US20020176985A1 - Methods of bonding metal surfaces, and components therefor - Google Patents

Methods of bonding metal surfaces, and components therefor Download PDF

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Publication number
US20020176985A1
US20020176985A1 US10/197,521 US19752102A US2002176985A1 US 20020176985 A1 US20020176985 A1 US 20020176985A1 US 19752102 A US19752102 A US 19752102A US 2002176985 A1 US2002176985 A1 US 2002176985A1
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Prior art keywords
epoxy
assembly according
adhesive
metal washer
predetermined
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US10/197,521
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US6808774B2 (en
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Christopher Autterson
John Haapala
Jeffery Perenic
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J5/00Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
    • C09J5/06Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers involving heating of the applied adhesive
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J5/00Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
    • C09J5/02Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers involving pretreatment of the surfaces to be joined
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/21Paper; Textile fabrics
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/30Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/35Heat-activated
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00Presence of inorganic and organic materials
    • C09J2400/10Presence of inorganic materials
    • C09J2400/16Metal
    • C09J2400/163Metal in the substrate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2463/00Presence of epoxy resin
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/17Surface bonding means and/or assemblymeans with work feeding or handling means
    • Y10T156/1702For plural parts or plural areas of single part
    • Y10T156/1744Means bringing discrete articles into assembled relationship
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/14Layer or component removable to expose adhesive
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/14Layer or component removable to expose adhesive
    • Y10T428/1438Metal containing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/14Layer or component removable to expose adhesive
    • Y10T428/1438Metal containing
    • Y10T428/1443Aluminum
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/14Layer or component removable to expose adhesive
    • Y10T428/1486Ornamental, decorative, pattern, or indicia
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/14Layer or component removable to expose adhesive
    • Y10T428/149Sectional layer removable
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/21Circular sheet or circular blank
    • Y10T428/215Seal, gasket, or packing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/21Circular sheet or circular blank
    • Y10T428/218Aperture containing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24273Structurally defined web or sheet [e.g., overall dimension, etc.] including aperture
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24917Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including metal layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/28Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/28Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2813Heat or solvent activated or sealable
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/28Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2852Adhesive compositions
    • Y10T428/287Adhesive compositions including epoxy group or epoxy polymer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/674Nonwoven fabric with a preformed polymeric film or sheet

Definitions

  • the present invention relates generally to a fabricated tape assembly for use in conjunction with a method of bonding metal objects in place to facilitate assembly operations, and components used in such a method. More particularly, the present invention relates to a unique process of bonding in place metal objects, at least one of said objects having pre-applied thereto an adhesive epoxy film or tape, and components used in such a process.
  • the present invention provides a washer device, comprising: a metal washer; a heat-curable adhesive bonding composition pre-applied to a first major surface of said metal washer; and said heat-curable adhesive bonding composition being capable of being cured to bond said first major surface of said metal washer to an external metal substrate when first major surface of said metal washer with said pre-applied heat-curable adhesive bonding composition is brought into intimate contact with said external metal substrate and is subjected to a predetermined heating until said pre-applied heat-curable adhesive composition cures to bond said first major surface of said metal washer and said external metal substrate together.
  • the present invention also provides a method of bonding a first metallic object to a second metallic object, comprising the steps of: applying a heat-curable adhesive bonding composition to a predetermined percentage of a predetermined metallic surface of said first metallic object; bringing said heat-curable adhesive bonding composition applied to said predetermined metallic surface said first metallic object into intimate contact with a predetermined metallic surface of said second metallic object; and while said intimate contact is maintained, subjecting said applied heat-curable adhesive bonding composition to heat until said adhesive composition cures to bond said predetermined metallic surfaces together.
  • the present invention further provides a fabricated tape assembly, comprising: a release paper backing member; a film of structural epoxy adhesive applied to said release paper backing member; said film of structural epoxy adhesive being cut or perforated into a series of adhesive annuli; said tape assembly being cut or perforated into a series of square tape sections; and each said square tape section containing a predetermined and pre-arranged array of said adhesive annuli.
  • the present invention also provides a tray device which serves as a shipping tray and an assembly fixture to align a fabricated tape assembly for washers, comprising: a main tray member divided into a predetermined number of square tray sections; two locating pins being provided in each said square section; and a plurality of posts affixed to said main tray member in each said square tray section.
  • the present invention further provides a method of bonding metal surfaces, comprising the steps of applying an adhesive epoxy film or tape to a first metal surface of a first object, wherein said adhesive epoxy film or tape is capable of withstanding production phosphating solutions, cathodic electro-coat primer solutions, and cathodic electro-primer bake temperatures.
  • the adhesive epoxy film or tape applied to the first object is then brought into intimate contact with a second metal surface of a second object. Thereafter, the first metal surface, the adhesive epoxy film or tape, and the second metal surface are subjected to cathodic electro-coat baking until the adhesive epoxy film or tape cures to bond the first and second metal surfaces together.
  • An object of the present invention is to provide a method of bonding as described hereinabove by preparing a die-cut cast epoxy film or tape on a release paper backing which is formed into predetermined shapes in accordance with the first metal surface to be bonded.
  • Another object of the present invention is to provide a method as described hereinabove which utilizes a high strength, heat cure, pre-applied, low tack, cast structural epoxy film or tape.
  • Yet a further object of the invention is to provide such an adhesive epoxy film or tape at a defined thickness and shape which is most efficient for the bonding of metal substrates as an assembly aid to post processing.
  • Another object of the invention is to provide such a method as described hereinabove for use in the bonding of steel locating hinge washers to the hinge assembly, to facilitate doors-off, doors-on processing through the trim shop and automotive assembly.
  • Yet a further object is to provide a method as described hereinabove wherein the adhesive epoxy cures during the cathodic electro-coat primer bake in assembly.
  • FIG. 1 is a top plan view of a novel shipping/assembly fixture tray of the present invention having assembled thereon a plurality of metal washers on top of adhesive tape.
  • FIG. 2 depicts a cross-sectional drawing illustrating the assembly process for bringing the metal objects into intimate contact with each other prior to bonding.
  • the release paper 1 may preferably, but not necessarily, constitute treated polyethylene coated kraft paper.
  • the adhesive epoxy may preferably, but not necessarily, constitute a structural adhesive supplied by 3M Corporation which is designated AF-126(0.08 wt).
  • the tape assemblage of the release paper 1 with its structural adhesive film thereon is then die cut into predetermined shapes and predetermined dimensions.
  • such an assemblage may be cut or perforated into a series of adhesive annuli 2 , with a plurality of said adhesive annuli 2 in a predetermined perforated section of such tape assemblage.
  • the tape assemblage may be cut or perforated into a series of square sections 3 , 4 , 5 or 6 , with each such square section 3 , 4 , 5 or 6 containing a three-by-three array of nine such adhesive annuli 2 .
  • a plurality of metal washers 9 which are countersunk on one side 10 thereof are fabricated.
  • the tray 11 serves as a shipping tray as well as an assembly fixture to align the die cut tape for the washers 9 .
  • the shipping/assembly tray is provided with a plurality of male protruding members or posts 12 upon which the release paper 1 with the adhesive annuli 2 are placed, and on top of which there are placed the washers 9 .
  • the shipping/assembly tray 11 as depicted in FIG. 1 is then sent to the automotive assembly plants.
  • a typical application includes the bonding of steel locating hinge washers 9 in the hinge assembly to facilitate doors-off, doors-on processing through the trim shop.
  • Each washer 9 is placed in a sandwich-like relation between two portions 13 and 14 of the hinge assembly and maintained in intimate contact therewith by way of a threaded bolt 15 .
  • the adhesive annulus 2 is maintained in intimate, positive contact with both of the metal surfaces being bonded, to insure adequate bonding performance and maximize bond surface area.
  • the epoxy annulus 2 has predetermined dimensions to be concentric with the washer 9 , but not coterminous therewith. Predetermined annular spaces 16 and 17 are provided within which the epoxy adhesive may spread without running over the edges of the washer 9 , and yet ensuring an adequate bonding performance.
  • the adhesive epoxy material is suitable for applications bonding metal surfaces, such as galvanized, galvanneal, and cold rolled steel, which may be coated with metal forming lubricants.
  • This special adhesive withstands production phosphating solutions, cathodic electro-primer solutions, and cathodic electro-primer bake temperatures.
  • the hinge portions 13 and 14 can be disassembled leaving the steel locating hinge washer 9 in place for later assembly.
  • the method includes all variations wherein application of the epoxy adhesive material can be at any point prior to the cathodic electro-coat bake in the body shop area of assembly or in the stamping plant.
  • the epoxy adhesive is not resistance weld through capable.

Abstract

A fabricated tape assembly for bonding of steel locating hinge washers to a hinge assembly to facilitate doors-off/door-on processing through an automotive trim shop. The adhesive bonding system cures during the cathodic electro-cost primer bake cycle. The adhesive maintains an intimate, positive contact with both metal surfaces ensuring adequate bonding performance and maximized bonding surface area during a defined heat or bake cycle.

Description

  • The present patent application claims priority from U.S. Provisional Patent Application Serial No. 60/244,998 filed Nov. 1, 2000, and is a divisional application of U.S. patent application Ser. No. 10/039,722 filed Oct. 24, 2001 in which a Petition to Make Special because of Actual Infringement was granted May 15, 2002.[0001]
  • The present invention relates generally to a fabricated tape assembly for use in conjunction with a method of bonding metal objects in place to facilitate assembly operations, and components used in such a method. More particularly, the present invention relates to a unique process of bonding in place metal objects, at least one of said objects having pre-applied thereto an adhesive epoxy film or tape, and components used in such a process. [0002]
  • BACKGROUND OF THE INVENTION
  • In the past, many techniques have been tried to make assembly operations, especially in automotive manufacture, more efficient. This has been especially true with respect to the locating of hinge washers in the door hinge assembly processes of automotive vehicles. [0003]
  • The techniques which have been tried in the past are inaccurate, expensive, complicated, cumbersome, slow, and subject to frequent malfunction. [0004]
  • It is a desideratum of the present invention to provide a novel process for bonding metal objects in place, and components used in such process, which avoid the animadversions of the prior art techniques. [0005]
  • SUMMARY OF THE INVENTION
  • The present invention provides a washer device, comprising: a metal washer; a heat-curable adhesive bonding composition pre-applied to a first major surface of said metal washer; and said heat-curable adhesive bonding composition being capable of being cured to bond said first major surface of said metal washer to an external metal substrate when first major surface of said metal washer with said pre-applied heat-curable adhesive bonding composition is brought into intimate contact with said external metal substrate and is subjected to a predetermined heating until said pre-applied heat-curable adhesive composition cures to bond said first major surface of said metal washer and said external metal substrate together. [0006]
  • The present invention also provides a method of bonding a first metallic object to a second metallic object, comprising the steps of: applying a heat-curable adhesive bonding composition to a predetermined percentage of a predetermined metallic surface of said first metallic object; bringing said heat-curable adhesive bonding composition applied to said predetermined metallic surface said first metallic object into intimate contact with a predetermined metallic surface of said second metallic object; and while said intimate contact is maintained, subjecting said applied heat-curable adhesive bonding composition to heat until said adhesive composition cures to bond said predetermined metallic surfaces together. [0007]
  • The present invention further provides a fabricated tape assembly, comprising: a release paper backing member; a film of structural epoxy adhesive applied to said release paper backing member; said film of structural epoxy adhesive being cut or perforated into a series of adhesive annuli; said tape assembly being cut or perforated into a series of square tape sections; and each said square tape section containing a predetermined and pre-arranged array of said adhesive annuli. [0008]
  • The present invention also provides a tray device which serves as a shipping tray and an assembly fixture to align a fabricated tape assembly for washers, comprising: a main tray member divided into a predetermined number of square tray sections; two locating pins being provided in each said square section; and a plurality of posts affixed to said main tray member in each said square tray section. [0009]
  • The present invention further provides a method of bonding metal surfaces, comprising the steps of applying an adhesive epoxy film or tape to a first metal surface of a first object, wherein said adhesive epoxy film or tape is capable of withstanding production phosphating solutions, cathodic electro-coat primer solutions, and cathodic electro-primer bake temperatures. The adhesive epoxy film or tape applied to the first object is then brought into intimate contact with a second metal surface of a second object. Thereafter, the first metal surface, the adhesive epoxy film or tape, and the second metal surface are subjected to cathodic electro-coat baking until the adhesive epoxy film or tape cures to bond the first and second metal surfaces together. [0010]
  • An object of the present invention is to provide a method of bonding as described hereinabove by preparing a die-cut cast epoxy film or tape on a release paper backing which is formed into predetermined shapes in accordance with the first metal surface to be bonded. [0011]
  • Another object of the present invention is to provide a method as described hereinabove which utilizes a high strength, heat cure, pre-applied, low tack, cast structural epoxy film or tape. [0012]
  • Yet a further object of the invention is to provide such an adhesive epoxy film or tape at a defined thickness and shape which is most efficient for the bonding of metal substrates as an assembly aid to post processing. [0013]
  • Another object of the invention is to provide such a method as described hereinabove for use in the bonding of steel locating hinge washers to the hinge assembly, to facilitate doors-off, doors-on processing through the trim shop and automotive assembly. [0014]
  • Yet a further object is to provide a method as described hereinabove wherein the adhesive epoxy cures during the cathodic electro-coat primer bake in assembly. [0015]
  • These and other objects, advantages and features of the present invention will become apparent to those persons skilled in this area of technology and to others when reading the detailed description set forth hereinbelow in conjunction with the accompanying drawings.[0016]
  • BRIEF DESCRIPTION OF THE DRAWING
  • FIG. 1 is a top plan view of a novel shipping/assembly fixture tray of the present invention having assembled thereon a plurality of metal washers on top of adhesive tape. [0017]
  • FIG. 2 depicts a cross-sectional drawing illustrating the assembly process for bringing the metal objects into intimate contact with each other prior to bonding.[0018]
  • DETAILED DESCRIPTION OF SOME PREFERRED EMBODIMENTS OF THE PRESENT INVENTION
  • A first preferred embodiment of the present invention will now be described. [0019]
  • First, there is fabricated tape comprising a backing or [0020] release paper 1 having applied thereto a film of structural epoxy adhesive. For example, the release paper 1 may preferably, but not necessarily, constitute treated polyethylene coated kraft paper. Furthermore, the adhesive epoxy may preferably, but not necessarily, constitute a structural adhesive supplied by 3M Corporation which is designated AF-126(0.08 wt).
  • The tape assemblage of the [0021] release paper 1 with its structural adhesive film thereon is then die cut into predetermined shapes and predetermined dimensions. For example, such an assemblage may be cut or perforated into a series of adhesive annuli 2, with a plurality of said adhesive annuli 2 in a predetermined perforated section of such tape assemblage. For example, the tape assemblage may be cut or perforated into a series of square sections 3,4,5 or 6, with each such square section 3,4,5 or 6 containing a three-by-three array of nine such adhesive annuli 2.
  • Four of [0022] such sections 3, 4, 5 and 6, each containing a three-by-three array of nine adhesive annuli 2, are placed in a shipping/assembly fixture tray 11 as illustrated in FIG. 1. Each square section 3, 4, 5 or 6 is placed on the two associated locating pins 7 and 8 and nine posts 12 of the tray 11 with the adhesive annuli 2 of the tape assemblage facing upwardly.
  • A plurality of [0023] metal washers 9 which are countersunk on one side 10 thereof are fabricated. The tray 11 serves as a shipping tray as well as an assembly fixture to align the die cut tape for the washers 9. For each square section 3, 4, 5 and 6 in the shipping/assembly fixture tray 11, there are placed nine such countersunk washers 9 with the countersunk surface 10 abutting an associated epoxy adhesive annulus 2.
  • The shipping/assembly tray is provided with a plurality of male protruding members or [0024] posts 12 upon which the release paper 1 with the adhesive annuli 2 are placed, and on top of which there are placed the washers 9.
  • The shipping/assembly tray [0025] 11 as depicted in FIG. 1 is then sent to the automotive assembly plants. A typical application includes the bonding of steel locating hinge washers 9 in the hinge assembly to facilitate doors-off, doors-on processing through the trim shop.
  • When each [0026] washer 9 is removed from the tray 11, the adhesive annulus 2 adheres to the countersunk side 10 of the washer 9 due to the tackiness of the adhesive annulus 2.
  • Each [0027] washer 9 is placed in a sandwich-like relation between two portions 13 and 14 of the hinge assembly and maintained in intimate contact therewith by way of a threaded bolt 15.
  • During the heat cure cycle, the [0028] adhesive annulus 2 is maintained in intimate, positive contact with both of the metal surfaces being bonded, to insure adequate bonding performance and maximize bond surface area. The epoxy annulus 2 has predetermined dimensions to be concentric with the washer 9, but not coterminous therewith. Predetermined annular spaces 16 and 17 are provided within which the epoxy adhesive may spread without running over the edges of the washer 9, and yet ensuring an adequate bonding performance.
  • The adhesive epoxy material is suitable for applications bonding metal surfaces, such as galvanized, galvanneal, and cold rolled steel, which may be coated with metal forming lubricants. This special adhesive withstands production phosphating solutions, cathodic electro-primer solutions, and cathodic electro-primer bake temperatures. [0029]
  • After the adhesive cures during the cathodic electro-primer bake and assembly, the [0030] hinge portions 13 and 14 can be disassembled leaving the steel locating hinge washer 9 in place for later assembly.
  • The method includes all variations wherein application of the epoxy adhesive material can be at any point prior to the cathodic electro-coat bake in the body shop area of assembly or in the stamping plant. [0031]
  • Preferably, but not necessarily, the epoxy adhesive is not resistance weld through capable. [0032]
  • Various modifications of the process and the components therefore as described hereinabove are contemplated by the present invention. Therefore, while there have been set forth some preferred embodiments of the present invention, it should be understood that the present invention is not to be limited or restricted to the particular embodiments described in detail hereinabove which have been set forth for illustrative purposes only. [0033]

Claims (20)

1. A fabricated tape assembly, comprising:
a release paper backing member;
a film of structural epoxy adhesive applied to said release paper backing member;
said film of structural epoxy adhesive being cut or perforated into a series of adhesive annuli;
said tape assembly being cut or perforated into a series of square tape sections; and
each said square tape section containing a predetermined and pre-arranged array of said adhesive annuli.
2. A fabricated tape assembly according to claim 1, wherein:
said film of structural epoxy adhesive comprises a heat-curable adhesive bonding composition.
3. The assembly according to claim 2, wherein:
said heat-curable adhesive bonding composition is resistant to phosphating solutions.
4. The assembly according to claim 2, wherein:
said heat-curable adhesive bonding composition is compatible with cathodic electro-coating.
5. The assembly according to claim 3, wherein:
said heat-curable adhesive bonding composition is compatible with cathodic electro-coating.
6. The assembly according to claim 2, wherein:
said heat-curable adhesive bonding composition is cured by a predetermined cathodic electro-coat primer baking thereof.
7. The assembly according to claim 3, wherein:
said heat-curable adhesive bonding composition is cured by a predetermined cathodic electro-coat primer baking thereof.
8. The assembly according to claim 1, wherein:
each said adhesive annuli comprises an epoxy annulus having predetermined dimensions to be concentric with a metal washer, but not coterminous therewith, and forming predetermined annular spaces on a first major surface of said metal washer within which annular spaces said epoxy will spread during curing without running over any edge of said metal washer.
9. The assembly according to claim 2, wherein:
each said adhesive annuli comprises an epoxy annulus having predetermined dimensions to be concentric with a metal washer, but not coterminous therewith, and forming predetermined annular spaces on a first major surface of said metal washer within which annular spaces said epoxy will spread during curing without running over any edge of said metal washer.
10. The assembly according to claim 3, wherein:
each said adhesive annuli comprises an epoxy annulus having predetermined dimensions to be concentric with a metal washer, but not coterminous therewith, and forming predetermined annular spaces on a first major surface of said metal washer within which annular spaces said epoxy will spread during curing without running over any edge of said metal washer.
11. A fabricated tape assembly, comprising:
a release paper backing member;
a film of structural epoxy adhesive applied to said release paper backing member;
a predetermined number and array of adhesive annuli being formed in said film of structural epoxy adhesive;
said tape assembly being fabricated into a predetermined number of substantially square tape sections; and
each said substantially square tape section containing a predetermined number and pre-arranged array of said adhesive annuli.
12. A fabricated tape assembly according to claim 11, wherein:
said film of structural epoxy adhesive comprises a heat-curable adhesive bonding composition.
13. The assembly according to claim 12, wherein:
said heat-curable adhesive bonding composition is resistant to phosphating solutions.
14. The assembly according to claim 12, wherein:
said heat-curable adhesive bonding composition is compatible with cathodic electro-coating.
15. The assembly according to claim 13, wherein:
said heat-curable adhesive bonding composition is compatible with cathodic electro-coating.
16. The assembly according to claim 12, wherein:
said heat-curable adhesive bonding composition is cured by a predetermined cathodic electro-coat primer baking thereof.
17. The assembly according to claim 13, wherein:
said heat-curable adhesive bonding composition is cured by a predetermined cathodic electro-coat primer baking thereof.
18. The assembly according to claim 11, wherein:
each said adhesive annuli comprises an epoxy annulus having predetermined dimensions to be concentric with a metal washer, but not coterminous therewith, and forming predetermined annular spaces on a first major surface of said metal washer within which annular spaces said epoxy will spread during curing without running over any edge of said metal washer.
19. The assembly according to claim 12, wherein:
each said adhesive annuli comprises an epoxy annulus having predetermined dimensions to be concentric with a metal washer, but not coterminous therewith, and forming predetermined annular spaces on a first major surface of said metal washer within which annular spaces said epoxy will spread during curing without running over any edge of said metal washer.
20. The assembly according to claim 13, wherein:
each said adhesive annul comprises an epoxy annulus having predetermined dimensions to be concentric with a metal washer, but not coterminous therewith, and forming predetermined annular spaces on a first major surface of said metal washer within which annular spaces said epoxy will spread during curing without running over any edge of said metal washer.
US10/197,521 2000-11-01 2002-07-10 Fabricated tape assembly Expired - Lifetime US6808774B2 (en)

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US24499800P 2000-11-01 2000-11-01
US10/039,722 US6669428B2 (en) 2000-11-01 2001-10-24 Locating door hinge washer device for hinge assembly
US10/197,521 US6808774B2 (en) 2000-11-01 2002-07-10 Fabricated tape assembly

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US10/193,725 Expired - Lifetime US6736925B2 (en) 2000-11-01 2002-07-10 Methods of bonding metal surfaces, and components therefor
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Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7090455B2 (en) * 1998-11-13 2006-08-15 Pneutools, Incorporated Stacked assembly of roofing caps
US6808216B2 (en) * 2002-08-30 2004-10-26 Cardinal Ig Company Methods and apparatus for handling workpieces
JP4328229B2 (en) * 2003-06-04 2009-09-09 株式会社ユニオン精密 Fastening structure using screw accessories and disassembly method using screw accessories
US20060239797A1 (en) * 2005-04-20 2006-10-26 Evanbar Michael S Pre-formed elastomeric fastener adhesive device and method of installation
US7527463B2 (en) * 2006-03-10 2009-05-05 Gm Global Technology Operations, Inc. Nut and method for adhesive nut attachment
US8142124B2 (en) * 2006-12-13 2012-03-27 The Boeing Company Methods and systems for captive fastening
US8002332B2 (en) 2007-01-30 2011-08-23 Zephyros, Inc. Structural mounting insert
US7880112B2 (en) * 2007-02-13 2011-02-01 GM Global Technology Operations LLC Method for welding and adhesively attaching a shaped fastener to inside of member
JP5099548B2 (en) * 2007-12-03 2012-12-19 学校法人東海大学 Fastening structure
US9194408B2 (en) 2008-02-08 2015-11-24 Zephyros, Inc. Mechanical method for improving bond joint strength
US8181327B2 (en) 2008-02-08 2012-05-22 Zephyros, Inc Mechanical method for improving bond joint strength
US8029221B2 (en) * 2008-03-31 2011-10-04 Illinois Tool Works, Inc. Cage nut assembly
US7984919B2 (en) * 2009-05-18 2011-07-26 Zephyros, Inc. Structural mounting insert having a non-conductive isolator
DE102010047637A1 (en) * 2010-10-06 2012-04-12 Profil Verbindungstechnik Gmbh & Co. Kg functional element
US8689516B2 (en) 2011-03-17 2014-04-08 Zephyros, Inc. Bonding assembly
US9915282B2 (en) 2012-06-06 2018-03-13 Pneutools, Incorporated Stacked caps with connecting stems
GB201318595D0 (en) 2013-10-21 2013-12-04 Zephyros Inc Improvements in or relating to laminates
CN105916651B (en) 2013-12-17 2018-11-02 泽菲罗斯公司 A kind of reinforced structure and its manufacturing method including fiber insert
WO2017117169A1 (en) 2015-12-31 2017-07-06 Henkel Ag & Co. Kgaa Low bake autodeposition coatings
US10760609B2 (en) * 2016-02-08 2020-09-01 Hamilton Sundstrand Corporation Sealant articles and method of applying sealant
USD825199S1 (en) * 2016-09-20 2018-08-14 Rockline Industries, Inc. Toilet tissue with raised pattern
US11852184B2 (en) * 2020-08-21 2023-12-26 Rtx Corporation Fastener element bonded to another fastener element

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4320158A (en) * 1980-05-30 1982-03-16 Monarch Marking Systems, Inc. Composite label web roll
US5051049A (en) * 1990-10-29 1991-09-24 Wills Kevin P Sticky nut fastener
US5770289A (en) * 1996-11-13 1998-06-23 Tracy; Peter Die cut self-adhesive label sheet for labeling CD-ROMS
US6030701A (en) * 1993-04-15 2000-02-29 3M Innovative Properties Company Melt-flowable materials and method of sealing surfaces
US6106915A (en) * 1998-08-28 2000-08-22 Ruben; Philip H. Paper reinforcing and repair rings
US6299955B1 (en) * 2000-02-25 2001-10-09 Yoo Tae Woo Supporting board for moxibusting implement of loess
US6479118B1 (en) * 2000-05-04 2002-11-12 Fellowes Inc. Foldable die cut self-adhesive label sheet for labeling CD-ROMS

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1874462A (en) * 1930-04-10 1932-08-30 Shakeproof Lock Washer Co Lock washer assembly
US3298271A (en) * 1964-11-12 1967-01-17 Gen Electric Fastener having layer of foamed resin with indexing means projecting therethrough
US3640379A (en) * 1970-02-26 1972-02-08 Marshall L Weingarden Cassette album
US3950204A (en) * 1972-09-29 1976-04-13 Texas Instruments Incorporated Low pressure, thin film bonding
US4760457A (en) * 1986-04-30 1988-07-26 Rca Licensing Corporation Self-fixtured kinescope
US4822224A (en) * 1987-11-05 1989-04-18 Chrysler Motors Corporation Harness retainer stud
US4855562A (en) * 1988-10-17 1989-08-08 Milton Hinden Weld pin for insulation attachment
US6485589B1 (en) * 1993-04-15 2002-11-26 3M Innovative Properties Company Melt-flowable materials and method of sealing surfaces
US5314280A (en) * 1993-07-06 1994-05-24 Ford Motor Company Settable height adjusting fastener
WO1995012646A1 (en) * 1993-11-03 1995-05-11 H.B. Fuller Automotive Products, Inc. Heat curable toughened epoxy resin compositions
FR2721075B1 (en) * 1994-06-14 1996-07-19 Procidec Screwed assembly means with captive washer and process for its manufacture.
US5731230A (en) * 1995-03-28 1998-03-24 Micron Technology, Inc. Method for processing and/or shipping integrated circuit devices
GB9604048D0 (en) * 1996-02-26 1996-04-24 Grossman Stanley I Labelling device and label
US5988394A (en) * 1996-11-28 1999-11-23 Kabushiki Kaisha Toshiba Tray for containing parts for storage and transportation
US6428650B1 (en) * 1998-06-23 2002-08-06 Amerasia International Technology, Inc. Cover for an optical device and method for making same
US6109445A (en) * 1998-06-24 2000-08-29 Tek Pak, Inc. Modular tray system

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4320158A (en) * 1980-05-30 1982-03-16 Monarch Marking Systems, Inc. Composite label web roll
US5051049A (en) * 1990-10-29 1991-09-24 Wills Kevin P Sticky nut fastener
US6030701A (en) * 1993-04-15 2000-02-29 3M Innovative Properties Company Melt-flowable materials and method of sealing surfaces
US5770289A (en) * 1996-11-13 1998-06-23 Tracy; Peter Die cut self-adhesive label sheet for labeling CD-ROMS
US6106915A (en) * 1998-08-28 2000-08-22 Ruben; Philip H. Paper reinforcing and repair rings
US6299955B1 (en) * 2000-02-25 2001-10-09 Yoo Tae Woo Supporting board for moxibusting implement of loess
US6479118B1 (en) * 2000-05-04 2002-11-12 Fellowes Inc. Foldable die cut self-adhesive label sheet for labeling CD-ROMS

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US6669428B2 (en) 2003-12-30
US7143895B2 (en) 2006-12-05
US20020175104A1 (en) 2002-11-28
US20020056517A1 (en) 2002-05-16
US20020170669A1 (en) 2002-11-21
US6736925B2 (en) 2004-05-18

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