US20050025909A1 - Method for the production of III-V laser components - Google Patents

Method for the production of III-V laser components Download PDF

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Publication number
US20050025909A1
US20050025909A1 US10/872,902 US87290204A US2005025909A1 US 20050025909 A1 US20050025909 A1 US 20050025909A1 US 87290204 A US87290204 A US 87290204A US 2005025909 A1 US2005025909 A1 US 2005025909A1
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Prior art keywords
iii
substrate
layer
deposited
buffer layer
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Abandoned
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US10/872,902
Inventor
Holger Jurgensen
Alois Krost
Armin Dadgar
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Aixtron SE
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Aixtron SE
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Priority claimed from DE10206750A external-priority patent/DE10206750A1/en
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Assigned to AIXTRON AG reassignment AIXTRON AG ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: DADGAR, ARMIN, KROST, ALOIS, JURGENSEN, HOLGER
Publication of US20050025909A1 publication Critical patent/US20050025909A1/en
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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/30Structure or shape of the active region; Materials used for the active region
    • H01S5/32Structure or shape of the active region; Materials used for the active region comprising PN junctions, e.g. hetero- or double- heterostructures
    • H01S5/323Structure or shape of the active region; Materials used for the active region comprising PN junctions, e.g. hetero- or double- heterostructures in AIIIBV compounds, e.g. AlGaAs-laser, InP-based laser
    • H01S5/32308Structure or shape of the active region; Materials used for the active region comprising PN junctions, e.g. hetero- or double- heterostructures in AIIIBV compounds, e.g. AlGaAs-laser, InP-based laser emitting light at a wavelength less than 900 nm
    • H01S5/32341Structure or shape of the active region; Materials used for the active region comprising PN junctions, e.g. hetero- or double- heterostructures in AIIIBV compounds, e.g. AlGaAs-laser, InP-based laser emitting light at a wavelength less than 900 nm blue laser based on GaN or GaP
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02104Forming layers
    • H01L21/02365Forming inorganic semiconducting materials on a substrate
    • H01L21/02367Substrates
    • H01L21/0237Materials
    • H01L21/02373Group 14 semiconducting materials
    • H01L21/02381Silicon, silicon germanium, germanium
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02104Forming layers
    • H01L21/02365Forming inorganic semiconducting materials on a substrate
    • H01L21/02367Substrates
    • H01L21/02433Crystal orientation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02104Forming layers
    • H01L21/02365Forming inorganic semiconducting materials on a substrate
    • H01L21/02436Intermediate layers between substrates and deposited layers
    • H01L21/02439Materials
    • H01L21/02455Group 13/15 materials
    • H01L21/02458Nitrides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02104Forming layers
    • H01L21/02365Forming inorganic semiconducting materials on a substrate
    • H01L21/02518Deposited layers
    • H01L21/02521Materials
    • H01L21/02538Group 13/15 materials
    • H01L21/0254Nitrides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/02Structural details or components not essential to laser action
    • H01S5/0206Substrates, e.g. growth, shape, material, removal or bonding
    • H01S5/021Silicon based substrates

Definitions

  • the invention relates to a method for producing III-V laser components, in which a III-V semiconductor layer, for example gallium nitride, is deposited on a silicon substrate from gaseous starting substances, for example trimethylgallium, trimethylindium, trimethylaluminum, phosphine or arsine, in a process chamber of a reactor.
  • a III-V semiconductor layer for example gallium nitride
  • gaseous starting substances for example trimethylgallium, trimethylindium, trimethylaluminum, phosphine or arsine
  • III nitride semiconductors on substrates of a different type such as for example sapphire, silicon carbite or silicon
  • this substrate material is less expensive than III-V substrate material.
  • one problem of this process is the lattice mismatch of the layer on the substrate. Suitable selection of the substrate material for the layer material allows matching to be effected, for example gallium nitride grows at a position rotated through 30° with respect to the sapphire, and thereby eliminates part of the lattice mismatch.
  • gallium nitride grows at a position rotated through 30° with respect to the sapphire, and thereby eliminates part of the lattice mismatch.
  • this rotated growth there is no common fracture or cleavage direction for the layer and the substrate.
  • the fracture line generally runs along the fracture line or cleavage line of the substrate, since the latter is considerably thicker than the layer deposited thereon. In the case described above, this leads to a rough laser facet which has to be reworked. Also, with laser mirrors produced in this manner, undesirable losses are produced in the event of, for example, a wet-chemical after treatment. The roughness of the laser mirrors or facets which are not precisely oriented lead to losses and thereby cause a high threshold current, which is associated with an increased thermal load in the subsequent component.
  • the invention is based on the object of providing an inexpensive method for producing high-quality lasers.
  • an aluminum-containing buffer layer is deposited on an Si substrate, in particular an Si( 111 ) substrate. This is carried out by means of MOCVD.
  • This buffer layer may consist of aluminum nitride and may be 20 to 100 nm thick.
  • the active III-V layer preferably a III nitride layer, and particularly preferably a gallium nitride layer, or a sequence of such layers for component layers, is deposited on this buffer layer, in such a manner that the lattice plane of the layer runs parallel to the cleavage direction of the substrate.
  • the fracture When the substrate is fractured, the fracture then takes place along a crystalographically suitable surface.
  • the fracture takes place substantially along one plane.
  • the fracture or cleavage lines of the Si( 111 ) substrate can then be selected in such a way that plane-parallel layer fracture surfaces are formed. These layer fracture surfaces then form the laser facets.
  • the laser facets are therefore formed simply by breaking or cleaving. This is possible on account of the fact that the crystalographic fracture direction of the silicon substrate and of the structure based on gallium nitride coincide.
  • a pertinent factor in this context is the aluminum-containing seed layer.
  • a seed layer of this type even allows gallium nitride which is matched in terms of fraction direction to be deposited on Si( 001 ). The only problem in this case is the absence of common crystal symmetry.
  • layers can be deposited on the layer sequence described above.
  • the pertinent factor is that the hexagonal crystal of gallium nitride is deposited on the cubic crystal lattice of the silicon with a corresponding crystal orientation, in such a manner that the natural fracture directions of the two crystals coincide in the plane in such a manner that plane-parallel laser facets are formed by simply fracturing the substrate along the natural fracture lines.

Abstract

The invention relates to a method for the production of III-V laser components, whereby a III-V semiconductor layer is deposited on a silicon substrate in a process chamber of a reactor from a gaseous starting material. According to the invention, an economical method for the production of qualitatively high-grade laser may be achieved whereby, firstly, an Al-containing buffer layer is deposited on the Si substrate, in particular a Si(III) substrate, on which the III-V semiconductor layer, in particular, GaN is then deposited such that the lattice plane thereof runs parallel to the cleavage direction of the substrate, whereby, on cleaving the substrate plane-parallel layer, cleavage surfaces are formed.

Description

  • This application is a continuation of pending International Patent Application No. PCT/EP02/12799 filed Nov. 15, 2002 which designates the United States and claims priority of pending German Patent Application Nos. 101 63 714.4 filed Dec. 21, 2001 and 102 06 750.3 filed Feb. 19, 2002.
  • The invention relates to a method for producing III-V laser components, in which a III-V semiconductor layer, for example gallium nitride, is deposited on a silicon substrate from gaseous starting substances, for example trimethylgallium, trimethylindium, trimethylaluminum, phosphine or arsine, in a process chamber of a reactor.
  • The deposition of III nitride semiconductors on substrates of a different type, such as for example sapphire, silicon carbite or silicon, is a cost-saving process, since this substrate material is less expensive than III-V substrate material. However, one problem of this process is the lattice mismatch of the layer on the substrate. Suitable selection of the substrate material for the layer material allows matching to be effected, for example gallium nitride grows at a position rotated through 30° with respect to the sapphire, and thereby eliminates part of the lattice mismatch. However, on account of this rotated growth there is no common fracture or cleavage direction for the layer and the substrate. The fracture line generally runs along the fracture line or cleavage line of the substrate, since the latter is considerably thicker than the layer deposited thereon. In the case described above, this leads to a rough laser facet which has to be reworked. Also, with laser mirrors produced in this manner, undesirable losses are produced in the event of, for example, a wet-chemical after treatment. The roughness of the laser mirrors or facets which are not precisely oriented lead to losses and thereby cause a high threshold current, which is associated with an increased thermal load in the subsequent component.
  • The invention is based on the object of providing an inexpensive method for producing high-quality lasers.
  • The object is achieved by the invention defined in the claims, in which it is substantially provided that first of all an aluminum-containing buffer layer is deposited on an Si substrate, in particular an Si(111) substrate. This is carried out by means of MOCVD. This buffer layer may consist of aluminum nitride and may be 20 to 100 nm thick. Then, in the same reactor and preferably without any further intermediate steps, the active III-V layer, preferably a III nitride layer, and particularly preferably a gallium nitride layer, or a sequence of such layers for component layers, is deposited on this buffer layer, in such a manner that the lattice plane of the layer runs parallel to the cleavage direction of the substrate. When the substrate is fractured, the fracture then takes place along a crystalographically suitable surface. The fracture takes place substantially along one plane. The fracture or cleavage lines of the Si(111) substrate can then be selected in such a way that plane-parallel layer fracture surfaces are formed. These layer fracture surfaces then form the laser facets. The laser facets are therefore formed simply by breaking or cleaving. This is possible on account of the fact that the crystalographic fracture direction of the silicon substrate and of the structure based on gallium nitride coincide.
  • A pertinent factor in this context is the aluminum-containing seed layer. A seed layer of this type even allows gallium nitride which is matched in terms of fraction direction to be deposited on Si(001). The only problem in this case is the absence of common crystal symmetry.
  • If necessary, further, in particular electrically active, layers can be deposited on the layer sequence described above. The pertinent factor, however, is that the hexagonal crystal of gallium nitride is deposited on the cubic crystal lattice of the silicon with a corresponding crystal orientation, in such a manner that the natural fracture directions of the two crystals coincide in the plane in such a manner that plane-parallel laser facets are formed by simply fracturing the substrate along the natural fracture lines.
  • All features disclosed are (inherently) pertinent to the invention. The disclosure content of the associated/appended priority documents (copy of the prior application) is hereby incorporated in its entirety in the disclosure of the application, partly with a view to incorporating features of these documents in claims of the present application.

Claims (3)

1. Method for producing III-V laser components, in which a III-V semiconductor layer is deposited on a silicon substrate, in particular an Si(111) substrate, from gaseous starting substances in a process chamber of a reactor, wherein first of all an Al-containing buffer layer is deposited on the Si substrate, then the III-V semiconductor layer, in particular a GAN layer, and if appropriate further active layers, are deposited on the buffer layer, in such a manner that the lattice plane thereof runs parallel to the cleavage direction of the substrate, plane-parallel layer fracture surfaces then being produced by cleaving the substrate in the cleavage direction, and components in which the layer fracture surfaces form the laser facets subsequently being fabricated.
2. Method according to claim 1, characterized in that the buffer layer consists of AIN or AIN with the addition of one or more further elements from group III or V.
3. Method according to claim 1, characterized in that the buffer layer is a III-V semiconductor layer and is between 20 and 100 nm thick.
US10/872,902 2001-12-21 2004-06-21 Method for the production of III-V laser components Abandoned US20050025909A1 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
DE10163714 2001-12-21
DE10163714.4 2001-12-21
DE10206750.3 2002-02-19
DE10206750A DE10206750A1 (en) 2001-12-21 2002-02-19 Process for the manufacture of III-V laser components
PCT/EP2002/012799 WO2003054921A2 (en) 2001-12-21 2002-11-15 Method for the production of iii-v laser components

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2002/012799 Continuation WO2003054921A2 (en) 2001-12-21 2002-11-15 Method for the production of iii-v laser components

Publications (1)

Publication Number Publication Date
US20050025909A1 true US20050025909A1 (en) 2005-02-03

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US10/872,902 Abandoned US20050025909A1 (en) 2001-12-21 2004-06-21 Method for the production of III-V laser components

Country Status (5)

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US (1) US20050025909A1 (en)
EP (1) EP1459365A2 (en)
JP (1) JP2005513797A (en)
AU (1) AU2002356608A1 (en)
WO (1) WO2003054921A2 (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080220555A1 (en) * 2007-03-09 2008-09-11 Adam William Saxler Nitride semiconductor structures with interlayer structures and methods of fabricating nitride semiconductor structures with interlayer structures
US20080217645A1 (en) * 2007-03-09 2008-09-11 Adam William Saxler Thick nitride semiconductor structures with interlayer structures and methods of fabricating thick nitride semiconductor structures
US8759169B2 (en) 2009-10-31 2014-06-24 X—FAB Semiconductor Foundries AG Method for producing silicon semiconductor wafers comprising a layer for integrating III-V semiconductor components
US9344200B2 (en) 2014-10-08 2016-05-17 International Business Machines Corporation Complementary metal oxide semiconductor device with III-V optical interconnect having III-V epitaxial semiconductor material formed using lateral overgrowth
US9395489B2 (en) 2014-10-08 2016-07-19 International Business Machines Corporation Complementary metal oxide semiconductor device with III-V optical interconnect having III-V epitaxially formed material
US9595805B2 (en) 2014-09-22 2017-03-14 International Business Machines Corporation III-V photonic integrated circuits on silicon substrate

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11308477B2 (en) 2005-04-26 2022-04-19 Spriv Llc Method of reducing fraud in on-line transactions
US11818287B2 (en) 2017-10-19 2023-11-14 Spriv Llc Method and system for monitoring and validating electronic transactions
US11354667B2 (en) 2007-05-29 2022-06-07 Spriv Llc Method for internet user authentication
US11792314B2 (en) 2010-03-28 2023-10-17 Spriv Llc Methods for acquiring an internet user's consent to be located and for authenticating the location information

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US5654583A (en) * 1994-06-24 1997-08-05 Hitachi, Ltd. Semiconductor device having first and second semiconductor structures directly bonded to each other
US6080599A (en) * 1995-03-30 2000-06-27 Kabushiki Kaisha Toshiba Semiconductor optoelectric device and method of manufacturing the same
US6121121A (en) * 1997-11-07 2000-09-19 Toyoda Gosei Co., Ltd Method for manufacturing gallium nitride compound semiconductor
US20020197841A1 (en) * 2001-06-05 2002-12-26 Seiji Nagai Group III nitride compound semiconductor element and method for producing the same
US20030136333A1 (en) * 2000-06-09 2003-07-24 Fabrice Semond Preparation method of a coating of gallium nitride
US6703253B2 (en) * 2001-11-15 2004-03-09 Sharp Kabushiki Kaisha Method for producing semiconductor light emitting device and semiconductor light emitting device produced by such method

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AU2430401A (en) * 1999-12-13 2001-06-18 North Carolina State University Methods of fabricating gallium nitride layers on textured silicon substrates, and gallium nitride semiconductor structures fabricated thereby
US6649287B2 (en) * 2000-12-14 2003-11-18 Nitronex Corporation Gallium nitride materials and methods

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5654583A (en) * 1994-06-24 1997-08-05 Hitachi, Ltd. Semiconductor device having first and second semiconductor structures directly bonded to each other
US6080599A (en) * 1995-03-30 2000-06-27 Kabushiki Kaisha Toshiba Semiconductor optoelectric device and method of manufacturing the same
US6121121A (en) * 1997-11-07 2000-09-19 Toyoda Gosei Co., Ltd Method for manufacturing gallium nitride compound semiconductor
US20030136333A1 (en) * 2000-06-09 2003-07-24 Fabrice Semond Preparation method of a coating of gallium nitride
US20020197841A1 (en) * 2001-06-05 2002-12-26 Seiji Nagai Group III nitride compound semiconductor element and method for producing the same
US6703253B2 (en) * 2001-11-15 2004-03-09 Sharp Kabushiki Kaisha Method for producing semiconductor light emitting device and semiconductor light emitting device produced by such method

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9054017B2 (en) 2007-03-09 2015-06-09 Cree, Inc. Thick nitride semiconductor structures with interlayer structures and methods of fabricating thick nitride semiconductor structures
US20080220555A1 (en) * 2007-03-09 2008-09-11 Adam William Saxler Nitride semiconductor structures with interlayer structures and methods of fabricating nitride semiconductor structures with interlayer structures
US7825432B2 (en) 2007-03-09 2010-11-02 Cree, Inc. Nitride semiconductor structures with interlayer structures
US8324005B2 (en) 2007-03-09 2012-12-04 Cree, Inc. Methods of fabricating nitride semiconductor structures with interlayer structures
US8362503B2 (en) 2007-03-09 2013-01-29 Cree, Inc. Thick nitride semiconductor structures with interlayer structures
US20080217645A1 (en) * 2007-03-09 2008-09-11 Adam William Saxler Thick nitride semiconductor structures with interlayer structures and methods of fabricating thick nitride semiconductor structures
US8759169B2 (en) 2009-10-31 2014-06-24 X—FAB Semiconductor Foundries AG Method for producing silicon semiconductor wafers comprising a layer for integrating III-V semiconductor components
US9595805B2 (en) 2014-09-22 2017-03-14 International Business Machines Corporation III-V photonic integrated circuits on silicon substrate
US10439356B2 (en) 2014-09-22 2019-10-08 International Business Machines Corporation III-V photonic integrated circuits on silicon substrate
US10756506B2 (en) 2014-09-22 2020-08-25 International Business Machines Corporation III-V photonic integrated circuits on silicon substrate
US9395489B2 (en) 2014-10-08 2016-07-19 International Business Machines Corporation Complementary metal oxide semiconductor device with III-V optical interconnect having III-V epitaxially formed material
US9590393B2 (en) 2014-10-08 2017-03-07 International Business Machines Corporation Complementary metal oxide semiconductor device with III-V optical interconnect having III-V epitaxial semiconductor material formed using lateral overgrowth
US9344200B2 (en) 2014-10-08 2016-05-17 International Business Machines Corporation Complementary metal oxide semiconductor device with III-V optical interconnect having III-V epitaxial semiconductor material formed using lateral overgrowth
US9726819B2 (en) 2014-10-08 2017-08-08 International Business Machines Corporation Complementary metal oxide semiconductor device with III-V optical interconnect having III-V epitaxial semiconductor material formed using lateral overgrowth
US9864135B2 (en) 2014-10-08 2018-01-09 International Business Machines Corporation Complementary metal oxide semiconductor device with III-V optical interconnect having III-V epitaxially formed material

Also Published As

Publication number Publication date
WO2003054921B1 (en) 2004-03-04
WO2003054921A3 (en) 2003-12-24
EP1459365A2 (en) 2004-09-22
WO2003054921A2 (en) 2003-07-03
AU2002356608A1 (en) 2003-07-09
AU2002356608A8 (en) 2003-07-09
JP2005513797A (en) 2005-05-12

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