US20050150911A1 - Anti-drip anti-foaming fluid dispensing system - Google Patents

Anti-drip anti-foaming fluid dispensing system Download PDF

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Publication number
US20050150911A1
US20050150911A1 US11/021,093 US2109304A US2005150911A1 US 20050150911 A1 US20050150911 A1 US 20050150911A1 US 2109304 A US2109304 A US 2109304A US 2005150911 A1 US2005150911 A1 US 2005150911A1
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United States
Prior art keywords
fluid
pump
dispensing system
fluid dispensing
exit orifice
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US11/021,093
Inventor
David Bach
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Scientific Products and Systems Inc
Original Assignee
Bach David T.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bach David T. filed Critical Bach David T.
Priority to US11/021,093 priority Critical patent/US20050150911A1/en
Publication of US20050150911A1 publication Critical patent/US20050150911A1/en
Assigned to SCIENTIFIC PRODUCTS AND SYSTEMS reassignment SCIENTIFIC PRODUCTS AND SYSTEMS ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: BACH, DAVID T.
Abandoned legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B67OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
    • B67DDISPENSING, DELIVERING OR TRANSFERRING LIQUIDS, NOT OTHERWISE PROVIDED FOR
    • B67D1/00Apparatus or devices for dispensing beverages on draught
    • B67D1/08Details
    • B67D1/12Flow or pressure control devices or systems, e.g. valves, gas pressure control, level control in storage containers
    • B67D1/1256Anti-dripping devices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B67OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
    • B67DDISPENSING, DELIVERING OR TRANSFERRING LIQUIDS, NOT OTHERWISE PROVIDED FOR
    • B67D1/00Apparatus or devices for dispensing beverages on draught
    • B67D1/08Details
    • B67D1/10Pump mechanism
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B67OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
    • B67DDISPENSING, DELIVERING OR TRANSFERRING LIQUIDS, NOT OTHERWISE PROVIDED FOR
    • B67D1/00Apparatus or devices for dispensing beverages on draught
    • B67D1/08Details
    • B67D1/10Pump mechanism
    • B67D1/108Pump mechanism of the peristaltic type

Definitions

  • This invention relates generally to the field of precision fluid dispensing and more specifically to a fluid dispensing system the is prevents dripping and foaming.
  • the present invention relates to a non-drip, anti-foaming fluid dispensing system that can contain a fluid pump that supplies a forward fluid pressure, a coupling tube (preferably of hydrophobic material) that is coupled to the pump for delivering fluid into a fluid container, and an elastomeric tip on the coupling tube that can contain at least one exit orifice.
  • the exit orifice can generally respond in response to the forward fluid pressure and contract when the forward fluid pressure is removed. This contraction prevents air from entering the delivery tube and causing dripping.
  • the fluid pump can be a positive displacement linear pump or a peristaltic pump or any other type of fluid pump causing a forward pressure on a fluid.
  • the tip can be a duck bill valve with one or more openings or orifices.
  • the pump can optionally supply a back pressure or suck-back after a predetermined amount of fluid has been dispensed.
  • FIG. 1 shows a schematic of an embodiment of the present invention.
  • FIG. 2A shows a duck bill valve on the end of a TEFLON tube.
  • FIG. 2B shows a duck bill valve on the of a steel tube.
  • FIG. 3 shows various cut patterns that can be used with a nozzle.
  • FIG. 4 shows an embodiment of a nozzle with vertical exit slits.
  • FIG. 1 shows a schematic of an embodiment of the present invention.
  • a pump 1 which can be a positive linear displacement pump, a peristaltic pump, or other controllable pump drives a delivery tube 2 that ends in an end control device or nozzle 3 .
  • the unique characteristics of the entire system allow a precise amount of fluid to be dispensed without dripping or foaming in to a container 4 .
  • FIGS. 2A and 2B show a tube with a duck bill valve 5 as a nozzle or tip.
  • a tube of 1 ⁇ 2 inch ID or larger can be attached to a duck bill valve of the type sold commercially.
  • the tube 2 shown in FIGS. 1 and 2 can be made of TEFLON. This material can be chosen to make the tube hydrophobic. While it is not critical that all tubes be of a hydrophobic material, much better results are generally achieved when hydrophobic materials are used.
  • the diameter of the tube usually must be chosen to match the required fill time against the volume of fluid being dispensed. For the example where a 125 ml container is to be filled with exactly 125 ml of fluid in 2 seconds or less, the tubing must have an ID of greater than 1 ⁇ 2 inch.
  • the problem with large tubes such as this is that after the initial fill, residual fluid on the inside of the tube drips causing the fill volume to be exceeded. The surface tension on such large tubes is not sufficient to stop air from flowing up the tube, and the solution continuing to flow down the tube.
  • a small nozzle must generally be used on the end of the tube to stop this air flow and drip.
  • An ideal nozzle is one made of an elastomeric material such as rubber or silicone with a small orifice 6 . Such a material expands to expel the initial flow under forward pressure from the pump, but then contracts to prevent the entry of air and any subsequent drip.
  • some pumps can be arranged to create a suck-back where the pump reverses direction and causes a negative pressure on the fluid.
  • a positive displacement linear piston pump is particularly suited for this.
  • FIG. 2A shows such a valve 5 on the end of a TEFLON tube
  • FIG. 2B shows such a valve on a steel tube.
  • the duck bill opens when the flow is pumped forward and closes when pumping is stopped. The contraction of the rubber slit helps prevent any further flow that could result in a drip. Suck-back can also be used to assist in fluid stoppage and in duck bill closure.
  • the duck bill reduces the apparent open area of the nozzle so that fluid surface tension is enough to block the air/fluid transfer up the larger diameter tube.
  • the duck bill nozzle 5 shown in FIGS. 2A and 2B opens for each dispense by an amount based on the fluid volume and the dispensing velocity.
  • a nozzle it is possible to large tubes and deliver large quantities of fluid exactly.
  • Using such a nozzle (or smaller versions of it) with smaller tubes allows systems that precisely deliver very small volumes.
  • a single tube/nozzle combination can accurately deliver both very large and very small quantities without drip or foaming.
  • FIG. 2B shows a steel tube 7 with a duck bill nozzle.
  • the tube can be any size including 1 ⁇ 2 stainless steel.
  • a possible nozzle 5 is the Vernay VL4513-103 duck bill. This silicon duck bill can be configured either as a single cut or with multiple cuts as shown in FIG. 3 .
  • FIG. 4 An alternative embodiment of the present invention is shown in FIG. 4 .
  • a nozzle head 8 can be made from a part of the tubing 2 equipped with cuts or slits 9 backed by a screen. It is preferred to use several axial cuts around the circumference as shown in FIG. 4 to create a side-port nozzle. Each cut can be backed by filter screens or any other device that will cause a slight back pressure.
  • the side ports 9 provide increased fluid exit area that slows the output stream velocity.
  • the side ports can be made vertical to also aid in keeping the exit velocity low and allow for a more gradual pressure drop from the top to the bottom of each slight. This results in a slightly downward flow angle out of the slot. In generally, the screen prevents dripping.
  • a preferred screen material is around 75 to 105 micron polypropylene screen.
  • Each screen provides a slight amount of back pressure so that fluid in the relatively short nozzle does not drip. It is necessary to keep the fluid column behind the screen from becoming too large or the static pressure behind the screen can still cause dripping.
  • a duck bill can be combined with the nozzle shown in FIG. 4 . This arrangement allows the length of the fluid column to be increased above the duck bill.
  • the duck bill provides an additional pressure to the fluid in a tube or reservoir above the side ports.
  • multiple screens can be used (not necessarily of the same size) to provide additional pressure drop.

Abstract

A system for dispensing exact quantities of fluid into containers without dripping or foaming can be made from the combination of a controllable pump, a tube (preferably hydrophobic), and a nozzle usually made of elastomeric material with an orifice or slit such a duck bill valves commercially available. Forward pressure causes the slit to open, while elastic force causes it to close when pumping stops. An alternative embodiment is to use slits backed by small diameter screen to achieve a back pressure.

Description

  • This application is related to and claims priority from U.S. Provisional patent application No. 60/532,307 filed Dec. 23, 2003. Application 60/532,307 is hereby incorporated by reference.
  • BACKGROUND
  • 1. Field of the Invention
  • This invention relates generally to the field of precision fluid dispensing and more specifically to a fluid dispensing system the is prevents dripping and foaming.
  • 2. Description of the Prior Art
  • Many applications in the field of bio-science and medicine require the precise dispensing of a quantity of fluid into a particular container. There is no tolerance for dripping. Also, some liquids tend to foam if dispensed too rapidly through a standard nozzle or through a tube with too small an inside diameter. For example, an application might require the precision dispensing of 125 ml of a particular liquid (like a salt solution) into a vessel holding exactly 125 ml. Usually such a fill needs to take place very rapidly (within a second or two). No liquid can be lost through dripping.
  • What is badly needed is a system and method for making fast fluid dispenses into containers designed to contain a precise amount of fluid without dripping or foaming.
  • SUMMARY OF THE INVENTION
  • The present invention relates to a non-drip, anti-foaming fluid dispensing system that can contain a fluid pump that supplies a forward fluid pressure, a coupling tube (preferably of hydrophobic material) that is coupled to the pump for delivering fluid into a fluid container, and an elastomeric tip on the coupling tube that can contain at least one exit orifice. The exit orifice can generally respond in response to the forward fluid pressure and contract when the forward fluid pressure is removed. This contraction prevents air from entering the delivery tube and causing dripping.
  • The fluid pump can be a positive displacement linear pump or a peristaltic pump or any other type of fluid pump causing a forward pressure on a fluid. In particular, the tip can be a duck bill valve with one or more openings or orifices. The pump can optionally supply a back pressure or suck-back after a predetermined amount of fluid has been dispensed.
  • DESCRIPTION OF THE FIGURES
  • FIG. 1 shows a schematic of an embodiment of the present invention.
  • FIG. 2A shows a duck bill valve on the end of a TEFLON tube.
  • FIG. 2B shows a duck bill valve on the of a steel tube.
  • FIG. 3 shows various cut patterns that can be used with a nozzle.
  • FIG. 4. shows an embodiment of a nozzle with vertical exit slits.
  • Several drawings and illustrations have been presented to aid in the understanding of the present invention. The scope of the present invention is not limited to the figures.
  • DESCRIPTION OF THE INVENTION
  • FIG. 1 shows a schematic of an embodiment of the present invention. A pump 1, which can be a positive linear displacement pump, a peristaltic pump, or other controllable pump drives a delivery tube 2 that ends in an end control device or nozzle 3. The unique characteristics of the entire system allow a precise amount of fluid to be dispensed without dripping or foaming in to a container 4.
  • FIGS. 2A and 2B show a tube with a duck bill valve 5 as a nozzle or tip. Here a tube of ½ inch ID or larger can be attached to a duck bill valve of the type sold commercially. The tube 2 shown in FIGS. 1 and 2 can be made of TEFLON. This material can be chosen to make the tube hydrophobic. While it is not critical that all tubes be of a hydrophobic material, much better results are generally achieved when hydrophobic materials are used.
  • The diameter of the tube usually must be chosen to match the required fill time against the volume of fluid being dispensed. For the example where a 125 ml container is to be filled with exactly 125 ml of fluid in 2 seconds or less, the tubing must have an ID of greater than ½ inch. The problem with large tubes such as this is that after the initial fill, residual fluid on the inside of the tube drips causing the fill volume to be exceeded. The surface tension on such large tubes is not sufficient to stop air from flowing up the tube, and the solution continuing to flow down the tube.
  • A small nozzle must generally be used on the end of the tube to stop this air flow and drip. An ideal nozzle is one made of an elastomeric material such as rubber or silicone with a small orifice 6. Such a material expands to expel the initial flow under forward pressure from the pump, but then contracts to prevent the entry of air and any subsequent drip. In addition, some pumps can be arranged to create a suck-back where the pump reverses direction and causes a negative pressure on the fluid. A positive displacement linear piston pump is particularly suited for this.
  • An ideal nozzle is a duck bill valve that can be purchased commercially. FIG. 2A shows such a valve 5 on the end of a TEFLON tube, while FIG. 2B shows such a valve on a steel tube. The duck bill opens when the flow is pumped forward and closes when pumping is stopped. The contraction of the rubber slit helps prevent any further flow that could result in a drip. Suck-back can also be used to assist in fluid stoppage and in duck bill closure. The duck bill reduces the apparent open area of the nozzle so that fluid surface tension is enough to block the air/fluid transfer up the larger diameter tube.
  • The duck bill nozzle 5 shown in FIGS. 2A and 2B opens for each dispense by an amount based on the fluid volume and the dispensing velocity. Using such a nozzle, it is possible to large tubes and deliver large quantities of fluid exactly. Using such a nozzle (or smaller versions of it) with smaller tubes allows systems that precisely deliver very small volumes. In fact, a single tube/nozzle combination can accurately deliver both very large and very small quantities without drip or foaming.
  • FIG. 2B shows a steel tube 7 with a duck bill nozzle. The tube can be any size including ½ stainless steel. A possible nozzle 5 is the Vernay VL4513-103 duck bill. This silicon duck bill can be configured either as a single cut or with multiple cuts as shown in FIG. 3.
  • An alternative embodiment of the present invention is shown in FIG. 4. Here a nozzle head 8 can be made from a part of the tubing 2 equipped with cuts or slits 9 backed by a screen. It is preferred to use several axial cuts around the circumference as shown in FIG. 4 to create a side-port nozzle. Each cut can be backed by filter screens or any other device that will cause a slight back pressure. The side ports 9 provide increased fluid exit area that slows the output stream velocity. The side ports can be made vertical to also aid in keeping the exit velocity low and allow for a more gradual pressure drop from the top to the bottom of each slight. This results in a slightly downward flow angle out of the slot. In generally, the screen prevents dripping. A preferred screen material is around 75 to 105 micron polypropylene screen. Each screen provides a slight amount of back pressure so that fluid in the relatively short nozzle does not drip. It is necessary to keep the fluid column behind the screen from becoming too large or the static pressure behind the screen can still cause dripping.
  • A duck bill can be combined with the nozzle shown in FIG. 4. This arrangement allows the length of the fluid column to be increased above the duck bill. The duck bill provides an additional pressure to the fluid in a tube or reservoir above the side ports. In addition to a duck bill, multiple screens can be used (not necessarily of the same size) to provide additional pressure drop.
  • Several illustrations and descriptions have been provided to aid in understanding of the present invention. One skilled in the art will realize that many changes and variations are possible. These changes and variations are within the scope of the present invention.

Claims (20)

1. A no-drip, anti-foaming fluid dispensing system comprising:
a fluid pump supplying a forward fluid pressure;
a delivery tube fluidly coupled to said pump for delivering said fluid into a fluid container;
an elastomeric tip on said delivery tube containing at least one exit orifice, said exit orifice expanding in response to said forward fluid pressure and contracting when said forward fluid pressure is removed.
2. The fluid dispensing system of claim 1 wherein said fluid pump is a positive displacement linear pump.
3. The fluid dispensing system of claim 1 wherein said fluid pump is a peristaltic pump.
4. The fluid dispensing system of claim 1 wherein said elastomeric tip is a duck bill valve.
5. The fluid dispensing system of claim 1 wherein said elastomeric tip has a plurality of orifices.
6. The fluid dispensing system of claim 1 further comprising said pump also supplying back pressure after a predetermined quantity of said fluid is dispensed.
7. The fluid dispensing system of claim 4 wherein said duck bill valve is silicone.
8. The fluid dispensing system of claim 1 wherein said delivery tube is a hydrophobic material.
9. A no-drip, anti-foaming fluid dispensing system comprising:
a fluid pump supplying a forward fluid pressure;
a coupling tube fluidly coupled to said pump for delivering said fluid into a fluid container;
a dispensing tip on said coupling tube containing at least one exit orifice;
a screen covering said exit orifice, said polymer screen preventing drip through when said forward fluid pressure is removed.
10. The fluid dispensing system of claim 9 wherein said exit orifice is elongated along the axis of said coupling tube.
11. The fluid dispensing system of claim 9 further comprising a second screen covering said exit orifice.
12. The fluid dispensing system of claim 9 wherein said screen is a polymer.
13. The fluid dispensing system of claim 9 wherein said pump is a positive displacement linear pump.
14. The fluid dispensing system of claim 9 wherein said pump is a peristaltic pump.
15. A method of dispensing a predetermined quantity of fluid into a container without drip or foaming comprising the steps of:
causing a fluid pump to move said predetermined quantity of fluid from a reservoir into a delivery tube, said delivery tube having at least one exit orifice, said exit orifice containing a means for causing backpressure on said flow, wherein a forward pressure from said pump overcomes this backpressure to allow said predetermined quantity of fluid to exit said orifice;
allowing said backpressure to keep any remaining fluid in said tube after said predetermined quantity of fluid has been dispensed.
16. The method of claim 15 wherein said means for causing backpressure is a duck bill valve.
17. The method of claim 15 wherein said means for causing backpressure is a screen.
18. The method of claim 15 wherein said delivery tube is hydrophobic.
19. The method of claim 15 wherein said pump is a linear displacement piston driven pump.
20. The method of claim 15 wherein said pump is a peristaltic pump.
US11/021,093 2003-12-23 2004-12-23 Anti-drip anti-foaming fluid dispensing system Abandoned US20050150911A1 (en)

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070197971A1 (en) * 2006-02-22 2007-08-23 Krueger John A Curable material delivery device with a rotatable supply section
US20070198024A1 (en) * 2006-02-22 2007-08-23 Cardinal Health 200, Inc. Curable material delivery device
US20070227620A1 (en) * 2004-04-13 2007-10-04 Mitsuru Kunii Liquid Filling Nozzle
GB2448703A (en) * 2007-04-24 2008-10-29 Imi Cornelius Self-draining dispenser nozzle
US7744817B2 (en) 2003-08-11 2010-06-29 Sakura Finetek U.S.A., Inc. Manifold assembly
US7767152B2 (en) 2003-08-11 2010-08-03 Sakura Finetek U.S.A., Inc. Reagent container and slide reaction retaining tray, and method of operation
US8459509B2 (en) 2006-05-25 2013-06-11 Sakura Finetek U.S.A., Inc. Fluid dispensing apparatus
US8580568B2 (en) 2011-09-21 2013-11-12 Sakura Finetek U.S.A., Inc. Traceability for automated staining system
US8752732B2 (en) 2011-02-01 2014-06-17 Sakura Finetek U.S.A., Inc. Fluid dispensing system
US8932543B2 (en) 2011-09-21 2015-01-13 Sakura Finetek U.S.A., Inc. Automated staining system and reaction chamber
US9518899B2 (en) 2003-08-11 2016-12-13 Sakura Finetek U.S.A., Inc. Automated reagent dispensing system and method of operation
WO2017029267A1 (en) 2015-08-17 2017-02-23 Nestec S.A. Anti-dripping system
WO2018190925A1 (en) 2017-04-14 2018-10-18 Sestra Systems, Inc. Touchless tap handle for beverage dispensing
US20200018629A1 (en) * 2017-03-06 2020-01-16 Hodges & Drake Design Limited Apparatus for dispensing a flowable product

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US5188289A (en) * 1991-06-20 1993-02-23 Euclid Spiral Paper Tube Co. Dripless, splashless nozzle
US5193593A (en) * 1990-08-13 1993-03-16 Colgate-Palmolive Company Package filling method and apparatus
US6189740B1 (en) * 1998-12-30 2001-02-20 Steris Inc Antiseptic soap dispenser with selectively variable dose
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US1790625A (en) * 1931-01-27 Eatjcet
US4365728A (en) * 1978-03-13 1982-12-28 Pilot Man-Nen-Hitsu Kabushiki Kaisha Liquid discharge apparatus
US4256242A (en) * 1979-10-23 1981-03-17 Christine William C Dispenser having a roller for squeezing amounts from a tube
US4607764A (en) * 1984-10-31 1986-08-26 Trinity Foundation Fluent product extraction system
US4651862A (en) * 1985-06-10 1987-03-24 Greenfield Jr Irving E Dual temperature beverage dispenser with removable operating module
US5105992A (en) * 1988-07-05 1992-04-21 Fender Franklin D Soapdispenser having a squeeze pump
US5193593A (en) * 1990-08-13 1993-03-16 Colgate-Palmolive Company Package filling method and apparatus
US5188289A (en) * 1991-06-20 1993-02-23 Euclid Spiral Paper Tube Co. Dripless, splashless nozzle
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Cited By (26)

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Publication number Priority date Publication date Assignee Title
US7744817B2 (en) 2003-08-11 2010-06-29 Sakura Finetek U.S.A., Inc. Manifold assembly
US9518899B2 (en) 2003-08-11 2016-12-13 Sakura Finetek U.S.A., Inc. Automated reagent dispensing system and method of operation
US7767152B2 (en) 2003-08-11 2010-08-03 Sakura Finetek U.S.A., Inc. Reagent container and slide reaction retaining tray, and method of operation
US7743798B2 (en) * 2004-04-13 2010-06-29 Kao Corporation Liquid filling nozzle
US20070227620A1 (en) * 2004-04-13 2007-10-04 Mitsuru Kunii Liquid Filling Nozzle
US20070198024A1 (en) * 2006-02-22 2007-08-23 Cardinal Health 200, Inc. Curable material delivery device
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US8361032B2 (en) 2006-02-22 2013-01-29 Carefusion 2200 Inc. Curable material delivery device with a rotatable supply section
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US8459509B2 (en) 2006-05-25 2013-06-11 Sakura Finetek U.S.A., Inc. Fluid dispensing apparatus
US9914124B2 (en) 2006-05-25 2018-03-13 Sakura Finetek U.S.A., Inc. Fluid dispensing apparatus
GB2448703A (en) * 2007-04-24 2008-10-29 Imi Cornelius Self-draining dispenser nozzle
US8752732B2 (en) 2011-02-01 2014-06-17 Sakura Finetek U.S.A., Inc. Fluid dispensing system
US9016526B2 (en) 2011-02-01 2015-04-28 Sakura Finetek U.S.A., Inc. Fluid dispensing system
US9005980B2 (en) 2011-09-21 2015-04-14 Sakura Finetek U.S.A., Inc. Traceability for automated staining system
US8932543B2 (en) 2011-09-21 2015-01-13 Sakura Finetek U.S.A., Inc. Automated staining system and reaction chamber
US8580568B2 (en) 2011-09-21 2013-11-12 Sakura Finetek U.S.A., Inc. Traceability for automated staining system
US10295444B2 (en) 2011-09-21 2019-05-21 Sakura Finetek U.S.A., Inc. Automated staining system and reaction chamber
WO2017029267A1 (en) 2015-08-17 2017-02-23 Nestec S.A. Anti-dripping system
US20200018629A1 (en) * 2017-03-06 2020-01-16 Hodges & Drake Design Limited Apparatus for dispensing a flowable product
US10928235B2 (en) * 2017-03-06 2021-02-23 Hodges & Drake Design Limited Apparatus for dispensing a flowable product
WO2018190925A1 (en) 2017-04-14 2018-10-18 Sestra Systems, Inc. Touchless tap handle for beverage dispensing
EP3609836A4 (en) * 2017-04-14 2020-05-13 Sestra Systems, Inc. Touchless tap handle for beverage dispensing

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Owner name: SCIENTIFIC PRODUCTS AND SYSTEMS, DELAWARE

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:BACH, DAVID T.;REEL/FRAME:020190/0562

Effective date: 20071112

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION