Búsqueda Imágenes Maps Play YouTube Noticias Gmail Drive Más »
Iniciar sesión
Usuarios de lectores de pantalla: deben hacer clic en este enlace para utilizar el modo de accesibilidad. Este modo tiene las mismas funciones esenciales pero funciona mejor con el lector.

Patentes

  1. Búsqueda avanzada de patentes
Número de publicaciónUS20030121627 A1
Tipo de publicaciónSolicitud
Número de solicitudUS 10/005,882
Fecha de publicación3 Jul 2003
Fecha de presentación3 Dic 2001
Fecha de prioridad3 Dic 2001
También publicado comoWO2003048453A1
Número de publicación005882, 10005882, US 2003/0121627 A1, US 2003/121627 A1, US 20030121627 A1, US 20030121627A1, US 2003121627 A1, US 2003121627A1, US-A1-20030121627, US-A1-2003121627, US2003/0121627A1, US2003/121627A1, US20030121627 A1, US20030121627A1, US2003121627 A1, US2003121627A1
InventoresSheng-Hsin Hu, Shan Chen, K.B. Makoui
Cesionario originalSheng-Hsin Hu, Shan Chen, K.B. Makoui
Exportar citaBiBTeX, EndNote, RefMan
Enlaces externos: USPTO, Cesión de USPTO, Espacenet
Tissue products having reduced lint and slough
US 20030121627 A1
Resumen
A method for forming a tissue product that is soft and produces relatively low levels of lint and slough is provided. The method includes providing a liquid furnish of cellulosic fibers and forming a multi-layered wet web therefrom. At least one latex having a glass transition temperature less than about 30° C. is applied to the furnish, wet web, or combinations thereof in an amount less than about 60 pounds per ton of the dry weight of the cellulosic fibers. The web is then dried such that at least one outer layer of the dried web contains the latex-treated cellulosic fibers.
Imágenes(4)
Previous page
Next page
Reclamaciones(47)
What is claimed is:
1. A method for forming a tissue product comprising:
providing a liquid furnish of cellulosic fibers;
forming a multi-layered wet web from said liquid furnish of cellulosic fibers;
applying a debonder to said furnish, said wet web, or combinations thereof;
applying at least one latex having a glass transition temperature less than about 30° C. to said liquid furnish, said wet web, or combinations thereof, said latex being applied in an amount less than about 60 pounds per ton of the dry weight of said cellulosic fibers; and
drying said wet web, wherein at least one outer layer of said dried web contains said latex-treated cellulosic fibers.
2. A method as defined in claim 1, wherein the glass transition temperature of said latex is greater than about −25° C.
3. A method as defined in claim 1, wherein the glass transition temperature of said latex is between about −15° C. to about 15° C.
4. A method as defined in claim 1, wherein the glass transition temperature of said latex is between about −10° C. to about 0° C.
5. A method as defined in claim 1, wherein said latex is selected from the group consisting of styrene-butadiene copolymers, polyvinyl acetate homopolymers, vinyl-acetate ethylene copolymers, vinyl-acetate acrylic copolymers, ethylene-vinyl chloride copolymers, ethylene-vinyl chloride-vinyl acetate terpolymers, acrylic polyvinyl chloride polymers, acrylic polymers, and nitrile polymers.
6. A method as defined in claim 1, wherein said latex is applied in an amount of between about 1 to about 40 pounds per ton of the dry weight of said cellulosic fibers.
7. A method as defined in claim 1, wherein said latex is applied in an amount of between about 1 to about 20 pounds per ton of the dry weight of said cellulosic fibers.
8. A method as defined in claim 1, wherein said debonder is applied prior to said latex.
9. A method as defined in claim 1, further comprising applying a wet strength agent to said furnish, said wet web, or combinations thereof;
10. A method as defined in claim 9, wherein said wet strength agent is applied prior to said latex.
11. A method as defined in claim 9, wherein said wet strength agent includes a temporary wet strength agent.
12. A method as defined in claim 11, wherein said temporary wet strength agent comprises a cationic polyacrylamide polymer.
13. A method as defined in claim 11, wherein said temporary wet strength agent is applied in an amount between about 1 to about 60 pounds per ton of the dry weight of said cellulosic fibers.
14. A method as defined in claim 9, wherein said wet strength agent includes a permanent wet strength agent.
15. A method as defined in claim 14, wherein said permanent wet strength agent comprises a cationic polyamide polymer.
16. A method as defined in claim 14, wherein said permanent wet strength agent is applied in an amount between about 1 to about 20 pounds per ton of the dry weight of said cellulosic fibers.
17. A method as defined in claim 1, wherein said debonder includes an imidazoline quaternary compound.
18. A method as defined in claim 1, wherein said debonder includes an ester-functional quaternary ammonium compound.
19. A method as defined in claim 1, wherein said debonder is applied in an amount between about 1 to about 30 pounds per ton of the dry weight of said cellulosic fibers.
20. A method as defined in claim 1, wherein greater than about 60% of said latex is retained on said cellulosic fibers.
21. A method as defined in claim 1, wherein between about 75% to about 90% of said latex is retained on said cellulosic fibers.
22. A method as defined in claim 1, wherein said latex is sprayed onto said wet web.
23. A method for forming a tissue product comprising:
providing a liquid furnish of cellulosic fibers;
forming a multi-layered wet web from said liquid furnish of cellulosic fibers;
applying a debonder to said furnish, said wet web, or combinations thereof, in an amount between about 1 to about 30 pounds per ton of said cellulosic fibers;
applying a wet strength agent to said furnish, said wet web, or combinations thereof, said wet strength agent being selected from the group consisting of temporary wet strength agents, permanent wet strength agents, and combinations thereof;
applying at least one latex to said to said furnish, said wet web, or combinations thereof in an amount between about 1 to about 40 pounds per ton of the dry weight of said cellulosic fibers, said latex having a glass transition temperature less than about 30° C. and greater than about −25° C.; and
drying said wet web, wherein at least one outer layer of said dried web contains said latex-treated cellulosic fibers.
24. A method as defined in claim 23, wherein the glass transition temperature of said latex is between about −15° C. to about 15° C.
25. A method as defined in claim 23, wherein the glass transition temperature of said latex is between about −10° C. to about 0° C.
26. A method as defined in claim 23, wherein said latex is selected from the group consisting of styrene-butadiene copolymers, polyvinyl acetate homopolymers, vinyl-acetate ethylene copolymers, vinyl-acetate acrylic copolymers, ethylene-vinyl chloride copolymers, ethylene-vinyl chloride-vinyl acetate terpolymers, acrylic polyvinyl chloride polymers, acrylic polymers, and nitrile polymers.
27. A method as defined in claim 23, wherein said debonder is applied prior to said latex.
28. A method as defined in claim 23, wherein said wet strength agent is applied prior to said latex.
29. A method as defined in claim 23, wherein greater than about 60% of said latex is retained on said cellulosic fibers.
30. A method as defined in claim 23, wherein between about 75% to about 90% of said latex is retained on said cellulosic fibers.
31. A method as defined in claim 23, wherein said latex is sprayed onto said wet web.
32. A method as defined in claim 23, wherein said latex is applied in an amount between about 1 to about 20 pounds per ton of the dry weight of said cellulosic fibers.
33. A tissue product having a basis weight less than about 80 grams per square meter, said tissue product comprising a multi-layered paper web having at least one outer layer that defines an outer surface of the tissue product, said outer layer being formed from cellulosic fibers, said cellulosic fibers being applied with a debonder, a wet strength agent, and at least one latex having a glass transition temperature less than about 30° C. and greater than about −25° C., said latex comprising less than about 3% of the dry weight of said outer layer.
34. A tissue product as defined in claim 33, wherein said latex comprises between about 0.05% to about 2% of the dry weight of said outer layer.
35. A tissue product as defined in claim 33, wherein said latex comprises between about 0.05% to about 1% of the dry weight of said outer layer.
36. A tissue product as defined in claim 33, wherein the glass transition temperature of said latex is between about −15° C. to about 15° C.
37. A tissue product as defined in claim 33, wherein the glass transition temperature of said latex is between about −10° C. to about 0° C.
38. A tissue product as defined in claim 33, wherein the remaining layers of said multi-layered paper web are substantially free of said latex.
39. A facial tissue as defined in claim 33.
40. A bath tissue as defined in claim 33.
41. A bath tissue as defined in claim 40, wherein said wet strength agent consists essentially of a temporary wet strength agent.
42. A paper towel as defined in claim 33.
43. A tissue product having a basis weight less than about 80 grams per square meter, said tissue product comprising a multi-layered paper web having at least one outer layer that defines an outer surface of the tissue product, said outer layer being formed from cellulosic fibers, said cellulosic fibers being applied with a debonder, a wet strength agent, and at least one latex having a glass transition temperature less than about 30° C. and greater than about −25° C., said latex comprising less than about 3% of the tissue product.
44. A tissue product as defined in claim 43, wherein said latex comprises between about 0.05% to about 2% of the dry weight of said outer layer.
45. A tissue product as defined in claim 43, wherein said latex comprises between about 0.05% to about 1% of the dry weight of said outer layer.
46. A tissue product as defined in claim 43, wherein the glass transition temperature of said latex is between about −15° C. to about 15° C.
47. A tissue product as defined in claim 43, wherein the glass transition temperature of said latex is between about −10° C. to about 0° C.
Descripción
    BACKGROUND OF THE INVENTION
  • [0001]
    Tissue products, such as facial tissues, paper towels, bath tissues, sanitary napkins, and other similar products, are designed to include several important properties. For example, the products should have good bulk, a soft feel, and should have good strength. Unfortunately, however, when steps are taken to increase one property of the product, other characteristics of the product are often adversely affected.
  • [0002]
    For example, during a papermaking process, it is common to use various resins to increase the wet strength of the web. Cationic resins, for example, are often used because they are believed to more readily bond to the anionically charged cellulosic fibers. In addition, resins that are anionic in nature have also been utilized. For example, U.S. Pat. No. 3,844,880 to Meisel, Jr., et al. describes anionic styrene-butadiene latexes that are adhered to the anionic cellulosic fibers with a deposition aid.
  • [0003]
    Although strength resins can increase the strength of the web, they also tend to stiffen the web, which is often undesired by consumers. Thus, various methods are often used to counteract this stiffness and to soften the product. For example, chemical debonders can be utilized to reduce fiber bonding and thereby increase softness.
  • [0004]
    Nevertheless, reducing fiber bonding with a chemical debonder can sometimes adversely affect the strength of the tissue product. For example, hydrogen bonds between adjacent fibers can be broken by such chemical debonders, as well as by mechanical forces of a papermaking process. Consequently, such debonding results in loosely bound fibers that extend from the surface of the tissue product. During processing and/or use, these loosely bound fibers can be freed from the tissue product, thereby creating lint, which is defined as individual airborne fibers and fiber fragments. Moreover, papermaking processes may also create zones of fibers that are poorly bound to each other but not to adjacent zones of fibers. As a result, during use, certain shear forces can liberate the weakly bound zones from the remaining fibers, thereby resulting in slough, i.e., bundles or pills on surfaces, such as skin or fabric. As such, the use of such debonders can often result in a much weaker paper product during use that exhibits substantial amounts of lint and slough.
  • [0005]
    As such, a need currently exists for a tissue product that is strong, soft, and that also has low lint and slough.
  • SUMMARY OF THE INVENTION
  • [0006]
    In accordance with one embodiment of the present invention, a method is provided for forming a tissue product. The method includes providing a liquid furnish of cellulosic fibers and forming a multi-layered wet web from the liquid furnish of cellulosic fibers. At least one latex (e.g., nonionic or anionic) is applied to the furnish, wet web (e.g., sprayed), or combinations thereof in an amount less than about 60 pounds per ton of the dry weight of the cellulosic fibers, in some embodiments, between about 1 to about 40 pounds per ton of the dry weight of the cellulosic fibers, and in some embodiments, between about 1 to about 20 pounds per metric ton of the dry weight of the cellulosic fibers. The latex has a glass transition temperature that is less than about 30° C., and in some embodiments, that is also greater than about −25° C. For example, in some embodiments, the glass transition temperature is between about −15° C. to about 15° C., and in some embodiments, between about −10° C. to about 0° C. The latex can be selected from the group consisting of styrene-butadiene copolymers, polyvinyl acetate homopolymers, vinyl-acetate ethylene copolymers, vinyl-acetate acrylic copolymers, ethylene-vinyl chloride copolymers, ethylene-vinyl chloride-vinyl acetate terpolymers, acrylic polyvinyl chloride polymers, acrylic polymers, and nitrile polymers.
  • [0007]
    A debonder is also be applied to the furnish, wet web, or combinations thereof. The total amount of debonder applied can be in an amount between about 1 to about 30 pounds per ton of the cellulosic fibers. In some embodiments, the debonder can contain an imidazoline quaternary compound and/or an ester-functional quaternary ammonium compound.
  • [0008]
    If desired, a wet strength agent (e.g., temporary or permanent) can also be applied to the furnish, wet web, or combinations thereof. For example, when utilized, the total amount of temporary wet strength agent applied can be in an amount between about 1 to about 60 pounds per ton of the dry weight of the cellulosic fibers. Moreover, when utilized, the total amount of permanent wet strength agent applied can be in an amount between about 1 to about 20 pounds per ton of the dry weight of the cellulosic fibers.
  • [0009]
    The wet web is then dried such that the resulting dried web has at least one outer layer containing the latex-treated cellulosic fibers.
  • [0010]
    Other features and aspects of the present invention are discussed in greater detail below.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • [0011]
    A full and enabling disclosure of the present invention, including the best mode thereof to one of ordinary skill in the art, is set forth more particularly in the remainder of the specification, including reference to the accompanying figures in which:
  • [0012]
    [0012]FIG. 1 is a schematic flow diagram of one embodiment of a papermaking process that can be used in the present invention;
  • [0013]
    [0013]FIG. 2 is a schematic flow diagram of another embodiment of a papermaking process that can be used in the present invention;
  • [0014]
    [0014]FIG. 3 is a schematic flow diagram of still another embodiment of a papermaking process that can be used in the present invention; and
  • [0015]
    [0015]FIG. 4 is a schematic illustration of one example of an apparatus that can be used to measure the slough of a tissue product.
  • [0016]
    Repeat use of reference characters in the present specification and drawings is intended to represent same or analogous features or elements of the present invention.
  • DETAILED DESCRIPTION OF REPRESENTATIVE EMBODIMENTS
  • [0017]
    Reference now will be made in detail to the embodiments of the invention, one or more examples of which are set forth below. Each example is provided by way of explanation of the invention, not limitation of the invention. In fact, it will be apparent to those skilled in the art that various modifications and variations can be made in the present invention without departing from the scope or spirit of the invention. For instance, features illustrated or described as part of one embodiment, can be used on another embodiment to yield a still further embodiment. Thus, it is intended that the present invention covers such modifications and variations as come within the scope of the appended claims and their equivalents.
  • [0018]
    In general, the present invention is directed to a tissue product containing a multi-layered paper web that has at least one outer layer formed from cellulosic fibers treated with a latex. The latex can form a flexible bond with the cellulosic fibers such that the resulting web is flexible, strong, and produces low amounts of lint and slough. As used herein, a “tissue product” generally refers to various paper products, such as facial tissue, bath tissue, paper towels, napkins, and the like. Normally, the basis weight of a tissue product of the present invention is less than about 80 grams per square meter (gsm), in some embodiments less than about 60 grams per square meter, and in some embodiments, between about 10 to about 60 gsm.
  • [0019]
    Any of a variety of materials can also be used to form the paper web(s) of the tissue product. For example, the material used to make the tissue product can include fibers formed by a variety of pulping processes, such as kraft pulp, sulfite pulp, thermomechanical pulp, etc. The pulp fibers may include softwood fibers having an average fiber length of greater than 1 mm and particularly from about 2 to 5 mm based on a length-weighted average. Such softwood fibers can include, but are not limited to, northern softwood, southern softwood, redwood, red cedar, hemlock, pine (e.g., southern pines), spruce (e.g., black spruce), combinations thereof, and the like. Exemplary commercially available pulp fibers suitable for the present invention include those available from Kimberly-Clark Corporation under the trade designations “Longlac-19”.
  • [0020]
    Hardwood fibers, such as eucalyptus, maple, birch, aspen, and the like, can also be used. In certain instances, eucalyptus fibers may be particularly desired to increase the softness of the web. Eucalyptus fibers can also enhance the brightness, increase the opacity, and change the pore structure of the web to increase its wicking ability. Moreover, if desired, secondary fibers obtained from recycled materials may be used, such as fiber pulp from sources such as, for example, newsprint, reclaimed paperboard, and office waste. Further, other natural fibers can also be used in the present invention, such as abaca, sabai grass, milkweed floss, pineapple leaf, and the like. In addition, in some instances, synthetic fibers can also be utilized. Some suitable synthetic fibers can include, but are not limited to, rayon fibers, ethylene vinyl alcohol copolymer fibers, polyolefin fibers, polyesters, and the like.
  • [0021]
    As stated above, the tissue product of the present invention contains at least one multi-layered paper web. The tissue product can be a single-ply tissue product in which the web forming the tissue is stratified, i.e., has multiple layers, or a multi-ply tissue product in which the webs forming the multi-ply tissue product may themselves be either single or multi-layered. For instance, in one embodiment, a tissue product contains a ply formed from three layers where the outer layers include eucalyptus fibers and the inner layer includes northern softwood kraft fibers. If desired, the layers may also include blends of various types of fibers. However, it should be understood that the tissue product can include any number of plies or layers and can be made from various types of fibers.
  • [0022]
    In accordance with the present invention, a latex is applied to the cellulosic fibers to reduce lint and slough of the resulting tissue product. As used herein, a “latex” generally refers to a natural or synthetic colloidal dispersion of a polymeric material in a liquid system that is primarily aqueous in nature. Latexes suitable for use in the present invention typically have a glass transition temperature less than about 30° C. so that the flexibility of the resulting web is not substantially restricted. Moreover, the latexes also typically have a glass transition temperature greater than about −25° C. to minimize the tackiness of the latex. For instance, in some embodiments, the latexes used in the present invention have a glass transition temperature between about −15° C. to about 15° C., and in some embodiments, between about −10° C. to about 0° C.
  • [0023]
    The latexes used in the present invention are typically nonionic or anionic to facilitate application to the paper web. For instance, some suitable latexes that can be utilized in the present invention include, but are not limited to, anionic styrene-butadiene copolymers, polyvinyl acetate homopolymers, vinyl-acetate ethylene copolymers, vinyl-acetate acrylic copolymers, ethylene-vinyl chloride copolymers, ethylene-vinyl chloride-vinyl acetate terpolymers, acrylic polyvinyl chloride polymers, acrylic polymers, nitrile polymers, and any other suitable anionic latex polymers known in the art. The charge (e.g., anionic or nonionic) of the latexes described above can be readily varied, as is well known in the art, by utilizing a stabilizing agent having the desired charge during preparation of the latex. Other examples of suitable latexes may be described in U.S. Pat. No. 3,844,880 to Meisel, Jr., et al., which is incorporated herein in its entirety by reference thereto for all purposes.
  • [0024]
    Although not required, the latex is typically applied to the cellulosic fibers at the “wet end” of a papermaking process. As used herein, the phrase “wet end” generally refers to any stage of the papermaking process that occurs either before or while the web is dried. For example, in some embodiments, the latex can be applied to the papermaking furnish at the pulper, dump chest, machine chest, clean stock chest, low density cleaner, added directly into the head box, etc. Moreover, the latex may also be applied after the furnish has been formed into a wet web. For instance, in some embodiments, the latex can be sprayed or printed onto the surface of a wet web. In one embodiment, for instance, a latex solution is sprayed onto the wet tissue web at any of a variety of different locations as the web courses through the papermaking machine.
  • [0025]
    Regardless of the particular location of the papermaking process at which the latex is added, at least one outer layer of the multi-layered paper web is incorporated with the latex. For instance, in one embodiment, the latex is incorporated into one outer layer of a three-layered paper web, which defines an outer surface of the tissue product. The presence of the latex in the outer layer(s) of the tissue product can reduce lint and slough produced by the tissue product.
  • [0026]
    To minimize the stiffness of the multi-layered paper web used to form the tissue product, a variety of different techniques can be utilized. For instance, the latex can be applied in relatively small amounts. In some embodiments, the latex is applied in an amount less than 60 pounds per ton (lb/T), in some embodiments between about 1 lb/T to about 40 lb/MT, and in some embodiments, between about 1 lb/MT to about 20 lb/MT of the dry weight of fibrous material. In addition, the latex is also typically applied in amounts less than about 3%, in some embodiments between about 0.05% to about 2%, and in some embodiments, between about 0.05% to about 1% of the dry weight of fibrous material within a given layer. Further, in some embodiments, the latex is applied in amounts less than about 3%, in some embodiments between about 0.05% to about 2%, and in some embodiments, between about 0.05% to about 1% of the dry weight of the entire tissue product.
  • [0027]
    Further, the stiffness of the web can also be reduced by restricting application of the latex to only the outer layers of the web. For instance, in one embodiments, a three-layered paper web can be formed in which each outer layer contains the latex, while the inner layer is substantially free of the latex. In another embodiment, the inner layer and one outer layer of a three-layered web can be substantially free of the latex. It should be understood that, when referring to a layer that is “substantially free” of the latex, minuscule amounts of latex may be present therein. However, such small amounts often arise from the latex applied to the outer layer, and do not typically substantially affect the stiffness of the tissue product.
  • [0028]
    If desired, the latex can also be applied to the cellulosic fibers in conjunction with a deposition aid to facilitate retention of the latex on the fibers. For example, it may be useful to apply to the cellulosic fibers a “reactive composition”. A reactive composition is a composition that can form a bond (e.g., covalent, ionic, etc.) with anionic groups located on the cellulosic fibers. For instance, in one embodiment, a cationic composition can be used to form an ionic bond with free carboxylic groups located on the fibers. Such a reactive composition can decrease the overall negative charge of the fibers, and in some instances, even impart a positive charge to the fibers. Accordingly, the latex, when applied to fibers having such an altered charge, can more readily be retained thereon.
  • [0029]
    In general, any of a variety of reactive compositions can be applied to the cellulosic fibers to aid in deposition of the latex. Normally, it is also desired that such a reactive composition have additional functionality, e.g., strength and/or softness enhancement. For example, in some embodiments, a wet strength agent can be utilized, to further increase the strength of the tissue product, as well as to aid in the deposition of the latex. As used herein, a “wet strength agent” is any material that, when added to cellulosic fibers, can provide a resulting web or sheet with a wet geometric tensile strength to dry geometric tensile strength ratio in excess of about 0.1. Typically these materials are termed either “permanent” wet strength agents or “temporary” wet strength agents. As is well known in the art, temporary and permanent wet strength agents may also sometimes function as dry strength agents to enhance the strength of the tissue product when dry.
  • [0030]
    Wet strength agents may be applied in various amounts, depending on the desired characteristics of the tissue product. For instance, in some embodiments, the total amount of wet strength agents added to the cellulosic fibers can be between about 1 pound per ton (lb/T) to about 60 lb/T, in some embodiments, between about 5 lb/T to about 30 lb/T, and in some embodiments, between about 7 lb/T to about 13 lb/T of the dry weight of fibrous material. The wet strength agents can be incorporated into any layer of the multi-layered paper web.
  • [0031]
    Suitable permanent wet strength agents are typically water soluble, cationic oligomeric or polymeric resins that are capable of either crosslinking with themselves (homocrosslinking) or with the cellulose or other constituents of the wood fiber. Examples of such compounds are described in U.S. Pat. Nos. 2,345,543; 2,926,116; and 2,926,154, which are incorporated herein in their entirety by reference thereto for all purposes. One class of such agents includes polyamine-epichlorohydrin, polyamide epichlorohydrin or polyamide-amine epichlorohydrin resins, collectively termed “PAE resins”. Examples of these materials are described in U.S. Pat. Nos. 3,700,623 to Keim and 3,772,076 to Keim, which are incorporated herein in their entirety by reference thereto for all purposes and are sold by Hercules, Inc., Wilmington, Del. under the trade designation “Kymene”, e.g., Kymene 557H or 557 LX. Kymene 557 LX, for example, is a polyamide epicholorohydrin polymer that contains both cationic sites, which can form ionic bonds with anionic groups on the pulp fibers, and azetidinium groups, which can form covalent bonds with carboxyl groups on the pulp fibers and crosslink with the polymer backbone when cured.
  • [0032]
    Other suitable materials include base-activated polyamide-epichlorohydrin resins, which are described in U.S. Pat. Nos. 3,885,158 to Petrovich; 3,899,388 to Petrovich; 4,129,528 to Petrovich; 4,147,586 to Petrovich; and 4,222,921 to van Eanam, which are incorporated herein in their entirety by reference thereto for all purposes. Polyethylenimine resins may also be suitable for immobilizing fiber-fiber bonds. Another class of permanent-type wet strength agents includes aminoplast resins (e.g., urea-formaldehyde and melamine-formaldehyde).
  • [0033]
    If utilized, the permanent wet strength agents can be added to the cellulosic fibers in an amount between about 1 lb/T to about 20 lb/T, in some embodiments, between about 2 lb/T to about 10 lb/T, and in some embodiments, between about 3 lb/T to about 6 lb/T of the dry weight of fibrous material.
  • [0034]
    Temporary wet strength agents can also be useful in the present invention. Suitable temporary wet strength agents can be selected from agents known in the art such as dialdehyde starch, polyethylene imine, mannogalactan gum, glyoxal, and dialdehyde mannogalactan. Also useful are glyoxylated vinylamide wet strength resins as described in U.S. Pat. No. 5,466,337 to Darlington, et al., which is incorporated herein in its entirety by reference thereto for all purposes. Useful water-soluble resins include polyacrylamide resins such as those sold under the Parez trademark, such as Parez 631 NC, by American Cyanamid Company of Stanford, Conn. Such resins are generally described in U.S. Pat. Nos. 3,556,932 to Coscia, et al. and 3,556,933 to Williams, et al., which are incorporated herein in their entirety by reference thereto for all purposes. For example, the “Parez” resins typically include a polyacrylamide-glyoxal polymer that contains cationic hemiacetal sites that can form ionic bonds with carboxyl or hydroxyl groups present on the cellulosic fibers. These bonds can provide increased strength to the web of pulp fibers. In addition, because the hemicetal groups are readily hydrolyzed, the wet strength provided by such resins is primarily temporary.
  • [0035]
    U.S. Pat. No. 4,605,702 to Guerro, et al., which is incorporated herein in its entirety by reference thereto for all purposes, also describes suitable temporary wet strength resins made by reacting a vinylamide polymer with glyoxal, and then subjecting the polymer to an aqueous base treatment. Similar resins are also described in U.S. Pat. Nos. 4,603,176 to Biorkquist, et al.; 5,935,383 to Sun, et al.; and 6,017,417 to Wendt, et al., which are incorporated herein in their entirety by reference thereto for all purposes.
  • [0036]
    The temporary wet strength agents are generally provided by the manufacturer as an aqueous solution and, in some embodiments, is added to the cellulosic fibers in an amount between about 1 lb/T to about 60 lb/T, in some embodiments, between about 3 lb/T to about 40 lb/T, and in some embodiments, between about 4 lb/T to about 15 lb/T of the dry weight of fibrous material. If desired, the pH of the pulp can be adjusted prior to adding the resin. The Parez resins, for example, are typically used at a pH of from about 4 to about 8.
  • [0037]
    A chemical debonder can also be applied to soften the web, as well as to aid in the deposition of the latex on the web. Specifically, a chemical debonder can reduce the amount of hydrogen bonds within one or more layers of the web, which results in a softer product. Depending on the desired characteristics of the resulting tissue product, the debonder can be utilized in varying amounts. For example, in some embodiments, the debonder can be applied in an amount in an amount between about 1 lb/T to about 30 lb/T, in some embodiments between about 3 lb/T to about 20 lb/T, and in some embodiments, between about 6 lb/T to about 15 lb/T of the dry weight of fibrous material. The debonder can be incorporated into any layer of the multi-layered paper web.
  • [0038]
    Any material that can be applied to cellulosic fibers and that is capable of enhancing the soft feel of a web by disrupting hydrogen bonding can generally be used as a debonder in the present invention. In particular, as stated above, it is typically desired that the debonder possess a cationic charge for forming an ionic bond with anionic groups present on the cellulosic fibers. Some examples of suitable cationic debonders can include, but are not limited to, quaternary ammonium compounds, imidazolinium compounds, bis-imidazolinium compounds, diquaternary ammonium compounds, polyquaternary ammonium compounds, ester-functional quaternary ammonium compounds (e.g., quaternized fatty acid trialkanolamine ester salts), phospholipid derivatives, polydimethylsiloxanes and related cationic and non-ionic silicone compounds, fatty & carboxylic acid derivatives, mono- and polysaccharide derivatives, polyhydroxy hydrocarbons, etc. For instance, some suitable debonders are described in U.S. Pat. Nos. 5,716,498 to Jenny, et al.; 5,730,839 to Wendt, et al.; 6,211,139 to Keys, et al.; 5,543,067 to Phan, et al.; and WO/0021918, which are incorporated herein in their entirety by reference thereto for all purposes. For instance, Jenny, et al. and Phan, et al. describe various ester-functional quaternary ammonium debonders (e.g., quaternized fatty acid trialkanolamine ester salts) suitable for use in the present invention. In addition, Wendt, et al. describes imidazolinium quaternary debonders that may be suitable for use in the present invention. Further, Keys, et al. describes polyester polyquaternary ammonium debonders that may be useful in the present invention.
  • [0039]
    Still other suitable debonders are disclosed in U.S. Pat. Nos. 5,529,665 to Kaun and 5,558,873 to Funk, et al., which are incorporated herein in their entirety by reference thereto for all purposes. In particular, Kaun discloses the use of various cationic silicone compositions as softening agents.
  • [0040]
    Although reactive compositions, such as described above, can be applied to the cellulosic fibers to aid in the deposition of the latex thereon, it should also be understood that such compositions may also be applied after application of the latex. In particular, the present invention is not limited to any specific order of application of the latex and the reactive compositions. For instance, in one embodiment, a latex, wet strength agent, and debonder can be sequentially applied to the web. In another embodiment, a wet strength agent, latex, and debonder can be sequentially applied to the web.
  • [0041]
    A tissue product made in accordance with the present invention can generally be formed according to a variety of papermaking processes known in the art. In fact, any process capable of making a paper web can be utilized in the present invention. For example, a papermaking process of the present invention can utilize wet-pressing, creping, through-air-drying, creped through-air-drying, uncreped through-air-drying, single recreping, double recreping, calendering, embossing, air laying, as well as other steps in processing the paper web.
  • [0042]
    In some embodiments, in addition to the use of various chemical treatments, such as described above, the papermaking process itself can also be selectively varied to achieve a tissue product with certain properties. For instance, a papermaking process can be utilized to form a multi-layered paper web, such as described and disclosed in U.S. Pat. Nos. 5,129,988 to Farrington, Jr.; 5,494,554 to Edwards, et al.; and 5,529,665 to Kaun, which are incorporated herein in their entirety by reference thereto for all purposes.
  • [0043]
    In this regard, various embodiments of a method for forming a multi-layered paper web will now be described in more detail. Referring to FIG. 1, a method of making a wet-pressed tissue in accordance with one embodiment of the present invention is shown, commonly referred to as couch forming, wherein two wet web layers are independently formed and thereafter combined into a unitary web. To form the first web layer, a specified fiber (either hardwood or softwood) is prepared in a manner well known in the papermaking arts and delivered to the first stock chest 1, in which the fiber is kept in an aqueous suspension. A stock pump 2 supplies the required amount of suspension to the suction side of the fan pump 4. If desired, a metering pump 5 can supply an additive (e.g., latex, reactive composition, etc.) into the fiber suspension. Additional dilution water 3 also is mixed with the fiber suspension.
  • [0044]
    The entire mixture of fibers is then pressurized and delivered to the headbox 6. The aqueous suspension leaves the headbox 6 and is deposited on an endless papermaking fabric 7 over the suction box 8. The suction box is under vacuum that draws water out of the suspension, thus forming the first layer. In this example, the stock issuing from the headbox 6 would be referred to as the “air side” layer, that layer eventually being positioned away from the dryer surface during drying.
  • [0045]
    The forming fabric can be any forming fabric, such as fabrics having a fiber support index of about 150 or greater. Some suitable forming fabrics include, but are not limited to, single layer fabrics, such as the Appleton Wire 94M available from Albany International Corporation, Appleton Wire Division, Menasha, Wis.; double layer fabrics, such as the Asten 866 available from Asten Group, Appleton, Wis.; and triple layer fabrics, such as the Lindsay 3080, available from Lindsay Wire, Florence, Miss.
  • [0046]
    The consistency of the aqueous suspension of papermaking fibers leaving the headbox can be from about 0.05 to about 2%, and in one embodiment, about 0.2%. The first headbox 6 can be a layered headbox with two or more layering chambers which delivers a stratified first wet web layer, or it can be a monolayered headbox which delivers a blended or homogeneous first wet web layer.
  • [0047]
    To form the second web layer, a specified fiber (either hardwood or softwood) is prepared in a manner well known in the papermaking arts and delivered to the second stock chest 11, in which the fiber is kept in an aqueous suspension. A stock pump 12 supplies the required amount of suspension to the suction side of the fan pump 14. A metering pump 5 can supply additives (e.g., latex, reactive composition, etc.) into the fiber suspension as described above. Additional dilution water 13 is also mixed with the fiber suspension. The entire mixture is then pressurized and delivered to the headbox 16. The aqueous suspension leaves the headbox 16 and is deposited onto an endless papermaking fabric 17 over the suction box 18. The suction box is under vacuum which draws water out of the suspension, thus forming the second wet web. In this example, the stock issuing from the headbox 16 is referred to as the “dryer side” layer as that layer will be in eventual contact with the dryer surface. Suitable forming fabrics for the forming fabric 17 of the second headbox include those forming fabrics previously mentioned with respect to the first headbox forming fabric.
  • [0048]
    After initial formation of the first and second wet web layers, the two web layers are brought together in contacting relationship (couched) while at a consistency of from about 10 to about 30%. Whatever consistency is selected, it is typically desired that the consistencies of the two wet webs be substantially the same. Couching is achieved by bringing the first wet web layer into contact with the second wet web layer at roll 19.
  • [0049]
    After the consolidated web has been transferred to the felt 22 at vacuum box 20, dewatering, drying and creping of the consolidated web is achieved in the conventional manner. More specifically, the couched web is further dewatered and transferred to a dryer 30 (e.g., Yankee dryer) using a pressure roll 31, which serves to express water from the web, which is absorbed by the felt, and causes the web to adhere to the surface of the dryer. The web is then dried, optionally creped and wound into a roll 32 for subsequent converting into the final creped product.
  • [0050]
    [0050]FIG. 2 is a schematic flow diagram of another embodiment of a papermaking process than can be used in the present invention. For instance, a layered headbox 41, a forming fabric 42, a forming roll 43, a papermaking felt 44, a press roll 45, a Yankee dryer 46, and a creping blade 47 are shown. Also shown, but not numbered, are various idler or tension rolls used for defining the fabric runs in the schematic diagram, which may differ in practice. In operation, a layered headbox 41 continuously deposits a layered stock jet between the forming fabric 42 and the felt 44, which is partially wrapped around the forming roll 43. Water is removed from the aqueous stock suspension through the forming fabric 42 by centrifugal force as the newly-formed web traverses the arc of the forming roll. As the forming fabric 42 and felt 44 separate, the wet web stays with the felt 44 and is transported to the Yankee dryer 46.
  • [0051]
    At the Yankee dryer 46, the creping chemicals are continuously applied on top of the existing adhesive in the form of an aqueous solution. The solution is applied by any convenient means, such as using a spray boom that evenly sprays the surface of the dryer with the creping adhesive solution. The point of application on the surface of the dryer 46 is immediately following the creping doctor blade 47, permitting sufficient time for the spreading and drying of the film of fresh adhesive.
  • [0052]
    In some instances, the latex, reactive compositions, etc., may be applied to the web as it is being dried, such as through the use of the spray boom. For example, the spray boom can apply the additives to the surface of the drum 46 separately and/or in combination with the creping adhesives such that such additives are applied to an outer layer of the web as it passes over the drum 46. In some embodiments, the point of application on the surface of the dryer 46 is the point immediately following the creping blade 47, thereby permitting sufficient time for the spreading and drying of the film of fresh adhesive before contacting the web in the press roll nip. Methods and techniques for applying an additive to a dryer drum are described in more detail in U.S. Pat. Nos. 5,853,539 to Smith, et al. and 5,993,602 to Smith, et al., which are incorporated herein in their entirety by reference thereto for all purposes.
  • [0053]
    The wet web is applied to the surface of the dryer 46 by a press roll 45 with an application force of, in one embodiment, about 200 pounds per square inch (psi). Following the pressing or dewatering step, the consistency of the web is typically at or above about 30%. Sufficient Yankee dryer steam power and hood drying capability are applied to this web to reach a final consistency of about 95% or greater, and particularly 97% or greater. The sheet or web temperature immediately preceding the creping blade 47, as measured, for example, by an infrared temperature sensor, is typically about 235° F.
  • [0054]
    The web can also be dried using non-compressive drying techniques, such as through-air drying. A through-air dryer accomplishes the removal of moisture from the web by passing air through the web without applying any mechanical pressure. Through-air drying can increase the bulk and softness of the web. Examples of such a technique are disclosed in U.S. Pat. Nos. 5,048,589 to Cook, et al.; 5,399,412 to Sudall, et al.; 5,510,001 to Hermans, et al.; 5,591,309 to Rugowski, et al.; and 6,017,417 to Wendt, et al., which are incorporated herein in their entirety by reference thereto for all purposes.
  • [0055]
    For example, referring to FIG. 3, one embodiment of a papermaking machine that can be used in forming an uncreped through-dried tissue product is illustrated. For simplicity, the various tensioning rolls schematically used to define the several fabric runs are shown but not numbered. As shown, a papermaking headbox 110 can be used to inject or deposit a stream of an aqueous suspension of papermaking fibers onto an upper forming fabric 112. The aqueous suspension of fibers is then transferred to a lower forming fabric 113, which serves to support and carry the newly-formed wet web 111 downstream in the process. If desired, dewatering of the wet web 111 can be carried out, such as by vacuum suction, while the wet web 111 is supported by the forming fabric 113.
  • [0056]
    The wet web 111 is then transferred from the forming fabric 113 to a transfer fabric 117 while at a solids consistency of between about 10% to about 35%, and particularly, between about 20% to about 30%. As used herein, a “transfer fabric” is a fabric that is positioned between the forming section and the drying section of the web manufacturing process. In this embodiment, the transfer fabric 117 is a patterned fabric having protrusions or impression knuckles, such as described in U.S. Pat. No. 6,017,417 to Wendt et al. Typically, the transfer fabric 117 travels at a slower speed than the forming fabric 113 to enhance the “MD stretch” of the web, which generally refers to the stretch of a web in its machine or length direction (expressed as percent elongation at sample failure). For example, the relative speed difference between the two fabrics can be from 0% to about 80%, in some embodiments greater than about 10%, in some embodiments from about 10% to about 60%, and in some embodiments, from about 15% to about 30%. This is commonly referred to as “rush” transfer. One useful method of performing rush transfer is taught in U.S. Pat. No. 5,667,636 to Engel et al., which is incorporated herein in its entirety by reference thereto for all purposes.
  • [0057]
    Transfer to the fabric 117 may be carried out with the assistance of positive and/or negative pressure. For example, in one embodiment, a vacuum shoe 118 can apply negative pressure such that the forming fabric 113 and the transfer fabric 117 simultaneously converge and diverge at the leading edge of the vacuum slot. Typically, the vacuum shoe 118 supplies pressure at levels between about 10 to about 25 inches of mercury. As stated above, the vacuum transfer shoe 118 (negative pressure) can be supplemented or replaced by the use of positive pressure from the opposite side of the web to blow the web onto the next fabric. In some embodiments, other vacuum shoes can also be used to assist in drawing the fibrous web 111 onto the surface of the transfer fabric 117.
  • [0058]
    From the transfer fabric 117, the fibrous web 111 is then transferred to the through-drying fabric 119. When the wet web 111 is transferred to the fabric 119. While supported by the through-drying fabric 119, the web 111 is then dried by a through-dryer 121 to a solids consistency of about 95% or greater. The through-dryer 121 accomplishes the removal of moisture from the web 111 by passing air therethrough without applying any mechanical pressure. Through-drying can also increase the bulk and softness of the web 111. In one embodiment, for example, the through-dryer 121 can contain a rotatable, perforated cylinder and a hood for receiving hot air blown through perforations of the cylinder as the through-drying fabric 119 carries the web 11 over the upper portion of the cylinder. The heated air is forced through the perforations in the cylinder of the through-dryer 121 and removes the remaining water from the web 111. The temperature of the air forced through the web 111 by the through-dryer 121 can vary, but is typically from about 250° F. to about 500° F. It should also be understood that other non-compressive drying methods, such as microwave or infrared heating, can be used.
  • [0059]
    As indicated above, the latex may sometimes be applied to the web as it courses through the papermaking machine. In one particular embodiment, for example, the latex may be sprayed onto the web. Spraying can enhance the ability of the latex to remain substantially on the outer layer of the web, thereby better inhibiting the production of slough therefrom. In general, the latex may be sprayed onto the web at any stage during its formation. For example, in the embodiment shown in FIG. 3, a spray nozzle 140 may spray the latex onto the web 111 after it is transferred to the fabric 117 and before it is dried. It should be understood, however, that the spray nozzle 140 may be positioned at any other location desired.
  • [0060]
    Any equipment suitable for spraying an additive onto a paper web may be utilized in the present invention. For instance, one example of suitable spraying equipment includes external mix, air atomizing nozzles, such as the 2 mm nozzle available from V.I.B. Systems, Inc., Tucker, Ga. Another nozzle that can be used is an H ⅛″ VV-SS 650017 VeeJet spray nozzle available from Spraying Systems, Inc. of Milwaukee, Wis. Still other spraying techniques and equipment are described in U.S. Pat. No. 5,164,046 to Ampulski, et al., which is incorporated herein in its entirety by reference thereto for all purposes.
  • [0061]
    In accordance with the present invention, it may sometimes be desired to control the retention % of the latex retained on the cellulosic fibers. Specifically, one or more variables, such as the sequence of application of the latex and reactive compositions, the type of latex, the type of reactive compositions, the amount of the latex and reactive compositions applied, etc., can be selectively altered so that the resulting retention % is within a desired range. For instance, in some embodiments, it may be desired that at least about 60% of the latex be retained on the fibers, and in some embodiments, between about 75% to about 90% of the latex be retained on the fibers.
  • [0062]
    The retention % of latex retained on the cellulosic fibers can be determined according the following formula:
  • % retention=100×[(L T −L F)/L T]
  • [0063]
    wherein,
  • [0064]
    LT is the total amount of latex applied to a pulp slurry; and
  • [0065]
    LF is the amount of latex remaining in the filtrate after removal of the pulp fibers therefrom. For example, LF can be determined from the “turbidity” value of the filtrate. As used herein, the term “turbidity” generally refers to the optical clarity of a material and can be measured, for instance, using a Model DRT 100B Turbidimeter obtained from HF Scientific, Inc., which measures turbidity in terms of “Nephelometric Turbidity Units” (NTU). For instance, in one embodiment, a linear regression equation can be developed using known “LF” values, e.g., LF=ax+b, where “a” and “b” are constants; and “x” is the turbidity value.
  • [0066]
    By controlling the retention % of the latex, the strength and stiffness imparted to the tissue product can be appropriately balanced as desired. Moreover, relatively high retention percentages can allow a lower total level of latex to be used than if the retention percentage was relatively low. Accordingly, because a lower amount of latex is required, the present invention can provide a substantial cost reduction and enhanced efficiency to the papermaking process. Moreover, the resulting tissue product can be strong and produce a relatively low amount of lint and slough, while also maintaining the flexibility and softness desired for many end uses of the tissue product.
  • [0067]
    The present invention may be better understood with reference to the following examples.
  • EXAMPLE 1
  • [0068]
    The ability to determine latex retention from turbidity was demonstrated. A fibrous slurry was initially prepared from 100% bleached Kraft softwood pulp fibers. The slurry was slushed in a British disintegrator at a solids consistency of 1.6% for 5 minutes. The slurry was then diluted to a consistency of 0.33%.
  • [0069]
    Four samples of the fibrous furnish (volume of 909 ml and weight of 3 grams) were then removed from the pulp slurry and placed into a beaker. Thereafter, an anionic styrene-butadiene latex solution (available from Dow Chemical under the trade designation “DL-239”), having a solids content of 0.5% by weight of solution, was applied to each sample of the fibrous furnish in varying amounts as set forth below in Table 1.
  • [0070]
    Once applied with the latex, the furnish samples were diluted with water to a volume of 1000 ml. After waiting 10 minutes, the samples were filtered through the screen of a Freeness Tester according to TAPPI test method T227.
  • [0071]
    The filtrates from both the bottom and side orifices were collected and mixed together for “turbidity” measurement. The presence of the anionic latex on a web of cellulosic material was detected by measuring the “turbidity” of the material. Specifically, a Model DRT 100B Turbidimeter obtained from HF Scientific, Inc. was first calibrated with a standard solution contained within in a test tube. 40 milliliters of the combined filtrates were then collected and added to the test tube. The test tube was then placed in the Turbidimeter, which contained a light source that provided light in a direction perpendicular to the tube. The resulting turbidity value was then read from the Turbidimeter and recorded.
  • [0072]
    The results for each sample were compared with a control sample that did not contain the pulp slurry. The results are shown below in Table
    TABLE 1
    Turbidity Test Results
    Turbidity
    Amount of Latex With Pulp Without Pulp
    Sample (lbs/ton) Slurry Slurry
    Control  0 4.4 N/A
    1  5 52  47
    2 10 87  83
    3 20 165 160
    4 40 274 268
  • [0073]
    As indicated above, under the same amount of latex addition, the filtrate from the pulp slurry samples had slightly higher turbidity values than the control sample. Although not limited by theory, it is believed that this result is due to the fact that the small amount of pulp particles contributed to the turbidity value.
  • [0074]
    The amount of latex remaining in the filtrate after the fibers were screened off was then measured by developing a regression equation where the amount of latex remaining within the filtrate (lbs/ton of pulp) was the “y” variable and the measured turbidity value of the control sample was the “x” variable. For the data provided in Table 1, the resulting regression equation was y=0.1504x−1.8589, wherein the coefficient of correlation (RA2) was equal to 0.99.
  • EXAMPLE 2
  • [0075]
    The ability to incorporate latex into a fibrous furnish was demonstrated. A fibrous slurry was initially prepared from 100% bleached Kraft softwood pulp fibers. The slurry was slushed in a British disintegrator at a consistency of 1.6% for 5 minutes. The slurry was then diluted to a consistency of 0.33%.
  • [0076]
    Six samples of the fibrous furnish (volume of 909 ml and weight of 3 grams) were then removed from the pulp slurry and placed into a 1000 ml beaker. Thereafter, an anionic styrene-butadiene latex (available from Dow Chemical under the trade designation “DL-239”), having a solids content of 0.5% by weight of solution, was applied to each sample of the fibrous furnish in an amount of 20 lb/T. In addition, an imidazoline quaternary debonder (available from Hercules, Inc. under the trade designation “Prosoft TQ-1003”) and “Parez” polyacrylamide temporary wet strength (also functions as dry strength agent) were also applied to the furnish in amount of 16.5 lb/T and 6.5 lb/T, respectively. The sequence of application for these additives was varied for each sample as set forth below in Table 2. A 5-minute interval existed between the application of each additive.
  • [0077]
    Once applied with the additives, the furnish samples were diluted with water to a volume of 1000 ml. After waiting 25 minutes, the samples were filtered through the screen of a Freeness Tester as set forth in Example 1. The turbidity and the amount of latex remaining in the filtrate were determined as set forth in Example 1. Once obtained, the value for the amount of latex remaining in the filtrate was then used to calculate the retention % of anionic latex retained on various cellulosic webs according owing formula:
  • % retention=100×[(L T −L F)/L T]
  • [0078]
    wherein,
  • [0079]
    LT is the total amount of latex applied to the pulp slurry; and
  • [0080]
    LF is the amount of latex remaining in the filtrate after removal of the pulp fibers therefrom.
  • [0081]
    The results are provided in Table 2.
    TABLE 2
    Sample Results
    1st 2nd 3rd Retention
    Sample Addition Addition Addition Turbidity %
    1 Debonder Latex Strength 38 81
    Agent
    2 Latex Debonder Strength 86 45
    Agent
    3 Strength Debonder Latex 51 71
    Agent
    4 Debonder Strength Latex 37 82
    Agent
    5 Latex Strength Debonder 66 60
    Agent
    6 Strength Latex Debonder 67 59
    Agent
  • [0082]
    As shown, the sequence of chemical addition can have an effect on latex retention. For instance, samples 1 and 4, in which the debonder is added prior to the latex, provided the lowest turbidity coefficients.
  • EXAMPLE 3
  • [0083]
    The ability to incorporate latex into a fibrous furnish was demonstrated. A fibrous slurry was initially prepared from 100% bleached Kraft softwood pulp fibers. The slurry was slushed in a British disintegrator at a consistency of 1.6% for 5 minutes. The slurry was then diluted to a consistency of 0.33%.
  • [0084]
    Six samples of the fibrous furnish (volume of 909 ml and weight of 3 grams) were then removed from the pulp slurry and placed into a 1000 ml beaker. Thereafter, an anionic styrene-butadiene latex (available from Dow Chemical under the trade designation “DL-239”), having a solids content of 0.5% by weight of solution, was applied to each sample of the fibrous furnish in an amount of 20 lb/T. In addition, a diamidoamine quaternary debonder (available from Goldschmidt under the trade designation “Arosurf PA-727”) and “Parez” polyacrylamide temporary wet strength agent (also functions as dry strength agent) were also applied to the furnish in amount of 16.5 lb/T and 6.5 lb/T, respectively. The sequence of application for these additives was varied for each sample as set forth below in Table 3. A 5-minute interval existed between the application of each additive.
  • [0085]
    Once applied with the additives, the furnish samples were diluted with water to a volume of 1000 ml. After waiting 25 minutes, the samples were filtered through the screen of a Freeness Tester as set forth in Example 1. The turbidity and retention % were then determined as set forth in Examples 1-2. The results are provided in Table 3.
    TABLE 3
    Sample Results
    1st 2nd 3rd Retention
    Sample Addition Addition Addition Turbidity %
    1 Debonder Latex Strength 66 60
    Agent
    2 Latex Debonder Strength 60 64
    Agent
    3 Strength Debonder Latex 48 73
    Agent
    4 Debonder Strength Latex 55 68
    Agent
    5 Latex Strength Debonder 55 68
    Agent
    6 Strength Latex Debonder 45 75
    Agent
  • [0086]
    As indicated, when utilizing a diamidoamine quaternary, the sequence of chemical addition did not have as large an effect on the turbidity coefficient than when using a imidazoline quaternary, as set forth in Example 2.
  • EXAMPLE 4
  • [0087]
    The ability to incorporate latex into a fibrous furnish was demonstrated. A fibrous slurry was initially prepared from 100% bleached Kraft softwood pulp fibers. The slurry was slushed in a British disintegrator at a consistency of 1.6% for 5 minutes. The slurry was then diluted to a consistency of 0.33%.
  • [0088]
    Six samples of the fibrous furnish (volume of 909 ml and weight of 3 grams) were then removed from the pulp slurry and placed into a 1000 ml beaker. Thereafter, an anionic styrene-butadiene latex (available from Dow Chemical under the trade designation “DL-239”), having a solids content of 0.5% by weight of solution, was applied to each sample of the fibrous furnish in an amount of 20 lb/T. In addition, a quaternized fatty acid trialkanolamine ester debonder (available from Goldschmidt under the trade designation “Varisoft We-16”) and “Parez” polyacrylamide temporary wet strength agent (also functions as dry strength agent) were also applied to the furnish in amount of 16.5 lb/T and 6.5 lb/T, respectively. The sequence of application for these additives was varied for each sample as set forth below in Table 4. A 5-minute interval existed between the application of each additive.
  • [0089]
    Once applied with the additives, the furnish samples were diluted with water to a volume of 1000 ml. After waiting 25 minutes, the samples were filtered through the screen of a Freeness Tester as set forth in Example 1. The turbidity and retention % were then determined as set forth in Examples 1-2. The results are provided in Table 4.
    TABLE 4
    Sample Results
    1st 2nd 3rd Retention
    Sample Addition Addition Addition Turbidity %
    1 Debonder Latex Strength 47 74
    Agent
    2 Latex Debonder Strength 43 77
    Agent
    3 Strength Debonder Latex 33 85
    Agent
    4 Debonder Strength Latex 44 76
    Agent
    5 Latex Strength Debonder 47 74
    Agent
    6 Strength Latex Debonder 40 79
    Agent
  • [0090]
    As indicated, the quaternized fatty acid trialkanolamine ester debonder provided low turbidity coefficients, regardless of the sequence
  • EXAMPLE 5
  • [0091]
    The ability to incorporate latex into a fibrous furnish was Demonstrated. A fibrous slurry was initially prepared from 100% bleached Kraft softwood pulp fibers. The slurry was slushed in a British disintegrator at a consistency of 1.6% for 5 minutes. The slurry was then diluted to a consistency of 0.33%.
  • [0092]
    Six samples of the fibrous furnish (volume of 909 ml and weight of 3 grams) were then removed from the pulp slurry and placed into a 1000 ml beaker. Thereafter, an anionic styrene-butadiene latex (available from Dow Chemical under the trade designation “DL-239”), having a solids content of 0.5% by weight of solution, was applied to each sample of the fibrous furnish in an amount of 20 lb/T. In addition, a dialkyldimethyl quaternary debonder (available from Goldschmidt under the trade designation “Varisoft 137”) and “Parez” polyacrylamide temporary wet strength agent (also functions as dry strength agent) were also applied to the furnish in amount of 16.5 lb/T and 6.5 lb/T, respectively. The sequence of application for these additives was varied for each sample as set forth below in Table 5. A 5-minute interval existed between the application of each additive.
  • [0093]
    Once applied with the additives, the furnish samples were diluted with water to a volume of 1000 ml. After waiting 25 minutes, the samples were filtered through the screen of a Freeness Tester as set forth in Example 1. The turbidity and retention % were then determined as set forth in Examples 1-2. The results are provided in Table 5.
    TABLE 5
    Sample Results
    1st 2nd 3rd Retention
    Sample Addition Addition Addition Turbidity %
    1 Debonder Latex Strength 60 65
    Agent
    2 Latex Debonder Strength 81 48
    Agent
    3 Strength Debonder Latex 80 49
    Agent
    4 Debonder Strength Latex 56 67
    Agent
    5 Latex Strength Debonder 56 67
    Agent
    6 Strength Latex Debonder 57 66
    Agent
  • [0094]
    As shown, the sequence of chemical addition can have an effect on latex retention on fiber. For instance, samples 4 and 5 provided low turbidity coefficients.
  • EXAMPLE 6
  • [0095]
    The ability to incorporate latex into a fibrous furnish was demonstrated. A fibrous slurry was initially prepared from 100% bleached Kraft softwood pulp fibers. The slurry was slushed in a British disintegrator at a consistency of 1.6% for 5 minutes. The slurry was then diluted to a consistency of 0.33%.
  • [0096]
    Four samples of the fibrous furnish (volume of 909 ml and weight of 3 grams) were then removed from the pulp slurry and placed into a 1000 ml beaker. Thereafter, an anionic styrene-butadiene latex (available from Dow Chemical under the trade designation “DL-239”), having a solids content of 0.5% by weight of solution, was applied to each sample of the fibrous furnish in an amount of 20 lb/T.
  • [0097]
    In addition, “Prosoft TQ-1003”, “Arosurf PA 727”, Varisoft We-16”, and “Varisoft 137” were applied respectively to Samples 1-4, each in an amount of 16.5 lb/T. “Kymene 557 LX”, a polyamide epicholorohydrin permanent wet strength agent, was also applied to the furnish in amount of 8.5 lb/T. The sequence of application for these additives was debonder, strength agent, and then the latex. A 5-minute interval existed between the application of each additive.
  • [0098]
    Once applied with the additives, the furnish samples were diluted with water to a volume of 1000 ml. After waiting 25 minutes, the samples were filtered through the screen of a Freeness Tester as set forth in Example 1. The turbidity and retention % were then determined as set forth in Example 1. The results are provided in Table 6.
    TABLE 6
    Sample Results
    Sample Debonder Turbidity Retention %
    1 Prosoft TQ-1003 (imidazoline 20 94
    quaternary)
    2 Arosurf PA 727 34 84
    (diamidoamine quaternary)
    3 Varisoft we-16 (quaternized 24 91
    fatty acid trialkanolamine
    ester debonder)
    4 Varisoft 137 (dialkyldimethyl 41 78
    quaternary)
  • [0099]
    As shown, ProsofTQ-1003 and Varisoft we-16 debonders provided the lowest turbidity coefficients.
  • EXAMPLE 7
  • [0100]
    The ability to form soft tissues that produce low amounts of slough was demonstrated. Nine tissue samples (Samples 7-15) were produced on a papermaking machine, such as illustrated in FIG. 1 and described above. Specifically, two separate tissue sheets were formed and couched together into a single sheet. The single sheet was then pressed, dried and creped. Separate stock chests were used to form each separate tissue sheet. The air-side stock chest contained northern softwood kraft fibers (LL-19, from Kimberly-Clark.), while the dryer-side stock chest contained eucalyptus fibers obtained from Bahil Su., Inc. For Samples 10-15, the LL-19 fibers were refined for 7 minutes with a refiner located below the stock chest. Each sample had a basis weight of 30 grams per square meter and contained 35% LL-19 softwood fibers and 65% eucalyptus fibers.
  • [0101]
    For Samples 7-9, “Kymene 557 LX”, a polyamide epicholorohydrin permanent wet strength agent, was applied in an amount of 4 lb/T to the dryer-side stock chest and in an amount of 4 lb/T to the air-side stock chest. In addition, “Parez” polyacrylamide temporary wet strength agent (also functions as dry strength agent) was applied to the air-side stock pump in an amount of between 0 to about 3 lb/T.
  • [0102]
    For Samples 10-12, “Kymene 557 LX” was applied in an amount of 4 lb/T to the dryer-side stock chest and in an amount of 4 lb/T to the air-side stock chest. After mixing the slurry for approximately 15 minutes, 6 lbs/T of Mackernium DC-183, an imidazoline quaternary debonder available from McIntyre, Inc., was also added to the dryer-side stock chest. Further, “Parez” polyacrylamide temporary wet strength agent (also functions as dry strength agent) was also applied to the air-side stock pump in an amount of between 0 to about 7.5 lb/T.
  • [0103]
    Samples 13-15 were formed in a manner identical to Samples 10-12, except that 20 lbs/T of Airflex A-105, a vinyl-acetate ethylene copolymer latex available from Air Products, was also added to the air-side stock chest. Further, “Parez” polyacrylamide temporary wet strength agent (also functions as dry strength agent) was applied to the air-side stock pump in an amount of between about 2 to about 10 lb/T.
  • [0104]
    Once formed, the tensile strength, slough, and stiffness of the samples were determined as follows.
  • [0105]
    Tensile Strength
  • [0106]
    Tensile strength was reported as “GMT” (grams per 3 inches of a sample), which is the geometric mean tensile strength and is calculated as the square root of the product of MD tensile strength and CD tensile strength. MD and CD tensile strengths were determined using a MTS/Sintech tensile tester (available from the MTS Systems Corp., Eden Prairie, Minn.). Tissue samples measuring 3 inch wide were cut in both the machine and cross-machine directions. For each test, a sample strip was placed in the jaws of the tester, set at a 4 inch gauge length for facial tissue and 2 inch gauge length for bath tissue. The crosshead speed during the test was 10 in./minute. The tester was connected with a computer loaded with data acquisition system; e.g., MTS TestWork for windows software. Readings were taken directly from a computer screen readout at the point of rupture to obtain the tensile strength of an individual sample.
  • [0107]
    Slough
  • [0108]
    In order to determine the abrasion resistance or tendency of the fibers to be rubbed from the web when handled, each sample was measured by abrading the tissue specimens via the following method. This test measures the resistance of tissue material to abrasive action when the material is subjected to a horizontally reciprocating surface abrader. All samples were conditioned at 23° C.±1° C. and 50±2% relative humidity for a minimum of 4 hours. FIG. 4 shows a diagram of the test equipment.
  • [0109]
    The abrading spindle contained a stainless steel rod, 0.5″ in diameter with the abrasive portion consisting of a 0.005″ deep diamond pattern extending 4.25″ in length around the entire circumference of the rod. The spindle was mounted perpendicularly to the face of the instrument such that the abrasive portion of the rod extends out its entire distance from the face of the instrument. On each side of the spindle were located guide pins with magnetic clamps, one movable and one fixed, spaced 4″ apart and centered about the spindle. The movable clamp and guide pins were allowed to slide freely in the vertical direction, the weight of the jaw providing the means for insuring a constant tension of the sample over the spindle surface.
  • [0110]
    Using a die press with a die cutter, the specimens were cut into 3″±0.05″ wide×8″ long strips with two holes at each end of the sample. For the tissue samples, the MD direction corresponds to the longer dimension. Each test strip was then weighed to the nearest 0.1 mg. Each end of the sample was slid onto the guide pins and magnetic clamps held the sheet in place. The movable jaw was then allowed to fall providing constant tension across the spindle.
  • [0111]
    The spindle was then moved back and forth at an approximate 15 degree angle from the centered vertical centerline in a reciprocal horizontal motion against the test strip for 20 cycles (each cycle is a back and forth stroke), at a speed of 80 cycles per minute, removing loose fibers from the web surface. Additionally, the spindle rotated counter clockwise (when looking at the front of the instrument) at an approximate speed of 5 RPMs. The magnetic clamp was then removed from the sample and the sample was slid off of the guide pins and any loose fibers on the sample surface are removed by blowing compressed air (approximately 5-10 psi) on the test sample. The test sample was then weighed to the nearest 0.1 mg and the weight loss calculated. Ten test samples per tissue sample were tested and the average weight loss value in milligrams was recorded.
  • [0112]
    Stiffness
  • [0113]
    Stiffness (or softness) was ranked on a scale from 0 to 16, where lower values represent softer tissues and higher values represent stiffer tissues. Twelve (12) panelists were asked to consider the amount of pointed, rippled or cracked edges or peaks felt from the sample while turning in your hand. The panelists were instructed to place two tissue samples flat on a smooth tabletop. The tissue samples overlapped one another by 0.5 inches (1.27 centimeters) and were flipped so that opposite sides of the tissue samples were represented during testing. With forearms/elbows of each panelist resting on the table, they placed their open hand, palm down, on the samples. Each was instructed to position their hand so their fingers were pointing toward the top of the samples, approximately 1.5 inches (approximately 3.81 centimeters) from the edge. Each panelist moved their fingers toward their palm with little or no downward pressure to gather the tissue samples. They gently moved the gathered samples around in the palm of their hand approximately 2 to 3 turns. The rank assigned by each panelist for a given tissue sample was then averaged and recorded.
  • [0114]
    The results are provided below in Table 7.
    TABLE 7
    Sample Results
    Sample GMT (grams/3 inches) Slough (mg) Panel Stiffness
     7 572 6.37 3.0
     8 583 5.78 2.9
     9 623 8.27 3.0
    10 513 12.34 2.4
    11 445 10.38 2.4
    12 638 18.71 2.7
    13 884 9.56 2.9
    14 729 10.33 2.8
    15 433 7.88 2.4
  • [0115]
    As indicated from the results set forth in Table 7, the addition of a latex in accordance with the present invention can provide a soft tissue product that is strong and produces relatively low amounts of slough.
  • EXAMPLE 8
  • [0116]
    The ability to form soft tissues that produce low amounts of slough was demonstrated. Three tissue samples (Samples 16-18) were formed as described above and shown in FIG. 3, with the exception that the uncreped through-dried tissue was formed from two separate sheets couched together into a single sheet, such as shown in FIG. 1.
  • [0117]
    The bottom sheet of the tissue was formed from a head box having two layers. The lower layer of the two-layered headbox was supplied with eucalyptus fibers obtained from Bahil Su., Inc. and the upper layer of the two-layered headbox was supplied with northern softwood kraft fibers (LL-19, from Kimberly-Clark.). The top sheet was formed from eucalyptus fibers obtained from Bahil Su., Inc. Each layer of the tissue had its own stock system including stock chest, metering pump, fan pump and white water handling. Each tissue sample had a basis weight of 30 grams per square meter and contained 40% LL-19 softwood fibers and 60% eucalyptus fibers (split equally between each sheet).
  • [0118]
    For Sample No. 16, 4.5 lb/T “Parez” polyacrylamide temporary wet strength agent (also functions as a dry strength agent) and 16.5 lb/T of Mackernium DC-183, a imidazoline quaternary debonder available from McIntyre, Inc., were applied to the eucalyptus stock chests supplied to the two-layered headbox and top sheet. In addition, 8 lb/T “Parez” polyacrylamide temporary wet strength agent (also functions as dry strength agent) was applied to the LL-19 stock pump. The LL-19 fibers were subjected to 10 minutes refining with a refiner located below the stock chest.
  • [0119]
    Sample 17 was prepared in an identical manner to Sample 16, except that 10 lb/T of Airflex A-105, a vinyl-acetate ethylene copolymer latex available from Air Products, was sprayed onto the eucalyptus layer of the lower sheet between the rush transfer section and the through-air dryer (See FIG. 3) while the sheet had a solids consistency of about 20%. The latex was sprayed onto the sheet using an H ⅛″ W-SS 650017 VeeJet spray nozzle available from Spraying Systems, Inc. of Milwaukee, Wis. The nozzle sprayed the latex onto the sheet at a 65° angle to the sheet at a rate of 0.017 gallons per minute and a pressure of 40 pounds per square inch. In addition, 6 lb/T “Parez” polyacrylamide temporary wet strength agent (also functions as dry strength agent) was applied to the LL-19 stock pump.
  • [0120]
    Sample 18 was prepared in an identical manner to Sample 17, except that the latex utilized was an anionic styrene-butadiene latex available from Dow Chemical under the trade designation “DL-239”. In addition, 7 lb/T “Parez” polyacrylamide temporary wet strength agent (also functions as dry strength agent) was applied to the LL-19 stock pump.
  • [0121]
    Once formed, the tensile strength, slough, and stiffness of the samples were determined as set forth in Example 7. The results are provide below in Table 8.
    TABLE 8
    Sample Results
    Sample GMT (grams/3 inches) Slough (mg) Panel Stiffness
    16 896 9.50 4.47
    17 707 7.36 4.53
    18 823 6.83 4.69
  • [0122]
    As indicated from the results set forth in Table 8, the addition of a latex in accordance with the present invention can provide a soft tissue product that is strong and produces relatively low amounts of slough.
  • [0123]
    While the invention has been described in detail with respect to the specific embodiments thereof, it will be appreciated that those skilled in the art, upon attaining an understanding of the foregoing, may readily conceive of alterations to, variations of, and equivalents to these embodiments. Accordingly, the scope of the present invention should be assessed as that of the appended claims and any equivalents thereto.
Citas de patentes
Patente citada Fecha de presentación Fecha de publicación Solicitante Título
US2345543 *31 Jul 194228 Mar 1944American Cyanamid CoCationic melamine-formaldehyde resin solution
US2745744 *9 Feb 195115 May 1956Permacel Tape CorpTreating agents incorporation
US2926116 *5 Sep 195723 Feb 1960Hercules Powder Co LtdWet-strength paper and method of making same
US2926154 *3 Mar 195923 Feb 1960Hercules Powder Co LtdCationic thermosetting polyamide-epichlorohydrin resins and process of making same
US3104198 *20 Oct 195917 Sep 1963Union Carbide CorpPapers with improved absorbent properties
US3256138 *8 Feb 196514 Jun 1966John A Manning Paper Co IncApplication of resin particles to a wet fibrous ply in forming a multi-ply water-laid web
US3556932 *17 Jul 196819 Ene 1971American Cyanamid CoWater-soluble,ionic,glyoxylated,vinylamide,wet-strength resin and paper made therewith
US3556933 *2 Abr 196919 Ene 1971American Cyanamid CoRegeneration of aged-deteriorated wet strength resins
US3695985 *29 Jul 19703 Oct 1972Kimberly Clark CoHigh bulk laminates
US3700623 *22 Abr 197024 Oct 1972Hercules IncReaction products of epihalohydrin and polymers of diallylamine and their use in paper
US3812000 *24 Jun 197121 May 1974Scott Paper CoSoft,absorbent,fibrous,sheet material formed by avoiding mechanical compression of the elastomer containing fiber furnished until the sheet is at least 80%dry
US3821068 *17 Oct 197228 Jun 1974Scott Paper CoSoft,absorbent,fibrous,sheet material formed by avoiding mechanical compression of the fiber furnish until the sheet is at least 80% dry
US3844880 *20 Jul 197329 Oct 1974Scott Paper CoSequential addition of a cationic debonder, resin and deposition aid to a cellulosic fibrous slurry
US3862877 *22 May 197228 Ene 1975Buckeye Cellulose CorpClothlike tissue laminates
US3879257 *30 Abr 197322 Abr 1975Scott Paper CoAbsorbent unitary laminate-like fibrous webs and method for producing them
US3885158 *23 Oct 197320 May 1975Harris CorpSpecimen block and specimen block holder
US3899388 *26 Feb 197312 Ago 1975Monsanto CoTreating compositions
US3903342 *30 Abr 19732 Sep 1975Scott Paper CoSoft, absorbent, unitary, laminate-like fibrous web with delaminating strength and method for producing it
US4018647 *10 Jun 197419 Abr 1977Chemische Industrie Aku-Goodrick B.V.Process for the impregnation of a wet fiber web with a heat sensitized foamed latex binder
US4081318 *16 Jul 197628 Mar 1978Chemische Industrie Aku-Goodrich B.V.Preparation of impregnated fibers
US4094717 *31 Ene 197713 Jun 1978Aai CorporationMethod of assembly of an insulating panel arrangement
US4099913 *25 Mar 197611 Jul 1978Union Carbide CorporationFoams for treating fabrics
US4121966 *4 Feb 197724 Oct 1978Mitsubishi Paper Mills, Ltd.Method for producing fibrous sheet
US4147586 *9 Ene 19783 Abr 1979Monsanto CompanyCellulosic paper containing the reaction product of a dihaloalkane alkylene diamine adduct and epihalohydrin
US4158594 *24 Jun 197119 Jun 1979Scott Paper CompanyBonded, differentially creped, fibrous webs and method and apparatus for making same
US4208459 *12 Nov 197617 Jun 1980Becker Henry EBonded, differentially creped, fibrous webs and method and apparatus for making same
US4222921 *19 Jun 197816 Sep 1980Monsanto CompanyPolyamine/epihalohydrin reaction products
US4326000 *29 Oct 197520 Abr 1982Scott Paper CompanySoft, absorbent, unitary, laminate-like fibrous web
US4351699 *15 Oct 198028 Sep 1982The Procter & Gamble CompanySoft, absorbent tissue paper
US4392861 *14 Oct 198012 Jul 1983Johnson & Johnson Baby Products CompanyTwo-ply fibrous facing material
US4441962 *30 Jul 198210 Abr 1984The Procter & Gamble CompanySoft, absorbent tissue paper
US4445972 *16 Feb 19821 May 1984Papeteries de Jean d'HeursProcess for the continuous manufacture in an aqueous medium of sheets made of fibrous material and containing latex or similar and/or phenoplasts or aminoplasts, sheets obtained by said process and their possible re-use
US4447294 *30 Dic 19818 May 1984The Procter & Gamble CompanyProcess for making absorbent tissue paper with high wet strength and low dry strength
US4507173 *22 Sep 198226 Mar 1985James River-Norwalk, Inc.Pattern bonding and creping of fibrous products
US4510019 *17 Nov 19829 Abr 1985Papeteries De Jeand'heursLatex containing papers
US4581254 *22 Mar 19858 Abr 1986Union Carbide CorporationFoam applicator used in paper treatment
US4603176 *25 Jun 198529 Jul 1986The Procter & Gamble CompanyTemporary wet strength resins
US4604313 *23 Abr 19845 Ago 1986Kimberly-Clark CorporationSelective layering of superabsorbents in meltblown substrates
US4605702 *27 Jun 198412 Ago 1986American Cyanamid CompanyTemporary wet strength resin
US4755421 *7 Ago 19875 Jul 1988James River Corporation Of VirginiaHydroentangled disintegratable fabric
US4795668 *31 Jul 19873 Ene 1989Minnesota Mining And Manufacturing CompanyBicomponent fibers and webs made therefrom
US4822452 *18 Jul 198818 Abr 1989James River Corporation Of VirginiaManufacture of wet laid nonwoven webs
US4849054 *14 Ene 198818 Jul 1989James River-Norwalk, Inc.High bulk, embossed fiber sheet material and apparatus and method of manufacturing the same
US4925528 *6 Abr 198915 May 1990James River Corporation Of VirginiaManufacture of wetlaid nonwoven webs
US4940513 *5 Dic 198810 Jul 1990The Procter & Gamble CompanyProcess for preparing soft tissue paper treated with noncationic surfactant
US4959125 *5 Dic 198825 Sep 1990The Procter & Gamble CompanySoft tissue paper containing noncationic surfactant
US5019211 *11 Oct 198828 May 1991Kimberly-Clark CorporationTissue webs containing curled temperature-sensitive bicomponent synthetic fibers
US5048589 *18 Dic 198917 Sep 1991Kimberly-Clark CorporationNon-creped hand or wiper towel
US5102501 *7 Jul 19887 Abr 1992James River-Norwalk, Inc.Multiple layer fibrous web products of enhanced bulk and method of manufacturing same
US5108820 *20 Abr 199028 Abr 1992Mitsui Petrochemical Industries, Ltd.Soft nonwoven fabric of filaments
US5129988 *21 Jun 199114 Jul 1992Kimberly-Clark CorporationExtended flexible headbox slice with parallel flexible lip extensions and extended internal dividers
US5238534 *24 Ene 199224 Ago 1993James River Corporation Of VirginiaWetlaid nonwovens on high speed machines
US5240562 *27 Oct 199231 Ago 1993Procter & Gamble CompanyPaper products containing a chemical softening composition
US5277976 *7 Oct 199111 Ene 1994Minnesota Mining And Manufacturing CompanyOriented profile fibers
US5336552 *26 Ago 19929 Ago 1994Kimberly-Clark CorporationNonwoven fabric made with multicomponent polymeric strands including a blend of polyolefin and ethylene alkyl acrylate copolymer
US5382400 *21 Ago 199217 Ene 1995Kimberly-Clark CorporationNonwoven multicomponent polymeric fabric and method for making same
US5385643 *10 Mar 199431 Ene 1995The Procter & Gamble CompanyProcess for applying a thin film containing low levels of a functional-polysiloxane and a nonfunctional-polysiloxane to tissue paper
US5397435 *22 Oct 199314 Mar 1995Procter & Gamble CompanyMulti-ply facial tissue paper product comprising chemical softening compositions and binder materials
US5399412 *21 May 199321 Mar 1995Kimberly-Clark CorporationUncreped throughdried towels and wipers having high strength and absorbency
US5405501 *30 Jun 199311 Abr 1995The Procter & Gamble CompanyMulti-layered tissue paper web comprising chemical softening compositions and binder materials and process for making the same
US5409768 *7 Abr 199425 Abr 1995Kimberly-Clark CorporationMulticomponent nonwoven fibrous web
US5427696 *14 Ene 199327 Jun 1995The Procter & Gamble CompanyBiodegradable chemical softening composition useful in fibrous cellulosic materials
US5437766 *22 Oct 19931 Ago 1995The Procter & Gamble CompanyMulti-ply facial tissue paper product comprising biodegradable chemical softening compositions and binder materials
US5494554 *30 Mar 199427 Feb 1996Kimberly-Clark CorporationMethod for making soft layered tissues
US5510000 *20 Sep 199423 Abr 1996The Procter & Gamble CompanyPaper products containing a vegetable oil based chemical softening composition
US5510001 *14 Sep 199423 Abr 1996Kimberly-Clark CorporationMethod for increasing the internal bulk of throughdried tissue
US5529665 *8 Ago 199425 Jun 1996Kimberly-Clark CorporationMethod for making soft tissue using cationic silicones
US5543067 *2 Nov 19946 Ago 1996The Procter & Gamble CompanyWaterless self-emulsiviable biodegradable chemical softening composition useful in fibrous cellulosic materials
US5558873 *8 Mar 199524 Sep 1996Kimberly-Clark CorporationSoft tissue containing glycerin and quaternary ammonium compounds
US5591309 *6 Feb 19957 Ene 1997Kimberly-Clark CorporationPapermaking machine for making uncreped throughdried tissue sheets
US5667636 *27 Oct 199416 Sep 1997Kimberly-Clark Worldwide, Inc.Method for making smooth uncreped throughdried sheets
US5716498 *12 Abr 199610 Feb 1998Witco CorporationProcess for softening paper in manufacture
US5730839 *21 Jul 199524 Mar 1998Kimberly-Clark Worldwide, Inc.Method of creping tissue webs containing a softener using a closed creping pocket
US5885418 *19 May 199723 Mar 1999Kimberly-Clark Worldwide, Inc.High water absorbent double-recreped fibrous webs
US5935383 *6 Mar 199810 Ago 1999Kimberly-Clark Worldwide, Inc.Method for improved wet strength paper
US6017417 *7 Oct 199725 Ene 2000Kimberly-Clark Worldwide, Inc.Method of making soft tissue products
US6017418 *6 May 199725 Ene 2000Fort James CorporationHydrophilic, humectant, soft, pliable, absorbent paper and method for its manufacture
US6096152 *30 Abr 19971 Ago 2000Kimberly-Clark Worldwide, Inc.Creped tissue product having a low friction surface and improved wet strength
US6200669 *26 Nov 199613 Mar 2001Kimberly-Clark Worldwide, Inc.Entangled nonwoven fabrics and methods for forming the same
US6203663 *5 May 199520 Mar 2001Kimberly-Clark Worldwide, Inc.Decorative formation of tissue
US6211139 *13 Oct 19983 Abr 2001Goldschmidt Chemical CorporationPolyester polyquaternary compounds, compositions containing them, and use thereof
US6231719 *19 Dic 199715 May 2001Kimberly-Clark Worldwide, Inc.Uncreped throughdried tissue with controlled coverage additive
US6241850 *16 Jun 19995 Jun 2001The Procter & Gamble CompanySoft tissue product exhibiting improved lint resistance and process for making
US6248211 *9 Ago 199919 Jun 2001Kimberly-Clark Worldwide, Inc.Method for making a throughdried tissue sheet
US6248212 *30 Dic 199719 Jun 2001Kimberly-Clark Worldwide, Inc.Through-air-dried post bonded creped fibrous web
US6261580 *31 Ago 199817 Jul 2001The Procter & Gamble CompanyTissue paper with enhanced lotion transfer
US6277241 *14 Nov 199721 Ago 2001Kimberly-Clark Worldwide, Inc.Liquid absorbent base web
US6368609 *12 Abr 19999 Abr 2002Kimberly-Clark Worldwide, Inc.Absorbent structure including a thin, calendered airlaid composite and a process for making the composite
US6387495 *7 Abr 200014 May 2002Kimberly-Clark Worldwide, Inc.Superabsorbent-containing composites
US6423180 *30 Nov 199923 Jul 2002Kimberly-Clark Worldwide, Inc.Soft and tough paper product with high bulk
US6432270 *20 Feb 200113 Ago 2002Kimberly-Clark Worldwide, Inc.Soft absorbent tissue
US6534151 *9 Abr 200118 Mar 2003Kimberly-Clark Worldwide, Inc.Creped wiping product containing binder fibers
US6585855 *11 May 20011 Jul 2003Kimberly-Clark Worldwide, Inc.Paper product having improved fuzz-on-edge property
US6852197 *22 Jul 20028 Feb 2005Akzo Nobel NvWet strong tissue paper
US20040065422 *8 Oct 20028 Abr 2004Kimberly-Clark Worldwide, Inc.Tissue products having reduced slough
US20040084162 *6 Nov 20026 May 2004Shannon Thomas GerardLow slough tissue products and method for making same
US20060081349 *4 Feb 200520 Abr 2006Bakken Andrew PNon-woven through air dryer and transfer fabrics for tissue making
US20060144541 *30 Dic 20046 Jul 2006Deborah Joy NickelSoftening agent pre-treated fibers
Citada por
Patente citante Fecha de presentación Fecha de publicación Solicitante Título
US7189307 *2 Sep 200313 Mar 2007Kimberly-Clark Worldwide, Inc.Low odor binders curable at room temperature
US7229529 *15 Jul 200412 Jun 2007Kimberly-Clark Worldwide, Inc.Low odor binders curable at room temperature
US767822817 Sep 200716 Mar 2010Kimberly-Clark Worldwide, Inc.Binders curable at room temperature with low blocking
US7678856 *17 Sep 200716 Mar 2010Kimberly-Clark Worldwide Inc.Binders curable at room temperature with low blocking
US77854437 Dic 200631 Ago 2010Kimberly-Clark Worldwide, Inc.Process for producing tissue products
US780702314 Jun 20075 Oct 2010Kimberly-Clark Worldwide, Inc.Process for increasing the basis weight of sheet materials
US782001015 Dic 200526 Oct 2010Kimberly-Clark Worldwide, Inc.Treated tissue products having increased strength
US783783115 Dic 200523 Nov 2010Kimberly-Clark Worldwide, Inc.Tissue products containing a polymer dispersion
US784216315 Dic 200530 Nov 2010Kimberly-Clark Worldwide, Inc.Embossed tissue products
US78791887 Dic 20061 Feb 2011Kimberly-Clark Worldwide, Inc.Additive compositions for treating various base sheets
US787918914 Jun 20071 Feb 2011Kimberly-Clark Worldwide, Inc.Additive compositions for treating various base sheets
US787919014 Jun 20071 Feb 2011Kimberly-Clark Worldwide, Inc.Tissue products with controlled lint properties
US787919114 Jun 20071 Feb 2011Kimberly-Clark Worldwide, Inc.Wiping products having enhanced cleaning abilities
US788360415 Dic 20058 Feb 2011Kimberly-Clark Worldwide, Inc.Creping process and products made therefrom
US810546320 Mar 200931 Ene 2012Kimberly-Clark Worldwide, Inc.Creped tissue sheets treated with an additive composition according to a pattern
US82628571 Jul 201011 Sep 2012Kimberly-Clark Worldwide, Inc.Process for producing tissue products
US828277621 Jun 20079 Oct 2012Kimberly-Clark Worldwide, Inc.Wiping product having enhanced oil absorbency
US828277730 Mar 20099 Oct 2012Sellars Absorbent Materials, Inc.Disposable wipers and towels containing 40% or more post-consumer waste
US841473718 Abr 20129 Abr 2013Wisconsin Note Investors, LlcMethod of manufacturing disposable wipers and towels containing 40% or more post-consumer waste
US844481114 Jun 200721 May 2013Kimberly-Clark Worldwide, Inc.Process for increasing the basis weight of sheet materials
US846621616 Abr 200718 Jun 2013Kimberly-Clark Worldwide, Inc.Low odor binders curable at room temperature
US851251531 Ene 201120 Ago 2013Kimberly-Clark Worldwide, Inc.Wiping products having enhanced cleaning abilities
US856856130 Ene 201229 Oct 2013Kimberly-Clark Worldwide, Inc.Creped tissue sheets treated with an additive composition according to a pattern
US889481317 Ago 201225 Nov 2014Kimberly-Clark Worldwide, Inc.Absorbent barrier tissue
US891602512 Mar 201323 Dic 2014Sellars Absorbent Materials, Inc.Disposable wipers and towels containing 100% recycled fibers
US928373017 Ago 201215 Mar 2016Kimberly-Clark Worldwide, Inc.High basis weight creped tissue
US94999425 Feb 201622 Nov 2016Kimberly-Clark Worldwide, Inc.High basis weight creped tissue
US20040043200 *28 Ago 20024 Mar 2004Masek Jan K.Pliable paper
US20050045293 *2 Sep 20033 Mar 2005Hermans Michael AlanPaper sheet having high absorbent capacity and delayed wet-out
US20050045294 *2 Sep 20033 Mar 2005Goulet Mike ThomasLow odor binders curable at room temperature
US20050045295 *15 Jul 20043 Mar 2005Kimberly-Clark Worldwide, Inc.Low odor binders curable at room temperature
US20050238860 *10 Dic 200427 Oct 2005Fuji Xerox Co., Ltd.Electrophotographic transfer paper and image forming method
US20060124261 *9 Nov 200515 Jun 2006Lindsay Jeffrey DMethod of making a clothlike pattern densified web
US20060144536 *30 Dic 20046 Jul 2006Nickel Deborah JSoft and durable tissues made with thermoplastic polymer complexes
US20060144541 *30 Dic 20046 Jul 2006Deborah Joy NickelSoftening agent pre-treated fibers
US20060159305 *16 Dic 200520 Jul 2006Asml Netherlands B.V.Imprint lithography
US20070137813 *15 Dic 200521 Jun 2007Kimberly-Clark Worldwide, Inc.Embossed tissue products
US20080006381 *17 Sep 200710 Ene 2008Goulet Mike TBinders curable at room temperature with low blocking
US20100243186 *30 Mar 200930 Sep 2010Sellars Absorbent Materials, Inc.Disposable wipers and towels containing 40% or more post-consumer waste
Clasificaciones
Clasificación de EE.UU.162/123, 162/168.2, 162/179, 162/169, 162/168.3
Clasificación internacionalD21H21/22, D21F11/14, D21H17/35, D21H23/76, D21H21/20, D21F11/04
Clasificación cooperativaD21H23/76, D21H21/20, D21H17/35, D21F11/14, D21F11/145, D21F11/04, D21H21/22
Clasificación europeaD21F11/14B, D21F11/14, D21H23/76, D21F11/04
Eventos legales
FechaCódigoEventoDescripción
12 Ago 2002ASAssignment
Owner name: KIMBERLY-CLARK WORLDWIDE, INC., WISCONSIN
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:HU, SHENG-HSIN;CHEN, SHAN;MAKOUI, KAMBIZ BAYAT;REEL/FRAME:013187/0659
Effective date: 20020207
4 Sep 2002ASAssignment
Owner name: KIMBERLY-CLARK WORLDWIDE, INC., WISCONSIN
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:CHUANG, STRONG C.;REEL/FRAME:013262/0437
Effective date: 20020824