US20030183426A1 - Polycrystalline Material Element with Improved Wear Resistance And Methods of Manufacture Thereof - Google Patents
Polycrystalline Material Element with Improved Wear Resistance And Methods of Manufacture Thereof Download PDFInfo
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- US20030183426A1 US20030183426A1 US10/249,199 US24919903A US2003183426A1 US 20030183426 A1 US20030183426 A1 US 20030183426A1 US 24919903 A US24919903 A US 24919903A US 2003183426 A1 US2003183426 A1 US 2003183426A1
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- 239000013078 crystal Substances 0.000 claims abstract description 81
- 229910003460 diamond Inorganic materials 0.000 claims abstract description 79
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- 229910017052 cobalt Inorganic materials 0.000 claims description 9
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- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 9
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- C04B35/52—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite
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- E—FIXED CONSTRUCTIONS
- E21—EARTH DRILLING; MINING
- E21B—EARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
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Definitions
- the invention relates to superhard polycrystalline material elements for wear, cutting, drawing, and other applications where engineered superhard surfaces are needed.
- the invention particularly relates to polycrystalline diamond and polycrystalline diamond-like (collectively called PCD) elements with greatly improved wear resistance and methods of manufacturing them.
- PCD elements Polycrystalline diamond and polycrystalline diamond-like elements are known, for the purposes of this specification, as PCD elements.
- PCD elements are formed from carbon based materials with exceptionally short inter-atomic distances between neighboring atoms.
- One type of diamond-like material similar to PCD is known as carbonitride (CN) described in U.S. Pat. No. 5,776,615.
- CN carbonitride
- PCD elements are formed from a mix of materials processed under high-temperature and high-pressure into a polycrystalline matrix of inter-bonded superhard carbon based crystals.
- a common trait of PCD elements is the use of catalyzing materials during their formation, the residue from which often imposes a limit upon the maximum useful operating temperature of the element while in service.
- PCD element A well known, manufactured form of PCD element is a two-layer or multi-layer PCD element where a facing table of polycrystalline diamond is integrally bonded to a substrate of less hard material, such as tungsten carbide.
- the PCD element may be in the form of a circular or part-circular tablet, or may be formed into other shapes, suitable for applications such as hollow dies, friction bearings, valve surfaces, indentors, tool mandrels, etc.
- PCD elements of this type may be used in almost any application where a hard wear and erosion resistant material is required.
- the substrate of the PCD element may be brazed to a carrier, often also of cemented tungsten carbide.
- PCDs used as cutting elements, for example in fixed cutter or rolling cutter earth boring bits when received in a socket of the drill bit, or when fixed to a post in a machine tool for machining.
- PCD elements are typically called polycrystalline diamond cutters (PDC).
- PCD elements are most often formed by sintering diamond powder with a suitable binder-catalyzing material in a high-pressure, high-temperature press.
- a suitable binder-catalyzing material in a high-pressure, high-temperature press.
- One particular method of forming this polycrystalline diamond is disclosed in U.S. Pat. No. 3,141,746 herein incorporated by reference for all it discloses.
- diamond powder is applied to the surface of a preformed tungsten carbide substrate incorporating cobalt. The assembly is then subjected to very high temperature and pressure in a press.
- cobalt migrates from the substrate into the diamond layer and acts as a binder-catalyzing material, causing the diamond particles to bond to one another with diamond-to-diamond bonding, and also causing the diamond layer to bond to the substrate.
- a finishing operation is performed which typically includes a step of machining the PCD.
- the machining operation may be similar to that described in U.S. Pat. No. 5,447,208 in which progressively smaller diamond grit particles are used to produce a highly polished working surface on the diamond material.
- the use of progressively small grit sizes is not essential, and depending upon the application in which the PCD is to be used, a less polished finish may be acceptable, in which case the machining operation may be performed with, say, only one relatively coarse diamond grit size.
- the action of the diamond grit on the working surface of the PCD during the machining operation is to cause slightly projecting parts of the PCD (at a microscopic level) to be worn or broken away from the remainder thereof to flat a working surface of good flatness.
- the finish working surface is of very good flatness, but will still include small scratches formed by the action of the diamond grit on the working surface.
- the machining operation causes the formation of very small fractures, referred to herein as microfractures, in the diamond crystals which are exposed at the working surface. These crystals may also be subject to other damage during the machining operation. It is thought that, in subsequent use, cracks may propagate relatively easily along the microfractures, and hence that the PCD finished in this manner is relatively weak, being of relatively low wear resistance.
- cobalt is most commonly used as the binder-catalyzing material
- any group VIII element including cobalt, nickel, iron, and alloys thereof, may be employed.
- thermally stable polycrystalline diamond silicon is used as the catalyzing material.
- the process for making polycrystalline diamond with a silicon catalyzing material is quite similar to that described above, except that at synthesis temperatures and pressures, most of the silicon is reacted to form silicon carbide, which is not an effective catalyzing material.
- the thermal resistance is somewhat improved, but thermal degradation still occurs due to some residual silicon remaining, generally uniformly distributed in the interstices of the interstitial matrix. There are mounting problems with this type of PCD element because there is no bondable surface.
- PCD carbonates
- Mg, Ca, Sr, and Ba carbonates
- PCD of this type typically has greater wear-resistance and hardness than the previous types of PCD elements.
- the material is difficult to produce on a commercial scale since much higher pressures are required for sintering than is the case with conventional and thermally stable polycrystalline diamond.
- thermal degradation may still occur due to the residual binder-catalyzing material remaining in the interstices. Again, because there is no integral substrate or other bondable surface, there are difficulties in mounting this material to a working surface.
- the present invention provides a superhard polycrystalline diamond or diamond-like element with improved wear resistance.
- PCD elements for the purposes of this specification, these elements are formed with a binder-catalyzing material in a high-temperature, high-pressure (HTHP) process.
- the diamond material is formed and integrally bonded to a substrate containing the catalyzing material during the HTHP process.
- the diamond body so formed has a working surface, a plurality of crystals being exposed at the working surface, and wherein the crystals exposed at at least a portion of the working surface are substantially free of microfractures as formed.
- the PCD element may be used in a wide range of applications.
- the PCD element may find applications in downhole equipment, either in cutters or for use in wear resistant bearings.
- the PCD element may alternatively be used in hollow dies, friction bearings, valve surfaces, indentors, tool mandrels and a wide range of other applications.
- the PCD element may be used in the machining of abrasive materials, for example abrasive wood materials, ferrous and non-ferrous materials, and hard or very abrasive engineering materials such as stone, asphalt and the like.
- a PCD element comprising a body including matrix of crystals of a superhard material, the body having a surface, a plurality of the crystals being exposed at the surface, wherein upon completion of the manufacturing process, at least the exposed part of each of the crystals exposed at at least a portion of the surface has a rounded shape. Crystals of this form are substantially free of microfractures and other defects and so a PCD of this form is of improved wear resistance.
- the PCD element conveniently comprises a substrate having a front surface, a table of superhard material being bonded to the substrate, the table of superhard material comprising a matrix of crystals.
- the crystals of superhard material conveniently comprise diamond crystals.
- the invention also relates to a PCD element which comprises a substrate having a front surface, a table of superhard material being bonded to the front surface of the substrate, the table of superhard material comprising a matrix of crystals, the table having a surface at which a plurality of the crystals are exposed, at least the exposed parts of the crystals which are exposed at at least a portion of the surface being substantially free of microfractures.
- the exposed parts of the exposed crystals are preferably of rounded form.
- a method of manufacturing a PCD element comprising:sintering diamond powder with a binder-catalyst material in a high pressure, high temperature press to-form a body including a matrix of diamond crystals;performing a machining operation on the body to form a working surface thereon at which a plurality of diamond crystals are exposed; and treating the body to render the crystals which are exposed at at least a portion of the working surface substantially free of microfractures.
- the step of treating the body may include performing a machining operation on the body in the absence of a coolant material.
- the step of treating the body may include performing a machining operation on the body with a restricted coolant supply.
- the temperature of the diamond crystals at the exposed surface is raised, and extremely high local temperatures and pressures are reached such that the exposed diamond surface becomes plastic. Under these conditions, the exposed surface of the diamond crystals can undergo limited plastic flow and thereby deform to generate a smooth rounded surface which is substantially free of microfractures. It is believed that the extreme localized surface temperature attained during this treatment is in excess of 2000° C.
- the machining operation may be an ultra-high speed grinding operation.
- the step of treating the body may include performing a thermochemical treatment on the body.
- the thermochemical treatment may involve the treatment of the working surface of the body with at least one oxidizing compound, or the treatment thereof with at least one iron group element.
- a method of manufacturing a PCD element comprising:sintering diamond powder with a binder-catalyst material in a high pressure, high temperature press to form a body including a matrix of diamond crystals;performing a machining operation on the body to form a working surface thereon at which a plurality of diamond crystals are exposed; and treating the body to render at least the exposed parts of the crystals exposed at at least a portion of the working surface of rounded form.
- Crystals treated so as to be of rounded form are substantially free of microfractures and other surface defects, and so a PCD manufactured in accordance with the invention has the advantage that it is of improved wear resistance as the likelihood of cracks propagating through the crystals thereof is reduced.
- FIG. 1 is a typical PCD element of the present invention.
- FIG. 2 is a micro-structural representation of part of the PCD element.
- FIG. 3 is a diagrammatic representation illustrating the crystal structure of part of a typical PCD element close to a working surface thereof.
- FIG. 4 is a view similar to FIG. 3 but illustrating the structure of a PCD in accordance with an embodiment of the invention.
- FIG. 5 is a typical PCD of the present invention shown as a cutting element.
- FIG. 6 is a perspective view of an insert used in machine tools utilizing the PCD element of the present invention.
- FIG. 7 is a perspective view of a dome shaped PCD element suitable for use in both rolling cutter drill bits and in fixed cutter drill bits.
- FIG. 8 is a side view of a fixed cutter rotary drill bit using a PCD element of the present invention.
- FIG. 9 is a perspective view of a rolling cutter rotary drill bit using a PCD element of the present invention.
- FIG. 10 is a section view of a wire drawing die having a PCD element of the present invention.
- FIG. 11 is perspective view of a bearing having a PCD element of the present invention.
- FIGS. 12 and 13 are front views of the mating parts of a valve having a PCD element of the present invention.
- FIG. 14 is a side view of an indentor having a PCD element of the present invention.
- FIG. 15 is a partial section view of a punch having a PCD element of the present invention.
- FIG. 16 is perspective view of a measuring device having a PCD element of the present invention.
- the polycrystalline diamond or diamond-like material (PCD) element 2 of the present invention is shown in FIG. 1.
- the PCD element 2 has a plurality of partially bonded superhard, diamond or diamond-like, crystals 60 , (shown in FIG. 2) a catalyzing material 64 , and an interstitial matrix 68 formed by the interstices 62 among the crystals 60 .
- the element 2 also has one or more working surfaces 4 and the diamond crystals 60 and the interstices 62 form the volume of the body 8 of the PCD element 2 .
- the element 2 is integrally formed with a metallic substrate 6 , typically tungsten carbide with a cobalt binder material.
- the volume density of the diamond in the body 8 should be greater than 85 volume %, and preferably be higher than 90%.
- the working surface 4 is any portion of the PCD body 8 which, in operation, may contact the object to be worked. In this specification, when the working surface 4 is discussed, it is understood that it applies to any portion of the body 8 which may be exposed and/or used as a working surface. Furthermore, any portion of any of the working surface 4 is, in and of itself, a working surface.
- FIG. 2 it is well known that there is a random crystallographic orientation of the diamond or diamond-like crystals 60 as shown by the parallel lines 61 representing the cleavage planes of each crystal 60 .
- adjacent crystals 60 have bonded together with interstitial spaces 62 among them.
- the cleavage planes 61 are oriented in different directions on adjacent crystals 60 there is generally no straight path available for diamond fracture. This structure allows PCD materials to perform well in extreme loading environments where high impact loads are common.
- the average diamond volume density in the body 8 of the PCD element 2 of the present invention ranges from about 85% to about 99%.
- the high diamond volume density is achieved by using diamond crystals 60 with a range of particle sizes, with an average particle size ranging from about 30 to about 60 microns.
- the diamond mixture may comprise 20% to 60% diamond crystals 60 in the 5-15 micron range, 20% to 40% diamond crystals 60 in the 25-40 micron range, and 20% to 40% diamond crystals 60 in the 50-80 micron diameter range, although numerous other size ranges and percentages may be used.
- This mixture of large and small diamond crystals 60 allows the diamond crystals 60 to have relatively high percentages of their outer surface areas dedicated to diamond-to-diamond bonding, often approaching 95%, contributing to a relatively high apparent abrasion resistance.
- a cleaning operation in performed on the element 2 .
- the cleaning operation includes a finishing operation of machining the working surfaces 4 of the element 2 to improve the smoothness thereof and to remove macroscopic defects therefrom.
- the crystals 60 of the element 2 include a plurality of crystals 65 exposed at the working surfaces 4 . As described hereinbefore, it is thought that the machining operation induces the formation of microfractures 63 and other defects into the crystals 65 of the element 2 which are exposed at the working surface 4 , as shown in FIG. 3.
- the element 2 is treated to render the crystals 65 exposed at the working surfaces 4 thereof, or at at least a portion of the working surface thereof, for example around at least a part of an edge portion 5 of the element 2 , substantially free of microfractures 70 and other surface defects.
- the treatment comprises performing a machining operation, for example an ultra-high speed grinding operation, in the absence of a coolant, or with a restricted coolant supply so that the machining operation is performed at a significantly higher surface temperature than usual.
- the surface temperature reached may be in excess of 2000° C.
- FIG. 4 is a diagrammatic view similar to FIG. 3 illustrating the effect of performing such a machining operation.
- the exposed parts of the crystals 65 exposed at the working surfaces 4 are of rounded or domed form, and are substantially free of stress raisers in the form of microfractures, cracks or other surface defects.
- the step of treating the element 2 to render its working surfaces 4 substantially free of microfractures and other surface defects may involve performing a machining operation in the absence of coolant or with a restricted supply of coolant, it will be appreciated that the element 2 could be treated in other ways to achieve the same result.
- a thermochemical treatment operation could be performed on the element 2 using, for example, iron group elements or oxidizing compounds. Further, combinations of these techniques may be used.
- a PCD element so manufactured may find application in a wide range of uses.
- One particularly useful application for the PCD element 2 of the present invention is as cutting elements 10 , 50 , 52 as shown in FIGS. 5, 6 and 7 .
- the working surface of the PCD cutting elements 10 , 50 , 52 may be a top working surface 70 and/or a peripheral working surface 72 .
- the PCD cutting element 10 of FIG. 5 is one that may be typically used in fixed cutter type rotary drill bits 12 , or for gauge protection in other types of downhole tools.
- the PCD cutting element 50 shown in FIG. 7 may be shaped as a dome 39 . This type of PCD cutting element 50 has an extended base 51 for insertion into sockets in a rolling cutter drill bit 38 or in the body of both types of rotary drill bits, 12 , 38 as will be described in detail.
- the PCD cutting element 52 of FIG. 6 is adapted for use in a machining process.
- the configuration of the cutting element 52 in FIG. 6 is rectangular, it would be appreciated by those skilled in the art that this element could be triangular, quadrilateral or many other shapes suitable for machining highly abrasive products that are difficult to machine with conventional tools.
- the PCD cutting element 10 may be a preform cutting element 10 of a fixed cutter rotary drill bit 12 (as shown in FIG. 8).
- the bit body 14 of the drill bit is formed with a plurality of blades 16 extending generally outwardly away from the central longitudinal axis of rotation 18 of the drill bit. Spaced apart side-by-side along the leading face 20 of each blade is a plurality of the PCD cutting elements 10 of the present invention.
- the PCD cutting element 10 has a body in the form of a circular tablet having a thin front facing table 30 of diamond or diamond-like (PCD) material, bonded in a high-pressure high-temperature press to a substrate 32 of less hard material such as cemented tungsten carbide or other metallic material.
- the cutting element 10 is preformed and then typically bonded on a generally cylindrical carrier 34 which is also formed from cemented tungsten carbide, or may alternatively be attached directly to the blade.
- the PCD cutting element 10 has working surfaces 70 and 72 .
- the cylindrical carrier 34 is received within a correspondingly shaped socket or recess in the blade 16 .
- the carrier 34 will usually be brazed or shrink fit in the socket.
- the fixed cutter drill bit 12 is rotated and weight is applied. This forces the cutting elements 10 into the earth being drilled, effecting a cutting and/or drilling action.
- the PCD cutting elements 10 may also be applied to the gauge region 36 of the bit 12 to provide a gauge reaming action as well as protecting the bit 12 from excessive wear in the gauge region 36 .
- the cutting element 50 (as shown in FIG. 7) of the present invention is on a rolling cutter type drill bit 38 , shown in FIG. 9.
- a rolling cutter drill bit 38 typically has one or more truncated rolling cone cutters 40 , 41 , 42 assembled on a bearing spindle on the leg 44 of the bit body 46 .
- the cutting elements 50 may be mounted as one or more of a plurality of cutting inserts arranged in rows on rolling cutters 40 , 41 , 42 , or alternatively the PCD cutting elements 50 may be arranged along the leg 44 of the bit 38 .
- the PCD cutting element 50 has a body in the form of a facing table 35 of diamond or diamond like material bonded to a less hard substrate 37 .
- the facing table 35 in this embodiment of the present invention is in the form of a domed surface 39 and has working surfaces 70 and 72 . Accordingly, there are often a number of transitional layers between the facing table 35 and the substrate 37 to help more evenly distribute the stresses generated during fabrication, as is well known to those skilled in the art.
- the rolling cutter drill bit 38 is rotated and weight is applied. This forces the cutting inserts 50 in the rows of the rolling cone cutters 40 , 41 , 42 into the earth, and as the bit 36 is rotated the rolling cutters 40 , 41 , 42 turn, effecting a drilling action.
- the PCD cutting element 52 of the present invention is in the form of a triangular, rectangular or other shaped material for use as a cutting insert in machining operations.
- the cutting element 52 has a body in the form of a facing table 54 of diamond or diamond like material bonded to a less hard substrate 56 with working surfaces 70 and 72 .
- the cutting element 52 would then be cut into a plurality of smaller pieces which are subsequently attached to an insert 58 that is mounted in the tool holder of a machine tool.
- the cutting element 52 may be attached to the insert by brazing, adhesives, welding, or clamping. It is also possible to finish form the cutting element 52 in the shape of the insert in a high-temperature high-pressure manufacturing process.
- PCD elements 2 , 102 , 202 of the present invention may also be used for other applications such as hollow dies, shown for example as a wire drawing die, 300 of FIG. 10 utilizing a PCD element 302 of the present invention.
- FIG. 11 Other applications include friction bearings 320 with a PCD bearing element 322 shown in FIG. 11 and the mating parts of a valve 340 , 344 with surfaces 342 having a PCD element 342 of the present invention as shown in FIGS. 12 and 13.
- indentors 360 for scribes, hardness testers, surface roughening, etc. may have PCD elements 362 of the present invention as shown in FIG. 14.
- Punches 370 may have either or both dies 372 , 374 made of the PCD material of the present invention, as shown in FIG. 15.
- tool mandrels 382 and other types of wear elements for measuring devices 380 shown in FIG. 16 may be made of PCD elements of the present inventions.
Abstract
The present invention provides a superhard polycrystalline diamond or diamond-like element with improved wear resistance. Collectively called PCD elements for the purposes of this specification, these elements are formed with a binder-catalyzing material in a high-temperature, high-pressure (HTHP) process. The diamond material is formed and integrally bonded to a substrate containing the catalyzing material during the HTHP process. The diamond body so formed has a working surface, a plurality of crystals being exposed at the working surface, and wherein the exposed crystals are substantially free of microfractures. The exposed parts of the exposed crystals are of rounded or domed form.
Description
- This application claims priority from U.S. Provisional Patent Application No. 60/319,157 filed Mar. 28, 2002, incorporated by reference herein for all it contains.
- 1. Field of the Invention
- The invention relates to superhard polycrystalline material elements for wear, cutting, drawing, and other applications where engineered superhard surfaces are needed. The invention particularly relates to polycrystalline diamond and polycrystalline diamond-like (collectively called PCD) elements with greatly improved wear resistance and methods of manufacturing them.
- 2. Description of Related Art
- Polycrystalline diamond and polycrystalline diamond-like elements are known, for the purposes of this specification, as PCD elements. PCD elements are formed from carbon based materials with exceptionally short inter-atomic distances between neighboring atoms. One type of diamond-like material similar to PCD is known as carbonitride (CN) described in U.S. Pat. No. 5,776,615. In general, PCD elements are formed from a mix of materials processed under high-temperature and high-pressure into a polycrystalline matrix of inter-bonded superhard carbon based crystals. A common trait of PCD elements is the use of catalyzing materials during their formation, the residue from which often imposes a limit upon the maximum useful operating temperature of the element while in service.
- A well known, manufactured form of PCD element is a two-layer or multi-layer PCD element where a facing table of polycrystalline diamond is integrally bonded to a substrate of less hard material, such as tungsten carbide. The PCD element may be in the form of a circular or part-circular tablet, or may be formed into other shapes, suitable for applications such as hollow dies, friction bearings, valve surfaces, indentors, tool mandrels, etc. PCD elements of this type may be used in almost any application where a hard wear and erosion resistant material is required. The substrate of the PCD element may be brazed to a carrier, often also of cemented tungsten carbide. This is a common configuration for PCDs used as cutting elements, for example in fixed cutter or rolling cutter earth boring bits when received in a socket of the drill bit, or when fixed to a post in a machine tool for machining. These PCD elements are typically called polycrystalline diamond cutters (PDC).
- There are numerous variations in the methods of manufacture of these PDC elements. For example various ranges of average diamond particle sizes may be utilized in the manufacture to enhance wear properties as shown in U.S. Pat. Nos., 4,861,350; 5,468,268; and 5,545,748 all herein incorporated by reference for all they disclose. Also, methods to provide a range of wear resistance across or into the working surface of a PDC are shown in U.S. Pat. Nos. 5,135,061 and 5,607,024 also herein incorporated by reference for all they disclose. However, because the wear resistance is varied by changing the average size of the diamond particles, there is an inherent trade-off between impact strength and wear resistance in these designs. As a consequence, the PDC elements with the higher wear resistance will tend to have poor impact strength, which for PDC's used in drilling applications, is often unacceptable.
- Typically, higher diamond volume densities in the diamond table increases wear resistance at the expense of impact strength. However, modern PDC elements typically utilize often complex geometrical interfaces between the diamond table and the substrate as well as other physical design configurations to improve the impact strength. Although this allows wear resistance and impact strength to be simultaneously maximized, the tradeoff still exists, and has not significantly changed for the past several years prior to the present invention.
- PCD elements are most often formed by sintering diamond powder with a suitable binder-catalyzing material in a high-pressure, high-temperature press. One particular method of forming this polycrystalline diamond is disclosed in U.S. Pat. No. 3,141,746 herein incorporated by reference for all it discloses. In one common process for manufacturing PCD elements, diamond powder is applied to the surface of a preformed tungsten carbide substrate incorporating cobalt. The assembly is then subjected to very high temperature and pressure in a press. During this process, cobalt migrates from the substrate into the diamond layer and acts as a binder-catalyzing material, causing the diamond particles to bond to one another with diamond-to-diamond bonding, and also causing the diamond layer to bond to the substrate.
- After completion of the sintering process, a finishing operation is performed which typically includes a step of machining the PCD. The machining operation may be similar to that described in U.S. Pat. No. 5,447,208 in which progressively smaller diamond grit particles are used to produce a highly polished working surface on the diamond material. However, the use of progressively small grit sizes is not essential, and depending upon the application in which the PCD is to be used, a less polished finish may be acceptable, in which case the machining operation may be performed with, say, only one relatively coarse diamond grit size.
- Regardless as to the finish to be produced, the action of the diamond grit on the working surface of the PCD during the machining operation is to cause slightly projecting parts of the PCD (at a microscopic level) to be worn or broken away from the remainder thereof to flat a working surface of good flatness. Where the machining operation is used to produce a highly polished finish, then the finish working surface is of very good flatness, but will still include small scratches formed by the action of the diamond grit on the working surface. In addition to forming a surface of good flatness, the machining operation causes the formation of very small fractures, referred to herein as microfractures, in the diamond crystals which are exposed at the working surface. These crystals may also be subject to other damage during the machining operation. It is thought that, in subsequent use, cracks may propagate relatively easily along the microfractures, and hence that the PCD finished in this manner is relatively weak, being of relatively low wear resistance.
- Although, as described hereinbefore, cobalt is most commonly used as the binder-catalyzing material, any group VIII element, including cobalt, nickel, iron, and alloys thereof, may be employed.
- In an alternative form of thermally stable polycrystalline diamond, silicon is used as the catalyzing material. The process for making polycrystalline diamond with a silicon catalyzing material is quite similar to that described above, except that at synthesis temperatures and pressures, most of the silicon is reacted to form silicon carbide, which is not an effective catalyzing material. The thermal resistance is somewhat improved, but thermal degradation still occurs due to some residual silicon remaining, generally uniformly distributed in the interstices of the interstitial matrix. There are mounting problems with this type of PCD element because there is no bondable surface.
- More recently, a further type of PCD has become available in which carbonates, such as powdery carbonates of Mg, Ca, Sr, and Ba are used as the binder-catalyzing material when sintering the diamond powder. PCD of this type typically has greater wear-resistance and hardness than the previous types of PCD elements. However, the material is difficult to produce on a commercial scale since much higher pressures are required for sintering than is the case with conventional and thermally stable polycrystalline diamond. One result of this is that the bodies of polycrystalline diamond produced by this method are smaller than conventional polycrystalline diamond elements. Again, thermal degradation may still occur due to the residual binder-catalyzing material remaining in the interstices. Again, because there is no integral substrate or other bondable surface, there are difficulties in mounting this material to a working surface.
- The present invention provides a superhard polycrystalline diamond or diamond-like element with improved wear resistance. Collectively called PCD elements for the purposes of this specification, these elements are formed with a binder-catalyzing material in a high-temperature, high-pressure (HTHP) process. The diamond material is formed and integrally bonded to a substrate containing the catalyzing material during the HTHP process. The diamond body so formed has a working surface, a plurality of crystals being exposed at the working surface, and wherein the crystals exposed at at least a portion of the working surface are substantially free of microfractures as formed.
- It will be appreciated that by providing a PCD element in which at least some of the crystals at the working surface are treated to be substantially free of microfractures, the likelihood of cracks propagating through the crystals is reduced, and as a consequence, the wear resistance of the element in improved and the useful working life of the PCD is increased.
- The PCD element may be used in a wide range of applications. By way of example only, the PCD element may find applications in downhole equipment, either in cutters or for use in wear resistant bearings. The PCD element may alternatively be used in hollow dies, friction bearings, valve surfaces, indentors, tool mandrels and a wide range of other applications. Additionally, the PCD element may be used in the machining of abrasive materials, for example abrasive wood materials, ferrous and non-ferrous materials, and hard or very abrasive engineering materials such as stone, asphalt and the like.
- In accordance with one aspect of the present invention there is provided a PCD element comprising a body including matrix of crystals of a superhard material, the body having a surface, a plurality of the crystals being exposed at the surface, wherein upon completion of the manufacturing process, at least the exposed part of each of the crystals exposed at at least a portion of the surface has a rounded shape. Crystals of this form are substantially free of microfractures and other defects and so a PCD of this form is of improved wear resistance.
- The PCD element conveniently comprises a substrate having a front surface, a table of superhard material being bonded to the substrate, the table of superhard material comprising a matrix of crystals. The crystals of superhard material conveniently comprise diamond crystals.
- The invention also relates to a PCD element which comprises a substrate having a front surface, a table of superhard material being bonded to the front surface of the substrate, the table of superhard material comprising a matrix of crystals, the table having a surface at which a plurality of the crystals are exposed, at least the exposed parts of the crystals which are exposed at at least a portion of the surface being substantially free of microfractures.
- The exposed parts of the exposed crystals are preferably of rounded form.
- In accordance with another aspect of the invention there is provided a method of manufacturing a PCD element comprising:sintering diamond powder with a binder-catalyst material in a high pressure, high temperature press to-form a body including a matrix of diamond crystals;performing a machining operation on the body to form a working surface thereon at which a plurality of diamond crystals are exposed; and treating the body to render the crystals which are exposed at at least a portion of the working surface substantially free of microfractures.
- The step of treating the body may include performing a machining operation on the body in the absence of a coolant material. Alternatively, the step of treating the body may include performing a machining operation on the body with a restricted coolant supply. In either case, the temperature of the diamond crystals at the exposed surface is raised, and extremely high local temperatures and pressures are reached such that the exposed diamond surface becomes plastic. Under these conditions, the exposed surface of the diamond crystals can undergo limited plastic flow and thereby deform to generate a smooth rounded surface which is substantially free of microfractures. It is believed that the extreme localized surface temperature attained during this treatment is in excess of 2000° C. It is well known in the art that diamond crystals deform in a plastic manner when subjected to high pressures and temperatures such as during the HTHP process described briefly hereinbefore. The deformation is normally revealed by the presence of “deformation twinning” within the crystals such as occurs in ductile metals at much lower temperatures. Prior to this invention, this plastic deformation was not known to occur locally at a surface as a result of a machining process, and such machining conditions are normally avoided.
- The machining operation may be an ultra-high speed grinding operation.
- Alternatively, the step of treating the body may include performing a thermochemical treatment on the body. The thermochemical treatment may involve the treatment of the working surface of the body with at least one oxidizing compound, or the treatment thereof with at least one iron group element.
- In accordance with another aspect of the invention there is provided a method of manufacturing a PCD element comprising:sintering diamond powder with a binder-catalyst material in a high pressure, high temperature press to form a body including a matrix of diamond crystals;performing a machining operation on the body to form a working surface thereon at which a plurality of diamond crystals are exposed; and treating the body to render at least the exposed parts of the crystals exposed at at least a portion of the working surface of rounded form.
- Crystals treated so as to be of rounded form are substantially free of microfractures and other surface defects, and so a PCD manufactured in accordance with the invention has the advantage that it is of improved wear resistance as the likelihood of cracks propagating through the crystals thereof is reduced.
- The invention will further be described, by way of example only, with reference to the accompanying drawings.
- FIG. 1 is a typical PCD element of the present invention.
- FIG. 2 is a micro-structural representation of part of the PCD element.
- FIG. 3 is a diagrammatic representation illustrating the crystal structure of part of a typical PCD element close to a working surface thereof.
- FIG. 4 is a view similar to FIG. 3 but illustrating the structure of a PCD in accordance with an embodiment of the invention.
- FIG. 5 is a typical PCD of the present invention shown as a cutting element.
- FIG. 6 is a perspective view of an insert used in machine tools utilizing the PCD element of the present invention.
- FIG. 7 is a perspective view of a dome shaped PCD element suitable for use in both rolling cutter drill bits and in fixed cutter drill bits.
- FIG. 8 is a side view of a fixed cutter rotary drill bit using a PCD element of the present invention.
- FIG. 9 is a perspective view of a rolling cutter rotary drill bit using a PCD element of the present invention.
- FIG. 10 is a section view of a wire drawing die having a PCD element of the present invention.
- FIG. 11 is perspective view of a bearing having a PCD element of the present invention.
- FIGS. 12 and 13 are front views of the mating parts of a valve having a PCD element of the present invention.
- FIG. 14 is a side view of an indentor having a PCD element of the present invention.
- FIG. 15 is a partial section view of a punch having a PCD element of the present invention.
- FIG. 16 is perspective view of a measuring device having a PCD element of the present invention.
- The polycrystalline diamond or diamond-like material (PCD)
element 2 of the present invention is shown in FIG. 1. ThePCD element 2 has a plurality of partially bonded superhard, diamond or diamond-like,crystals 60, (shown in FIG. 2) a catalyzingmaterial 64, and an interstitial matrix 68 formed by theinterstices 62 among thecrystals 60. Theelement 2 also has one or more working surfaces 4 and thediamond crystals 60 and theinterstices 62 form the volume of the body 8 of thePCD element 2. Preferably, theelement 2 is integrally formed with ametallic substrate 6, typically tungsten carbide with a cobalt binder material. To be effective when used in an abrasive wear application, the volume density of the diamond in the body 8 should be greater than 85 volume %, and preferably be higher than 90%. - The working surface4 is any portion of the PCD body 8 which, in operation, may contact the object to be worked. In this specification, when the working surface 4 is discussed, it is understood that it applies to any portion of the body 8 which may be exposed and/or used as a working surface. Furthermore, any portion of any of the working surface 4 is, in and of itself, a working surface.
- During manufacture, under conditions of high-temperature and high-pressure (HTHP), the
interstices 62 among thecrystals 60 fill with the catalyzingmaterial 64 followed by bonds forming among thecrystals 60. - Referring now to FIG. 2, it is well known that there is a random crystallographic orientation of the diamond or diamond-
like crystals 60 as shown by theparallel lines 61 representing the cleavage planes of eachcrystal 60. As can be seen,adjacent crystals 60 have bonded together withinterstitial spaces 62 among them. Because the cleavage planes 61 are oriented in different directions onadjacent crystals 60 there is generally no straight path available for diamond fracture. This structure allows PCD materials to perform well in extreme loading environments where high impact loads are common. - In the process of bonding the
crystals 60 in a high-temperature, high-pressure press, theinterstitial spaces 62 among thecrystals 60 become filled with a binder-catalyzingmaterial 64. It is this catalyzingmaterial 64 that allows the bonds to be formed betweenadjacent diamond crystals 60 at the relatively low pressures and temperatures present in the press. - The average diamond volume density in the body8 of the
PCD element 2 of the present invention ranges from about 85% to about 99%. The high diamond volume density is achieved by usingdiamond crystals 60 with a range of particle sizes, with an average particle size ranging from about 30 to about 60 microns. Typically, the diamond mixture may comprise 20% to 60% diamond crystals 60 in the 5-15 micron range, 20% to 40% diamond crystals 60 in the 25-40 micron range, and 20% to 40% diamond crystals 60 in the 50-80 micron diameter range, although numerous other size ranges and percentages may be used. This mixture of large andsmall diamond crystals 60 allows thediamond crystals 60 to have relatively high percentages of their outer surface areas dedicated to diamond-to-diamond bonding, often approaching 95%, contributing to a relatively high apparent abrasion resistance. - After completion of the sintering operation to form the body8 of the
PCD element 2, and to bond theelement 2 to thesubstrate 6, a cleaning operation in performed on theelement 2. The cleaning operation includes a finishing operation of machining the working surfaces 4 of theelement 2 to improve the smoothness thereof and to remove macroscopic defects therefrom. Thecrystals 60 of theelement 2 include a plurality ofcrystals 65 exposed at the working surfaces 4. As described hereinbefore, it is thought that the machining operation induces the formation ofmicrofractures 63 and other defects into thecrystals 65 of theelement 2 which are exposed at the working surface 4, as shown in FIG. 3. The formation of these defects in thecrystals 65 which are exposed at the working surface 4 may result in theelement 2 being weakened as, in use, cracks may propagate through thecrystals 65, starting at themicrofractures 63, and then typically following the cleavage planes 61 of the crystals. - In accordance with the invention, rather than simply performing a machining operation on the
element 2, theelement 2 is treated to render thecrystals 65 exposed at the working surfaces 4 thereof, or at at least a portion of the working surface thereof, for example around at least a part of anedge portion 5 of theelement 2, substantially free ofmicrofractures 70 and other surface defects. The treatment comprises performing a machining operation, for example an ultra-high speed grinding operation, in the absence of a coolant, or with a restricted coolant supply so that the machining operation is performed at a significantly higher surface temperature than usual. By way of example, the surface temperature reached may be in excess of 2000° C. The performance of the machining operation under such high temperature conditions is thought to affect the way in which material is removed from theelement 2 such that the removal of the material does not result in the formation of microfractures or other defects in the exposed parts of the exposedcrystals 65. Rather, the exposed diamond surface undergoes limited plastic deformation, the diamond flowing to form a rounded surface which is substantially free of microfractures. FIG. 4 is a diagrammatic view similar to FIG. 3 illustrating the effect of performing such a machining operation. As shown in FIG. 4, the exposed parts of thecrystals 65 exposed at the working surfaces 4 are of rounded or domed form, and are substantially free of stress raisers in the form of microfractures, cracks or other surface defects. As a result, in use, the risk of cracks forming in thecrystals 65 is reduced, and hence the wear resistance of theelement 2 is improved. - Although as described above the step of treating the
element 2 to render its working surfaces 4 substantially free of microfractures and other surface defects may involve performing a machining operation in the absence of coolant or with a restricted supply of coolant, it will be appreciated that theelement 2 could be treated in other ways to achieve the same result. For example, a thermochemical treatment operation could be performed on theelement 2 using, for example, iron group elements or oxidizing compounds. Further, combinations of these techniques may be used. - As indicated hereinbefore, a PCD element so manufactured may find application in a wide range of uses. One particularly useful application for the
PCD element 2 of the present invention is as cuttingelements - The working surface of the
PCD cutting elements surface 70 and/or a peripheral workingsurface 72. ThePCD cutting element 10 of FIG. 5 is one that may be typically used in fixed cutter typerotary drill bits 12, or for gauge protection in other types of downhole tools. ThePCD cutting element 50 shown in FIG. 7 may be shaped as adome 39. This type ofPCD cutting element 50 has an extendedbase 51 for insertion into sockets in a rollingcutter drill bit 38 or in the body of both types of rotary drill bits, 12, 38 as will be described in detail. - The
PCD cutting element 52 of FIG. 6 is adapted for use in a machining process. Although the configuration of the cuttingelement 52 in FIG. 6 is rectangular, it would be appreciated by those skilled in the art that this element could be triangular, quadrilateral or many other shapes suitable for machining highly abrasive products that are difficult to machine with conventional tools. - The
PCD cutting element 10 may be apreform cutting element 10 of a fixed cutter rotary drill bit 12 (as shown in FIG. 8). Thebit body 14 of the drill bit is formed with a plurality ofblades 16 extending generally outwardly away from the central longitudinal axis ofrotation 18 of the drill bit. Spaced apart side-by-side along the leadingface 20 of each blade is a plurality of thePCD cutting elements 10 of the present invention. - Typically, the
PCD cutting element 10 has a body in the form of a circular tablet having a thin front facing table 30 of diamond or diamond-like (PCD) material, bonded in a high-pressure high-temperature press to asubstrate 32 of less hard material such as cemented tungsten carbide or other metallic material. The cuttingelement 10 is preformed and then typically bonded on a generallycylindrical carrier 34 which is also formed from cemented tungsten carbide, or may alternatively be attached directly to the blade. ThePCD cutting element 10 has workingsurfaces - The
cylindrical carrier 34 is received within a correspondingly shaped socket or recess in theblade 16. Thecarrier 34 will usually be brazed or shrink fit in the socket. In operation the fixedcutter drill bit 12 is rotated and weight is applied. This forces the cuttingelements 10 into the earth being drilled, effecting a cutting and/or drilling action. - The
PCD cutting elements 10 may also be applied to thegauge region 36 of thebit 12 to provide a gauge reaming action as well as protecting thebit 12 from excessive wear in thegauge region 36. In order to space these cuttingelements 10 as closely as possible, it may be desirable to cut the elements into shapes, such as the rectangular shape shown, which more readily fit into thegauge region 36. - In a second embodiment, the cutting element50 (as shown in FIG. 7) of the present invention is on a rolling cutter
type drill bit 38, shown in FIG. 9. A rollingcutter drill bit 38 typically has one or more truncatedrolling cone cutters leg 44 of thebit body 46. The cuttingelements 50 may be mounted as one or more of a plurality of cutting inserts arranged in rows on rollingcutters PCD cutting elements 50 may be arranged along theleg 44 of thebit 38. ThePCD cutting element 50 has a body in the form of a facing table 35 of diamond or diamond like material bonded to a lesshard substrate 37. The facing table 35 in this embodiment of the present invention is in the form of adomed surface 39 and has workingsurfaces substrate 37 to help more evenly distribute the stresses generated during fabrication, as is well known to those skilled in the art. - In operation the rolling
cutter drill bit 38 is rotated and weight is applied. This forces the cutting inserts 50 in the rows of the rollingcone cutters bit 36 is rotated the rollingcutters - In another embodiment, the
PCD cutting element 52 of the present invention is in the form of a triangular, rectangular or other shaped material for use as a cutting insert in machining operations. In this embodiment, the cuttingelement 52 has a body in the form of a facing table 54 of diamond or diamond like material bonded to a lesshard substrate 56 with workingsurfaces element 52 would then be cut into a plurality of smaller pieces which are subsequently attached to aninsert 58 that is mounted in the tool holder of a machine tool. The cuttingelement 52 may be attached to the insert by brazing, adhesives, welding, or clamping. It is also possible to finish form the cuttingelement 52 in the shape of the insert in a high-temperature high-pressure manufacturing process. - As shown in FIGS.10-16,
PCD elements 2, 102, 202 of the present invention may also be used for other applications such as hollow dies, shown for example as a wire drawing die, 300 of FIG. 10 utilizing aPCD element 302 of the present invention. - Other applications include
friction bearings 320 with aPCD bearing element 322 shown in FIG. 11 and the mating parts of avalve surfaces 342 having aPCD element 342 of the present invention as shown in FIGS. 12 and 13. In addition,indentors 360 for scribes, hardness testers, surface roughening, etc. may havePCD elements 362 of the present invention as shown in FIG. 14.Punches 370 may have either or both dies 372, 374 made of the PCD material of the present invention, as shown in FIG. 15. Also,tool mandrels 382 and other types of wear elements for measuringdevices 380, shown in FIG. 16 may be made of PCD elements of the present inventions. - Whereas the present invention has been described in particular relation to the drawings attached hereto, it should be understood that other and further modifications apart from those shown or suggested herein, may be made within the scope and spirit of the present invention.
Claims (38)
1. A PCD element comprising a body including a matrix of crystals of a superhard material, the body having a surface, a plurality of the crystals of the matrix being exposed at the surface, wherein at least an exposed part of each of the crystals exposed at at least a portion of the surface has a rounded shape as formed.
2. A PCD element according to claim 1 , further comprising a substrate to which the body is bonded.
3. A PCD element according to claim 1 , wherein the matrix of crystals defines a plurality of interstices, at least some of the interstices containing a binder-catalyst material.
4. A PCD element according to claim 3 , wherein the binder-catalyst material comprises a Group VIII material.
5. A PCD element according to claim 4 , wherein the binder-catalyst comprises cobalt.
6. A PCD element according to claim 1 , wherein the crystals of superhard material comprise diamond crystals.
7. A PCD element comprising a substrate having a front face, a table of superhard material being bonded to the front face of the substrate, the table of superhard material comprising a matrix of crystals, the table having a surface at which a plurality of the crystals are exposed, at least exposed parts of the crystals exposed at at least a portion of the surface being substantially free of microfractures.
8. A PCD element according to claim 7 , wherein the exposed parts of the exposed crystals are of rounded form.
9. A PCD element according to claim 7 , wherein the matrix of crystals defines a plurality of interstices, at least some of the interstices containing a binder-catalyst material.
10. A PCD element according to claim 9 , wherein the binder-catalyst material comprises a Group VIII material.
11. A PCD element according to claim 10 , wherein the binder-catalyst comprises cobalt.
12. A PCD element according to claim 7 , wherein the crystals of superhard material comprise diamond crystals.
13. A method of manufacturing a PCD element comprising:
sintering diamond powder with a binder-catalyst material in a high pressure, high temperature press to form a body including a matrix of diamond crystals;
performing a machining operation on the body to form a working surface thereon at which a plurality of diamond crystals are exposed; and
treating the body to render the crystals which are exposed at at least a portion of the working surface substantially free of microfractures.
14. A method according to claim 13 , wherein the binder-catalyst material is a Group VIII material.
15. A method according to claim 14 , wherein the binder-catalyst material is cobalt.
16. A method according to claim 13 , further comprising sintering the diamond powder with a substrate in the high pressure, high temperature press to bond the body to the substrate.
17. A method according to claim 16 , wherein the substrate is a tungsten carbide substrate.
18. A method according to claim 13 , wherein the step of treating the body includes performing a machining operation on the body in the absence of a coolant material.
19. A method according to claim 13 , wherein the step of treating the body includes performing a machining operation on the body with a restricted coolant supply.
20. A method according to claim 13 , wherein the step of treating the body includes performing a thermochemical treatment on the body.
21. A method according to claim 20 , wherein the thermochemical treatment involves the treatment of the working surface of the body with at least one oxidizing compound.
22. A method according to claim 20 , wherein the thermochemical treatment involves the treatment of the working surface of the body with at least one iron group element.
23. A method according to claim 13 , wherein a local temperature in excess of 2000° C. is reached at at least a portion of the working surface during the step of treating the body.
24. A method of manufacturing a PCD element comprising:
sintering diamond powder with a binder-catalyst material in a high pressure, high temperature press to form a body including a matrix of diamond crystals;
performing a machining operation on the body to form a working surface thereon at which a plurality of diamond crystals are exposed; and
treating the body to render at least the exposed parts of the crystals exposed at at least a portion of the working surface of rounded form.
25. A method according to claim 24 , wherein the binder-catalyst material is a Group VIII material.
26. A method according to claim 25 , wherein the binder-catalyst material is cobalt.
27. A method according to claim 24 , further comprising sintering the diamond powder with a substrate in the high pressure, high temperature press to bond the body to the substrate.
28. A method according to claim 27 , wherein the substrate is a tungsten carbide substrate
29. A method according to claim 24 , wherein the step of treating the body includes performing a machining operation on the body in the absence of a coolant material.
30. A method according to claim 24 , wherein the step of treating the body includes performing a machining operation on the body with a restricted coolant supply.
31. A method according to claim 24 , wherein the step of treating the body includes performing a thermochemical treatment on the body.
32. A method according to claim 31 , wherein the thermochemical treatment involves the treatment of the working surface of the body with at least one oxidizing compound.
33. A method according to claim 31 , wherein the thermochemical treatment involves the treatment of the working surface of the body with at least one iron group element.
34. A method according to claim 25 , wherein a local temperature in excess of 2000° C. is reached at at least a portion of the working surface during the step of treating the body.
35. A PCD element according to claim 1 , comprising a preform cutting element having a facing table and a cutting surface, wherein the cutting element is mounted upon a cutting face of a fixed cutter rotary drill bit.
36. A PCD element according to claim 1 , comprising a preform cutting element having a facing table and a cutting surface, wherein the cutting element is mounted upon a body of a rolling cutter drill bit.
37. A PCD element according to claim 1 , comprising a cutting element with a cutting surface adapted for use as a cutting insert in a machining operation.
38. A PCD element according to claim 1 , comprising a drawing die.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/249,199 US20030183426A1 (en) | 2002-03-28 | 2003-03-21 | Polycrystalline Material Element with Improved Wear Resistance And Methods of Manufacture Thereof |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US31915702P | 2002-03-28 | 2002-03-28 | |
US10/249,199 US20030183426A1 (en) | 2002-03-28 | 2003-03-21 | Polycrystalline Material Element with Improved Wear Resistance And Methods of Manufacture Thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
US20030183426A1 true US20030183426A1 (en) | 2003-10-02 |
Family
ID=28675209
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/249,199 Abandoned US20030183426A1 (en) | 2002-03-28 | 2003-03-21 | Polycrystalline Material Element with Improved Wear Resistance And Methods of Manufacture Thereof |
Country Status (6)
Country | Link |
---|---|
US (1) | US20030183426A1 (en) |
EP (1) | EP1488019A1 (en) |
AU (1) | AU2003205885A1 (en) |
CA (1) | CA2445301A1 (en) |
WO (1) | WO2003083148A1 (en) |
ZA (1) | ZA200308160B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20100243337A1 (en) * | 2009-03-31 | 2010-09-30 | Baker Hughes Incorporated | Methods for bonding preformed cutting tables to cutting element substrates and cutting elements formed by such processes |
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Publication number | Priority date | Publication date | Assignee | Title |
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US7368079B2 (en) * | 2003-12-09 | 2008-05-06 | Smith International, Inc. | Method for forming ultra hard sintered compacts using metallic peripheral structures in the sintering cell |
CA2748711C (en) | 2009-01-30 | 2014-07-08 | Drilformance Ulc | Drill bit |
US8512023B2 (en) | 2011-01-12 | 2013-08-20 | Us Synthetic Corporation | Injection mold assembly including an injection mold cavity at least partially defined by a polycrystalline diamond material |
US8702412B2 (en) | 2011-01-12 | 2014-04-22 | Us Synthetic Corporation | Superhard components for injection molds |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20100243337A1 (en) * | 2009-03-31 | 2010-09-30 | Baker Hughes Incorporated | Methods for bonding preformed cutting tables to cutting element substrates and cutting elements formed by such processes |
US8573333B2 (en) * | 2009-03-31 | 2013-11-05 | Baker Hughes Incorporated | Methods for bonding preformed cutting tables to cutting element substrates and cutting elements formed by such processes |
US8851208B2 (en) | 2009-03-31 | 2014-10-07 | Baker Hughes Incorporated | Cutting elements including adhesion materials, earth-boring tools including such cutting elements, and related methods |
US9839989B2 (en) | 2009-03-31 | 2017-12-12 | Baker Hughes Incorporated | Methods of fabricating cutting elements including adhesion materials for earth-boring tools |
Also Published As
Publication number | Publication date |
---|---|
EP1488019A1 (en) | 2004-12-22 |
AU2003205885A1 (en) | 2003-10-13 |
CA2445301A1 (en) | 2003-10-09 |
ZA200308160B (en) | 2004-09-16 |
WO2003083148A1 (en) | 2003-10-09 |
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Owner name: REEDHYCALOG (UK) LIMITED, UNITED KINGDOM Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:GRIFFIN, NIGEL DENNIS;HUGHES, PETER RAYMOND;REEL/FRAME:014790/0349 Effective date: 20040622 |
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STCB | Information on status: application discontinuation |
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