|Número de publicación||US20030029617 A1|
|Tipo de publicación||Solicitud|
|Número de solicitud||US 09/925,788|
|Fecha de publicación||13 Feb 2003|
|Fecha de presentación||9 Ago 2001|
|Fecha de prioridad||9 Ago 2001|
|También publicado como||CN1564904A, US20050231022, US20060138853, WO2003015025A2, WO2003015025A3|
|Número de publicación||09925788, 925788, US 2003/0029617 A1, US 2003/029617 A1, US 20030029617 A1, US 20030029617A1, US 2003029617 A1, US 2003029617A1, US-A1-20030029617, US-A1-2003029617, US2003/0029617A1, US2003/029617A1, US20030029617 A1, US20030029617A1, US2003029617 A1, US2003029617A1|
|Inventores||Neil Brown, Karl Nesselrode|
|Cesionario original||Anadarko Petroleum Company|
|Exportar cita||BiBTeX, EndNote, RefMan|
|Citas de patentes (5), Citada por (58), Clasificaciones (6), Eventos legales (1)|
|Enlaces externos: USPTO, Cesión de USPTO, Espacenet|
 This invention relates to solution-mining of subterranean materials. The following discusses the disclosed solution-mining invention as applied to trona, but it is understood that this solution-mining invention applies to all subterranean materials.
 The subterranean material trona, also known as natural soda ash, is a crystalline form of sodium carbonate and sodium bicarbonate, known as sodium sesquicarbonate, having the formula Na2CO3·NaHCO3·2H2O. Worldwide, deposits of natural trona are rare, but the world's largest known deposit is located in the Green River Basin of southwestern Wyoming. Smaller deposits of trona are found near Memphis, Egypt and the Lower Nile Valley, widely throughout the soda lakes of Africa, Armenia, and Iran, and in the alkali deserts of Mongolia and Tibet. From natural trona, the primary end product is soda ash. In fact, Wyoming produces 90% of the processed soda ash in the United States and 30% of the world's supply. Other end-products from trona include sodium bicarbonate, caustic soda, sodium sulfite, sodium cyanide and sodium phosphate. Improved and cheaper processes for mining trona from natural deposits are desired.
 Mining is an age-old approach for removing subterranean materials, e.g., trona, nahcolite, dawsonite, wegscheiderite, thermonatrite, pirssonite, natron, gaylussite, shortite, halite, and other salts, minerals, and so forth. Many deposits of subterranean materials, however, do not permit commercially viable extraction, whether through underground mechanical mining or solution-mining. For example, not even 10% of known trona deposits permit commercially viable underground mechanical mining, and trona solution-mining has not been economical.
 Underground mechanical mining requires deep shafts to remove the subterranean material, and ever-deeper shafts are used as more material is extracted. In addition, mechanical mining is people-intensive. This creates a dangerous operating environment.
 After lifting the material to the surface, the material is calcined to expel volatile components, such as carbon dioxide. Calcination is an energy-intensive processing step that affects the economics of mechanical mining. After calcination, the calcined material is recrystallized in aqueous solution, collected, dried and ready for further processing or shipping.
 Solution-mining is a touted alternative to mechanical mining, but solution-mining has not proven as economical as desired. Solution-mining of subterranean materials, in particular, trona, is possible using hot water or alkaline solutions. For example, U.S. Pat. No. 2,388,009 (Pike) discloses the use of a hot water or hot carbonate solution as the mining fluid. See also U.S. Pat. Nos. 2,625,384 (Pike et al.); 2,847,202 (Pullen); 2,979,315 (Bays); 3,018,095 (Redlinger); 3,050,290 (Caldwell et al.); 3,086,760 (Bays); U.S. Pat. No. 3,184,287 (Gancy); 3,405,974 (Handley et al.); U.S. Pat. No. 3,952,073 (Kube); U.S. Pat. No. 4,283,372 (Frint et al.); 4,288,419 (Copenhafer et al.); and U.S. Pat. No. 4,344,650 (Pinsky et al.), all of which are incorporated herein by reference. These disclosures, and other documented solution-mining processes, reveal use of two or more of the following economic drains on commercial viability: high temperatures, high pressure calcination, hydraulic fracturing (“fracturing”), and two wells, wherein one well is for injection and one well is for production, see e.g., U.S. Pat. No. 4,815,790, Rosar, et al.; U.S. Pat. No. 4,344,650, Pinsky, et al.; U.S. Pat. No. 4,252,781, Fujita, et al.; U.S. Pat. No. 4,022,868, Poncha, et al.; U.S. Pat. No. 4,021,526, Gancy et al.; and U.S. Pat. No. 4,021,525, Poncha, all of which are incorporated herein by reference. Fracturing rarely fractures only the material to be removed, so injecting hot water or alkaline solution dissolves other materials, including salts, and contaminates the subterranean material product collected from the production well. Collection of contaminated subterranean materials is yet another economic drain to commercial viable solution-mining processes.
 In addition to solution-mining of trona, various U.S. patents disclose solution-mining of nahcolite (predominantly NaHCO3). For example, U.S. Pat. No. 3,779,602 (Beard et al.) and U.S. Pat. Nos. 3,792,902 (Towell et al.), and U.S. Pat. No. 3,952,073 (Cube) and U.S. Pat. No. 4,283,372 (Frint, et al.) disclose basic solution-mining of nahcolite and wegscheiderite (predominately Na2CO3·3NaHCO3), all of which are incorporated herein by reference. Like the trona solution-mining processes, however, these nahcolite and wegscheiderite solution-recovery processes also possess economic drains on commercial viability.
 A need, therefore, exists for improved solution-mining of subterranean materials through improved, more efficient methods and systems.
 The claimed invention is a method, system, and apparatus for solution-mining of subterranean materials. According to a first aspect of the invention, a method is provided for solution-mining of a subterranean material, the method comprising injecting a fluid into an elbow well, the fluid forming a subterranean mixture with the subterranean material, and collecting the subterranean mixture from the elbow well. According to another aspect of the invention, a system is provided for solution-mining of a subterranean material, the system comprising a means for injecting a fluid into an elbow well, the fluid forming a subterranean mixture with the subterranean material, and a means for collecting the subterranean mixture from the elbow well. According to still another aspect of the invention, an apparatus is provided for solution-mining of a subterranean material, the apparatus comprising an injection tube, wherein the injection tube has an injection tube inner diameter of sufficient size to allow for injection of a fluid for mining of a subterranean material. The apparatus further comprises a production casing, wherein the production casing has a production casing inner diameter of sufficient size to allow for production of a subterranean mixture of the fluid and the subterranean material between an outer surface of the injection tube and an inner surface of the production casing.
FIG. 1 is a schematic of the cased elbow well drilled into a bed of a subterranean material, wherein the elbow well comprises an injection tube, a production casing, and a production tube that is connected to a pump to help lift the subterranean mixture in the cavity to a collection location, here, the earth's surface.
FIG. 2 is a cross-sectional view of the initial cavity in the elbow well.
FIG. 3 is a cross-sectional view of the cavity in the elbow well, wherein the cavity is larger than in FIG. 2.
FIG. 4 is a cross-sectional view of the cavity in the elbow well, wherein the cavity is larger than in FIG. 3.
 The disclosed solution-mining invention is a device, method, and system for solution-mining of subterranean materials, such as trona, nahcolite, dawsonite, wegscheiderite, thermonatrite, pirssonite, natron, gaylussite, shortite, halite, and other salts, minerals, and so forth. Although this detailed disclosure focuses on the subterranean material trona, it is understood that the disclosed device, method, and system for solution-mining applies to all solution-minable subterranean materials.
 In one example embodiment of the claimed invention, seen in FIG. 1, an elbow well 15 is drilled into a bed 30 of the subterranean material 25 being mined. An elbow well 15 is a well that begins at the earth's surface 70, and first penetrates vertically before penetrating horizontally. Although the elbow well 15 does not necessarily resemble the shape of a human elbow, there is a vertical portion that eventually turns to a horizontal portion. For trona, the estimated depth 160 for mining is 2000 feet below the earth's surface 70. Both an injection tube 45 and a production tube 60 a are located in the elbow well 15, wherein 3-½″ J55 tubing is used in one example for the injection tube 45, but other sizes and types of tubing will occur to those of skill in the art without departing from the scope of the present invention. A fluid 10 is injected into the injection tube 45, wherein the fluid 10 reacts with the subterranean material 25 to create a mixture 55 (e.g., a solution) and a cavity 50. The mixture 55 flows between the injection tube 45 and the production casing 60 b. In another example embodiment, a pump 140 is attached to the production tube 60 a to help lift the mixture 55 to the collection point 65 (here, the earth's surface 70).
 Fracturing is unnecessary in many embodiments of the invention, because the injection tube 45, production casing 60 b, and production tube 60 a are in the same well 15. The elbow well 15, in some embodiments, is over 3000 linear feet in length 155 within the bed 30 of the subterranean material 25.
 According to another embodiment of the invention, seen in FIGS. 2-4, the cavity 50 expands as more fluid 10 is injected into the well 15 dissolving more subterranean material 25. The cavity 50 expands outward from the end of the elbow well 15, and therefore the cavity 50 propagates back to the well 15. In the event that a collapse of the cavity 50, or other obstruction, reduces the flow of the mixture 55, the injection tube 45 is perforated in some embodiments to permit further amounts of the mixture 55 to be collected. Alternatively, rather than perforation, the injection tube 45 is withdrawn, partially, until debris from the collapse is clear and flow of the mixture 55 is raised to an acceptable level.
 High pressures of operation may cause the material 25 in the mixture 55 to escape before collection of the subterranean material mixture 55. Low pressures of operation, however, reduce the total collection of the subterranean material 25, because the cavity 50 may collapse prematurely. Selection of the well pressure to avoid these problems should be observed. At present, there is no known empirical method to make such selection other than trial and error. It is believed, however, that the following pressures and flow rates are acceptable, at least for trona: at 2000 feet deep, the pressure is 800-900 psi in the cavity 50 and the flow rate is 200-300 gal/min.
 In further example embodiments of the invention, the subterranean material 25 is selected from a group consisting essentially of trona, dawsonite, wegscheiderite, nahcolite, thermonatrite, pirssonite, natron, gaylussite, shortite, halite, and other salts, minerals, and so forth.
 In various example embodiments, the fluid 10 is selected from a group consisting essentially of water, a caustic mixture, a sodium carbonate solution, or any other fluid 10 capable of mechanically and/or chemically reacting with the subterranean material 25 to be mined so as to produce a mixture 55 capable of being removed from the production casing 60 b through a production tube 60 a. Such fluids 10 will occur to those of skill in the art. In some embodiments, the fluid 10 is heated.
 In a further example embodiment, the mixture 55 is lifted, for example, by pumping with a pump 140 connected to the production tube 60 a, and the mixture 55 is delivered to a collection location 65, such as the earth's surface 70. According to one example embodiment, an acceptable pump 140 comprises an electric submersible centrifugal pump, 140 such as those manufactured by Baker Hughes Centrilift. In addition, placement of the pump 140 is above the bed 30 of subterranean mineral 25, that is, above the mining areas. For example, with trona, the pump 140 is placed in some embodiments about 1100 feet below the earth's surface 70 in the elbow well 15. Other pumps 140 acceptable for use with the claimed invention include piston/cylinder pumps, driven by sucks rods from the surface 70. Still other pumps 140 acceptable for use with the claimed invention will occur to those of skill in the art.
 Having thus described exemplary embodiments of the invention, it will be apparent that various alterations, modifications and improvements will readily occur to those skilled in the art. Such alterations, modifications and improvements, though not expressly described above, are nevertheless within the spirit and scope of the invention. Accordingly, the foregoing discussion is intended to be illustrative only, and not limiting; the invention is limited and defined by the following claims and equivalents thereto.
|Patente citada||Fecha de presentación||Fecha de publicación||Solicitante||Título|
|US2151733||4 May 1936||28 Mar 1939||American Box Board Co||Container|
|CH283612A *||Título no disponible|
|FR1392029A *||Título no disponible|
|FR2166276A1 *||Título no disponible|
|GB533718A||Título no disponible|
|Patente citante||Fecha de presentación||Fecha de publicación||Solicitante||Título|
|US6742603 *||7 Jun 2002||1 Jun 2004||Exxonmobil Research And Engineering Company||Hydrothermal drilling method and system|
|US7611208||17 Ago 2005||3 Nov 2009||Sesqui Mining, Llc||Methods for constructing underground borehole configurations and related solution mining methods|
|US7644765||19 Oct 2007||12 Ene 2010||Shell Oil Company||Heating tar sands formations while controlling pressure|
|US7673681||19 Oct 2007||9 Mar 2010||Shell Oil Company||Treating tar sands formations with karsted zones|
|US7673786||20 Abr 2007||9 Mar 2010||Shell Oil Company||Welding shield for coupling heaters|
|US7677310||19 Oct 2007||16 Mar 2010||Shell Oil Company||Creating and maintaining a gas cap in tar sands formations|
|US7677314||19 Oct 2007||16 Mar 2010||Shell Oil Company||Method of condensing vaporized water in situ to treat tar sands formations|
|US7681647||19 Oct 2007||23 Mar 2010||Shell Oil Company||Method of producing drive fluid in situ in tar sands formations|
|US7683296||20 Abr 2007||23 Mar 2010||Shell Oil Company||Adjusting alloy compositions for selected properties in temperature limited heaters|
|US7703513||19 Oct 2007||27 Abr 2010||Shell Oil Company||Wax barrier for use with in situ processes for treating formations|
|US7717171||19 Oct 2007||18 May 2010||Shell Oil Company||Moving hydrocarbons through portions of tar sands formations with a fluid|
|US7730945||19 Oct 2007||8 Jun 2010||Shell Oil Company||Using geothermal energy to heat a portion of a formation for an in situ heat treatment process|
|US7730946||19 Oct 2007||8 Jun 2010||Shell Oil Company||Treating tar sands formations with dolomite|
|US7730947||19 Oct 2007||8 Jun 2010||Shell Oil Company||Creating fluid injectivity in tar sands formations|
|US7785427||20 Abr 2007||31 Ago 2010||Shell Oil Company||High strength alloys|
|US7793722||20 Abr 2007||14 Sep 2010||Shell Oil Company||Non-ferromagnetic overburden casing|
|US7798220||18 Abr 2008||21 Sep 2010||Shell Oil Company||In situ heat treatment of a tar sands formation after drive process treatment|
|US7831133||21 Abr 2006||9 Nov 2010||Shell Oil Company||Insulated conductor temperature limited heater for subsurface heating coupled in a three-phase WYE configuration|
|US7831134||21 Abr 2006||9 Nov 2010||Shell Oil Company||Grouped exposed metal heaters|
|US7832484||18 Abr 2008||16 Nov 2010||Shell Oil Company||Molten salt as a heat transfer fluid for heating a subsurface formation|
|US7841401||19 Oct 2007||30 Nov 2010||Shell Oil Company||Gas injection to inhibit migration during an in situ heat treatment process|
|US7841408||18 Abr 2008||30 Nov 2010||Shell Oil Company||In situ heat treatment from multiple layers of a tar sands formation|
|US7841425||18 Abr 2008||30 Nov 2010||Shell Oil Company||Drilling subsurface wellbores with cutting structures|
|US7845411||19 Oct 2007||7 Dic 2010||Shell Oil Company||In situ heat treatment process utilizing a closed loop heating system|
|US7849922||18 Abr 2008||14 Dic 2010||Shell Oil Company||In situ recovery from residually heated sections in a hydrocarbon containing formation|
|US7860377||21 Abr 2006||28 Dic 2010||Shell Oil Company||Subsurface connection methods for subsurface heaters|
|US7866385||20 Abr 2007||11 Ene 2011||Shell Oil Company||Power systems utilizing the heat of produced formation fluid|
|US7866386||13 Oct 2008||11 Ene 2011||Shell Oil Company||In situ oxidation of subsurface formations|
|US7866388||13 Oct 2008||11 Ene 2011||Shell Oil Company||High temperature methods for forming oxidizer fuel|
|US7912358||20 Abr 2007||22 Mar 2011||Shell Oil Company||Alternate energy source usage for in situ heat treatment processes|
|US7931086||18 Abr 2008||26 Abr 2011||Shell Oil Company||Heating systems for heating subsurface formations|
|US7942197||21 Abr 2006||17 May 2011||Shell Oil Company||Methods and systems for producing fluid from an in situ conversion process|
|US7942203||4 Ene 2010||17 May 2011||Shell Oil Company||Thermal processes for subsurface formations|
|US7950453||18 Abr 2008||31 May 2011||Shell Oil Company||Downhole burner systems and methods for heating subsurface formations|
|US8057765||24 Sep 2009||15 Nov 2011||Sesqui Mining, Llc||Methods for constructing underground borehole configurations and related solution mining methods|
|US8220539||9 Oct 2009||17 Jul 2012||Shell Oil Company||Controlling hydrogen pressure in self-regulating nuclear reactors used to treat a subsurface formation|
|US8256512||9 Oct 2009||4 Sep 2012||Shell Oil Company||Movable heaters for treating subsurface hydrocarbon containing formations|
|US8261832||9 Oct 2009||11 Sep 2012||Shell Oil Company||Heating subsurface formations with fluids|
|US8267170||9 Oct 2009||18 Sep 2012||Shell Oil Company||Offset barrier wells in subsurface formations|
|US8267185||9 Oct 2009||18 Sep 2012||Shell Oil Company||Circulated heated transfer fluid systems used to treat a subsurface formation|
|US8281861||9 Oct 2009||9 Oct 2012||Shell Oil Company||Circulated heated transfer fluid heating of subsurface hydrocarbon formations|
|US8327932||9 Abr 2010||11 Dic 2012||Shell Oil Company||Recovering energy from a subsurface formation|
|US8353347||9 Oct 2009||15 Ene 2013||Shell Oil Company||Deployment of insulated conductors for treating subsurface formations|
|US8434555||9 Abr 2010||7 May 2013||Shell Oil Company||Irregular pattern treatment of a subsurface formation|
|US8448707||28 May 2013||Shell Oil Company||Non-conducting heater casings|
|US8678513||29 Jul 2009||25 Mar 2014||Solvay Chemicals, Inc.||Traveling undercut solution mining systems and methods|
|US8851170||9 Abr 2010||7 Oct 2014||Shell Oil Company||Heater assisted fluid treatment of a subsurface formation|
|US8881806||9 Oct 2009||11 Nov 2014||Shell Oil Company||Systems and methods for treating a subsurface formation with electrical conductors|
|US8899691||29 Jul 2011||2 Dic 2014||Sesqui Mining, Llc||Methods for constructing underground borehole configurations and related solution mining methods|
|US9022118||9 Oct 2009||5 May 2015||Shell Oil Company||Double insulated heaters for treating subsurface formations|
|US9051829||9 Oct 2009||9 Jun 2015||Shell Oil Company||Perforated electrical conductors for treating subsurface formations|
|US20020053431 *||24 Abr 2001||9 May 2002||Wellington Scott Lee||In situ thermal processing of a hydrocarbon containing formation to produce a selected ratio of components in a gas|
|US20020077515 *||24 Abr 2001||20 Jun 2002||Wellington Scott Lee||In situ thermal processing of a hydrocarbon containing formation to produce hydrocarbons having a selected carbon number range|
|US20040140096 *||24 Oct 2003||22 Jul 2004||Sandberg Chester Ledlie||Insulated conductor temperature limited heaters|
|US20040144541 *||24 Oct 2003||29 Jul 2004||Picha Mark Gregory||Forming wellbores using acoustic methods|
|US20040145969 *||24 Oct 2003||29 Jul 2004||Taixu Bai||Inhibiting wellbore deformation during in situ thermal processing of a hydrocarbon containing formation|
|US20040177966 *||24 Oct 2003||16 Sep 2004||Vinegar Harold J.||Conductor-in-conduit temperature limited heaters|
|US20050051327 *||23 Abr 2004||10 Mar 2005||Vinegar Harold J.||Thermal processes for subsurface formations|
|Clasificación de EE.UU.||299/5, 166/369, 299/17|
|9 Ago 2001||AS||Assignment|
Owner name: ANADARKO PETROLEUM COMPANY, TEXAS
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:BROWN, NEIL;NESSELRODE, KARL;REEL/FRAME:012079/0869
Effective date: 20010809