US20040154072A1 - Gloves - Google Patents

Gloves Download PDF

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Publication number
US20040154072A1
US20040154072A1 US10/471,097 US47109704A US2004154072A1 US 20040154072 A1 US20040154072 A1 US 20040154072A1 US 47109704 A US47109704 A US 47109704A US 2004154072 A1 US2004154072 A1 US 2004154072A1
Authority
US
United States
Prior art keywords
glove
electro
detectable
microns
powder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US10/471,097
Inventor
Dennis Connor
Original Assignee
CK EUROPEAN SAFETY EQUIPMENT Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CK EUROPEAN SAFETY EQUIPMENT Ltd filed Critical CK EUROPEAN SAFETY EQUIPMENT Ltd
Assigned to CK EUROPEAN SAFETY EQUIPMENT LIMITED reassignment CK EUROPEAN SAFETY EQUIPMENT LIMITED ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: CONNOR, DENNIS FREDERICK
Publication of US20040154072A1 publication Critical patent/US20040154072A1/en
Assigned to DENNIS FREDERICK CONNOR reassignment DENNIS FREDERICK CONNOR ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: CK EUROPEAN SAFETY EQUIPMENT LIMITED
Abandoned legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D19/00Gloves
    • A41D19/0055Plastic or rubber gloves
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/01Magnetic additives

Definitions

  • This invention relates to gloves and more especially to gloves whose presence can be detected electro-magnetically.
  • Electro-magnetic inspection of products leaving a production line is undertaken as a matter of course in many industries. Such inspections enable metal-based foreign bodies present in otherwise non-metallic products to be detected. In this way, contaminated products can be selectively discarded. Operatives' gloves are generally produced from a polymeric substance (e.g. a plastisol) and their presence in a product would not at present be detected other than by visual inspection.
  • a polymeric substance e.g. a plastisol
  • U.S. Pat. No. 5,922,482 discloses polymeric protective articles, such as gloves, normally used in manufacturing, conversion or packaging lines, especially in the agri-foodstuffs, pharmaceuticals or food sector.
  • the articles are multi-layered with one layer containing a material having conducting and/or magnetic properties, which is detectable by a metal-particle detector.
  • a process for preparing the said articles is also-disclosed.
  • One object of the present invention is to provide a glove for use by operatives on, for example, manufacturing production lines which can be detected electro-magnetically in the event that it or a part thereof becomes mixed with products during the manufacturing process.
  • a glove produced entirely from a plastic material containing an evenly dispersed quantity of electromagnetically detectable particles, the average particle size of the electro-magnetically detectable powder being between 1 and 200 microns.
  • the plastics material may be a plastisol such a natural latex, acrylonitrile-butadiene (nitrite) or polyvinylchloride (pvc).
  • the gloves are produced by a process in which a glove-shaped former is immersed for a relatively short period of time in a solution of the plastics material.
  • the solution may also include various additives such as stabilisers, accelerators and fillers.
  • the former may be sequentially immersed two or more times.
  • the average particle size of the electromagnetically detachable material is in the range 50 to 200 microns, preferably between 50 and 100 microns.
  • the electro-magnetically detectable material is preferably a ferrous material, more preferably ferrous oxide typically comprising ⁇ Fe 2 O 3 .
  • the material may consist solely of a single metallic substance e.g. a ferromagnetic or ferrimagnetic material, or it may comprise a mixture of two or more different electro-magnetically detectable materials including an iron-containing powder.
  • the material may comprise a bronze alloy of copper with aluminium, manganese or beryllium.
  • the alloy may be an alloy of copper and tin and may include other metals such as zinc or lead.
  • the electro-magnetically detectable powder is preferably mixed with the liquid plastisol to produce a relatively homogenous mix and the quantity of powder added preferably represents between 3% and 6% by volume of the mix. Typically, the quantity is of the order of 5% by volume. Homogenous distribution of the electro-magnetically detectable material allows even small fragments of a glove to be detected with conventional electro-magnetically operating detection equipment.
  • the electro-magnetically detectable material is in powder form, then its type and particle size is preferably such as to be detectable in the frequency range 50 kHz to 600 kHz, which is a frequency range that is employed by conventional detection equipment.
  • the particle size of the majority of the powder is preferably below 200 microns, and would usually be above 1 micron. More preferably the particle size of the majority of the powder is in the range 50 to 200 microns and most preferably it is in the range 50 to 100 microns.
  • the intimate presence of the electro-magnetically detectable powder within the glove material is sufficient to activate conventional detection equipment in the event that a glove or a relatively small part of a glove is present in manufactured products leaving a production line as set out in the appended claims.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Gloves (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Eye Examination Apparatus (AREA)
  • Advancing Webs (AREA)

Abstract

A glove produced form a plastics material containing an evenly dispersed quantity of electro-magnetically detectable particles.

Description

  • This invention relates to gloves and more especially to gloves whose presence can be detected electro-magnetically. [0001]
  • The wearing of gloves by operatives in manufacturing industries, such as pharmaceutical, food and tobacco industries, is important to protect products from contamination and to preserve the required high standards of hygiene and cleanliness. A cosequence of this is that a glove or a relatively small piece of a glove caused, for example, by the glove snagging or being torn, may become detached from an operative's glove and be mixed with products being manufactured. [0002]
  • To meet this problem, it is accepted practice that operatives' gloves should be coloured blue and it is now a requirement in many countries that this procedure be followed so that gloves can be detected visually. Visual detection is not foolproof, particularly where small glove pieces are concerned. [0003]
  • Electro-magnetic inspection of products leaving a production line is undertaken as a matter of course in many industries. Such inspections enable metal-based foreign bodies present in otherwise non-metallic products to be detected. In this way, contaminated products can be selectively discarded. Operatives' gloves are generally produced from a polymeric substance (e.g. a plastisol) and their presence in a product would not at present be detected other than by visual inspection. [0004]
  • U.S. Pat. No. 5,922,482 discloses polymeric protective articles, such as gloves, normally used in manufacturing, conversion or packaging lines, especially in the agri-foodstuffs, pharmaceuticals or food sector. The articles are multi-layered with one layer containing a material having conducting and/or magnetic properties, which is detectable by a metal-particle detector. A process for preparing the said articles is also-disclosed.[0005]
  • One object of the present invention is to provide a glove for use by operatives on, for example, manufacturing production lines which can be detected electro-magnetically in the event that it or a part thereof becomes mixed with products during the manufacturing process. [0006]
  • According to the present invention in one aspect, there is provided a glove produced entirely from a plastic material containing an evenly dispersed quantity of electromagnetically detectable particles, the average particle size of the electro-magnetically detectable powder being between 1 and 200 microns. [0007]
  • The plastics material may be a plastisol such a natural latex, acrylonitrile-butadiene (nitrite) or polyvinylchloride (pvc). Typically, the gloves are produced by a process in which a glove-shaped former is immersed for a relatively short period of time in a solution of the plastics material. The solution may also include various additives such as stabilisers, accelerators and fillers. To produce a single glove, the former may be sequentially immersed two or more times. [0008]
  • Typically, the average particle size of the electromagnetically detachable material is in the range 50 to 200 microns, preferably between 50 and 100 microns. [0009]
  • The electro-magnetically detectable material is preferably a ferrous material, more preferably ferrous oxide typically comprising γFe[0010] 2O3. The material may consist solely of a single metallic substance e.g. a ferromagnetic or ferrimagnetic material, or it may comprise a mixture of two or more different electro-magnetically detectable materials including an iron-containing powder. Alternatively, the material may comprise a bronze alloy of copper with aluminium, manganese or beryllium. The alloy may be an alloy of copper and tin and may include other metals such as zinc or lead.
  • The electro-magnetically detectable powder is preferably mixed with the liquid plastisol to produce a relatively homogenous mix and the quantity of powder added preferably represents between 3% and 6% by volume of the mix. Typically, the quantity is of the order of 5% by volume. Homogenous distribution of the electro-magnetically detectable material allows even small fragments of a glove to be detected with conventional electro-magnetically operating detection equipment. [0011]
  • When the electro-magnetically detectable material is in powder form, then its type and particle size is preferably such as to be detectable in the frequency range 50 kHz to 600 kHz, which is a frequency range that is employed by conventional detection equipment. As mentioned, the particle size of the majority of the powder is preferably below 200 microns, and would usually be above 1 micron. More preferably the particle size of the majority of the powder is in the range 50 to 200 microns and most preferably it is in the range 50 to 100 microns. [0012]
  • In use, the intimate presence of the electro-magnetically detectable powder within the glove material is sufficient to activate conventional detection equipment in the event that a glove or a relatively small part of a glove is present in manufactured products leaving a production line as set out in the appended claims. [0013]
  • It will be appreciated that the foregoing is merely exemplary of gloves in accordance with the invention and that modifications can readily be made thereto without departing from the true scope of the invention as set out in the appended claims. [0014]

Claims (14)

1. A glove produced entirely from a plastics material containing an evenly dispersed quantity of electromagnetically detectable particles, the average particle size of the electromagnetically detectable powder being between 1 and 200 microns.
2. A glove as claimed in claim 1 wherein the plastics material is a plastisol.
3. A glove as claimed in claim 2 which the plastisol is natural latex, acrylonitrile-butadiene or polyvinylchloride.
4. A glove as claimed in any one of claims 1 to 3 wherein the average particle size is in the range 50 to 200 microns.
5. A glove as claimed in any one of claims 1 to 4 wherein the average particle size is in the range of 50 and 100 microns.
6. A glove as claimed in any one of the preceding claims wherein the composition of the electromagnetically detectable particles includes a ferrous material.
7. A glove as claimed in claim 6 wherein the ferrous material is an oxide of iron.
8. A glove as claimed in claim 7 wherein the material is ferrous oxide.
9. A glove as claimed in claim 8 wherein the ferrous oxide is γFe2O3.
10. A glove as claimed in any one of claims 1 to 9 wherein the composition of the particles comprises a mixture of two or more different electro-magnetically detectable materials.
11. A glove as claimed in any one of claims 1 to 5 wherein the composition of the electro-magnetically detectable material comprises a bronze alloy of copper with aluminium, manganese or beryllium.
12. A glove as claimed in claim 11 wherein the alloy is an alloy of copper and tin.
13. A method of producing a glove as claimed in any one of the preceding claims wherein the electro magnetically detectable particles or powder is mixed with a liquid plastisol to produce a relatively homogenous mix, the quantity of electromagnetic powder or particles added to the liquid plastisol representing between 3% and 6% by volume of the mix.
14. A method as claimed in claim 15 wherein the quantity is of the order of 6% by volume.
US10/471,097 2001-03-09 2001-10-29 Gloves Abandoned US20040154072A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB0105797.5 2001-03-09
GB0105797A GB2372934A (en) 2001-03-09 2001-03-09 Glove containing electromagnetically detectable particles
PCT/GB2001/004784 WO2002071876A1 (en) 2001-03-09 2001-10-29 Gloves

Publications (1)

Publication Number Publication Date
US20040154072A1 true US20040154072A1 (en) 2004-08-12

Family

ID=9910291

Family Applications (1)

Application Number Title Priority Date Filing Date
US10/471,097 Abandoned US20040154072A1 (en) 2001-03-09 2001-10-29 Gloves

Country Status (7)

Country Link
US (1) US20040154072A1 (en)
EP (1) EP1365665B1 (en)
AT (1) ATE427668T1 (en)
DE (1) DE60138311D1 (en)
ES (1) ES2325202T3 (en)
GB (1) GB2372934A (en)
WO (1) WO2002071876A1 (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20160024699A1 (en) * 2014-07-25 2016-01-28 Illinois Tool Works, Inc. Particle-filled fiber and articles formed from the same
WO2016174418A1 (en) 2015-04-27 2016-11-03 Midas Safety Innovations Limited Polyurethane coated fabric
USD876748S1 (en) 2019-06-24 2020-03-03 Hempvana, Llc Glove
US10619268B2 (en) * 2013-11-13 2020-04-14 Illinois Tool Works, Inc. Metal detectable fiber and articles formed from the same
WO2021053353A1 (en) * 2019-09-20 2021-03-25 Smith Sean Ronald Improvements to gloves and a method of manufacture
WO2021084335A1 (en) 2019-10-30 2021-05-06 Dipped Products Plc A latex dipped article containing a natural mineral composite with a magnetically detectable property and method of making
US11542634B2 (en) 2014-07-25 2023-01-03 Illinois Tool Works Inc. Particle-filled fiber and articles formed from the same
US11839247B2 (en) 2019-09-20 2023-12-12 Detectamet Limited Gloves and the manufacture thereof
US11952478B2 (en) 2020-06-26 2024-04-09 Top Glove International Sdn. Bhd. Latex formulation and X-ray detectable glove prepared thereof

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1465942A4 (en) 2002-01-14 2005-06-29 Ansell Healthcare Prod Inc Magnetically detectable latex articles
GB2428629A (en) * 2005-07-27 2007-02-07 B S Teasdale & Son Ltd Magnetically detectable bag
GB2438930B (en) * 2006-06-07 2011-04-13 C K Europ Ltd Apparatus and method for manufacturing a glove containing electro-magnetically detectable particles
DE202008007992U1 (en) * 2008-06-17 2008-09-11 Rosenfelder, Bernd Protective clothing, in particular protective gloves
US8980982B2 (en) * 2011-03-25 2015-03-17 Illinois Tool Works, Inc. Electromagnetic spectrally detectable plastic packaging components
US10947664B2 (en) 2018-02-19 2021-03-16 Illinois Tool Works Inc. Metal detectable scouring pad
EP3663332A1 (en) * 2018-12-07 2020-06-10 Skinprotect Corporation SDN BHD Detectable and multi detectable articles
JP2022042504A (en) * 2020-09-02 2022-03-14 トップ グローブ インターナショナル センディリアン ベルハッド Glove

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4918754A (en) * 1988-05-04 1990-04-24 William C. Heller, Jr. Flocked glove and plastic sleeve member bonded thereto
US4937995A (en) * 1988-06-16 1990-07-03 Carlisle Corporation Noninvasively identifiable membrane roof system
US5051034A (en) * 1989-12-18 1991-09-24 Gas Research Institute Magnetically detectable plastic pipe
US5922482A (en) * 1995-11-09 1999-07-13 Hutchinson Detectable polymeric protective gloves
US6380294B1 (en) * 1997-10-17 2002-04-30 The Dow Chemical Company COMPOSITIONS OF INTERPOLYMERS OF α-OLEFIN MONOMERS WITH ONE OR MORE VINYL OR VINYLIDENE AROMATIC MONOMERS AND/OR ONE OR MORE HINDERED ALIPHATIC OR CYCLOALIPHATIC VINYL OR VINYLIDENE MONOMERS BLENDED WITH A CONDUCTIVE ADDITIVE

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2078861A5 (en) * 1971-02-19 1971-11-05 Greenberg Irving
US3916448A (en) * 1975-03-03 1975-11-04 John S Hamel Protective glove
US5215701A (en) * 1987-08-14 1993-06-01 Arnold S. Gould Process for making a surgical glove
JP3563752B2 (en) * 1992-11-24 2004-09-08 エイチエヌエイ・ホールディングス・インコーポレーテッド Filled fiber
WO1999066253A1 (en) * 1998-06-16 1999-12-23 Intelligent Safety Development Device for individual protection against mechanical, electrical or thermal risks

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4918754A (en) * 1988-05-04 1990-04-24 William C. Heller, Jr. Flocked glove and plastic sleeve member bonded thereto
US4937995A (en) * 1988-06-16 1990-07-03 Carlisle Corporation Noninvasively identifiable membrane roof system
US5051034A (en) * 1989-12-18 1991-09-24 Gas Research Institute Magnetically detectable plastic pipe
US5922482A (en) * 1995-11-09 1999-07-13 Hutchinson Detectable polymeric protective gloves
US6380294B1 (en) * 1997-10-17 2002-04-30 The Dow Chemical Company COMPOSITIONS OF INTERPOLYMERS OF α-OLEFIN MONOMERS WITH ONE OR MORE VINYL OR VINYLIDENE AROMATIC MONOMERS AND/OR ONE OR MORE HINDERED ALIPHATIC OR CYCLOALIPHATIC VINYL OR VINYLIDENE MONOMERS BLENDED WITH A CONDUCTIVE ADDITIVE

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10619268B2 (en) * 2013-11-13 2020-04-14 Illinois Tool Works, Inc. Metal detectable fiber and articles formed from the same
US20160024699A1 (en) * 2014-07-25 2016-01-28 Illinois Tool Works, Inc. Particle-filled fiber and articles formed from the same
US10753022B2 (en) * 2014-07-25 2020-08-25 Illinois Tool Works, Inc. Particle-filled fiber and articles formed from the same
US11542634B2 (en) 2014-07-25 2023-01-03 Illinois Tool Works Inc. Particle-filled fiber and articles formed from the same
WO2016174418A1 (en) 2015-04-27 2016-11-03 Midas Safety Innovations Limited Polyurethane coated fabric
US10662579B2 (en) 2015-04-27 2020-05-26 Midas Safety Innovations Limited Polyurethane coated fabric
USD876748S1 (en) 2019-06-24 2020-03-03 Hempvana, Llc Glove
WO2021053353A1 (en) * 2019-09-20 2021-03-25 Smith Sean Ronald Improvements to gloves and a method of manufacture
US11839247B2 (en) 2019-09-20 2023-12-12 Detectamet Limited Gloves and the manufacture thereof
US11896068B2 (en) 2019-09-20 2024-02-13 Detectamet Limited To gloves and a method of manufacture
WO2021084335A1 (en) 2019-10-30 2021-05-06 Dipped Products Plc A latex dipped article containing a natural mineral composite with a magnetically detectable property and method of making
US11952478B2 (en) 2020-06-26 2024-04-09 Top Glove International Sdn. Bhd. Latex formulation and X-ray detectable glove prepared thereof

Also Published As

Publication number Publication date
EP1365665B1 (en) 2009-04-08
GB0105797D0 (en) 2001-04-25
EP1365665A1 (en) 2003-12-03
GB2372934A (en) 2002-09-11
ATE427668T1 (en) 2009-04-15
DE60138311D1 (en) 2009-05-20
WO2002071876A1 (en) 2002-09-19
ES2325202T3 (en) 2009-08-28

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Legal Events

Date Code Title Description
AS Assignment

Owner name: CK EUROPEAN SAFETY EQUIPMENT LIMITED, GREAT BRITAI

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:CONNOR, DENNIS FREDERICK;REEL/FRAME:015058/0137

Effective date: 20030925

AS Assignment

Owner name: DENNIS FREDERICK CONNOR, GREAT BRITAIN

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:CK EUROPEAN SAFETY EQUIPMENT LIMITED;REEL/FRAME:018281/0411

Effective date: 20060731

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION