US20040139730A1 - Method and apparatus for directing exhaust gas and reductant fluid in an emission abatement system - Google Patents

Method and apparatus for directing exhaust gas and reductant fluid in an emission abatement system Download PDF

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US20040139730A1
US20040139730A1 US10/345,681 US34568103A US2004139730A1 US 20040139730 A1 US20040139730 A1 US 20040139730A1 US 34568103 A US34568103 A US 34568103A US 2004139730 A1 US2004139730 A1 US 2004139730A1
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valve
outlet
exhaust gas
emission abatement
trap
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US10/345,681
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William Taylor
John Nohl
Yougen Kong
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Faurecia Emissions Control Technologies USA LLC
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Assigned to ARVIN TECHNOLOGIES, INC. reassignment ARVIN TECHNOLOGIES, INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: TAYLOR, WILLIAM III, KONG, YOUGEN, NOHL, JOHN P.
Publication of US20040139730A1 publication Critical patent/US20040139730A1/en
Assigned to ET US HOLDINGS LLC reassignment ET US HOLDINGS LLC ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: ARVIN TECHNOLOGIES, INC.
Assigned to THE CIT GROUP/BUSINESS CREDIT, INC. reassignment THE CIT GROUP/BUSINESS CREDIT, INC. SECURITY AGREEMENT Assignors: ET US HOLDINGS LLC
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0828Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents characterised by the absorbed or adsorbed substances
    • F01N3/0842Nitrogen oxides
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0814Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents combined with catalytic converters, e.g. NOx absorption/storage reduction catalysts
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0821Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents combined with particulate filters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0871Regulation of absorbents or adsorbents, e.g. purging
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2240/00Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being
    • F01N2240/28Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being a plasma reactor
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2610/00Adding substances to exhaust gases
    • F01N2610/03Adding substances to exhaust gases the substance being hydrocarbons, e.g. engine fuel
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2610/00Adding substances to exhaust gases
    • F01N2610/04Adding substances to exhaust gases the substance being hydrogen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0871Regulation of absorbents or adsorbents, e.g. purging
    • F01N3/0878Bypassing absorbents or adsorbents
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

Definitions

  • the present disclosure relates to generally to emission abatement systems, and more particularly to emission abatement systems which utilize reductant fluids to regenerate emission abatement devices.
  • Devices for removing NO X from the exhaust gas of an internal combustion engine may be embodied as traps for removing NO X from the exhaust gas by “trapping” the NO X as the exhaust gas advances therethrough.
  • a NO X trap must be periodically regenerated to purge the trap of the trapped NO X . To do so, the NO X trap periodically undergoes a catalytic reaction in which the trapped NO X is converted to less harmful gases that are subsequently exhausted from the trap.
  • Reductant fluids may be utilized to facilitate such regeneration of the trap.
  • Reductant fluids may take a number of different forms.
  • liquids such as untreated diesel fuel may be used as a reductant fluid.
  • gases such as hydrogen gas or carbon monoxide gas may also be used as a reductant fluid.
  • One way to generate a gaseous reductant fluid is by use of an onboard fuel reformer.
  • a fuel reformer is operated to reform a hydrocarbon fuel into a reformate gas.
  • the reformate gas produced by the fuel reformer may be utilized as the reductant fluid to regenerate or otherwise condition an emission abatement device associated with an internal combustion engine such as a NO X trap.
  • an emission abatement assembly includes a pair of NO X traps arranged in a parallel arrangement.
  • a fuel reformer generates a reductant fluid in the form of a reformate gas which is selectively supplied one of the traps during regeneration thereof.
  • engine exhaust gas is directed through the other trap.
  • a catalyzed soot filter is positioned downstream of the NO X traps.
  • the catalyzed soot filter may be regenerated with heat from the engine exhaust gas.
  • the catalyzed soot filter may also be regenerated with reformate gas from the fuel reformer by advancing the reformate gas into contact with an oxidation catalyst to generate heat for igniting the soot trapped in the filter.
  • the fuel reformer may be embodied as a plasma fuel reformer.
  • a method of operating an emission abatement assembly includes the step of regenerating a first NO X trap with reformate gas from a fuel reformer while engine exhaust gas is advanced through a second NO X trap. Exhaust gas exiting the second NO X trap is then advanced through a catalyzed soot filter.
  • the method may include regenerating the catalyzed soot filter with heat from the exhaust gas.
  • the method may also include regenerating the catalyzed soot filter by advancing reformate gas from the fuel reformer into contact with an oxidation catalyst to generate heat for igniting the soot trapped in the filter.
  • a diverter valve for diverting both engine exhaust gas and a reductant fluid between a number of emission abatement devices.
  • the valve may be used to divert engine exhaust gas to a first NO X trap while contemporaneously diverting reductant fluid to a second NO X trap.
  • a method of operating a diverter valve of an emission abatement assembly includes positioning the diverter valve between a number of different valve positions to selectively divert both engine exhaust gas and a reductant fluid between a number of different emission abatement devices.
  • FIG. 1 is a simplified block diagram of a fuel reforming assembly having a plasma fuel reformer under the control of an electronic control unit;
  • FIG. 2 is a diagrammatic cross sectional view of the plasma fuel reformer of FIG. 1;
  • FIG. 3 is a simplified block diagram of an emission abatement assembly
  • FIG. 4 is a fragmentary perspective view of the diverter valve of the emission abatement assembly of FIG. 3, note that a portion of the valve housing has been cutaway for clarity of description;
  • FIGS. 5 and 6 are simplified diagrammatic views of the diverter valve of FIG. 4 showing the valve in opposite valve positions;
  • FIG. 7 is a flowchart of a control routine executed by the control unit of FIG. 3 to monitor and control regeneration the NO X traps;
  • FIG. 8 is a flowchart of a control routine executed by the control unit of FIG. 3 to monitor and control regeneration of the soot filter;
  • FIG. 9 is a view similar to FIG. 3, but showing a second embodiment of an emission abatement assembly.
  • a fuel reformer may be utilized to regenerate or otherwise condition an emission abatement assembly having a number of different devices for treating a number of different exhaust effluents from the exhaust gas of an internal combustion engine.
  • a fuel reformer may be operated to generate and supply a reductant fluid in the form of a reformate gas to a pair of NO X traps. Reformate gas from the fuel reformer may also be utilized to regenerate a catalyzed soot filter.
  • a diverter valve may be utilized to divert not only engine exhaust gas, but also reductant fluid between a number of different emission abatement devices. In such a way, the need for multiple flow valves is eliminated.
  • the fuel reformer described herein may be embodied as any type of fuel reformer such as, for example, a catalytic fuel reformer, a thermal fuel reformer, a steam fuel reformer, or any other type of partial oxidation fuel reformer.
  • the fuel reformer of the present disclosure may also be embodied as a plasma fuel reformer.
  • a plasma fuel reformer uses plasma to convert a mixture of air and hydrocarbon fuel into a reformate gas which is rich in, amongst other things, hydrogen gas and carbon monoxide.
  • Systems including plasma fuel reformers are disclosed in U.S. Pat. No. 5,425,332 issued to Rabinovich et al.; U.S. Pat. No.
  • the plasma fuel reforming assembly includes a plasma fuel reformer 12 and a control unit 16 .
  • the plasma fuel reformer 12 reforms (i.e., converts) hydrocarbon fuels into a reformate gas that includes, amongst other things, hydrogen and carbon monoxide.
  • the plasma fuel reformer 12 as described further herein, may be used in the construction of an onboard fuel reforming system of a vehicle or a stationary power generator. In such a way, the reformate gas produced by the onboard plasma fuel reformer 12 may be utilized as a reductant fluid to regenerate or otherwise condition an emission abatement device associated with an internal combustion engine (e.g., a diesel engine or a gasoline engine).
  • an internal combustion engine e.g., a diesel engine or a gasoline engine
  • the plasma fuel reformer 12 includes a plasma-generating assembly 42 and a reactor 44 .
  • the reactor 44 includes a reactor housing 48 having a reaction chamber 50 defined therein.
  • the plasma-generating assembly 42 is secured to an upper portion of the reactor housing 48 .
  • the plasma-generating assembly 42 includes an upper electrode 54 and a lower electrode 56 .
  • the electrodes 54 , 56 are spaced apart from one another so as to define an electrode gap 58 therebetween.
  • An insulator 60 electrically insulates the electrodes from one another.
  • the electrodes 54 , 56 are electrically coupled to an electrical power supply 36 (see FIG. 1) such that, when energized, an electrical current is supplied to one of the electrodes thereby generating a plasma arc 62 across the electrode gap 58 (i.e., between the electrodes 54 , 56 ).
  • a fuel input mechanism such as a fuel injector 38 injects a hydrocarbon fuel 64 into the plasma arc 62 .
  • the fuel injector 38 may be any type of fuel injection mechanism which injects a desired amount of fuel into plasma-generating assembly 42 . In certain configurations, it may be desirable to atomize the fuel prior to, or during, injection of the fuel into the plasma-generating assembly 42 .
  • Such fuel injector assemblies i.e., injectors which atomize the fuel
  • injector assemblies are commercially available.
  • the plasma-generating assembly 42 has an annular air chamber 72 .
  • Pressurized air is advanced into the air chamber 72 through an air inlet 74 and is thereafter directed radially inwardly through the electrode gap 58 so as to “bend” the plasma arc 62 inwardly.
  • Such bending of the plasma arc 62 ensures that the injected fuel 64 is directed through the plasma arc 62 .
  • Such bending of the plasma arc 62 also reduces erosion of the electrodes 56 , 58 .
  • advancement of air into the electrode gap 58 also produces a desired mixture of air and fuel (“air/fuel mixture”).
  • the plasma reformer 12 reforms or otherwise processes the fuel in the form of a mixture of air and fuel.
  • the air-to-fuel ratio of the air/fuel mixture being reformed by the fuel reformer is controlled via control of the fuel injector 38 and an air inlet valve 40 .
  • the air inlet valve 40 may be embodied as any type of electronically-controlled air valve.
  • the air inlet valve 40 may be embodied as a discrete device, as shown in FIG. 2, or may be integrated into the design of the plasma fuel reformer 12 . In either case, the air inlet valve 40 controls the amount of air that is introduced into the plasma-generating assembly 42 thereby controlling the air-to-fuel ratio of the air/fuel mixture being processed by the plasma fuel reformer 12 .
  • the lower electrode 56 extends downwardly into the reactor housing 48 .
  • gas (either reformed or partially reformed) exiting the plasma arc 62 is advanced into the reaction chamber 50 .
  • a catalyst 78 may be positioned in the reaction chamber 50 .
  • the catalyst 78 completes the fuel reforming process, or otherwise treats the gas, prior to exit of the reformate gas through a gas outlet 76 .
  • some or all of the gas exiting the plasma-generating assembly 42 may only be partially reformed, and the catalyst 78 is configured to complete the reforming process (i.e., catalyze a reaction which completes the reforming process of the partially reformed gas exiting the plasma-generating assembly 42 ).
  • the catalyst 78 may be embodied as any type of catalyst that is configured to catalyze such reactions.
  • the catalyst 78 is embodied as substrate having a precious metal or other type of catalytic material disposed thereon.
  • a substrate may be constructed of ceramic, metal, or other suitable material.
  • the catalytic material may be, for example, embodied as platinum, rhodium, palladium, including combinations thereof, along with any other similar catalytic materials.
  • the plasma fuel reformer 12 may be embodied without the catalyst 78 .
  • the plasma fuel reformer 12 has a temperature sensor 34 associated therewith.
  • the temperature sensor 34 is used as a feedback mechanism to determine the temperature of a desired structure of the plasma fuel reformer 12 or the gas advancing therethrough.
  • the temperature sensor 34 may be used to measure the temperature of the reformate gas being produced by the plasma fuel reformer 12 , the ambient temperature within the reaction chamber 50 , the temperature of the catalyst 78 , etcetera.
  • the temperature sensor 34 may be located in any number of locations.
  • the temperature sensor 34 may be positioned within the reaction chamber 50 at location in operative contact with the a structure (e.g., the catalyst 78 or the walls of the reaction chamber 50 ) or a substance (e.g., the gas in the reaction chamber 50 ). To do so, the temperature sensor 34 may be positioned in physical contact with the structure or substance, or may be positioned a predetermined distance away from the structure or out of the flow of the substance, depending on the type and configuration of the temperature sensor. In such a way, the temperature sensor 34 may function as a feedback mechanism for controlling operation of the plasma fuel reformer 12 .
  • a structure e.g., the catalyst 78 or the walls of the reaction chamber 50
  • a substance e.g., the gas in the reaction chamber 50
  • the temperature sensor 34 may be positioned in physical contact with the structure or substance, or may be positioned a predetermined distance away from the structure or out of the flow of the substance, depending on the type and configuration of the temperature sensor. In such a way, the temperature sensor 34 may function as
  • the plasma fuel reformer 12 and its associated components are under the control of the control unit 16 .
  • the temperature sensor 34 is electrically coupled to the electronic control unit 16 via a signal line 18
  • the fuel injector 38 is electrically coupled to the electronic control unit 16 via a signal line 20
  • the air inlet valve 40 is electrically coupled to the electronic control unit 16 via a signal line 22
  • the power supply 36 is electrically coupled to the electronic control unit 16 via a signal line 24 .
  • a number of other components associated with the emission abatement assembly 14 may also be under the control of the control unit 16 , and, as a result, electrically coupled thereto.
  • a flow diverter valve 88 for selectively diverting an exhaust gas flow from an internal combustion engine and a flow of reformate gas from the plasma fuel reformer 12 between any number of components may be under the control of the control unit 16 .
  • a number of sensors such as NO X sensors and pressure sensors associated with the emission abatement assembly 14 are also electrically coupled to the control unit 16 .
  • the signal lines 18 , 20 , 22 , 24 (and any of the signal lines used to couple other devices associated with the emission abatement assembly 14 to the control unit) are shown schematically as a single line, it should be appreciated that the signal lines may be configured as any type of signal carrying assembly which allows for the transmission of electrical signals in either one or both directions between the electronic control unit 16 and the corresponding component.
  • any one or more of the signal lines 18 , 20 , 22 , 24 may be embodied as a wiring harness having a number of signal lines which transmit electrical signals between the electronic control unit 16 and the corresponding component. It should be appreciated that any number of other wiring configurations may also be used.
  • signal lines 18 , 20 , 22 , 24 may be used, or a system utilizing a signal multiplexer may be used for the design of any one or more of the signal lines 18 , 20 , 22 , 24 (or any other signal line).
  • the signal lines 18 , 20 , 22 , 24 may be integrated such that a single harness or system is utilized to electrically couple some or all of the components associated with the plasma fuel reformer 12 to the electronic control unit 16 .
  • the electronic control unit 16 is, in essence, the master computer responsible for interpreting electrical signals sent by sensors associated with the plasma fuel reformer 12 and for activating electronically-controlled components associated with the plasma fuel reformer 12 in order to control the plasma fuel reformer 12 , the flow of reformate gas exiting therefrom, and an exhaust gas flow from an internal combustion engine.
  • the electronic control unit 16 of the present disclosure is operable to, amongst many other things, determine the beginning and end of each injection cycle of fuel into the plasma-generating assembly 42 , calculate and control the amount and ratio of air and fuel to be introduced into the plasma-generating assembly 42 , determine the temperature of the reformer 12 or the reformate gas, determine the power level to supply to the plasma fuel reformer 12 , and determine which component (e.g., a NO X trap or a soot filter) to regenerate.
  • a NO X trap or a soot filter e.g., a NO X trap or a soot filter
  • the electronic control unit 16 includes a number of electronic components commonly associated with electronic units which are utilized in the control of electromechanical systems.
  • the electronic control unit 16 may include, amongst other components customarily included in such devices, a processor such as a microprocessor 28 and a memory device 30 such as a programmable read-only memory device (“PROM”) including erasable PROM's (EPROM's or EEPROM's).
  • the memory device 30 is configured to store, amongst other things, instructions in the form of, for example, a software routine (or routines) which, when executed by the processor 28 , allows the electronic control unit 16 to control operation of the plasma fuel reformer 12 and other devices associated with the emission abatement assembly 14 .
  • the electronic control unit 16 also includes an analog interface circuit 32 .
  • the analog interface circuit 32 converts the output signals from the various fuel reformer sensors (e.g., the temperature sensor 34 ) or other sensors associated with the with the emission abatement assembly (e.g., the NO X sensor and the pressure sensors) into a signal which is suitable for presentation to an input of the microprocessor 28 .
  • the analog interface circuit 32 by use of an analog-to-digital (A/D) converter (not shown) or the like, converts the analog signals generated by the sensors into a digital signal for use by the microprocessor 28 .
  • A/D converter may be embodied as a discrete device or number of devices, or may be integrated into the microprocessor 28 . It should also be appreciated that if any one or more of the sensors associated with the plasma fuel reformer 12 or the emission abatement assembly 14 generate a digital output signal, the analog interface circuit 32 may be bypassed.
  • the analog interface circuit 32 converts signals from the microprocessor 28 into an output signal which is suitable for presentation to the electrically-controlled components associated with the plasma fuel reformer 12 (e.g., the fuel injector 38 , the air inlet valve 40 , the power supply 36 ), or other system components associated with the emission abatement assembly 14 (e.g., the diverter valve 88 ).
  • the analog interface circuit 32 by use of a digital-to-analog (D/A) converter (not shown) or the like, converts the digital signals generated by the microprocessor 28 into analog signals for use by the electronically-controlled components associated with the fuel reformer 12 and the emission abatement assembly 14 .
  • D/A digital-to-analog
  • the D/A converter may be embodied as a discrete device or number of devices, or may be integrated into the microprocessor 28 . It should also be appreciated that if any one or more of the electronically-controlled components associated with the plasma fuel reformer 12 or the emission abatement assembly 14 operate on a digital input signal, the analog interface circuit 32 may be bypassed.
  • the electronic control unit 16 may be operated to control operation of the plasma fuel reformer 12 , and components associated therewith, and the components associated with the emission abatement assembly 14 .
  • the electronic control unit 16 executes a routine including, amongst other things, a closed-loop control scheme in which the electronic control unit 16 monitors the outputs from a number of sensors in order to control the inputs to the electronically-controlled components associated therewith.
  • the electronic control unit 16 communicates with the sensors associated with the fuel reformer 12 and the emission abatement assembly 14 to determine, amongst numerous other things, the amount, temperature, and/or pressure of air and/or fuel being supplied to the plasma fuel reformer 12 , the amount of hydrogen and/or oxygen in the reformate gas, the temperature of the reformer or the reformate gas, the composition of the reformate gas, the accumulation level within an emission abatement device (e.g., a NO X trap or soot filter), etcetera.
  • an emission abatement device e.g., a NO X trap or soot filter
  • the electronic control unit 16 performs numerous calculations each second, including looking up values in preprogrammed tables, in order to execute algorithms to perform such functions as determining when or how long the fuel reformer's fuel injector or other fuel input device is opened, controlling the power level input to the fuel reformer, controlling the amount of air advanced through air inlet valve, controlling the position of a flow diverter valve responsible for directing the flow of reformate gas and exhaust gas to one component or the other, determining the quantity and/or composition of reformate gas to generate and deliver to a particular component, etcetera.
  • the emission abatement assembly 14 includes a pair of NO X traps 84 , 86 for removing and treating NO X present in the exhaust gas from an internal combustion engine 82 such as a diesel engine, a gasoline engine, a gasoline direct injection (GDI) engine, or natural gas engine.
  • the NO X traps 84 , 86 are arranged in a parallel relationship with one another.
  • the NO X trap 84 will herein be referred to as the right NO X trap
  • the NO X trap 86 will herein be referred to as the left NO X trap.
  • such use of directional terms i.e., right and left
  • the NO X traps 84 , 86 may be any type of commercially available NO X trap, including a lean NO X trap, which facilitates the trapping and removal of NO X in the lean conditions associated with exhaust gases from diesel engines, GDI engines, or natural gas engines.
  • Specific examples of NO X traps which may be used as the NO X traps 84 , 86 of the present disclosure include, but are not limited to, NO X traps commercially available from, or NO X traps constructed with materials commercially available from, EmeraChem, LLC of Knoxville, Tenn. (formerly known as Goal Line Environmental Technologies, LLC of Knoxville, Tenn.).
  • the emission abatement assembly 14 also includes an oxidation catalyst 94 and a catalyzed soot filter 96 .
  • the catalyst 94 may be embodied as any type of catalyst that is configured to catalyze oxidation reactions in an exhaust gas stream.
  • the catalyst 94 is embodied as substrate having a precious metal or other type of catalytic material disposed thereon. Such a substrate may be constructed of ceramic, metal, or other suitable material.
  • the catalytic material may be, for example, embodied as platinum, rhodium, palladium, including combinations thereof, along with any other similar catalytic materials.
  • the catalyst 94 may function to clean up any hydrogen or hydrocarbon “slip” from the NO X traps 84 , 86 .
  • the oxidation catalyst 94 may be used to oxidize any H 2 , certain hydrocarbons, or H 2 S that may be present in the gases exiting the traps 84 , 86 .
  • the catalyst 94 may be utilized during assisted regeneration of soot filter 96 .
  • the soot filter 96 may be embodied as any type of commercially available particulate filter.
  • the soot particulate filter may be embodied as any known exhaust particulate filter such as a “deep bed” or “wall flow” filter.
  • Deep bed filters may be embodied as metallic mesh filters, metallic or ceramic foam filters, ceramic fiber mesh filters, and the like.
  • Wall flow filters may be embodied as a cordierite or silicon carbide ceramic filter with alternating channels plugged at the front and rear of the filter thereby forcing the gas advancing therethrough into one channel, through the walls, and out another channel.
  • the soot filter 96 is impregnated with a catalytic material.
  • the catalytic material may be, for example, embodied as platinum, rhodium, palladium, including combinations thereof, along with any other similar catalytic materials.
  • the temperature at which soot particles trapped in the filter combust is lowered such that regeneration of the soot filter 96 may occur in the presence of the heat of the engine exhaust gas.
  • reformate gas from the fuel reformer 12 may be used to regenerate the filter.
  • a diverter valve 88 selectively diverts the flow of exhausts gas from the engine 82 between the traps 84 , 86 .
  • the diverter valve 88 may be operated to divert a flow of exhaust gas from the engine 82 between a right flow path 102 and a left flow path 104 .
  • the right NO X trap 84 is positioned in the right flow path 102 such that exhaust gas or reformate gas advancing through the right flow path 102 is advanced through the right NO X trap 84 .
  • the left NO X trap 86 is positioned in the left flow path 104 such that exhaust gas or reformate gas advancing through the left flow path 104 is advanced through the left NO X trap 86 .
  • the right flow path 102 and the left flow path 104 are recombined by a flow coupler 106 .
  • the flow coupler 106 is positioned downstream of the NO X traps 84 , 86 and upstream of oxidation catalyst 94 and the soot filter 96 .
  • gas exiting the NO X traps 84 , 86 is directed through both the oxidation catalyst 94 and the soot filter 96 .
  • an exhaust gas inlet 108 of the diverter valve 88 is fluidly coupled to an exhaust manifold 110 of the engine 82 via a fluid line 112 .
  • a right outlet 114 of the diverter valve 88 is fluidly coupled to an inlet 116 of the right NO X trap 84 via a fluid line 118
  • a left outlet 120 of the diverter valve 88 is fluidly coupled to an inlet 122 of the left NO X trap 86 via a fluid line 124 .
  • An outlet 126 of the right NO X trap 84 is fluidly coupled to the flow coupler 106 via a fluid line 128
  • an outlet 130 of the left NO X trap 86 is fluidly coupled to the flow coupler 106 via the fluid line 132 .
  • a fluid line 134 fluidly couples the flow coupler 106 to an inlet 136 of the oxidation catalyst 94 .
  • An outlet 138 of the oxidation catalyst 94 is fluidly coupled to an inlet 140 of the soot filter 96 via a fluid line 142 .
  • an outlet 146 of the soot filter 96 is either open to the atmosphere or coupled to an additional exhaust system component (not shown) positioned downstream of the soot filter 96 .
  • exhaust gas from the engine 82 may be routed through the emission abatement assembly 14 to remove, amongst other things, NO X and soot therefrom.
  • exhaust gas may be selectively routed between the two NO X traps 84 , 86 to allow for both treatment of the exhaust gas and trap regeneration.
  • exhaust gas may be routed through the right NO X trap 84 while the left NO X trap 86 is maintained “offline.” While offline, the left NO X trap 86 may undergo regeneration.
  • exhaust gas is advanced along a fluid path which includes the fluid line 112 from the exhaust manifold 110 , the diverter valve 88 , the fluid line 118 to the right NO X trap 84 , through the trap 84 and the fluid line 128 to the flow coupler 106 , the fluid line 134 to the oxidation catalyst 94 , through the catalyst 94 and the fluid line 142 to the soot filter 96 , through the soot filter 96 and out the fluid line 144 .
  • the position of the diverter valve 88 may be switched such that exhaust gas from the engine 82 is routed through the left NO X trap 86 while the right NO X trap 84 is offline for regeneration.
  • exhaust gas is advanced along a fluid path which includes the fluid line 112 from the exhaust manifold 110 , the diverter valve 88 , the fluid line 124 to the left NO X trap 86 , through the trap 86 and the fluid line 132 to the flow coupler 106 , the fluid line 134 to the oxidation catalyst 94 , through the catalyst 94 and the fluid line 142 to the soot filter 96 , through the soot filter 96 and out the fluid line 144 .
  • the diverter valve 88 is also configured to divert reformate gas from the fuel reformer 12 to the appropriate NO X trap 84 , 86 .
  • the outlet 76 (see FIG. 2) of the fuel reformer 12 is fluidly coupled to a reductant fluid inlet 148 of the diverter valve 88 via a fluid line 150 .
  • the diverter valve 88 diverts reformate gas from the fuel reformer 12 to the offline NO X trap 84 , 86 .
  • engine exhaust gas is routed by the diverter valve 88 through one of the traps 84 , 86 while the other trap is maintained offline for regeneration.
  • the diverter valve 88 routes engine exhaust gas through one of the traps 84 , 86 , while routing reformate gas from the fuel reformer 12 through the other trap 84 , 86 .
  • the diverter valve 88 is electrically coupled to the electronic control unit 16 via a signal line 152 . As such, the position of the diverter valve 88 is under the control of the electronic control unit 16 . Hence, the electronic control unit 16 , amongst its other functions, selectively directs the flow of exhaust gas from the engine 82 and the flow of reformate gas from the fuel reformer 12 to either the right NO X trap 84 or the left NO X trap 86 , or a combination of both traps 84 , 86 .
  • the control scheme for controlling the position of the diverter valve 88 may be designed in a number of different manners. For example, a sensor-based control scheme may be utilized. In such a case, the position of the diverter valve 88 is changed as a function of output from one or more sensors associated with the NO X traps 84 , 86 . For instance, regeneration of one of the NO X traps 84 , 86 may commence when the output from a NO X sensor 154 is indicative of a predetermined NO X accumulation level within the online trap. More specifically, the NO X sensor 154 is positioned to sense the NO X content of exhaust gas passing through the fluid line 134 .
  • the sensor 154 may be used to monitor the NO X accumulation level of the NO X trap 84 , 86 through which engine exhaust gas is being routed. As such, when the output from the NO X sensor 154 indicates that a particular NO X trap 84 , 86 is in need of regeneration, the control unit 16 takes the trap 84 , 86 in need of regeneration offline, and brings the other trap 84 , 86 online in the manner described above.
  • a timing-based control scheme may be utilized in which the position of the diverter valve 88 is changed as a function of time. For instance, regeneration of the traps 84 , 86 may be performed at predetermined timed intervals. In such a case, the NO X sensor 154 may be all together eliminated, or used merely as a “failsafe” to ensure that regeneration is not prematurely needed during a timed interval.
  • an engine-mapped control scheme may be utilized in which the position of the diverter valve 88 is changed as a function of engine load over time.
  • an engine map may be created which allows the control unit 16 to track the amount of NO X which has been created by the engine 82 based on engine load conditions.
  • the control unit 16 determines that the engine 82 has generated a predetermined amount of NO X , with such an amount being trapped in the online trap 84 , 86 , the control unit 16 swaps the position of the diverter valve 88 thereby taking the trap offline for regeneration and routing exhaust gas through the other trap.
  • the NO X sensor 154 may be all together eliminated from this control scheme, or used merely as a “failsafe” to ensure that regeneration is not prematurely needed during a mapped interval.
  • the soot filter 96 may become impregnated with an amount of soot that cannot be removed by use of engine heat alone. For example, if the engine operating conditions were to cause an abnormally large amount of soot to be generated (and hence trapped by the filter 96 ), the soot filter 96 may not be able to completely purge the soot by use of exhaust gas heat alone. Moreover, if the engine 82 is operated in sustained transient conditions (e.g., startup, idle, etcetera), exhaust gas temperatures will be lowered thereby reducing regeneration efficiency of the soot filter 96 .
  • sustained transient conditions e.g., startup, idle, etcetera
  • reformate gas from the fuel reformer 12 may be used to assist in regeneration of the filter 96 .
  • a quantity of reformate gas from the plasma fuel reformer 12 may be advanced into contact with the oxidation catalyst 94 to catalyze an oxidation reaction between the oxygen in the exhaust gas of the engine 82 and the reformate gas.
  • the oxidation catalyst 94 catalyzes an oxidation reaction which converts the hydrogen gas present in the reformate gas and the oxygen present in the exhaust gases into, amongst other things, water.
  • the catalyst catalyzes an oxidation reaction which converts the carbon monoxide present in the reformate gas and the oxygen present in the exhaust gases into carbon dioxide.
  • Both of these oxidation reactions are highly exothermic, and, as a result, produce heat that is transferred to the downstream-positioned soot filter 96 .
  • the heat which may illustratively be in the range of 600-650 degrees Celsius, ignites and burns soot particles trapped in the particulate filter 96 thereby regenerating the filter 96 .
  • soot filter 96 may be self-sustaining once initiated by heat from the exothermic reaction catalyzed by the oxidation catalyst 94 . Specifically, once the soot filter 96 is heated to a temperature at which the soot particles trapped therein begin to ignite, the ignition of an initial portion of soot particles trapped therein can cause the ignition of the remaining soot particles much in the same way a cigar slowly burns from one end to the other. In essence, as the soot particles “burn,” an amount of heat is released in the “burn zone.” Locally, the soot layer (in the burn zone) is now much hotter than the immediate surroundings.
  • heat is transferred to the as yet un-ignited soot layer downstream of the burn zone.
  • the energy transferred may be sufficient to initiate oxidation reactions that raise the un-ignited soot to a temperature above its ignition temperature.
  • heat from the oxidation catalyst 94 may only be required to commence the regeneration process of the soot filter 96 (i.e., begin the ignition process of the soot particles trapped therein).
  • the soot filter 96 is impregnated on the surfaces thereof with a catalytic material such as, for example, a precious metal catalytic material, the ignition temperature of the soot particles trapped in the filter 96 is reduced. Indeed, depending on, amongst other things, the amount of catalytic material disposed on the filter 96 and the amount of accumulated soot particles, the ignition temperature of the soot particles may be lowered to an ignition temperature of between 300-600 degrees Celsius. In other exemplary implementations, the soot ignition temperature may be lowered to a temperature in the range of 300-550 degrees Celsius, more particularly in the range of 300-450 degrees Celsius, and even more particularly in the range of 300-350 degrees Celsius.
  • a catalytic material such as, for example, a precious metal catalytic material
  • the electronic control unit 16 is also electrically coupled to a pair of pressure sensors 156 , 158 via a pair of signal lines 160 , 162 , respectively.
  • the pressure sensors 156 , 158 may be utilized to determine when the soot filter 96 is in need of regeneration assistance from the fuel reformer 12 .
  • the pressure sensors 156 , 158 sense the pressure difference across the soot filter 96 in order to determine the soot accumulation level in the soot filter 96 .
  • the electronic control unit 16 determines that the filter 96 is in need of regeneration and commences the assisted filter regeneration process.
  • a single pressure sensor on either side of soot filter 96 may be utilized, if desired.
  • the electronic control unit 16 would monitor when the pressure sensed by the single pressure sensor exceeded a predetermined upper threshold or was below a predetermined lower threshold, as opposed to monitoring the pressure drop across the soot filter 96 .
  • the control unit 16 operates the fuel reformer 12 so as to generate a flow of reformate gas which is directed into contact with the oxidation catalyst 94 thereby commencing the assisted regeneration process described above.
  • the reformate gas may be advanced to the oxidation catalyst 94 via the NO X traps 84 , 86 in a number of different manners.
  • the control unit 16 may operate the diverter valve 88 to divert reformate gas through a recently regenerated NO X trap 84 , 86 thereby causing a predetermined portion of the reformate gas to pass through the NO X trap to the oxidation catalyst 94 without being “consumed” by the trap.
  • assisted regeneration of the soot filter 96 may be tied to regeneration of one of the NO X traps 84 , 86 .
  • the next regeneration cycle of one of the NO X traps 84 , 86 may be extended.
  • reformate gas from the fuel reformer 12 may continue to be advanced through the NO X trap even after the trap has been sufficiently regenerated thereby allowing amounts of reformate gas to reach the oxidation catalyst 94 .
  • Reformate gas from the fuel reformer 12 may also be advanced to the oxidation catalyst 94 via a fluid line (not shown) which bypasses the NO X traps.
  • a fluid line (not shown) may be coupled at one end to the outlet 76 of the fuel reformer 12 and at the other end to the fluid line 134 at a position upstream of the oxidation catalyst 94 .
  • a diverter valve (not shown) may be used to selectively direct reformate gas through either such a bypass line or through the fluid line 150 to the diverter valve 88 and hence the NO X traps 84 , 86 .
  • the soot filter 96 may be regenerated with heat generated in the fuel reformer 12 by increasing the air-to-fuel ratio of the air/fuel mixture being processed by the fuel reformer 12 (e.g., using an air/fuel mixture having an oxygen-to-carbon ratio between 1.4-4.0, instead of typical 1.0 to 1.4). Such operation will convert some or all of the H 2 and CO in the reformate gas into heat at the reformer 12 . This heat may then be carried through the system to the soot filter 96 to commence the regeneration process in a similar manner to as described above when commencement of the filter regeneration process is facilitated by heat from the oxidation catalyst.
  • Such lean operation of the fuel reformer 12 may also be used to temporarily heat the NO X traps 84 , 86 to their de-sulfurization temperature (e.g., 600 degrees Celsius). As such, a scheme may be utilized in which heat from the fuel reformer 12 is used to both de-sulfurize the NO X traps 84 , 86 and regenerate the soot filter 96 .
  • de-sulfurization temperature e.g. 600 degrees Celsius
  • a pair of temperature sensors may also be used on each side of the soot filter 96 .
  • the temperature sensors may be used to sense the temperature at the inlet 140 and outlet 146 of the soot filter 96 thereby allowing for the temperature of the exhaust gas entering and/or exiting the soot filter 96 to be determined.
  • Such temperature readings may be used as a feedback mechanism to the control unit 16 to monitor regeneration of the filter 96 .
  • filter regeneration may be self-sustaining after being commenced by reformate gas from the fuel reformer 12 .
  • a temperature reading taken near the outlet 146 of the soot filter 96 may be used to ensure that combustion of the soot particles within the trap is being self-sustained in such a manner.
  • the diverter valve 88 includes a valve housing 164 having a valve chamber 166 defined therein. Note that in FIG. 4, all but a small portion of the top plate 172 of the valve housing 164 has been cut away for clarity of view into the valve chamber 166 .
  • the exhaust gas inlet 108 , the reductant fluid inlet 148 , the right outlet 114 , and the left outlet 120 are also defined in the valve housing 164 .
  • each of the inlets and outlets associated with the diverter valve 88 are exemplary embodied as an orifice defined in the walls of the valve housing 164 , it should be appreciated that any or all of such inlets and outlets may, alternatively, be embodied to include a tube, coupling assembly, or other structure which extends through the wall of the housing 164 .
  • the fluid lines 112 , 118 , 124 , and 150 are secured to the valve housing 164 such that fluids conducted therein may be advanced into or out of the valve chamber 166 thereby fluidly coupling the valve chamber 166 to a particular component.
  • one end of the fluid line 112 (shown as a pipe in FIG. 4) extends through the exhaust gas inlet 108 of the valve housing 164 thereby fluidly coupling the valve chamber 166 to the exhaust manifold 110 of the engine 82 .
  • An end of the fluid line 118 (shown as a pipe in FIG.
  • valve housing 164 extends through the right outlet 114 of the valve housing 164 thereby fluidly coupling the valve chamber 166 to the inlet 116 of the right NO X trap 84
  • one end of the fluid line 124 extends through the left outlet 120 of the valve housing 164 thereby fluidly coupling the valve chamber 166 to the inlet 122 of the left NO X trap 86
  • An end of the fluid line 150 extends through the reductant fluid inlet 148 of the valve housing 164 thereby fluidly coupling the valve chamber 166 to the outlet 76 of the fuel reformer 12 .
  • a valve member 168 in the form of a movable plate or “flap” is positioned in the valve chamber 166 .
  • the flap 168 is movable between a number of valve positions to selectively divert both exhaust gas from the engine 82 and reformate gas from the fuel reformer 12 to either one of the NO X traps 84 , 86 .
  • the flap 168 is positionable to direct engine exhaust gas to one of the NO X traps 84 , 86 (i.e., the “online” trap) while directing reformate gas from the fuel reformer 12 to the other NO X trap 84 , 86 (i.e., the “offline” trap).
  • the flap 168 diverts engine exhaust gas to the right NO X trap 84 , while also diverting reformate gas from the fuel reformer 12 to the left NO X trap 86 .
  • the flap 168 fluidly couples the exhaust gas inlet 108 to the right outlet 114 , but fluidly isolates the exhaust gas inlet 108 from the left outlet 120 .
  • the flap 168 also fluidly couples the reductant fluid inlet 148 to the left outlet 120 , but fluidly isolates the reductant fluid inlet 148 from the right outlet 114 .
  • the flap 168 diverts engine exhaust gas to the left NO X trap 86 , while also diverting reformate gas from the fuel reformer 12 to the right NO X trap 84 .
  • the flap 168 fluidly couples the exhaust gas inlet 108 to the left outlet 120 , but fluidly isolates the exhaust gas inlet 108 from the right outlet 114 .
  • the flap 168 also fluidly couples the reductant fluid inlet 148 to the right outlet 114 , but fluidly isolates the reductant fluid inlet 148 from the left outlet 120 .
  • the diverter valve 88 also includes a valve actuator 170 which, as alluded to above, is electrically coupled to the control unit 16 via the signal line 152 . As such, the position of the diverter valve 88 is under the control of the control unit 16 . As a result, the control unit 16 , amongst its other functions, may selectively direct the flow of exhaust gas from the engine 82 and reformate gas from the plasma fuel reformer 12 to either the right NO X trap 84 or the left NO X trap 86 . Specifically, the control unit 16 may generate control signals on the signal line 152 which cause the valve actuator 170 to selectively position the flap 168 in either the valve position of FIG. 5 or the valve position of FIG. 6.
  • the valve actuator 170 may be embodied as any type of electrically-controlled actuator for moving the flap 168 in such a manner.
  • the valve actuator may be embodied as a linear solenoid or a stepper motor.
  • diverter valve 88 is herein described as a two position valve in which the flow of engine exhaust gas is completely interrupted to the offline trap 84 , 86 and the flow of reformate gas is completely interrupted to the online trap
  • other control configurations of the diverter valve 88 are also contemplated.
  • a variable flow configuration is also contemplated in which a desired amount of engine exhaust gas may be directed through the offline trap 84 , 86 and/or a desired amount of reformate gas may be directed through the online trap 84 , 86 .
  • While such a configuration may not be particularly useful during regeneration of the NO X trap since it is usually desirable to have little to no flow of exhaust gas through the trap, such a configuration may be useful in the case of the aforedescribed assisted regeneration of the soot filter 96 since it may be desirable to have some degree of a flow of exhaust gases through the soot filter during regeneration thereof.
  • the components of the diverter valve 88 may be constructed with any type of material suitable for withstanding the operating conditions to which the valve 88 is subjected.
  • the components of the diverter valve 88 may be constructed with any of the 300 -series or 400 -series stainless steels.
  • the components of the diverter valve 88 may be constructed with either “ 304 ” stainless steel or “ 409 ” stainless steel.
  • the components of the diverter valve 88 may also be constructed with other materials such as ceramic coated metals or the like.
  • control routine 200 for controlling operation of the NO X traps during operation of the engine 14 .
  • the control routine 200 begins with step 202 in which the control unit 16 determines the NO X accumulation level in the online NO X trap 84 , 86 .
  • the NO X accumulation in the online NO X trap 84 , 86 may be determined in a number of different manners.
  • the NO X sensor 154 may be utilized in which case the control unit 16 scans or otherwise reads the signal line coupling the sensor 154 to the control unit 16 to monitor output from the sensor 154 .
  • the output signals produced by the NO X sensor 154 are indicative of the NO X accumulation level of the online NO X trap 84 , 86 .
  • the control unit 16 may determine the NO X accumulation level of the online NO X trap by determining the amount of time which has elapsed since the NO X trap was last regenerated.
  • the control unit 16 may also determine the accumulation level of the online trap by use of an engine-map technique. In any case, once the control unit 16 has determined the NO X accumulation level of the online NO X trap 84 , 86 , the control routine 200 advances to step 204 .
  • step 204 the control unit 16 determines if the NO X accumulation level within the online NO X trap 84 , 86 necessitates regeneration of the trap.
  • a predetermined accumulation level or “set point” may be established at which point the NO X trap is in need of regeneration.
  • the control unit 16 determines if the NO X accumulation level of the online NO X trap equals or exceeds the set point. If the NO X accumulation level within the online NO X trap is below the set point, the control routine 200 loops back to step 202 to continue monitoring the NO X accumulation level within the online NO X trap 84 , 86 . However, if the NO X accumulation level within the online NO X trap 84 , 86 is greater than or equal to the set point, a control signal is generated, and the control routine 200 advances to step 206 .
  • step 206 the control unit 16 redirects engine exhaust gas to the offline NO X trap 84 , 86 .
  • the control unit 16 generates an output signal on the signal line 152 thereby causing the valve actuator 170 to move the diverter valve 88 from its current valve position to the opposite valve position.
  • Such movement of the diverter valve 88 swaps the online/offline status of the NO X traps 84 , 86 .
  • the control unit 16 generates an output signal on the signal line 152 which causes the diverter valve 88 to be moved from the valve position shown in FIG. 5 to the valve position shown in FIG. 6.
  • control unit 16 Conversely, if the left NO X trap 86 is online (and determined to be saturated beyond the set point in step 204 ), the control unit 16 generates an output signal on the signal line 152 which causes the diverter valve 88 to be moved from the valve position shown in FIG. 6 to the valve position shown in FIG. 5. Once the position of the diverter valve 88 has been switched in such a manner, engine exhaust gas will be directed to the newly online NO X trap. The control routine 200 then advances to step 208 .
  • step 208 the control unit 16 regenerates the newly offline NO X trap 84 , 86 (i.e., the NO X trap determined to be saturated beyond the set point in step 204 ).
  • the control unit 16 commences operation of the fuel reformer 12 so as to generate reformate gas therewith.
  • the reformate gas exiting the fuel reformer 12 is then advanced to the diverter valve 88 where, based on the valve's repositioning in step 206 , the reformate gas is directed to the offline NO X trap.
  • the diverter valve 88 is positioned by the control unit 16 into the valve position shown in FIG. 5, reformate gas from the fuel reformer 12 is advanced to the left NO X trap 86 .
  • step 206 reformate gas from the fuel reformer 12 is advanced to the right NO X trap 84 .
  • reformate gas from the fuel reformer 12 is used to regenerate the offline NO X trap.
  • the control routine 200 then loops back to step 202 to commence monitoring of the online NO X trap.
  • exhaust gas exiting the online NO X trap 84 , 86 is directed through the oxidation catalyst 94 and thereafter the catalyzed soot filter 96 .
  • any “slip” from the NO X traps 84 , 86 e.g., hydrogen, hydrocarbons, or H 2 S
  • soot particles in the exhaust gas exiting the NO X traps 84 , 86 are trapped in the soot filter 96 .
  • regeneration of the soot filter 96 will by in large be sustained by the introduction of heat from the engine's exhaust gas.
  • soot trapped on the soot filter 96 will be constantly ignited or otherwise purged from the filter 96 during operation of the engine.
  • the soot filter 96 may become impregnated with an amount of soot that cannot be removed by use of engine heat alone.
  • control unit 16 executes a control routine 300 , as shown in FIG. 8.
  • the control routine 300 is executed contemporaneously with the control routine 200 of FIG. 7.
  • the routine 300 begins with step 302 in which the control unit 16 determines the soot accumulation level in the soot filter 96 .
  • the control unit 16 scans or otherwise reads the signal lines 160 , 162 to monitor output from the pressure sensors 156 , 158 , respectively.
  • the output signals produced by the pressure sensors 156 , 158 reflect the pressure drop across the soot filter 96 , and, as a result, are indicative of the soot accumulation level of the filter 96 .
  • the control routine 300 advances to step 304 .
  • step 304 the control unit 16 determines if the soot accumulation level within the soot filter 96 necessitates regeneration of the filter 96 .
  • a predetermined accumulation level or “set point” may be established at which point the soot filter 96 is deemed to be in need of assistance in regard to regeneration thereof.
  • a set point in the form of a variable obtained from an engine map or a measured exhaust flow may be used.
  • the control unit 16 determines if the soot accumulation level of the soot filter 96 equals or exceeds the set point.
  • control routine 300 loops back to step 302 to continue monitoring the soot accumulation level within the soot filter 96 . However, if the soot accumulation level within the soot filter 96 is greater than or equal to the set point, a control signal is generated, and the control routine 300 advances to step 306 .
  • step 306 the control unit 16 positions the diverter valve 88 to allow for the advancement of reformate gas from the fuel reformer 12 to the oxidation catalyst 94 .
  • the control unit 16 generates an output signal on the signal line 152 thereby causing the valve actuator 170 to move the diverter valve 88 to a valve position in which reformate gas may be diverted through a recently regenerated NO X trap 84 , 86 thereby causing a predetermined portion of the reformate gas to pass through the NO X trap to the oxidation catalyst 94 without being “consumed” by the trap.
  • such advancement of the reformate gas through the trap may be performed as an extended NO X trap regeneration.
  • the reformate gas may be advanced to the catalyst via a dedicated bypass line.
  • the control routine 300 then advances to step 308 .
  • step 308 the control unit 16 commences operation of the fuel reformer 12 so as to generate reformate gas therewith.
  • the reformate gas exiting the fuel reformer 12 is then advanced into contact with the oxidation catalyst 94 to catalyze an oxidation reaction between the oxygen in the exhaust gas of the engine 82 and the reformate gas, as described in detail above.
  • the heat generated by such a reaction is transferred to the downstream-positioned soot filter 96 thereby igniting and burning soot particles trapped in the particulate filter 96 so as to regenerate the filter 96 .
  • the control routine 300 then loops back to step 302 to commence monitoring of the soot filter 96 .
  • FIG. 9 there is shown an emission abatement assembly which is similar to the assembly shown in FIG. 3.
  • the same reference numerals are used in FIG. 9 to designate common components which were previously discussed in regard to FIG. 3 with additional discussion thereof being unwarranted.
  • FIG. 9 The system of FIG. 9 is somewhat similar to the system of FIG. 3 with the exception that only a single NO X trap 84 is used.
  • the use of a single NO X trap may be particularly useful in the case of a vehicle retrofit application.
  • a pair of exhaust diverter valves 402 , 404 are utilized in lieu of the diverter valve 88 .
  • Use of the diverter valves 402 , 404 allows for advancement of engine exhaust gas through either a trap flow path 406 or a bypass flow path 408 .
  • the NO X trap 84 is positioned in the trap flow path 406 , but is isolated from the bypass flow path 408 .
  • the diverter valve 402 is positioned in its open position and the diverter valve 404 is positioned in its closed position
  • exhaust gas from the engine 82 is directed along the trap flow path 406 and hence through the NO X trap 84 .
  • the diverter valve 402 is positioned in its closed position and the diverter valve 404 is positioned in its open position
  • exhaust gas from the engine 82 is directed along the bypass flow path 408 and hence bypasses the NO X trap 84 .
  • the diverter valves 402 , 404 are electrically coupled to the electronic control unit 16 via a pair of signal lines 412 , 414 , respectively. As such, the position of each of the diverter valves 402 , 404 is under the control of the electronic control unit 16 .
  • the electronic control unit 16 amongst its other functions, selectively directs the flow of exhaust gas from the engine 82 to either the NO X trap 84 or the bypass flow path 408 , or a combination thereof.
  • the control scheme for controlling the position of the diverter valves 402 , 404 may be designed in a number of different manners. For example, a sensor-based control scheme similar to described herein in regard to FIG. 3 may be utilized. In such a case, the position of each of the diverter valves 402 , 404 is changed as a function of output from the NO X sensor 154 .
  • control unit 16 operates the diverter valves 402 , 404 to direct the exhaust gas from the engine 82 through the bypass flow path 408 thereby allowing for offline regeneration of the NO X trap 84 by use of reformate gas from the fuel reformer 12 in the manner described above.
  • a timing-based control scheme may be utilized in which the position of each of the diverter valves 402 , 404 is changed as a function of time. For instance, regeneration of the NO X trap 84 may be performed at predetermined timed intervals. In such a case, the NO X sensor 154 may be all together eliminated, or used merely as a “failsafe” to ensure that regeneration is not prematurely needed during a timed interval.
  • an engine-mapped control scheme may be utilized in which the position of each of the diverter valves 402 , 404 is changed as a function of engine load over time.
  • an engine map may be created which allows the control unit 16 to track the amount of NO X which has been created by the engine 82 based on engine load conditions.
  • the control unit 16 determines that the engine 82 has generated a predetermined amount of NO X , with such an amount being trapped in the NO X trap 84 , the control unit 16 operates the diverter valves 402 , 404 to direct the exhaust gas from the engine 82 through the bypass flow path 408 thereby allowing for offline regeneration of the NO X trap 84 by use of reformate gas from the fuel reformer 12 in the manner described above.
  • the NO X sensor 154 may be all together eliminated from this control scheme, or used merely as a “failsafe” to ensure that regeneration is not prematurely needed during a mapped interval.
  • each of the right flow path 102 and the left flow path 104 may be configured to include an oxidation catalyst and an uncatalyzed soot filter positioned downstream of the respective NO X traps.
  • an oxidation catalyst e.g., a diesel oxidation catalyst
  • uncatalyzed soot filter e.g., a soot filter which has not been impregnated with catalytic material
  • Such an arrangement advantageously allows for filter regeneration in the presence of a significantly smaller engine exhaust flow thereby lowering the amount of reformate gas required to regenerate each soot filter relative to use of a soot filter that is regenerated in the presence of the entire engine exhaust flow.
  • the concepts of the present disclosure provide numerous features and advantages relative to other systems.
  • the concepts of the present disclosure allow for the use of a single fuel reformer to regenerate a number of different exhaust treatment devices.
  • multiple exhaust compounds e.g., NO X and soot
  • soot filter enhances the reliability of the emission abatement assembly. Indeed, use of a catalyzed filter allows for soot filter regeneration to be performed primarily without assistance from the fuel reformer. Moreover, positioning the soot filter downstream of the NO X traps, as opposed to visa versa, eliminates the possibility of damage to the NO X traps as a result of heat from an assisted filter regeneration cycle.
  • a single valve may be used in place of numerous valves. Indeed, a single valve may be used in lieu of one or more valves for diverting exhaust gas from the engine between the two traps and one or more valves for diverting reformate gas between the two traps.
  • NO X abatement devices are herein described as NO X traps, and have numerous advantages thereby in regard to the disclosed systems, certain of such advantages may also be achieved by use of other NO X abatement devices.
  • SCR devices may be used in certain system configurations in lieu of the NO X traps described herein.
  • valve 88 is herein described in regard to the directing of engine exhaust gas, along with a reductant fluid in the form of reformate gas from a fuel reformer, it should be appreciated that the valve 88 may be used in regard to other types of reductant fluids.
  • the diverter valve 88 may be used to direct reductant fluids in the form of reductant gases which originate from sources other than onboard reformers such as tanks or other storage devices.
  • the diverter valve 88 may also be used to direct reductant fluids in forms other than gases.
  • the diverter valve 88 may be used to direct reductant fluids in the form of liquid hydrocarbon fuels.
  • the diverter valve 88 may be used to direct reductant fluid in the form of untreated diesel fuel.
  • the untreated diesel fuel may be injected into the valve 88 (e.g., through the reductant fluid inlet 148 ) by use of a fuel injector assembly (including a fuel injector assembly that atomizes the diesel fuel prior to or during injection thereof).

Abstract

A diverter valve includes a valve member positionable between a number of valve positions to selectively divert both engine exhaust gas and a reductant fluid between a number of emission abatement devices. The valve may be used to divert engine exhaust gas to a first NOX trap while contemporaneously diverting reductant fluid to a second NOX trap. A method of operating a diverter valve of an emission abatement assembly is also disclosed.

Description

    CROSS REFERENCE
  • Cross reference is made to copending U.S. Utility patent application Ser. No. 10/246,118 entitled “Combination Emission Abatement Assembly and Method of Operating the Same” which was filed on Sep. 18, 2002, is assigned to the same assignee as the present application, and is hereby incorporated by reference. Cross reference is also made to copending U.S. Utility patent application Ser. No. XX/XXX,XXX entitled “Method and Apparatus for Removing NO[0001] X and Soot from Engine Exhaust Gas” (Attorney Docket No. 9501-72273, 03MRA0122) which is assigned to the same assignee as the present application, filed concurrently herewith, and hereby incorporated by reference.
  • FIELD OF THE DISCLOSURE
  • The present disclosure relates to generally to emission abatement systems, and more particularly to emission abatement systems which utilize reductant fluids to regenerate emission abatement devices. [0002]
  • BACKGROUND OF THE DISCLOSURE
  • Devices for removing NO[0003] X from the exhaust gas of an internal combustion engine may be embodied as traps for removing NOX from the exhaust gas by “trapping” the NOX as the exhaust gas advances therethrough. Such a NOX trap must be periodically regenerated to purge the trap of the trapped NOX. To do so, the NOX trap periodically undergoes a catalytic reaction in which the trapped NOX is converted to less harmful gases that are subsequently exhausted from the trap.
  • Reductant fluids may be utilized to facilitate such regeneration of the trap. Reductant fluids may take a number of different forms. For example, liquids such as untreated diesel fuel may be used as a reductant fluid. Alternatively, gases such as hydrogen gas or carbon monoxide gas may also be used as a reductant fluid. [0004]
  • One way to generate a gaseous reductant fluid is by use of an onboard fuel reformer. A fuel reformer is operated to reform a hydrocarbon fuel into a reformate gas. In the case of an onboard fuel reformer, such as a fuel reformer associated with a vehicle or a stationary power generator, the reformate gas produced by the fuel reformer may be utilized as the reductant fluid to regenerate or otherwise condition an emission abatement device associated with an internal combustion engine such as a NO[0005] X trap.
  • SUMMARY OF THE DISCLOSURE
  • According to one aspect of the present disclosure, there is provided a an emission abatement assembly. The emission abatement assembly includes a pair of NO[0006] X traps arranged in a parallel arrangement. A fuel reformer generates a reductant fluid in the form of a reformate gas which is selectively supplied one of the traps during regeneration thereof. During regeneration of the trap, engine exhaust gas is directed through the other trap. A catalyzed soot filter is positioned downstream of the NOX traps.
  • The catalyzed soot filter may be regenerated with heat from the engine exhaust gas. The catalyzed soot filter may also be regenerated with reformate gas from the fuel reformer by advancing the reformate gas into contact with an oxidation catalyst to generate heat for igniting the soot trapped in the filter. [0007]
  • The fuel reformer may be embodied as a plasma fuel reformer. [0008]
  • According to another aspect of the present disclosure, there is provided a method of operating an emission abatement assembly. The method includes the step of regenerating a first NO[0009] X trap with reformate gas from a fuel reformer while engine exhaust gas is advanced through a second NOX trap. Exhaust gas exiting the second NOX trap is then advanced through a catalyzed soot filter.
  • The method may include regenerating the catalyzed soot filter with heat from the exhaust gas. The method may also include regenerating the catalyzed soot filter by advancing reformate gas from the fuel reformer into contact with an oxidation catalyst to generate heat for igniting the soot trapped in the filter. [0010]
  • According to a further aspect of the present disclosure, there is provided a diverter valve for diverting both engine exhaust gas and a reductant fluid between a number of emission abatement devices. [0011]
  • The valve may be used to divert engine exhaust gas to a first NO[0012] X trap while contemporaneously diverting reductant fluid to a second NOX trap.
  • According to another aspect of the present disclosure, there is provided a method of operating a diverter valve of an emission abatement assembly. The method includes positioning the diverter valve between a number of different valve positions to selectively divert both engine exhaust gas and a reductant fluid between a number of different emission abatement devices. [0013]
  • The above and other features of the present disclosure will become apparent from the following description and the attached drawings.[0014]
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 is a simplified block diagram of a fuel reforming assembly having a plasma fuel reformer under the control of an electronic control unit; [0015]
  • FIG. 2 is a diagrammatic cross sectional view of the plasma fuel reformer of FIG. 1; [0016]
  • FIG. 3 is a simplified block diagram of an emission abatement assembly; [0017]
  • FIG. 4 is a fragmentary perspective view of the diverter valve of the emission abatement assembly of FIG. 3, note that a portion of the valve housing has been cutaway for clarity of description; [0018]
  • FIGS. 5 and 6 are simplified diagrammatic views of the diverter valve of FIG. 4 showing the valve in opposite valve positions; [0019]
  • FIG. 7 is a flowchart of a control routine executed by the control unit of FIG. 3 to monitor and control regeneration the NO[0020] X traps;
  • FIG. 8 is a flowchart of a control routine executed by the control unit of FIG. 3 to monitor and control regeneration of the soot filter; and [0021]
  • FIG. 9 is a view similar to FIG. 3, but showing a second embodiment of an emission abatement assembly.[0022]
  • DETAILED DESCRIPTION OF THE DRAWINGS
  • As will herein be described in more detail, a fuel reformer, according to the concepts of the present disclosure, may be utilized to regenerate or otherwise condition an emission abatement assembly having a number of different devices for treating a number of different exhaust effluents from the exhaust gas of an internal combustion engine. For example, a fuel reformer may be operated to generate and supply a reductant fluid in the form of a reformate gas to a pair of NO[0023] X traps. Reformate gas from the fuel reformer may also be utilized to regenerate a catalyzed soot filter.
  • According to additional concepts of the present disclosure, a diverter valve may be utilized to divert not only engine exhaust gas, but also reductant fluid between a number of different emission abatement devices. In such a way, the need for multiple flow valves is eliminated. [0024]
  • The fuel reformer described herein may be embodied as any type of fuel reformer such as, for example, a catalytic fuel reformer, a thermal fuel reformer, a steam fuel reformer, or any other type of partial oxidation fuel reformer. The fuel reformer of the present disclosure may also be embodied as a plasma fuel reformer. A plasma fuel reformer uses plasma to convert a mixture of air and hydrocarbon fuel into a reformate gas which is rich in, amongst other things, hydrogen gas and carbon monoxide. Systems including plasma fuel reformers are disclosed in U.S. Pat. No. 5,425,332 issued to Rabinovich et al.; U.S. Pat. No. 5,437,250 issued to Rabinovich et al.; U.S. Pat. No. 5,409,784 issued to Bromberg et al.; and U.S. Pat. No. 5,887,554 issued to Cohn, et al., the disclosures of each of which is hereby incorporated by reference. [0025]
  • For purposes of the following description, the concepts of the present disclosure will herein be described in regard to a plasma fuel reformer. However, as described above, the fuel reformer of the present disclosure may be embodied as any type of fuel reformer, and the claims attached hereto should not be interpreted to be limited to any particular type of fuel reformer unless expressly defined therein. [0026]
  • Referring now to FIGS. 1 and 2, there is shown an exemplary embodiment of a plasma [0027] fuel reforming assembly 10 of an emission abatement assembly 14. The plasma fuel reforming assembly includes a plasma fuel reformer 12 and a control unit 16. The plasma fuel reformer 12 reforms (i.e., converts) hydrocarbon fuels into a reformate gas that includes, amongst other things, hydrogen and carbon monoxide. As such, the plasma fuel reformer 12, as described further herein, may be used in the construction of an onboard fuel reforming system of a vehicle or a stationary power generator. In such a way, the reformate gas produced by the onboard plasma fuel reformer 12 may be utilized as a reductant fluid to regenerate or otherwise condition an emission abatement device associated with an internal combustion engine (e.g., a diesel engine or a gasoline engine).
  • As shown in FIG. 2, the [0028] plasma fuel reformer 12 includes a plasma-generating assembly 42 and a reactor 44. The reactor 44 includes a reactor housing 48 having a reaction chamber 50 defined therein. The plasma-generating assembly 42 is secured to an upper portion of the reactor housing 48. The plasma-generating assembly 42 includes an upper electrode 54 and a lower electrode 56. The electrodes 54, 56 are spaced apart from one another so as to define an electrode gap 58 therebetween. An insulator 60 electrically insulates the electrodes from one another.
  • The [0029] electrodes 54, 56 are electrically coupled to an electrical power supply 36 (see FIG. 1) such that, when energized, an electrical current is supplied to one of the electrodes thereby generating a plasma arc 62 across the electrode gap 58 (i.e., between the electrodes 54, 56). A fuel input mechanism such as a fuel injector 38 injects a hydrocarbon fuel 64 into the plasma arc 62. The fuel injector 38 may be any type of fuel injection mechanism which injects a desired amount of fuel into plasma-generating assembly 42. In certain configurations, it may be desirable to atomize the fuel prior to, or during, injection of the fuel into the plasma-generating assembly 42. Such fuel injector assemblies (i.e., injectors which atomize the fuel) are commercially available.
  • As shown in FIG. 2, the plasma-generating [0030] assembly 42 has an annular air chamber 72. Pressurized air is advanced into the air chamber 72 through an air inlet 74 and is thereafter directed radially inwardly through the electrode gap 58 so as to “bend” the plasma arc 62 inwardly. Such bending of the plasma arc 62 ensures that the injected fuel 64 is directed through the plasma arc 62. Such bending of the plasma arc 62 also reduces erosion of the electrodes 56, 58. Moreover, advancement of air into the electrode gap 58 also produces a desired mixture of air and fuel (“air/fuel mixture”). In particular, the plasma reformer 12 reforms or otherwise processes the fuel in the form of a mixture of air and fuel. The air-to-fuel ratio of the air/fuel mixture being reformed by the fuel reformer is controlled via control of the fuel injector 38 and an air inlet valve 40. The air inlet valve 40 may be embodied as any type of electronically-controlled air valve. The air inlet valve 40 may be embodied as a discrete device, as shown in FIG. 2, or may be integrated into the design of the plasma fuel reformer 12. In either case, the air inlet valve 40 controls the amount of air that is introduced into the plasma-generating assembly 42 thereby controlling the air-to-fuel ratio of the air/fuel mixture being processed by the plasma fuel reformer 12.
  • The [0031] lower electrode 56 extends downwardly into the reactor housing 48. As such, gas (either reformed or partially reformed) exiting the plasma arc 62 is advanced into the reaction chamber 50. A catalyst 78 may be positioned in the reaction chamber 50. The catalyst 78 completes the fuel reforming process, or otherwise treats the gas, prior to exit of the reformate gas through a gas outlet 76. In particular, some or all of the gas exiting the plasma-generating assembly 42 may only be partially reformed, and the catalyst 78 is configured to complete the reforming process (i.e., catalyze a reaction which completes the reforming process of the partially reformed gas exiting the plasma-generating assembly 42). The catalyst 78 may be embodied as any type of catalyst that is configured to catalyze such reactions. In one exemplary embodiment, the catalyst 78 is embodied as substrate having a precious metal or other type of catalytic material disposed thereon. Such a substrate may be constructed of ceramic, metal, or other suitable material. The catalytic material may be, for example, embodied as platinum, rhodium, palladium, including combinations thereof, along with any other similar catalytic materials. The plasma fuel reformer 12 may be embodied without the catalyst 78.
  • As shown in FIG. 2, the [0032] plasma fuel reformer 12 has a temperature sensor 34 associated therewith. The temperature sensor 34 is used as a feedback mechanism to determine the temperature of a desired structure of the plasma fuel reformer 12 or the gas advancing therethrough. For example, the temperature sensor 34 may be used to measure the temperature of the reformate gas being produced by the plasma fuel reformer 12, the ambient temperature within the reaction chamber 50, the temperature of the catalyst 78, etcetera. The temperature sensor 34 may be located in any number of locations. In particular, as shown in solid lines, the temperature sensor 34 may be positioned within the reaction chamber 50 at location in operative contact with the a structure (e.g., the catalyst 78 or the walls of the reaction chamber 50) or a substance (e.g., the gas in the reaction chamber 50). To do so, the temperature sensor 34 may be positioned in physical contact with the structure or substance, or may be positioned a predetermined distance away from the structure or out of the flow of the substance, depending on the type and configuration of the temperature sensor. In such a way, the temperature sensor 34 may function as a feedback mechanism for controlling operation of the plasma fuel reformer 12.
  • As shown in FIG. 1, the [0033] plasma fuel reformer 12 and its associated components are under the control of the control unit 16. In particular, the temperature sensor 34 is electrically coupled to the electronic control unit 16 via a signal line 18, the fuel injector 38 is electrically coupled to the electronic control unit 16 via a signal line 20, the air inlet valve 40 is electrically coupled to the electronic control unit 16 via a signal line 22, and the power supply 36 is electrically coupled to the electronic control unit 16 via a signal line 24. Moreover, as will herein be described in greater detail, a number of other components associated with the emission abatement assembly 14 may also be under the control of the control unit 16, and, as a result, electrically coupled thereto. For example, a flow diverter valve 88 for selectively diverting an exhaust gas flow from an internal combustion engine and a flow of reformate gas from the plasma fuel reformer 12 between any number of components may be under the control of the control unit 16. A number of sensors such as NOX sensors and pressure sensors associated with the emission abatement assembly 14 are also electrically coupled to the control unit 16.
  • Although the signal lines [0034] 18, 20, 22, 24 (and any of the signal lines used to couple other devices associated with the emission abatement assembly 14 to the control unit) are shown schematically as a single line, it should be appreciated that the signal lines may be configured as any type of signal carrying assembly which allows for the transmission of electrical signals in either one or both directions between the electronic control unit 16 and the corresponding component. For example, any one or more of the signal lines 18, 20, 22, 24 (or any other signal line disclosed herein) may be embodied as a wiring harness having a number of signal lines which transmit electrical signals between the electronic control unit 16 and the corresponding component. It should be appreciated that any number of other wiring configurations may also be used. For example, individual signal wires may be used, or a system utilizing a signal multiplexer may be used for the design of any one or more of the signal lines 18, 20, 22, 24 (or any other signal line). Moreover, the signal lines 18, 20, 22, 24 may be integrated such that a single harness or system is utilized to electrically couple some or all of the components associated with the plasma fuel reformer 12 to the electronic control unit 16.
  • The [0035] electronic control unit 16 is, in essence, the master computer responsible for interpreting electrical signals sent by sensors associated with the plasma fuel reformer 12 and for activating electronically-controlled components associated with the plasma fuel reformer 12 in order to control the plasma fuel reformer 12, the flow of reformate gas exiting therefrom, and an exhaust gas flow from an internal combustion engine. For example, the electronic control unit 16 of the present disclosure is operable to, amongst many other things, determine the beginning and end of each injection cycle of fuel into the plasma-generating assembly 42, calculate and control the amount and ratio of air and fuel to be introduced into the plasma-generating assembly 42, determine the temperature of the reformer 12 or the reformate gas, determine the power level to supply to the plasma fuel reformer 12, and determine which component (e.g., a NOX trap or a soot filter) to regenerate.
  • To do so, the [0036] electronic control unit 16 includes a number of electronic components commonly associated with electronic units which are utilized in the control of electromechanical systems. For example, the electronic control unit 16 may include, amongst other components customarily included in such devices, a processor such as a microprocessor 28 and a memory device 30 such as a programmable read-only memory device (“PROM”) including erasable PROM's (EPROM's or EEPROM's). The memory device 30 is configured to store, amongst other things, instructions in the form of, for example, a software routine (or routines) which, when executed by the processor 28, allows the electronic control unit 16 to control operation of the plasma fuel reformer 12 and other devices associated with the emission abatement assembly 14.
  • The [0037] electronic control unit 16 also includes an analog interface circuit 32. The analog interface circuit 32 converts the output signals from the various fuel reformer sensors (e.g., the temperature sensor 34) or other sensors associated with the with the emission abatement assembly (e.g., the NOX sensor and the pressure sensors) into a signal which is suitable for presentation to an input of the microprocessor 28. In particular, the analog interface circuit 32, by use of an analog-to-digital (A/D) converter (not shown) or the like, converts the analog signals generated by the sensors into a digital signal for use by the microprocessor 28. It should be appreciated that the A/D converter may be embodied as a discrete device or number of devices, or may be integrated into the microprocessor 28. It should also be appreciated that if any one or more of the sensors associated with the plasma fuel reformer 12 or the emission abatement assembly 14 generate a digital output signal, the analog interface circuit 32 may be bypassed.
  • Similarly, the [0038] analog interface circuit 32 converts signals from the microprocessor 28 into an output signal which is suitable for presentation to the electrically-controlled components associated with the plasma fuel reformer 12 (e.g., the fuel injector 38, the air inlet valve 40, the power supply 36), or other system components associated with the emission abatement assembly 14 (e.g., the diverter valve 88). In particular, the analog interface circuit 32, by use of a digital-to-analog (D/A) converter (not shown) or the like, converts the digital signals generated by the microprocessor 28 into analog signals for use by the electronically-controlled components associated with the fuel reformer 12 and the emission abatement assembly 14. It should be appreciated that, similar to the A/D converter described above, the D/A converter may be embodied as a discrete device or number of devices, or may be integrated into the microprocessor 28. It should also be appreciated that if any one or more of the electronically-controlled components associated with the plasma fuel reformer 12 or the emission abatement assembly 14 operate on a digital input signal, the analog interface circuit 32 may be bypassed.
  • Hence, the [0039] electronic control unit 16 may be operated to control operation of the plasma fuel reformer 12, and components associated therewith, and the components associated with the emission abatement assembly 14. In particular, the electronic control unit 16 executes a routine including, amongst other things, a closed-loop control scheme in which the electronic control unit 16 monitors the outputs from a number of sensors in order to control the inputs to the electronically-controlled components associated therewith. To do so, the electronic control unit 16 communicates with the sensors associated with the fuel reformer 12 and the emission abatement assembly 14 to determine, amongst numerous other things, the amount, temperature, and/or pressure of air and/or fuel being supplied to the plasma fuel reformer 12, the amount of hydrogen and/or oxygen in the reformate gas, the temperature of the reformer or the reformate gas, the composition of the reformate gas, the accumulation level within an emission abatement device (e.g., a NOX trap or soot filter), etcetera. Armed with this data, the electronic control unit 16 performs numerous calculations each second, including looking up values in preprogrammed tables, in order to execute algorithms to perform such functions as determining when or how long the fuel reformer's fuel injector or other fuel input device is opened, controlling the power level input to the fuel reformer, controlling the amount of air advanced through air inlet valve, controlling the position of a flow diverter valve responsible for directing the flow of reformate gas and exhaust gas to one component or the other, determining the quantity and/or composition of reformate gas to generate and deliver to a particular component, etcetera.
  • Referring now to FIG. 3, there is shown the [0040] emission abatement assembly 14 in greater detail. The emission abatement assembly 14 includes a pair of NOX traps 84, 86 for removing and treating NOX present in the exhaust gas from an internal combustion engine 82 such as a diesel engine, a gasoline engine, a gasoline direct injection (GDI) engine, or natural gas engine. The NOX traps 84, 86 are arranged in a parallel relationship with one another. As such, for purposes of clarity of description, the NOX trap 84 will herein be referred to as the right NOX trap, whereas the NOX trap 86 will herein be referred to as the left NOX trap. However, such use of directional terms (i.e., right and left) is not intended to infer any particular orientation, but rather is only used herein only for ease of description.
  • The NO[0041] X traps 84, 86 may be any type of commercially available NOX trap, including a lean NOX trap, which facilitates the trapping and removal of NOX in the lean conditions associated with exhaust gases from diesel engines, GDI engines, or natural gas engines. Specific examples of NOX traps which may be used as the NOX traps 84, 86 of the present disclosure include, but are not limited to, NOX traps commercially available from, or NOX traps constructed with materials commercially available from, EmeraChem, LLC of Knoxville, Tenn. (formerly known as Goal Line Environmental Technologies, LLC of Knoxville, Tenn.).
  • The [0042] emission abatement assembly 14 also includes an oxidation catalyst 94 and a catalyzed soot filter 96. The catalyst 94 may be embodied as any type of catalyst that is configured to catalyze oxidation reactions in an exhaust gas stream. In one exemplary embodiment, the catalyst 94 is embodied as substrate having a precious metal or other type of catalytic material disposed thereon. Such a substrate may be constructed of ceramic, metal, or other suitable material. The catalytic material may be, for example, embodied as platinum, rhodium, palladium, including combinations thereof, along with any other similar catalytic materials. When positioned downstream of the NOX traps 84, 86, the catalyst 94 may function to clean up any hydrogen or hydrocarbon “slip” from the NOX traps 84, 86. For example, the oxidation catalyst 94 may be used to oxidize any H2, certain hydrocarbons, or H2S that may be present in the gases exiting the traps 84, 86. Moreover, as will be discussed herein in greater detail, when positioned upstream of the soot filter 96, the catalyst 94 may be utilized during assisted regeneration of soot filter 96.
  • The [0043] soot filter 96 may be embodied as any type of commercially available particulate filter. For example, the soot particulate filter may be embodied as any known exhaust particulate filter such as a “deep bed” or “wall flow” filter. Deep bed filters may be embodied as metallic mesh filters, metallic or ceramic foam filters, ceramic fiber mesh filters, and the like. Wall flow filters, on the other hand, may be embodied as a cordierite or silicon carbide ceramic filter with alternating channels plugged at the front and rear of the filter thereby forcing the gas advancing therethrough into one channel, through the walls, and out another channel.
  • The [0044] soot filter 96 is impregnated with a catalytic material. The catalytic material may be, for example, embodied as platinum, rhodium, palladium, including combinations thereof, along with any other similar catalytic materials. By use of catalytic material, the temperature at which soot particles trapped in the filter combust is lowered such that regeneration of the soot filter 96 may occur in the presence of the heat of the engine exhaust gas. However, as will be discussed in greater detail herein, if the soot accumulation level within the soot filter 96 reaches a predetermined level (i.e., regeneration based on exhaust gas heat alone is not sufficient to clear the filter), reformate gas from the fuel reformer 12 may be used to regenerate the filter.
  • As shown in FIG. 3, a [0045] diverter valve 88 selectively diverts the flow of exhausts gas from the engine 82 between the traps 84, 86. In particular, the diverter valve 88 may be operated to divert a flow of exhaust gas from the engine 82 between a right flow path 102 and a left flow path 104. The right NOX trap 84 is positioned in the right flow path 102 such that exhaust gas or reformate gas advancing through the right flow path 102 is advanced through the right NOX trap 84. The left NOX trap 86 is positioned in the left flow path 104 such that exhaust gas or reformate gas advancing through the left flow path 104 is advanced through the left NOX trap 86.
  • As also shown in FIG. 3, the [0046] right flow path 102 and the left flow path 104 are recombined by a flow coupler 106. The flow coupler 106 is positioned downstream of the NOX traps 84, 86 and upstream of oxidation catalyst 94 and the soot filter 96. As a result, gas exiting the NOX traps 84, 86 is directed through both the oxidation catalyst 94 and the soot filter 96.
  • In the exemplary embodiment described herein, a number of fluid lines such as pipes, tubes, or the like are utilized to create the various flow paths. In particular, an [0047] exhaust gas inlet 108 of the diverter valve 88 is fluidly coupled to an exhaust manifold 110 of the engine 82 via a fluid line 112. A right outlet 114 of the diverter valve 88 is fluidly coupled to an inlet 116 of the right NOX trap 84 via a fluid line 118, whereas a left outlet 120 of the diverter valve 88 is fluidly coupled to an inlet 122 of the left NOX trap 86 via a fluid line 124. An outlet 126 of the right NOX trap 84 is fluidly coupled to the flow coupler 106 via a fluid line 128, whereas an outlet 130 of the left NOX trap 86 is fluidly coupled to the flow coupler 106 via the fluid line 132. A fluid line 134 fluidly couples the flow coupler 106 to an inlet 136 of the oxidation catalyst 94. An outlet 138 of the oxidation catalyst 94 is fluidly coupled to an inlet 140 of the soot filter 96 via a fluid line 142. Via a fluid line 144, an outlet 146 of the soot filter 96 is either open to the atmosphere or coupled to an additional exhaust system component (not shown) positioned downstream of the soot filter 96.
  • In such a configuration, exhaust gas from the [0048] engine 82 may be routed through the emission abatement assembly 14 to remove, amongst other things, NOX and soot therefrom. To do so, exhaust gas may be selectively routed between the two NOX traps 84, 86 to allow for both treatment of the exhaust gas and trap regeneration. For example, exhaust gas may be routed through the right NOX trap 84 while the left NOX trap 86 is maintained “offline.” While offline, the left NOX trap 86 may undergo regeneration. In such a case, exhaust gas is advanced along a fluid path which includes the fluid line 112 from the exhaust manifold 110, the diverter valve 88, the fluid line 118 to the right NOX trap 84, through the trap 84 and the fluid line 128 to the flow coupler 106, the fluid line 134 to the oxidation catalyst 94, through the catalyst 94 and the fluid line 142 to the soot filter 96, through the soot filter 96 and out the fluid line 144.
  • Once the left NO[0049] X trap 86 has been regenerated, the position of the diverter valve 88 may be switched such that exhaust gas from the engine 82 is routed through the left NOX trap 86 while the right NOX trap 84 is offline for regeneration. In this case, exhaust gas is advanced along a fluid path which includes the fluid line 112 from the exhaust manifold 110, the diverter valve 88, the fluid line 124 to the left NOX trap 86, through the trap 86 and the fluid line 132 to the flow coupler 106, the fluid line 134 to the oxidation catalyst 94, through the catalyst 94 and the fluid line 142 to the soot filter 96, through the soot filter 96 and out the fluid line 144.
  • As will be discussed herein in greater detail, in addition to diverting exhaust gas from the [0050] engine 82 to the appropriate NOX trap 84, 86, the diverter valve 88 is also configured to divert reformate gas from the fuel reformer 12 to the appropriate NOX trap 84, 86. In particular, the outlet 76 (see FIG. 2) of the fuel reformer 12 is fluidly coupled to a reductant fluid inlet 148 of the diverter valve 88 via a fluid line 150. The diverter valve 88 diverts reformate gas from the fuel reformer 12 to the offline NOX trap 84, 86. In particular, as described above, engine exhaust gas is routed by the diverter valve 88 through one of the traps 84, 86 while the other trap is maintained offline for regeneration. The diverter valve 88 routes engine exhaust gas through one of the traps 84, 86, while routing reformate gas from the fuel reformer 12 through the other trap 84, 86.
  • The [0051] diverter valve 88 is electrically coupled to the electronic control unit 16 via a signal line 152. As such, the position of the diverter valve 88 is under the control of the electronic control unit 16. Hence, the electronic control unit 16, amongst its other functions, selectively directs the flow of exhaust gas from the engine 82 and the flow of reformate gas from the fuel reformer 12 to either the right NOX trap 84 or the left NOX trap 86, or a combination of both traps 84, 86.
  • The control scheme for controlling the position of the [0052] diverter valve 88 may be designed in a number of different manners. For example, a sensor-based control scheme may be utilized. In such a case, the position of the diverter valve 88 is changed as a function of output from one or more sensors associated with the NOX traps 84, 86. For instance, regeneration of one of the NOX traps 84, 86 may commence when the output from a NOX sensor 154 is indicative of a predetermined NOX accumulation level within the online trap. More specifically, the NOX sensor 154 is positioned to sense the NOX content of exhaust gas passing through the fluid line 134. In such a downstream position relative to the NOX traps 84, 86, the sensor 154 may be used to monitor the NOX accumulation level of the NOX trap 84, 86 through which engine exhaust gas is being routed. As such, when the output from the NOX sensor 154 indicates that a particular NOX trap 84, 86 is in need of regeneration, the control unit 16 takes the trap 84, 86 in need of regeneration offline, and brings the other trap 84, 86 online in the manner described above.
  • Alternatively, a timing-based control scheme may be utilized in which the position of the [0053] diverter valve 88 is changed as a function of time. For instance, regeneration of the traps 84, 86 may be performed at predetermined timed intervals. In such a case, the NOX sensor 154 may be all together eliminated, or used merely as a “failsafe” to ensure that regeneration is not prematurely needed during a timed interval.
  • Moreover, an engine-mapped control scheme may be utilized in which the position of the [0054] diverter valve 88 is changed as a function of engine load over time. In particular, an engine map may be created which allows the control unit 16 to track the amount of NOX which has been created by the engine 82 based on engine load conditions. When the control unit 16 determines that the engine 82 has generated a predetermined amount of NOX, with such an amount being trapped in the online trap 84, 86, the control unit 16 swaps the position of the diverter valve 88 thereby taking the trap offline for regeneration and routing exhaust gas through the other trap. As with the timing-based control scheme, the NOX sensor 154 may be all together eliminated from this control scheme, or used merely as a “failsafe” to ensure that regeneration is not prematurely needed during a mapped interval.
  • In regard to regeneration of the [0055] soot filter 96, use of a catalyzed filter allows for regeneration of the soot filter 96 to be performed primarily as a result of the introduction of heat from the engine's exhaust gas onto the filter 96. In other words, soot trapped in the soot filter 96 will be constantly ignited or otherwise purged from the filter 96 during operation of the engine.
  • However, in certain circumstances, the [0056] soot filter 96 may become impregnated with an amount of soot that cannot be removed by use of engine heat alone. For example, if the engine operating conditions were to cause an abnormally large amount of soot to be generated (and hence trapped by the filter 96), the soot filter 96 may not be able to completely purge the soot by use of exhaust gas heat alone. Moreover, if the engine 82 is operated in sustained transient conditions (e.g., startup, idle, etcetera), exhaust gas temperatures will be lowered thereby reducing regeneration efficiency of the soot filter 96. In such cases, or any other case in which the soot filter 96 becomes impregnated with an amount of soot that cannot be removed by use of exhaust gas heat alone, reformate gas from the fuel reformer 12 may be used to assist in regeneration of the filter 96.
  • Specifically, a quantity of reformate gas from the [0057] plasma fuel reformer 12 may be advanced into contact with the oxidation catalyst 94 to catalyze an oxidation reaction between the oxygen in the exhaust gas of the engine 82 and the reformate gas. Specifically, when the reformate gas is advanced into contact with the oxidation catalyst 94 in the presence of exhaust gas, the oxidation catalyst 94 catalyzes an oxidation reaction which converts the hydrogen gas present in the reformate gas and the oxygen present in the exhaust gases into, amongst other things, water. Moreover, the catalyst catalyzes an oxidation reaction which converts the carbon monoxide present in the reformate gas and the oxygen present in the exhaust gases into carbon dioxide. Both of these oxidation reactions are highly exothermic, and, as a result, produce heat that is transferred to the downstream-positioned soot filter 96. The heat, which may illustratively be in the range of 600-650 degrees Celsius, ignites and burns soot particles trapped in the particulate filter 96 thereby regenerating the filter 96.
  • It should be appreciated that such assisted regeneration of the [0058] soot filter 96 may be self-sustaining once initiated by heat from the exothermic reaction catalyzed by the oxidation catalyst 94. Specifically, once the soot filter 96 is heated to a temperature at which the soot particles trapped therein begin to ignite, the ignition of an initial portion of soot particles trapped therein can cause the ignition of the remaining soot particles much in the same way a cigar slowly burns from one end to the other. In essence, as the soot particles “burn,” an amount of heat is released in the “burn zone.” Locally, the soot layer (in the burn zone) is now much hotter than the immediate surroundings. As such, heat is transferred to the as yet un-ignited soot layer downstream of the burn zone. The energy transferred may be sufficient to initiate oxidation reactions that raise the un-ignited soot to a temperature above its ignition temperature. As a result of this, heat from the oxidation catalyst 94 may only be required to commence the regeneration process of the soot filter 96 (i.e., begin the ignition process of the soot particles trapped therein).
  • Moreover, since the [0059] soot filter 96 is impregnated on the surfaces thereof with a catalytic material such as, for example, a precious metal catalytic material, the ignition temperature of the soot particles trapped in the filter 96 is reduced. Indeed, depending on, amongst other things, the amount of catalytic material disposed on the filter 96 and the amount of accumulated soot particles, the ignition temperature of the soot particles may be lowered to an ignition temperature of between 300-600 degrees Celsius. In other exemplary implementations, the soot ignition temperature may be lowered to a temperature in the range of 300-550 degrees Celsius, more particularly in the range of 300-450 degrees Celsius, and even more particularly in the range of 300-350 degrees Celsius.
  • Soot particulate filters functioning in such a manner are described in copending, commonly assigned U.S. Provisional Patent Application Serial No. 60/375,134 entitled “Apparatus and Method for Regenerating a Particulate Filter of an Exhaust System of an Internal Combustion Engine” filed on Apr. 24, 2002 by Rudolf M. Smaling. The entirety of this provisional patent application (i.e., Serial No. 60/375,134) is hereby incorporated by reference. [0060]
  • As shown in FIG. 3, the [0061] electronic control unit 16 is also electrically coupled to a pair of pressure sensors 156, 158 via a pair of signal lines 160, 162, respectively. The pressure sensors 156, 158 may be utilized to determine when the soot filter 96 is in need of regeneration assistance from the fuel reformer 12. In particular, the pressure sensors 156, 158 sense the pressure difference across the soot filter 96 in order to determine the soot accumulation level in the soot filter 96. Specifically, when the pressure drop across the soot filter 96 increases to a predetermined value, the electronic control unit 16 determines that the filter 96 is in need of regeneration and commences the assisted filter regeneration process. In lieu of such a dual sensor arrangement, a single pressure sensor on either side of soot filter 96 may be utilized, if desired. In such a configuration, the electronic control unit 16 would monitor when the pressure sensed by the single pressure sensor exceeded a predetermined upper threshold or was below a predetermined lower threshold, as opposed to monitoring the pressure drop across the soot filter 96. In any of these sensor configurations, when sensor output indicates that the soot filter 96 is in need of regeneration, the control unit 16 operates the fuel reformer 12 so as to generate a flow of reformate gas which is directed into contact with the oxidation catalyst 94 thereby commencing the assisted regeneration process described above.
  • It should be appreciated that the reformate gas may be advanced to the [0062] oxidation catalyst 94 via the NOX traps 84, 86 in a number of different manners. For example, the control unit 16 may operate the diverter valve 88 to divert reformate gas through a recently regenerated NOX trap 84, 86 thereby causing a predetermined portion of the reformate gas to pass through the NOX trap to the oxidation catalyst 94 without being “consumed” by the trap. As such, assisted regeneration of the soot filter 96 may be tied to regeneration of one of the NOX traps 84, 86. For example, if the soot filter 96 is in need of regeneration, the next regeneration cycle of one of the NOX traps 84, 86 may be extended. In other words, reformate gas from the fuel reformer 12 may continue to be advanced through the NOX trap even after the trap has been sufficiently regenerated thereby allowing amounts of reformate gas to reach the oxidation catalyst 94.
  • Reformate gas from the [0063] fuel reformer 12 may also be advanced to the oxidation catalyst 94 via a fluid line (not shown) which bypasses the NOX traps. In particular, a fluid line (not shown) may be coupled at one end to the outlet 76 of the fuel reformer 12 and at the other end to the fluid line 134 at a position upstream of the oxidation catalyst 94. A diverter valve (not shown) may be used to selectively direct reformate gas through either such a bypass line or through the fluid line 150 to the diverter valve 88 and hence the NOX traps 84, 86.
  • It should be appreciated that other assisted filter regeneration schemes utilizing reformate gas from the [0064] fuel reformer 12 are also contemplated. For example, the soot filter 96 may be regenerated with heat generated in the fuel reformer 12 by increasing the air-to-fuel ratio of the air/fuel mixture being processed by the fuel reformer 12 (e.g., using an air/fuel mixture having an oxygen-to-carbon ratio between 1.4-4.0, instead of typical 1.0 to 1.4). Such operation will convert some or all of the H2 and CO in the reformate gas into heat at the reformer 12. This heat may then be carried through the system to the soot filter 96 to commence the regeneration process in a similar manner to as described above when commencement of the filter regeneration process is facilitated by heat from the oxidation catalyst. Such lean operation of the fuel reformer 12 may also be used to temporarily heat the NOX traps 84, 86 to their de-sulfurization temperature (e.g., 600 degrees Celsius). As such, a scheme may be utilized in which heat from the fuel reformer 12 is used to both de-sulfurize the NOX traps 84, 86 and regenerate the soot filter 96.
  • It should also be appreciated that a pair of temperature sensors (not shown) may also be used on each side of the [0065] soot filter 96. In particular, the temperature sensors may be used to sense the temperature at the inlet 140 and outlet 146 of the soot filter 96 thereby allowing for the temperature of the exhaust gas entering and/or exiting the soot filter 96 to be determined. Such temperature readings may be used as a feedback mechanism to the control unit 16 to monitor regeneration of the filter 96. In particular, as described above, filter regeneration may be self-sustaining after being commenced by reformate gas from the fuel reformer 12. A temperature reading taken near the outlet 146 of the soot filter 96 may be used to ensure that combustion of the soot particles within the trap is being self-sustained in such a manner.
  • Referring now to FIGS. [0066] 4-6, there is shown the diverter valve 88 in greater detail. The diverter valve 88 includes a valve housing 164 having a valve chamber 166 defined therein. Note that in FIG. 4, all but a small portion of the top plate 172 of the valve housing 164 has been cut away for clarity of view into the valve chamber 166.
  • The [0067] exhaust gas inlet 108, the reductant fluid inlet 148, the right outlet 114, and the left outlet 120 are also defined in the valve housing 164. Although each of the inlets and outlets associated with the diverter valve 88 are exemplary embodied as an orifice defined in the walls of the valve housing 164, it should be appreciated that any or all of such inlets and outlets may, alternatively, be embodied to include a tube, coupling assembly, or other structure which extends through the wall of the housing 164.
  • The fluid lines [0068] 112, 118, 124, and 150 are secured to the valve housing 164 such that fluids conducted therein may be advanced into or out of the valve chamber 166 thereby fluidly coupling the valve chamber 166 to a particular component. In particular, as shown in FIG. 4, one end of the fluid line 112 (shown as a pipe in FIG. 4) extends through the exhaust gas inlet 108 of the valve housing 164 thereby fluidly coupling the valve chamber 166 to the exhaust manifold 110 of the engine 82. An end of the fluid line 118 (shown as a pipe in FIG. 4) extends through the right outlet 114 of the valve housing 164 thereby fluidly coupling the valve chamber 166 to the inlet 116 of the right NOX trap 84, whereas one end of the fluid line 124 (shown as a pipe in FIG. 4) extends through the left outlet 120 of the valve housing 164 thereby fluidly coupling the valve chamber 166 to the inlet 122 of the left NOX trap 86. An end of the fluid line 150 (shown as a pipe in FIG. 4) extends through the reductant fluid inlet 148 of the valve housing 164 thereby fluidly coupling the valve chamber 166 to the outlet 76 of the fuel reformer 12.
  • A [0069] valve member 168 in the form of a movable plate or “flap” is positioned in the valve chamber 166. The flap 168 is movable between a number of valve positions to selectively divert both exhaust gas from the engine 82 and reformate gas from the fuel reformer 12 to either one of the NOX traps 84, 86. Specifically, the flap 168 is positionable to direct engine exhaust gas to one of the NOX traps 84, 86 (i.e., the “online” trap) while directing reformate gas from the fuel reformer 12 to the other NOX trap 84, 86 (i.e., the “offline” trap).
  • For example, when positioned in the valve position shown in FIG. 5, the [0070] flap 168 diverts engine exhaust gas to the right NOX trap 84, while also diverting reformate gas from the fuel reformer 12 to the left NOX trap 86. Specifically, when positioned in the valve position of FIG. 5, the flap 168 fluidly couples the exhaust gas inlet 108 to the right outlet 114, but fluidly isolates the exhaust gas inlet 108 from the left outlet 120. When positioned in the valve position of FIG. 5, the flap 168 also fluidly couples the reductant fluid inlet 148 to the left outlet 120, but fluidly isolates the reductant fluid inlet 148 from the right outlet 114.
  • Conversely, when positioned in the valve position shown in FIG. 6, the [0071] flap 168 diverts engine exhaust gas to the left NOX trap 86, while also diverting reformate gas from the fuel reformer 12 to the right NOX trap 84. Specifically, when positioned in the valve position of FIG. 6, the flap 168 fluidly couples the exhaust gas inlet 108 to the left outlet 120, but fluidly isolates the exhaust gas inlet 108 from the right outlet 114. When positioned in the valve position of FIG. 6, the flap 168 also fluidly couples the reductant fluid inlet 148 to the right outlet 114, but fluidly isolates the reductant fluid inlet 148 from the left outlet 120.
  • The [0072] diverter valve 88 also includes a valve actuator 170 which, as alluded to above, is electrically coupled to the control unit 16 via the signal line 152. As such, the position of the diverter valve 88 is under the control of the control unit 16. As a result, the control unit 16, amongst its other functions, may selectively direct the flow of exhaust gas from the engine 82 and reformate gas from the plasma fuel reformer 12 to either the right NOX trap 84 or the left NOX trap 86. Specifically, the control unit 16 may generate control signals on the signal line 152 which cause the valve actuator 170 to selectively position the flap 168 in either the valve position of FIG. 5 or the valve position of FIG. 6. The valve actuator 170 may be embodied as any type of electrically-controlled actuator for moving the flap 168 in such a manner. For example, the valve actuator may be embodied as a linear solenoid or a stepper motor.
  • It should be appreciated that although the [0073] diverter valve 88 is herein described as a two position valve in which the flow of engine exhaust gas is completely interrupted to the offline trap 84, 86 and the flow of reformate gas is completely interrupted to the online trap, other control configurations of the diverter valve 88 are also contemplated. For example, a variable flow configuration is also contemplated in which a desired amount of engine exhaust gas may be directed through the offline trap 84, 86 and/or a desired amount of reformate gas may be directed through the online trap 84, 86. While such a configuration may not be particularly useful during regeneration of the NOX trap since it is usually desirable to have little to no flow of exhaust gas through the trap, such a configuration may be useful in the case of the aforedescribed assisted regeneration of the soot filter 96 since it may be desirable to have some degree of a flow of exhaust gases through the soot filter during regeneration thereof. In particular, during performance of the aforedescribed assisted filter regeneration scheme, it may be desirable to put a controlled flow of exhaust gas through the oxidation catalyst 94 to supply sufficient amounts of oxygen to sustain the oxidation reactions at the face of the catalyst 94 and to provide sufficient amounts of oxygen to burn the soot in the soot filter 96 with the heat generated by the catalyst 94.
  • The components of the [0074] diverter valve 88 may be constructed with any type of material suitable for withstanding the operating conditions to which the valve 88 is subjected. For example, the components of the diverter valve 88 may be constructed with any of the 300-series or 400-series stainless steels. In a specific implementation, the components of the diverter valve 88 may be constructed with either “304” stainless steel or “409” stainless steel. The components of the diverter valve 88 may also be constructed with other materials such as ceramic coated metals or the like.
  • Referring now to FIG. 7, there is shown a [0075] control routine 200 for controlling operation of the NOX traps during operation of the engine 14. The control routine 200 begins with step 202 in which the control unit 16 determines the NOX accumulation level in the online NOX trap 84, 86. As described above, the NOX accumulation in the online NOX trap 84, 86 may be determined in a number of different manners. For example, the NOX sensor 154 may be utilized in which case the control unit 16 scans or otherwise reads the signal line coupling the sensor 154 to the control unit 16 to monitor output from the sensor 154. As described above, the output signals produced by the NOX sensor 154 are indicative of the NOX accumulation level of the online NOX trap 84, 86. Alternatively, the control unit 16 may determine the NOX accumulation level of the online NOX trap by determining the amount of time which has elapsed since the NOX trap was last regenerated. Moreover, the control unit 16 may also determine the accumulation level of the online trap by use of an engine-map technique. In any case, once the control unit 16 has determined the NOX accumulation level of the online NOX trap 84, 86, the control routine 200 advances to step 204.
  • In [0076] step 204, the control unit 16 determines if the NOX accumulation level within the online NOX trap 84, 86 necessitates regeneration of the trap. In particular, a predetermined accumulation level or “set point” may be established at which point the NOX trap is in need of regeneration. As such, in step 204, the control unit 16 determines if the NOX accumulation level of the online NOX trap equals or exceeds the set point. If the NOX accumulation level within the online NOX trap is below the set point, the control routine 200 loops back to step 202 to continue monitoring the NOX accumulation level within the online NOX trap 84, 86. However, if the NOX accumulation level within the online NOX trap 84, 86 is greater than or equal to the set point, a control signal is generated, and the control routine 200 advances to step 206.
  • In [0077] step 206, the control unit 16 redirects engine exhaust gas to the offline NOX trap 84, 86. In particular, the control unit 16 generates an output signal on the signal line 152 thereby causing the valve actuator 170 to move the diverter valve 88 from its current valve position to the opposite valve position. Such movement of the diverter valve 88 swaps the online/offline status of the NOX traps 84, 86. For example, if the right NOX trap 84 is online (and determined to be saturated beyond the set point in step 204), the control unit 16 generates an output signal on the signal line 152 which causes the diverter valve 88 to be moved from the valve position shown in FIG. 5 to the valve position shown in FIG. 6. Conversely, if the left NOX trap 86 is online (and determined to be saturated beyond the set point in step 204), the control unit 16 generates an output signal on the signal line 152 which causes the diverter valve 88 to be moved from the valve position shown in FIG. 6 to the valve position shown in FIG. 5. Once the position of the diverter valve 88 has been switched in such a manner, engine exhaust gas will be directed to the newly online NOX trap. The control routine 200 then advances to step 208.
  • In [0078] step 208, the control unit 16 regenerates the newly offline NOX trap 84, 86 (i.e., the NOX trap determined to be saturated beyond the set point in step 204). In particular, the control unit 16 commences operation of the fuel reformer 12 so as to generate reformate gas therewith. The reformate gas exiting the fuel reformer 12 is then advanced to the diverter valve 88 where, based on the valve's repositioning in step 206, the reformate gas is directed to the offline NOX trap. For example, if in step 206 the diverter valve 88 is positioned by the control unit 16 into the valve position shown in FIG. 5, reformate gas from the fuel reformer 12 is advanced to the left NOX trap 86. Conversely, if in step 206 the diverter valve 88 is positioned by the control unit 16 into the valve position shown in FIG. 6, reformate gas from the fuel reformer 12 is advanced to the right NOX trap 84. As such, reformate gas from the fuel reformer 12 is used to regenerate the offline NOX trap. The control routine 200 then loops back to step 202 to commence monitoring of the online NOX trap.
  • As described above, exhaust gas exiting the online NO[0079] X trap 84, 86 is directed through the oxidation catalyst 94 and thereafter the catalyzed soot filter 96. As a result, any “slip” from the NOX traps 84, 86 (e.g., hydrogen, hydrocarbons, or H2S) is oxidized by the oxidation catalyst 94. Moreover, soot particles in the exhaust gas exiting the NOX traps 84, 86 are trapped in the soot filter 96. As described above, by use of a catalyzed filter, regeneration of the soot filter 96 will by in large be sustained by the introduction of heat from the engine's exhaust gas. In other words, soot trapped on the soot filter 96 will be constantly ignited or otherwise purged from the filter 96 during operation of the engine. However, in certain circumstances, the soot filter 96 may become impregnated with an amount of soot that cannot be removed by use of engine heat alone.
  • To monitor for such situations, the [0080] control unit 16 executes a control routine 300, as shown in FIG. 8. The control routine 300 is executed contemporaneously with the control routine 200 of FIG. 7. The routine 300 begins with step 302 in which the control unit 16 determines the soot accumulation level in the soot filter 96. Specifically, the control unit 16 scans or otherwise reads the signal lines 160, 162 to monitor output from the pressure sensors 156, 158, respectively. As described above, the output signals produced by the pressure sensors 156, 158 reflect the pressure drop across the soot filter 96, and, as a result, are indicative of the soot accumulation level of the filter 96. Once the control unit 16 has determined the soot accumulation level in the soot filter 96, the control routine 300 advances to step 304.
  • In [0081] step 304, the control unit 16 determines if the soot accumulation level within the soot filter 96 necessitates regeneration of the filter 96. In particular, a predetermined accumulation level or “set point” may be established at which point the soot filter 96 is deemed to be in need of assistance in regard to regeneration thereof. For example, a set point in the form of a variable obtained from an engine map or a measured exhaust flow may be used. As such, in step 304, the control unit 16 determines if the soot accumulation level of the soot filter 96 equals or exceeds the set point. If the soot accumulation level within the soot filter 96 is below the set point, the control routine 300 loops back to step 302 to continue monitoring the soot accumulation level within the soot filter 96. However, if the soot accumulation level within the soot filter 96 is greater than or equal to the set point, a control signal is generated, and the control routine 300 advances to step 306.
  • In [0082] step 306, the control unit 16 positions the diverter valve 88 to allow for the advancement of reformate gas from the fuel reformer 12 to the oxidation catalyst 94. In particular, the control unit 16 generates an output signal on the signal line 152 thereby causing the valve actuator 170 to move the diverter valve 88 to a valve position in which reformate gas may be diverted through a recently regenerated NOX trap 84, 86 thereby causing a predetermined portion of the reformate gas to pass through the NOX trap to the oxidation catalyst 94 without being “consumed” by the trap. As described above, such advancement of the reformate gas through the trap may be performed as an extended NOX trap regeneration. Moreover, the reformate gas may be advanced to the catalyst via a dedicated bypass line. The control routine 300 then advances to step 308.
  • In [0083] step 308, the control unit 16 commences operation of the fuel reformer 12 so as to generate reformate gas therewith. The reformate gas exiting the fuel reformer 12 is then advanced into contact with the oxidation catalyst 94 to catalyze an oxidation reaction between the oxygen in the exhaust gas of the engine 82 and the reformate gas, as described in detail above. The heat generated by such a reaction is transferred to the downstream-positioned soot filter 96 thereby igniting and burning soot particles trapped in the particulate filter 96 so as to regenerate the filter 96. The control routine 300 then loops back to step 302 to commence monitoring of the soot filter 96.
  • Referring now to FIG. 9, there is shown an emission abatement assembly which is similar to the assembly shown in FIG. 3. The same reference numerals are used in FIG. 9 to designate common components which were previously discussed in regard to FIG. 3 with additional discussion thereof being unwarranted. [0084]
  • The system of FIG. 9 is somewhat similar to the system of FIG. 3 with the exception that only a single NO[0085] X trap 84 is used. The use of a single NOX trap may be particularly useful in the case of a vehicle retrofit application.
  • In the assembly of FIG. 9, a pair of [0086] exhaust diverter valves 402, 404 are utilized in lieu of the diverter valve 88. Use of the diverter valves 402, 404 allows for advancement of engine exhaust gas through either a trap flow path 406 or a bypass flow path 408. As shown in FIG. 9, the NOX trap 84 is positioned in the trap flow path 406, but is isolated from the bypass flow path 408. As such, when the diverter valve 402 is positioned in its open position and the diverter valve 404 is positioned in its closed position, exhaust gas from the engine 82 is directed along the trap flow path 406 and hence through the NOX trap 84. However, when the diverter valve 402 is positioned in its closed position and the diverter valve 404 is positioned in its open position, exhaust gas from the engine 82 is directed along the bypass flow path 408 and hence bypasses the NOX trap 84.
  • To operate in such a manner, the [0087] diverter valves 402, 404 are electrically coupled to the electronic control unit 16 via a pair of signal lines 412, 414, respectively. As such, the position of each of the diverter valves 402, 404 is under the control of the electronic control unit 16. Hence, the electronic control unit 16, amongst its other functions, selectively directs the flow of exhaust gas from the engine 82 to either the NOX trap 84 or the bypass flow path 408, or a combination thereof.
  • The control scheme for controlling the position of the [0088] diverter valves 402, 404 may be designed in a number of different manners. For example, a sensor-based control scheme similar to described herein in regard to FIG. 3 may be utilized. In such a case, the position of each of the diverter valves 402, 404 is changed as a function of output from the NOX sensor 154. As such, when the output from the NOX sensor 154 indicates that the NOX trap 84 is in need of regeneration, the control unit 16 operates the diverter valves 402, 404 to direct the exhaust gas from the engine 82 through the bypass flow path 408 thereby allowing for offline regeneration of the NOX trap 84 by use of reformate gas from the fuel reformer 12 in the manner described above.
  • Alternatively, a timing-based control scheme may be utilized in which the position of each of the [0089] diverter valves 402, 404 is changed as a function of time. For instance, regeneration of the NOX trap 84 may be performed at predetermined timed intervals. In such a case, the NOX sensor 154 may be all together eliminated, or used merely as a “failsafe” to ensure that regeneration is not prematurely needed during a timed interval.
  • Moreover, an engine-mapped control scheme may be utilized in which the position of each of the [0090] diverter valves 402, 404 is changed as a function of engine load over time. In particular, an engine map may be created which allows the control unit 16 to track the amount of NOX which has been created by the engine 82 based on engine load conditions. When the control unit 16 determines that the engine 82 has generated a predetermined amount of NOX, with such an amount being trapped in the NOX trap 84, the control unit 16 operates the diverter valves 402, 404 to direct the exhaust gas from the engine 82 through the bypass flow path 408 thereby allowing for offline regeneration of the NOX trap 84 by use of reformate gas from the fuel reformer 12 in the manner described above. As with the timing-based control scheme, the NOX sensor 154 may be all together eliminated from this control scheme, or used merely as a “failsafe” to ensure that regeneration is not prematurely needed during a mapped interval.
  • In addition to the exemplary embodiments shown in FIGS. 3 and 9, other system configurations are also contemplated which incorporate the features of the present disclosure therein. For example, in lieu of the use of a single oxidation catalyst (e.g., the oxidation catalyst [0091] 94) and a single catalyzed soot filter (e.g., the soot filter 96) positioned in the recombined flow path downstream of both NOX traps 84, 86, each of the right flow path 102 and the left flow path 104 may be configured to include an oxidation catalyst and an uncatalyzed soot filter positioned downstream of the respective NOX traps. In other words, an oxidation catalyst (e.g., a diesel oxidation catalyst) and uncatalyzed soot filter (e.g., a soot filter which has not been impregnated with catalytic material) may be positioned in each of the parallel flow paths at a position downstream of each NOX trap. Such an arrangement advantageously allows for filter regeneration in the presence of a significantly smaller engine exhaust flow thereby lowering the amount of reformate gas required to regenerate each soot filter relative to use of a soot filter that is regenerated in the presence of the entire engine exhaust flow.
  • As can be seen from the foregoing description, the concepts of the present disclosure provide numerous features and advantages relative to other systems. For example, amongst other things, the concepts of the present disclosure allow for the use of a single fuel reformer to regenerate a number of different exhaust treatment devices. In such a way, multiple exhaust compounds (e.g., NO[0092] X and soot) can be removed from the exhaust gas flow by use of a single reformer.
  • Moreover, the configuration and positioning of the soot filter enhances the reliability of the emission abatement assembly. Indeed, use of a catalyzed filter allows for soot filter regeneration to be performed primarily without assistance from the fuel reformer. Moreover, positioning the soot filter downstream of the NO[0093] X traps, as opposed to visa versa, eliminates the possibility of damage to the NOX traps as a result of heat from an assisted filter regeneration cycle.
  • Further, by use of the diverter valve of FIGS. [0094] 3-6, a single valve may be used in place of numerous valves. Indeed, a single valve may be used in lieu of one or more valves for diverting exhaust gas from the engine between the two traps and one or more valves for diverting reformate gas between the two traps.
  • While the disclosure is susceptible to various modifications and alternative forms, specific exemplary embodiments thereof have been shown by way of example in the drawings and has herein be described in detail. It should be understood, however, that there is no intent to limit the disclosure to the particular forms disclosed, but on the contrary, the intention is to cover all modifications, equivalents, and alternatives falling within the spirit and scope of the disclosure. [0095]
  • There are a plurality of advantages of the present disclosure arising from the various features of the apparatus, systems, and methods described herein. It will be noted that alternative embodiments of the apparatus, systems, and methods of the present disclosure may not include all of the features described yet still benefit from at least some of the advantages of such features. Those of ordinary skill in the art may readily devise their own implementations of apparatus, systems, and methods that incorporate one or more of the features of the present disclosure and fall within the spirit and scope of the present disclosure. [0096]
  • For example, although the NO[0097] X abatement devices are herein described as NOX traps, and have numerous advantages thereby in regard to the disclosed systems, certain of such advantages may also be achieved by use of other NOX abatement devices. For example, SCR devices may be used in certain system configurations in lieu of the NOX traps described herein.
  • Moreover, although the [0098] diverter valve 88 is herein described in regard to the directing of engine exhaust gas, along with a reductant fluid in the form of reformate gas from a fuel reformer, it should be appreciated that the valve 88 may be used in regard to other types of reductant fluids. For example, the diverter valve 88 may be used to direct reductant fluids in the form of reductant gases which originate from sources other than onboard reformers such as tanks or other storage devices.
  • The [0099] diverter valve 88 may also be used to direct reductant fluids in forms other than gases. For example, in certain embodiments, the diverter valve 88 may be used to direct reductant fluids in the form of liquid hydrocarbon fuels. For instance, the diverter valve 88 may be used to direct reductant fluid in the form of untreated diesel fuel. In such a case, for example, the untreated diesel fuel may be injected into the valve 88 (e.g., through the reductant fluid inlet 148) by use of a fuel injector assembly (including a fuel injector assembly that atomizes the diesel fuel prior to or during injection thereof).

Claims (19)

1. A method of operating a diverter valve of an emission abatement assembly, the method comprising the steps of:
positioning the diverter valve in a first valve position so as to (i) direct exhaust gas from an internal combustion engine to a first emission abatement device, and (ii) direct a reductant fluid to a second emission abatement device, and
positioning the diverter valve in a second valve position so as to (i) direct exhaust gas from the internal combustion engine to the second emission abatement device, and (ii) direct the reductant fluid to the first emission abatement device.
2. The method of claim 1, wherein:
the diverter valve comprises (i) an exhaust gas inlet, (ii) a reductant fluid inlet, (iii) a first outlet fluidly coupled to the first emission abatement device, and (iv) a second outlet fluidly coupled to the second emission abatement device,
the step of positioning the diverter valve in the first valve position comprises fluidly coupling (i) the exhaust gas inlet to the first outlet, and (ii) the reductant fluid inlet to the second outlet, and
the step of positioning the diverter valve in the second valve position comprises fluidly coupling (i) the exhaust gas inlet to the second outlet, and (ii) the reductant fluid inlet to the first outlet.
3. The method of claim 2, wherein:
the step of positioning the diverter valve in the first valve position further comprises fluidly isolating (i) the exhaust gas inlet from the second outlet, and (ii) the reductant fluid inlet from the first outlet, and
the step of positioning the diverter valve in the second valve position further comprises fluidly isolating (i) the exhaust gas inlet from the first outlet, and (ii) the reductant fluid inlet from the second outlet.
4. The method of claim 1, wherein:
the reductant fluid comprises reformate gas generated by a fuel reformer,
the step of positioning the diverter valve in the first valve position comprises fluidly coupling the fuel reformer to the second emission abatement device so as to direct reformate gas from the fuel reformer to the second emission abatement device, and
the step of positioning the diverter valve in the second valve position comprises fluidly coupling the fuel reformer to the first emission abatement device so as to direct reformate gas from the fuel reformer to the first emission abatement device.
5. The method of claim 1, further comprising moving the diverter valve from the first valve position to the second valve position with a valve actuator.
6. The method of claim 5, wherein:
the valve actuator comprises a linear solenoid, and
the moving step comprises moving the solenoid from a first solenoid position to a second solenoid position.
7. The method of claim 5, wherein:
the valve actuator comprises a stepper motor, and
the moving step comprises actuating the stepper motor so as to move the diverter valve from the first valve position to the second valve position.
8. A diverter valve of an emission abatement assembly, the diverter valve comprising:
a valve housing defining a valve chamber, the valve housing having (i) an exhaust gas inlet, (ii) a reductant fluid inlet, (iii) a first outlet, and (iv) a second outlet, and
a valve member positioned in the valve chamber, the valve member being positionable between (i) a first valve position in which the exhaust gas inlet is fluidly coupled to the first outlet and the reductant fluid inlet is fluidly coupled to the second outlet, and (ii) a second valve position in which the exhaust gas inlet is fluidly coupled to the second outlet and the reductant fluid inlet is fluidly coupled to the first outlet.
9. The diverter valve of claim 8, wherein
when the valve member is positioned in the first valve position (i) the exhaust gas inlet is fluidly isolated from the second outlet, and (ii) the reductant fluid inlet is isolated from the first outlet, and
when the diverter valve is positioned in the second valve position (i) the exhaust gas inlet is fluidly isolated from the first outlet, and (ii) the reductant fluid inlet is fluidly isolated from the second outlet.
10. The diverter valve of claim 8, further comprising a valve actuator coupled to the valve member.
11. The diverter valve of claim 10, wherein the valve actuator comprises a linear solenoid.
12. The diverter valve of claim 10, wherein the valve actuator comprises a stepper motor.
13. An emission abatement assembly, comprising:
a first emission abatement device,
a second emission abatement device,
a source of reductant fluid, and
a diverter valve, the diverter valve being configured to selectively divert both engine exhaust gas and reductant fluid between the first emission abatement device and the second emission abatement device.
14. The emission abatement assembly of claim 13, further comprising a control unit electrically coupled to the diverter valve.
15. The emission abatement assembly of claim 13, wherein the source of reductant fluid comprises a fuel reformer.
16. An emission abatement assembly, comprising:
a first NOX trap,
a second NOX trap,
a fuel reformer configured to convert hydrocarbon fuel into a reformate gas, and
a diverter valve having (i) an exhaust gas inlet configured to receive engine exhaust gas, (ii) a reductant fluid inlet fluidly coupled to the fuel reformer, (iii) a first outlet fluidly coupled to an inlet of the first NOX trap, and (iv) a second outlet fluidly coupled o the inlet of the second NOX trap.
17. The emission abatement assembly of claim 16, wherein the diverter valve comprises a valve member positionable between (i) a first valve position in which the exhaust gas inlet is fluidly coupled to the first outlet and the reductant fluid inlet is fluidly coupled to the second outlet, and (ii) a second valve position in which the exhaust gas inlet is fluidly coupled to the second outlet and the reductant fluid inlet is fluidly coupled to the first outlet.
18. The emission abatement assembly of claim 16, wherein the diverter valve further comprises a valve actuator coupled to the valve member.
19. The emission abatement assembly of claim 16, wherein the fuel reformer further comprises a plasma fuel reformer.
US10/345,681 2003-01-16 2003-01-16 Method and apparatus for directing exhaust gas and reductant fluid in an emission abatement system Abandoned US20040139730A1 (en)

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