US20020037419A1 - Thermal conductive sheet with conductive foil - Google Patents
Thermal conductive sheet with conductive foil Download PDFInfo
- Publication number
- US20020037419A1 US20020037419A1 US09/923,509 US92350901A US2002037419A1 US 20020037419 A1 US20020037419 A1 US 20020037419A1 US 92350901 A US92350901 A US 92350901A US 2002037419 A1 US2002037419 A1 US 2002037419A1
- Authority
- US
- United States
- Prior art keywords
- thermal conductive
- foil
- thermal
- layer
- conductive sheet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/552—Protection against radiation, e.g. light or electromagnetic waves
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/34—Arrangements for cooling, heating, ventilating or temperature compensation ; Temperature sensing arrangements
- H01L23/36—Selection of materials, or shaping, to facilitate cooling or heating, e.g. heatsinks
- H01L23/373—Cooling facilitated by selection of materials for the device or materials for thermal expansion adaptation, e.g. carbon
- H01L23/3737—Organic materials with or without a thermoconductive filler
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/0001—Technical content checked by a classifier
- H01L2924/0002—Not covered by any one of groups H01L24/00, H01L24/00 and H01L2224/00
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/254—Polymeric or resinous material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/256—Heavy metal or aluminum or compound thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/258—Alkali metal or alkaline earth metal or compound thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
- Y10T428/31692—Next to addition polymer from unsaturated monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
- Y10T428/31692—Next to addition polymer from unsaturated monomers
- Y10T428/31696—Including polyene monomers [e.g., butadiene, etc.]
Definitions
- This invention relates to a thermal conductive sheet with conductive foil produced by press bonding a thermal conductive sheet and conductive foil via a primer layer
- a thermal conductive sheet has been generally produced by kneading and forming a material, such as silicone rubber and EPDM, with a thermal conductive filler.
- a thermal conductive sheet is arranged, for example, between a heat-generating electronic component and a heat sink such as a heat dissipation plate or a metal case panel, inside an electric/electronic apparatus to efficiently radiate the heat produced from the electronic component. Therefore, such thermal conductive sheet is in demand and regarded as essential for increasing in speed of the CPUs, for example.
- external electromagnetic waves may be superimposed on the input/output signals of the electronic component, such as a CPU, as noise, or electromagnetic waves generated by the electronic component itself may be superimposed on the other signals as noise.
- conductive foil may be adhered to one side of the above thermal conductive sheet facing the heat sink. Since the conductive foil is generally composed of metal having a -high thermal conductivity, presence of the conductive foil between the thermal conductive sheet and the heat sink does not inhibit radiation of the thermal conductive sheet.
- a skin layer is formed on the surface of the thermal conductive sheet, and there is the possibility that this skin layer may interrupt thermal conduction from the thermal conductive sheet to the conductive foil.
- the skin layer can be removed by preprocessing, an uneven surface of the thermal conductive sheet is created. As a result, low adhesion between the thermal conductive sheet and the conductive foil occurs and causes reduction of thermal conductivity.
- the conductive foil is adhered to the thermal conductive sheet, it is conventional to provide a primer layer between them so as to improve the adhesion. In this case, however, the primer layer may also interrupt the thermal conduction from the thermal conductive sheet to the conductive foil.
- An object of the present invention in the thermal conductive sheet with conductive foil produced by press bonding the thermal conductive sheet and the conductive foil via a primer layer, is to improve thermal conduction from the thermal conductive layer to the conductive foil and thus to improve heat radiation of the thermal conductive sheet with conductive foil.
- a thermal conductive sheet with conductive foil of the present invention is produced by press bonding a thermal conductive layer and conductive foil via a primer layer into which a thermal conductive filler in the form of powder, chop, whisker or fiber is mixed.
- silane compound titanate compound, alminate compound, caboxylic acid compound and phosphate compound can be used as a base material of the primer layer.
- the primer layer of the present invention has the thermal conductive filler mixed into it, it does not interrupt thermal conduction from the thermal conductive sheet from the conductive foil.
- the thermal conductive filler is in the form of powder, chop, whisker or fiber, and the thermal conductive layer and the conductive foil are press bonded via the primer layer into which the thermal conductive filler is mixed. Accordingly, the thermal conductive filler, at the time of the press bonding, mechanically destroys a skin layer on the surface of the thermal conductive layer. Therefore, the thermal conduction from the thermal conductive layer to the conductive foil is not hindered by the skin layer at all.
- the thermal conductive sheet with conductive foil of the present invention improves thermal conduction from the thermal conductive layer to the conductive foil, eliminating the negative effect of the skin layer and the primer layer, and thus improves heat radiation of the thermal conductive sheet with conductive foil.
- the thermal conductive sheet with conductive foil of the present invention is superior in strength.
- the thermal conductive sheet with conductive foil of the present invention efficiently prevents the external electromagnetic waves from being superimposed on the input/output signals of the electronic component as well as prevents the electromagnetic waves generated by the electronic component itself from being superimposed on the other signals
- FIGURE is an explanatory view illustrating a schematic structure of a thermal conductive sheet with conductive foil according to the present invention
- a thermal conductive sheet as a thermal conductive layer of the present invention is produced as follows.
- the thermal conductive filler By mixing a fluid base material, a thermal conductive filler and oil, the thermal conductive filler is dispersed in the base material.
- Paraffin or polyethylene rubber or resin can be used as the base material having thermoplasticity, and silicone rubber or other synthetic rubber can be used as the base material having thermosetting properties.
- the thermal conductive filler alumina, silicon carbide, boron nitride, metal oxide, metallic powder and so on can be used.
- an extrusion machine for mixing the base material and the filler, an extrusion machine, a two-roll machine, a kneader, a planetary mixer can be used. Such solid-form base material kneaded with the thermal conductive filler is formed into a sheet, and the thermal conductive sheet is obtained.
- a calendar roller, an extrusion machine, a press machine, a coater and the like can be used for the press molding.
- FIGURE shows an explanatory view illustrating a schematic structure of a thermal conductive sheet with conductive foil of the present embodiment.
- the thermal conductive sheet 1 with conductive foil of the embodiment is obtained by press bonding magnetic foil 5 , which is conductive foil made of magnetic metallic foil, to the thermal conductive layer 3 made as above via a primer layer 7 .
- base materials of the primer layer 7 silane compounds, titanate compounds, alminate compounds, caboxylic acid compounds and phosphate compounds can be used.
- a silane compound for example, is a silane coupling material such as ⁇ -methacryloxypropyl trimethoxy silane, ⁇ -aminopropyl triethoxysilane and poly ethoxy dimethylsiloxane.
- the primer layer 7 is made from a mixture of the above mentioned compounds and a solvent such as xylene, cyclohexane and ethyl acetate. Before the press bonding, the primer layer 7 is kneaded with the same thermal conductive filler 9 as that used in the thermal conductive layer 3 , and it is adhered to the magnetic foil 5 . After the press bonding, the thermal conductive layer 3 is vulcanized so that the base material attains an elastomeric state. Thus the thermal conductive sheet 1 with conductive foil of the present embodiment is obtained.
- the primer layer 7 of the thermal conductive sheet 1 with conductive foil has the dispersed thermal conductive filler 9 . Accordingly, the primer layer 7 has high thermal conductivity and does not interrupt the thermal conduction from the thermal conductive layer 3 to the magnetic foil 5 .
- the thermal conductive filler 9 is in the form of powder, chop, whisker or fiber, and via the primer 7 which contains the thermal conductive filler 9 the thermal conductive layer 3 and the magnetic foil 5 are press bonded. Therefore, upon the press bonding, the thermal conductive filler 9 spontaneously destroys a skin layer on the surface of the thermal conductive layer 3 .
- the skin layer with low thermal conductivity is formed on the surface of the thermal conductive layer 3 when the thermal conductive layer 3 is formed into a sheet. Nevertheless, the skin layer does not interrupt the thermal conduction from the thermal conductive layer. 3 to the magnetic foil 5 , because the skin layer of the thermal conductive sheet 1 with conductive foil is destroyed. Therefore, the thermal conductive sheet with conductive foil of the present invention improves thermal conduction from the thermal conductive layer to the conductive foil, eliminating the unfavorable effects of the skin layer and the primer layer, and thus improves heat radiation of the thermal conductive sheet with conductive foil. In addition, because the thermal conductive layer and the conductive foil are press bonded via the primer layer, the thermal conductive sheet with conductive foil of the present invention is superior in strength
- the thermal conductive sheet 1 with conductive foil is actually produced and the difference in properties derived from the amount of the thermal conductive filler 9 is examined.
- EPDM ethylene-propylene-diene terpolymer
- silicon carbide as the thermal conductive filler
- a press machine or a calendar roller
- the thermal conductive sheet 1 with conductive foil is produced.
- the primer layer 7 of the present example comprises a mixture of ⁇ -methacryloxypropyl trimethoxy silane and xylene.
- a flat-rolled magnetic material such as Fe—Si, Fe—Cr, Fe—Si—Al, Fe, Fe—Ni, Fe-based nanocrystal, or amorphous one can be used.
- the thermal conductive sheet 1 and the magnetic foil 6 are press bonded via the primer layer 7 containing no alumina powder, and other thermal conductive sheet with conductive foil are produced.
- the thermal conductivity of each thermal conductive sheet produced are shown in Table 1. TABLE 1 Amount of alumina powder in primer layer Thermal conductivity (wt. %) (W/m ⁇ k) 0 1.71 10 1.77 20 1.88 30 1.84 50 1.82
- Table 1 shows that a thermal conductive sheet with conductive foil having the primer layer 7 with alumina powder has higher thermal conductivity than the one with no alumina powder. The reason for this is assumedly, because when the thermal conductive layer 3 and the magnetic foil 5 are press bonded via the primer layer 7 , the skin layer on the surface of the thermal conductive layer 3 is spontaneously destroyed by alumina powder in the primer layer 7 . Additionally, Table 1 indicates that although thermal conductivity is increased in accordance with the increase of alumina powder contained in the primer layer 7 , it starts to decrease after it reaches its peak at approximately 20 weight % of alumina powder.
- the present invention is not limited to the above embodiment, and other modifications and variations are possible within the scope of the present invention.
- aluminum hydroxide can be substituted for the thermal conductive filler contained in the primer layer.
- Foil made by vapor deposition of PVD or CVD can be used as the magnetic foil.
- Aluminum foil, iron foil and copper foil are also included in metallic foil (one form of conductive foil).
- the combination of materials to be used for the thermal conductive layer the conductive foil, the primer layer and the thermal conductive filler contained in the primer layer can be freely chosen from the previously mentioned materials.
Abstract
A thermal conductive sheet with conductive foil is obtained by press bonding a magnetic foil to a thermal conductive layer via a primer layer. Since the primer layer contains a thermal conductive filler, it has high thermal conductivity and does not interrupt thermal conduction from the thermal conductive layer to the magnetic foil. It also spontaneously destroys a skin layer on the surface of the thermal conductive layer upon the press bonding. Accordingly, the thermal conductive sheet with conductive foil of the present invention improves thermal conduction from the thermal conductive layer to the conductive foil, eliminating the unfavorable effects of the skin layer and the primer layer, and thus improves heat radiation of the thermal conductive sheet with conductive foil.
Description
- This invention relates to a thermal conductive sheet with conductive foil produced by press bonding a thermal conductive sheet and conductive foil via a primer layer
- A thermal conductive sheet has been generally produced by kneading and forming a material, such as silicone rubber and EPDM, with a thermal conductive filler. Such a thermal conductive sheet is arranged, for example, between a heat-generating electronic component and a heat sink such as a heat dissipation plate or a metal case panel, inside an electric/electronic apparatus to efficiently radiate the heat produced from the electronic component. Therefore, such thermal conductive sheet is in demand and regarded as essential for increasing in speed of the CPUs, for example.
- Additionally in the electric/electronic apparatus, external electromagnetic waves may be superimposed on the input/output signals of the electronic component, such as a CPU, as noise, or electromagnetic waves generated by the electronic component itself may be superimposed on the other signals as noise. To protect the electronic component from the influence of the external electromagnetic waves as well as to interfere with the electromagnetic waves generated by the electronic component, conductive foil may be adhered to one side of the above thermal conductive sheet facing the heat sink. Since the conductive foil is generally composed of metal having a -high thermal conductivity, presence of the conductive foil between the thermal conductive sheet and the heat sink does not inhibit radiation of the thermal conductive sheet.
- During the process of forming the thermal conductive sheet, however, a skin layer is formed on the surface of the thermal conductive sheet, and there is the possibility that this skin layer may interrupt thermal conduction from the thermal conductive sheet to the conductive foil. Although the skin layer can be removed by preprocessing, an uneven surface of the thermal conductive sheet is created. As a result, low adhesion between the thermal conductive sheet and the conductive foil occurs and causes reduction of thermal conductivity. Additionally, when the conductive foil is adhered to the thermal conductive sheet, it is conventional to provide a primer layer between them so as to improve the adhesion. In this case, however, the primer layer may also interrupt the thermal conduction from the thermal conductive sheet to the conductive foil.
- An object of the present invention, in the thermal conductive sheet with conductive foil produced by press bonding the thermal conductive sheet and the conductive foil via a primer layer, is to improve thermal conduction from the thermal conductive layer to the conductive foil and thus to improve heat radiation of the thermal conductive sheet with conductive foil.
- In order to attain the above object, a thermal conductive sheet with conductive foil of the present invention is produced by press bonding a thermal conductive layer and conductive foil via a primer layer into which a thermal conductive filler in the form of powder, chop, whisker or fiber is mixed.
- As a base material of the primer layer, silane compound, titanate compound, alminate compound, caboxylic acid compound and phosphate compound can be used.
- Since the primer layer of the present invention has the thermal conductive filler mixed into it, it does not interrupt thermal conduction from the thermal conductive sheet from the conductive foil. The thermal conductive filler is in the form of powder, chop, whisker or fiber, and the thermal conductive layer and the conductive foil are press bonded via the primer layer into which the thermal conductive filler is mixed. Accordingly, the thermal conductive filler, at the time of the press bonding, mechanically destroys a skin layer on the surface of the thermal conductive layer. Therefore, the thermal conduction from the thermal conductive layer to the conductive foil is not hindered by the skin layer at all.
- The thermal conductive sheet with conductive foil of the present invention improves thermal conduction from the thermal conductive layer to the conductive foil, eliminating the negative effect of the skin layer and the primer layer, and thus improves heat radiation of the thermal conductive sheet with conductive foil In addition, because the thermal conductive layer and the conductive foil are press bonded via the primer layer, the thermal conductive sheet with conductive foil of the present invention is superior in strength.
- In the present invention, magnetic foil is employed as the conductive foil Accordingly, the electromagnetic waves shielding effect of the conductive foil is further improved Therefore, in addition to the previously mentioned advantages, the thermal conductive sheet with conductive foil of the present invention efficiently prevents the external electromagnetic waves from being superimposed on the input/output signals of the electronic component as well as prevents the electromagnetic waves generated by the electronic component itself from being superimposed on the other signals
- The invention will now be described, by way of example, with reference to the accompanying drawing, in which:
- A single FIGURE is an explanatory view illustrating a schematic structure of a thermal conductive sheet with conductive foil according to the present invention
- Firstly, a thermal conductive sheet as a thermal conductive layer of the present invention is produced as follows.
- By mixing a fluid base material, a thermal conductive filler and oil, the thermal conductive filler is dispersed in the base material. Paraffin or polyethylene rubber or resin can be used as the base material having thermoplasticity, and silicone rubber or other synthetic rubber can be used as the base material having thermosetting properties. As the thermal conductive filler, alumina, silicon carbide, boron nitride, metal oxide, metallic powder and so on can be used.
- For mixing the base material and the filler, an extrusion machine, a two-roll machine, a kneader, a planetary mixer can be used. Such solid-form base material kneaded with the thermal conductive filler is formed into a sheet, and the thermal conductive sheet is obtained. A calendar roller, an extrusion machine, a press machine, a coater and the like can be used for the press molding.
- With the use of the above-described thermal conductive sheet as the thermal conductive layer, the thermal conductive sheet with conductive foil of the present invention will now be produced. A single FIGURE shows an explanatory view illustrating a schematic structure of a thermal conductive sheet with conductive foil of the present embodiment. As seen in the FIGURE, the thermal conductive sheet1 with conductive foil of the embodiment is obtained by press bonding magnetic foil 5, which is conductive foil made of magnetic metallic foil, to the thermal conductive layer 3 made as above via a primer layer 7. As base materials of the primer layer 7, silane compounds, titanate compounds, alminate compounds, caboxylic acid compounds and phosphate compounds can be used. A silane compound, for example, is a silane coupling material such as γ-methacryloxypropyl trimethoxy silane, γ-aminopropyl triethoxysilane and poly ethoxy dimethylsiloxane. The primer layer 7 is made from a mixture of the above mentioned compounds and a solvent such as xylene, cyclohexane and ethyl acetate. Before the press bonding, the primer layer 7 is kneaded with the same thermal
conductive filler 9 as that used in the thermal conductive layer 3, and it is adhered to the magnetic foil 5. After the press bonding, the thermal conductive layer 3 is vulcanized so that the base material attains an elastomeric state. Thus the thermal conductive sheet 1 with conductive foil of the present embodiment is obtained. - The primer layer7 of the thermal conductive sheet 1 with conductive foil has the dispersed thermal
conductive filler 9. Accordingly, the primer layer 7 has high thermal conductivity and does not interrupt the thermal conduction from the thermal conductive layer 3 to the magnetic foil 5. The thermalconductive filler 9 is in the form of powder, chop, whisker or fiber, and via the primer 7 which contains the thermalconductive filler 9 the thermal conductive layer 3 and the magnetic foil 5 are press bonded. Therefore, upon the press bonding, the thermalconductive filler 9 spontaneously destroys a skin layer on the surface of the thermal conductive layer 3. - In other words, the skin layer with low thermal conductivity is formed on the surface of the thermal conductive layer3 when the thermal conductive layer 3 is formed into a sheet. Nevertheless, the skin layer does not interrupt the thermal conduction from the thermal conductive layer. 3 to the magnetic foil 5, because the skin layer of the thermal conductive sheet 1 with conductive foil is destroyed. Therefore, the thermal conductive sheet with conductive foil of the present invention improves thermal conduction from the thermal conductive layer to the conductive foil, eliminating the unfavorable effects of the skin layer and the primer layer, and thus improves heat radiation of the thermal conductive sheet with conductive foil. In addition, because the thermal conductive layer and the conductive foil are press bonded via the primer layer, the thermal conductive sheet with conductive foil of the present invention is superior in strength
- The present invention will be now specifically described with reference to an example. The thermal conductive sheet1 with conductive foil is actually produced and the difference in properties derived from the amount of the thermal
conductive filler 9 is examined. Firstly, EPDM (ethylene-propylene-diene terpolymer), as the base material, and silicon carbide, as the thermal conductive filler, are kneaded and formed by a press machine (or a calendar roller) to obtain the thermal conductive layer 3. Then, by press bonding the thermal conductive layer 3 and the magnetic foil 5 via the primer layer 7 containing different amounts of alumina powder, the thermal conductive sheet 1 with conductive foil is produced. The primer layer 7 of the present example comprises a mixture of γ-methacryloxypropyl trimethoxy silane and xylene. As for the magnetic foil 5, a flat-rolled magnetic material such as Fe—Si, Fe—Cr, Fe—Si—Al, Fe, Fe—Ni, Fe-based nanocrystal, or amorphous one can be used. Additionally, as a comparison, the thermal conductive sheet 1 and the magnetic foil 6 are press bonded via the primer layer 7 containing no alumina powder, and other thermal conductive sheet with conductive foil are produced. The thermal conductivity of each thermal conductive sheet produced are shown in Table 1.TABLE 1 Amount of alumina powder in primer layer Thermal conductivity (wt. %) (W/m · k) 0 1.71 10 1.77 20 1.88 30 1.84 50 1.82 - Table 1 shows that a thermal conductive sheet with conductive foil having the primer layer7 with alumina powder has higher thermal conductivity than the one with no alumina powder. The reason for this is assumedly, because when the thermal conductive layer 3 and the magnetic foil 5 are press bonded via the primer layer 7, the skin layer on the surface of the thermal conductive layer 3 is spontaneously destroyed by alumina powder in the primer layer 7. Additionally, Table 1 indicates that although thermal conductivity is increased in accordance with the increase of alumina powder contained in the primer layer 7, it starts to decrease after it reaches its peak at approximately 20 weight % of alumina powder.
- The present invention is not limited to the above embodiment, and other modifications and variations are possible within the scope of the present invention. For instance, aluminum hydroxide can be substituted for the thermal conductive filler contained in the primer layer. Foil made by vapor deposition of PVD or CVD can be used as the magnetic foil. Aluminum foil, iron foil and copper foil are also included in metallic foil (one form of conductive foil). The combination of materials to be used for the thermal conductive layer the conductive foil, the primer layer and the thermal conductive filler contained in the primer layer can be freely chosen from the previously mentioned materials.
Claims (10)
1. A thermal conductive sheet comprising a thermal conductive layer press bonded to a conductive foil via a primer layer into which a thermal conductive filler in the form of powder, chop, whisker or fiber is mixed.
2. The thermal conductive sheet as set forth in claim 1 , wherein said conductive foil is magnetic foil.
3. A thermal conductive sheet for use as a thermal conductive layer between a heat producing element and a heat dissipating element, the thermal conductive sheet comprising:
a conductive foil;
a thermal conductive layer; and
a primer layer situated between the conductive foil and the thermal conductive layer to facilitate the adherence and thermal conductivity between the conductive foil and the thermal conductive layer.
4. The thermal conductive sheet as set forth in claim 3 wherein the primer layer comprises a thermal conductive filler material in the form of powder, chop, whisker or fiber.
5. The thermal conductive sheet as set forth in claim 4 wherein the conductive foil is press bonded to the thermal conductive layer via the primer layer.
6. The thermal conductive sheet as set forth in claim 4 wherein the thermal conductive layer has a first surface having a skin layer which is mechanically destroyed during press bonding to enhance thermal conductivity through the skin layer.
7. The thermal conductive sheet as set forth in claim 3 wherein the conductive foil is a magnetic metallic foil.
8. The thermal conductive sheet as set forth in claim 7 wherein the magnetic metallic foil is a flat rolled magnetic material chosen from the group of Fe—Si, Fe—Cr, Fe—Si—Al, Fe, Fe—Ni, Fe-based nanocrystal.
9. The thermal conductive sheet as set forth in claim 4 wherein the primer layer is fabricated from a thermoplastic base material of paraffin or polyethylene rubber or resin and the thermal conductive filler Ls chosen from the group, alumina, silicon carbide, boron nitride, metal oxide, metallic powder.
10. A process of forming a thermal conductive sheet for use as a thermal conductive layer between a heat producing element and a heat dissipating element, the method of forming the thermal conductive sheet comprising the steps of:
forming a primer layer having a base material containing a thermal conductive filler material in the form of powder, chop, whisker or fiber and
sandwiching the primer layer between a conductive foil and a thermal conductive layer to facilitate the adherence and thermal conductivity between the conductive foil and the thermal conductive layer.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/358,425 US6733614B2 (en) | 2000-08-10 | 2003-02-04 | Process for forming thermal conductive sheet |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000242788A JP3609697B2 (en) | 2000-08-10 | 2000-08-10 | Thermal conductive sheet with conductive foil for electrical and electronic equipment |
JP2000-242788 | 2000-08-10 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/358,425 Division US6733614B2 (en) | 2000-08-10 | 2003-02-04 | Process for forming thermal conductive sheet |
Publications (1)
Publication Number | Publication Date |
---|---|
US20020037419A1 true US20020037419A1 (en) | 2002-03-28 |
Family
ID=18733753
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09/923,509 Abandoned US20020037419A1 (en) | 2000-08-10 | 2001-08-06 | Thermal conductive sheet with conductive foil |
US10/358,425 Expired - Lifetime US6733614B2 (en) | 2000-08-10 | 2003-02-04 | Process for forming thermal conductive sheet |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/358,425 Expired - Lifetime US6733614B2 (en) | 2000-08-10 | 2003-02-04 | Process for forming thermal conductive sheet |
Country Status (4)
Country | Link |
---|---|
US (2) | US20020037419A1 (en) |
EP (1) | EP1180798B1 (en) |
JP (1) | JP3609697B2 (en) |
DE (1) | DE60130176T2 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20050048803A1 (en) * | 2001-10-16 | 2005-03-03 | Erwann Guillet | Insulator for an organic electronic component |
CN110643182A (en) * | 2019-09-17 | 2020-01-03 | 厦门市科源电子工业有限公司 | Conductive silicone rubber and preparation method thereof |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007027026A1 (en) * | 2005-08-31 | 2007-03-08 | Lg Chem, Ltd. | Reflection plate for backlight unit and backlight unit of liquid crystal display having good thermal conductivity |
US20080166552A1 (en) * | 2006-11-06 | 2008-07-10 | Arlon, Inc. | Silicone based compositions for thermal interface materials |
DE102013218826A1 (en) | 2013-09-19 | 2015-03-19 | Siemens Aktiengesellschaft | heatsink |
JP2020008247A (en) * | 2018-07-11 | 2020-01-16 | 株式会社デンソー | Magneto-caloric element and thermomagnetic cycle device |
WO2021025089A1 (en) * | 2019-08-08 | 2021-02-11 | 積水ポリマテック株式会社 | Thermally conductive sheet and production method therefor |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3959063A (en) | 1971-06-02 | 1976-05-25 | Foseco International Limited | Method of protecting a surface from a heat source |
JPS585452B2 (en) | 1975-08-28 | 1983-01-31 | 富士写真フイルム株式会社 | magnetic recording medium |
JPS5566951A (en) | 1978-11-13 | 1980-05-20 | Shin Etsu Chem Co Ltd | Primer composition |
JPS5765758A (en) | 1980-10-09 | 1982-04-21 | Toray Silicone Co Ltd | Primer composition for bonding |
US5180625A (en) | 1989-05-03 | 1993-01-19 | Trw Inc. | Ceramic aluminum laminate and thermally conductive adhesive therefor |
JPH0721308Y2 (en) | 1990-10-30 | 1995-05-17 | 信越化学工業株式会社 | Thermal conductive sheet |
JP3182257B2 (en) * | 1993-02-02 | 2001-07-03 | 電気化学工業株式会社 | Heat dissipation sheet |
US5741579A (en) | 1995-04-28 | 1998-04-21 | Shin-Etsu Polymer Co., Ltd. | Heat-conductive sheet |
US5753361A (en) | 1996-05-03 | 1998-05-19 | Eastman Kodak Company | Fuser member having chromium oxide-filled, addition cured layer |
JPH10135383A (en) * | 1996-10-30 | 1998-05-22 | Canon Inc | Electronic-part mounting board, and electronic appliance with the same |
JPH10255250A (en) | 1997-03-11 | 1998-09-25 | Fuji Photo Film Co Ltd | Magnetic storage medium and its manufacturing method |
JP2941801B1 (en) * | 1998-09-17 | 1999-08-30 | 北川工業株式会社 | Thermal conductive material |
JP2000124660A (en) * | 1998-10-12 | 2000-04-28 | Polymatech Co Ltd | Heat-conductive electromagnetic wave shield sheet |
US6365280B1 (en) * | 2000-11-28 | 2002-04-02 | Xerox Corporation | Nitrile-silicone rubber surface release layer for electrostatographic members |
-
2000
- 2000-08-10 JP JP2000242788A patent/JP3609697B2/en not_active Expired - Lifetime
-
2001
- 2001-08-06 US US09/923,509 patent/US20020037419A1/en not_active Abandoned
- 2001-08-08 EP EP20010710043 patent/EP1180798B1/en not_active Expired - Lifetime
- 2001-08-08 DE DE2001630176 patent/DE60130176T2/en not_active Expired - Lifetime
-
2003
- 2003-02-04 US US10/358,425 patent/US6733614B2/en not_active Expired - Lifetime
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20050048803A1 (en) * | 2001-10-16 | 2005-03-03 | Erwann Guillet | Insulator for an organic electronic component |
US7298023B2 (en) * | 2001-10-16 | 2007-11-20 | Polyic Gmbh & Co. Kg | Electronic device with organic insulator |
CN110643182A (en) * | 2019-09-17 | 2020-01-03 | 厦门市科源电子工业有限公司 | Conductive silicone rubber and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
EP1180798B1 (en) | 2007-08-29 |
DE60130176T2 (en) | 2008-01-10 |
US20030143412A1 (en) | 2003-07-31 |
JP3609697B2 (en) | 2005-01-12 |
EP1180798A1 (en) | 2002-02-20 |
DE60130176D1 (en) | 2007-10-11 |
US6733614B2 (en) | 2004-05-11 |
JP2002057254A (en) | 2002-02-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US5290624A (en) | Heat-conductive adhesive films, laminates with heat-conductive adhesive layers and the use thereof | |
CN107039289B (en) | Thermal interface material with defined thermal, mechanical and electrical properties | |
US6886625B1 (en) | Elastomeric heat sink with a pressure sensitive adhesive backing | |
US6733614B2 (en) | Process for forming thermal conductive sheet | |
DE102015116807A1 (en) | Functionalized interface structure | |
JP2008153430A (en) | Heatsink substrate and heat conductive sheet, and power module using these | |
EP1238425A1 (en) | Heat conductive sheet and method of producing the sheet | |
CN107452690A (en) | Composite magnetic encapsulant | |
KR20150052591A (en) | Composition for complex sheet, complex sheet comprising the same, and preparation method of the complex sheet | |
WO2018235919A1 (en) | Heat dissipation sheet, method for producing heat dissipation sheet, and laminate | |
EP3608384B1 (en) | Heat-conductive sheet | |
TW200416976A (en) | Electromagnetic-wave absorptive heat-conduction sheet | |
US6794030B1 (en) | Heat conductive sheet and method of producing the sheet | |
US6890970B2 (en) | Thermal conductive material and method for producing the same | |
JP2002164481A (en) | Heat conductive sheet | |
JP3520257B2 (en) | Manufacturing method of multifunctional sheet | |
JP2915665B2 (en) | A method for manufacturing an insulating sheet and a metal wiring board using the same. | |
JP7101871B2 (en) | Agglomerated boron nitride particles, heat conductive resin composition and heat dissipation member | |
JP2002076683A (en) | Electromagnetic wave absorbing radiating sheet | |
JP3189590B2 (en) | Heat dissipation sheet and its manufacturing method | |
JP3762675B2 (en) | Thermal softening sheet | |
JP2001210764A (en) | Heat conducting board and its manufacturing method | |
JP2003198173A (en) | Electromagnetic wave shielding sheet which functions as thermal radiator and electromagnetic wave suppressing sheet which functions as thermal radiator | |
JPH05299545A (en) | Heat dissipation body | |
JP2001291810A (en) | Heat radiating sheet and electromagnetic wave shielding sheet |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: KITAGAWA INDUSTRIES CO., LTD., JAPAN Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:YAMAGUCHI, AKIO;KAWAI, HIDEHARU;KAWAGUCHI, YASUHIRO;REEL/FRAME:012063/0486 Effective date: 20010803 |
|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |