US20050064265A9 - Gasket material for a fuel cell - Google Patents

Gasket material for a fuel cell Download PDF

Info

Publication number
US20050064265A9
US20050064265A9 US10/389,452 US38945203A US2005064265A9 US 20050064265 A9 US20050064265 A9 US 20050064265A9 US 38945203 A US38945203 A US 38945203A US 2005064265 A9 US2005064265 A9 US 2005064265A9
Authority
US
United States
Prior art keywords
fuel cell
assembly
accordance
cell assembly
mica
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
US10/389,452
Other versions
US7008716B2 (en
US20040180254A1 (en
Inventor
Diane England
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Aptiv Technologies Ag
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/968,270 external-priority patent/US6821667B2/en
Assigned to DELPHI TECHNOLOGIES, INC. reassignment DELPHI TECHNOLOGIES, INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: ENGLAND, DIANE M.
Priority to US10/389,452 priority Critical patent/US7008716B2/en
Application filed by Individual filed Critical Individual
Priority to EP04075618A priority patent/EP1458041A1/en
Publication of US20040180254A1 publication Critical patent/US20040180254A1/en
Publication of US20050064265A9 publication Critical patent/US20050064265A9/en
Assigned to UNITED STATES DEPARTMENT OF ENERGY reassignment UNITED STATES DEPARTMENT OF ENERGY CONFIRMATORY LICENSE (SEE DOCUMENT FOR DETAILS). Assignors: DELPHI AUTOMOTIVE SYSTEMS
Publication of US7008716B2 publication Critical patent/US7008716B2/en
Application granted granted Critical
Assigned to APTIV TECHNOLOGIES LIMITED reassignment APTIV TECHNOLOGIES LIMITED ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: DELPHI TECHNOLOGIES INC.
Adjusted expiration legal-status Critical
Assigned to APTIV TECHNOLOGIES (2) S.À R.L. reassignment APTIV TECHNOLOGIES (2) S.À R.L. ENTITY CONVERSION Assignors: APTIV TECHNOLOGIES LIMITED
Assigned to APTIV MANUFACTURING MANAGEMENT SERVICES S.À R.L. reassignment APTIV MANUFACTURING MANAGEMENT SERVICES S.À R.L. MERGER Assignors: APTIV TECHNOLOGIES (2) S.À R.L.
Assigned to Aptiv Technologies AG reassignment Aptiv Technologies AG ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: APTIV MANUFACTURING MANAGEMENT SERVICES S.À R.L.
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0204—Non-porous and characterised by the material
    • H01M8/0206—Metals or alloys
    • H01M8/0208—Alloys
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16J—PISTONS; CYLINDERS; SEALINGS
    • F16J15/00—Sealings
    • F16J15/02—Sealings between relatively-stationary surfaces
    • F16J15/06—Sealings between relatively-stationary surfaces with solid packing compressed between sealing surfaces
    • F16J15/10—Sealings between relatively-stationary surfaces with solid packing compressed between sealing surfaces with non-metallic packing
    • F16J15/102—Sealings between relatively-stationary surfaces with solid packing compressed between sealing surfaces with non-metallic packing characterised by material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0204—Non-porous and characterised by the material
    • H01M8/0206—Metals or alloys
    • H01M8/0208—Alloys
    • H01M8/021—Alloys based on iron
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0271—Sealing or supporting means around electrodes, matrices or membranes
    • H01M8/0273—Sealing or supporting means around electrodes, matrices or membranes with sealing or supporting means in the form of a frame
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0271—Sealing or supporting means around electrodes, matrices or membranes
    • H01M8/0276—Sealing means characterised by their form
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0271—Sealing or supporting means around electrodes, matrices or membranes
    • H01M8/028—Sealing means characterised by their material
    • H01M8/0282—Inorganic material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/241—Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes
    • H01M8/2425—High-temperature cells with solid electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2465—Details of groupings of fuel cells
    • H01M8/2483—Details of groupings of fuel cells characterised by internal manifolds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2465—Details of groupings of fuel cells
    • H01M8/2484—Details of groupings of fuel cells characterised by external manifolds
    • H01M8/2485—Arrangements for sealing external manifolds; Arrangements for mounting external manifolds around a stack
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M2008/1293—Fuel cells with solid oxide electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2250/00—Fuel cells for particular applications; Specific features of fuel cell system
    • H01M2250/20—Fuel cells in motive systems, e.g. vehicle, ship, plane
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T90/00—Enabling technologies or technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02T90/40—Application of hydrogen technology to transportation, e.g. using fuel cells

Definitions

  • the present invention relates to fuel cells; more particularly, solid-oxide fuel cell assemblies which operate at elevated temperatures; and most particularly, to gasket material for sealing joints between components of such fuel cell assemblies.
  • Fuel cells for combining hydrogen and oxygen to produce electricity are well known.
  • a known class of fuel cells includes a solid oxide electrolyte layer through which oxygen anions migrate; such fuel cells are referred to in the art as “solid-oxide” fuel cells (SOFCs).
  • SOFCs solid-oxide fuel cells
  • an SOFC is preferably fueled by “reformate” gas, which is the effluent from a catalytic gasoline oxidizing reformer.
  • Reformate typically includes amounts of carbon monoxide (CO) as fuel in addition to molecular hydrogen.
  • CO carbon monoxide
  • the reforming operation and the fuel cell operation may be considered as first and second oxidative steps of the liquid hydrocarbon, resulting ultimately in water and carbon dioxide. Both reactions are exothermic, and both are preferably carried out at relatively high temperatures, for example, in the range of 700° C. to 1000° C.
  • a complete fuel cell assembly comprises a plurality of components and sub-assemblies joined together mechanically to provide the desired flow paths and control pathways for the liquid hydrocarbon, reactive gases, spent gases, and cooling gases. It is essential that the joints or interfaces between the components and sub-assemblies be durably leak-free at temperatures from below 0° C. to as high as 1000° C., at pressures from subatmospheric to up to several atmospheres. Such conditions place very high demands on materials selected for gaskets at these joints and interfaces.
  • sealants It is known to use various glass and ceramic compositions as sealants. However, a drawback is that such sealants, though effective, tend to be quite brittle and are easily fractured in assembly or in use. Further, typically they require high-temperature sintering during manufacture of a fuel cell system, which adds difficulty and cost.
  • What is needed is a material for gasketing in an SOFC system which is thermally stable over the range between shutdown and operating temperatures for both the reformer and the fuel cell assembly; which is chemically stable in oxidizing and reducing environments; which is more robust during assembly and during operation of the system; which is compatible with other materials of the system; and which is relatively inexpensive.
  • the port interfaces are sealed by gaskets that include fluorophlogopite mica (F-mica).
  • F-mica fluorophlogopite mica
  • FIG. 1 is an isometric view from above of a fuel cell assembly having gasketing in accordance with the invention.
  • gasketing in accordance with the invention may be best illustrated by considering the exemplary gasketing requirements of an integrated SOFC fuel cell assembly.
  • fuel cell assembly 10 includes a plurality of sub-assemblies and components assembled together generally by bolts.
  • An integrated base manifold 12 comprises a bottom plate 14 , and lower section 16 , an intermediate plate 18 , an upper section 20 , and a top plate 22 .
  • the plates 14 , 18 , 22 have patterns of apertures (not visible) formed therein which mate with other patterns of chambers (also not visible) formed in sections 16 , 20 such that manifold 12 is a three-dimensional structure of interwoven flow paths for various gases.
  • Patterned sheet gaskets 24 , 26 , 28 , 30 in accordance with the invention are provided between the sections and plates to seal the port interfaces against leakage of gases flowing through the manifold.
  • Fuel cell sub-assembly 32 is mounted on manifold 12 , ports (not visible) in the sub-assembly being mateable with ports (not visible) in the manifold to provide reformate from the manifold into the sub-assembly, to exhaust spent reformate from the sub-assembly, and to provide cooling air to and from the assembly.
  • a patterned sheet gasket 34 is disposed therebetween to seal the port interfaces against gas leakage.
  • Manifold 12 and sub-assembly 32 are bolted together by bolts 36 .
  • Fuel cell sub-assembly 32 also contains passage joints (not visible) which are gasketed (not shown) between adjacent plates and fuel cell modules.
  • a hydrocarbon fuel reformer 38 is mounted to manifold 12 via bolts 40 , having a patterned sheet gasket (not visible) therebetween.
  • a fuel pre-heater and vaporization sub-assembly 42 is attached to reformer 38 for supplying heated and vaporized hydrocarbon fuel to the reformer.
  • a patterned sheet gasket 44 is provided therebetween, and sub-assembly 42 is secured to reformer 38 via throughbolts 46 .
  • a cover plate 48 for sub-assembly 42 supports a fuel injector 50 for the reformer.
  • a patterned sheet gasket 52 is provided under the cover plate.
  • Heat exchangers 54 a , 54 b are mounted to manifold 12 via bolts 56 , having a patterned sheet gasket 58 therebetween.
  • Air inlet fittings 60 a , 60 b , 62 are received, as for example by a threaded connection, into bores in manifold 12 , the threads 64 preferably being sealed with gasket material.
  • the various patterned sheet gaskets and the thread-sealing material include, and preferably are formed from, fluorophlogopite mica (F-mica).
  • F-mica a synthetic fluorine mica believed to have the formula KMg 3 (AlSi 3 O 10 )F 2 contains no (OH) ⁇ of natural phlogopite KMg 3 (AlSi 3 O 10 )(OH) 2 .
  • the (OH) ⁇ is fully substituted with F ⁇ .
  • the fluorine mica has the following unique characteristics which are much superior to those of natural mica: high chemical stability, excellent transmittance, outgassing-free at high temperature in vacuum, excellent electrical insulation, high heat endurance (up to 1100° C.), non-radioactive background, and highly flexible and cleavable.
  • F-mica sheets may be made by the processes of, as for example, screening, paper making, inorganic binder impregnating and hot pressing etc. F-mica sheets are known in the prior art for a variety of uses, such as substrates of thin film, windows and monochromater for x-ray, neutron diffraction, microwave and optics, spacers of electrical vacuum devices, scanning electron microscopes, and water gauges of high pressure boilers, which uses are important in industry and science.
  • F-mica has not heretofore been used for gasketing in high-temperature fuel cells, as disclosed herein.
  • Both sheet and tape forms of F-mica are commercially available from, for example, G.B. Group, Inc., New York, N.Y., USA, in thicknesses from 0.05 mm to 5 mm.

Abstract

A solid-oxide fuel cell system comprising a plurality of components having mating ports therebetween, the port interfaces being sealed by gaskets that include fluorophlogopite mica (F-mica).

Description

    TECHNICAL FIELD
  • The present invention relates to fuel cells; more particularly, solid-oxide fuel cell assemblies which operate at elevated temperatures; and most particularly, to gasket material for sealing joints between components of such fuel cell assemblies.
    • BACKGROUND OF THE INVENTION
  • Fuel cells for combining hydrogen and oxygen to produce electricity are well known. A known class of fuel cells includes a solid oxide electrolyte layer through which oxygen anions migrate; such fuel cells are referred to in the art as “solid-oxide” fuel cells (SOFCs).
  • In some applications, for example, as an auxiliary power unit (APU) for an automotive vehicle, an SOFC is preferably fueled by “reformate” gas, which is the effluent from a catalytic gasoline oxidizing reformer. Reformate typically includes amounts of carbon monoxide (CO) as fuel in addition to molecular hydrogen. The reforming operation and the fuel cell operation may be considered as first and second oxidative steps of the liquid hydrocarbon, resulting ultimately in water and carbon dioxide. Both reactions are exothermic, and both are preferably carried out at relatively high temperatures, for example, in the range of 700° C. to 1000° C.
  • A complete fuel cell assembly comprises a plurality of components and sub-assemblies joined together mechanically to provide the desired flow paths and control pathways for the liquid hydrocarbon, reactive gases, spent gases, and cooling gases. It is essential that the joints or interfaces between the components and sub-assemblies be durably leak-free at temperatures from below 0° C. to as high as 1000° C., at pressures from subatmospheric to up to several atmospheres. Such conditions place very high demands on materials selected for gaskets at these joints and interfaces.
  • It is known to use various glass and ceramic compositions as sealants. However, a drawback is that such sealants, though effective, tend to be quite brittle and are easily fractured in assembly or in use. Further, typically they require high-temperature sintering during manufacture of a fuel cell system, which adds difficulty and cost.
  • What is needed is a material for gasketing in an SOFC system which is thermally stable over the range between shutdown and operating temperatures for both the reformer and the fuel cell assembly; which is chemically stable in oxidizing and reducing environments; which is more robust during assembly and during operation of the system; which is compatible with other materials of the system; and which is relatively inexpensive.
  • It is a principle object of the present invention to provide an improved material for gasketing joints and seals in a fuel cell assembly.
    • SUMMARY OF THE INVENTION
  • Briefly described, in a solid-oxide fuel cell assembly comprising a plurality of components having mating ports therebetween, the port interfaces are sealed by gaskets that include fluorophlogopite mica (F-mica).
    • BRIEF DESCRIPTION OF THE DRAWINGS
  • These and other features and advantages of the invention will be more fully understood and appreciated from the following description of certain exemplary embodiments of the invention taken together with the accompanying drawings, in which:
  • FIG. 1 is an isometric view from above of a fuel cell assembly having gasketing in accordance with the invention.
    • DESCRIPTION OF THE PREFERRED EMBODIMENTS
  • The advantage and benefit of gasketing in accordance with the invention may be best illustrated by considering the exemplary gasketing requirements of an integrated SOFC fuel cell assembly.
  • Referring to FIG. 1, fuel cell assembly 10 includes a plurality of sub-assemblies and components assembled together generally by bolts. An integrated base manifold 12 comprises a bottom plate 14, and lower section 16, an intermediate plate 18, an upper section 20, and a top plate 22. The plates 14, 18, 22 have patterns of apertures (not visible) formed therein which mate with other patterns of chambers (also not visible) formed in sections 16, 20 such that manifold 12 is a three-dimensional structure of interwoven flow paths for various gases. Patterned sheet gaskets 24, 26, 28, 30 in accordance with the invention are provided between the sections and plates to seal the port interfaces against leakage of gases flowing through the manifold.
  • Fuel cell sub-assembly 32 is mounted on manifold 12, ports (not visible) in the sub-assembly being mateable with ports (not visible) in the manifold to provide reformate from the manifold into the sub-assembly, to exhaust spent reformate from the sub-assembly, and to provide cooling air to and from the assembly. A patterned sheet gasket 34 is disposed therebetween to seal the port interfaces against gas leakage. Manifold 12 and sub-assembly 32 are bolted together by bolts 36.
  • Fuel cell sub-assembly 32 also contains passage joints (not visible) which are gasketed (not shown) between adjacent plates and fuel cell modules.
  • A hydrocarbon fuel reformer 38 is mounted to manifold 12 via bolts 40, having a patterned sheet gasket (not visible) therebetween. A fuel pre-heater and vaporization sub-assembly 42 is attached to reformer 38 for supplying heated and vaporized hydrocarbon fuel to the reformer. A patterned sheet gasket 44 is provided therebetween, and sub-assembly 42 is secured to reformer 38 via throughbolts 46.
  • A cover plate 48 for sub-assembly 42 supports a fuel injector 50 for the reformer. A patterned sheet gasket 52 is provided under the cover plate.
  • Heat exchangers 54 a, 54 b are mounted to manifold 12 via bolts 56, having a patterned sheet gasket 58 therebetween.
  • Air inlet fittings 60 a, 60 b, 62 are received, as for example by a threaded connection, into bores in manifold 12, the threads 64 preferably being sealed with gasket material.
  • The various patterned sheet gaskets and the thread-sealing material include, and preferably are formed from, fluorophlogopite mica (F-mica). F-mica, a synthetic fluorine mica believed to have the formula KMg3(AlSi3O10)F2 contains no (OH)− of natural phlogopite KMg3(AlSi3O10)(OH)2. The (OH)− is fully substituted with F−. The fluorine mica has the following unique characteristics which are much superior to those of natural mica: high chemical stability, excellent transmittance, outgassing-free at high temperature in vacuum, excellent electrical insulation, high heat endurance (up to 1100° C.), non-radioactive background, and highly flexible and cleavable. F-mica sheets may be made by the processes of, as for example, screening, paper making, inorganic binder impregnating and hot pressing etc. F-mica sheets are known in the prior art for a variety of uses, such as substrates of thin film, windows and monochromater for x-ray, neutron diffraction, microwave and optics, spacers of electrical vacuum devices, scanning electron microscopes, and water gauges of high pressure boilers, which uses are important in industry and science. F-mica has not heretofore been used for gasketing in high-temperature fuel cells, as disclosed herein. Both sheet and tape forms of F-mica are commercially available from, for example, G.B. Group, Inc., New York, N.Y., USA, in thicknesses from 0.05 mm to 5 mm.
  • While the invention has been described by reference to various specific embodiments, it should be understood that numerous changes may be made within the spirit and scope of the inventive concepts described. Accordingly, it is intended that the invention not be limited to the described embodiments, but will have full scope defined by the language of the following claims.

Claims (8)

1. A fuel cell assembly comprising a plurality of components wherein at least one joint between two adjacent components is sealed by a material including fluorophlogopite mica.
2. A fuel cell assembly in accordance with claim 1 wherein said material is formed as a gasket.
3. A fuel cell assembly in accordance with claim 1 wherein said components include passages for flow of gas and wherein said joint is formed for the purpose of joining adjacent passages.
4. A fuel cell assembly in accordance with claim 1 wherein said components include a fuel cell sub-assembly, a manifold, and a hydrocarbon reformer.
5. A fuel cell assembly in accordance with claim 1 wherein said assembly is an auxiliary power unit for a vehicle.
6. A fuel cell assembly in accordance with claim 1 wherein said fluorophlogopite mica is of the formula KMg3(AlSi3O10)F2.
7. A fuel cell assembly in accordance with claim 1 wherein said fuel cell sub-assembly includes a solid-oxide fuel cell.
8. A gasket for a fuel cell assembly comprising fluorophlogopite mica.
US10/389,452 2001-10-01 2003-03-14 Gasket material for a fuel cell Expired - Lifetime US7008716B2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US10/389,452 US7008716B2 (en) 2001-10-01 2003-03-14 Gasket material for a fuel cell
EP04075618A EP1458041A1 (en) 2003-03-14 2004-02-26 Gasket material including mica for a solid oxide fuel cell

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/968,270 US6821667B2 (en) 2001-10-01 2001-10-01 Fuel cell stack having foil interconnects and laminated spacers
US10/389,452 US7008716B2 (en) 2001-10-01 2003-03-14 Gasket material for a fuel cell

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
US09/968,270 Continuation-In-Part US6821667B2 (en) 2001-10-01 2001-10-01 Fuel cell stack having foil interconnects and laminated spacers

Publications (3)

Publication Number Publication Date
US20040180254A1 US20040180254A1 (en) 2004-09-16
US20050064265A9 true US20050064265A9 (en) 2005-03-24
US7008716B2 US7008716B2 (en) 2006-03-07

Family

ID=32771650

Family Applications (1)

Application Number Title Priority Date Filing Date
US10/389,452 Expired - Lifetime US7008716B2 (en) 2001-10-01 2003-03-14 Gasket material for a fuel cell

Country Status (2)

Country Link
US (1) US7008716B2 (en)
EP (1) EP1458041A1 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7222406B2 (en) * 2002-04-26 2007-05-29 Battelle Memorial Institute Methods for making a multi-layer seal for electrochemical devices
US7294424B2 (en) * 2002-06-24 2007-11-13 Delphi Technologies, Inc. Solid-oxide fuel cell assembly having simplified arrangement of current collectors
US7386375B2 (en) * 2004-09-07 2008-06-10 General Motors Corporation Gasoline fuel cell power system transient control
EP2297807A1 (en) * 2008-06-17 2011-03-23 Battelle Memorial Institute Sofc double seal with dimensional control for superior thermal cycle stability
EP2656428A4 (en) * 2010-12-23 2016-10-26 24M Technologies Inc Semi-solid filled battery and method of manufacture
CN104229733B (en) * 2014-07-02 2016-08-24 广东合即得能源科技有限公司 The reformer of methanol-water hydrogen producer and manufacturing process thereof

Citations (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3615838A (en) * 1968-05-10 1971-10-26 Albert C Erickson Fuel cell unit with novel fluid distribution drain and vent features
US3844920A (en) * 1973-11-21 1974-10-29 Gen Motors Corp Air fuel ratio sensor
US5100740A (en) * 1989-09-25 1992-03-31 General Electric Company Direct bonded symmetric-metallic-laminate/substrate structures
US5219673A (en) * 1991-08-23 1993-06-15 Kaun Thomas D Cell structure for electrochemical devices and method of making same
US5505498A (en) * 1994-05-16 1996-04-09 Eg&G Pressure Science, Inc. Flexible pressure-energized joint
US5543239A (en) * 1995-04-19 1996-08-06 Electric Power Research Institute Electrode design for solid state devices, fuel cells and sensors
US5688610A (en) * 1995-07-25 1997-11-18 Dornier Gmbh Device for generating energy
US6054231A (en) * 1998-07-24 2000-04-25 Gas Research Institute Solid oxide fuel cell interconnector
US6074771A (en) * 1998-02-06 2000-06-13 Igr Enterprises, Inc. Ceramic composite electrolytic device and method for manufacture thereof
US6106966A (en) * 1996-01-18 2000-08-22 The Arizona Board Of Regents On Behalf Of The University Of Arizona Single-crystal oxygen ion conductor
US6106967A (en) * 1999-06-14 2000-08-22 Gas Research Institute Planar solid oxide fuel cell stack with metallic foil interconnect
US6326096B1 (en) * 1998-02-04 2001-12-04 Gas Research Institute Solid oxide fuel cell interconnector
US6458477B1 (en) * 1994-08-08 2002-10-01 Ztek Corporation Fuel cell stacks for ultra-high efficiency power systems
US6492053B1 (en) * 1997-06-10 2002-12-10 Ceramic Fuel Cells Limited Planar fuel cell assembly
US6537629B1 (en) * 1998-02-21 2003-03-25 Wilfried Ensinger Spacer
US20030064612A1 (en) * 2001-10-01 2003-04-03 England Diane M. Fuel cell stack having foil interconnects and laminated spacers
US20030203267A1 (en) * 2002-04-26 2003-10-30 Yeong-Shyung Chou Multi-layer seal for electrochemical devices

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1257054A (en) 1985-03-25 1989-07-11 Thomas M. Tymon Flocced mineral materials and water-resistant articles materials made therefrom
US4829655A (en) 1987-03-24 1989-05-16 W. R. Grace & Co.-Conn. Catalyst support and method for making same
JPH0714591A (en) 1993-06-24 1995-01-17 Tokyo Gas Co Ltd Gas seal structure of solid electrolytic fuel cell
AUPQ078899A0 (en) 1999-06-04 1999-06-24 Ceramic Fuel Cells Limited A fuel cell gas separator
EP1368154A4 (en) 2001-02-05 2005-06-15 Univ Rutgers Transient eutectic phase process for ceramic-metal bonding, metallilzation, and compositing
DE10116046A1 (en) 2001-03-30 2002-10-24 Elringklinger Ag poetry

Patent Citations (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3615838A (en) * 1968-05-10 1971-10-26 Albert C Erickson Fuel cell unit with novel fluid distribution drain and vent features
US3844920A (en) * 1973-11-21 1974-10-29 Gen Motors Corp Air fuel ratio sensor
US5100740A (en) * 1989-09-25 1992-03-31 General Electric Company Direct bonded symmetric-metallic-laminate/substrate structures
US5219673A (en) * 1991-08-23 1993-06-15 Kaun Thomas D Cell structure for electrochemical devices and method of making same
US5505498A (en) * 1994-05-16 1996-04-09 Eg&G Pressure Science, Inc. Flexible pressure-energized joint
US6458477B1 (en) * 1994-08-08 2002-10-01 Ztek Corporation Fuel cell stacks for ultra-high efficiency power systems
US5543239A (en) * 1995-04-19 1996-08-06 Electric Power Research Institute Electrode design for solid state devices, fuel cells and sensors
US5688610A (en) * 1995-07-25 1997-11-18 Dornier Gmbh Device for generating energy
US6106966A (en) * 1996-01-18 2000-08-22 The Arizona Board Of Regents On Behalf Of The University Of Arizona Single-crystal oxygen ion conductor
US6492053B1 (en) * 1997-06-10 2002-12-10 Ceramic Fuel Cells Limited Planar fuel cell assembly
US6326096B1 (en) * 1998-02-04 2001-12-04 Gas Research Institute Solid oxide fuel cell interconnector
US6074771A (en) * 1998-02-06 2000-06-13 Igr Enterprises, Inc. Ceramic composite electrolytic device and method for manufacture thereof
US6537629B1 (en) * 1998-02-21 2003-03-25 Wilfried Ensinger Spacer
US6054231A (en) * 1998-07-24 2000-04-25 Gas Research Institute Solid oxide fuel cell interconnector
US6106967A (en) * 1999-06-14 2000-08-22 Gas Research Institute Planar solid oxide fuel cell stack with metallic foil interconnect
US20030064612A1 (en) * 2001-10-01 2003-04-03 England Diane M. Fuel cell stack having foil interconnects and laminated spacers
US20030203267A1 (en) * 2002-04-26 2003-10-30 Yeong-Shyung Chou Multi-layer seal for electrochemical devices

Also Published As

Publication number Publication date
US7008716B2 (en) 2006-03-07
EP1458041A1 (en) 2004-09-15
US20040180254A1 (en) 2004-09-16

Similar Documents

Publication Publication Date Title
AU754899B2 (en) Sheet metal bipolar plate design for polymer electrolyte membrane fuel cells
US6670068B1 (en) Fuel cell unit, composite block of fuel cells and method for manufacturing a composite block of fuel cells
JP3516693B2 (en) Fuel cell stack with complete internal manifold
US7422819B2 (en) Ceramic coatings for insulating modular fuel cell cassettes in a solid-oxide fuel cell stack
JP5524836B2 (en) Improvements in gaskets and bipolar plates for proton exchange membrane fuel cells.
US9123946B2 (en) Fuel cell stack
EP1235289A2 (en) Stamped bipolar plate for PEM fuel cell stack
EP2270912A2 (en) Solid polymer electrolyte fuel cell and method for producing the same
CN1339181A (en) Fuel cell stacks for ultra-high efficiency power systems
JPH0696783A (en) Fuel cell
US7601450B2 (en) Hybrid interconnect for a solid-oxide fuel cell stack
US7008716B2 (en) Gasket material for a fuel cell
US20020110719A1 (en) Multipart separator plate for an electrochemical cell
JP2007292373A (en) Heat exchanger and heat exchange-type reformer
US7597986B2 (en) Method and apparatus for gasketing a fuel cell
JPH03219563A (en) Solid electrolyte type fuel cell
US6905793B2 (en) Folded metal bipolar sheets for fuel cells
WO2021201098A1 (en) Annular packing material, electrochemical module, electrochemical apparatus, energy system, solid oxide fuel cell, and solid oxide electrolysis cell
JP2011517049A (en) FUEL CELL STACK AND METHOD FOR MANUFACTURING FUEL CELL STACK
AU2011376555B2 (en) Fuel cell stack with thin endplate with integrated gas distribution tubes
Ruzhnikov et al. Planar LT-SOFC, Stack and Fuel Processor Development at IPPE

Legal Events

Date Code Title Description
AS Assignment

Owner name: DELPHI TECHNOLOGIES, INC., MICHIGAN

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:ENGLAND, DIANE M.;REEL/FRAME:013884/0259

Effective date: 20030312

AS Assignment

Owner name: UNITED STATES DEPARTMENT OF ENERGY, DISTRICT OF CO

Free format text: CONFIRMATORY LICENSE;ASSIGNOR:DELPHI AUTOMOTIVE SYSTEMS;REEL/FRAME:017593/0521

Effective date: 20051222

STCF Information on status: patent grant

Free format text: PATENTED CASE

FPAY Fee payment

Year of fee payment: 4

FPAY Fee payment

Year of fee payment: 8

MAFP Maintenance fee payment

Free format text: PAYMENT OF MAINTENANCE FEE, 12TH YEAR, LARGE ENTITY (ORIGINAL EVENT CODE: M1553)

Year of fee payment: 12

AS Assignment

Owner name: APTIV TECHNOLOGIES LIMITED, BARBADOS

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:DELPHI TECHNOLOGIES INC.;REEL/FRAME:047143/0874

Effective date: 20180101

AS Assignment

Owner name: APTIV TECHNOLOGIES (2) S.A R.L., LUXEMBOURG

Free format text: ENTITY CONVERSION;ASSIGNOR:APTIV TECHNOLOGIES LIMITED;REEL/FRAME:066746/0001

Effective date: 20230818

Owner name: APTIV MANUFACTURING MANAGEMENT SERVICES S.A R.L., LUXEMBOURG

Free format text: MERGER;ASSIGNOR:APTIV TECHNOLOGIES (2) S.A R.L.;REEL/FRAME:066566/0173

Effective date: 20231005

Owner name: APTIV TECHNOLOGIES AG, SWITZERLAND

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:APTIV MANUFACTURING MANAGEMENT SERVICES S.A R.L.;REEL/FRAME:066551/0219

Effective date: 20231006