US20040074012A1 - Method for providing textile material with uv protection - Google Patents
Method for providing textile material with uv protection Download PDFInfo
- Publication number
- US20040074012A1 US20040074012A1 US10/470,265 US47026503A US2004074012A1 US 20040074012 A1 US20040074012 A1 US 20040074012A1 US 47026503 A US47026503 A US 47026503A US 2004074012 A1 US2004074012 A1 US 2004074012A1
- Authority
- US
- United States
- Prior art keywords
- textile material
- component
- acid
- components
- esters
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000004753 textile Substances 0.000 title claims abstract description 55
- 239000000463 material Substances 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title claims abstract description 14
- 230000006750 UV protection Effects 0.000 title description 12
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 52
- -1 amino-substituted hydroxybenzophenones Chemical class 0.000 claims abstract description 51
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 43
- 239000006096 absorbing agent Substances 0.000 claims abstract description 27
- 239000011787 zinc oxide Substances 0.000 claims abstract description 26
- 150000002148 esters Chemical class 0.000 claims abstract description 23
- 150000001875 compounds Chemical class 0.000 claims abstract description 17
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 claims abstract description 12
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims abstract description 8
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical class OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 claims abstract description 7
- DWYHDSLIWMUSOO-UHFFFAOYSA-N 2-phenyl-1h-benzimidazole Chemical class C1=CC=CC=C1C1=NC2=CC=CC=C2N1 DWYHDSLIWMUSOO-UHFFFAOYSA-N 0.000 claims abstract description 7
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims abstract description 7
- 150000003918 triazines Chemical class 0.000 claims abstract description 7
- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 claims abstract description 6
- BVNWQSXXRMNYKH-UHFFFAOYSA-N 4-phenyl-2h-benzotriazole Chemical class C1=CC=CC=C1C1=CC=CC2=C1NN=N2 BVNWQSXXRMNYKH-UHFFFAOYSA-N 0.000 claims abstract description 5
- NZZIMKJIVMHWJC-UHFFFAOYSA-N dibenzoylmethane Chemical class C=1C=CC=CC=1C(=O)CC(=O)C1=CC=CC=C1 NZZIMKJIVMHWJC-UHFFFAOYSA-N 0.000 claims abstract description 5
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 claims abstract description 4
- 229960004050 aminobenzoic acid Drugs 0.000 claims abstract description 4
- 229930016911 cinnamic acid Natural products 0.000 claims abstract description 4
- 235000013985 cinnamic acid Nutrition 0.000 claims abstract description 4
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 claims abstract description 4
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229960004889 salicylic acid Drugs 0.000 claims abstract description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims description 41
- 238000009472 formulation Methods 0.000 claims description 17
- 230000003750 conditioning effect Effects 0.000 claims description 14
- 230000005855 radiation Effects 0.000 claims description 13
- 150000003839 salts Chemical class 0.000 claims description 13
- 239000004408 titanium dioxide Substances 0.000 claims description 13
- 239000003599 detergent Substances 0.000 claims description 12
- 238000010521 absorption reaction Methods 0.000 claims description 8
- 238000005562 fading Methods 0.000 claims description 7
- 230000009931 harmful effect Effects 0.000 claims description 7
- 239000004615 ingredient Substances 0.000 claims description 7
- 239000003093 cationic surfactant Substances 0.000 claims description 5
- 239000000470 constituent Substances 0.000 claims description 5
- 238000004900 laundering Methods 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 150000005621 tetraalkylammonium salts Chemical group 0.000 claims description 3
- 238000009988 textile finishing Methods 0.000 claims description 2
- 150000002462 imidazolines Chemical class 0.000 claims 1
- FMRHJJZUHUTGKE-UHFFFAOYSA-N Ethylhexyl salicylate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1O FMRHJJZUHUTGKE-UHFFFAOYSA-N 0.000 description 39
- 239000003795 chemical substances by application Substances 0.000 description 15
- 239000004744 fabric Substances 0.000 description 13
- 239000002253 acid Substances 0.000 description 12
- 229910052739 hydrogen Inorganic materials 0.000 description 11
- 239000001257 hydrogen Substances 0.000 description 11
- 150000002431 hydrogen Chemical class 0.000 description 10
- 229920000642 polymer Polymers 0.000 description 9
- 150000003254 radicals Chemical class 0.000 description 9
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- 125000004433 nitrogen atom Chemical group N* 0.000 description 8
- 229920000742 Cotton Polymers 0.000 description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
- 239000007844 bleaching agent Substances 0.000 description 7
- 239000003112 inhibitor Substances 0.000 description 7
- 239000001023 inorganic pigment Substances 0.000 description 7
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 7
- 230000004224 protection Effects 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- 125000002947 alkylene group Chemical group 0.000 description 6
- 229920006317 cationic polymer Polymers 0.000 description 6
- 239000000975 dye Substances 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 239000002689 soil Substances 0.000 description 6
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 5
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- 150000001298 alcohols Chemical class 0.000 description 5
- 150000001735 carboxylic acids Chemical class 0.000 description 5
- 239000000835 fiber Substances 0.000 description 5
- 239000002736 nonionic surfactant Substances 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 239000000049 pigment Substances 0.000 description 5
- 125000001424 substituent group Chemical group 0.000 description 5
- 238000012546 transfer Methods 0.000 description 5
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 description 4
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- WSSJONWNBBTCMG-UHFFFAOYSA-N 2-hydroxybenzoic acid (3,3,5-trimethylcyclohexyl) ester Chemical compound C1C(C)(C)CC(C)CC1OC(=O)C1=CC=CC=C1O WSSJONWNBBTCMG-UHFFFAOYSA-N 0.000 description 4
- 125000006374 C2-C10 alkenyl group Chemical group 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- 239000003945 anionic surfactant Substances 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 4
- 235000006708 antioxidants Nutrition 0.000 description 4
- SODJJEXAWOSSON-UHFFFAOYSA-N bis(2-hydroxy-4-methoxyphenyl)methanone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=C(OC)C=C1O SODJJEXAWOSSON-UHFFFAOYSA-N 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 150000002191 fatty alcohols Chemical class 0.000 description 4
- 229920001519 homopolymer Polymers 0.000 description 4
- 229910052744 lithium Inorganic materials 0.000 description 4
- 229920000962 poly(amidoamine) Polymers 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 230000003595 spectral effect Effects 0.000 description 4
- CXVGEDCSTKKODG-UHFFFAOYSA-N sulisobenzone Chemical compound C1=C(S(O)(=O)=O)C(OC)=CC(O)=C1C(=O)C1=CC=CC=C1 CXVGEDCSTKKODG-UHFFFAOYSA-N 0.000 description 4
- VSXIZXFGQGKZQG-UHFFFAOYSA-N 2-cyano-3,3-diphenylprop-2-enoic acid Chemical compound C=1C=CC=CC=1C(=C(C#N)C(=O)O)C1=CC=CC=C1 VSXIZXFGQGKZQG-UHFFFAOYSA-N 0.000 description 3
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 3
- 0 CC.CC.[3*]/C([4*])=C(/[H])C([H])=C(C1=CC=CC=C1)C1=CC=CC=C1 Chemical compound CC.CC.[3*]/C([4*])=C(/[H])C([H])=C(C1=CC=CC=C1)C1=CC=CC=C1 0.000 description 3
- 102000004190 Enzymes Human genes 0.000 description 3
- 108090000790 Enzymes Proteins 0.000 description 3
- 206010015150 Erythema Diseases 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- YBGZDTIWKVFICR-JLHYYAGUSA-N Octyl 4-methoxycinnamic acid Chemical compound CCCCC(CC)COC(=O)\C=C\C1=CC=C(OC)C=C1 YBGZDTIWKVFICR-JLHYYAGUSA-N 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- 229920002873 Polyethylenimine Polymers 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 3
- 239000012190 activator Substances 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- XNEFYCZVKIDDMS-UHFFFAOYSA-N avobenzone Chemical compound C1=CC(OC)=CC=C1C(=O)CC(=O)C1=CC=C(C(C)(C)C)C=C1 XNEFYCZVKIDDMS-UHFFFAOYSA-N 0.000 description 3
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 239000008139 complexing agent Substances 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 229940088598 enzyme Drugs 0.000 description 3
- 231100000321 erythema Toxicity 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 239000002979 fabric softener Substances 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 150000004760 silicates Chemical class 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 230000000475 sunscreen effect Effects 0.000 description 3
- 239000000516 sunscreening agent Substances 0.000 description 3
- 125000003258 trimethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])[*:1] 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical group CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 2
- 125000004642 (C1-C12) alkoxy group Chemical group 0.000 description 2
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 2
- NFDXQGNDWIPXQL-UHFFFAOYSA-N 1-cyclooctyldiazocane Chemical compound C1CCCCCCC1N1NCCCCCC1 NFDXQGNDWIPXQL-UHFFFAOYSA-N 0.000 description 2
- MEZZCSHVIGVWFI-UHFFFAOYSA-N 2,2'-Dihydroxy-4-methoxybenzophenone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1O MEZZCSHVIGVWFI-UHFFFAOYSA-N 0.000 description 2
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-Tetramethylpiperidine Substances CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 2
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 description 2
- GWXXFGWOWOJEEX-UHFFFAOYSA-N 4,4,4-trihydroxy-1-phenylbutan-1-one Chemical compound OC(CCC(=O)C1=CC=CC=C1)(O)O GWXXFGWOWOJEEX-UHFFFAOYSA-N 0.000 description 2
- 229940086681 4-aminobenzoate Drugs 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- ZCTQGTTXIYCGGC-UHFFFAOYSA-N Benzyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OCC1=CC=CC=C1 ZCTQGTTXIYCGGC-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 2
- 239000004322 Butylated hydroxytoluene Substances 0.000 description 2
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
- ZYEMGPIYFIJGTP-UHFFFAOYSA-N O-methyleugenol Chemical compound COC1=CC=C(CC=C)C=C1OC ZYEMGPIYFIJGTP-UHFFFAOYSA-N 0.000 description 2
- 239000004435 Oxo alcohol Substances 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 208000000453 Skin Neoplasms Diseases 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric Acid Chemical class [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
- BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 description 2
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- SLXIKWJMGICOAO-UHFFFAOYSA-N [4-(2-ethylhexoxy)-2-hydroxyphenyl]-phenylmethanone Chemical compound OC1=CC(OCC(CC)CCCC)=CC=C1C(=O)C1=CC=CC=C1 SLXIKWJMGICOAO-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 229940087168 alpha tocopherol Drugs 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 235000010323 ascorbic acid Nutrition 0.000 description 2
- BLFLLBZGZJTVJG-UHFFFAOYSA-N benzocaine Chemical compound CCOC(=O)C1=CC=C(N)C=C1 BLFLLBZGZJTVJG-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- IOWYKGHBFYJVFG-UHFFFAOYSA-N bis(2,2-dimethylpropyl) 2-(3,3-diphenylprop-2-enylidene)propanedioate Chemical compound C=1C=CC=CC=1C(=CC=C(C(=O)OCC(C)(C)C)C(=O)OCC(C)(C)C)C1=CC=CC=C1 IOWYKGHBFYJVFG-UHFFFAOYSA-N 0.000 description 2
- WXNRYSGJLQFHBR-UHFFFAOYSA-N bis(2,4-dihydroxyphenyl)methanone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=C(O)C=C1O WXNRYSGJLQFHBR-UHFFFAOYSA-N 0.000 description 2
- 235000019282 butylated hydroxyanisole Nutrition 0.000 description 2
- 229940095259 butylated hydroxytoluene Drugs 0.000 description 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- 150000007942 carboxylates Chemical class 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 235000015165 citric acid Nutrition 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 239000012973 diazabicyclooctane Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- HEOCBCNFKCOKBX-SDNWHVSQSA-N enzacamene Chemical compound C1=CC(C)=CC=C1\C=C/1C(=O)C2(C)CCC\1C2(C)C HEOCBCNFKCOKBX-SDNWHVSQSA-N 0.000 description 2
- 230000032050 esterification Effects 0.000 description 2
- 238000005886 esterification reaction Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- UYTPUPDQBNUYGX-UHFFFAOYSA-N guanine Chemical compound O=C1NC(N)=NC2=C1N=CN2 UYTPUPDQBNUYGX-UHFFFAOYSA-N 0.000 description 2
- 125000001072 heteroaryl group Chemical group 0.000 description 2
- LPTIRUACFKQDHZ-UHFFFAOYSA-N hexadecyl sulfate;hydron Chemical compound CCCCCCCCCCCCCCCCOS(O)(=O)=O LPTIRUACFKQDHZ-UHFFFAOYSA-N 0.000 description 2
- 239000003752 hydrotrope Substances 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 2
- MJVGBKJNTFCUJM-UHFFFAOYSA-N mexenone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=C(C)C=C1 MJVGBKJNTFCUJM-UHFFFAOYSA-N 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 2
- FMJSMJQBSVNSBF-UHFFFAOYSA-N octocrylene Chemical compound C=1C=CC=CC=1C(=C(C#N)C(=O)OCC(CC)CCCC)C1=CC=CC=C1 FMJSMJQBSVNSBF-UHFFFAOYSA-N 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 239000000825 pharmaceutical preparation Substances 0.000 description 2
- ZQBAKBUEJOMQEX-UHFFFAOYSA-N phenyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=CC=C1 ZQBAKBUEJOMQEX-UHFFFAOYSA-N 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 238000000985 reflectance spectrum Methods 0.000 description 2
- 201000000849 skin cancer Diseases 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 235000002906 tartaric acid Nutrition 0.000 description 2
- 239000004250 tert-Butylhydroquinone Substances 0.000 description 2
- 235000019281 tert-butylhydroquinone Nutrition 0.000 description 2
- 229960000984 tocofersolan Drugs 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 239000002076 α-tocopherol Substances 0.000 description 2
- PDHSAQOQVUXZGQ-JKSUJKDBSA-N (2r,3s)-2-(3,4-dihydroxyphenyl)-3-methoxy-3,4-dihydro-2h-chromene-5,7-diol Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@@H]2OC)=CC=C(O)C(O)=C1 PDHSAQOQVUXZGQ-JKSUJKDBSA-N 0.000 description 1
- VKZRWSNIWNFCIQ-WDSKDSINSA-N (2s)-2-[2-[[(1s)-1,2-dicarboxyethyl]amino]ethylamino]butanedioic acid Chemical compound OC(=O)C[C@@H](C(O)=O)NCCN[C@H](C(O)=O)CC(O)=O VKZRWSNIWNFCIQ-WDSKDSINSA-N 0.000 description 1
- GGAUUQHSCNMCAU-ZXZARUISSA-N (2s,3r)-butane-1,2,3,4-tetracarboxylic acid Chemical compound OC(=O)C[C@H](C(O)=O)[C@H](C(O)=O)CC(O)=O GGAUUQHSCNMCAU-ZXZARUISSA-N 0.000 description 1
- ZHKXQINATDRSHN-UHFFFAOYSA-N (3,3,5-trimethylcyclohexyl) 2-acetamidobenzoate Chemical compound C1C(C)(C)CC(C)CC1OC(=O)C1=CC=CC=C1NC(C)=O ZHKXQINATDRSHN-UHFFFAOYSA-N 0.000 description 1
- AALXZHPCKJILAZ-UHFFFAOYSA-N (4-propan-2-ylphenyl)methyl 2-hydroxybenzoate Chemical compound C1=CC(C(C)C)=CC=C1COC(=O)C1=CC=CC=C1O AALXZHPCKJILAZ-UHFFFAOYSA-N 0.000 description 1
- 125000006823 (C1-C6) acyl group Chemical group 0.000 description 1
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N (R)-alpha-Tocopherol Natural products OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- MAAFMNFCKWEWLO-UHFFFAOYSA-N (diaminomethylideneamino)methylphosphonic acid Chemical compound NC(N)=NCP(O)(O)=O MAAFMNFCKWEWLO-UHFFFAOYSA-N 0.000 description 1
- KMHNRJDDHTZZDZ-RMKNXTFCSA-N (e)-2-cyano-3-(4-methoxyphenyl)prop-2-enoic acid Chemical compound COC1=CC=C(\C=C(/C#N)C(O)=O)C=C1 KMHNRJDDHTZZDZ-RMKNXTFCSA-N 0.000 description 1
- CEGRHPCDLKAHJD-UHFFFAOYSA-N 1,1,1-propanetricarboxylic acid Chemical compound CCC(C(O)=O)(C(O)=O)C(O)=O CEGRHPCDLKAHJD-UHFFFAOYSA-N 0.000 description 1
- QOEPTMXREDTATR-UHFFFAOYSA-N 1,2,2,3-tetramethyl-1-oxidopiperidin-1-ium-4-ol Chemical compound CC1C(O)CC[N+](C)([O-])C1(C)C QOEPTMXREDTATR-UHFFFAOYSA-N 0.000 description 1
- YAXWOADCWUUUNX-UHFFFAOYSA-N 1,2,2,3-tetramethylpiperidine Chemical compound CC1CCCN(C)C1(C)C YAXWOADCWUUUNX-UHFFFAOYSA-N 0.000 description 1
- 150000005206 1,2-dihydroxybenzenes Chemical class 0.000 description 1
- GNMDORSUZRRMFS-UHFFFAOYSA-N 1,3-bis(4-methoxyphenyl)propane-1,3-dione Chemical compound C1=CC(OC)=CC=C1C(=O)CC(=O)C1=CC=C(OC)C=C1 GNMDORSUZRRMFS-UHFFFAOYSA-N 0.000 description 1
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- WHQOKFZWSDOTQP-UHFFFAOYSA-N 2,3-dihydroxypropyl 4-aminobenzoate Chemical compound NC1=CC=C(C(=O)OCC(O)CO)C=C1 WHQOKFZWSDOTQP-UHFFFAOYSA-N 0.000 description 1
- PFEFOYRSMXVNEL-UHFFFAOYSA-N 2,4,6-tritert-butylphenol Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 PFEFOYRSMXVNEL-UHFFFAOYSA-N 0.000 description 1
- OPLCSTZDXXUYDU-UHFFFAOYSA-N 2,4-dimethyl-6-tert-butylphenol Chemical compound CC1=CC(C)=C(O)C(C(C)(C)C)=C1 OPLCSTZDXXUYDU-UHFFFAOYSA-N 0.000 description 1
- SLUKQUGVTITNSY-UHFFFAOYSA-N 2,6-di-tert-butyl-4-methoxyphenol Chemical compound COC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SLUKQUGVTITNSY-UHFFFAOYSA-N 0.000 description 1
- DKCPKDPYUFEZCP-UHFFFAOYSA-N 2,6-di-tert-butylphenol Chemical compound CC(C)(C)C1=CC=CC(C(C)(C)C)=C1O DKCPKDPYUFEZCP-UHFFFAOYSA-N 0.000 description 1
- KDQKAUFQBKSYTC-UHFFFAOYSA-N 2,6-ditert-butyl-6-(5-chlorobenzotriazol-2-yl)cyclohexa-2,4-dien-1-ol Chemical compound OC1C(C(C)(C)C)=CC=CC1(C(C)(C)C)N1N=C2C=C(Cl)C=CC2=N1 KDQKAUFQBKSYTC-UHFFFAOYSA-N 0.000 description 1
- CFPOJWPDQWJEMO-UHFFFAOYSA-N 2-(1,2-dicarboxyethoxy)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)OC(C(O)=O)CC(O)=O CFPOJWPDQWJEMO-UHFFFAOYSA-N 0.000 description 1
- PQHYOGIRXOKOEJ-UHFFFAOYSA-N 2-(1,2-dicarboxyethylamino)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)NC(C(O)=O)CC(O)=O PQHYOGIRXOKOEJ-UHFFFAOYSA-N 0.000 description 1
- ZJQYDXBSSWRHGF-UHFFFAOYSA-N 2-(2H-benzotriazol-4-yl)-6-dodecyl-4-methylphenol Chemical compound CCCCCCCCCCCCC1=CC(C)=CC(C=2C=3N=NNC=3C=CC=2)=C1O ZJQYDXBSSWRHGF-UHFFFAOYSA-N 0.000 description 1
- ZMWRRFHBXARRRT-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-bis(2-methylbutan-2-yl)phenol Chemical compound CCC(C)(C)C1=CC(C(C)(C)CC)=CC(N2N=C3C=CC=CC3=N2)=C1O ZMWRRFHBXARRRT-UHFFFAOYSA-N 0.000 description 1
- LHPPDQUVECZQSW-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-ditert-butylphenol Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(N2N=C3C=CC=CC3=N2)=C1O LHPPDQUVECZQSW-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- ZMASJFWJGZNJBH-UHFFFAOYSA-N 2-[6-(1h-benzimidazol-2-yl)-2,3-disulfophenyl]-1h-benzimidazole-5,6-disulfonic acid Chemical compound OS(=O)(=O)C1=C(S(O)(=O)=O)C=C2NC(C=3C(C=4NC5=CC=CC=C5N=4)=CC=C(C=3S(O)(=O)=O)S(=O)(=O)O)=NC2=C1 ZMASJFWJGZNJBH-UHFFFAOYSA-N 0.000 description 1
- CMDKPGRTAQVGFQ-UHFFFAOYSA-N 2-ethoxyethyl 3-(4-methoxyphenyl)prop-2-enoate Chemical compound CCOCCOC(=O)C=CC1=CC=C(OC)C=C1 CMDKPGRTAQVGFQ-UHFFFAOYSA-N 0.000 description 1
- TWAOKHHZKFMFMD-UHFFFAOYSA-N 2-ethylhexyl 2-(4-phenylbenzoyl)benzoate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)C1=CC=C(C=2C=CC=CC=2)C=C1 TWAOKHHZKFMFMD-UHFFFAOYSA-N 0.000 description 1
- QHOSTUMWCHFCGK-UHFFFAOYSA-N 2-ethylhexyl 2-cyano-2-(3-oxoisoindol-1-ylidene)acetate Chemical compound C1=CC=C2C(=C(C#N)C(=O)OCC(CC)CCCC)NC(=O)C2=C1 QHOSTUMWCHFCGK-UHFFFAOYSA-N 0.000 description 1
- NPSJHQMIVNJLNN-UHFFFAOYSA-N 2-ethylhexyl 4-nitrobenzoate Chemical compound CCCCC(CC)COC(=O)C1=CC=C([N+]([O-])=O)C=C1 NPSJHQMIVNJLNN-UHFFFAOYSA-N 0.000 description 1
- 239000004808 2-ethylhexylester Substances 0.000 description 1
- HZLCGUXUOFWCCN-UHFFFAOYSA-N 2-hydroxynonadecane-1,2,3-tricarboxylic acid Chemical compound CCCCCCCCCCCCCCCCC(C(O)=O)C(O)(C(O)=O)CC(O)=O HZLCGUXUOFWCCN-UHFFFAOYSA-N 0.000 description 1
- IMOYOUMVYICGCA-UHFFFAOYSA-N 2-tert-butyl-4-hydroxyanisole Chemical compound COC1=CC=C(O)C=C1C(C)(C)C IMOYOUMVYICGCA-UHFFFAOYSA-N 0.000 description 1
- ODJQKYXPKWQWNK-UHFFFAOYSA-N 3,3'-Thiobispropanoic acid Chemical compound OC(=O)CCSCCC(O)=O ODJQKYXPKWQWNK-UHFFFAOYSA-N 0.000 description 1
- HMKKFLSUPRUBOO-IUPFWZBJSA-N 3,4-dihydroxy-5-[3,4,5-tris[[(z)-octadec-9-enoyl]oxy]benzoyl]oxybenzoic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC1=C(OC(=O)CCCCCCC\C=C/CCCCCCCC)C(OC(=O)CCCCCCC\C=C/CCCCCCCC)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(O)=O)O)=C1 HMKKFLSUPRUBOO-IUPFWZBJSA-N 0.000 description 1
- CTYWXRDQWMRIIM-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)prop-2-enoic acid Chemical compound CC(C)(C)C1=CC(C=CC(O)=O)=CC(C(C)(C)C)=C1O CTYWXRDQWMRIIM-UHFFFAOYSA-N 0.000 description 1
- UWRBFYBQPCJRRL-UHFFFAOYSA-N 3-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)CCN(CC(O)=O)CC(O)=O UWRBFYBQPCJRRL-UHFFFAOYSA-N 0.000 description 1
- QDHUJKQTILCXTA-UHFFFAOYSA-N 3-benzoyl-2-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=CC(C(=O)C=2C=CC=CC=2)=C1O QDHUJKQTILCXTA-UHFFFAOYSA-N 0.000 description 1
- GGKJPERNBJUNJF-UHFFFAOYSA-N 3-butan-2-yl-5-tert-butyl-2-hydroxy-1h-benzotriazole Chemical compound C1=C(C(C)(C)C)C=C2N(C(C)CC)N(O)NC2=C1 GGKJPERNBJUNJF-UHFFFAOYSA-N 0.000 description 1
- KRFXUBMJBAXOOZ-UHFFFAOYSA-N 4-ethenyl-1-oxidopyridin-1-ium Chemical compound [O-][N+]1=CC=C(C=C)C=C1 KRFXUBMJBAXOOZ-UHFFFAOYSA-N 0.000 description 1
- KFDVPJUYSDEJTH-UHFFFAOYSA-N 4-ethenylpyridine Chemical compound C=CC1=CC=NC=C1 KFDVPJUYSDEJTH-UHFFFAOYSA-N 0.000 description 1
- WDMFHQNUSVLQMS-UHFFFAOYSA-N 5-(3,3-dimethyl-2-bicyclo[2.2.1]heptanylidene)pent-3-en-2-one Chemical compound C1CC2C(C)(C)C(=CC=CC(=O)C)C1C2 WDMFHQNUSVLQMS-UHFFFAOYSA-N 0.000 description 1
- XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical compound CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 description 1
- RDBLNMQDEWOUIB-UHFFFAOYSA-N 5-methyl-2-phenyl-1,3-benzoxazole Chemical compound N=1C2=CC(C)=CC=C2OC=1C1=CC=CC=C1 RDBLNMQDEWOUIB-UHFFFAOYSA-N 0.000 description 1
- PJTNSWOJMXNNFG-UHFFFAOYSA-N 8-methylnonyl 2-hydroxybenzoate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1O PJTNSWOJMXNNFG-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- RLTXHLNQAKVKIP-UHFFFAOYSA-N C.C=C1C(C=CC(=O)O)C=C(C(=C1C(C)(C)C)O)C(C)(C)C.C=C1C(C=CC(=O)O)C=C(C(=C1C(C)(C)C)O)C(C)(C)C.C=C1C(C=CC(=O)O)C=C(C(=C1C(C)(C)C)O)C(C)(C)C.C=C1C(C=CC(=O)O)C=C(C(=C1C(C)(C)C)O)C(C)(C)C Chemical compound C.C=C1C(C=CC(=O)O)C=C(C(=C1C(C)(C)C)O)C(C)(C)C.C=C1C(C=CC(=O)O)C=C(C(=C1C(C)(C)C)O)C(C)(C)C.C=C1C(C=CC(=O)O)C=C(C(=C1C(C)(C)C)O)C(C)(C)C.C=C1C(C=CC(=O)O)C=C(C(=C1C(C)(C)C)O)C(C)(C)C RLTXHLNQAKVKIP-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 102000005575 Cellulases Human genes 0.000 description 1
- 108010084185 Cellulases Proteins 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 1
- 239000003508 Dilauryl thiodipropionate Substances 0.000 description 1
- RPWFJAMTCNSJKK-UHFFFAOYSA-N Dodecyl gallate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC(O)=C(O)C(O)=C1 RPWFJAMTCNSJKK-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000004258 Ethoxyquin Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 150000000996 L-ascorbic acids Chemical class 0.000 description 1
- QAQJMLQRFWZOBN-LAUBAEHRSA-N L-ascorbyl-6-palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](O)[C@H]1OC(=O)C(O)=C1O QAQJMLQRFWZOBN-LAUBAEHRSA-N 0.000 description 1
- 239000011786 L-ascorbyl-6-palmitate Substances 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 102000004882 Lipase Human genes 0.000 description 1
- 108090001060 Lipase Proteins 0.000 description 1
- 239000004367 Lipase Substances 0.000 description 1
- 239000004472 Lysine Chemical group 0.000 description 1
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Chemical group NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- JYXGIOKAKDAARW-UHFFFAOYSA-N N-(2-hydroxyethyl)iminodiacetic acid Chemical compound OCCN(CC(O)=O)CC(O)=O JYXGIOKAKDAARW-UHFFFAOYSA-N 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- 241000233803 Nypa Species 0.000 description 1
- 235000005305 Nypa fruticans Nutrition 0.000 description 1
- YIKSCQDJHCMVMK-UHFFFAOYSA-N Oxamide Chemical compound NC(=O)C(N)=O YIKSCQDJHCMVMK-UHFFFAOYSA-N 0.000 description 1
- 102000004316 Oxidoreductases Human genes 0.000 description 1
- 108090000854 Oxidoreductases Proteins 0.000 description 1
- WYWZRNAHINYAEF-UHFFFAOYSA-N Padimate O Chemical compound CCCCC(CC)COC(=O)C1=CC=C(N(C)C)C=C1 WYWZRNAHINYAEF-UHFFFAOYSA-N 0.000 description 1
- 102000035195 Peptidases Human genes 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- 108700020962 Peroxidase Proteins 0.000 description 1
- 102000003992 Peroxidases Human genes 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920000805 Polyaspartic acid Polymers 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- HVWGGPRWKSHASF-UHFFFAOYSA-N Sulfuric acid, monooctadecyl ester Chemical compound CCCCCCCCCCCCCCCCCCOS(O)(=O)=O HVWGGPRWKSHASF-UHFFFAOYSA-N 0.000 description 1
- 206010042496 Sunburn Diseases 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 238000000862 absorption spectrum Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000001720 action spectrum Methods 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 229940040563 agaric acid Drugs 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 229940062909 amyl salicylate Drugs 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 229940025131 amylases Drugs 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 238000010936 aqueous wash Methods 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 235000010385 ascorbyl palmitate Nutrition 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- XVAMCHGMPYWHNL-UHFFFAOYSA-N bemotrizinol Chemical compound OC1=CC(OCC(CC)CCCC)=CC=C1C1=NC(C=2C=CC(OC)=CC=2)=NC(C=2C(=CC(OCC(CC)CCCC)=CC=2)O)=N1 XVAMCHGMPYWHNL-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- BJFLSHMHTPAZHO-UHFFFAOYSA-N benzotriazole Chemical compound [CH]1C=CC=C2N=NN=C21 BJFLSHMHTPAZHO-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- OCWYEMOEOGEQAN-UHFFFAOYSA-N bumetrizole Chemical compound CC(C)(C)C1=CC(C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O OCWYEMOEOGEQAN-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- FOYJYXHISWUSDL-UHFFFAOYSA-N butyl 4-(dimethylamino)benzoate Chemical compound CCCCOC(=O)C1=CC=C(N(C)C)C=C1 FOYJYXHISWUSDL-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- YKPUWZUDDOIDPM-SOFGYWHQSA-N capsaicin Chemical compound COC1=CC(CNC(=O)CCCC\C=C\C(C)C)=CC=C1O YKPUWZUDDOIDPM-SOFGYWHQSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229940080284 cetyl sulfate Drugs 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 1
- 229940106681 chloroacetic acid Drugs 0.000 description 1
- VZWXIQHBIQLMPN-UHFFFAOYSA-N chromane Chemical class C1=CC=C2CCCOC2=C1 VZWXIQHBIQLMPN-UHFFFAOYSA-N 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 125000000582 cycloheptyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- FGEUKKGODAGXOD-UHFFFAOYSA-N cyclohexyl 3-(4-methoxyphenyl)prop-2-enoate Chemical compound C1=CC(OC)=CC=C1C=CC(=O)OC1CCCCC1 FGEUKKGODAGXOD-UHFFFAOYSA-N 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- STZIXLPVKZUAMV-UHFFFAOYSA-N cyclopentane-1,1,2,2-tetracarboxylic acid Chemical compound OC(=O)C1(C(O)=O)CCCC1(C(O)=O)C(O)=O STZIXLPVKZUAMV-UHFFFAOYSA-N 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 125000005265 dialkylamine group Chemical group 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- FDATWRLUYRHCJE-UHFFFAOYSA-N diethylamino hydroxybenzoyl hexyl benzoate Chemical compound CCCCCCOC(=O)C1=CC=CC=C1C(=O)C1=CC=C(N(CC)CC)C=C1O FDATWRLUYRHCJE-UHFFFAOYSA-N 0.000 description 1
- 235000019304 dilauryl thiodipropionate Nutrition 0.000 description 1
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N dimethylmethane Natural products CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000007884 disintegrant Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 1
- SAFZYAAIZAZINS-UHFFFAOYSA-N dodecyl 4-(dimethylamino)benzoate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC=C(N(C)C)C=C1 SAFZYAAIZAZINS-UHFFFAOYSA-N 0.000 description 1
- 235000010386 dodecyl gallate Nutrition 0.000 description 1
- 239000000555 dodecyl gallate Substances 0.000 description 1
- 229940080643 dodecyl gallate Drugs 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 229940043264 dodecyl sulfate Drugs 0.000 description 1
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 1
- HUVYTMDMDZRHBN-UHFFFAOYSA-N drometrizole trisiloxane Chemical compound C[Si](C)(C)O[Si](C)(O[Si](C)(C)C)CC(C)CC1=CC(C)=CC(N2N=C3C=CC=CC3=N2)=C1O HUVYTMDMDZRHBN-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- UVCJGUGAGLDPAA-UHFFFAOYSA-N ensulizole Chemical compound N1C2=CC(S(=O)(=O)O)=CC=C2N=C1C1=CC=CC=C1 UVCJGUGAGLDPAA-UHFFFAOYSA-N 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 125000005670 ethenylalkyl group Chemical group 0.000 description 1
- 235000019285 ethoxyquin Nutrition 0.000 description 1
- DECIPOUIJURFOJ-UHFFFAOYSA-N ethoxyquin Chemical compound N1C(C)(C)C=C(C)C2=CC(OCC)=CC=C21 DECIPOUIJURFOJ-UHFFFAOYSA-N 0.000 description 1
- 229940093500 ethoxyquin Drugs 0.000 description 1
- KCDAMWRCUXGACP-DHZHZOJOSA-N ethyl (e)-2-cyano-3-phenylprop-2-enoate Chemical compound CCOC(=O)C(\C#N)=C\C1=CC=CC=C1 KCDAMWRCUXGACP-DHZHZOJOSA-N 0.000 description 1
- NYNCZOLNVTXTTP-UHFFFAOYSA-N ethyl 2-(1,3-dioxoisoindol-2-yl)acetate Chemical compound C1=CC=C2C(=O)N(CC(=O)OCC)C(=O)C2=C1 NYNCZOLNVTXTTP-UHFFFAOYSA-N 0.000 description 1
- IAJNXBNRYMEYAZ-UHFFFAOYSA-N ethyl 2-cyano-3,3-diphenylprop-2-enoate Chemical compound C=1C=CC=CC=1C(=C(C#N)C(=O)OCC)C1=CC=CC=C1 IAJNXBNRYMEYAZ-UHFFFAOYSA-N 0.000 description 1
- HPMLGOFBKNGJAM-UHFFFAOYSA-N ethyl 3-(1h-imidazol-5-yl)prop-2-enoate Chemical compound CCOC(=O)C=CC1=CNC=N1 HPMLGOFBKNGJAM-UHFFFAOYSA-N 0.000 description 1
- XCRHYAQWBYDRGV-UHFFFAOYSA-N ethyl 3-(4-propan-2-ylphenyl)prop-2-enoate Chemical compound CCOC(=O)C=CC1=CC=C(C(C)C)C=C1 XCRHYAQWBYDRGV-UHFFFAOYSA-N 0.000 description 1
- UONUEPNDJQOXAG-UHFFFAOYSA-N ethyl 4-[bis(3-hydroxypropyl)amino]benzoate Chemical compound CCOC(=O)C1=CC=C(N(CCCO)CCCO)C=C1 UONUEPNDJQOXAG-UHFFFAOYSA-N 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 125000004395 glucoside group Chemical group 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- LHGVFZTZFXWLCP-UHFFFAOYSA-N guaiacol Chemical class COC1=CC=CC=C1O LHGVFZTZFXWLCP-UHFFFAOYSA-N 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- KLFVEJIEFZPZAM-UHFFFAOYSA-N hexyl 2-cyano-3-(4-methoxyphenyl)prop-2-enoate Chemical compound CCCCCCOC(=O)C(C#N)=CC1=CC=C(OC)C=C1 KLFVEJIEFZPZAM-UHFFFAOYSA-N 0.000 description 1
- 150000002443 hydroxylamines Chemical class 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical class C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 150000004693 imidazolium salts Chemical class 0.000 description 1
- 238000000338 in vitro Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- CSFWPUWCSPOLJW-UHFFFAOYSA-N lawsone Chemical compound C1=CC=C2C(=O)C(O)=CC(=O)C2=C1 CSFWPUWCSPOLJW-UHFFFAOYSA-N 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 239000012669 liquid formulation Substances 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000002370 magnesium bicarbonate Substances 0.000 description 1
- 235000014824 magnesium bicarbonate Nutrition 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical class [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 235000011160 magnesium carbonates Nutrition 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 235000012243 magnesium silicates Nutrition 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- SOXAGEOHPCXXIO-DVOMOZLQSA-N menthyl anthranilate Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1OC(=O)C1=CC=CC=C1N SOXAGEOHPCXXIO-DVOMOZLQSA-N 0.000 description 1
- SJOXEWUZWQYCGL-DVOMOZLQSA-N menthyl salicylate Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1OC(=O)C1=CC=CC=C1O SJOXEWUZWQYCGL-DVOMOZLQSA-N 0.000 description 1
- 229960004665 menthyl salicylate Drugs 0.000 description 1
- 229960002248 meradimate Drugs 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 229940116837 methyleugenol Drugs 0.000 description 1
- PRHTXAOWJQTLBO-UHFFFAOYSA-N methyleugenol Natural products COC1=CC=C(C(C)=C)C=C1OC PRHTXAOWJQTLBO-UHFFFAOYSA-N 0.000 description 1
- 229950000999 mexenone Drugs 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- YIMHRDBSVCPJOV-UHFFFAOYSA-N n'-(2-ethoxyphenyl)-n-(2-ethylphenyl)oxamide Chemical compound CCOC1=CC=CC=C1NC(=O)C(=O)NC1=CC=CC=C1CC YIMHRDBSVCPJOV-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910021527 natrosilite Inorganic materials 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 125000002560 nitrile group Chemical group 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229960001679 octinoxate Drugs 0.000 description 1
- VIKVSUVYUVJHOA-UHFFFAOYSA-N octyl 3-phenylprop-2-enoate Chemical compound CCCCCCCCOC(=O)C=CC1=CC=CC=C1 VIKVSUVYUVJHOA-UHFFFAOYSA-N 0.000 description 1
- YAGMLECKUBJRNO-UHFFFAOYSA-N octyl 4-(dimethylamino)benzoate Chemical compound CCCCCCCCOC(=O)C1=CC=C(N(C)C)C=C1 YAGMLECKUBJRNO-UHFFFAOYSA-N 0.000 description 1
- 235000010387 octyl gallate Nutrition 0.000 description 1
- 239000000574 octyl gallate Substances 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229960001173 oxybenzone Drugs 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- LXTZRIBXKVRLOA-UHFFFAOYSA-N padimate a Chemical compound CCCCCOC(=O)C1=CC=C(N(C)C)C=C1 LXTZRIBXKVRLOA-UHFFFAOYSA-N 0.000 description 1
- FZUGPQWGEGAKET-UHFFFAOYSA-N parbenate Chemical compound CCOC(=O)C1=CC=C(N(C)C)C=C1 FZUGPQWGEGAKET-UHFFFAOYSA-N 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229960000969 phenyl salicylate Drugs 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229910052615 phyllosilicate Inorganic materials 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000083 poly(allylamine) Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- XATKDVHSLQMHSY-UHFFFAOYSA-N propan-2-yl 3-(4-methoxyphenyl)prop-2-enoate Chemical compound COC1=CC=C(C=CC(=O)OC(C)C)C=C1 XATKDVHSLQMHSY-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- WZXKPNYMUZGZIA-RMKNXTFCSA-N propyl (e)-3-(4-methoxyphenyl)prop-2-enoate Chemical compound CCCOC(=O)\C=C\C1=CC=C(OC)C=C1 WZXKPNYMUZGZIA-RMKNXTFCSA-N 0.000 description 1
- 235000010388 propyl gallate Nutrition 0.000 description 1
- 239000000473 propyl gallate Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- HFIYIRIMGZMCPC-YOLJWEMLSA-J remazole black-GR Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]S(=O)(=O)C1=CC2=CC(S([O-])(=O)=O)=C(\N=N\C=3C=CC(=CC=3)S(=O)(=O)CCOS([O-])(=O)=O)C(O)=C2C(N)=C1\N=N\C1=CC=C(S(=O)(=O)CCOS([O-])(=O)=O)C=C1 HFIYIRIMGZMCPC-YOLJWEMLSA-J 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
- 229960001860 salicylate Drugs 0.000 description 1
- SJOXEWUZWQYCGL-UHFFFAOYSA-N salicylic acid menthyl ester Natural products CC(C)C1CCC(C)CC1OC(=O)C1=CC=CC=C1O SJOXEWUZWQYCGL-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 230000009759 skin aging Effects 0.000 description 1
- 230000037380 skin damage Effects 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- URLJMZWTXZTZRR-UHFFFAOYSA-N sodium myristyl sulfate Chemical compound CCCCCCCCCCCCCCOS(O)(=O)=O URLJMZWTXZTZRR-UHFFFAOYSA-N 0.000 description 1
- 229950005425 sodium myristyl sulfate Drugs 0.000 description 1
- 239000012418 sodium perborate tetrahydrate Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
- KVSYNOOPFSVLNF-UHFFFAOYSA-M sodium;4-nonanoyloxybenzenesulfonate Chemical compound [Na+].CCCCCCCCC(=O)OC1=CC=C(S([O-])(=O)=O)C=C1 KVSYNOOPFSVLNF-UHFFFAOYSA-M 0.000 description 1
- 239000013042 solid detergent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- KBVBZJLGCBJUSU-UHFFFAOYSA-N stilbene;triazine Chemical compound C1=CN=NN=C1.C=1C=CC=CC=1C=CC1=CC=CC=C1 KBVBZJLGCBJUSU-UHFFFAOYSA-N 0.000 description 1
- 230000001180 sulfating effect Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 125000006318 tert-butyl amino group Chemical group [H]N(*)C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 150000003512 tertiary amines Chemical group 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- AOBORMOPSGHCAX-DGHZZKTQSA-N tocofersolan Chemical compound OCCOC(=O)CCC(=O)OC1=C(C)C(C)=C2O[C@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C AOBORMOPSGHCAX-DGHZZKTQSA-N 0.000 description 1
- LOIYMIARKYCTBW-OWOJBTEDSA-N trans-urocanic acid Chemical compound OC(=O)\C=C\C1=CNC=N1 LOIYMIARKYCTBW-OWOJBTEDSA-N 0.000 description 1
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical compound OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 1
- 239000001226 triphosphate Substances 0.000 description 1
- 238000002211 ultraviolet spectrum Methods 0.000 description 1
- UIYCHXAGWOYNNA-UHFFFAOYSA-N vinyl sulfide Chemical group C=CSC=C UIYCHXAGWOYNNA-UHFFFAOYSA-N 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
- 235000004835 α-tocopherol Nutrition 0.000 description 1
- 229910003319 β-Na2Si2O5 Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/1213—Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C11D3/42—Brightening agents ; Blueing agents
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic System; Zincates; Cadmates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic System; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/12—Aldehydes; Ketones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/1845—Aromatic mono- or polycarboxylic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/203—Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/2035—Aromatic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/335—Amines having an amino group bound to a carbon atom of a six-membered aromatic ring
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/352—Heterocyclic compounds having five-membered heterocyclic rings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
- D06M13/358—Triazines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
Definitions
- This invention relates to a method for UV protecting textile material, laundry detergent, laundry aftertreatment, and fabric conditioning formulations, finish compositions for UV protecting textile material, the thus finished textile material itself and the use of zinc oxide and/or titanium dioxide together with organic UV absorbers.
- UV-B-range UV radiation i.e., the range from about 280 to about 315 nm.
- the peak of the erythema action spectrum is located at 308 nm.
- Textiles scatter or absorb UV radiation and so act as a physical barrier to protect the skin against the harmful effects of sunlight (“textile skin protection”).
- textile skin protection the skin-protecting effect of textiles is dependent on many factors such as fiber type, fabric construction, fabric weight, color, moisture content or nature of finish.
- Summer clothing in the form of lightweight and light-colored cotton textiles offers only slight and hence inadequate protection against UV radiation.
- UV radiation may not only cause skin damage, but is also crucially responsible for sunlight-induced fading of colored textiles. There is therefore considerable interest in protecting colored textiles as well as human skin against the harmful effects of UV radiation.
- WO 97/44422 discloses that sunscreens especially from the group consisting of phenylbenzotriazoles, dibenzoylmethanes, p-aminobenzoic esters, cinnamic esters, salicylic esters, nonnitrogenous 2-hydroxybenzophenones, phenylbenzimidazoles and 2-cyano-3,3-diphenylacrylic esters and also mixtures thereof—without the respective mixing ratios being specified, however—are able to protect dyed textile material against fading.
- WO 96/03486 describes essentially the same sunscreens as mentioned in WO 97/44422 as agents for protecting dyed textile material against fading. But these agents are likewise still in need of improvement with regard to their efficacy and possess a number of disadvantages. An essential disadvantage is the frequently inadequate UV stability of the abovementioned agents.
- JP 03/277699 describes solid detergents, specifically soaps, containing from 0.1 to 15% by weight of zinc oxide.
- the soaps exhibit good UV absorption and possess a deodorizing effect.
- WO 98/42909 describes UV protecting textile fabric by treatment with inorganic particles in combination with a binder that are capable of absorbing, reflecting or scattering UV radiation. These particles may be applied during the washing or laundering of clothing as well as by other methods.
- UV absorber systems which are improved in their efficacy and photostability.
- organic UV absorbers and inorganic pigments comprising zinc oxide and/or titanium dioxide in textile finishes, laundry detergents or fabric conditioner compositions leads to a more effective UV protection of the textiles treated with these compositions than the sole use of the organic UV absorbers or inorganic pigments. Not only is skin better and more consistently protected against harmful UV radiation, but colored fabric is provided with improved protection against UV induced color fading.
- Component A comprises zinc oxide and/or titanium dioxide as UV absorbing inorganic pigments.
- Component A can consist of zinc oxide or titanium dioxide each on their own or of mixtures of the two pigments.
- Titanium dioxide can be used in its three crystal forms rutile, anatase or brookite, with rutile being preferred.
- the particle size is generally in the range from 0.01 to 100 ⁇ m and preferably in the range from 0.02 to 0.25 ⁇ m.
- Zinc oxide is generally used in a particle size of from 0.01 to 100 ⁇ m.
- the particle size is preferably in the range from 0.02 to 2 ⁇ m and more preferably in the range from 0.08 to 0.25 ⁇ m.
- the titanium dioxide and zinc oxide pigment particles may be passivated with a layer of inorganic oxides, especially silicon dioxide or aluminum oxide.
- the pigment surface may further be specifically hydrophilicized or hydrophobicized by treatment with organic compounds or silicones.
- Useful surface modifiers include for example amines, cationic polymers such as amino-containing polymers, polyols, organophosphates, alkyl phthalates, stearic acid, lauric acid or silicone oils.
- Component B may be commercially available sunscreen having at least one UV absorption maximum in the range from 280 to 450 nm.
- component B comprises such compounds as have at least one UV absorption maximum in the range from 290 to 375 nm.
- component (B) comprises compounds having at least one UV absorption maximum in the range from 280 to 315 nm (UV-B range) with an E 1 1 value of at least 200, especially at least 250, and at least one UV absorption maximum in the range from 315 to 400 nm (UV-A range) with an E 1 1 value of at least 200, especially at least 250.
- Organic UV absorbers B have one or more bands in the UV absorption spectrum.
- UV absorption maxima for the purposes of the present invention are the bands belonging to the corresponding local or absolute maxima in the UV spectrum of the particular compound, measured in customary organic solvents such as dichloromethane or methanol at room temperature.
- the E 1 1 value designates the extinction of the organic UV absorbers B which is measured in solution at a concentration of 1% by weight and a path length of 1 cm.
- the solvent used for this solution is customarily dichloromethane, although the use of other solvents customary for such UV measurements does not give fundamentally different values.
- the organic UV absorbers present as component B in the mixture of the invention have an n-octanol/water partition coefficient log P of at least 1.9, especially of at least 2.5, in particular of at least 3.3.
- Log P can be determined experimentally or arithmetically. Both techniques are described in Chemical Reviews Volume 71, No. 5, pages 52-5-616 (1971).
- organic UV absorbers B selected from the group consisting of
- Typical UV-absorbing phenylbenzotriazoles (I) are:
- Typical UV-absorbing dibenzoylmethanes (II) are:
- Typical UV-absorbing esters of p-aminobenzoic acid (II) are:
- Typical UV-absorbing esters of cinnamic acid (IV) are:
- Typical UV-absorbing esters of salicylic acid (V) are:
- Typical UV-absorbing nonnitrogenous 2-hydroxybenzophenones are:
- Typical UV-absorbing phenylbenzimidazoles are:
- Typical UV-absorbing acrylates are:
- Preferred acrylates include C 6 - to C 18 -alkyl esters or C 5 - to C 8 -cycloalkylesters of 2-cyano-3,3-diphenylacrylic acid.
- the C 6 - to C 1-8 -alcohol radical in the cyano-3,3-diphenylacrylic esters can be linear or singly or multiply branched, and it can be of natural or synthetic origin.
- Such alcohols can be for example fatty alcohols, oxo alcohols, Ziegler alcohols or Guerbet alcohols.
- Typical examples of such compounds are n-hexyl, n-heptyl, n-octyl, 2-ethylhexyl, n-nonyl, isononyl, n-decyl, n-dodecyl, n-tridecyl, isotridecyl, n-tetradecyl, n-pentadecyl, n-hexadecyl, n-heptadecyl, n-octadecyl or eicosyl ester.
- unsaturated alcohol radicals such as the oleyl, linolyl or linolenyl radical to occur. Mixtures of such esters can also be present.
- C 5 - to C 8 -cycloalkanol radicals in the cyano-3,3-diphenylacrylic esters there may be mentioned for example cyclopentyl, 2- or 3-methylcyclopentyl, cyclohexyl, 2-, 3- or 4-methylcyclohexyl, dimethylcyclohexyl, cycloheptyl or cyclooctyl radicals.
- Typical UV-absorbing diarylbutadienes are especially 4,4-diarylbutadienes of the formula (1) as are described in DE-A 198 28 463 for cosmetic and pharmaceutical preparations:
- diene system has the Z,Z; Z,E; E,Z or E,E configuration or a mixture thereof, and where the variables independently of one another have the following meanings:
- substituents which confer solubility in water and are selected from the group consisting of carboxylate, sulfonate or ammonium radicals;
- R 3 hydrogen, COOR 5 , COR 5 , CONR 5 R 6 , CN;
- R 5 hydrogen, [X] o -R 7 , C 1 -C 6 -alkylene-SO 3 Y, C 1 -C 6 -alkylene-PO 3 Y, C 1 -C 6 -alkylene-N(R 8 ) 3 + A ⁇ ;
- R 6 [X] o -R 7 , C 1 -C 6 -alkylene-SO 3 Y, C 1 -C 6 -alkylene-PO 3 Y, C 1 -C 6 -alkylene-N(R 8 ) 3 + A ⁇ ;
- R 9 hydrogen, C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl
- Typical UV-absorbing amino-substituted hydroxybenzophenones are in particular those of the formula (2) as are described in German patent application 199 17 906.9 for cosmetic and pharmaceutical preparations:
- R 1 and R 2 are hydrogen, C 1 -C 20 -alkyl, C 2 -C 10 -alkenyl, C 3 -C 10 -cycloalkyl, C 3 -C 10 -cycloalkenyl, where the substituents R 1 and R 2 together with the nitrogen atom to which they are bonded can form a 5- or 6-membered ring;
- R 3 and R 4 are C 1 -C 20 -alkyl, C 2 -C 10 -alkenyl, C 3 -C 10 -cycloalkyl, C 3 -C 10 -cycloalkenyl, C 1 -C 12 -alkoxy, C 1 -C 20 -alkoxycarbonyl, C 1 -C 1-2 -alkylamino, C 1 -C 12 -dialkylamino, aryl, heteroaryl, optionally substituted, and
- substituents which confer solubility in water and are selected from the group consisting of a nitrile group, carboxylate, sulfonate or ammonium radicals;
- X is hydrogen, COOR 5 , CONR 6 R 7 ;
- R 5 to R 7 are hydrogen, C 1 -C 20 -alkyl, C 2 -C 10 -alkenyl, C 3 -C 10 -cycloalkyl, C 3 -C 10 -cycloalkenyl, —(Y—O) o -Z, aryl;
- Y is —(CH 2 ) 2 —, —CH 2 ) 3 —, —(CH 2 ) 4 —, —CH(CH 3 )—CH 2 —;
- Z is —CH 2 —CH 3 , —CH 2 —CH 2 —CH 3 , —CH 2 —CH 2 —CH 2 —CH 3 , —CH(CH 3 )—CH 3 ;
- m is from 0 to 3;
- n is from 0 to 4.
- o is from 1 to 20.
- Typical UV-absorbing triazines are:
- useful organic UV absorbers B further include for example the following:
- Particularly preferred organic UV absorbers B which are used together with zinc oxide and/or titanium dioxide, include the compounds:
- antioxidants and/or free-radical traps which may be used here include all compounds customarily used for stabilizing food and feed but also for stabilizing plastics or lubricants. A list of such compounds may be found for example in Kirk-Othmer, Encyclopedia of Chemical Technology, fourth edition, volume 3, p. 424-447 or in Ullmann's Encyclopedia of Industrial Chemistry, sixth edition, 2000 Electronic Release, chapters antioxidants and food additives.
- substituted phenols, hydroquinones, pyrocatechols and gallates such as 2,6-di-tert-butylphenol, 2,4,6-tri-tert-butylphenol, 2,4-dimethyl-6-tert-butylphenol, 2,6-di-tert-butyl-4-methylphenol, 2,6-di-tert-butyl-4-methoxyphenol, 3-tert-butyl-4-methoxyphenol, 2,2′-methylenebis(4-methyl-6-tert-butylphenol), propyl, octyl and dodecyl gallate or tert-butylhydroquinone (TBHQ), butylated hydroxyanisoles (BHA) and butylated hydroxytoluene (BHT),
- TBHQ butylated hydroxyanisoles
- BHT butylated hydroxytoluene
- Irganox® antioxidants from Ciba-Geigy such as Irganox® 1010 (tetrakis(methylene 3,5-di-tert-butyl-4-hydroxycinnamate)-methane), Irganox® 1035 (thiodiethylene bis(3,5-di-tert-butyl-4-hydroxycinnamate)) and Irganox® 1076 (octadecyl propane(3-benzene-3′,5′-di-tert-butyl-4′-hydroxybenzyl)phosphonate),
- ⁇ -tocopherol and its natural or synthetic derivatives such as acetyl- ⁇ -tocopherol,
- ascorbic acid and ascorbic acid derivatives especially esterification products with long-chain fatty acids such as ascorbyl palmitate,
- DABCO diazabicyclooctane
- chroman derivatives such as long-chain esters of 2,5,7,8-tetramethyl-6-hydroxychroman-2 acid
- aromatic amines such as ethoxyquin
- organic sulfides such as 3,3′-thiodipropionic acid and dilauryl thiodipropionate
- sterically hindered amines for example of the tetramethylpiperidine type such as Uvinul®4049H, Uvinul® 4050H and Uvinul® 5050H from BASF AG,
- hydroxylamines such as those of dialkylamines and hydroxylamine ether derivatives of tetramethylpiperidine compounds,
- the inorganic pigments A and organic UV absorbers B cooperate very well as UV absorbers possessing textile fiber affinity and mutually reinforce their effect. First, they protect, when applied to a textile material, the human skin against harmful UV radiation. Secondly, they protect dyed textile material against fading. The two protective effects preferably occur simultaneously.
- Textile materials with which the components A and B have affinity and where they develop their protective effect include in particular apparel articles, i.e., articles which are worn on the human skin, but also house and garden articles comprising dyed textiles such as awnings and sunshades which are exposed to intensive solar irradiation.
- This textile material to be protected preferably comprises cellulose (cotton), for example apparel textiles comprising cotton or cotton-polyester blends.
- the present invention also provides for the use of zinc oxide and/or titanium dioxide together with organic UV absorbers on textile material to protect human skin against harmful UV radiation and/or to protect dyed textile material against fading.
- the mixture containing the components A and B is customarily applied to the textile material in the form of an aqueous liquor containing the components A and B alongside further ingredients, for example by spraying or dipping and squeezing off.
- the components A and B can be applied to the textile material in the course of textile finishing during the manufacture of the textile material, in the course of laundering, in the course of laundry pretreatment and/or laundry aftertreatment.
- the UV protection factor UPF of the textile material is increased as a result.
- the UV protection factor or Ultraviolet Radiation Protection Factor UPF of textiles is determined in accordance with the Australian/New Zealand standard AS/NZS 4399:1996 using an in vitro method. It measures the UV transmission of the textile object.
- S ⁇ is the spectral irradiation of the sun in the UV region at the wavelength ⁇
- E ⁇ is the spectral erythema action of the UV radiation at the wavelength ⁇
- T ⁇ is the spectral transmissivity of the textile object at the wavelength ⁇ .
- the present invention also provides a laundry detergent formulation comprising from 0.01% to 20% by weight, preferably from 0.1% to 10% by weight, particularly preferably from 0.1 to 5% by weight of the components A and B alongside further customary ingredients.
- the weight ratio of component A to component B is preferably in the range from 20:1 to 1:10, particularly preferably in the range from 8:1 to 1:5 and specifically preferably in the range from 3:1 to 1:1.
- the components A and B can be added separately to the formulation or a ready-prepared mixture of A and B can be incorporated into the formulation.
- Laundry detergent formulations according to the invention can be solid or liquid formulations.
- Solid laundry detergent formulations according to the invention generally include as further customary ingredients
- customary ingredients such as cationic surfactants, standardizing agents, enzymes, perfume, complexing agents, corrosion inhibitors, bleaching agents, bleach activators, bleach catalysts, dye transfer inhibitors, soil antiredeposition agents, soil release polyesters, colorants, dissolution improvers and/or disintegrants as component F,
- components A to F adding up to 100% by weight.
- the solid laundry detergent formulations of the invention are customarily present in powder, granule, extrudate or tablet form.
- Liquid laundry detergent formulations according to the invention generally include as further customary constituents
- customary ingredients such as cationic surfactants, sodium carbonate, enzymes, perfume, complexing agents, corrosion inhibitors, bleaching agents, bleach activators, bleach catalysts, dye transfer inhibitors, soil antiredeposition agents, soil release polyesters, colorants, nonaqueous solvents, hydrotropes, thickeners and/or alkanolamines as component F, and
- Useful anionic surfactants are in particular:
- sulfated alkoxylated C 8 - to C 22 -alcohols (alkyl ether sulfates).
- Compounds of this kind are prepared for example by first alkoxylating a C 8 - to C 22 -alcohol, preferably a C 10 - to C 18 -alcohol, for example a fatty alcohol, and then sulfating the alkoxylation product.
- the alkoxylation is preferably carried out using ethylene oxide;
- linear C 8 - to C 20 -alkylbenzenesulfonates LAS
- linear C 9 - to C 13 -alkylbenzenesulfonates and -alkyltoluenesulfonates LAS
- alkanesulfonates such as C 8 - to C 24 - and preferably C 10 - to C 18 -alkanesulfonates,
- soaps such as for example the sodium and potassium salts of C 8 - to C 24 -carboxylic acids.
- the anionic surfactants mentioned are preferably included in the laundry detergent in the form of salts. Suitable cations in these salts are alkali metal ions such as sodium, potassium and lithium and ammonium ions such as hydroxyethylammonium, di(hydroxyethyl)ammonium and tri(hydroxyethyl)ammonium.
- Useful nonionic surfactants are in particular:
- alkoxylated C 8 - to C 22 -alcohols such as fatty alcohol alkoxylates or oxo alcohol alkoxylates. These may have been alkoxylated with ethylene oxide, propylene oxide and/or butylene oxide.
- Useful surfactants here include all alkoxylated alcohols which contain at least two molecules of one of the aforementioned alkylene oxides. Here it is possible to use block polymers of ethylene oxide, propylene oxide and/or butylene oxide or addition products which contain the aforementioned alkylene oxides in random distribution.
- Nonionic surfactants generally contain from 2 to 50 and preferably from 3 to 20 mol of at least one alkylene oxide per mole of alcohol.
- the alkylene oxide component is preferably ethylene oxide.
- the alcohols preferably have from 10 to 18 carbon atoms.
- alkoxylates have a broad or narrow alkylene oxide homologue distribution;
- alkylphenol alkoxylates such as alkylphenol ethoxylates having C 6 - to C 14 -alkyl chains and from 5 to 30 alkylene oxide units;
- alkylpolyglucosides having from 8 to 22 and preferably from 10 to 18 carbon atoms in the alkyl chain and generally from 1 to 20 and preferably from 1.1 to 5 glucoside units;
- N-alkylglucamides fatty acid amide alkoxylates, fatty acid alkanolamide alkoxylates and also block copolymers of ethylene oxide, propylene oxide and/or butylene oxide.
- Useful inorganic builders are in particular:
- crystalline or amorphous aluminosilicates having ion-exchanging properties such as zeolites in particular.
- Useful zeolites include in particular zeolites A, X, B, P, MAP and HS in their sodium form or in forms in which sodium has been partly replaced by other cations such as lithium, potassium, calcium, magnesium or ammonium;
- crystalline silicates such as in particular disilicates or sheet-silicates, for example ⁇ -Na 2 Si 2 O 5 or ⁇ -Na 2 Si 2 O 5
- the silicates can be used in the form of their alkali metal, alkaline earth metal or ammonium salts, preferably as sodium, lithium and magnesium silicates;
- amorphous silicates such as sodium metasilicate or amorphous disilicate
- carbonates and bicarbonates are used in the form of their alkali metal, alkaline earth metal or ammonium salts. Preference is given to sodium, lithium and magnesium carbonates or bicarbonates, especially sodium carbonate and/or sodium bicarbonate;
- polyphosphates such as pentasodium triphosphate.
- Useful organic cobuilders include in particular low molecular weight, oligomeric or polymeric carboxylic acids.
- Useful low molecular weight carboxylic acids include for example citric acid, hydrophobically modified citric acid such as for example agaric acid, malic acid, tartaric acid, gluconic acid, glutaric acid, succinic acid, imidodisuccinic acid, oxydisuccinic acid, propanetricarboxylic acid, butanetetracarboxylic acid, cyclopentanetetracarboxylic acid, alkyl- and alkenylsuccinic acids and aminopolycarboxylic acids such as for example nitrilotriacetic acid, ⁇ -alaninediacetic acid, ethylenediaminetetraacetic acid, serinediacetic acid, isoserinediacetic acid, N-(2-hydroxyethyl)iminodiacetic acid, ethylenediaminedisuccinic acid and methyl- and ethylglycinediacetic acid;
- citric acid hydrophobically modified citric acid such as for example
- useful oligomeric or polymeric carboxylic acids include for example homopolymers of acrylic acid, oligomaleic acids, copolymers of maleic acid with acrylic acid, methacrylic acid, C 2 -C 22 -olefins such as for example isobutene or long-chain ⁇ -olefins, vinyl alkyl ethers having C 1 -C 8 -alkyl groups, vinyl acetate, vinyl propionate, methacrylic esters of C 1 -C 8 -alcohols and styrene. Preference is given to using the homopolymers of acrylic acid and also copolymers of acrylic acid with maleic acid. Polyaspartic acids are also useful as organic cobuilders. Oligomeric and polymeric carboxylic acids are used in acid form or as sodium salt.
- Useful bleaching agents include for example adducts of hydrogen peroxide with inorganic salts such as for example sodium perborate monohydrate, sodium perborate tetrahydrate or sodium carbonate perhydrate or percarboxylic acids such as phthalimidopercaproic acid.
- Suitable bleaching activators are e.g. N,N,N′,N′-tetraacetyl ethylendiamine (TAED), sodium p-nonanoyloxybenzenesulfonate or N-methylmorpholiniumacetonitrilmethylsulfate.
- TAED N,N,N′,N′-tetraacetyl ethylendiamine
- sodium p-nonanoyloxybenzenesulfonate sodium p-nonanoyloxybenzenesulfonate or N-methylmorpholiniumacetonitrilmethylsulfate.
- Enzymes preferably used in laundry detergents are proteases, lipases, amylases, cellulases, oxidases or peroxidases.
- Suitable dye transfer inhibitors are e.g. homopolymers and copolymers of 1-vinylpyrrolidone, 1-vinylimidazole or 4-vinylpyridine-N-oxide. Homopolymers and copolymers of 4-vinylpyridine reacted with chloroacetic acid are also suitable dye transfer inhibitors.
- the present invention further provides laundry aftertreatment and laundry conditioning compositions comprising from 0.01% to 20% by weight, preferably from 0.1 to 10% by weight and particularly preferably from 0.1% to 5% by weight of components A and B as well as other customary constituents.
- the weight ratio of component A to component B is preferably in the range from 20:1 to 1:10, more preferably in the range from 8:1 to 1:5 and especially in the range from 3:1 to 1:1.
- the components A and B can be added separately to the formulation or a ready-prepared mixture of A and B can be incorporated into the formulation.
- the laundry aftertreatment and laundry conditioning compositions of the invention generally include as further customary constituents c) from 0.1 to 40% by weight of at least one cationic surfactant as component C,
- further customary ingredients such as scents, colorants, stabilizers, fiber and color protection additives, viscosity modifiers, soil release additives, soil antiredeposition agents, dye transfer inhibitors, complexing agents, corrosion control additives, bactericides, preservatives, nonaqueous solvents, hydrotropes and/or alkanolamines as component E,
- Useful cationic polymers include all natural or synthetic cationic polymers containing amino and/or ammonium groups and being soluble or dispersible in water.
- cationic polymers are polyethyleneimines, amidated, alkoxylated and/or alkylated polyethyleneimines, crosslinked polyethyleneimines, polyamidoamines, alkoxylated and/or alkylated polyamidoamines, crosslinked polyamidoamines, ethyleneimine-grafted crosslinked polyamidoamines, amine-epichlorohydrin polycondensates, polyvinylamines, alkoxylated polyvinylamines, partially hydrolyzed polyvinylformamides, polyallylamines, polydimethyldiallylammonium chlorides, polymers containing 1-vinylimidazole units such as poly-1-vinylimidazole or poly-(1-vinylimidazole-co-1-vinylpyrrolidon
- cationic polymers also comprehends amphoteric addition polymers which have a net cationic charge, i.e., the polymers contain both anionic and cationic monomers in copolymerized form, but the molar fraction of the cationic units present in the polymers is greater than that of the anionic units.
- Preferred cationic surfactants are selected from the group consisting of the quaternary diesterammonium salts, the quaternary tetraalkylammonium salts, the quaternary diamidoammonium salts, the amidoamine esters and imidazolium salts. These are preferably present in the fabric conditioners in an amount of from 3 to 30% by weight.
- Examples are quaternary diesterammonium salts having two C 11 - to C 22 -alk(en)ylcarbonyloxy(mono- to pentamethylene) radicals and two C 1 - to C 3 -alkyl- or hydroxyalkyl radicals on the quaternary nitrogen atom and, for example, chloride, bromide, methosulfate or sulfate as counterion.
- Quaternary diesterammonium salts are further in particular those which have a C 11 - to C 2-2 -alk(en)ylcarbonyloxytrimethyleneradical bearing a C 11 - to C 22 -alk(en)ylcarbonyloxy radical on the central carbon atom of the trimethylene group and three C 1 - to C 3 -alkyl- or hydroxyalkyl radicals on the quaternary nitrogen atom and, for example, chloride, bromide, methosulfate or sulfate as counterion.
- Quaternary tetraalkylammonium salts are in particular those which have two C 1 - to C 6 -alkylradicals and two C 8 - to C 24 -alk(en)yl radicals on the quaternary nitrogen atom and, for example, chloride, bromide, methosulfate or sulfate as counterion.
- Quaternary diamidoammonium salts are in particular those which have two C 8 - to C 24 -alk(en)ylcarbonylaminoethyleneradicals, a substituent selected from hydrogen, methyl, ethyl and polyoxyethylene having up to 5 oxyethylene units and as fourth radical a methyl group on the quaternary nitrogen atom and, for example, chloride, bromide, methosulfate or sulfate as counterion.
- Amidoamino esters are in particular tertiary amines bearing a C 11 - to C 22 -alk(en)ylcarbonylamino(mono- to trimethylene) radical, a C 11 - to C 22 -alk(en)ylcarbonyloxy(mono- to trimethylene) radical and a methyl group as substituents on the nitrogen atom.
- Imidazolinium salts are in particular those which bear a C 14 - to C 18 -alk(en)yl radical in position 2 of the heterocycle, a C 14 - to C 18 -alk(en)ylcarbonyl(oxy or amino)ethylene radical on the neutral nitrogen atom and hydrogen, methyl or ethyl on the nitrogen atom carrying the positive charge, while counterions here are for example chloride, bromide, methosulfate or sulfate.
- the present invention also provides for the use of zinc oxide and/or titanium dioxide together with organic UV absorbers in laundry detergent, laundry aftertreatment and laundry conditioning compositions.
- the present invention also provides a finishing composition for UV protection of textile materials comprising the components A and B.
- finishing compositions according to the invention are present for example as finishes in the narrower sense in the course of the manufacture of the textiles or in the form of an aqueous wash liquor or as a liquid textile treatment composition. It is accordingly possible for example to treat the textiles with the finishing composition in connection with the manufacture of the textiles. Textiles never treated or only inadequately treated with a finish may be treated for example in the home before or after washing with a textile treatment composition containing the inorganic pigments A and the organic UV absorbers B. But it is also possible to treat the textiles with the components (A) and (B) in the main wash cycle or after the main wash cycle in the conditioning rinse cycle of the washing machine, partly using the above-described formulations.
- UV Protectant as a Laundry Aftertreatment in the Conditioning Rinse Bath and Determination of the UV Protection Factor UPF
- White woven cotton fabric having a basis weight of 100 g/m 2 and a UV protection factor (UPF) of 4.1 was washed at a water hardness of 3 mmol/l.
- the laundering process was a main wash cycle at 40° C. with a commercially available laundry detergent (Ariel® Color) and a subsequent conditioning rinse.
- the conditioner used was a commercially available formulation (Downy from Lenor®) in a dosage of 1000 ppm, based on the liquor.
- the fabric conditioner formulation included either no UV absorber or in each case 100 or 200 ppm, based on the liquor, of an inventive UV absorber combination, added before the conditioning rinse.
- the liquor ratio was 12.5:1.
- the fabric was removed and its UV protection factor was determined in the dried state. Subsequently the fabric was tested for photostability.
- the fabric sample was exposed in a SUNTEST® CPS tabletop accelerated lighting unit from Heraeus, Hanau, for 4 and 24 hours under outdoor conditions using a WG 295 filter at the maximum radiative power output of the instrument.
- the UV protection factor was redetermined after 4 and 24 hours of exposure.
- Z-COTE® an amphiphilic zinc oxide from BASF AG
- organic UV absorbers were used as follows:
- A 2-ethylhexyl 2-cyano-3,3-diphenylacrylate (Uvinul® N-539 T)
- Zinc oxide and titanium dioxide increase the UV protection factor of the cotton fabric only insignificantly when used alone in either case.
- a woven cotton fabric dyed with Reactive Black 5 to 1 ⁇ 3 standard depth was treated in the conditioning rinse cycle with a commercially available formulation (Downy from Lenor®, 1000 ppm, based on the liquor) in the presence of an inventive UV absorber combination (in each case 200 ppm, based on the liquor) in a liquor ratio of 12.5:1. After the conditioning rinse cycle, the dyed fabrics were removed and tested for photostability in the dried state.
- a commercially available formulation Downy from Lenor®, 1000 ppm, based on the liquor
- an inventive UV absorber combination in each case 200 ppm, based on the liquor
- the inorganic pigment used was Z-COTE® from BASF AG.
- D 1-(4-tert-butylphenyl)-3-(4-methoxyphenyl)propane-1,3-dione (Uvinul® BMBM) TABLE 2 K/S (24 h)/K/S (0 h) ⁇ K/S (8 h)/K/S (0 h) ⁇ 100% 100% no additive 77.2% 57.7% 400 ppm of ZnO 82.0% 63.7% 400 ppm of C 81.3% 62.0% 200 ppm of C + 85.5% 68.8% 200 ppm of ZnO 400 ppm of D 80.8% 61.0% 200 ppm of D + 84.9% 67.0% 200 ppm of ZnO
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
A method for UV protecting a textile material which comprises applying
(a) zinc oxide and/or titanium oxide as a component A and
(b) one or more organic UV absorbers as a component B to said textile material.
Component B preferably comprises one or more compounds selected from the group consisting of
phenylbenzotriazoles,
dibenzoylmethanes,
esters of p-aminobenzoic acid,
esters of cinnamic acid,
esters of salicylic acid,
nonnitrogenous 2-hydroxybenzophenones,
phenylbenzimidazoles,
acrylates,
diarylbutadienes,
amino-substituted hydroxybenzophenones,
triazines.+
Description
- This invention relates to a method for UV protecting textile material, laundry detergent, laundry aftertreatment, and fabric conditioning formulations, finish compositions for UV protecting textile material, the thus finished textile material itself and the use of zinc oxide and/or titanium dioxide together with organic UV absorbers.
- The harmful effects of the UV content of sunlight on human skin are not restricted to premature skin aging and the formation of erythemas (skin reddening, sunburn). Excessively long and intensive exposure of the skin to UV radiation also raises the risk of developing skin cancer. The chief culprit responsible for skin reddening and the increased risk of skin cancer is the UV-B-range of UV radiation, i.e., the range from about 280 to about 315 nm. The peak of the erythema action spectrum is located at 308 nm.
- Textiles scatter or absorb UV radiation and so act as a physical barrier to protect the skin against the harmful effects of sunlight (“textile skin protection”). However, the skin-protecting effect of textiles is dependent on many factors such as fiber type, fabric construction, fabric weight, color, moisture content or nature of finish. Summer clothing in the form of lightweight and light-colored cotton textiles offers only slight and hence inadequate protection against UV radiation.
- An excessive dose of UV radiation may not only cause skin damage, but is also crucially responsible for sunlight-induced fading of colored textiles. There is therefore considerable interest in protecting colored textiles as well as human skin against the harmful effects of UV radiation.
- It is mainly customary optical brighteners which have hitherto been used to finish and to protect the textiles themselves and also for textile skin protection, especially stilbene- and triazine-based optical brighteners as described for example in EP-A 682 145, GB-A 2 313 375 or EP-A 728 749. But the agents are still in need of improvement with regard to their efficacy and possess a number of disadvantages. Significant disadvantages are their poor formulatability and their inadequate solubility in the respective application medium.
- WO 97/44422 discloses that sunscreens especially from the group consisting of phenylbenzotriazoles, dibenzoylmethanes, p-aminobenzoic esters, cinnamic esters, salicylic esters, nonnitrogenous 2-hydroxybenzophenones, phenylbenzimidazoles and 2-cyano-3,3-diphenylacrylic esters and also mixtures thereof—without the respective mixing ratios being specified, however—are able to protect dyed textile material against fading. WO 96/03486 describes essentially the same sunscreens as mentioned in WO 97/44422 as agents for protecting dyed textile material against fading. But these agents are likewise still in need of improvement with regard to their efficacy and possess a number of disadvantages. An essential disadvantage is the frequently inadequate UV stability of the abovementioned agents.
- The incorporation of pigments such as titanium dioxide or zinc oxide in fibers is a tried and tested way of conferring UV protection on textiles comprising these fibers. Especially manufactured fibers comprising polyamide, polyester or polyacrylonitrile are useful for this kind of UV protection. Cellulose fibers less so.
- JP 03/277699 describes solid detergents, specifically soaps, containing from 0.1 to 15% by weight of zinc oxide. The soaps exhibit good UV absorption and possess a deodorizing effect.
- WO 98/42909 describes UV protecting textile fabric by treatment with inorganic particles in combination with a binder that are capable of absorbing, reflecting or scattering UV radiation. These particles may be applied during the washing or laundering of clothing as well as by other methods.
- It is an object of the present invention to provide UV absorber systems which are improved in their efficacy and photostability.
- We have found that this object is achieved by a method for UV protecting a textile material, which comprises applying
- (a) zinc oxide and/or titanium oxide as a component A and
- (b) one or more organic UV absorbers as a component B to said textile material.
- Surprisingly, the combined use of organic UV absorbers and inorganic pigments comprising zinc oxide and/or titanium dioxide in textile finishes, laundry detergents or fabric conditioner compositions leads to a more effective UV protection of the textiles treated with these compositions than the sole use of the organic UV absorbers or inorganic pigments. Not only is skin better and more consistently protected against harmful UV radiation, but colored fabric is provided with improved protection against UV induced color fading.
- Component A comprises zinc oxide and/or titanium dioxide as UV absorbing inorganic pigments. Component A can consist of zinc oxide or titanium dioxide each on their own or of mixtures of the two pigments.
- Titanium dioxide can be used in its three crystal forms rutile, anatase or brookite, with rutile being preferred. The particle size is generally in the range from 0.01 to 100 μm and preferably in the range from 0.02 to 0.25 μm.
- Zinc oxide is generally used in a particle size of from 0.01 to 100 μm. The particle size is preferably in the range from 0.02 to 2 μm and more preferably in the range from 0.08 to 0.25 μm.
- The titanium dioxide and zinc oxide pigment particles may be passivated with a layer of inorganic oxides, especially silicon dioxide or aluminum oxide. The pigment surface may further be specifically hydrophilicized or hydrophobicized by treatment with organic compounds or silicones. Useful surface modifiers include for example amines, cationic polymers such as amino-containing polymers, polyols, organophosphates, alkyl phthalates, stearic acid, lauric acid or silicone oils.
- Examples of very useful surface modifiers are:
- Uvinul® TiO2 (from BASF AG),
- Z-COTE® (from BASF AG) and
- Z-COTE HP1® (from BASF AG).
- Component B may be commercially available sunscreen having at least one UV absorption maximum in the range from 280 to 450 nm.
- In a preferred embodiment, component B comprises such compounds as have at least one UV absorption maximum in the range from 290 to 375 nm.
- In a further preferred embodiment, component (B) comprises compounds having at least one UV absorption maximum in the range from 280 to 315 nm (UV-B range) with an E1 1 value of at least 200, especially at least 250, and at least one UV absorption maximum in the range from 315 to 400 nm (UV-A range) with an E1 1 value of at least 200, especially at least 250.
- Organic UV absorbers B have one or more bands in the UV absorption spectrum. UV absorption maxima for the purposes of the present invention are the bands belonging to the corresponding local or absolute maxima in the UV spectrum of the particular compound, measured in customary organic solvents such as dichloromethane or methanol at room temperature.
- The E1 1 value designates the extinction of the organic UV absorbers B which is measured in solution at a concentration of 1% by weight and a path length of 1 cm. The solvent used for this solution is customarily dichloromethane, although the use of other solvents customary for such UV measurements does not give fundamentally different values.
- In a further preferred embodiment, the organic UV absorbers present as component B in the mixture of the invention have an n-octanol/water partition coefficient log P of at least 1.9, especially of at least 2.5, in particular of at least 3.3. Log P can be determined experimentally or arithmetically. Both techniques are described in Chemical Reviews Volume 71, No. 5, pages 52-5-616 (1971).
- Preference is given to using organic UV absorbers B selected from the group consisting of
- (I) phenylbenzotriazoles,
- (II) dibenzoylmethanes,
- (III) esters of p-aminobenzoic acid,
- (IV) esters of cinnamic acid,
- (V) esters of salicylic acid,
- (VI) nonnitrogenous 2-hydroxybenzophenones,
- (VII) phenylbenzimidazoles,
- (VIII)acrylates,
- (IX) diarylbutadienes,
- (X) amino-substituted hydroxybenzophenones and
- (XI) triazines.
- Typical UV-absorbing phenylbenzotriazoles (I) are:
- 2,2′-hydroxy-5-methylphenylbenzotriazole,
- 2,2′-hydroxy-5-tert-octylphenylbenzotriazole,
- 2-hydroxy-3-sec-butyl-5-tert-butylbenzotriazole (Tinuvin® 350),
- 2-hydroxy-3-dodecyl-5-methylphenylbenzotriazole (Tinuvin® 571),
- 2-(2H-benzotriazol-2-yl)-4-methylphenol (Tinuvin® P),
- 2-(2H-benzotriazol-2-yl)-4-n-octylphenyl (Tinuvin® 329),
- 2-(2H-benzotriazol-2-yl)-4,6-di(2′-phenylisopropyl)phenol (Tinuvin® 234),
- 2-(2H-benzotriazol-2-yl)-4,6-di(tert-butyl)phenol (Tinuvin® 320),
- 2-(6-chloro-2H-benzotriazol-2-yl)-4-methyl-6-tert-butylphenol (Tinuvin® 326),
- 2-(6-chloro-2H-benzotriazol-2-yl)-2,6-di-tert-butylphenol (Tinuvin® 327),
- 2-(2′-hydroxy-3′,5′-di-tert-amylphenyl)-2H-benzotriazole (Tinuvin® 328),
- mixture of polyoxyethylene glycol α-[3-(2H-benzotriazol-2-yl)-5-tert-butyl-4-hydroxyphenyl] propionate and polyoxyethylene glycol bisβ-[3-(2H-benzotriazol-2-yl)-5-tert-butyl-4-hydroxyphenyl] propionate having an average molecular weight>600 (Tinuvin® 1130),
- cocoyl-2-[2′-hydroxy-3′-(cocoyl dimethylbutanoate)-5′-methylphenyl]benzotriazole,
- cocoyl 3-[3′-(2H-benzotriazol-2′-yl)-5-tert-butyl-4′-hydroxyphenyl]propionate,
- 2,2′-methylenebis[6-(2H-benzotriazol-2-yl)-4-(1,1,3,3-tetramethylbutyl)]phenol (Tinuvin® 360),
- 2-(2H-1,2,3-benzotriazol-2-yl)-4-methyl-6-(2-methyl-3-{1,3,3,3-tetramethyl-1-[(trimethylsilyl)oxy]disiloxanyl}propyl)phenol.
- Typical UV-absorbing dibenzoylmethanes (II) are:
- 3-(4-isopropylphenyl)-3-phenylpropane-1,3-dione (Eusolex® 8020),
- 1-(4-tert-butylphenyl)-3-(4-methoxyphenyl)propane-1,3-dione (Uvinul® BMBM),
- 1,3-bis(4-methoxyphenyl)propane-1,3-dione.
- Typical UV-absorbing esters of p-aminobenzoic acid (II) are:
- ethyl 4-bis(hydroxypropyl)aminobenzoate (Amerscheen®P),
- 2,3-dihydroxypropyl 4-aminobenzoate (Nipa® GMPA),
- menthyl 2-aminobenzoate (Sunarome® UVA),
- 2-ethylhexyl 4-dimethylaminobenzoate (Escalol® 507),
- amyl 4-dimethylaminobenzoate,
- ethyl 4-dimethylaminobenzoate,
- butyl 4-dimethylaminobenzoate,
- octyl 4-dimethylaminobenzoate,
- lauryl 4-dimethylaminobenzoate,
- oleyl 4-dimethylaminobenzoate,
- polyethoxyethyl 4-bis(polyethoxy)-4-aminobenzoate (Uvinul® P-25),
- N-propoxylated ethyl 4-aminobenzoate.
- Typical UV-absorbing esters of cinnamic acid (IV) are:
- 2-ethylhexyl 4-methoxycinnamate (Uvinul® MC80, Parsol® MCX),
- 2-ethoxyethyl 4-methoxycinnamate,
- propyl 4-methoxycinnamate,
- isoamyl 4-methoxycinnamate,
- cyclohexyl 4-methoxycinnamate,
- isopropyl 4-methoxycinnamate,
- octyl cinnamate,
- ethyl 4-isopropylcinnamate,
- ethyl α-cyano-β-phenylcinnamate,
- 2-ethylhexyl α-cyano-β-phenylcinnamate.
- Typical UV-absorbing esters of salicylic acid (V) are:
- 2-ethylhexyl salicylate (Sunarome® WMO),
- 3,3,5-trimethylcyclohexyl 2-hydroxybenzoate,
- 3,3,5-trimethylcyclohexyl 2-acetamidobenzoate,
- 2-ethylhexyl 2-(4-phenylbenzoyl)benzoate,
- 4-isopropylbenzyl salicylate,
- amyl salicylate,
- menthyl salicylate,
- homomethyl salicylate,
- phenyl salicylate,
- benzyl salicylate,
- isodecyl salicylate.
- Typical UV-absorbing nonnitrogenous 2-hydroxybenzophenones (VI) are:
- 2-hydroxy-4-methoxybenzophenone (Uvinul® M40),
- 2,2′-dihydroxy4-methoxybenzophenone (Spectra-Sorb® UV-24),
- 2,4-dihydroxybenzophenone (Uvinul® 3000),
- 2,2′,4,4′-tetrahydroxybenzophenone (Uvinul® D-50),
- 2,2′-dihydroxy-4,4′-dimethoxybenzophenone (Uvinul® D-49),
- 2,2-dihydroxy-4,4-dimethoxybenzophenone (Uvinul® 3049),
- 2-hydroxy-4-(2-ethylhexyloxy)benzophenone,
- 2-hydroxy-4-(n-octyloxy)benzophenone (Uvinul® 3008),
- 2-hydroxy-4-methoxy-4′-methylbenzophenone (Mexenone®),
- 2-ethylhexyl 4′-phenylbenzophenone-2-carboxylate,
- 2-hydroxy-3-carboxybenzophenone,
- benzophenone-3 cocoyl acetate ether,
- 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid (Uvinul® MS 40) and its sodium salt,
- 2,2′-dihydroxy-4,4′-dimethoxybenzophenone-5,5′-bissulfonic acid and its sodium salt (Uvinul® DS 49).
- Typical UV-absorbing phenylbenzimidazoles (VII) are:
- 2-phenylbenzimidazole-5-sulfonic acid (Eusolex® 232) and its potassium, sodium and triethanolamine salts,
- 2-[5,6-disulfo-(1H-benzimidazol-2-yl)phenyl]-1H-benzimidazole5,6-disulfonic acid.
- Typical UV-absorbing acrylates (VIII) are:
- 3-imidazol-4-ylacrylic acid,
- ethyl 3-imidazol-4-ylacrylate,
- 2-cyano-3-(4-methoxyphenyl)acrylic acid,
- hexyl 2-cyano-3-(4-methoxyphenyl)acrylate.
- Preferred acrylates include C6- to C18-alkyl esters or C5- to C8-cycloalkylesters of 2-cyano-3,3-diphenylacrylic acid. The C6- to C1-8-alcohol radical in the cyano-3,3-diphenylacrylic esters can be linear or singly or multiply branched, and it can be of natural or synthetic origin. Such alcohols can be for example fatty alcohols, oxo alcohols, Ziegler alcohols or Guerbet alcohols. Typical examples of such compounds are n-hexyl, n-heptyl, n-octyl, 2-ethylhexyl, n-nonyl, isononyl, n-decyl, n-dodecyl, n-tridecyl, isotridecyl, n-tetradecyl, n-pentadecyl, n-hexadecyl, n-heptadecyl, n-octadecyl or eicosyl ester. It is also possible for unsaturated alcohol radicals such as the oleyl, linolyl or linolenyl radical to occur. Mixtures of such esters can also be present.
- As C5- to C8-cycloalkanol radicals in the cyano-3,3-diphenylacrylic esters there may be mentioned for example cyclopentyl, 2- or 3-methylcyclopentyl, cyclohexyl, 2-, 3- or 4-methylcyclohexyl, dimethylcyclohexyl, cycloheptyl or cyclooctyl radicals.
- Preference is given to linear or singly or multiply branched C8- to C13-alkyl esters of 2-cyano-3,3-diphenylacrylic acid. The corresponding 2-ethylhexyl ester is commercially available as Uvinul® N-539 T from BASF Aktiengesellschaft.
-
- where the diene system has the Z,Z; Z,E; E,Z or E,E configuration or a mixture thereof, and where the variables independently of one another have the following meanings:
- R1 and R2
- hydrogen, C1-C20-alkyl, C2-C10-alkenyl, C3-C10-cycloalkyl, C3-C10-cycloalkenyl, C1-C12-alkoxy, C1-C20-alkoxycarbonyl, C1-C12-alkylamino, C1-C12-dialkylamino, aryl, hetaryl, unsubstituted or substituted, and
- substituents which confer solubility in water and are selected from the group consisting of carboxylate, sulfonate or ammonium radicals;
- R3 hydrogen, COOR5, COR5, CONR5R6, CN;
- R4 COOR6, COR6, CONR5R6;
- R5 hydrogen, [X]o-R7, C1-C6-alkylene-SO3Y, C1-C6-alkylene-PO3Y, C1-C6-alkylene-N(R8)3 +A−;
- R6 [X]o-R7, C1-C6-alkylene-SO3Y, C1-C6-alkylene-PO3Y, C1-C6-alkylene-N(R8)3 +A−;
- x —CH2—CH2-Z-, —CH2—CH2—CH2-Z-, —CH(CH3)—CH2-Z-, —CH2—CH2—CH2—CH2-Z-, —CH2CH(CH2—CH3)-Z-;
- A Cl, Br, I, SO4R9;
- Y hydrogen, Na+, K+, Mg2+, Ca2+, Li+, A+, N(R8)4+;
- Z O, NH;
- R7 and R8
- hydrogen, C1-C6-alkyl, C2-C6-alkenyl, C1-C6-acyl;
- R9 hydrogen, C1-C6-alkyl, C2-C6-alkenyl;
- n 1 to 3;
- o 1 to 150.
- With regard to a more particular specification of the structures of the 4,4-diarylbutadienes of the formula (1) and examples of such compounds (1), the disclosure in DE-A 198 28 463 is expressly incorporated herein by reference. A typical example of a representative of such a compound (IX) is 1,1-bis(neopentyloxycarbonyl)-4,4-diphenyl-1,3-butadiene.
-
- in which the variables independently of one another have the following meanings:
- R1 and R2 are hydrogen, C1-C20-alkyl, C2-C10-alkenyl, C3-C10-cycloalkyl, C3-C10-cycloalkenyl, where the substituents R1 and R2 together with the nitrogen atom to which they are bonded can form a 5- or 6-membered ring;
- R3 and R4 are C1-C20-alkyl, C2-C10-alkenyl, C3-C10-cycloalkyl, C3-C10-cycloalkenyl, C1-C12-alkoxy, C1-C20-alkoxycarbonyl, C1-C1-2-alkylamino, C1-C12-dialkylamino, aryl, heteroaryl, optionally substituted, and
- substituents which confer solubility in water and are selected from the group consisting of a nitrile group, carboxylate, sulfonate or ammonium radicals;
- X is hydrogen, COOR5, CONR6R7;
- R5 to R7 are hydrogen, C1-C20-alkyl, C2-C10-alkenyl, C3-C10-cycloalkyl, C3-C10-cycloalkenyl, —(Y—O)o-Z, aryl;
- Y is —(CH2)2—, —CH2)3—, —(CH2)4—, —CH(CH3)—CH2—;
- Z is —CH2—CH3, —CH2—CH2—CH3, —CH2—CH2—CH2—CH3, —CH(CH3)—CH3;
- m is from 0 to 3;
- n is from 0 to 4;
- o is from 1 to 20.
- With regard to a more particular specification of the structures of the amino-substituted hydroxybenzophenones of the formula II and examples of such compounds II, the disclosure in German patent application 199 17 906.9 is expressly incorporated herein by reference. A typical example of a representative of such a compound (X) is n-hexyl 2-(4′-diethylamino-2′-hydroxybenzoyl) benzoate.
- Typical UV-absorbing triazines (XI) are:
- 2,4,6-trianilino-4-(carbo-2′-ethylhexyl-1′-oxy)-1,3,5-triazine (Uvinul® T-150),
- 2-ethylhexyl 4-{[4-{4-[tert-butylamino)carbonyl]anilino}-6(4-{[2-ethylhexyl)oxy]carbonyl} anilino)-1,3,5-triazin-2-yl]amino}benzoate,
- 2-(4-methoxyphenyl)-4,6-di[4-(2-ethylhexyloxy)-2-hydroxyphenyl]-1,3,5-triazine.
- Representatives of the compounds (B) of the type (I) to (VIII) and (XI) are incidentally described in WO 97/44422 and WO 96/03486.
- As well as compounds of type (I) to (XI), useful organic UV absorbers B further include for example the following:
- 3-(4-methylbenzylidene)boman-2-one (Eusolex® 6300),
- 5-(3,3-dimethyl-2-norbornylidene)-3-penten-2-one,
- 3-benzylideneboman-2-one,
- digalloyl trioleate,
- 2-hydroxy-1,4-naphthalenedione,
- 5-methyl-2-phenylbenzoxazole, dibenzaldehydeamine,
- dianisoylmethane,
- methyleugenol,
- 2-amino-6-hydroxypurine,
- N-(4-ethoxycarbonylphenyl)-N′-methyl-N′-phenylformamidine (Givosorb® UV 1),
- N-(4-ethoxycarbonylphenyl)-N′-ethyl-N′-phenylformamidine (Givosorb® UV2),
- 3-(4′-methylbenzylidene)camphor (Uvinul® MBC95),
- N1-(2-ethoxyphenyl)-N 2(2-ethylphenyl)ethanediamide,
- N1-(2-ethoxyphenyl)-N-(4-dodectphenyl)ethanediamide,
- 2-ethylhexyl 2-cyano-(3-oxo-2,3-dihydro-1H-isoindol-1-ylidene)ethanoate,
- 1,1-dicyano-2-(4-butyloxy)phenyl-2-phenylethene.
- Particularly preferred organic UV absorbers B, which are used together with zinc oxide and/or titanium dioxide, include the compounds:
- 1-(4-tert-butylphenyl)-3-(4-methoxyphenyl)propane-1,3-dione (Uvinul® BMBM),
- polyethoxyethyl 4-bis(polyethoxy)-4-aminobenzoate (Uvinul® P-25),
- 2-ethylhexyl 4-methoxycinnamate (Uvinul® MC80),
- 2-hydroxy-4-methoxybenzophenone (Uvinul® M40),
- 2,4-dihydroxybenzophenone (Uvinul® 3000),
- 2,2′,4,4′-tetrahydroxybenzophenone (Uvinul® D-50),
- 2,2′-dihydroxy-4,4′-dimethoxybenzophenone (Uvinul® D-49),
- 2,2-dihydroxy-4,4-dimethoxybenzophenone (Uvinul® 3049),
- 2-hydroxy-4-(2-ethylhexyloxy)benzophenone,
- 2-hydroxy-4-(n-octyloxy)benzophenone (Uvinul® 3008),
- 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid (Uvinul®) MS 40) and salts thereof,
- 2,2′-dihydroxy-4,4′-dimethoxybenzophenone-5,5′-bissulfonic acid and salts thereof (Uvinul® DS49),
- 2′-ethylhexyl 2-cyano-3,3-diphenylacrylate (Uvinul® N 539 T),
- ethyl 2-cyano-3,3-diphenylacrylate (Uvinul® 3035),
- 1,1-bis(neopentyloxycarbonyl)-4,4-diphenyl-1,3-butadiene,
- n-hexyl 2-(4′-diethylamino-2′-hydroxybenzoyl)benzoate,
- 2,4,6-trianilino-4-(carbo-2′-ethylhexyl-1′-oxy)-1,3,5-triazine (Uvinul® T-150),
- 3-(4′-methylbenzylidene)camphor (Uvinul®) MBC95).
- It may occasionally be of advantage for components A and B to be used together with antioxidants and/or free-radical traps. Antioxidants and free-radical traps which may be used here include all compounds customarily used for stabilizing food and feed but also for stabilizing plastics or lubricants. A list of such compounds may be found for example in Kirk-Othmer, Encyclopedia of Chemical Technology, fourth edition, volume 3, p. 424-447 or in Ullmann's Encyclopedia of Industrial Chemistry, sixth edition, 2000 Electronic Release, chapters antioxidants and food additives.
- However, they include in particular:
- substituted phenols, hydroquinones, pyrocatechols and gallates such as 2,6-di-tert-butylphenol, 2,4,6-tri-tert-butylphenol, 2,4-dimethyl-6-tert-butylphenol, 2,6-di-tert-butyl-4-methylphenol, 2,6-di-tert-butyl-4-methoxyphenol, 3-tert-butyl-4-methoxyphenol, 2,2′-methylenebis(4-methyl-6-tert-butylphenol), propyl, octyl and dodecyl gallate or tert-butylhydroquinone (TBHQ), butylated hydroxyanisoles (BHA) and butylated hydroxytoluene (BHT),
- Irganox® antioxidants (from Ciba-Geigy) such as Irganox® 1010 (tetrakis(methylene 3,5-di-tert-butyl-4-hydroxycinnamate)-methane), Irganox® 1035 (thiodiethylene bis(3,5-di-tert-butyl-4-hydroxycinnamate)) and Irganox® 1076 (octadecyl propane(3-benzene-3′,5′-di-tert-butyl-4′-hydroxybenzyl)phosphonate),
- trihydroxybutyrophenone (THBP),
- α-tocopherol and its natural or synthetic derivatives such as acetyl-α-tocopherol,
- ascorbic acid and ascorbic acid derivatives, especially esterification products with long-chain fatty acids such as ascorbyl palmitate,
- diazabicyclooctane (DABCO),
- chroman derivatives such as long-chain esters of 2,5,7,8-tetramethyl-6-hydroxychroman-2 acid,
- aromatic amines such as ethoxyquin,
- organic sulfides such as 3,3′-thiodipropionic acid and dilauryl thiodipropionate,
- sterically hindered amines, for example of the tetramethylpiperidine type such as Uvinul®4049H, Uvinul® 4050H and Uvinul® 5050H from BASF AG,
- free radicals of the N-oxyl type such as 4-hydroxytetramethylpiperidine N-oxide, esterification products thereof with carboxylic acids and further derivatives,
- hydroxylamines such as those of dialkylamines and hydroxylamine ether derivatives of tetramethylpiperidine compounds,
- ascorbic, lactic, citric and tartaric acids and salts thereof.
- The inorganic pigments A and organic UV absorbers B cooperate very well as UV absorbers possessing textile fiber affinity and mutually reinforce their effect. First, they protect, when applied to a textile material, the human skin against harmful UV radiation. Secondly, they protect dyed textile material against fading. The two protective effects preferably occur simultaneously.
- Textile materials with which the components A and B have affinity and where they develop their protective effect include in particular apparel articles, i.e., articles which are worn on the human skin, but also house and garden articles comprising dyed textiles such as awnings and sunshades which are exposed to intensive solar irradiation. This textile material to be protected preferably comprises cellulose (cotton), for example apparel textiles comprising cotton or cotton-polyester blends.
- The present invention also provides for the use of zinc oxide and/or titanium dioxide together with organic UV absorbers on textile material to protect human skin against harmful UV radiation and/or to protect dyed textile material against fading.
- The mixture containing the components A and B is customarily applied to the textile material in the form of an aqueous liquor containing the components A and B alongside further ingredients, for example by spraying or dipping and squeezing off. The components A and B can be applied to the textile material in the course of textile finishing during the manufacture of the textile material, in the course of laundering, in the course of laundry pretreatment and/or laundry aftertreatment.
- The UV protection factor UPF of the textile material is increased as a result.
- The UV protection factor or Ultraviolet Radiation Protection Factor UPF of textiles is determined in accordance with the Australian/New Zealand standard AS/NZS 4399:1996 using an in vitro method. It measures the UV transmission of the textile object. The spectral transmission can be used to determine the protection factor directly using the following equation:
- where:
- Sλ is the spectral irradiation of the sun in the UV region at the wavelength λ,
- Eλ is the spectral erythema action of the UV radiation at the wavelength λ, and
- Tλ is the spectral transmissivity of the textile object at the wavelength λ.
- The present invention also provides a laundry detergent formulation comprising from 0.01% to 20% by weight, preferably from 0.1% to 10% by weight, particularly preferably from 0.1 to 5% by weight of the components A and B alongside further customary ingredients. The weight ratio of component A to component B is preferably in the range from 20:1 to 1:10, particularly preferably in the range from 8:1 to 1:5 and specifically preferably in the range from 3:1 to 1:1. In this connection, the components A and B can be added separately to the formulation or a ready-prepared mixture of A and B can be incorporated into the formulation.
- Laundry detergent formulations according to the invention can be solid or liquid formulations.
- Solid laundry detergent formulations according to the invention generally include as further customary ingredients
- (c) from 0.1 to 40% by weight of at least one nonionic and/or anionic surfactant as component C,
- (d) from 0 to 50% by weight of one or more inorganic builders as component D,
- (e) from 0 to 20% by weight of one or more organic cobuilders E,
- (f) from 0 to 60% by weight of other customary ingredients such as cationic surfactants, standardizing agents, enzymes, perfume, complexing agents, corrosion inhibitors, bleaching agents, bleach activators, bleach catalysts, dye transfer inhibitors, soil antiredeposition agents, soil release polyesters, colorants, dissolution improvers and/or disintegrants as component F,
- components A to F adding up to 100% by weight.
- The solid laundry detergent formulations of the invention are customarily present in powder, granule, extrudate or tablet form.
- Liquid laundry detergent formulations according to the invention generally include as further customary constituents
- (c) from 0.1 to 40% by weight of at least one nonionic and/or anionic surfactant as component C,
- (d) from 0 to 20% by weight of one or more inorganic builders as component D,
- (e) from 0 to 10% by weight of one or more organic cobuilders as component E,
- (f) from 0 to 40% by weight of other customary ingredients such as cationic surfactants, sodium carbonate, enzymes, perfume, complexing agents, corrosion inhibitors, bleaching agents, bleach activators, bleach catalysts, dye transfer inhibitors, soil antiredeposition agents, soil release polyesters, colorants, nonaqueous solvents, hydrotropes, thickeners and/or alkanolamines as component F, and
- (g) from 0 to 99.85% by weight of water as component G,
- components A to G adding up to 100% by weight.
- Useful anionic surfactants are in particular:
- fatty alcohol sulfates of fatty alcohols having from 8 to 22 and preferably from 10 to 18 carbon atoms, for example C9- to C11-alcohol sulfates, C12- to C14-alcohol sulfates, C12- to C18-alcohol sulfates, lauryl sulfate, cetyl sulfate, myristyl sulfate, palmityl sulfate, stearyl sulfate and tallow fatty alcohol sulfate;
- sulfated alkoxylated C8- to C22-alcohols (alkyl ether sulfates). Compounds of this kind are prepared for example by first alkoxylating a C8- to C22-alcohol, preferably a C10- to C18-alcohol, for example a fatty alcohol, and then sulfating the alkoxylation product. The alkoxylation is preferably carried out using ethylene oxide;
- linear C8- to C20-alkylbenzenesulfonates (LAS), preferably linear C9- to C13-alkylbenzenesulfonates and -alkyltoluenesulfonates,
- alkanesulfonates such as C8- to C24- and preferably C10- to C18-alkanesulfonates,
- soaps such as for example the sodium and potassium salts of C8- to C24-carboxylic acids.
- The anionic surfactants mentioned are preferably included in the laundry detergent in the form of salts. Suitable cations in these salts are alkali metal ions such as sodium, potassium and lithium and ammonium ions such as hydroxyethylammonium, di(hydroxyethyl)ammonium and tri(hydroxyethyl)ammonium.
- Useful nonionic surfactants are in particular:
- alkoxylated C8- to C22-alcohols such as fatty alcohol alkoxylates or oxo alcohol alkoxylates. These may have been alkoxylated with ethylene oxide, propylene oxide and/or butylene oxide. Useful surfactants here include all alkoxylated alcohols which contain at least two molecules of one of the aforementioned alkylene oxides. Here it is possible to use block polymers of ethylene oxide, propylene oxide and/or butylene oxide or addition products which contain the aforementioned alkylene oxides in random distribution. Nonionic surfactants generally contain from 2 to 50 and preferably from 3 to 20 mol of at least one alkylene oxide per mole of alcohol. The alkylene oxide component is preferably ethylene oxide. The alcohols preferably have from 10 to 18 carbon atoms. Depending on the nature of the alkoxylation catalyst used to make them, alkoxylates have a broad or narrow alkylene oxide homologue distribution;
- alkylphenol alkoxylates such as alkylphenol ethoxylates having C6- to C14-alkyl chains and from 5 to 30 alkylene oxide units;
- alkylpolyglucosides having from 8 to 22 and preferably from 10 to 18 carbon atoms in the alkyl chain and generally from 1 to 20 and preferably from 1.1 to 5 glucoside units;
- N-alkylglucamides, fatty acid amide alkoxylates, fatty acid alkanolamide alkoxylates and also block copolymers of ethylene oxide, propylene oxide and/or butylene oxide.
- Useful inorganic builders are in particular:
- crystalline or amorphous aluminosilicates having ion-exchanging properties such as zeolites in particular. Useful zeolites include in particular zeolites A, X, B, P, MAP and HS in their sodium form or in forms in which sodium has been partly replaced by other cations such as lithium, potassium, calcium, magnesium or ammonium;
- crystalline silicates such as in particular disilicates or sheet-silicates, for example δ-Na2Si2O5 or β-Na2Si2O5 The silicates can be used in the form of their alkali metal, alkaline earth metal or ammonium salts, preferably as sodium, lithium and magnesium silicates;
- amorphous silicates such as sodium metasilicate or amorphous disilicate;
- carbonates and bicarbonates. These can be used in the form of their alkali metal, alkaline earth metal or ammonium salts. Preference is given to sodium, lithium and magnesium carbonates or bicarbonates, especially sodium carbonate and/or sodium bicarbonate;
- polyphosphates such as pentasodium triphosphate.
- Useful organic cobuilders include in particular low molecular weight, oligomeric or polymeric carboxylic acids.
- Useful low molecular weight carboxylic acids include for example citric acid, hydrophobically modified citric acid such as for example agaric acid, malic acid, tartaric acid, gluconic acid, glutaric acid, succinic acid, imidodisuccinic acid, oxydisuccinic acid, propanetricarboxylic acid, butanetetracarboxylic acid, cyclopentanetetracarboxylic acid, alkyl- and alkenylsuccinic acids and aminopolycarboxylic acids such as for example nitrilotriacetic acid, β-alaninediacetic acid, ethylenediaminetetraacetic acid, serinediacetic acid, isoserinediacetic acid, N-(2-hydroxyethyl)iminodiacetic acid, ethylenediaminedisuccinic acid and methyl- and ethylglycinediacetic acid;
- useful oligomeric or polymeric carboxylic acids include for example homopolymers of acrylic acid, oligomaleic acids, copolymers of maleic acid with acrylic acid, methacrylic acid, C2-C22-olefins such as for example isobutene or long-chain α-olefins, vinyl alkyl ethers having C1-C8-alkyl groups, vinyl acetate, vinyl propionate, methacrylic esters of C1-C8-alcohols and styrene. Preference is given to using the homopolymers of acrylic acid and also copolymers of acrylic acid with maleic acid. Polyaspartic acids are also useful as organic cobuilders. Oligomeric and polymeric carboxylic acids are used in acid form or as sodium salt.
- Useful bleaching agents include for example adducts of hydrogen peroxide with inorganic salts such as for example sodium perborate monohydrate, sodium perborate tetrahydrate or sodium carbonate perhydrate or percarboxylic acids such as phthalimidopercaproic acid.
- Suitable bleaching activators are e.g. N,N,N′,N′-tetraacetyl ethylendiamine (TAED), sodium p-nonanoyloxybenzenesulfonate or N-methylmorpholiniumacetonitrilmethylsulfate.
- Enzymes preferably used in laundry detergents are proteases, lipases, amylases, cellulases, oxidases or peroxidases.
- Suitable dye transfer inhibitors are e.g. homopolymers and copolymers of 1-vinylpyrrolidone, 1-vinylimidazole or 4-vinylpyridine-N-oxide. Homopolymers and copolymers of 4-vinylpyridine reacted with chloroacetic acid are also suitable dye transfer inhibitors.
- The present invention further provides laundry aftertreatment and laundry conditioning compositions comprising from 0.01% to 20% by weight, preferably from 0.1 to 10% by weight and particularly preferably from 0.1% to 5% by weight of components A and B as well as other customary constituents. The weight ratio of component A to component B is preferably in the range from 20:1 to 1:10, more preferably in the range from 8:1 to 1:5 and especially in the range from 3:1 to 1:1. In this connection, the components A and B can be added separately to the formulation or a ready-prepared mixture of A and B can be incorporated into the formulation.
- The laundry aftertreatment and laundry conditioning compositions of the invention generally include as further customary constituents c) from 0.1 to 40% by weight of at least one cationic surfactant as component C,
- d) from 0 to 30% by weight of one or more nonionic surfactants as component D,
- e) from 0 to 30% by weight of further customary ingredients such as scents, colorants, stabilizers, fiber and color protection additives, viscosity modifiers, soil release additives, soil antiredeposition agents, dye transfer inhibitors, complexing agents, corrosion control additives, bactericides, preservatives, nonaqueous solvents, hydrotropes and/or alkanolamines as component E,
- f) from 0 to 25% by weight of cationic polymers as binders as component F, and
- g) water to 100% by weight as component G.
- Useful cationic polymers (component F) include all natural or synthetic cationic polymers containing amino and/or ammonium groups and being soluble or dispersible in water. Examples of such cationic polymers are polyethyleneimines, amidated, alkoxylated and/or alkylated polyethyleneimines, crosslinked polyethyleneimines, polyamidoamines, alkoxylated and/or alkylated polyamidoamines, crosslinked polyamidoamines, ethyleneimine-grafted crosslinked polyamidoamines, amine-epichlorohydrin polycondensates, polyvinylamines, alkoxylated polyvinylamines, partially hydrolyzed polyvinylformamides, polyallylamines, polydimethyldiallylammonium chlorides, polymers containing 1-vinylimidazole units such as poly-1-vinylimidazole or poly-(1-vinylimidazole-co-1-vinylpyrrolidone), polymers containing quaternary vinylimidazole units, condensates of imidazole and epichlorohydrin, polymers containing basic methacrylamide or methacrylic ester units, polymers containing basic quaternary methacrylamide or methacrylic ester units and/or lysine condensates.
- The term “cationic polymers” also comprehends amphoteric addition polymers which have a net cationic charge, i.e., the polymers contain both anionic and cationic monomers in copolymerized form, but the molar fraction of the cationic units present in the polymers is greater than that of the anionic units.
- Preferred cationic surfactants (component C) are selected from the group consisting of the quaternary diesterammonium salts, the quaternary tetraalkylammonium salts, the quaternary diamidoammonium salts, the amidoamine esters and imidazolium salts. These are preferably present in the fabric conditioners in an amount of from 3 to 30% by weight. Examples are quaternary diesterammonium salts having two C11- to C22-alk(en)ylcarbonyloxy(mono- to pentamethylene) radicals and two C1- to C3-alkyl- or hydroxyalkyl radicals on the quaternary nitrogen atom and, for example, chloride, bromide, methosulfate or sulfate as counterion.
- Quaternary diesterammonium salts are further in particular those which have a C11- to C2-2-alk(en)ylcarbonyloxytrimethyleneradical bearing a C11- to C22-alk(en)ylcarbonyloxy radical on the central carbon atom of the trimethylene group and three C1- to C3-alkyl- or hydroxyalkyl radicals on the quaternary nitrogen atom and, for example, chloride, bromide, methosulfate or sulfate as counterion.
- Quaternary tetraalkylammonium salts are in particular those which have two C1- to C6-alkylradicals and two C8- to C24-alk(en)yl radicals on the quaternary nitrogen atom and, for example, chloride, bromide, methosulfate or sulfate as counterion.
- Quaternary diamidoammonium salts are in particular those which have two C8- to C24-alk(en)ylcarbonylaminoethyleneradicals, a substituent selected from hydrogen, methyl, ethyl and polyoxyethylene having up to 5 oxyethylene units and as fourth radical a methyl group on the quaternary nitrogen atom and, for example, chloride, bromide, methosulfate or sulfate as counterion.
- Amidoamino esters are in particular tertiary amines bearing a C11- to C22-alk(en)ylcarbonylamino(mono- to trimethylene) radical, a C11- to C22-alk(en)ylcarbonyloxy(mono- to trimethylene) radical and a methyl group as substituents on the nitrogen atom.
- Imidazolinium salts are in particular those which bear a C14- to C18-alk(en)yl radical in position 2 of the heterocycle, a C14- to C18-alk(en)ylcarbonyl(oxy or amino)ethylene radical on the neutral nitrogen atom and hydrogen, methyl or ethyl on the nitrogen atom carrying the positive charge, while counterions here are for example chloride, bromide, methosulfate or sulfate.
- The present invention also provides for the use of zinc oxide and/or titanium dioxide together with organic UV absorbers in laundry detergent, laundry aftertreatment and laundry conditioning compositions.
- The present invention also provides a finishing composition for UV protection of textile materials comprising the components A and B.
- The finishing compositions according to the invention are present for example as finishes in the narrower sense in the course of the manufacture of the textiles or in the form of an aqueous wash liquor or as a liquid textile treatment composition. It is accordingly possible for example to treat the textiles with the finishing composition in connection with the manufacture of the textiles. Textiles never treated or only inadequately treated with a finish may be treated for example in the home before or after washing with a textile treatment composition containing the inorganic pigments A and the organic UV absorbers B. But it is also possible to treat the textiles with the components (A) and (B) in the main wash cycle or after the main wash cycle in the conditioning rinse cycle of the washing machine, partly using the above-described formulations.
- The examples hereinbelow illustrate the present invention.
- White woven cotton fabric having a basis weight of 100 g/m2 and a UV protection factor (UPF) of 4.1 was washed at a water hardness of 3 mmol/l. The laundering process was a main wash cycle at 40° C. with a commercially available laundry detergent (Ariel® Color) and a subsequent conditioning rinse. The conditioner used was a commercially available formulation (Downy from Lenor®) in a dosage of 1000 ppm, based on the liquor. The fabric conditioner formulation included either no UV absorber or in each case 100 or 200 ppm, based on the liquor, of an inventive UV absorber combination, added before the conditioning rinse. The liquor ratio was 12.5:1. After the conditioning rinse cycle, the fabric was removed and its UV protection factor was determined in the dried state. Subsequently the fabric was tested for photostability. The fabric sample was exposed in a SUNTEST® CPS tabletop accelerated lighting unit from Heraeus, Hanau, for 4 and 24 hours under outdoor conditions using a WG 295 filter at the maximum radiative power output of the instrument. The UV protection factor was redetermined after 4 and 24 hours of exposure.
- The inorganic pigments used were as follows:
- Z-COTE®, an amphiphilic zinc oxide from BASF AG
- Uvinul® TiO2 from BASF AG
- The organic UV absorbers were used as follows:
- A=2-ethylhexyl 2-cyano-3,3-diphenylacrylate (Uvinul® N-539 T)
- B=2-hydroxy-4-(n-octyloxy)benzophenone (Uvinul® 3008)
- The results are summarized in table 1.
TABLE 1 UPF UPF after 4 h after 24 h UPF Δ exposure Δ exposure Δ no additive 4.3 4.2 4.2 50 ppm of ZnO 4.7 0.4 4.5 0.3 4.6 0.4 100 ppm of ZnO 5.5 1.2 5.5 1.3 5.4 1.2 50 ppm of A 8.5 4.2 7.2 3.0 5.5 1.2 100 ppm of A 13.4 9.1 11.4 7.2 8.5 4.3 50 ppm of A + 50 12.3 8.0 11.8 7.6 10.3 6.1 ppm of ZnO 100 ppm of A + 100 19.2 14.9 18.4 14.2 16.5 12.3 ppm of ZnO 100 ppm of TiO2 5.0 0.7 4.9 0.7 4.8 0.6 100 ppm of A + 100 17.6 13.3 17.5 13.3 14.5 10.3 ppm of TiO2 100 ppm of B 10.1 5.8 9.0 4.8 7.4 3.2 100 ppm of B + 100 14.8 10.5 14.5 10.3 12.4 8.2 ppm of TiO2 - The results clearly show the synergistic effect on the combined use of UV absorbers A and B with zinc oxide and titanium dioxide respectively. It is similarly clear that the pigment oxides have a positive effect on the photostability of the organic UV absorbers A and B.
- Zinc oxide and titanium dioxide increase the UV protection factor of the cotton fabric only insignificantly when used alone in either case.
- A woven cotton fabric dyed with Reactive Black 5 to ⅓ standard depth was treated in the conditioning rinse cycle with a commercially available formulation (Downy from Lenor®, 1000 ppm, based on the liquor) in the presence of an inventive UV absorber combination (in each case 200 ppm, based on the liquor) in a liquor ratio of 12.5:1. After the conditioning rinse cycle, the dyed fabrics were removed and tested for photostability in the dried state.
- Photostability was measured as follows:
- The samples were exposed in a SUNTEST® tabletop accelerated lighting unit from Heraeus, Hanau for 8 or 24 hours under outdoor conditions using a WG 295 filter at the maximum radiative power output of the instrument. A spectrophotometer with an integration sphere Lambda 900 from Perkin Elmer was used to measure the reflectance spectra of the dyes before and after exposure. These reflectance spectra were converted in line with the Kubelka-Munk theory into K/S spectra (K=absorption coefficient, S=scattering coefficient). The photostabilities were evaluated with reference to the K/S values after 8 or 24 hour exposure relative to the K/S values prior to exposure (K/S in each case at the maximum of the K/S spectra). The higher the value in % reported in table 2, the higher the photostability.
- The inorganic pigment used was Z-COTE® from BASF AG.
- The organic UV absorbers used were as follows:
- C=n-hexyl 2-(4′-diethylamino-2′-hydroxybenzoyl)benzoate
- D=1-(4-tert-butylphenyl)-3-(4-methoxyphenyl)propane-1,3-dione (Uvinul® BMBM)
TABLE 2 K/S (24 h)/K/S (0 h) × K/S (8 h)/K/S (0 h) × 100% 100% no additive 77.2% 57.7% 400 ppm of ZnO 82.0% 63.7% 400 ppm of C 81.3% 62.0% 200 ppm of C + 85.5% 68.8% 200 ppm of ZnO 400 ppm of D 80.8% 61.0% 200 ppm of D + 84.9% 67.0% 200 ppm of ZnO - The results clearly show the synergistic effect on the combined use of C or D with zinc oxide.
Claims (12)
1. A method for UV protecting a textile material, which comprises applying
(a) zinc oxide and/or titanium oxide as a component A and
(b) one or more organic UV absorbers as a component B to said textile material.
2. A method as claimed in claim 1 , wherein said component A comprises UV absorbers having an absorption maximum in the range from 280 to 450 nm.
3. A method as claimed in claim 1 or 2, wherein said component B comprises one or more compounds selected from the group consisting of
phenylbenzotriazoles,
dibenzoylmethanes,
esters of p-aminobenzoic acid,
esters of cinnamic acid,
esters of salicylic acid,
nonnitrogenous 2-hydroxybenzophenones,
phenylbenzimidazoles,
acrylates,
diarylbutadienes,
amino-substituted hydroxybenzophenones,
triazines.
4. A method as claimed in any of claims 1 to 3 , wherein the weight ratio of said component A to said component B is in the range from 20:1 to 1:10.
5. A method as claimed in any of claims 1 to 4 , wherein said components A and B are applied to said textile material in the form of an aqueous liquor containing said components A and B alongside further ingredients.
6. A method as claimed in any of claims 1 to 5 , wherein said components A and B are applied to said textile material in the course of textile finishing during the manufacture of said textile material, in the course of laundering and/or in the course of laundry aftertreatment.
7. A laundry detergent formulation comprising from 0.01 to 20% by weight, based on their total, of said components A and B as defined in any of claims 1 to 4 as well as further customary constituents.
8. A laundry aftertreatment and laundry conditioning formulation comprising from 0.01 to 20% by weight, based on their total, of said components A and B as defined in any of claims 1 to 4 as well as further customary constituents.
9. A laundry aftertreatment and laundry conditioning formulation as claimed in claim 8 , comprising from 1 to 50% by weight of one or more cationic surfactants selected from the group consisting of quaternary diesterammonium salts, quaternary tetraalkylammonium salts, quaternary diamidoammonium salts, amidoamino esters and imidazolines.
10. A finishing composition for UV protecting a textile material, comprising a mixture of said components A and B as defined in any of claims 1 to 4 .
11. Textile material comprising a mixture of said components A and B as defined in any of claims 1 to 4 .
12. The use of zinc oxide and/or titanium dioxide together with organic UV absorbers on textile material to protect the human skin against harmful UV radiation and/or to protect dyed textile material against fading.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10105143A DE10105143A1 (en) | 2001-02-06 | 2001-02-06 | Process for UV protective equipment of textile material |
DE10105143.3 | 2001-02-06 | ||
PCT/EP2002/001179 WO2002063091A2 (en) | 2001-02-06 | 2002-02-05 | Method for providing textile material with uv protection |
Publications (1)
Publication Number | Publication Date |
---|---|
US20040074012A1 true US20040074012A1 (en) | 2004-04-22 |
Family
ID=7672904
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/470,265 Abandoned US20040074012A1 (en) | 2001-02-06 | 2002-02-05 | Method for providing textile material with uv protection |
Country Status (8)
Country | Link |
---|---|
US (1) | US20040074012A1 (en) |
EP (1) | EP1383952A2 (en) |
JP (1) | JP2004528486A (en) |
BR (1) | BR0206936A (en) |
CA (1) | CA2437613A1 (en) |
DE (1) | DE10105143A1 (en) |
MX (1) | MXPA03006782A (en) |
WO (1) | WO2002063091A2 (en) |
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20050005367A1 (en) * | 2003-05-27 | 2005-01-13 | The Hong Kong University Of Science And Technology | Methods of fabric treatment |
US20080119383A1 (en) * | 2006-11-17 | 2008-05-22 | Christopher Boardman | Fabric treatment method and composition to impart differential Hydrophobicity |
US20080233298A1 (en) * | 2003-05-27 | 2008-09-25 | The Hong Kong University Of Science And Technology | Methods of fabric treatment |
CN102330343A (en) * | 2011-07-27 | 2012-01-25 | 吴江市瑞丰织造有限公司 | Ultraviolet shielding coatings for fabrics |
US8277518B1 (en) | 2011-10-11 | 2012-10-02 | The Sweet Living Group, LLC | Ecological fabric having ultraviolet radiation protection |
CN102817236A (en) * | 2012-08-28 | 2012-12-12 | 北京中纺化工股份有限公司 | Efficient light fastness enhancing agent as well as preparation method and application of enhancing agent |
CN102851766A (en) * | 2012-08-29 | 2013-01-02 | 昆山铁牛衬衫厂 | Anti-ultraviolet fiber production method |
CN102851942A (en) * | 2012-08-29 | 2013-01-02 | 昆山铁牛衬衫厂 | Anti-ultraviolet pure cotton fabric finishing method |
CN103469559A (en) * | 2013-08-21 | 2013-12-25 | 昆山铁牛衬衫厂 | UV-resistant composite finishing agent and preparation method thereof |
US8690964B2 (en) | 2011-10-11 | 2014-04-08 | The Sweet Living Group, LLC | Fabric having ultraviolet radiation protection |
US20150223411A1 (en) * | 2012-09-12 | 2015-08-13 | Extenday Ip Limited | Netting, crop cover, and ground cover materials |
US9234310B2 (en) | 2011-10-11 | 2016-01-12 | The Sweet Living Group, LLC | Fabric having ultraviolet radiation protection, enhanced resistance to degradation, and enhanced resistance to fire |
US9464260B2 (en) | 2011-10-11 | 2016-10-11 | The Sweet Living Group, LLC | Laundry detergent composition for providing ultraviolet radiation protection for a fabric |
CN107057125A (en) * | 2017-05-18 | 2017-08-18 | 句容亿格纳米材料厂 | Modified salicylic acid aligns the preparation and its application in anti-light pollution plastics of octyl phenyl ester |
US20180230314A1 (en) * | 2011-10-11 | 2018-08-16 | The Sweet Living Group, LLC | Fabric having ultraviolet radiation protection |
CN110592963A (en) * | 2019-10-09 | 2019-12-20 | 陈晓彤 | Production process of anti-aging and anti-ultraviolet fabric |
US10676861B1 (en) | 2019-11-08 | 2020-06-09 | The Sweet Living Group, LLC | Method for incorporating ultraviolet radiation protection and antimicrobial protection into rayon |
US10907048B2 (en) | 2018-04-12 | 2021-02-02 | The Sweet Living Group, LLC | Product having ultraviolet radiation protection |
US20210269648A1 (en) * | 2011-10-11 | 2021-09-02 | The Sweet Living Group, LLC | Product having ultraviolet radiation protection |
WO2023215483A1 (en) * | 2022-05-04 | 2023-11-09 | Claros Technologies Inc. | Pre- ultraviolet radiation protective additives for textiles and methods of use |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10161861A1 (en) * | 2001-12-14 | 2003-07-03 | Basf Ag | Stabilizer composition I |
ATE498729T1 (en) * | 2002-08-02 | 2011-03-15 | Massimo Guarducci S R L | MATERIAL PROTECTED AGAINST UV RADIATION AND ITS PRODUCTION |
JP2007538082A (en) * | 2004-05-18 | 2007-12-27 | コックレル ダーマトロジー デベロップメント,リミテッド | Solid synthetic soap that protects against ultraviolet rays |
DE102007019374A1 (en) * | 2007-04-23 | 2008-11-06 | Henkel Ag & Co. Kgaa | Photocatalytic material-containing liquid systems |
BRPI0812279A2 (en) * | 2007-05-29 | 2014-11-18 | Henkel Corp | ADHESIVE DETECTION METHODS. |
DE102007042862A1 (en) * | 2007-09-10 | 2009-03-12 | Henkel Ag & Co. Kgaa | Modified titanium dioxide |
US20090092561A1 (en) * | 2007-10-09 | 2009-04-09 | Lupia Joseph A | Body-care and household products and compositions comprising specific sulfur-containing compounds |
CN102712876B (en) * | 2009-10-07 | 2014-03-12 | 荷兰联合利华有限公司 | Fabric conditioners |
US20150275418A1 (en) * | 2012-10-26 | 2015-10-01 | As Corporation | Cool-feeling fiber fabric and method for producing same |
CN103726297B (en) * | 2013-11-26 | 2016-10-05 | 常熟常圣服饰有限公司 | The production technology of uvioresistant fabrics |
JP6485800B2 (en) * | 2014-01-07 | 2019-03-20 | 株式会社Adeka | Functionality imparting agent for fibers |
Citations (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3957098A (en) * | 1972-06-26 | 1976-05-18 | George Hepworth | Erosion control bag |
US4390585A (en) * | 1982-05-05 | 1983-06-28 | Bond Cote Of Virginia, Inc. | Durable flexible membrane and method of making same |
US4648983A (en) * | 1985-08-20 | 1987-03-10 | Colgate-Palmolive Company | Built non aqueous liquid nonionic laundry detergent composition containing urea stabilizer and method of use |
US4715969A (en) * | 1984-12-24 | 1987-12-29 | Colgate Palmolive Co. | Controlling viscosity of fabric softening heavy duty liquid detergent containing bentonite |
US4786431A (en) * | 1984-12-31 | 1988-11-22 | Colgate-Palmolive Company | Liquid laundry detergent-bleach composition and method of use |
US4800038A (en) * | 1988-01-21 | 1989-01-24 | Colgate-Palmolive Company | Acetylated sugar ethers as bleach activators detergency boosters and fabric softeners |
US5441726A (en) * | 1993-04-28 | 1995-08-15 | Sunsmart, Inc. | Topical ultra-violet radiation protectants |
US5777091A (en) * | 1994-11-24 | 1998-07-07 | Ciba Specialty Chemicals Corporation | Phosphonomethylated chitosans |
US5798331A (en) * | 1994-12-02 | 1998-08-25 | Imperial Chemical Industries Plc | Succinic acid derivatives and their use as surfactants |
US5853430A (en) * | 1997-09-03 | 1998-12-29 | The Procter & Gamble Company | Method for predissolving detergent compositions |
US5929148A (en) * | 1994-05-26 | 1999-07-27 | Asahi Kasei Kogyo Kabushiki Kaisha | Polyhexamethylene adipamide fibers and process for producing the same |
US5968485A (en) * | 1998-10-16 | 1999-10-19 | The Procter & Gamble Company | UV protection compositions |
US6043204A (en) * | 1997-11-07 | 2000-03-28 | Kaufman; Stacy R. | Body cleansing composition providing protection against sunburn after rinsing |
US6071501A (en) * | 1999-02-05 | 2000-06-06 | The Procter & Gamble Company | Photostable UV protection compositions |
US6103642A (en) * | 1997-08-29 | 2000-08-15 | Kanbo Pras Corporation | Stain resistant sheet material |
US6494920B1 (en) * | 1999-02-04 | 2002-12-17 | Cognis Deutschland Gmbh & Co. Kg | Detergent mixtures |
US6528070B1 (en) * | 2000-09-15 | 2003-03-04 | Stepan Company | Emulsion comprising a ternary surfactant blend of cationic, anionic, and bridging surfactants, oil and water, and methods of preparing same |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04289268A (en) * | 1991-03-13 | 1992-10-14 | Kanebo Ltd | Fabric processed to prevent ultraviolettransmission and its production |
US5134223A (en) * | 1991-07-17 | 1992-07-28 | Lever Brothers Company, Division Of Conopco, Inc. | Water dispersible or water soluble copolymer containing UV-absorbing monomer |
US5250652A (en) * | 1992-07-30 | 1993-10-05 | Lever Brothers Company, Division Of Conopco, Inc. | High loading water-dispersible UVA and/or UVB light-absorbing copolymer |
-
2001
- 2001-02-06 DE DE10105143A patent/DE10105143A1/en not_active Withdrawn
-
2002
- 2002-02-05 CA CA002437613A patent/CA2437613A1/en not_active Abandoned
- 2002-02-05 EP EP02704685A patent/EP1383952A2/en not_active Withdrawn
- 2002-02-05 MX MXPA03006782A patent/MXPA03006782A/en unknown
- 2002-02-05 JP JP2002562817A patent/JP2004528486A/en not_active Withdrawn
- 2002-02-05 WO PCT/EP2002/001179 patent/WO2002063091A2/en not_active Application Discontinuation
- 2002-02-05 BR BR0206936-9A patent/BR0206936A/en not_active Application Discontinuation
- 2002-02-05 US US10/470,265 patent/US20040074012A1/en not_active Abandoned
Patent Citations (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3957098A (en) * | 1972-06-26 | 1976-05-18 | George Hepworth | Erosion control bag |
US4390585A (en) * | 1982-05-05 | 1983-06-28 | Bond Cote Of Virginia, Inc. | Durable flexible membrane and method of making same |
US4715969A (en) * | 1984-12-24 | 1987-12-29 | Colgate Palmolive Co. | Controlling viscosity of fabric softening heavy duty liquid detergent containing bentonite |
US4786431A (en) * | 1984-12-31 | 1988-11-22 | Colgate-Palmolive Company | Liquid laundry detergent-bleach composition and method of use |
US4648983A (en) * | 1985-08-20 | 1987-03-10 | Colgate-Palmolive Company | Built non aqueous liquid nonionic laundry detergent composition containing urea stabilizer and method of use |
US4800038A (en) * | 1988-01-21 | 1989-01-24 | Colgate-Palmolive Company | Acetylated sugar ethers as bleach activators detergency boosters and fabric softeners |
US5441726A (en) * | 1993-04-28 | 1995-08-15 | Sunsmart, Inc. | Topical ultra-violet radiation protectants |
US5929148A (en) * | 1994-05-26 | 1999-07-27 | Asahi Kasei Kogyo Kabushiki Kaisha | Polyhexamethylene adipamide fibers and process for producing the same |
US5777091A (en) * | 1994-11-24 | 1998-07-07 | Ciba Specialty Chemicals Corporation | Phosphonomethylated chitosans |
US5798331A (en) * | 1994-12-02 | 1998-08-25 | Imperial Chemical Industries Plc | Succinic acid derivatives and their use as surfactants |
US6103642A (en) * | 1997-08-29 | 2000-08-15 | Kanbo Pras Corporation | Stain resistant sheet material |
US5853430A (en) * | 1997-09-03 | 1998-12-29 | The Procter & Gamble Company | Method for predissolving detergent compositions |
US6043204A (en) * | 1997-11-07 | 2000-03-28 | Kaufman; Stacy R. | Body cleansing composition providing protection against sunburn after rinsing |
US5968485A (en) * | 1998-10-16 | 1999-10-19 | The Procter & Gamble Company | UV protection compositions |
US6494920B1 (en) * | 1999-02-04 | 2002-12-17 | Cognis Deutschland Gmbh & Co. Kg | Detergent mixtures |
US6071501A (en) * | 1999-02-05 | 2000-06-06 | The Procter & Gamble Company | Photostable UV protection compositions |
US6528070B1 (en) * | 2000-09-15 | 2003-03-04 | Stepan Company | Emulsion comprising a ternary surfactant blend of cationic, anionic, and bridging surfactants, oil and water, and methods of preparing same |
Cited By (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20050005367A1 (en) * | 2003-05-27 | 2005-01-13 | The Hong Kong University Of Science And Technology | Methods of fabric treatment |
US20080233298A1 (en) * | 2003-05-27 | 2008-09-25 | The Hong Kong University Of Science And Technology | Methods of fabric treatment |
US8038728B2 (en) | 2003-05-27 | 2011-10-18 | The Hong Kong University Of Science And Technology | Methods of fabric treatment |
US20080119383A1 (en) * | 2006-11-17 | 2008-05-22 | Christopher Boardman | Fabric treatment method and composition to impart differential Hydrophobicity |
US20110016637A1 (en) * | 2006-11-17 | 2011-01-27 | The Sun Products Corporation | Fabric treatment method and composition to impart differential hydrophobicity |
CN102330343A (en) * | 2011-07-27 | 2012-01-25 | 吴江市瑞丰织造有限公司 | Ultraviolet shielding coatings for fabrics |
US10662317B1 (en) | 2011-10-11 | 2020-05-26 | The Sweet Living Group, LLC | Additive for incorporating ultraviolet radiation protection into a polymer |
US10472523B2 (en) | 2011-10-11 | 2019-11-12 | The Sweet Living Group, LLC | Additive for incorporating ultraviolet radiation protection into a polymer |
US11306208B2 (en) * | 2011-10-11 | 2022-04-19 | The Sweet Living Group, LLC | Product having ultraviolet radiation protection |
US20210269648A1 (en) * | 2011-10-11 | 2021-09-02 | The Sweet Living Group, LLC | Product having ultraviolet radiation protection |
US11001712B2 (en) | 2011-10-11 | 2021-05-11 | The Sweet Living Group, LLC | Product having ultraviolet radiation protection |
US8690964B2 (en) | 2011-10-11 | 2014-04-08 | The Sweet Living Group, LLC | Fabric having ultraviolet radiation protection |
US20200172735A1 (en) * | 2011-10-11 | 2020-06-04 | The Sweet Living Group, LLC | Product having ultraviolet radiation protection |
US9234310B2 (en) | 2011-10-11 | 2016-01-12 | The Sweet Living Group, LLC | Fabric having ultraviolet radiation protection, enhanced resistance to degradation, and enhanced resistance to fire |
US9284682B2 (en) | 2011-10-11 | 2016-03-15 | The Sweet Living Group, LLC | Fabric having ultraviolet radiation protection |
US9404214B2 (en) | 2011-10-11 | 2016-08-02 | The Sweet Living Group, LLC | Additive having ultraviolet radiation protection for a laundry detergent |
US9464260B2 (en) | 2011-10-11 | 2016-10-11 | The Sweet Living Group, LLC | Laundry detergent composition for providing ultraviolet radiation protection for a fabric |
US8277518B1 (en) | 2011-10-11 | 2012-10-02 | The Sweet Living Group, LLC | Ecological fabric having ultraviolet radiation protection |
US20180230314A1 (en) * | 2011-10-11 | 2018-08-16 | The Sweet Living Group, LLC | Fabric having ultraviolet radiation protection |
US10577503B2 (en) * | 2011-10-11 | 2020-03-03 | The Sweet Libing Group, Llc | Fabric having ultraviolet radiation protection |
US10472762B2 (en) | 2011-10-11 | 2019-11-12 | The Sweet Living Group, LLC | Method for incorporating ultraviolet radiation protection and antimicrobial protection into rayon |
US10494528B2 (en) | 2011-10-11 | 2019-12-03 | The Sweet Living Group, LLC | Product having ultraviolet radiation protection |
CN102817236A (en) * | 2012-08-28 | 2012-12-12 | 北京中纺化工股份有限公司 | Efficient light fastness enhancing agent as well as preparation method and application of enhancing agent |
CN102851942A (en) * | 2012-08-29 | 2013-01-02 | 昆山铁牛衬衫厂 | Anti-ultraviolet pure cotton fabric finishing method |
CN102851766A (en) * | 2012-08-29 | 2013-01-02 | 昆山铁牛衬衫厂 | Anti-ultraviolet fiber production method |
US20150223411A1 (en) * | 2012-09-12 | 2015-08-13 | Extenday Ip Limited | Netting, crop cover, and ground cover materials |
US10791680B2 (en) * | 2012-09-12 | 2020-10-06 | Nine Ip Limited | Netting, crop cover, and ground cover materials |
CN103469559A (en) * | 2013-08-21 | 2013-12-25 | 昆山铁牛衬衫厂 | UV-resistant composite finishing agent and preparation method thereof |
CN107057125A (en) * | 2017-05-18 | 2017-08-18 | 句容亿格纳米材料厂 | Modified salicylic acid aligns the preparation and its application in anti-light pollution plastics of octyl phenyl ester |
US10907048B2 (en) | 2018-04-12 | 2021-02-02 | The Sweet Living Group, LLC | Product having ultraviolet radiation protection |
CN110592963A (en) * | 2019-10-09 | 2019-12-20 | 陈晓彤 | Production process of anti-aging and anti-ultraviolet fabric |
US10676861B1 (en) | 2019-11-08 | 2020-06-09 | The Sweet Living Group, LLC | Method for incorporating ultraviolet radiation protection and antimicrobial protection into rayon |
WO2023215483A1 (en) * | 2022-05-04 | 2023-11-09 | Claros Technologies Inc. | Pre- ultraviolet radiation protective additives for textiles and methods of use |
Also Published As
Publication number | Publication date |
---|---|
CA2437613A1 (en) | 2002-08-15 |
DE10105143A1 (en) | 2002-08-08 |
MXPA03006782A (en) | 2003-11-13 |
WO2002063091A2 (en) | 2002-08-15 |
JP2004528486A (en) | 2004-09-16 |
BR0206936A (en) | 2004-08-10 |
EP1383952A2 (en) | 2004-01-28 |
WO2002063091A3 (en) | 2003-11-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US20040074012A1 (en) | Method for providing textile material with uv protection | |
US20060076542A1 (en) | UV absorber mixture with affinity for textile fiber | |
EP0682145B1 (en) | Textile treatment | |
JP2007302891A (en) | Protective use | |
US5810889A (en) | Aqueous textile treatment compositions containing an ultra-violet absorbing agent | |
JPH0813327A (en) | Processing of cloth | |
JP4233874B2 (en) | Cloth Rinse Composition Containing Benztriazole Absorber | |
MXPA97003799A (en) | Compounds of estilben and its | |
AU2002254958A1 (en) | Fabric rinse composition containing a benztriazole UV absorber | |
US20040103482A1 (en) | Fabric rinse composition containing a cationic uv absorber | |
WO2000065142A1 (en) | Uv-absorbers with an affinity for textile fibres | |
US20040078901A1 (en) | Fabric rinse composition comprising a triazine uv absorber | |
AU2002315254A1 (en) | Fabric rinse composition comprising a triazine UV absorber | |
AU2002240950A1 (en) | Fabric rinse composition containing a cationic UV absorber | |
DE19958703A1 (en) | Fibre-reactive UV absorbers such as alpha, omega-bis(2-cyano-3,3-diphenylacryloylamide), can be applied to fabrics during washing to protect human skin against UV, or applied to colored fabrics to reduce fading |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: BASF AKTIENGESELLSCHAFT, GERMANY Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:HEIDENFELDER, THOMAS;DETERING, JUERGEN;WAGENBLAST, GERHARD;REEL/FRAME:014967/0908 Effective date: 20030604 |
|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |