US20030116791A1 - Semiconductor device with vertical electron injection and method for making same - Google Patents

Semiconductor device with vertical electron injection and method for making same Download PDF

Info

Publication number
US20030116791A1
US20030116791A1 US10/276,691 US27669102A US2003116791A1 US 20030116791 A1 US20030116791 A1 US 20030116791A1 US 27669102 A US27669102 A US 27669102A US 2003116791 A1 US2003116791 A1 US 2003116791A1
Authority
US
United States
Prior art keywords
thin film
electronic component
monocrystalline thin
monocrystalline
recess
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US10/276,691
Inventor
Robert Baptist
Fabrice Letertre
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Original Assignee
Commissariat a lEnergie Atomique CEA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Commissariat a lEnergie Atomique CEA filed Critical Commissariat a lEnergie Atomique CEA
Assigned to COMMISSARIAT A L'ENERGIE ATOMIQUE reassignment COMMISSARIAT A L'ENERGIE ATOMIQUE ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: BAPTIST, ROBERT, LETERTRE, FABRICE
Publication of US20030116791A1 publication Critical patent/US20030116791A1/en
Priority to US11/561,685 priority Critical patent/US7820461B2/en
Abandoned legal-status Critical Current

Links

Images

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/02Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
    • H01L33/20Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies with a particular shape, e.g. curved or truncated substrate
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J31/00Cathode ray tubes; Electron beam tubes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/005Processes
    • H01L33/0062Processes for devices with an active region comprising only III-V compounds
    • H01L33/0066Processes for devices with an active region comprising only III-V compounds with a substrate not being a III-V compound
    • H01L33/007Processes for devices with an active region comprising only III-V compounds with a substrate not being a III-V compound comprising nitride compounds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/005Processes
    • H01L33/0093Wafer bonding; Removal of the growth substrate
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/02Structural details or components not essential to laser action
    • H01S5/0206Substrates, e.g. growth, shape, material, removal or bonding
    • H01S5/0207Substrates having a special shape
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2924/00Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/0001Technical content checked by a classifier
    • H01L2924/0002Not covered by any one of groups H01L24/00, H01L24/00 and H01L2224/00
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S3/00Lasers, i.e. devices using stimulated emission of electromagnetic radiation in the infrared, visible or ultraviolet wave range
    • H01S3/09Processes or apparatus for excitation, e.g. pumping
    • H01S3/0955Processes or apparatus for excitation, e.g. pumping using pumping by high energy particles
    • H01S3/0959Processes or apparatus for excitation, e.g. pumping using pumping by high energy particles by an electron beam
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/02Structural details or components not essential to laser action
    • H01S5/0206Substrates, e.g. growth, shape, material, removal or bonding
    • H01S5/021Silicon based substrates
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/02Structural details or components not essential to laser action
    • H01S5/0206Substrates, e.g. growth, shape, material, removal or bonding
    • H01S5/0215Bonding to the substrate
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/02Structural details or components not essential to laser action
    • H01S5/0206Substrates, e.g. growth, shape, material, removal or bonding
    • H01S5/0217Removal of the substrate
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/04Processes or apparatus for excitation, e.g. pumping, e.g. by electron beams
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/04Processes or apparatus for excitation, e.g. pumping, e.g. by electron beams
    • H01S5/042Electrical excitation ; Circuits therefor
    • H01S5/0425Electrodes, e.g. characterised by the structure
    • H01S5/04254Electrodes, e.g. characterised by the structure characterised by the shape
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/10Construction or shape of the optical resonator, e.g. extended or external cavity, coupled cavities, bent-guide, varying width, thickness or composition of the active region
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/30Structure or shape of the active region; Materials used for the active region
    • H01S5/3013AIIIBV compounds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/30Structure or shape of the active region; Materials used for the active region
    • H01S5/32Structure or shape of the active region; Materials used for the active region comprising PN junctions, e.g. hetero- or double- heterostructures
    • H01S5/323Structure or shape of the active region; Materials used for the active region comprising PN junctions, e.g. hetero- or double- heterostructures in AIIIBV compounds, e.g. AlGaAs-laser, InP-based laser
    • H01S5/32308Structure or shape of the active region; Materials used for the active region comprising PN junctions, e.g. hetero- or double- heterostructures in AIIIBV compounds, e.g. AlGaAs-laser, InP-based laser emitting light at a wavelength less than 900 nm
    • H01S5/32341Structure or shape of the active region; Materials used for the active region comprising PN junctions, e.g. hetero- or double- heterostructures in AIIIBV compounds, e.g. AlGaAs-laser, InP-based laser emitting light at a wavelength less than 900 nm blue laser based on GaN or GaP

Definitions

  • the present invention relates to a semiconductor device with vertical electron injection. It also concerns a manufacturing method for such a device.
  • the semiconductor device with vertical electron injection is produced in an active layer in semiconducting material with a small gap or a big gap.
  • the invention proves to be of particular interest in the case of an active layer in semiconducting material with a big gap.
  • Semiconductors are characterised by their forbidden band or gap separating the last filled states of the valence band and the following empty states in the conduction band.
  • semiconductors with a small gap, such as silicon and germanium, and semiconductors with a big gap such as, for example, GaN and SiC.
  • epitaxy of GaN on sapphire is made particularly delicate because of the difference in lattice structure existing between GaN and sapphire (of the order of 16%). Therefore, obtaining crystalline layers of sufficiently high quality for producing optoelectronic devices requires perfecting sophisticated epitaxy methods.
  • the use of the sapphire substrate is essentially explained by its structural and chemical compatibility with GaN, its low cost and its availability under the form of large diameter substrate.
  • the electrically insulating property of sapphire requires production, in the epitaxial GaN, of horizontal components with electrodes located in the front face.
  • the other method used for retail components is that of GaN on a solid SiC substrate.
  • SiC substrates remain rare and very expensive. This is the method developed and marketed by the company of Cree Research Inc., profiting from the advantage it has of retailing the major part of SiC substrates.
  • the interest of solid SiC for epitaxy and the production of devices with a GaN base is evident.
  • the low difference in lattice structure (3.5%) between SiC and GaN makes it possible to simplify epitaxy methods while still producing layers with high crystalline quality.
  • the use of a conducting SiC substrate makes it possible to produce a vertical component for passing current (that is, with an electrode on each face).
  • This structure enables production of components of smaller size than those produced on an insulating substrate, which is of interest from the economic point of view.
  • SiC with its high thermal conductivity, makes it possible to adjust or lower the component temperature during its operation. This is an important point as far as performance, service life and reliability are concerned.
  • the optoelectronic components produced on the above-mentioned materials therefore have either a lateral structure (with two electrodes located on the front face of the substrate), or a vertical structure with one electrode on the active layer (generally in GaN) and another electrode on the rear face of the solid substrate (in SiC, for example).
  • a lateral structure with two electrodes located on the front face of the substrate
  • a vertical structure with one electrode on the active layer (generally in GaN) and another electrode on the rear face of the solid substrate (in SiC, for example).
  • the size of the chip evidently varies. From a strictly economic point of view, the production of a vertically operational chip is clearly more advantageous because it makes it possible to produce more compact devices.
  • the first method depends on eliminating the sapphire substrate and producing a thick epitaxy of GaN (greater than 100 ⁇ m) at the rear face in order to obtain a self-supporting rigid membrane. This again means producing a GaN substrate. This approach makes it possible to produce a device with vertical operation and to dissipate the generated heat.
  • the second method depends on eliminating the sapphire substrate and adhering the active layer onto an electrically and thermally conducting sole (adhesion on a copper substrate, for example). Thus it would be possible to obtain a vertically operational device enabling dissipation of the produced heat.
  • the SiC approach represents a very promising future for developing optoelectronic branches with a GaN base.
  • the trend for growth techniques other than those on SiC is to produce devices with vertical current flow and to eliminate the generated heat as much as possible during operation of the device, whatsoever the epitaxial support.
  • this substrate In the case of epitaxy on sapphire, this substrate only plays the role of epitaxial support and no longer limits the operation of devices because it can be eliminated.
  • the present invention proposes a new device that can be less costly than prior art solutions, for obtaining a semiconductor device with vertical electron injection.
  • a first aim of the invention consists of a vertical electron injection semiconductor device comprising a support substrate, a structure comprising at least one monocrystalline thin film transferred onto the support substrate and integral with the support substrate, at least one electronic component, the support substrate comprising at least one recess enabling electric or electronic access to the electronic component, through the monocrystalline thin film, the device also comprising means enabling vertical electron injection into the electronic component.
  • the structure may comprise at least one active layer formed by crystal growth of semiconducting material on the monocrystalline thin film, the electronic component being produced in said active layer.
  • the epitaxial active layer is homogeneous or heterogeneous depending on the applications.
  • the monocrystalline thin film can be an active layer, from which the electronic component is formed.
  • the device can furthermore comprise a layer called an adhesion layer, situated between the support substrate and the structure and making it possible to solidarise the monocrystalline thin film on the support, the adhesion layer allowing electric or electronic access to the electronic component.
  • This adhesion layer can be in SiO 2 .
  • the adhesion layer is insulating and comprises at least one recess enabling electric or electronic access to the electronic component.
  • the adhesion layer can also be conducting or semiconducting.
  • the monocrystalline thin film can comprise at least one recess enabling direct electric or electronic access to the electronic component.
  • the support substrate can be in silicon, in SiC, in A 1 N, in sapphire or in GaN
  • the monocrystalline thin film can be in SiC, in silicon, in GaN, in sapphire or in ZnO
  • the active layer can comprise a semiconducting material selected from among the group consisting of SiC, GaN, the compounds III-V and their derivatives, and diamond.
  • the electronic component can comprise at least one junction produced from two semiconductors of the same nature or of different natures. It can comprise at least one metal-semiconductor type junction. Furthermore, it can comprise at least one stack of the semiconductor-metal-oxide type.
  • the means enabling vertical electron injection into the electronic component comprise an electrode set on the electronic component and an electrode set under the electronic component, in said recess enabling access to the electronic component.
  • an earth can be provided in said recess, in contact with said electrode set under the component in order to constitute a heat sink.
  • the electron injection being achieved by means of an electron beam directed onto the electronic component by passing through said recess, the means enabling vertical electron injection comprise a conducting coating for guiding the electrons towards the electronic component.
  • the recess in the support substrate comprises cells enabling electric or electronic access to electronic components formed from the structure.
  • the electronic component can be selected from among the group consisting of light emitters, light detectors, power electronic components and diodes.
  • the structure can be chosen to be vacuum sealed.
  • the electronic component is a component able to emit a light beam in response to an electron beam received
  • the monocrystalline thin film can be such that it allows passage of said electron beam.
  • the structure can form a membrane that is deformable under the effect of a pressure difference, said electronic component being a component providing a signal representative of the deformation undergone by the membrane.
  • a second aim of the invention consists of a manufacturing method for such a semiconducting device with vertical electron injection, characterised in that it comprises the following stages:
  • production of means allowing vertical electron injection into the electronic component.
  • the method can furthermore comprise a stage for formation of at least one active layer by crystal growth of semiconducting material on the monocrystalline thin film, the electronic component being produced in said active layer, the crystal growth being produced before or after transfer. If the thin film is an active layer, the electronic component can be formed from this monocrystalline thin film.
  • the electronic component can be partly made before the transfer; especially when the active layer is produced before the transfer.
  • the transfer stage of the monocrystalline thin film comprises the following operations:
  • the transfer of said monocrystalline thin film is carried out through the intermediary of an adhesion layer.
  • This adhesion layer can be in SiO 2 .
  • the production of means enabling vertical electron injection into the electronic component comprises depositing an electrode on the electronic component and depositing an electrode under the electronic component, in said recess enabling access to the electronic component.
  • the method can then comprise the deposit of an earth in said recess, in contact with said electrode set under the component in order to constitute a heat sink.
  • the method comprises the deposit of a conducting coating able to guide an electron beam directed onto the electronic component passing through said recess.
  • the method also comprises the formation of cells prolonging the recess in the support substrate to enable electric or electronic access to the electronic components formed from the structure.
  • FIGS. 1A to 1 E show the main stages of a manufacturing method of a semiconductor device with vertical electron injection according to the invention
  • FIG. 2 shows, in cross-section, another semiconductor device with vertical electron injection according to the invention
  • FIG. 3 shows the device of FIG. 2 installed on equipment provided with a cathode with micro-points
  • FIG. 4 shows, in cross-section, another semiconductor device with vertical electron injection and with cell structure, according to the invention.
  • the manufacture of a semiconductor device with vertical electron injection comprises the transfer of a monocrystalline thin film of very high crystalline quality (semiconducting or not, insulating or electrically conducting) onto the front face of a substrate, semiconducting or not.
  • This transfer can be carried out through the intermediary of an insulating thin film, metallic or semiconducting.
  • the required active layer or layers are obtained by crystal growth before or after transfer.
  • One or several electronic components are thus formed.
  • the rear face of the substrate is machined or micro-machined locally in order to create a membrane.
  • the monocrystalline thin film can possibly be thinned.
  • the active layer and the monocrystalline thin film form a single and same layer.
  • the electronic component or components can be manufactured before or after the formation of the membrane. Nonetheless, it is preferable to manufacture the electronic components before forming the membrane in order to relax the mechanic stresses in the device during manufacture.
  • transfer of the monocrystalline thin film can be carried out using the method known under the name of Smartcut® and described in particular in the document FR-A-2 681 472 (corresponding to the U.S. Pat. No. 5,374,564).
  • FIGS. 1A and 1B show this transfer method.
  • FIG. 1A shows the fixation of a first substrate 1 in SiC onto a second substrate 2 in silicon, with an adhesion interface.
  • the substrate 1 possesses a layer 3 of SiO 2 on its junction face with the substrate 2 .
  • An ionic implantation produced through this face has made it possible to create a layer of micro-cavities 5 separating the substrate 1 into a thin film 7 and a remainder part 9 of the substrate.
  • the substrate 2 also possesses a layer 4 of SiO 2 on its junction face with the substrate 1 . Nonetheless, the two opposite faces can be of different nature on condition that adhesion is possible.
  • the junction of the two substrates is obtained by molecular adhesion.
  • the fracture of the substrate 1 along the zone of micro-cavities 5 can be obtained by means of heat treatment and/or by application of mechanical stresses.
  • the fracture provides the structure shown in FIG. 1B and constituted of a support substrate 2 in silicon supporting first of all a layer 6 in SiO 2 (formed by the combination of layers 3 and 4 ), and then a layer 7 of SiC. It would also be possible to transfer the layer 7 from its initial substrate 9 to the support substrate 2 via at least one intermediary substrate.
  • a thin film 10 of GaN is then epitaxied on the layer 7 of SiC with its free face prepared for this. This is shown in FIG. 1C.
  • the layer 10 of GaN constitutes the active layer in which the electronic component can be formed.
  • the layer 10 could have been produced before transfer.
  • the transfer of the structure formed by the layer 7 and the layer 10 must be made either by means of an intermediary support, or directly, the layer 7 needing to be eliminated for certain applications.
  • FIG. 1D shows that the recess 11 made in the substrate 2 is prolonged into the layer 6 of SiO 2 , as far as the layer 7 of SiC. This layer 7 could also possibly be recessed.
  • the first case concerns an electron excitation through vertical passage of the current into the component formed in the active layer by two electrodes, one of these electrodes being deposited on the top of the component and the other being deposited under the component.
  • the second case involves electron excitation by vertical passage of current in the component following electron injection by electron bombardment on the rear face of the device.
  • the first case requires the presence of electrodes on top of and underneath the device as shown in FIG. 1E.
  • An electrode 13 has been formed on the front face of the electronic component produced in the layer 10 .
  • a conducting material 14 is deposited on the rear face of the device. It covers the recessed rear face of the substrate 2 as well as the apparent face of the layer 7 of SiC.
  • the electric connection with the component is obtained through the layer 7 of SiC which is electrically conducting.
  • the recess is filled with a conducting material advantageously forming a heat sink 15 , making it possible to evacuate the heat produced by the device during operation.
  • An electrode 16 is deposited on the heat sink 15 to allow joining an electric connection wire. In the absence of the material 15 , the second electrode is formed by the conducting material 14 .
  • FIG. 2 shows, in cross section, a device 20 according to the invention and with electron excitation by vertical passage of current through the device, the current being due to electron bombardment directed towards the rear face of the device.
  • the device 20 is produced as above, from a stacked structure comprising a substrate 21 in silicon, a layer 22 of SiO 2 , and a thin film 23 of SiC.
  • a recess 24 is made in the rear face of the substrate 21 as far as the thin film 23 of SiC.
  • a layer of GaN has been epitaxied from the layer 23 of SiC and an electronic component 25 has been formed from the layer of GaN.
  • the component 25 is a laser source. It is equipped on two opposite flanks with mirrors 26 and 27 enabling optical amplification. The production of such mirrors is known to those skilled in the art.
  • the recess is of truncated shape with circular or polygonal cross sections.
  • a conducting layer 28 is deposited on the rear face of the device. This conducting layer 28 acts as an anode relative to the electron beam and must allow it to pass.
  • a conducting layer 28 ′ can be deposited on the component 25 and connected electrically to the conducting layer 28 in order to define a potential and to direct the injected electrons more efficiently towards the rear face of the device.
  • the component 25 will emit a laser beam 31 .
  • FIG. 3 shows, as an example of an embodiment, the device 20 shown in FIG. 2 installed on equipment 40 provided with a micro-point cathode.
  • the equipment 40 comprises a tubular chamber 41 with one end 42 provided with a tip 43 through which the vacuum is formed in the chamber 41 .
  • the tip 43 can contain a getter 44 .
  • the other end 45 of the chamber 41 comprises an opening which is closed by the device 20 , the recess 24 of the device 20 (see FIG. 2) being turned towards the inside of the chamber 41 .
  • the equipment 40 comprises a cathode with micro-points 46 supplied live in appropriate fashion relative to the earth.
  • the conducting layer 28 of the device 20 is also connected to the earth.
  • the cathode with micropoints 46 emits an electron beam 30 in the direction of the device 20 .
  • the micro-points can be brought to ⁇ 10 kV, the extraction grid of the cathode to about 50 or 100 V above this voltage, that is to ⁇ 9950 or ⁇ 9900 V.
  • the conducting layer 28 of the rear face of the device 20 ensures that the voltage is well defined and that therefore the electrons will be certain to enter the recess of the device, crossing the thin film in SiC and penetrating the component 25 .
  • the thin film 23 of the device 20 provided with the conducting layer 28 and the component 25 plays the role of a sealed vacuum membrane in this application. It is permeable to electrons and serves as epitaxial substrate.
  • the device has the advantages of compactness and of integration into a piece of equipment.
  • FIG. 4 shows, in cross section, another semiconductor device with vertical electron injection and cell structure, according to the invention.
  • the device of FIG. 4 comprises, superposed, a substrate 51 in silicon, a layer 52 of SiO 2 and a thin film 53 of SiC.
  • a layer of GaN has been epitaxied from the layer of SiC and two electronic components 54 and 55 (laser sources here) have been formed from the layer of GaN.
  • a recess 56 has been made from the rear face of the substrate 51 .
  • This recess is prolonged by two cells 57 and 58 revealing parts of the thin film 53 of SiC situated under the components 54 and 55 .
  • This strengthener enables the membrane, constituted by the free part of the thin film 53 , to be made mechanically rigid.
  • the cross section of the cells can be hexagonal just like a honeycomb element.
  • the invention has the following advantages. It makes it possible to manufacture a semiconductor device, especially with a big gap, electronic or optoelectronic, on a low cost substrate, for example in silicon, using well known techniques for transfer of layers, deep engraving and metallizing. It allows integration of an electronic device on a monocrystalline membrane. It enables the creation of a vacuum sealed membrane, permeable to an electron beam focussed on the rear face of the membrane whose front face supports one or several electronic components. It enables the production of vertical semiconductor devices on a substrate which is not necessarily an electrical conductor throughout the whole of its volume. The substrate can possibly possess an integrated heat sink. The manufacture of vertical structure components allows a reduction in the size of components.
  • the invention makes it possible to manufacture vertical semiconductor devices with low electrical resistance through replacement of the solid substrate by a semiconducting thin film. It makes it possible to integrate a laser on a micro-machined torch through the intermediary of a membrane which assures a three-fold role: sealing, permeability to electrons, and epitaxial substrate for the GaN.

Abstract

The present invention relates to a semiconductor device with vertical electron injection, comprising a support substrate (2), a structure comprising at least one monocrystalline thin film (7) transferred onto the support substrate and integral with the support substrate, and at least one electronic component, the support substrate (2) comprising at least one recess enabling electric or electronic access to the electronic component, through the monocrystalline thin film, the device also comprising means (13, 14) enabling vertical electron injection into the electronic component.

Description

    TECHNICAL FIELD
  • The present invention relates to a semiconductor device with vertical electron injection. It also concerns a manufacturing method for such a device. [0001]
  • The semiconductor device with vertical electron injection is produced in an active layer in semiconducting material with a small gap or a big gap. However, the invention proves to be of particular interest in the case of an active layer in semiconducting material with a big gap. [0002]
  • STATE OF PRIOR ART
  • Semiconductors are characterised by their forbidden band or gap separating the last filled states of the valence band and the following empty states in the conduction band. Among the semiconductors, one can distinguish between semiconductors with a small gap, such as silicon and germanium, and semiconductors with a big gap such as, for example, GaN and SiC. [0003]
  • At present it is extremely difficult or even impossible to obtain solid substrates in a semiconductor with a big gap. In the case of GaN for example, no solid substrate of electronic quality exists despite intense research carried out in this field. On the other hand, hetero-epitaxial GaN on a solid substrate in sapphire or in SiC exists. This technique was developed for production of blue diode type optoelectronic components. [0004]
  • Nonetheless, epitaxy of GaN on sapphire is made particularly delicate because of the difference in lattice structure existing between GaN and sapphire (of the order of 16%). Therefore, obtaining crystalline layers of sufficiently high quality for producing optoelectronic devices requires perfecting sophisticated epitaxy methods. The use of the sapphire substrate is essentially explained by its structural and chemical compatibility with GaN, its low cost and its availability under the form of large diameter substrate. The electrically insulating property of sapphire requires production, in the epitaxial GaN, of horizontal components with electrodes located in the front face. [0005]
  • The other method used for retail components is that of GaN on a solid SiC substrate. SiC substrates remain rare and very expensive. This is the method developed and marketed by the company of Cree Research Inc., profiting from the advantage it has of retailing the major part of SiC substrates. The interest of solid SiC for epitaxy and the production of devices with a GaN base is evident. First of all, the low difference in lattice structure (3.5%) between SiC and GaN makes it possible to simplify epitaxy methods while still producing layers with high crystalline quality. Furthermore, the use of a conducting SiC substrate makes it possible to produce a vertical component for passing current (that is, with an electrode on each face). This structure enables production of components of smaller size than those produced on an insulating substrate, which is of interest from the economic point of view. Moreover, the use of SiC, with its high thermal conductivity, makes it possible to adjust or lower the component temperature during its operation. This is an important point as far as performance, service life and reliability are concerned. [0006]
  • Other methods are also being studied, but their present state of development restricts them to laboratory use. The general approach consists of using a substrate of solid silicon in order to benefit from the low cost and large size of these substrates. Thus one can obtain GaN on SiC covering silicon. These techniques, developed under laboratory conditions, rely on the use of a film of epitaxial cubic SiC either on an SOI substrate or directly on a solid silicon substrate. This SiC layer must make it possible to facilitate epitaxy by reducing the difference in the lattice parameter between the GaN and the silicon, that is to arrive at a configuration of epitaxial GaN on SiC. Apart from the problem of producing epitaxial GaN, the first epitaxy of SiC poses significant technical problems. However, the growth of GaN on such a structure is of particular interest because it would make it possible to obtain GaN with cubic structure (sapphire obtains a hexagonal structure) which, because of its properties, is interesting for optoelectronic applications. For the moment this method is still at the research stage. [0007]
  • Finally, a more recent method relates to the direct epitaxy of GaN on silicon, without any buffer film of SiC. For this, one uses silicon ([0008] 111). This approach, based on a principle equivalent to that adopted for epitaxy on sapphire, suffers at present from being far behind, relative to other techniques. Nonetheless, correct control of the material silicon makes it possible to envisage using electrically insulating or conducting epitaxial support substrates, leaving a certain freedom for the operating mode of the epitaxied device (vertical or horizontal).
  • The optoelectronic components produced on the above-mentioned materials therefore have either a lateral structure (with two electrodes located on the front face of the substrate), or a vertical structure with one electrode on the active layer (generally in GaN) and another electrode on the rear face of the solid substrate (in SiC, for example). According to the structure adopted, or imposed by the nature of the substrate, the size of the chip evidently varies. From a strictly economic point of view, the production of a vertically operational chip is clearly more advantageous because it makes it possible to produce more compact devices. [0009]
  • Furthermore, the nature of the substrate chosen for epitaxy has an influence on the performance of the device via the problem of heat dissipation during operation. From this point of view, solid SiC has a considerable advantage. The limitations recognised concerning devices produced on GaN supported by sapphire, are under study at present. Two methods are described in publications concerning the solution of this problem for sapphire. Each depends on eliminating the sapphire substrate after producing active epitaxial layers. [0010]
  • The first method depends on eliminating the sapphire substrate and producing a thick epitaxy of GaN (greater than 100 μm) at the rear face in order to obtain a self-supporting rigid membrane. This again means producing a GaN substrate. This approach makes it possible to produce a device with vertical operation and to dissipate the generated heat. [0011]
  • The second method depends on eliminating the sapphire substrate and adhering the active layer onto an electrically and thermally conducting sole (adhesion on a copper substrate, for example). Thus it would be possible to obtain a vertically operational device enabling dissipation of the produced heat. [0012]
  • Thus it can be understood that the SiC approach represents a very promising future for developing optoelectronic branches with a GaN base. The trend for growth techniques other than those on SiC is to produce devices with vertical current flow and to eliminate the generated heat as much as possible during operation of the device, whatsoever the epitaxial support. In the case of epitaxy on sapphire, this substrate only plays the role of epitaxial support and no longer limits the operation of devices because it can be eliminated. [0013]
  • DESCRIPTION OF THE INVENTION
  • The present invention proposes a new device that can be less costly than prior art solutions, for obtaining a semiconductor device with vertical electron injection. [0014]
  • A first aim of the invention consists of a vertical electron injection semiconductor device comprising a support substrate, a structure comprising at least one monocrystalline thin film transferred onto the support substrate and integral with the support substrate, at least one electronic component, the support substrate comprising at least one recess enabling electric or electronic access to the electronic component, through the monocrystalline thin film, the device also comprising means enabling vertical electron injection into the electronic component. [0015]
  • The structure may comprise at least one active layer formed by crystal growth of semiconducting material on the monocrystalline thin film, the electronic component being produced in said active layer. The epitaxial active layer is homogeneous or heterogeneous depending on the applications. The monocrystalline thin film can be an active layer, from which the electronic component is formed. [0016]
  • Possibly, the device can furthermore comprise a layer called an adhesion layer, situated between the support substrate and the structure and making it possible to solidarise the monocrystalline thin film on the support, the adhesion layer allowing electric or electronic access to the electronic component. This adhesion layer can be in SiO[0017] 2.
  • Possibly, the adhesion layer is insulating and comprises at least one recess enabling electric or electronic access to the electronic component. The adhesion layer can also be conducting or semiconducting. [0018]
  • The monocrystalline thin film can comprise at least one recess enabling direct electric or electronic access to the electronic component. [0019]
  • Advantageously, the support substrate can be in silicon, in SiC, in A[0020] 1N, in sapphire or in GaN, the monocrystalline thin film can be in SiC, in silicon, in GaN, in sapphire or in ZnO, and the active layer can comprise a semiconducting material selected from among the group consisting of SiC, GaN, the compounds III-V and their derivatives, and diamond.
  • The electronic component can comprise at least one junction produced from two semiconductors of the same nature or of different natures. It can comprise at least one metal-semiconductor type junction. Furthermore, it can comprise at least one stack of the semiconductor-metal-oxide type. [0021]
  • According to an embodiment of the invention, the means enabling vertical electron injection into the electronic component comprise an electrode set on the electronic component and an electrode set under the electronic component, in said recess enabling access to the electronic component. In this case, an earth can be provided in said recess, in contact with said electrode set under the component in order to constitute a heat sink. [0022]
  • According to another embodiment of the invention, the electron injection being achieved by means of an electron beam directed onto the electronic component by passing through said recess, the means enabling vertical electron injection comprise a conducting coating for guiding the electrons towards the electronic component. [0023]
  • According to a further embodiment of the invention, the recess in the support substrate comprises cells enabling electric or electronic access to electronic components formed from the structure. [0024]
  • The electronic component can be selected from among the group consisting of light emitters, light detectors, power electronic components and diodes. [0025]
  • The structure can be chosen to be vacuum sealed. In this case, if the electronic component is a component able to emit a light beam in response to an electron beam received, the monocrystalline thin film can be such that it allows passage of said electron beam. The structure can form a membrane that is deformable under the effect of a pressure difference, said electronic component being a component providing a signal representative of the deformation undergone by the membrane. [0026]
  • A second aim of the invention consists of a manufacturing method for such a semiconducting device with vertical electron injection, characterised in that it comprises the following stages: [0027]
  • transfer of the monocrystalline thin film onto a first face of the support substrate, [0028]
  • production of at least one electronic component from the structure, [0029]
  • formation of at least one recess from a second face of the substrate to allow electric or electronic access to the electronic component through the monocrystalline thin film, [0030]
  • production of means allowing vertical electron injection into the electronic component. [0031]
  • The method can furthermore comprise a stage for formation of at least one active layer by crystal growth of semiconducting material on the monocrystalline thin film, the electronic component being produced in said active layer, the crystal growth being produced before or after transfer. If the thin film is an active layer, the electronic component can be formed from this monocrystalline thin film. [0032]
  • Possibly, the electronic component can be partly made before the transfer; especially when the active layer is produced before the transfer. [0033]
  • According to a particularly advantageous embodiment of the invention, the transfer stage of the monocrystalline thin film comprises the following operations: [0034]
  • definition of said monocrystalline thin film in a substrate of monocrystalline material by introducing gaseous species into this substrate of monocrystalline material in order to create a fracture zone, the monocrystalline thin film being located between one face of the substrate in monocrystalline material and the cleavage zone, [0035]
  • solidarisation of said monocrystalline thin film on the first face of the support substrate, [0036]
  • fracture separation of the monocrystalline thin film from the rest of the substrate of monocrystalline material, the separation being produced before or after the solidarisation operation, obtained for example by molecular adhesion. [0037]
  • Preferably, the transfer of said monocrystalline thin film is carried out through the intermediary of an adhesion layer. This adhesion layer can be in SiO[0038] 2.
  • According to an application variant, the production of means enabling vertical electron injection into the electronic component comprises depositing an electrode on the electronic component and depositing an electrode under the electronic component, in said recess enabling access to the electronic component. The method can then comprise the deposit of an earth in said recess, in contact with said electrode set under the component in order to constitute a heat sink. [0039]
  • According to another application variant, the method comprises the deposit of a conducting coating able to guide an electron beam directed onto the electronic component passing through said recess. [0040]
  • According to a further application variant, the method also comprises the formation of cells prolonging the recess in the support substrate to enable electric or electronic access to the electronic components formed from the structure.[0041]
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • The invention will be understood better and other advantages and particularities will become clear by reading the description below, evidently given as a non-limiting example, and accompanied by the attached drawings in which: [0042]
  • FIGS. 1A to [0043] 1E show the main stages of a manufacturing method of a semiconductor device with vertical electron injection according to the invention,
  • FIG. 2 shows, in cross-section, another semiconductor device with vertical electron injection according to the invention, [0044]
  • FIG. 3 shows the device of FIG. 2 installed on equipment provided with a cathode with micro-points, [0045]
  • FIG. 4 shows, in cross-section, another semiconductor device with vertical electron injection and with cell structure, according to the invention.[0046]
  • DETAILED DESCRIPTION OF EMBODIMENTS ACCORDING TO THE INVENTION
  • The manufacture of a semiconductor device with vertical electron injection according to the invention comprises the transfer of a monocrystalline thin film of very high crystalline quality (semiconducting or not, insulating or electrically conducting) onto the front face of a substrate, semiconducting or not. This transfer can be carried out through the intermediary of an insulating thin film, metallic or semiconducting. The required active layer or layers are obtained by crystal growth before or after transfer. One or several electronic components are thus formed. The rear face of the substrate is machined or micro-machined locally in order to create a membrane. The monocrystalline thin film can possibly be thinned. [0047]
  • According to an embodiment of the invention, the active layer and the monocrystalline thin film form a single and same layer. [0048]
  • The electronic component or components can be manufactured before or after the formation of the membrane. Nonetheless, it is preferable to manufacture the electronic components before forming the membrane in order to relax the mechanic stresses in the device during manufacture. [0049]
  • Advantageously, transfer of the monocrystalline thin film can be carried out using the method known under the name of Smartcut® and described in particular in the document FR-A-2 681 472 (corresponding to the U.S. Pat. No. 5,374,564). FIGS. 1A and 1B show this transfer method. [0050]
  • FIG. 1A shows the fixation of a [0051] first substrate 1 in SiC onto a second substrate 2 in silicon, with an adhesion interface. The substrate 1 possesses a layer 3 of SiO2 on its junction face with the substrate 2. An ionic implantation produced through this face has made it possible to create a layer of micro-cavities 5 separating the substrate 1 into a thin film 7 and a remainder part 9 of the substrate. In this example, the substrate 2 also possesses a layer 4 of SiO2 on its junction face with the substrate 1. Nonetheless, the two opposite faces can be of different nature on condition that adhesion is possible.
  • Advantageously, the junction of the two substrates is obtained by molecular adhesion. Once the junction has been established, one proceeds to the fracture of the [0052] substrate 1 along the zone of micro-cavities 5. This fracture can be obtained by means of heat treatment and/or by application of mechanical stresses. The fracture provides the structure shown in FIG. 1B and constituted of a support substrate 2 in silicon supporting first of all a layer 6 in SiO2 (formed by the combination of layers 3 and 4), and then a layer 7 of SiC. It would also be possible to transfer the layer 7 from its initial substrate 9 to the support substrate 2 via at least one intermediary substrate.
  • A [0053] thin film 10 of GaN is then epitaxied on the layer 7 of SiC with its free face prepared for this. This is shown in FIG. 1C. The layer 10 of GaN constitutes the active layer in which the electronic component can be formed.
  • As above-mentioned, the [0054] layer 10 could have been produced before transfer. In this case, the transfer of the structure formed by the layer 7 and the layer 10 must be made either by means of an intermediary support, or directly, the layer 7 needing to be eliminated for certain applications.
  • In order to obtain electric or electronic access to the component produced in the [0055] layer 10, a recess is made starting from the rear face of the substrate 2. FIG. 1D shows that the recess 11 made in the substrate 2 is prolonged into the layer 6 of SiO2, as far as the layer 7 of SiC. This layer 7 could also possibly be recessed.
  • Taking into account the different applications aimed at by the invention, at least two cases of electron excitation can be distinguished. The first case concerns an electron excitation through vertical passage of the current into the component formed in the active layer by two electrodes, one of these electrodes being deposited on the top of the component and the other being deposited under the component. The second case involves electron excitation by vertical passage of current in the component following electron injection by electron bombardment on the rear face of the device. [0056]
  • The first case requires the presence of electrodes on top of and underneath the device as shown in FIG. 1E. An [0057] electrode 13 has been formed on the front face of the electronic component produced in the layer 10. A conducting material 14 is deposited on the rear face of the device. It covers the recessed rear face of the substrate 2 as well as the apparent face of the layer 7 of SiC. The electric connection with the component is obtained through the layer 7 of SiC which is electrically conducting. Possibly, the recess is filled with a conducting material advantageously forming a heat sink 15, making it possible to evacuate the heat produced by the device during operation. An electrode 16 is deposited on the heat sink 15 to allow joining an electric connection wire. In the absence of the material 15, the second electrode is formed by the conducting material 14.
  • FIG. 2 shows, in cross section, a [0058] device 20 according to the invention and with electron excitation by vertical passage of current through the device, the current being due to electron bombardment directed towards the rear face of the device.
  • The [0059] device 20 is produced as above, from a stacked structure comprising a substrate 21 in silicon, a layer 22 of SiO2, and a thin film 23 of SiC. A recess 24 is made in the rear face of the substrate 21 as far as the thin film 23 of SiC. A layer of GaN has been epitaxied from the layer 23 of SiC and an electronic component 25 has been formed from the layer of GaN. In the example shown, the component 25 is a laser source. It is equipped on two opposite flanks with mirrors 26 and 27 enabling optical amplification. The production of such mirrors is known to those skilled in the art.
  • In this embodiment, the recess is of truncated shape with circular or polygonal cross sections. In order to guide an [0060] electron beam 30, arriving on the rear face of the device, towards the component 25, a conducting layer 28 is deposited on the rear face of the device. This conducting layer 28 acts as an anode relative to the electron beam and must allow it to pass. Possibly, a conducting layer 28′ can be deposited on the component 25 and connected electrically to the conducting layer 28 in order to define a potential and to direct the injected electrons more efficiently towards the rear face of the device. In response to the excitation by the electron beam 30, the component 25 will emit a laser beam 31.
  • FIG. 3 shows, as an example of an embodiment, the [0061] device 20 shown in FIG. 2 installed on equipment 40 provided with a micro-point cathode. The equipment 40 comprises a tubular chamber 41 with one end 42 provided with a tip 43 through which the vacuum is formed in the chamber 41. The tip 43 can contain a getter 44. The other end 45 of the chamber 41 comprises an opening which is closed by the device 20, the recess 24 of the device 20 (see FIG. 2) being turned towards the inside of the chamber 41.
  • Inside the [0062] chamber 41, the equipment 40 comprises a cathode with micro-points 46 supplied live in appropriate fashion relative to the earth. The conducting layer 28 of the device 20 is also connected to the earth. When in use, the cathode with micropoints 46 emits an electron beam 30 in the direction of the device 20.
  • As an example, the micro-points can be brought to −10 kV, the extraction grid of the cathode to about 50 or 100 V above this voltage, that is to −9950 or −9900 V. The conducting [0063] layer 28 of the rear face of the device 20 ensures that the voltage is well defined and that therefore the electrons will be certain to enter the recess of the device, crossing the thin film in SiC and penetrating the component 25.
  • The [0064] thin film 23 of the device 20 provided with the conducting layer 28 and the component 25 plays the role of a sealed vacuum membrane in this application. It is permeable to electrons and serves as epitaxial substrate. The device has the advantages of compactness and of integration into a piece of equipment.
  • FIG. 4 shows, in cross section, another semiconductor device with vertical electron injection and cell structure, according to the invention. [0065]
  • The device of FIG. 4 comprises, superposed, a [0066] substrate 51 in silicon, a layer 52 of SiO2 and a thin film 53 of SiC. A layer of GaN has been epitaxied from the layer of SiC and two electronic components 54 and 55 (laser sources here) have been formed from the layer of GaN.
  • A [0067] recess 56 has been made from the rear face of the substrate 51. This recess is prolonged by two cells 57 and 58 revealing parts of the thin film 53 of SiC situated under the components 54 and 55. Between the cells 57 and 58 there exists a part 59 of the initial structure acting as strengthener. This strengthener enables the membrane, constituted by the free part of the thin film 53, to be made mechanically rigid. Thus one avoids risks of the membrane bursting when put under vacuum in equipment such as that of FIG. 3. It is to be noted that the cross section of the cells can be hexagonal just like a honeycomb element.
  • In particular, the invention has the following advantages. It makes it possible to manufacture a semiconductor device, especially with a big gap, electronic or optoelectronic, on a low cost substrate, for example in silicon, using well known techniques for transfer of layers, deep engraving and metallizing. It allows integration of an electronic device on a monocrystalline membrane. It enables the creation of a vacuum sealed membrane, permeable to an electron beam focussed on the rear face of the membrane whose front face supports one or several electronic components. It enables the production of vertical semiconductor devices on a substrate which is not necessarily an electrical conductor throughout the whole of its volume. The substrate can possibly possess an integrated heat sink. The manufacture of vertical structure components allows a reduction in the size of components. The invention makes it possible to manufacture vertical semiconductor devices with low electrical resistance through replacement of the solid substrate by a semiconducting thin film. It makes it possible to integrate a laser on a micro-machined torch through the intermediary of a membrane which assures a three-fold role: sealing, permeability to electrons, and epitaxial substrate for the GaN. [0068]

Claims (40)

1. Semiconductor device with vertical electron injection comprising a support substrate (2, 21, 51), a structure comprising at least one monocrystalline thin film (7, 23, 53) transferred onto the support substrate and integral with the support substrate, at least one electronic component (25, 541 55), the support substrate comprising at least one recess (11, 24, 56) enabling electric or electronic access to the electronic component through the monocrystalline thin film, the device also comprising means enabling vertical electron injection into the vertical component.
2. Device according to claim 1, characterised in that the structure comprises at least one active layer (10) formed by crystal growth of the semiconducting material on the monocrystalline thin film (7, 23, 53), the electronic component (25, 54, 55) being produced in said active layer (10).
3. Device according to claim 1, characterised in that the monocrystalline thin film is an active layer from which the electronic component is produced.
4. Device according to any one of claims 1 to 3, characterised in that it furthermore comprises a layer (6, 22, 52), called adhesion layer, situated between the support substrate (2, 21, 51) and the structure and enabling solidarisation of the monocrystalline thin film on the support, the adhesion layer enabling electric or electronic access to the electronic component.
5. Device according to claim 4, characterised in that the adhesion layer (22) is insulating and comprises at least one recess enabling electric or electronic access to the electronic component (25).
6. Device according to claim 4, characterised in that the adhesion layer is conducting or semiconducting.
7. Device according to any one of claims 1 to 6, characterised in that the monocrystalline thin film comprises at least one recess enabling direct electric or electronic access to the electronic component.
8. Device according to claim 1, characterised in that the support substrate (2, 21, 51) is in a material selected from the group consisting of silicon, SiC, AlN, sapphire and GaN.
9. Device according to claim 1, characterised in that the monocrystalline thin film (7, 23, 53) is in a material selected from the group consisting of SiC, silicon, GaN, sapphire or ZnO.
10. Device according to claim 5, characterised in that the adhesion layer (6, 22, 52) is in SiO2.
11. Device according to claim 2, characterised in that the active layer (10) comprises a semiconducting material chosen among SiC, GaN, the compounds III-V and their derivatives, and diamond.
12. Device according to any one of claims 1 to 11, characterised in that the electronic component comprises at least one junction produced from two semiconductors of the same nature or of different natures.
13. Device according to any one of claims 1 to 11, characterised in that the electronic component comprises at least one junction of the metal-semiconductor type.
14. Device according to any one of claims 1 to 11, characterised in that the electronic component comprises at least one stack of the semiconductor-metal-oxide type.
15. Device according to any one of claims 1 to 14, characterised in that the means enabling vertical electron injection into the electronic component comprise an electrode (13) set on the electronic component and an electrode (14) set under the electronic component, in said recess enabling access to the electronic component.
16. Device according to claim 15, characterised in that an earth (15) is provided in said recess, in contact with said electrode (14) set under the component in order to constitute a heat sink.
17. Device according to any one of claims 1 to 14, characterised in that electron injection is carried out by means of an electron beam (30) directed onto the electronic component (25) passing in said recess (24), the means enabling vertical electron injection comprising a conducting coating (28) for guiding the electrons towards the electronic component (25).
18. Device according to any one of claims 1 to 17, characterised in that the recess (56) of the support substrate (51) comprises cells (57, 58) enabling electric or electronic access to the electronic components (54, 55) produced from the structure.
19. Device according to claim 1, characterised in that said electronic component is selected from the group consisting of light emitters, light detectors, power electronic components and diodes.
20. Device according to any one of claims 1 to 7, characterised in that the structure is vacuum sealed.
21. Device according claim 20, characterised in that the electronic component (25), being a component able to emit a light beam in response to a received electron beam (30), the monocrystalline thin film (23) is such that it allows passage of said electron beam.
22. Device according to claim 20, characterised in that the structure forms a membrane deformable under the effect of a pressure difference, said electronic component being a component providing a signal indicative of the deformation undergone by the membrane.
23. Manufacturing method for a semiconductor device with vertical electron injection according to claim 1, characterised in that it comprises the following stages:
transfer of the monocrystalline thin film (7) onto a first face of the support substrate (2),
production of at least one electronic component from the structure,
formation of at least one recess (11) from a second face of the substrate (2) to enable electric or electronic access to the electronic component through the monocrystalline thin film (7),
production of means (13, 14) allowing vertical electron injection into the electronic component.
24. Method according to claim 23, characterised in that it furthermore comprises a stage of formation of at least one active layer (10) by crystal growth of semiconducting material on the monocrystalline thin film (7), the electronic component being produced in said active layer, the crystal growth being before or after transfer.
25. Method according to claim 23, characterised in that the monocrystalline thin film is an active layer, the electronic component being produced from this monocrystalline thin film
26. Method according to claim 23, characterised in that the transfer stage for the monocrystalline thin film (7) comprises the following operations:
definition of said monocrystalline thin film (7) in a substrate of monocrystalline material (1) by introducing gaseous species into this substrate of monocrystalline material in order to create a fracture zone (5), the monocrystalline thin film (7) being located between one face of the substrate in monocrystalline material (1) and the cleavage zone (5),
solidarisation of said monocrystalline thin film on the first face of the support substrate (2),
fracture separation of the monocrystalline thin film (7) from the rest (9) of the substrate (1) of monocrystalline material, the separation being produced before or after the solidarisation operation.
27. Method according to any one of claims 23 to 26, characterised in that the transfer of said monocrystalline thin film is carried out through the intermediary of an adhesion layer (6).
28. Method according to claim 26, characterised in that the solidarisation of said thin film is obtained by molecular adhesion.
29. Method according to any one of claims 23 to 28, characterised in that the transfer stage of the monocrystalline thin film (7) is formed on a first face of a support substrate in silicon (2).
30. Method according to any one of claims 23 to 28, characterised in that the transfer stage consists of transferring a thin film of monocrystalline SiC (7).
31. Method according to claim 27, characterised in that the transfer of said monocrystalline thin film (7) is carried out with the intermediary of an adhesion layer (6) in SiO2.
32. Method according to claim 24, characterised in that the active layer (10) is formed by crystal growth on a layer of semiconducting material selected from the group consisting of SiC, GaN, the compounds III-V and their derivatives, and diamond.
33. Method according to any one of claims 23 to 32, characterised in that the production of means allowing vertical electron injection into the electronic component comprises the deposit of an electrode (13) on the electronic component and the deposit of an electrode (14) under the electronic component, in said recess (11) enabling access to the electronic component.
34. Method according to claim 33, characterised in that it comprises deposit of an earth (15) in said recess (11), in contact with said electrode (14) set under the component in order to constitute a heat sink.
35. Method according to any one of claims 23 to 32, characterised in that it comprises the deposit of a conducting coating (28) capable of guiding an electron beam (30) directed onto the electronic component (25) passing in said recess (24).
36. Method according to any one of claims 23 to 32, characterised in that it also comprises the formation of cells (57, 58) prolonging the recess (56) of the support substrate (51) to allow electric or electronic access to the electronic components (54, 55) formed from the structure.
37. Method according to any one of claims 23 to 32, characterised in that the formation stage of at least one electronic component consists of producing a component selected from the group consisting of light emitters, light detectors, power electronic components and diodes.
38. Method according to any one of claims 23 to 32, characterised in that the transfer stage of a monocrystalline thin film (23) consists of transferring a monocrystalline thin film such that the structure is vacuum sealed.
39. Method according to claim 38, characterised in that the stage for transferring a monocrystalline thin film (23) consists of transferring a monocrystalline thin film able to be crossed by an electron beam.
40. Method according to claim 38, characterised in that the stage for transferring a monocrystalline thin film consists of transferring a monocrystalline thin film such that the structure forms a membrane deformable under the effect of a difference of pressure, the stage of forming at least one electronic component comprising the production of a component providing a signal indicative of the deformation undergone by the membrane.
US10/276,691 2000-05-26 2001-05-23 Semiconductor device with vertical electron injection and method for making same Abandoned US20030116791A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US11/561,685 US7820461B2 (en) 2000-05-26 2006-11-20 Semiconductor device with vertical electron injection and its manufacturing method

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0006761A FR2809534B1 (en) 2000-05-26 2000-05-26 SEMICONDUCTOR DEVICE WITH VERTICAL ELECTRONIC INJECTION AND MANUFACTURING METHOD THEREOF
FR00/06761 2000-05-26

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US11/561,685 Division US7820461B2 (en) 2000-05-26 2006-11-20 Semiconductor device with vertical electron injection and its manufacturing method

Publications (1)

Publication Number Publication Date
US20030116791A1 true US20030116791A1 (en) 2003-06-26

Family

ID=8850659

Family Applications (2)

Application Number Title Priority Date Filing Date
US10/276,691 Abandoned US20030116791A1 (en) 2000-05-26 2001-05-23 Semiconductor device with vertical electron injection and method for making same
US11/561,685 Expired - Fee Related US7820461B2 (en) 2000-05-26 2006-11-20 Semiconductor device with vertical electron injection and its manufacturing method

Family Applications After (1)

Application Number Title Priority Date Filing Date
US11/561,685 Expired - Fee Related US7820461B2 (en) 2000-05-26 2006-11-20 Semiconductor device with vertical electron injection and its manufacturing method

Country Status (4)

Country Link
US (2) US20030116791A1 (en)
EP (1) EP1284025A2 (en)
FR (1) FR2809534B1 (en)
WO (1) WO2001093310A2 (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040046179A1 (en) * 2001-03-09 2004-03-11 Johannes Baur Radiation-emitting semiconductor component and method for producing the semiconductor component
US20040130002A1 (en) * 2001-02-23 2004-07-08 Nitronex Corporation Gallium nitride material devices and methods of forming the same
US20040150013A1 (en) * 2003-01-22 2004-08-05 Renesas Technology Corp. Semiconductor device
US20080067562A1 (en) * 2006-09-15 2008-03-20 Kabushiki Kaisha Toshiba Semiconductor device and manufacturing method thereof
US20090309113A1 (en) * 2006-04-25 2009-12-17 Osram Opto Semiconductors Gmbh Optoelectronic Semiconductor Component
US20180267238A1 (en) * 2015-11-06 2018-09-20 Nanjing University Of Posts And Telecommunications Integrated photonic device comprising hollowed silicon substrate-based led and optical waveguide and manufacturing method thereof
WO2022223214A1 (en) * 2021-04-21 2022-10-27 Robert Bosch Gmbh Gan semiconductor device on a silicon substrate with a back-side trench and method for producing same

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6611002B2 (en) * 2001-02-23 2003-08-26 Nitronex Corporation Gallium nitride material devices and methods including backside vias
GB2467911B (en) * 2009-02-16 2013-06-05 Rfmd Uk Ltd A semiconductor structure and a method of manufacture thereof
US20110017972A1 (en) * 2009-07-22 2011-01-27 Rfmd (Uk) Limited Light emitting structure with integral reverse voltage protection
US8138068B2 (en) * 2010-08-11 2012-03-20 International Business Machines Corporation Method to form nanopore array
FR2977069B1 (en) 2011-06-23 2014-02-07 Soitec Silicon On Insulator METHOD FOR MANUFACTURING A SEMICONDUCTOR STRUCTURE USING TEMPORARY COLLAGE
US9093420B2 (en) 2012-04-18 2015-07-28 Rf Micro Devices, Inc. Methods for fabricating high voltage field effect transistor finger terminations
US9124221B2 (en) 2012-07-16 2015-09-01 Rf Micro Devices, Inc. Wide bandwidth radio frequency amplier having dual gate transistors
US9917080B2 (en) 2012-08-24 2018-03-13 Qorvo US. Inc. Semiconductor device with electrical overstress (EOS) protection
US9142620B2 (en) 2012-08-24 2015-09-22 Rf Micro Devices, Inc. Power device packaging having backmetals couple the plurality of bond pads to the die backside
US9147632B2 (en) 2012-08-24 2015-09-29 Rf Micro Devices, Inc. Semiconductor device having improved heat dissipation
US8988097B2 (en) 2012-08-24 2015-03-24 Rf Micro Devices, Inc. Method for on-wafer high voltage testing of semiconductor devices
US9202874B2 (en) 2012-08-24 2015-12-01 Rf Micro Devices, Inc. Gallium nitride (GaN) device with leakage current-based over-voltage protection
WO2014035794A1 (en) 2012-08-27 2014-03-06 Rf Micro Devices, Inc Lateral semiconductor device with vertical breakdown region
US9070761B2 (en) 2012-08-27 2015-06-30 Rf Micro Devices, Inc. Field effect transistor (FET) having fingers with rippled edges
US9325281B2 (en) 2012-10-30 2016-04-26 Rf Micro Devices, Inc. Power amplifier controller
US9455327B2 (en) 2014-06-06 2016-09-27 Qorvo Us, Inc. Schottky gated transistor with interfacial layer
US9536803B2 (en) 2014-09-05 2017-01-03 Qorvo Us, Inc. Integrated power module with improved isolation and thermal conductivity
US10062684B2 (en) 2015-02-04 2018-08-28 Qorvo Us, Inc. Transition frequency multiplier semiconductor device
US10615158B2 (en) 2015-02-04 2020-04-07 Qorvo Us, Inc. Transition frequency multiplier semiconductor device
US9960127B2 (en) 2016-05-18 2018-05-01 Macom Technology Solutions Holdings, Inc. High-power amplifier package
US10134658B2 (en) 2016-08-10 2018-11-20 Macom Technology Solutions Holdings, Inc. High power transistors

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3853650A (en) * 1973-02-12 1974-12-10 Honeywell Inc Stress sensor diaphragms over recessed substrates
US4279690A (en) * 1975-10-28 1981-07-21 Texas Instruments Incorporated High-radiance emitters with integral microlens
US4797890A (en) * 1985-12-24 1989-01-10 Mitsubishi Cable Industries, Ltd. Semiconductor light emitting device with vertical light emission
US5259247A (en) * 1991-02-28 1993-11-09 Robert Bosch Gmbh Sensor
US5383993A (en) * 1989-09-01 1995-01-24 Nippon Soken Inc. Method of bonding semiconductor substrates
US5455203A (en) * 1992-02-20 1995-10-03 Seiko Instruments Inc. Method of adjusting the pressure detection value of semiconductor pressure switches
US5701321A (en) * 1995-04-28 1997-12-23 Mitsubishi Denki Kabushiki Kaisha Semiconductor laser producing short wavelength light
US5864171A (en) * 1995-03-30 1999-01-26 Kabushiki Kaisha Toshiba Semiconductor optoelectric device and method of manufacturing the same
US6139760A (en) * 1997-12-19 2000-10-31 Electronics And Telecommunications Research Institute Short-wavelength optoelectronic device including field emission device and its fabricating method
US6593159B1 (en) * 1997-04-09 2003-07-15 Matsushita Electric Industrial Co., Ltd. Semiconductor substrate, semiconductor device and method of manufacturing the same

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5932073B2 (en) * 1979-06-01 1984-08-06 三菱電機株式会社 Light emitting diode and its manufacturing method
FR2484710A1 (en) * 1980-06-13 1981-12-18 Thomson Csf Light emitting diode used for coupling bidirectional optical fibres - provides low attenuation when feeding light into outer annular zone of fibre
JPS57190371A (en) * 1981-05-20 1982-11-22 Nippon Telegr & Teleph Corp <Ntt> Semiconductor photoelectric converter and manufacture thereof
WO1987006060A1 (en) * 1986-03-28 1987-10-08 Fairchild Semiconductor Corporation Method for joining two or more wafers and the resulting structure
FR2681472B1 (en) * 1991-09-18 1993-10-29 Commissariat Energie Atomique PROCESS FOR PRODUCING THIN FILMS OF SEMICONDUCTOR MATERIAL.
EP0539741B1 (en) * 1991-09-30 2003-01-15 Canon Kabushiki Kaisha Anodic bonding process with light irradiation
JPH0690014A (en) * 1992-07-22 1994-03-29 Mitsubishi Electric Corp Thin solar cell and its production, etching method and automatic etching device, and production of semiconductor device
JPH06196727A (en) * 1992-12-08 1994-07-15 Terumo Corp Photoelectric conversion device
JPH08152356A (en) * 1994-11-30 1996-06-11 Terumo Corp Infrared sensor
US6239033B1 (en) * 1998-05-28 2001-05-29 Sony Corporation Manufacturing method of semiconductor device
US5933750A (en) * 1998-04-03 1999-08-03 Motorola, Inc. Method of fabricating a semiconductor device with a thinned substrate
US6744800B1 (en) * 1998-12-30 2004-06-01 Xerox Corporation Method and structure for nitride based laser diode arrays on an insulating substrate
US7601271B2 (en) 2005-11-28 2009-10-13 S.O.I.Tec Silicon On Insulator Technologies Process and equipment for bonding by molecular adhesion

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3853650A (en) * 1973-02-12 1974-12-10 Honeywell Inc Stress sensor diaphragms over recessed substrates
US4279690A (en) * 1975-10-28 1981-07-21 Texas Instruments Incorporated High-radiance emitters with integral microlens
US4797890A (en) * 1985-12-24 1989-01-10 Mitsubishi Cable Industries, Ltd. Semiconductor light emitting device with vertical light emission
US5383993A (en) * 1989-09-01 1995-01-24 Nippon Soken Inc. Method of bonding semiconductor substrates
US5259247A (en) * 1991-02-28 1993-11-09 Robert Bosch Gmbh Sensor
US5455203A (en) * 1992-02-20 1995-10-03 Seiko Instruments Inc. Method of adjusting the pressure detection value of semiconductor pressure switches
US5864171A (en) * 1995-03-30 1999-01-26 Kabushiki Kaisha Toshiba Semiconductor optoelectric device and method of manufacturing the same
US5701321A (en) * 1995-04-28 1997-12-23 Mitsubishi Denki Kabushiki Kaisha Semiconductor laser producing short wavelength light
US6593159B1 (en) * 1997-04-09 2003-07-15 Matsushita Electric Industrial Co., Ltd. Semiconductor substrate, semiconductor device and method of manufacturing the same
US6139760A (en) * 1997-12-19 2000-10-31 Electronics And Telecommunications Research Institute Short-wavelength optoelectronic device including field emission device and its fabricating method

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7233028B2 (en) 2001-02-23 2007-06-19 Nitronex Corporation Gallium nitride material devices and methods of forming the same
US20040130002A1 (en) * 2001-02-23 2004-07-08 Nitronex Corporation Gallium nitride material devices and methods of forming the same
US20070295985A1 (en) * 2001-02-23 2007-12-27 Nitronex Corporation Gallium nitride material devices and methods of forming the same
US8138511B2 (en) 2001-03-09 2012-03-20 Osram Ag Radiation-emitting semiconductor component and method for producing the semiconductor component
US20080179380A1 (en) * 2001-03-09 2008-07-31 Johannes Baur Radiation-emitting semiconductor component and method for producing the semiconductor component
US20040046179A1 (en) * 2001-03-09 2004-03-11 Johannes Baur Radiation-emitting semiconductor component and method for producing the semiconductor component
US20040150013A1 (en) * 2003-01-22 2004-08-05 Renesas Technology Corp. Semiconductor device
WO2005022639A3 (en) * 2003-08-25 2006-01-19 Nitronex Corp Gallium nitride material devices and methods of forming the same
WO2005022639A2 (en) * 2003-08-25 2005-03-10 Nitronex Corporation Gallium nitride material devices and methods of forming the same
US20090309113A1 (en) * 2006-04-25 2009-12-17 Osram Opto Semiconductors Gmbh Optoelectronic Semiconductor Component
US8093607B2 (en) 2006-04-25 2012-01-10 Osram Opto Semiconductors Gmbh Optoelectronic semiconductor component
US20080067562A1 (en) * 2006-09-15 2008-03-20 Kabushiki Kaisha Toshiba Semiconductor device and manufacturing method thereof
US7888713B2 (en) 2006-09-15 2011-02-15 Kabushiki Kaisha Toshiba Semiconductor device and manufacturing method thereof
US20180267238A1 (en) * 2015-11-06 2018-09-20 Nanjing University Of Posts And Telecommunications Integrated photonic device comprising hollowed silicon substrate-based led and optical waveguide and manufacturing method thereof
US10386574B2 (en) * 2015-11-06 2019-08-20 Nanjing University Of Posts And Telecommunications Integrated photonic device comprising hollowed silicon substrate-based LED and optical waveguide and manufacturing method thereof
WO2022223214A1 (en) * 2021-04-21 2022-10-27 Robert Bosch Gmbh Gan semiconductor device on a silicon substrate with a back-side trench and method for producing same

Also Published As

Publication number Publication date
EP1284025A2 (en) 2003-02-19
WO2001093310A2 (en) 2001-12-06
US7820461B2 (en) 2010-10-26
WO2001093310A9 (en) 2002-05-30
US20070093009A1 (en) 2007-04-26
FR2809534B1 (en) 2005-01-14
FR2809534A1 (en) 2001-11-30
WO2001093310A3 (en) 2002-03-14

Similar Documents

Publication Publication Date Title
US7820461B2 (en) Semiconductor device with vertical electron injection and its manufacturing method
US6611002B2 (en) Gallium nitride material devices and methods including backside vias
KR100279737B1 (en) Short-wavelength photoelectric device composed of field emission device and optical device and fabrication method thereof
US7233028B2 (en) Gallium nitride material devices and methods of forming the same
KR101178361B1 (en) Method for the production of semi-conductor chips
KR100483049B1 (en) A METHOD OF PRODUCING VERTICAL GaN LIGHT EMITTING DIODES
KR100495215B1 (en) VERTICAL GaN LIGHT EMITTING DIODE AND METHOD OF PRODUCING THE SAME
US8217498B2 (en) Gallium nitride semiconductor device on SOI and process for making same
JP2007067418A (en) Group iii nitride light emitting device having light emitting region with double hetero-structure
TWI520175B (en) Methods for fabricating compound semiconductor cyrstal and electronic device, and semiconductor substrate
JPH11154648A (en) Manufacture of plural semiconductor chip
KR20090008401A (en) Composite substrate, and method for the production of a composite substrate
JPH11238913A (en) Semiconductor light-emitting device chip
EP1320902B1 (en) The semiconductor led device and producing method
JP2728190B2 (en) Semiconductor laser device
US9048343B2 (en) Semiconductor light emitting device and method of manufacturing the same
WO2004018743A1 (en) Diboride single crystal substrate, semiconductor device using this and its manufacturing method
JP3713124B2 (en) Semiconductor light emitting device and manufacturing method thereof
JP2013118272A (en) Method of manufacturing group iii nitride semiconductor device
CN116632100A (en) Integrated device of LED and detector and preparation method thereof
JP2005206400A (en) Method for growing group iii nitride crystal, group iii nitride crystal, semiconductor device, and system
JPH11121792A (en) Infrared emitting diode and manufacture thereof
JP2004179433A (en) Semiconductor laser element and manufacturing method therefor

Legal Events

Date Code Title Description
AS Assignment

Owner name: COMMISSARIAT A L'ENERGIE ATOMIQUE, FRANCE

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:BAPTIST, ROBERT;LETERTRE, FABRICE;REEL/FRAME:013692/0860

Effective date: 20021107

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION