jan Karlsson
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Volvo Car Corp
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Volvo Car Corp
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Assigned to VOLVO CAR CORPORATION reassignment VOLVO CAR CORPORATION ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: KARLSSON, JAN
Publication of US20010047790A1 publication Critical patent/US20010047790A1/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0828Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents characterised by the absorbed or adsorbed substances
    • F01N3/0835Hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02MSUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M23/00Apparatus for adding secondary air to fuel-air mixture
    • F02M23/14Apparatus for adding secondary air to fuel-air mixture characterised by adding hot secondary air
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02MSUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M31/00Apparatus for thermally treating combustion-air, fuel, or fuel-air mixture
    • F02M31/02Apparatus for thermally treating combustion-air, fuel, or fuel-air mixture for heating
    • F02M31/04Apparatus for thermally treating combustion-air, fuel, or fuel-air mixture for heating combustion-air or fuel-air mixture
    • F02M31/06Apparatus for thermally treating combustion-air, fuel, or fuel-air mixture for heating combustion-air or fuel-air mixture by hot gases, e.g. by mixing cold and hot air
    • F02M31/08Apparatus for thermally treating combustion-air, fuel, or fuel-air mixture for heating combustion-air or fuel-air mixture by hot gases, e.g. by mixing cold and hot air the gases being exhaust gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/45Gas separation or purification devices adapted for specific applications
    • B01D2259/455Gas separation or purification devices adapted for specific applications for transportable use
    • B01D2259/4558Gas separation or purification devices adapted for specific applications for transportable use for being employed as mobile cleaners for ambient air, i.e. the earth's atmosphere
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

Definitions

  • the present invention relates to an internal combustion engine installation in a motor vehicle. More specifically, the present invention relates to an internal combustion engine arranged in an engine compartment, with the engine having an intake air conduit that opens to an intake manifold, and an exhaust manifold that opens to an exhaust conduit.
  • the present invention intends to achieve an engine installation which makes it possible to remove additional toxic substances in ambient air, such as existing hydrocarbons from the exhaust of other vehicles.
  • the hydrocarbon-absorbing device can be a zeolite with a honeycomb structure, or an active carbon filter that absorbs hydrocarbons in ambient air. After a certain time, such a device becomes saturated with hydrocarbons and needs to be regenerated, i.e., have the absorbed hydrocarbons removed. This is done by heating the device, thereby enabling the hydrocarbons to be desorbed. Once desorbed, they are sucked into the engine combustion chambers and combusted.
  • the hydrocarbon-absorbing element can be a disc that is rotatable by the engine. The disc may be rotated stepwise after a certain time period, e.g., every ten minutes, so that a new sector of the disc is rotated into the heating device and regenerated while the rest of the disc is exposed to ambient air flowing into the engine compartment.
  • FIG. 1 is a schematic representation of a first embodiment of an engine installation according to the present invention.
  • FIG. 2 is a corresponding schematic representation of a second embodiment of an engine installation according to the present invention.
  • FIG. 1, 1 designates a four-cylinder internal combustion engine with an intake manifold 2 , an air intake filter 3 and an air intake conduit 4 , having a throttle 5 . While a foru-cylinder engine is illustrated, it should be understood that the present invention is applicable to engines of various cylinder configurations.
  • An exhaust manifold 6 has exhaust manifold conduits (not shown) surrounded by an outer cover 7 , which has an inlet 8 and an outlet 9 for air.
  • the exhaust manifold 6 opens into a catalytic converter 27 .
  • the inlet 8 communicates via a conduit 10 with one side of a heat exchanger 11
  • the outlet 9 communicates with the other side of the heat exchanger 11 via a conduit 12 .
  • the heat exchanger 11 is a two-part heat exchanger 11 with a gap 19 between the parts.
  • the gap 19 has a width corresponding to the width of a circular disc-shaped porous element 20 .
  • the element 20 is one that can absorb hydrocarbons, e.g., a zeolite or an active carbon filter.
  • the heat exchanger 11 may be placed behind (or alternatively in front of) and to one side of the engine radiator 21 in the engine compartment so that a major portion of the element 20 outside the heat exchanger is exposed to the radiator 21 .
  • an engine cooling fan 22 with its motor 23 .
  • the element 20 is fixed on a shaft 25 of a step motor 26 , which turns the element 20 a certain angle after a certain period, e.g., one quarter turn every ten minutes.
  • the heat exchanger is dimensioned so that it heats a fourth of the element 20 at a time.
  • a number of plates fixed to a chain conveyor may be used. The plates move past the radiator and are preferably dimensioned so that they overlap the entire surface of the radiator.
  • the segment of the element 20 in the heat exchanger gap 19 is heated by the heat exchanger 11 .
  • the exchanger 11 operates at a temperature of about 150° C., which is needed to desorb those hydrocarbons absorbed by the element 20 from air flowing through the radiator 21 .
  • the desorbed hydrocarbons are then brought by air flowing through the conduit 14 into the intake manifold 2 of the engine.
  • FIG. 2 differs from that described above in that the heat exchanger 11 has been replaced by a heating device 24 .
  • air heated by the exhaust manifold 6 flows directly into the engine intake manifold 2 .
  • the inlet conduit 10 is connected to the engine intake conduit 4 directly after the air filter 3 .
  • the regeneration of the hydrocarbon-absorbing device 20 takes place at low load. This is the predominant operating state for common passenger cars with subatmospheric pressure in the intake pipe downstream of the throttle 5 .
  • the throttles 17 are closed by the step motor 18 to prevent poorer response due to mixing heated air with the intake air.
  • the throttles can be individually controllable, for example, to utilize the suction pulses in the various intake pipes 16 .
  • Tests have shown that merely supply of hot air to the intake air in the manner described at low load can reduce fuel consumption by approximately 3%.
  • additional energy is provided in the order of about 0.05, to about 0.1%.
  • the hydrocarbon absorbent is heated by air which, in turn, has been heated by the exhaust, i.e., the heating is done indirectly by the exhaust.
  • the exhaust it is also possible within the scope of the invention to use the exhaust for direct heating and transport of evaporated hydrocarbons to the intake manifold of the engine, a type of EGR.

Abstract

Internal combustion engine installation in a motor vehicle, comprising an internal combustion engine, arranged in an engine compartment, with a radiator and a hydrocarbon-absorbent arranged behind the radiator, in the form of a disc. A heating device is heated by air, which is heated by the engine exhaust manifold. The disc is rotatable by a motor and is arranged so in relation to the heating device that a portion of the disc is exposed to the radiator when another portion is heated to evaporate absorbed hydrocarbons and regenerate the hydrocarbon absorbent. Released hydrocarbons are drawn through a conduit from the heating device to the engine intake manifold.

Description

    CROSS REFERENCE TO RELATED APPLICATIONS
  • This application claims priority to Swedish Application No. 0001920-8, filed May 23, 2000. [0001]
  • BACKGROUND OF INVENTION
  • 1. Technical Field [0002]
  • The present invention relates to an internal combustion engine installation in a motor vehicle. More specifically, the present invention relates to an internal combustion engine arranged in an engine compartment, with the engine having an intake air conduit that opens to an intake manifold, and an exhaust manifold that opens to an exhaust conduit. [0003]
  • 2. Background Information [0004]
  • The development of new engines for vehicles has been directed for quite some time to increasing the engine efficiency in order to, inter alia, reduce the amount of exhaust and its damaging effects to the environment. Catalytic converters are typically used to reduce the percentage of damaging substances in vehicle exhaust. It is also known to use a hydrocarbon absorbent, e.g., a zeolite, between the exhaust manifold and the catalytic converter to take care of the hydrocarbons before the catalytic converter has become sufficiently hot. Also, combined electric and internal combustion engines, called hybrid engines, have come into commercial use as a means for reducing the amount of exhaust released from engines. [0005]
  • Lately, however, methods have been developed to clean the air already polluted by other vehicles, including breaking down toxic ozone found close to the ground. This ozone is formed by photosynthesis of hydrocarbons and nitrogen oxides, i.e., the smog formed when these substances from vehicle exhaust are subjected to sunlight. In a known method, a catalytic coating is sprayed onto the radiator flanges and pipes of the vehicle. When the ozone comes in contact with the heated catalytic converter coating, it is transformed into oxygen. [0006]
  • SUMMARY OF INVENTION
  • The present invention intends to achieve an engine installation which makes it possible to remove additional toxic substances in ambient air, such as existing hydrocarbons from the exhaust of other vehicles. [0007]
  • This is achieved according to the invention by arranging a hydrocarbon-absorbing element and a heating device relative to each other in an engine compartment so that a portion of the hydrocarbon-absorbing element is exposed to the surrounding engine compartment when another portion of the element is exposed to the heating device. In such manner, by heating the portion of the hydrocarbon-absorbing element with the heating device, hydrocarbons from ambient air that are absorbed by the hydrocarbon-absorbing element are removed from the element. The hydrocarbon-absorbing element is movable in such manner that a portion of the element is able to move to the heating device at the same time as another portion moves away from the heating device. [0008]
  • The hydrocarbon-absorbing device can be a zeolite with a honeycomb structure, or an active carbon filter that absorbs hydrocarbons in ambient air. After a certain time, such a device becomes saturated with hydrocarbons and needs to be regenerated, i.e., have the absorbed hydrocarbons removed. This is done by heating the device, thereby enabling the hydrocarbons to be desorbed. Once desorbed, they are sucked into the engine combustion chambers and combusted. The hydrocarbon-absorbing element can be a disc that is rotatable by the engine. The disc may be rotated stepwise after a certain time period, e.g., every ten minutes, so that a new sector of the disc is rotated into the heating device and regenerated while the rest of the disc is exposed to ambient air flowing into the engine compartment. [0009]
  • BRIEF DESCRIPTION OF DRAWINGS
  • The invention will be described in more detail below with reference to examples shown in the accompanying drawings, wherein: [0010]
  • FIG. 1 is a schematic representation of a first embodiment of an engine installation according to the present invention; and [0011]
  • FIG. 2 is a corresponding schematic representation of a second embodiment of an engine installation according to the present invention.[0012]
  • DETAILED DESCRIPTION
  • In FIG. 1, 1 designates a four-cylinder internal combustion engine with an intake manifold [0013] 2, an air intake filter 3 and an air intake conduit 4, having a throttle 5. While a foru-cylinder engine is illustrated, it should be understood that the present invention is applicable to engines of various cylinder configurations. An exhaust manifold 6 has exhaust manifold conduits (not shown) surrounded by an outer cover 7, which has an inlet 8 and an outlet 9 for air. The exhaust manifold 6 opens into a catalytic converter 27. The inlet 8 communicates via a conduit 10 with one side of a heat exchanger 11, while the outlet 9 communicates with the other side of the heat exchanger 11 via a conduit 12. Cold ambient air is sucked into the heat exchanger 11 at the arrow 13 and flows via the conduit 10 to a space defined between the outsides of the exhaust manifold pipes and the cover 7. The air heated by the exhaust manifold 6 flows to the heat exchanger 11, which in turn is heated. The air continues through an outlet conduit 14 having an air filter 14 a to a pipe 15 that communicates with the inlets of each branch pipe 16 of the intake manifold 2. In each inlet there is a throttle 17 that is controlled by a step motor 18 for controlling the flow of heated air to the combustion chambers of the engine 1.
  • The [0014] heat exchanger 11 is a two-part heat exchanger 11 with a gap 19 between the parts. The gap 19 has a width corresponding to the width of a circular disc-shaped porous element 20. The element 20 is one that can absorb hydrocarbons, e.g., a zeolite or an active carbon filter. As illustrated, the heat exchanger 11 may be placed behind (or alternatively in front of) and to one side of the engine radiator 21 in the engine compartment so that a major portion of the element 20 outside the heat exchanger is exposed to the radiator 21. Between the radiator 21 and the element 20 there is an engine cooling fan 22 with its motor 23.
  • The [0015] element 20 is fixed on a shaft 25 of a step motor 26, which turns the element 20 a certain angle after a certain period, e.g., one quarter turn every ten minutes. In this example, the heat exchanger is dimensioned so that it heats a fourth of the element 20 at a time. Instead of a rotating disc 20, a number of plates fixed to a chain conveyor may be used. The plates move past the radiator and are preferably dimensioned so that they overlap the entire surface of the radiator.
  • The segment of the [0016] element 20 in the heat exchanger gap 19 is heated by the heat exchanger 11. The exchanger 11 operates at a temperature of about 150° C., which is needed to desorb those hydrocarbons absorbed by the element 20 from air flowing through the radiator 21. The desorbed hydrocarbons are then brought by air flowing through the conduit 14 into the intake manifold 2 of the engine.
  • The embodiment in FIG. 2 differs from that described above in that the [0017] heat exchanger 11 has been replaced by a heating device 24. In this embodiment, air heated by the exhaust manifold 6 flows directly into the engine intake manifold 2. This is in contrast to the heat exchanger 11 of FIG. 1, wherein air flowing in at the arrow 13 is conducted twice through the heat exchanger 11 before being conducted into the engine 1. Instead, in the embodiment of FIG. 2, the inlet conduit 10 is connected to the engine intake conduit 4 directly after the air filter 3.
  • The regeneration of the hydrocarbon-absorbing [0018] device 20 takes place at low load. This is the predominant operating state for common passenger cars with subatmospheric pressure in the intake pipe downstream of the throttle 5. At high load (acceleration), the throttles 17 are closed by the step motor 18 to prevent poorer response due to mixing heated air with the intake air. By arranging a pipe 15 with separate throttles 17 to each of the intake branch conduits 16, the supply of heated air can be rapidly throttled while limiting the heating of adjacent portions of the engine. In an alternative embodiment, the throttles can be individually controllable, for example, to utilize the suction pulses in the various intake pipes 16.
  • Tests have shown that merely supply of hot air to the intake air in the manner described at low load can reduce fuel consumption by approximately 3%. By supplying hydrocarbons from regeneration of the hydrocarbon absorbent to the intake air, additional energy is provided in the order of about 0.05, to about 0.1%. [0019]
  • As described above, the hydrocarbon absorbent is heated by air which, in turn, has been heated by the exhaust, i.e., the heating is done indirectly by the exhaust. However, it is also possible within the scope of the invention to use the exhaust for direct heating and transport of evaporated hydrocarbons to the intake manifold of the engine, a type of EGR. [0020]
  • An internal combustion engine installation and its components have been described herein. These and other variations, which will be appreciated by those skilled in the art, are within the intended scope of this invention as claimed below. As previously stated, detailed embodiments of the present invention are discussed herein. However, it is to be understood that the disclosed embodiments are merely exemplary of the invention that may be embodied in various forms. [0021]

Claims (10)

1. An internal combustion engine installation in a motor vehicle having an internal combustion engine arranged in an engine compartment, said engine having an air intake conduit, which opens to an intake manifold, and an exhaust manifold which opens to an exhaust conduit, comprising:
a hydrocarbon-absorbing element, and
a heating device for heating and removal of hydrocarbon from said hydrocarbon-absorbing element,
wherein said hydrogen-absorbing element of said heating device are so arranged in said engine compartment relative to each other that a portion of said hydrocarbon-absorbing element is exposed to the surrounding engine compartment when another portion of said element is exposed to said heating device, and
further wherein said hydrocarbon-absorbing element is movable such that a portion of said element moves to said heating device at the same time as another portion moves away from said heating device.
2. The engine installation according to
claim 1
wherein said heating device is an element heated by the engine exhaust.
3. The engine installation according to
claim 1
wherein the exhaust manifold forms heating elements in a container through which ambient air flows, said container communicating with an inlet to said heating device, and wherein said heating device has an outlet for communicating with said intake manifold.
4. The engine installation according to
claim 1
wherein said heating device has an inlet to each branch conduit of said intake manifold downstream of a throttle of said intake conduit, and wherein each said inlet from the heating device contains a throttle for controlling air supply from the heating device.
5. The engine installation according to
claim 1
wherein said hydrocarbon-absorbing element has a portion exposed to a radiator in said engine compartment and another portion exposed to said heating device.
6. The engine installation according to
claim 1
wherein said hydrocarbon-absorbing element is a disc element rotatable by a motor.
7. An internal combustion engine arrangement having an air intake conduit and an exhaust manifold in an engine compartment comprising:
a hydrocarbon-absorbing element, and
a heating device for heating and removal of hydrocarbon from said hydrocarbon-absorbing element,
wherein said hydrogen-absorbing element of said heating device are so arranged in said engine compartment relative to each other that a portion of said hydrocarbon-absorbing element is exposed to the surrounding engine compartment when another portion of said element is exposed to said heating device.
8. The internal combustion engine arrangement of
claim 7
wherein said hydrocarbon-absorbing element is movable such that a portion of said element moves to said heating device at the same time as another portion moves away from said heating device.
9. The internal combustion engine arrangement of
claim 7
wherein said hydrocarbon-absorbing element has a portion exposed to a radiator in said engine compartment and another portion exposed to said heating device.
10. The internal combustion engine arrangement of
claim 7
wherein said heating device is heated by air heated by said exhaust manifold.
US09/681,701 2000-05-23 2001-05-23 Internal combustion engine installation in a motor vehicle Expired - Fee Related US6408815B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
SE0001920 2000-05-23
SE0001920A SE523269C2 (en) 2000-05-23 2000-05-23 Combustion engine installation in a motor vehicle
SE0001920-8 2000-05-23

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US20010047790A1 true US20010047790A1 (en) 2001-12-06
US6408815B2 US6408815B2 (en) 2002-06-25

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EP (1) EP1157730B1 (en)
DE (1) DE60108804T2 (en)
SE (1) SE523269C2 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6598581B2 (en) 2001-12-13 2003-07-29 Visteon Global Technologies, Inc. Metallic coating on a component of an internal combustion engine
US20060272508A1 (en) * 2005-06-01 2006-12-07 Hoke Jeffrey B Coated screen adsorption unit for controlling evaporative hydrocarbon emissions
US20070107701A1 (en) * 2005-11-17 2007-05-17 Buelow Mark T Hydrocarbon adsorption filter for air intake system evaporative emission control
CN113082967A (en) * 2021-03-25 2021-07-09 赣州步莱铽新资源有限公司 Treatment fluorination device for secondary fluorine removal of fluorine-containing molten salt electrolytic slag and implementation method thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8372477B2 (en) * 2009-06-11 2013-02-12 Basf Corporation Polymeric trap with adsorbent

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04297341A (en) * 1991-03-26 1992-10-21 Nagatoshi Suzuki Atmospheric purifier
DE4318738C1 (en) * 1993-06-05 1994-07-14 Von Langen Ursula Lang Ambient air cleaning
US5509853A (en) * 1994-07-11 1996-04-23 Wells; Del Method and manufacture for purifying the atmosphere
US5912423A (en) * 1997-01-23 1999-06-15 Calgon Carbon Corporation Method and means for purifying air with a regenerable carbon cloth sorbent
US6212882B1 (en) * 1999-09-07 2001-04-10 Volvo Personvagnar Ab & Engelhard Corp. Assembly, method, and motor vehicle for cleaning ambient air in the vicinity of an internal combustion engine

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6598581B2 (en) 2001-12-13 2003-07-29 Visteon Global Technologies, Inc. Metallic coating on a component of an internal combustion engine
US20060272508A1 (en) * 2005-06-01 2006-12-07 Hoke Jeffrey B Coated screen adsorption unit for controlling evaporative hydrocarbon emissions
US7531029B2 (en) 2005-06-01 2009-05-12 Basf Catalysts Llc Coated screen adsorption unit for controlling evaporative hydrocarbon emissions
US20070107701A1 (en) * 2005-11-17 2007-05-17 Buelow Mark T Hydrocarbon adsorption filter for air intake system evaporative emission control
US7578285B2 (en) 2005-11-17 2009-08-25 Basf Catalysts Llc Hydrocarbon adsorption filter for air intake system evaporative emission control
US20090272361A1 (en) * 2005-11-17 2009-11-05 Basf Catalysts, Llc Hydrocarbon Adsorption Filter for Air Intake System Evaporative Emission Control
US7677226B2 (en) 2005-11-17 2010-03-16 Basf Catalysts Llc Hydrocarbon adsorption filter for air intake system evaporative emission control
CN113082967A (en) * 2021-03-25 2021-07-09 赣州步莱铽新资源有限公司 Treatment fluorination device for secondary fluorine removal of fluorine-containing molten salt electrolytic slag and implementation method thereof

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Publication number Publication date
EP1157730A1 (en) 2001-11-28
SE523269C2 (en) 2004-04-06
DE60108804T2 (en) 2005-07-21
DE60108804D1 (en) 2005-03-17
SE0001920D0 (en) 2000-05-23
SE0001920L (en) 2001-11-24
US6408815B2 (en) 2002-06-25
EP1157730B1 (en) 2005-02-09

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