US20040253488A1 - Method of qualifying at least a portion of a fuel cell system and an apparatus employing same - Google Patents
Method of qualifying at least a portion of a fuel cell system and an apparatus employing same Download PDFInfo
- Publication number
- US20040253488A1 US20040253488A1 US10/879,551 US87955104A US2004253488A1 US 20040253488 A1 US20040253488 A1 US 20040253488A1 US 87955104 A US87955104 A US 87955104A US 2004253488 A1 US2004253488 A1 US 2004253488A1
- Authority
- US
- United States
- Prior art keywords
- fuel cell
- test
- cell system
- result
- reactant gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
- H01M8/04701—Temperature
- H01M8/04708—Temperature of fuel cell reactants
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
- H01M8/04537—Electric variables
- H01M8/04544—Voltage
- H01M8/04552—Voltage of the individual fuel cell
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
- H01M8/04701—Temperature
- H01M8/04723—Temperature of the coolant
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Definitions
- This invention relates generally to fuel cells and more particularly to methods and apparatus for qualifying at least a portion of a fuel cell system.
- Fuel cells electrochemically convert fuels and oxidants to electricity and they can be categorized according to the type of electrolyte (e.g., solid oxide, molten carbonate, alkaline, phosphoric acid, or solid polymer) used to accommodate ion transfer during operation.
- electrolyte e.g., solid oxide, molten carbonate, alkaline, phosphoric acid, or solid polymer
- fuel cell assemblies can be employed in many (e.g., automotive to aerospace to industrial to residential) environments, for multiple applications.
- a Proton Exchange Membrane (hereinafter “PEM”) fuel cell converts the chemical energy of fuels such as hydrogen and oxidants such as air/oxygen directly into electrical energy.
- the PEM is a solid polymer electrolyte that permits the passage of protons (i.e., H+ions) from the “anode” side of a fuel cell to the “cathode” side of the fuel cell while preventing passage therethrough of reactant fluids (e.g., hydrogen and air/oxygen gases).
- an individual PEM-type fuel cell assembly or stack has multiple, generally transversely extending layers assembled in a longitudinal direction.
- all layers which extend to the periphery of the fuel cells have holes therethrough for alignment and formation of fluid manifolds that generally service fluids for the stack.
- fluid manifolds distribute fuel (e.g., hydrogen) and oxidant (e.g., air/oxygen) to, and remove unused fuel and oxidant as well as product water from, fluid flow plates having fluid flow channels.
- the present invention provides, in a first aspect, a method for enabling qualification of a fuel cell system.
- the method includes electronically obtaining at least one result of a test of at least a portion of the fuel cell system and electronically comparing the at least one result to at least one qualifying criteria.
- the present invention provides, in a second aspect, an apparatus for enabling qualification of a fuel cell system.
- the apparatus includes a testing mechanism couplable to a computing unit and couplable to the fuel cell system.
- the testing mechanism is adapted to perform a test on at least a portion of the fuel cell system and the computing unit is adapted to control a testing mechanism, obtain a result of a test, and compare the result to a qualification criteria.
- the present invention provides, in a third aspect, an apparatus for enabling qualification of a fuel cell system.
- the apparatus includes means for electronically obtaining at least one result of a test on at least a portion of the fuel cell system and means for electronically comparing the at least one result to at least one qualifying criteria.
- the present invention provides, in a fourth aspect, an apparatus for enabling qualification of a fuel cell system.
- the apparatus includes a computing unit adapted to obtain at least one result of a test on at least a portion of the fuel cell system and a computing unit adapted to compare the at least one result to at least one qualifying criteria.
- the present invention provides, in a fifth aspect, an article of manufacture including at least one computer usable medium having computer readable program code means embodied therein for enabling qualification of a fuel cell system.
- the computer readable program code means in the article of manufacture includes computer readable program code means for causing a first computing unit to obtain at least one result of a test on at least a portion of the fuel cell system and computer readable program code means for comparing the at least one result to at least one qualifying criteria.
- the present invention provides, in a sixth aspect, at least one program storage device readable by a machine, tangibly embodying at least one program of instructions executable by the machine to perform a method of qualifying a fuel cell system.
- the method includes electronically obtaining at least one result of a test on at least a portion of the fuel cell system and electronically comparing the at least one result to at least one qualifying criteria.
- FIG. 1 is a block diagram of an apparatus for enabling qualification of a fuel cell system in accordance with the present invention
- FIG. 2 is a depiction of a fluid flow plate having dive through holes
- FIGS. 3-5 illustrate a flowchart of a method in accordance with the present invention for qualifying at least a portion of a fuel cell system of FIG. 1.
- an apparatus 9 for qualifying a fuel cell system 30 includes a computing unit 10 coupled to a testing mechanism 20 or a test station which is coupled to fuel cell system 30 or portions thereof.
- Fuel cell system 30 may comprise an entire fuel cell system, including a fuel cell stack 32 , fuel processor or reformer 34 , an inverter 36 , and various other components.
- a fuel cell system may include only a subset of the components of the fuel cell system, either individually or assembled into a subsystem.
- the testing mechanism is utilized to test the fuel cell system, or portions thereof, for various parameters to qualify it, or verify that it is functioning properly, such that it is suitable for use in a system for generating electrical power.
- performance or qualification criteria are set for comparison to the results of various tests. These criteria might include various measurements of the performance of the fuel cell system and portions thereof. For example, regarding fuel cell stack 32 , the criteria might include average fuel cell voltage drops for the stack, variations between voltage drops for individual cells, stack temperature, gas temperature or coolant temperature.
- Computing unit 10 may control testing mechanism 20 to conduct a test on fuel cell system 30 or a portion thereof, e.g., fuel cell stack 32 .
- computing unit 10 electronically and desirably automatically obtains a result of the test, e.g., from various sensors (e.g., voltage readings, etc.), electronically and desirably automatically compares the result to the preset performance qualifying criteria for the particular test.
- Computing unit 10 might be a personal computer, such as a personal computer running Microsoft WINDOWS as the operating system, and based on Intel PC architecture.
- Computing unit 10 might also be a portion of a computer of this type, such as a microprocessor or other computing component capable of performing the requirements of the present invention.
- the computing unit may output a message to an output device 40 , such as a display screen for an operator to view.
- Such message may include indicating that the system or portion thereof has passed or failed a particular test. Alternate means of informing an operator could include lights or sound identifying a particular outcome or the printing of a report.
- computing unit 10 may cause testing mechanism 20 to conduct a further test on fuel cell system 30 or a portion thereof. This process may be repeated until fuel cell system 30 has passed a series of tests resulting in it being qualified for use. Alternatively, fuel cell system 30 may fail to be qualified after one of the particular tests.
- the above-described process is desirably used to qualify newly manufactured fuel cell components or fuel cell systems, but also could be used to ascertain the qualification of fuel cell systems or components already in service.
- this process might be performed by coupling computing unit 10 via a communications network to testing mechanism 20 , which might be at a location remote from computing unit 10 .
- Computing unit 10 might then compare a result of a test on fuel cell system 30 or a portion thereof to predetermined criteria and determine whether fuel cell system 30 or a component thereof is still qualified.
- An indication regarding the comparison might be provided by computing unit 10 by coupling it to an output device at the remote location.
- This setup would allow a single computing unit at a central location to qualify a plurality of fuel cell systems or components thereof at various remote locations.
- FIGS. 3-5 depict a flowchart which outlines one exemplary embodiment of a qualifying process of the present invention under which a fuel cell stack 32 (FIG. 1) of the fuel cell system 30 (FIG. 1) may be qualified or disqualified for use. It is desirable to disqualify a defective fuel cell stack as early as possible in the qualification process due to the expenses associated with the progressive tests involved in the process. This is particularly true of the expenses associated with purification, provision, and use of the reactant gases, i.e., hydrogen, oxygen, and carbon monoxide. Also, it is particularly desirable to avoid the expense of incubating a defective fuel cell stack by determining early in the process of its defective nature.
- the reactant gases i.e., hydrogen, oxygen, and carbon monoxide.
- characteristics of the fuel cell stack to be tested are input into a computing unit such as computing unit 10 (FIG. 1) which may comprise a display screen with entry fields.
- the characteristics to be input could include the type of stack, e.g., a model number, qualification criteria, location of a database stored on or connected to computing unit 10 where qualification criteria might be found, flow rates of reactant gases, a desired temperature of reactant gases, or a desired temperature of coolant, among others.
- rates of data acquisition, or logging, to be performed by the testing mechanism are set.
- Step 120 a mixture of hydrogen, nitrogen, and optionally carbon dioxide, serving as a surrogate for reformate produced by a reformer in full scale operation, and coolant are preheated and introduced into fuel cell stack 32 (FIG. 1).
- This mixture of gases may be referred to as surrogate reformate or reactant gases.
- the reformate and coolant might be preheated, for example, by a steam injection system.
- the fuel cell stack is held at a temperature for a period of time in Step 125 .
- An open circuit voltage test is then performed on fuel cell stack 32 (FIG. 1) to determine if the input or reactant gases are reaching all the fuel cells of fuel cell stack 32 (FIG. 1) in Step 130 .
- An open circuit voltage test may comprise measuring voltage drops of the fuel cell plates in the stack, for example at a pin on each plate, when no load is being applied to fuel cell stack 32 (FIG. 1). Alternatively, voltage drops might be measured using a voltage monitoring system for a full cell stack, as described in U.S. patent application Ser. No. 09/629,548, entitled “VOLTAGE MONITORING SYSTEM FOR A FULL CELL STACK”.
- the results of this test are compared by computing unit 10 (FIG. 1) to the predetermined criteria, input at Step 110 , for example.
- the criteria might require that the difference between fuel cell voltage drops falls within a range (e.g., 0.85-1.0 volts) or a percentage, for example. If a fuel cell or multiple fuel cells in fuel cell stack 32 (FIG. 1) do not meet this criteria, the cells would be considered “dropped out” as is known in the art. Since such cells would not be producing sufficient electricity relative to other cells, the stack would fail the test. A failing result causes a report to be printed, or a message to be communicated by computing unit 10 (FIG. 1) to the operator via display 40 (FIG. 1), or otherwise, regarding the test result and further testing to be avoided as in Step 132 .
- Step 135 a load or electrical demand is applied to the fuel cell stack.
- This test allows determining whether dive through holes were properly formed in the fluid flow plates. For example, as shown in FIG. 2, dive through holes, 4 and 7 , are used to fluidly connect fluid flow manifolds 2 with their respective flow channels 3 .
- Fluid flow plate 1 has a plurality of fluid flow manifolds 2 , and a plurality of active area flow channels 3 located on each side of the fluid flow plate.
- the active area flow channels on the opposite side of fluid flow plate 1 are connected to fluid flow manifolds 2 , by use of dive through holes 4 and inlet channels 6 .
- flow channels 3 are connected to fluid flow manifolds 2 by the use of dive through holes 7 and inlet channels located on the opposite side of fluid flow plate 1 (not shown in FIG. 2).
- the dive through holes extend through fluid flow plate 1 thereby allowing fluid from the fluid flow manifolds to enter the flow channels.
- the use of dive through holes creates a smooth surface 8 on the fluid face plate thereby allowing a gasket 5 to aid in the sealing of one plate to another. Gasket 5 also aids in sealing the respective fluid manifolds, thereby preventing leaking of fluid.
- Step 145 voltage drops across at least two fuel cells are measured.
- the drops are compared to predetermined criteria to determine whether the fluid flow plates of fuel cell stack 32 (FIG. 1) have been correctly formed such that dive through holes 4 and 7 (FIG. 2), satisfactorily allow the gases to pass from a fluid flow manifold 2 (FIG. 2) to active area fluid flow channels 3 (FIG. 2).
- the criteria might limit the allowed variation in fuel cell drop such that no fuel cells “drop out.” If the test fails, a report is printed in Step 147 , or an operator is informed in other ways, e.g. via a display, sounds, lights, etc., and testing is stopped. Alternatively, if the result of the test is favorable, testing continues with the load being reduced in Step 150 .
- Step 155 carbon monoxide is added to the reactant gases and in Step 160 the load is again increased.
- the system is held at the same flow rates and temperature for a period of time in Step 170 and in Step 175 a voltage drop test is performed.
- the membranes utilized in the fuel cells may be platinum on one side and a platinum- ruthenium alloy on the opposite side. Alternatively, membranes and catalysts may be formed of different materials, as is known by those skilled in the art.
- the introduction of carbon monoxide allows this test to determine if any of the membranes have been installed backwards. Correct installation calls for the membranes to be installed such that the platinum-ruthenium portion faces the reformate portion of a flow channel of a fuel cell.
- Platinum is not tolerant of carbon monoxide and thus if a membrane was installed backwards the interaction of the carbon monoxide and platinum would cause a voltage drop that would indicate that a membrane has been installed incorrectly. Carbon monoxide attaches itself to the platinum catalyst and prevents an electricity producing reaction from occurring thus causing a particular fuel cell to “drop out.” Such a test may be performed in Step 175 and the result may be compared to predefined criteria. A failed test results in a report being created and the testing being stopped in Step 165 .
- Step 180 If the fluid flow plates are determined to be installed correctly, e.g., if there are no membranes which are reversed, then the flow of carbon monoxide is stopped and the reactant gases provided are altered to include hydrogen, nitrogen, and perhaps carbon dioxide in Step 180 .
- a new data logging rate may be set in Step 185 and the flow rate of reactant gases and desired temperatures of the gases and coolant are set in Step 190 .
- the flow rate of the gases is set at a level which mimics minimum power output for fuel cell stack 32 (FIG. 1) and thus a low current density.
- a second load is applied in Step 195 also to mimic low electrical demand and the system is run at constant parameters for a period of time in Step 200 .
- a voltage drop test is performed in Step 205 to insure that all the fuel cells are producing electricity at the new load and flow rates of the reactant gases. Results of the test are compared by computing unit 10 to predetermined criteria and a report is created or the operator is otherwise informed if fuel cell stack 32 (FIG. 1) fails the test at Step 210 .
- Step 250 the flow rate is changed and the reactant gas mixture is changed to consist of substantially pure hydrogen and incubation is performed in Step 299 , as is known by those skilled in the art.
- Incubation can be performed in several ways and an exemplary incubation process is described in co-pending U.S. patent application Ser. No. 09/694,768, entitled “METHOD OF PRE-CONDITIONING OF FUEL CELL STACKS FOR SHORT INCUBATION”, and filed Oct. 23, 2000; now U.S. Pat. No. 6,576,356, the entire contents of this application is incorporated herein by reference.
- the reactant gas mixture is changed, regulated, or altered to include hydrogen, nitrogen, carbon monoxide and optionally carbon dioxide, in Step 300 .
- the flow rate is changed in Step 310 and the load is changed in Step 320 to mimic actual full scale operating conditions.
- the system is run at these parameters for a period of time to equilibrate the system in Step 330 and in Step 340 a voltage drop test is performed.
- Computing unit 10 compares the result of this test to predetermined criteria to determine if the voltage drops of the individual fuel cells are satisfactory, for example, to determine if they are within an accepted range. Also, the average fuel cell voltage drop is determined and it is compared by computing unit 10 (FIG.
- computing unit 10 may communicate a message to the operator via display 40 (FIG. 1) or print a report which indicates that fuel cell stack 32 (FIG. 1) has been qualified for use. In the alternative, if this test is failed, computing unit 10 (FIG. 1) may communicate a message to the operator, or print a report which indicates that fuel cell stack 32 (FIG. 1) has failed the test and is not qualified for use at Step 350 .
- An additional benefit of the present invention is that during the first several qualification tests described, fuel cell stack 32 (FIG. 1) is concurrently being warmed through the heating of the reactant gases and coolant prior to incubation.
- Testing mechanism 20 (FIG. 1) warms these gases and coolant, for example through a steam injection system. This permits immediate incubation of fuel cell stack 32 (FIG. 1) on completion of these initial tests if fuel cell stack 32 (FIG. 1) has passed all the pre- incubation tests. Since fuel cell stack 32 (FIG. 1) is already at the required temperature, it is not necessary to warm the gases and coolant prior to incubation which can require, e.g., up to thirty minutes to perform.
Abstract
The present invention provides a method for enabling qualification of at least a portion of a fuel cell system. The method includes electronically obtaining at least one result of a test of the at least a portion of a fuel cell system and electronically comparing the at least one result to at least one qualifying criteria.
Description
- This application is a Continuation of U.S. patent application Ser. No. 09/726,839, filed Nov. 30, 2000, which is incorporated herein by reference.
- This invention relates generally to fuel cells and more particularly to methods and apparatus for qualifying at least a portion of a fuel cell system.
- Fuel cells electrochemically convert fuels and oxidants to electricity and they can be categorized according to the type of electrolyte (e.g., solid oxide, molten carbonate, alkaline, phosphoric acid, or solid polymer) used to accommodate ion transfer during operation. Moreover, fuel cell assemblies can be employed in many (e.g., automotive to aerospace to industrial to residential) environments, for multiple applications.
- A Proton Exchange Membrane (hereinafter “PEM”) fuel cell converts the chemical energy of fuels such as hydrogen and oxidants such as air/oxygen directly into electrical energy. The PEM is a solid polymer electrolyte that permits the passage of protons (i.e., H+ions) from the “anode” side of a fuel cell to the “cathode” side of the fuel cell while preventing passage therethrough of reactant fluids (e.g., hydrogen and air/oxygen gases).
- Usually, an individual PEM-type fuel cell assembly or stack has multiple, generally transversely extending layers assembled in a longitudinal direction. In the typical fuel cell assembly or stack, all layers which extend to the periphery of the fuel cells have holes therethrough for alignment and formation of fluid manifolds that generally service fluids for the stack. As is known in the art, some of the fluid manifolds distribute fuel (e.g., hydrogen) and oxidant (e.g., air/oxygen) to, and remove unused fuel and oxidant as well as product water from, fluid flow plates having fluid flow channels.
- Before a fuel cell stack is qualified for use in a system to provide electrical power, it must be incubated or prepared for use, as is known by those of ordinary skill in the art. This process uses hydrogen, oxygen, carbon monoxide, carbon dioxide and/or nitrogen as a substitute or surrogate for reformate in the fuel cell stack. These gases are expensive to purify, store, and use in the amounts that this process requires.
- Thus, there is a need for an efficient method and apparatus for qualifying fuel cell systems and portions thereof.
- The present invention provides, in a first aspect, a method for enabling qualification of a fuel cell system. The method includes electronically obtaining at least one result of a test of at least a portion of the fuel cell system and electronically comparing the at least one result to at least one qualifying criteria.
- The present invention provides, in a second aspect, an apparatus for enabling qualification of a fuel cell system. The apparatus includes a testing mechanism couplable to a computing unit and couplable to the fuel cell system. The testing mechanism is adapted to perform a test on at least a portion of the fuel cell system and the computing unit is adapted to control a testing mechanism, obtain a result of a test, and compare the result to a qualification criteria.
- The present invention provides, in a third aspect, an apparatus for enabling qualification of a fuel cell system. The apparatus includes means for electronically obtaining at least one result of a test on at least a portion of the fuel cell system and means for electronically comparing the at least one result to at least one qualifying criteria.
- The present invention provides, in a fourth aspect, an apparatus for enabling qualification of a fuel cell system. The apparatus includes a computing unit adapted to obtain at least one result of a test on at least a portion of the fuel cell system and a computing unit adapted to compare the at least one result to at least one qualifying criteria.
- The present invention provides, in a fifth aspect, an article of manufacture including at least one computer usable medium having computer readable program code means embodied therein for enabling qualification of a fuel cell system. The computer readable program code means in the article of manufacture includes computer readable program code means for causing a first computing unit to obtain at least one result of a test on at least a portion of the fuel cell system and computer readable program code means for comparing the at least one result to at least one qualifying criteria.
- The present invention provides, in a sixth aspect, at least one program storage device readable by a machine, tangibly embodying at least one program of instructions executable by the machine to perform a method of qualifying a fuel cell system. The method includes electronically obtaining at least one result of a test on at least a portion of the fuel cell system and electronically comparing the at least one result to at least one qualifying criteria.
- The subject matter which is regarded as the invention is particularly pointed out and distinctly claimed in the claims at the conclusion of the specification. The foregoing and other features, and advantages of the invention will be readily understood from the following detailed description of preferred embodiments taken in conjunction with the accompanying drawings in which:
- FIG. 1 is a block diagram of an apparatus for enabling qualification of a fuel cell system in accordance with the present invention;
- FIG. 2 is a depiction of a fluid flow plate having dive through holes; and
- FIGS. 3-5 illustrate a flowchart of a method in accordance with the present invention for qualifying at least a portion of a fuel cell system of FIG. 1.
- In accordance with the principles of the present invention, a method for qualifying a fuel cell system or portion thereof and an apparatus for performing the method are provided.
- In an exemplary embodiment depicted in FIG. 1, an
apparatus 9 for qualifying afuel cell system 30, or portions thereof, includes acomputing unit 10 coupled to atesting mechanism 20 or a test station which is coupled tofuel cell system 30 or portions thereof.Fuel cell system 30 may comprise an entire fuel cell system, including afuel cell stack 32, fuel processor orreformer 34, aninverter 36, and various other components. Alternatively, a fuel cell system may include only a subset of the components of the fuel cell system, either individually or assembled into a subsystem. After the manufacture of various fuel cell system components, the testing mechanism is utilized to test the fuel cell system, or portions thereof, for various parameters to qualify it, or verify that it is functioning properly, such that it is suitable for use in a system for generating electrical power. - Prior to the initiation of the testing process, performance or qualification criteria are set for comparison to the results of various tests. These criteria might include various measurements of the performance of the fuel cell system and portions thereof. For example, regarding
fuel cell stack 32, the criteria might include average fuel cell voltage drops for the stack, variations between voltage drops for individual cells, stack temperature, gas temperature or coolant temperature.Computing unit 10 maycontrol testing mechanism 20 to conduct a test onfuel cell system 30 or a portion thereof, e.g.,fuel cell stack 32. At the conclusion of the test, computingunit 10 electronically and desirably automatically obtains a result of the test, e.g., from various sensors (e.g., voltage readings, etc.), electronically and desirably automatically compares the result to the preset performance qualifying criteria for the particular test.Computing unit 10 might be a personal computer, such as a personal computer running Microsoft WINDOWS as the operating system, and based on Intel PC architecture.Computing unit 10 might also be a portion of a computer of this type, such as a microprocessor or other computing component capable of performing the requirements of the present invention. - After the comparison, the computing unit may output a message to an
output device 40, such as a display screen for an operator to view. Such message may include indicating that the system or portion thereof has passed or failed a particular test. Alternate means of informing an operator could include lights or sound identifying a particular outcome or the printing of a report. If the test is passed,computing unit 10 may causetesting mechanism 20 to conduct a further test onfuel cell system 30 or a portion thereof. This process may be repeated untilfuel cell system 30 has passed a series of tests resulting in it being qualified for use. Alternatively,fuel cell system 30 may fail to be qualified after one of the particular tests. - The above-described process is desirably used to qualify newly manufactured fuel cell components or fuel cell systems, but also could be used to ascertain the qualification of fuel cell systems or components already in service. For example, this process might be performed by
coupling computing unit 10 via a communications network to testingmechanism 20, which might be at a location remote fromcomputing unit 10.Computing unit 10 might then compare a result of a test onfuel cell system 30 or a portion thereof to predetermined criteria and determine whetherfuel cell system 30 or a component thereof is still qualified. An indication regarding the comparison might be provided bycomputing unit 10 by coupling it to an output device at the remote location. This setup would allow a single computing unit at a central location to qualify a plurality of fuel cell systems or components thereof at various remote locations. - FIGS. 3-5 depict a flowchart which outlines one exemplary embodiment of a qualifying process of the present invention under which a fuel cell stack32 (FIG. 1) of the fuel cell system 30 (FIG. 1) may be qualified or disqualified for use. It is desirable to disqualify a defective fuel cell stack as early as possible in the qualification process due to the expenses associated with the progressive tests involved in the process. This is particularly true of the expenses associated with purification, provision, and use of the reactant gases, i.e., hydrogen, oxygen, and carbon monoxide. Also, it is particularly desirable to avoid the expense of incubating a defective fuel cell stack by determining early in the process of its defective nature.
- At
Step 110, characteristics of the fuel cell stack to be tested are input into a computing unit such as computing unit 10 (FIG. 1) which may comprise a display screen with entry fields. The characteristics to be input could include the type of stack, e.g., a model number, qualification criteria, location of a database stored on or connected to computingunit 10 where qualification criteria might be found, flow rates of reactant gases, a desired temperature of reactant gases, or a desired temperature of coolant, among others. AtStep 115, rates of data acquisition, or logging, to be performed by the testing mechanism are set. InStep 120, a mixture of hydrogen, nitrogen, and optionally carbon dioxide, serving as a surrogate for reformate produced by a reformer in full scale operation, and coolant are preheated and introduced into fuel cell stack 32 (FIG. 1). This mixture of gases may be referred to as surrogate reformate or reactant gases. The reformate and coolant might be preheated, for example, by a steam injection system. - The fuel cell stack is held at a temperature for a period of time in
Step 125. An open circuit voltage test is then performed on fuel cell stack 32 (FIG. 1) to determine if the input or reactant gases are reaching all the fuel cells of fuel cell stack 32 (FIG. 1) inStep 130. An open circuit voltage test may comprise measuring voltage drops of the fuel cell plates in the stack, for example at a pin on each plate, when no load is being applied to fuel cell stack 32 (FIG. 1). Alternatively, voltage drops might be measured using a voltage monitoring system for a full cell stack, as described in U.S. patent application Ser. No. 09/629,548, entitled “VOLTAGE MONITORING SYSTEM FOR A FULL CELL STACK”. The results of this test are compared by computing unit 10 (FIG. 1) to the predetermined criteria, input atStep 110, for example. The criteria might require that the difference between fuel cell voltage drops falls within a range (e.g., 0.85-1.0 volts) or a percentage, for example. If a fuel cell or multiple fuel cells in fuel cell stack 32 (FIG. 1) do not meet this criteria, the cells would be considered “dropped out” as is known in the art. Since such cells would not be producing sufficient electricity relative to other cells, the stack would fail the test. A failing result causes a report to be printed, or a message to be communicated by computing unit 10 (FIG. 1) to the operator via display 40 (FIG. 1), or otherwise, regarding the test result and further testing to be avoided as inStep 132. - If the open circuit voltage test is acceptable, the process proceeds to Step135 in which a load or electrical demand is applied to the fuel cell stack. This test allows determining whether dive through holes were properly formed in the fluid flow plates. For example, as shown in FIG. 2, dive through holes, 4 and 7, are used to fluidly connect
fluid flow manifolds 2 with theirrespective flow channels 3.Fluid flow plate 1 has a plurality offluid flow manifolds 2, and a plurality of activearea flow channels 3 located on each side of the fluid flow plate. In this example, the active area flow channels on the opposite side of fluid flow plate 1 (now shown in FIG. 2), are connected tofluid flow manifolds 2, by use of dive throughholes 4 andinlet channels 6. Similarly,flow channels 3 are connected tofluid flow manifolds 2 by the use of dive throughholes 7 and inlet channels located on the opposite side of fluid flow plate 1 (not shown in FIG. 2). The dive through holes extend throughfluid flow plate 1 thereby allowing fluid from the fluid flow manifolds to enter the flow channels. The use of dive through holes, creates asmooth surface 8 on the fluid face plate thereby allowing agasket 5 to aid in the sealing of one plate to another.Gasket 5 also aids in sealing the respective fluid manifolds, thereby preventing leaking of fluid. - With reference again to FIG. 3, the system is held for a period of time at a constant temperature in
Step 140 and inStep 145 voltage drops across at least two fuel cells are measured. The drops are compared to predetermined criteria to determine whether the fluid flow plates of fuel cell stack 32 (FIG. 1) have been correctly formed such that dive throughholes 4 and 7 (FIG. 2), satisfactorily allow the gases to pass from a fluid flow manifold 2 (FIG. 2) to active area fluid flow channels 3 (FIG. 2). For example, the criteria might limit the allowed variation in fuel cell drop such that no fuel cells “drop out.” If the test fails, a report is printed inStep 147, or an operator is informed in other ways, e.g. via a display, sounds, lights, etc., and testing is stopped. Alternatively, if the result of the test is favorable, testing continues with the load being reduced inStep 150. - In
Step 155, carbon monoxide is added to the reactant gases and inStep 160 the load is again increased. The system is held at the same flow rates and temperature for a period of time inStep 170 and in Step 175 a voltage drop test is performed. The membranes utilized in the fuel cells may be platinum on one side and a platinum- ruthenium alloy on the opposite side. Alternatively, membranes and catalysts may be formed of different materials, as is known by those skilled in the art. The introduction of carbon monoxide allows this test to determine if any of the membranes have been installed backwards. Correct installation calls for the membranes to be installed such that the platinum-ruthenium portion faces the reformate portion of a flow channel of a fuel cell. Platinum is not tolerant of carbon monoxide and thus if a membrane was installed backwards the interaction of the carbon monoxide and platinum would cause a voltage drop that would indicate that a membrane has been installed incorrectly. Carbon monoxide attaches itself to the platinum catalyst and prevents an electricity producing reaction from occurring thus causing a particular fuel cell to “drop out.” Such a test may be performed inStep 175 and the result may be compared to predefined criteria. A failed test results in a report being created and the testing being stopped inStep 165. - If the fluid flow plates are determined to be installed correctly, e.g., if there are no membranes which are reversed, then the flow of carbon monoxide is stopped and the reactant gases provided are altered to include hydrogen, nitrogen, and perhaps carbon dioxide in
Step 180. A new data logging rate may be set inStep 185 and the flow rate of reactant gases and desired temperatures of the gases and coolant are set inStep 190. The flow rate of the gases is set at a level which mimics minimum power output for fuel cell stack 32 (FIG. 1) and thus a low current density. A second load is applied inStep 195 also to mimic low electrical demand and the system is run at constant parameters for a period of time inStep 200. A voltage drop test is performed inStep 205 to insure that all the fuel cells are producing electricity at the new load and flow rates of the reactant gases. Results of the test are compared by computingunit 10 to predetermined criteria and a report is created or the operator is otherwise informed if fuel cell stack 32 (FIG. 1) fails the test atStep 210. - If fuel cell stack32 (FIG. 1) passes this test, then in
Step 250 the flow rate is changed and the reactant gas mixture is changed to consist of substantially pure hydrogen and incubation is performed inStep 299, as is known by those skilled in the art. Incubation can be performed in several ways and an exemplary incubation process is described in co-pending U.S. patent application Ser. No. 09/694,768, entitled “METHOD OF PRE-CONDITIONING OF FUEL CELL STACKS FOR SHORT INCUBATION”, and filed Oct. 23, 2000; now U.S. Pat. No. 6,576,356, the entire contents of this application is incorporated herein by reference. - Following incubation, the reactant gas mixture is changed, regulated, or altered to include hydrogen, nitrogen, carbon monoxide and optionally carbon dioxide, in
Step 300. The flow rate is changed inStep 310 and the load is changed inStep 320 to mimic actual full scale operating conditions. The system is run at these parameters for a period of time to equilibrate the system inStep 330 and in Step 340 a voltage drop test is performed. Computing unit 10 (FIG. 1) compares the result of this test to predetermined criteria to determine if the voltage drops of the individual fuel cells are satisfactory, for example, to determine if they are within an accepted range. Also, the average fuel cell voltage drop is determined and it is compared by computing unit 10 (FIG. 1) to a predetermined criteria, for example a power output requirement or, to determine if overall performance of fuel cell stack 32 (FIG. 1) is satisfactory. If the results compare favorably then computing unit 10 (FIG. 1) may communicate a message to the operator via display 40 (FIG. 1) or print a report which indicates that fuel cell stack 32 (FIG. 1) has been qualified for use. In the alternative, if this test is failed, computing unit 10 (FIG. 1) may communicate a message to the operator, or print a report which indicates that fuel cell stack 32 (FIG. 1) has failed the test and is not qualified for use atStep 350. - An additional benefit of the present invention is that during the first several qualification tests described, fuel cell stack32 (FIG. 1) is concurrently being warmed through the heating of the reactant gases and coolant prior to incubation. Testing mechanism 20 (FIG. 1) warms these gases and coolant, for example through a steam injection system. This permits immediate incubation of fuel cell stack 32 (FIG. 1) on completion of these initial tests if fuel cell stack 32 (FIG. 1) has passed all the pre- incubation tests. Since fuel cell stack 32 (FIG. 1) is already at the required temperature, it is not necessary to warm the gases and coolant prior to incubation which can require, e.g., up to thirty minutes to perform.
- It will be appreciated by those skilled in the art that the present invention is applicable to testing the inverter, fuel processor, or other components or subsystems of the fuel cell system.
- Although preferred embodiments have been depicted and described in detail herein, it will be apparent to those skilled in the relevant art that various modifications, additions, substitutions and the like can be made without departing from the spirit of the invention and these are therefore considered to be within the scope of the invention as defined in the following claims.
Claims (28)
1. A method for enabling qualification of a fuel cell system, the method comprising:
performing a first test on a first portion of the fuel cell system;
electronically obtaining a first result of the first test;
electronically comparing the first result to a first qualifying criteria; and
performing a second test on a second portion of the fuel cell system in response to the first result comparing favorably relative to the first qualifying criteria.
2. The method of claim 1 wherein the first test is different from the second test.
3. The method of claim 2 further comprising:
electronically obtaining a second result of the second test;
electronically comparing the second result to a second qualifying criteria; and
providing an indication that the fuel cell is functioning properly to produce electrical energy in response to the electronically comparing the first result and the electronically comparing the second result.
4. The method of claim 1 wherein the first test comprises a first measurement of performance of the fuel cell system and the second test comprises a second measurement of performance of the fuel cell system, the first test being different from the second test.
5. The method of claim 1 wherein the first test comprises a first electrical demand, a first reactant gas composition, and a first temperature of reactant gas, wherein the second test comprises a second electrical demand, a second reactant gas composition, and a second temperature of reactant gas, and wherein at least one of the first electrical demand differs from the second electrical demand, the first temperature differs from the second temperature, and the first reactant gas composition differs from the second reactant gas composition.
6. The method of claim 1 wherein the performing the first test and the performing the second test comprise warming the fuel cell system prior to incubation of the fuel cell system.
7. A method for enabling qualification of a fuel cell stack, the method comprising:
providing a flow rate of reactant gases to the fuel cell stack to mimic full scale operating conditions;
applying a load to the fuel cell stack to mimic the full scale operating conditions;
electronically obtaining at least one measurement of voltage drop from a voltage drop test across a plurality of fuel cells of the fuel cell stack;
electronically comparing the at least one measurement of voltage drop of the voltage drop test to a qualifying criteria; and
providing at least one of an indication that each fuel cell of the fuel cell stack is functioning properly to produce electrical energy and an indication that each fuel cell is not functioning properly in response to the comparison of the at least one measurement of voltage drop of the voltage drop test to the qualifying criteria.
8. The method of claim 7 further comprising:
determining an average of fuel cell voltage drop from the at least one measurement of voltage drop of the voltage drop test;
electronically comparing the average to a second qualifying criteria; and
providing an indication regarding an electrical output capability of the fuel cell stack based on the comparison of the average to the second qualifying criteria.
9. An apparatus for enabling qualification of at least a portion of a fuel cell system comprising:
a testing mechanism couplable to the at least a portion of a fuel cell system;
a computing unit couplable to said testing mechanism; and
wherein said testing mechanism is configured to perform a first test on the at least a portion of a fuel cell system;
wherein the computing unit is configured to control the testing mechanism to obtain a first result of the first test on the at least a portion of a fuel cell system and to compare the first result to a first qualification criteria; and
wherein the computing unit is configured to provide an indication: that the fuel cell system is disqualified in response to the first result comparing negatively relative to the first qualification criteria, that the system is qualified in response to the first result comparing favorably relative to the first qualification criteria and the first test being a last test of a plurality of tests, and that the fuel cell system requires further testing in response to the first result comparing favorably relative to the first qualification criteria.
10. The apparatus of claim 9 wherein the computing unit is configured to control the testing mechanism to obtain a second result of a second test in response to the first result comparing favorably relative to the first qualification criteria.
11. The apparatus of claim 9 wherein the computing unit is configured to cause the testing mechanism to perform a second test on the at least a portion of the fuel cell system, in response to the first result comparing favorably to the first qualification criteria.
12. The apparatus of claim 11 wherein the first test comprises a first electrical demand, a first reactant gas composition, and a first temperature of reactant gas, wherein the second test comprises a second electrical demand, a second reactant gas composition, and a second temperature of reactant gas, and wherein at least one of the first electrical demand differs from the second electrical demand, the first temperature differs from the second temperature, and the first reactant gas composition differs from the second reactant gas composition.
13. The apparatus of claim 11 wherein the performing the first test and the performing the second test comprise warming the fuel cell system prior to incubation of the fuel cell system.
14. The apparatus of claim 9 wherein the computing unit is configured to control the testing mechanism to obtain the first result before incubation of the at least a portion of the fuel cell system.
15. An apparatus for enabling qualification of a fuel cell system comprising:
means for electronically obtaining a result of a test on the fuel cell system;
means for electronically comparing the result to at least one qualifying criteria; and
means for indicating: that the fuel cell system is qualified in response to the result comparing favorably relative to the at least one qualifying criteria and the first test being a last test of a plurality of tests, that the system is disqualified in response to the result comparing negatively relative to the at least one qualifying criteria, and that the fuel cell system requires further testing in response to the result comparing favorably relative to the at least one qualifying criteria.
16. The apparatus of claim 15 wherein the means for electronically obtaining is configured to obtain a second result of a second test in response to the result comparing favorably relative to the at least one qualifying criteria.
17. The apparatus of claim 16 wherein the test comprises a first electrical demand, a first reactant gas composition, and a first temperature of reactant gas, wherein the second test comprises a second electrical demand, a second reactant gas composition, and a second temperature of reactant gas, and wherein at least one of the first electrical demand differs from the second electrical demand, the first temperature differs from the second temperature, and the first reactant gas composition differs from the second reactant gas composition.
18. The apparatus of claim 16 wherein performing the test and performing the second test comprise warming the fuel cell system prior to incubation of the fuel cell system.
19. An apparatus for enabling qualification of at least a portion of a fuel cell system comprising:
a first computing unit adapted to obtain a first result of a first test on the at least a portion of a fuel cell system;
a second computing unit adapted to compare the first result to at least one qualifying criteria;
and a third computing unit adapted to provide an indication: that the fuel cell system is disqualified in response to the first result comparing negatively relative to the first qualification criteria, that the system is qualified in response to the first result comparing favorably relative to the first qualification criteria and the first test being a last test of a plurality of tests, and that the fuel cell system requires further testing in response to the first result comparing favorably relative to the first qualification criteria.
20. The apparatus of claim 19 wherein the first computing unit is adapted to control a testing mechanism to obtain a second result of a second test in response to the first result comparing favorably relative to the first qualification criteria.
21. The apparatus of claim 20 wherein the first test comprises a first electrical demand, a first reactant gas composition, and a first temperature of reactant gas, wherein the second test comprises a second electrical demand, a second reactant gas composition, and a second temperature of reactant gas, and wherein at least one of the first electrical demand differs from the second electrical demand, the first temperature differs from the second temperature, and the first reactant gas composition differs from the second reactant gas composition.
22. The apparatus of claim 20 wherein performing the first test and performing the second test comprise warming the fuel cell system prior to incubation of the fuel cell system.
23. The apparatus of claim 19 wherein the first computing unit, the second computing unit, and the third computing unit comprise a same computing unit.
24. An article of manufacture comprising:
at least one computer usable medium having computer readable program code means embodied therein for enabling qualification of at least a portion of a fuel cell system, the computer readable program code means in said article of manufacture comprising:
computer readable program code means for causing a computing unit to obtain a first result of a first test on the at least a portion of a fuel cell system;
computer readable program code means for electronically comparing the first result to at least one qualifying criteria; and
computer readable program code means for providing an indication: that the fuel cell system is disqualified in response to the first result comparing negatively relative to the first qualification criteria, that the system is qualified in response to the first result comparing favorably relative to the first qualification criteria and the first test being a last test of a plurality of tests, and that the fuel cell system requires further testing in response to the first result comparing favorably relative to the first qualification criteria.
25. The article of manufacture of claim 24 further comprising computer readable program code for causing the computing unit to obtain a second result of a second test in response to the first result comparing favorably relative to the first qualification criteria.
26. The article of manufacture of claim 24 wherein the first test comprises a first electrical demand, a first reactant gas composition, and a first temperature of reactant gas, wherein the second test comprises a second electrical demand, a second reactant gas composition, and a second temperature of reactant gas, and wherein at least one of the first electrical demand differs from the second electrical demand, the first temperature differs from the second temperature, and the first reactant gas composition differs from the second reactant gas composition.
27. The article of manufacture of claim 25 wherein performing the first test and performing the second test comprise warming the fuel cell system prior to incubation of the fuel cell system.
28. The article of manufacture of claim 24 wherein the obtaining the first result comprises obtaining the first result of the first test before incubation of the at least a portion of the fuel cell system.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/879,551 US20040253488A1 (en) | 2000-11-30 | 2004-06-29 | Method of qualifying at least a portion of a fuel cell system and an apparatus employing same |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/726,839 US6774637B2 (en) | 2000-11-30 | 2000-11-30 | Method of qualifying at least a portion of a fuel cell system and an apparatus employing same |
US10/879,551 US20040253488A1 (en) | 2000-11-30 | 2004-06-29 | Method of qualifying at least a portion of a fuel cell system and an apparatus employing same |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09/726,839 Continuation US6774637B2 (en) | 2000-11-30 | 2000-11-30 | Method of qualifying at least a portion of a fuel cell system and an apparatus employing same |
Publications (1)
Publication Number | Publication Date |
---|---|
US20040253488A1 true US20040253488A1 (en) | 2004-12-16 |
Family
ID=24920220
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09/726,839 Expired - Fee Related US6774637B2 (en) | 2000-11-30 | 2000-11-30 | Method of qualifying at least a portion of a fuel cell system and an apparatus employing same |
US10/879,551 Abandoned US20040253488A1 (en) | 2000-11-30 | 2004-06-29 | Method of qualifying at least a portion of a fuel cell system and an apparatus employing same |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09/726,839 Expired - Fee Related US6774637B2 (en) | 2000-11-30 | 2000-11-30 | Method of qualifying at least a portion of a fuel cell system and an apparatus employing same |
Country Status (1)
Country | Link |
---|---|
US (2) | US6774637B2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006096956A1 (en) * | 2005-03-17 | 2006-09-21 | Hydrogenics Corporation | Method, system and apparatus for diagnostic testing of an electrochemical cell stack |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6774637B2 (en) * | 2000-11-30 | 2004-08-10 | Plug Power, Inc. | Method of qualifying at least a portion of a fuel cell system and an apparatus employing same |
US6889147B2 (en) * | 2002-09-17 | 2005-05-03 | Hydrogenics Corporation | System, computer program product and method for controlling a fuel cell testing device |
DE10258865B4 (en) * | 2002-12-17 | 2019-12-12 | Robert Bosch Gmbh | Fuel cell system with a starting device |
JP2007529854A (en) * | 2004-03-15 | 2007-10-25 | ハイドロジェニクス コーポレイション | Test station for fuel cell power module |
CN104035033A (en) * | 2013-03-06 | 2014-09-10 | 绿洲混合动力科技有限公司 | System and method for controlling battery test equipment |
CN113642265A (en) * | 2021-06-29 | 2021-11-12 | 东风汽车集团股份有限公司 | Method and device for evaluating fluid flow of fuel cell short stack |
Citations (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4904548A (en) * | 1987-08-03 | 1990-02-27 | Fuji Electric Co., Ltd. | Method for controlling a fuel cell |
US5013617A (en) * | 1989-12-29 | 1991-05-07 | International Fuel Cells Corporation | Air ejector system for fuel cell passivation |
US5170124A (en) * | 1990-06-08 | 1992-12-08 | Minister Of National Defence Of Her Majesty's Canadian Government | Method and apparatus for monitoring fuel cell performance |
US5512831A (en) * | 1994-11-23 | 1996-04-30 | Lynntech, Inc. | Method and apparatus for testing electrochemical energy conversion devices |
US5605770A (en) * | 1995-05-04 | 1997-02-25 | Finmeccanica S.P.A. Azienda Ansaldo | Supply system for fuel cells of the S.P.E. (solid polymer electrolyte) type for hybrid vehicles |
US5763113A (en) * | 1996-08-26 | 1998-06-09 | General Motors Corporation | PEM fuel cell monitoring system |
US5928805A (en) * | 1997-11-20 | 1999-07-27 | Siemens Westinghouse Power Corporation | Cover and startup gas supply system for solid oxide fuel cell generator |
US5945229A (en) * | 1997-02-28 | 1999-08-31 | General Motors Corporation | Pattern recognition monitoring of PEM fuel cell |
US6007930A (en) * | 1998-05-06 | 1999-12-28 | Ford Global Technologies, Inc. | Method for initiating a fuel cell |
US6063516A (en) * | 1997-10-24 | 2000-05-16 | General Motors Corporation | Method of monitoring CO concentrations in hydrogen feed to a PEM fuel cell |
US6093500A (en) * | 1998-07-28 | 2000-07-25 | International Fuel Cells Corporation | Method and apparatus for operating a fuel cell system |
US6096449A (en) * | 1997-11-20 | 2000-08-01 | Avista Labs | Fuel cell and method for controlling same |
US6103410A (en) * | 1998-06-05 | 2000-08-15 | International Fuel Cells Corporation | Start up of frozen fuel cell |
US20040053089A1 (en) * | 2002-09-16 | 2004-03-18 | Balliet Ryan J. | System for determining a gas composition within a shut down fuel cell power plant and method of operation |
US20040124843A1 (en) * | 2002-12-17 | 2004-07-01 | Shigetaka Hamada | Diagnostic method for fuel cell |
US6774637B2 (en) * | 2000-11-30 | 2004-08-10 | Plug Power, Inc. | Method of qualifying at least a portion of a fuel cell system and an apparatus employing same |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58206071A (en) | 1982-05-25 | 1983-12-01 | Mitsubishi Electric Corp | Fuel-cell controlling device |
JP3451111B2 (en) | 1993-06-29 | 2003-09-29 | 本田技研工業株式会社 | Control method of polymer electrolyte fuel cell |
JPH0837013A (en) | 1994-07-26 | 1996-02-06 | Toshiba Corp | Fuel cell device |
-
2000
- 2000-11-30 US US09/726,839 patent/US6774637B2/en not_active Expired - Fee Related
-
2004
- 2004-06-29 US US10/879,551 patent/US20040253488A1/en not_active Abandoned
Patent Citations (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4904548A (en) * | 1987-08-03 | 1990-02-27 | Fuji Electric Co., Ltd. | Method for controlling a fuel cell |
US5013617A (en) * | 1989-12-29 | 1991-05-07 | International Fuel Cells Corporation | Air ejector system for fuel cell passivation |
US5170124A (en) * | 1990-06-08 | 1992-12-08 | Minister Of National Defence Of Her Majesty's Canadian Government | Method and apparatus for monitoring fuel cell performance |
US5512831A (en) * | 1994-11-23 | 1996-04-30 | Lynntech, Inc. | Method and apparatus for testing electrochemical energy conversion devices |
US5605770A (en) * | 1995-05-04 | 1997-02-25 | Finmeccanica S.P.A. Azienda Ansaldo | Supply system for fuel cells of the S.P.E. (solid polymer electrolyte) type for hybrid vehicles |
US5763113A (en) * | 1996-08-26 | 1998-06-09 | General Motors Corporation | PEM fuel cell monitoring system |
US5945229A (en) * | 1997-02-28 | 1999-08-31 | General Motors Corporation | Pattern recognition monitoring of PEM fuel cell |
US6063516A (en) * | 1997-10-24 | 2000-05-16 | General Motors Corporation | Method of monitoring CO concentrations in hydrogen feed to a PEM fuel cell |
US6096449A (en) * | 1997-11-20 | 2000-08-01 | Avista Labs | Fuel cell and method for controlling same |
US5928805A (en) * | 1997-11-20 | 1999-07-27 | Siemens Westinghouse Power Corporation | Cover and startup gas supply system for solid oxide fuel cell generator |
US6007930A (en) * | 1998-05-06 | 1999-12-28 | Ford Global Technologies, Inc. | Method for initiating a fuel cell |
US6103410A (en) * | 1998-06-05 | 2000-08-15 | International Fuel Cells Corporation | Start up of frozen fuel cell |
US6093500A (en) * | 1998-07-28 | 2000-07-25 | International Fuel Cells Corporation | Method and apparatus for operating a fuel cell system |
US6774637B2 (en) * | 2000-11-30 | 2004-08-10 | Plug Power, Inc. | Method of qualifying at least a portion of a fuel cell system and an apparatus employing same |
US20040053089A1 (en) * | 2002-09-16 | 2004-03-18 | Balliet Ryan J. | System for determining a gas composition within a shut down fuel cell power plant and method of operation |
US20040124843A1 (en) * | 2002-12-17 | 2004-07-01 | Shigetaka Hamada | Diagnostic method for fuel cell |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006096956A1 (en) * | 2005-03-17 | 2006-09-21 | Hydrogenics Corporation | Method, system and apparatus for diagnostic testing of an electrochemical cell stack |
Also Published As
Publication number | Publication date |
---|---|
US6774637B2 (en) | 2004-08-10 |
US20020064694A1 (en) | 2002-05-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US7544430B2 (en) | Online detection of stack crossover rate for adaptive hydrogen bleed strategy | |
US20110287327A1 (en) | Detection of small anode leaks in fuel cell systems | |
US11043682B2 (en) | Method to detect fuel cell gas leak | |
US20030077495A1 (en) | Fuel cell system, and method of testing a fuel cell for a gas leak | |
US6893756B2 (en) | Lambda sensing with a fuel cell stack | |
US8900767B2 (en) | Algorithm for in-situ quantification of PEMFC membrane health over its life | |
US20050260471A1 (en) | Electrical current measurement in a fuel cell | |
US8268494B2 (en) | Fuel cell system | |
US20050064252A1 (en) | Method for operating polymer electrolyte fuel cell | |
US6774637B2 (en) | Method of qualifying at least a portion of a fuel cell system and an apparatus employing same | |
US20230411655A1 (en) | Methods and apparatus for end-of-line testing of fuel cell stacks and electrolyzers | |
Harel et al. | PEMFC durability test under specific dynamic current solicitation, linked to a vehicle road cycle | |
Chen et al. | Analytical methods for the effect of anode nitrogen concentration on performance and voltage consistency of proton exchange membrane fuel cell stack | |
US8765318B2 (en) | System and method for electrochemical cell system and leak detection and indication | |
KR102068009B1 (en) | Fault diagnosis method of fuel cell air supply system | |
KR20160016967A (en) | Health monitoring of an electrochemical cell stack | |
JP2010108815A (en) | Electrochemical device | |
CN116072936A (en) | On-line detection device and method for leakage of proton exchange membrane fuel cell stack | |
JP6170796B2 (en) | Fuel cell diagnostic method and operation method | |
US20130017465A1 (en) | Leakage diagnostic for a fuel cell system in idle-stop mode | |
US8192878B2 (en) | Method and algorithm to detect frozen anode pressure sensor | |
JP2002056883A (en) | Fuel cell device and operating method for the same | |
US20130004872A1 (en) | Method for early detection of membrane failures of fuel cell stacks and fuel cell system component defects | |
CN117217031B (en) | Intelligent production method and system for fuel cell stack | |
US20230327154A1 (en) | Assessing health of a fuel stack using fuel cell voltage diagnostics |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |