US20020006263A1 - Compound for the sheaths of optical or electrical cables - Google Patents
Compound for the sheaths of optical or electrical cables Download PDFInfo
- Publication number
- US20020006263A1 US20020006263A1 US09/880,033 US88003301A US2002006263A1 US 20020006263 A1 US20020006263 A1 US 20020006263A1 US 88003301 A US88003301 A US 88003301A US 2002006263 A1 US2002006263 A1 US 2002006263A1
- Authority
- US
- United States
- Prior art keywords
- compound
- compound according
- sheaths
- phosphoric acid
- optical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000001875 compounds Chemical class 0.000 title claims abstract description 21
- 230000003287 optical effect Effects 0.000 title claims abstract description 4
- 239000003063 flame retardant Substances 0.000 claims abstract description 12
- 150000003014 phosphoric acid esters Chemical class 0.000 claims abstract description 7
- 229920002635 polyurethane Polymers 0.000 claims abstract description 6
- 239000004814 polyurethane Substances 0.000 claims abstract description 6
- 229910000000 metal hydroxide Inorganic materials 0.000 claims abstract description 5
- 150000004692 metal hydroxides Chemical class 0.000 claims abstract description 5
- UOCIZHQMWNPGEN-UHFFFAOYSA-N dialuminum;oxygen(2-);trihydrate Chemical compound O.O.O.[O-2].[O-2].[O-2].[Al+3].[Al+3] UOCIZHQMWNPGEN-UHFFFAOYSA-N 0.000 claims description 4
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 3
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 3
- 239000000347 magnesium hydroxide Substances 0.000 claims description 3
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 7
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 6
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 6
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000007789 gas Substances 0.000 description 4
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 4
- 229920001169 thermoplastic Polymers 0.000 description 4
- 239000004416 thermosoftening plastic Substances 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/29—Protection against damage caused by extremes of temperature or by flame
- H01B7/295—Protection against damage caused by extremes of temperature or by flame using material resistant to flame
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
- G02B1/045—Light guides
- G02B1/048—Light guides characterised by the cladding material
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/44—Mechanical structures for providing tensile strength and external protection for fibres, e.g. optical transmission cables
- G02B6/4401—Optical cables
- G02B6/4429—Means specially adapted for strengthening or protecting the cables
- G02B6/4436—Heat resistant
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
- Communication Cables (AREA)
- Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
- Insulated Conductors (AREA)
Abstract
A compound for the sheaths of optical or electrical cables, based on polyurethane with the addition of so-called fire retardants, wherein the fire retardant comprises a metal hydroxide and at least one phosphoric acid ester.
Description
- This application is based on and claims the benefit of European Patent Application No. 00401675.4 filed Jun. 14, 2000, which is incorporated by reference herein.
- The invention concerns a compound polyurethane-based for the sheaths of optical or electrical cables.
- Thermoplastic polyurethane (TPU) is a material which, due to its excellent mechanical properties, is often used as a material for sheaths for cables and lines which are subject to high mechanical stresses. However, thermoplastic polyurethane does not display any fire retardant behavior. In case of fire, the polyurethane drips off of the cable or line, respectively.
- Through the addition of so-called fire retardants, thermoplastic polyurethane can have its fire resistance improved enough that the cables and lines produced with it meet the necessary requirements.
- Halogenated substances in combination with antimony trioxide, as well as nonhalogenated substances such as, for example, phosphoric acid esters or a combination of such esters with nitrogenous compounds, are known as fire retardants for thermoplastic polyurethanes.
- Halogenated substances have the disadvantage that in case of fire, compounds are produced that are both toxic and generate corrosive gases (hydrochloric acid). Compounds which contain such fire retardants therefore do not meet the requirements in regard to the corrosiveness of gases produced in case of fire (IEC [International Electrotechnical Commission] 754-2) and freedom from halogens (VDE [Association of German Electrical Engineers] 0472/section 815).
- The halogen-free fire retardants do not produce corrosive gases in case of fire, but they have the disadvantage that, if only phosphoric acid esters are used, the fire resistance is not sufficient, or, if additional nitrogenous substances are used, considerable quantities of nitrogenous, toxic compounds such as nitrogen oxides (NO x) and hydrogen cyanide (HCN, prussic acid) are released.
- Fire retardant silicone compositions for thermoplastics are known, e.g., from EP 0 537 013 B1, in which a fire retardant in the form of a powder, consisting of silicone oil, silicone resin, and magnesium hydroxide, all in very precise ratios to one another, is added to thermoplastics which are normally flammable. The thermoplastic can be a polyethylene, polypropylene, polycarbonate, polystyrene, polyurethane, polyamide, or another thermoplastic. The mixture can, furthermore, have salts of the phosphoric acids or, as a filler, aluminum oxide trihydrate, among other things, added to it.
- The essential effect in regard to fire resistance is achieved in EP 0 537 013 B1 through the silicon oil, the silicon resin soluble in the silicon oil, and the magnesium hydroxide.
- It is an object of the present invention to provide a TPU-based compound which contains neither halogenated nor nitrogenous substances and fulfills the prescriptions according to IEC 754-2 and VDE 0472/section 815.
- This object is achieved by a compound wherein a metal hydroxide and at least one phosphoric acid ester are added to the compound as a fire retardant.
- The compound according to the teaching of the invention meets the requirements in regard to fire resistance, corrosiveness, and freedom from halogens and, in case of fire, only generates a fraction of the toxic substances NO x and NCN which are released when the known products are used.
- Further advantageous features of the invention will be apparent from the detailed description below.
- The invention will be described in more detail with reference to an exemplary embodiment.
- A compound was produced from
- 100 parts polyether urethane of Shore hardness A87
- 18.6 parts resorcinol-bis-diphenyl phosphate
- 66.7 parts aluminum hydroxide and/or aluminum oxide trihydrate
- 0.6 parts erucic acid amide
- and the compound was granulated. The granulate was fed into an extruder and extruded at a temperature of 200° C. onto a cable core consisting of several insulated electrical lines stranded together.
- After cooling, several samples were subjected to a fire test. No corrosive gases were released and only a small amount of toxic gases was measured.
Claims (8)
1. A compound for the sheaths of optical or electrical cables, said compound comprising a polyurethane with the addition of a fire retardant, wherein said fire retardant comprises metal hydroxide and at least one phosphoric acid ester.
2. A compound according to claim 1 , wherein said polyurethane is a polyether urethane.
3. A compound according to claim 1 , wherein said metal hydroxide comprises at least one of aluminum hydroxide and aluminum oxide trihydrate.
4. A compound according to claim 1 , wherein said metal hydroxide comprises magnesium hydroxide.
5. A compound according to claim 1 , wherein said phosphoric acid ester is a low-volatility phosphoric acid ester.
6. A compound according to claim 1 , wherein said compound contains 30 to 70 parts polyether urethane, and 25 to 60 parts aluminum hydroxide and/or aluminum oxide trihydrate.
7. A compound according to claim 6 , wherein resorcinol-bis-diphenyl phosphate.
8. An electrical cable or line with a sheath made of a compound according to claim 1 , wherein the sheath is cross-linked, preferably cross-linked by irradiation.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP00401675.4 | 2000-06-14 | ||
| EP00401675A EP1167429B1 (en) | 2000-06-14 | 2000-06-14 | Mixture for optical or electrical cable sheaths |
| EP00401675 | 2000-06-14 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| US20020006263A1 true US20020006263A1 (en) | 2002-01-17 |
| US6404971B2 US6404971B2 (en) | 2002-06-11 |
Family
ID=8173725
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US09/880,033 Expired - Lifetime US6404971B2 (en) | 2000-06-14 | 2001-06-14 | Compound for the sheaths of optical or electrical cables |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6404971B2 (en) |
| EP (1) | EP1167429B1 (en) |
| AT (1) | ATE258204T1 (en) |
| DE (1) | DE50005081D1 (en) |
| DK (1) | DK1167429T3 (en) |
| ES (1) | ES2209780T3 (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100047469A1 (en) * | 2006-12-21 | 2010-02-25 | Basf Se | Article, especially cable sheathing, comprising thermoplastic polyurethane and crosslinked polyethylene in adhesive-bonded form |
| WO2011011921A1 (en) * | 2009-07-31 | 2011-02-03 | Dow Global Technologies Inc. | Flame retardant thermoplastic elastomer |
| JP2012530801A (en) * | 2009-06-18 | 2012-12-06 | ダウ グローバル テクノロジーズ エルエルシー | Color-stable halogen-free flame retardant composition |
| WO2013029250A1 (en) * | 2011-08-31 | 2013-03-07 | Dow Global Technologies Llc | Migration-free, halogen-free, flame retardant thermoplastic polyurethane compositions |
| FR2987367A1 (en) * | 2012-02-28 | 2013-08-30 | Commissariat Energie Atomique | FIRE PROTECTIVE MATERIAL, HIGH PRESSURE STORAGE TANK COATED WITH SUCH MATERIAL, PROCESSES FOR THEIR PREPARATION AND USES THEREOF |
| CN104159973A (en) * | 2012-03-13 | 2014-11-19 | 巴斯夫欧洲公司 | Flame-retardant thermoplastic polyurethane comprising coated metal hydroxides based on aluminum |
| CN105542443A (en) * | 2016-01-28 | 2016-05-04 | 常熟市中联光电新材料有限责任公司 | Halogen-free flame-retardant thermal plastic polyurethane cable sheath material and preparation method thereof |
| US9670337B2 (en) | 2012-03-13 | 2017-06-06 | Basf Se | Flame-retardant thermoplastic polyurethane comprising coated metal hydroxides based on aluminum |
| KR101785136B1 (en) * | 2010-06-03 | 2017-10-12 | 다우 글로벌 테크놀로지스 엘엘씨 | Halogen-free, flame retardant tpu composite |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7367364B2 (en) * | 2003-04-08 | 2008-05-06 | Omega Flex, Inc. | Fire retardant jacket for tubing |
| EP1491580B1 (en) * | 2003-06-02 | 2007-09-26 | Nexans | Mixture for optical or electrical cable sheaths |
| DE10343121A1 (en) * | 2003-09-16 | 2005-04-07 | Basf Ag | Thermoplastic polyurethane containing metal hydroxide |
| EP2199351A1 (en) | 2008-12-19 | 2010-06-23 | Sika Technology AG | Fluid film based on silane-terminated polymers |
| CN104004343B (en) | 2009-08-10 | 2019-03-08 | 联合碳化化学及塑料技术有限责任公司 | Composition for thermoplastic elastomer comprising intumescence fire retardant He the flame retardancy synergists for being not based on phosphorus |
| JP5499177B2 (en) | 2009-10-28 | 2014-05-21 | ダウ グローバル テクノロジーズ エルエルシー | Thermoplastic polyurethane composition having high insulation resistance |
| US9334395B2 (en) | 2009-12-11 | 2016-05-10 | Dow Global Technologies Llc | Thermoplastic polymer blends comprising dynamically crosslinked polyurethane in an olefin polymer matrix |
| KR20170051524A (en) | 2009-12-31 | 2017-05-11 | 다우 글로벌 테크놀로지스 엘엘씨 | Halogen-free, flame retardant thermoplastic compositions for wire and cable applications |
| WO2011120225A1 (en) * | 2010-03-31 | 2011-10-06 | Dow Global Technologies Llc | Migration-free, halogen-free, flame retardant thermoplastic polyurethane compositions |
| EP2374843A1 (en) * | 2010-04-07 | 2011-10-12 | Nexans | Degradation-resistant polyurethane mixture |
| US9336927B2 (en) | 2010-12-17 | 2016-05-10 | Dow Global Technologies Llc | Halogen-free, flame retardant composition for wire and cable applications |
| CA2839031C (en) | 2011-06-21 | 2017-02-14 | Dow Global Technologies Llc | Halogen-free flame-retardant polymer composition comprising piperazine based intumescent flame retardant |
| US10109393B2 (en) | 2011-08-31 | 2018-10-23 | Dow Global Technologies Llc | Halogen-free flame retardant TPU composition for wire and cable |
| ES2632263T3 (en) | 2012-06-22 | 2017-09-12 | Basf Se | Fire retardant thermoplastic polyurethane based on polycarbonate diols |
| BR112014026397A2 (en) | 2012-07-27 | 2017-06-27 | Basf Se | composition and use of a composition |
| CN105308115B (en) | 2013-06-28 | 2018-06-12 | 陶氏环球技术有限责任公司 | Plastics photovoltaic module frame and bracket and the composition for being used to prepare it |
| JP6554471B2 (en) | 2013-12-20 | 2019-07-31 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | Flame retardant thermoplastic polyurethane |
| US10047214B2 (en) | 2013-12-20 | 2018-08-14 | Basf Se | Flame-retardant thermoplastic polyurethane |
| CZ2015375A3 (en) | 2015-06-03 | 2016-12-14 | Borcad Cz S.R.O. | Polyurethane foam with reduced flammability, reduced smoke generation and low smoke toxicity |
| EP3645617A4 (en) | 2017-06-29 | 2021-02-17 | Dow Global Technologies Llc | Polyolefin composition |
| MX2020011128A (en) | 2018-05-25 | 2020-11-11 | Union Carbide Corp | Moisture-curable polyolefin formulation. |
| JP2023507089A (en) | 2019-12-19 | 2023-02-21 | ダウ グローバル テクノロジーズ エルエルシー | Polyolefin composition |
| WO2022093682A1 (en) | 2020-10-30 | 2022-05-05 | Dow Global Technologies Llc | Polyolefin formulation |
| KR20240041976A (en) | 2021-08-04 | 2024-04-01 | 다우 글로벌 테크놀로지스 엘엘씨 | Polyolefin formulations containing combinations of voltage stabilizer compounds |
| TW202307117A (en) | 2021-08-04 | 2023-02-16 | 美商陶氏全球科技有限責任公司 | Polyolefin formulation containing crotophenone compound |
| US20230175615A1 (en) * | 2021-12-02 | 2023-06-08 | Omega Flex, Inc. | Arc resistant corrugated tubing system with protective jacket and fitting |
| WO2024002869A1 (en) | 2022-06-27 | 2024-01-04 | Basf Se | Thermoplastic polyurethane (tpu) composition with improved properties |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE793200A (en) * | 1971-12-27 | 1973-06-22 | Monsanto Co | FLAME RESISTANT COMPOSITIONS |
| FR2246606B3 (en) * | 1973-10-09 | 1977-07-15 | Grace W R Ltd | |
| JPS5783518A (en) * | 1980-11-11 | 1982-05-25 | Mitsubishi Chem Ind Ltd | Curable polymer composition |
| DE3113385A1 (en) * | 1981-04-02 | 1982-10-21 | Bayer Ag, 5090 Leverkusen | LOW-HALOGEN, THERMOPLASTIC POLYURETHANE ELASTOMER IMPROVED FLAME RESISTANCE THROUGH THE ADDITION OF A 4-SUBSTANCE ADDITIVE COMBINATION, ITS PRODUCTION AND USE |
| DE3904802A1 (en) * | 1989-02-17 | 1990-08-23 | Standard Elektrik Lorenz Ag | POLYMER BLEND |
| JPH04248506A (en) * | 1991-02-04 | 1992-09-04 | Mitsubishi Rayon Co Ltd | Optical fiber cord |
| JPH059376A (en) * | 1991-07-03 | 1993-01-19 | Nippon Mirakutoran Kk | Flame-retardant urethane composition |
| US5401788A (en) * | 1993-03-16 | 1995-03-28 | Daihachi Chemical Industry Co., Ltd. | Organic phosphorus compounds and flame-retarded resin compositions containing the same |
| ATE178915T1 (en) * | 1996-02-14 | 1999-04-15 | Sika Ag | FLAME RETARDANT POLYURETHANE SYSTEMS |
-
2000
- 2000-06-14 DE DE50005081T patent/DE50005081D1/en not_active Expired - Lifetime
- 2000-06-14 AT AT00401675T patent/ATE258204T1/en active
- 2000-06-14 ES ES00401675T patent/ES2209780T3/en not_active Expired - Lifetime
- 2000-06-14 DK DK00401675T patent/DK1167429T3/en active
- 2000-06-14 EP EP00401675A patent/EP1167429B1/en not_active Expired - Lifetime
-
2001
- 2001-06-14 US US09/880,033 patent/US6404971B2/en not_active Expired - Lifetime
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100047469A1 (en) * | 2006-12-21 | 2010-02-25 | Basf Se | Article, especially cable sheathing, comprising thermoplastic polyurethane and crosslinked polyethylene in adhesive-bonded form |
| JP2012530801A (en) * | 2009-06-18 | 2012-12-06 | ダウ グローバル テクノロジーズ エルエルシー | Color-stable halogen-free flame retardant composition |
| WO2011011921A1 (en) * | 2009-07-31 | 2011-02-03 | Dow Global Technologies Inc. | Flame retardant thermoplastic elastomer |
| EP2459632A1 (en) | 2009-07-31 | 2012-06-06 | Dow Global Technologies LLC (formerly Known As Dow Global Technologies Inc.) | Flame retardant thermoplastic elastomer |
| US8987597B2 (en) | 2009-07-31 | 2015-03-24 | Dow Global Technologies Llc | Flame retardant thermoplastic elastomer |
| KR101785136B1 (en) * | 2010-06-03 | 2017-10-12 | 다우 글로벌 테크놀로지스 엘엘씨 | Halogen-free, flame retardant tpu composite |
| WO2013029250A1 (en) * | 2011-08-31 | 2013-03-07 | Dow Global Technologies Llc | Migration-free, halogen-free, flame retardant thermoplastic polyurethane compositions |
| CN103874735A (en) * | 2011-08-31 | 2014-06-18 | 陶氏环球技术有限责任公司 | Migration-free, halogen-free, flame retardant thermoplastic polyurethane compositions |
| US9080038B2 (en) | 2011-08-31 | 2015-07-14 | Dow Global Technologies Llc | Migration-free, halogen-free, flame retardant thermoplastic polyurethane compositions |
| KR101825258B1 (en) | 2011-08-31 | 2018-02-02 | 다우 글로벌 테크놀로지스 엘엘씨 | Migration-free, halogen-free, flame retardant thermoplastic polyurethane compositions |
| FR2987367A1 (en) * | 2012-02-28 | 2013-08-30 | Commissariat Energie Atomique | FIRE PROTECTIVE MATERIAL, HIGH PRESSURE STORAGE TANK COATED WITH SUCH MATERIAL, PROCESSES FOR THEIR PREPARATION AND USES THEREOF |
| US10765897B2 (en) | 2012-02-28 | 2020-09-08 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | Fire protection material, high-pressure storage tank coated with said material, methods for preparing same, and uses thereof |
| CN104159974A (en) * | 2012-03-13 | 2014-11-19 | 巴斯夫欧洲公司 | Flame-retardant thermoplastic polyurethane comprising coated metal hydroxides based on aluminium |
| US9670337B2 (en) | 2012-03-13 | 2017-06-06 | Basf Se | Flame-retardant thermoplastic polyurethane comprising coated metal hydroxides based on aluminum |
| CN104159973A (en) * | 2012-03-13 | 2014-11-19 | 巴斯夫欧洲公司 | Flame-retardant thermoplastic polyurethane comprising coated metal hydroxides based on aluminum |
| CN105542443A (en) * | 2016-01-28 | 2016-05-04 | 常熟市中联光电新材料有限责任公司 | Halogen-free flame-retardant thermal plastic polyurethane cable sheath material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| ATE258204T1 (en) | 2004-02-15 |
| US6404971B2 (en) | 2002-06-11 |
| DK1167429T3 (en) | 2004-03-08 |
| EP1167429B1 (en) | 2004-01-21 |
| ES2209780T3 (en) | 2004-07-01 |
| DE50005081D1 (en) | 2004-02-26 |
| EP1167429A1 (en) | 2002-01-02 |
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