Búsqueda Imágenes Maps Play YouTube Noticias Gmail Drive Más »
Iniciar sesión
Usuarios de lectores de pantalla: deben hacer clic en este enlace para utilizar el modo de accesibilidad. Este modo tiene las mismas funciones esenciales pero funciona mejor con el lector.

Patentes

  1. Búsqueda avanzada de patentes
Número de publicaciónUS20050153190 A1
Tipo de publicaciónSolicitud
Número de solicitudUS 10/993,856
Fecha de publicación14 Jul 2005
Fecha de presentación19 Nov 2004
Fecha de prioridad1 Oct 2001
También publicado comoDE60224250D1, DE60224250T2, EP1298755A2, EP1298755A3, EP1298755B1, US6821667, US20030064612
Número de publicación10993856, 993856, US 2005/0153190 A1, US 2005/153190 A1, US 20050153190 A1, US 20050153190A1, US 2005153190 A1, US 2005153190A1, US-A1-20050153190, US-A1-2005153190, US2005/0153190A1, US2005/153190A1, US20050153190 A1, US20050153190A1, US2005153190 A1, US2005153190A1
InventoresDiane England, Sean Kelly, Subhasish Mukerjee
Cesionario originalDelphi Technologies, Inc.
Exportar citaBiBTeX, EndNote, RefMan
Enlaces externos: USPTO, Cesión de USPTO, Espacenet
Fuel cell stack having foil interconnects and laminated spacers
US 20050153190 A1
Resumen
Interconnects and perimeter spacers for a fuel cell stack are provided as flexible elements which can conform to non-planarities in a stack's electrolyte elements and thereby avoid inducing torsional stresses in the electrolyte elements. The interconnects are foil elements about 0.005 inches thick, formed of a superalloy such as Hastelloy, Haynes 230, or a stainless steel. The perimeter spacers comprise a plurality of laminate thin spacer elements, each thin spacer element being a laminate of superalloy and a “soft” material such as copper, nickel, or mica. The spacer elements can slide past one another; thus the perimeter spacers can be physically thick, to form the gas flow spaces within the stack, while also being torsionally flexible.
Imágenes(4)
Previous page
Next page
Reclamaciones(4)
1. A perimeter spacer for use in a fuel cell stack, comprising between two and ten laminate spacer elements positioned adjacent to one another, at least one of said spacer elements being formed of a superalloy and a soft material, wherein said soft material is selected from the group consisting of copper and dielectric materials and wherein at least one of the outermost of the laminate spacer elements is formed of mica for sealing and insulating disposition against an electrolyte element in said fuel cell stack.
2. A perimeter spacer in accordance with claim 1 wherein said dielectric material is mica.
3. A perimeter spacer in accordance with claim 1 configured for spacing an electrolyte element from an interconnect element, wherein said perimeter spacer includes between two and ten laminate spacer elements.
4. A perimeter spacer in accordance with claim 2 wherein at least one of the outermost of the laminate spacer elements is formed of mica for sealing and insulating disposition against an electrolyte element in said fuel cell stack.
Descripción
    TECHNICAL FIELD
  • [0001]
    The present invention relates to fuel cells; more particularly, to stacks comprising a plurality of individual cells being both physically separated and electrically connected by interconnect elements; and most particularly, to such a fuel cell stack wherein the interconnect elements are thin foils and the spacers are laminates of foils formed alternately of superalloy and a compliant material.
  • BACKGROUND OF THE INVENTION
  • [0002]
    Fuel cells which generate electric current by controllably combining elemental hydrogen and oxygen are well known. In one form of such a fuel cell, an anodic layer and a cathodic layer are separated by a permeable electrolyte formed of a ceramic solid oxide. Such a fuel cell is known in the art as a “solid oxide fuel cell” (SOFC). Either pure hydrogen or reformate is flowed along the outer surface of the anode and diffuses into the anode. Oxygen, typically from air, is flowed along the outer surface of the cathode and diffuses into the cathode. Each O2 molecule is split and reduced to two O−2 ions at the cathode/electrolyte interface. The oxygen ions diffuse through the electrolyte and combine at the anode/electrolyte interface with four hydrogen ions to form two molecules of water. The anode and the cathode are connected externally through the load to complete the circuit whereby four electrons are transferred from the anode to the cathode. When hydrogen is derived from “reformed” hydrocarbons, the “reformate” gas includes CO which is converted to CO2 at the anode/electrolyte interface. Reformed gasoline is a commonly used fuel in automotive fuel cell applications.
  • [0003]
    A single cell is capable of generating a relatively small voltage and wattage, typically about 0.7 volts and less than about 2 watts per cm2 of active area. Therefore, in practice it is usual to stack together in electrical series a plurality of cells. Because each anode and cathode must have a free space for passage of gas over its surface, the cells are separated by perimeter spacers which are vented to permit flow of gas to the anodes and cathodes as desired but which form seals on their axial surfaces to prevent gas leakage from the sides of the stack. Adjacent cells are connected electrically by “interconnect” elements in the stack, the outer surfaces of the anodes and cathodes being electrically connected to their respective interconnects by electrical contacts disposed within the gas-flow space, typically by a metallic foam or a metallic mesh which is readily gas-permeable or by conductive filaments. The outermost, or end, interconnects of the stack define electrical terminals, or “current collectors,” connected across a load.
  • [0004]
    In the prior art, the interconnect elements are relatively thick, flat plates formed of a superalloy or stainless steel. Also, the perimeter spacers that form the gas flow spaces adjacent to the electrodes are typically formed from sheet stock having a thickness selected to yield a desired height of the flow space.
  • [0005]
    One problem encountered in prior art fuel cell stacks is that they are relatively bulky and heavy. It is very desirable to reduce the height and weight of a stack without sacrificing performance.
  • [0006]
    Another problem encountered in some prior art fuel cell stacks involves the brittleness of the ceramic oxide electrolyte elements. In some fuel cells, the anode is a relatively thick structural element supporting a thin electrolyte layer and a thin cathode layer. Such a fuel cell is said to be “anode-supported.” The ceramic oxide electrolyte elements, which extend to the edges of the stack in contact with the anodes, typically are not optically flat and are also quite brittle. The anodes may also not be optically flat. Prior art perimeter spacers, being monolithic, cannot twist to accommodate non-planarities in the electrolyte elements and anodes, so that sealing between the non-flat surfaces becomes difficult. Also, because of the non-flat surfaces, an electrolyte element may be cracked during assembly of the stack. In either case, failure of the stack can occur. Avoiding these problems by finishing the electrolyte elements to be optically flat is cost-prohibitive.
  • [0007]
    It is a principal object of the present invention to provide a fuel cell stack that is lighter and smaller than prior art fuel cells of the same electrical capacity.
  • [0008]
    It is a further object of the present invention to provide spacer means for a fuel cell stack that can sealably conform to non-planarities in the electrolyte elements and will not induce torsional stress in such elements.
  • SUMMARY OF THE INVENTION
  • [0009]
    Briefly described, the interconnects and perimeter spacers for a fuel cell stack are provided as flexible elements which can conform to non-planarities in a stack's elements. The interconnects are foil elements about 0.005 inches thick, formed of a superalloy, such as Hastelloy or Haynes 230, or stainless steel. The thick perimeter spacers comprise a plurality of thin spacer elements. Each spacer element is a laminate of a superalloy and a compliant soft material such as copper, nickel, or mica. The spacer elements can slide past one another; thus the perimeter spacers can be physically thick, to form gas flow spaces within the stack, while also being torsionally flexible.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • [0010]
    These and other features and advantages of the invention will be more fully understood and appreciated from the following description of certain exemplary embodiments of the invention taken together with the accompanying drawings, in which:
  • [0011]
    FIG. 1 is a schematic cross-sectional view of a prior art two-cell stack of solid oxide fuel cells;
  • [0012]
    FIG. 2 is an isometric view of a fuel-cell stack comprising five cells;
  • [0013]
    FIG. 3 is an isometric view like that shown in FIG. 2, showing the addition of current collectors, end plates, and bolts to form a complete fuel cell stack (exploded view) ready for use; and
  • [0014]
    FIG. 4 is a schematic cross-sectional view of a two-cell stack of solid oxide fuel cells in accordance with the invention, showing the use of a laminate foil spacers and a foil interconnect element for providing the reformate and air flow passageways across the anodes and cathodes, respectively.
  • DESCRIPTION OF THE PREFERRED EMBODIMENTS
  • [0015]
    Referring to FIG. 1, a prior art fuel cell stack 10 includes elements normal in the art to solid oxide fuel cell stacks comprising more than one fuel cell. The example shown includes two fuel cells A and B, connected in series, and is of a class of such fuel cells said to be “anode-supported” in that the anode is a structural element having the electrolyte and cathode deposited upon it. Element thicknesses as shown are not to scale.
  • [0016]
    Each fuel cell includes an electrolyte element 14 separating an anodic element 16 and a cathodic element 18. Each anode and cathode is in direct chemical contact with its respective surface of the electrolyte, and each anode and cathode has a respective free surface 20,22 forming one wall of a respective passageway 24,26 for flow of gas across the surface. Anode 16 of fuel cell B faces and is electrically connected to an interconnect 28 by filaments 30 extending across but not blocking passageway 24. Similarly, cathode 18 of fuel cell A faces and is electrically connected to interconnect 28 by filaments 30 extending across but not blocking passageway 26. Similarly, cathode 18 of fuel cell B faces and is electrically connected to a cathodic current collector 32 by filaments 30 extending across but not blocking passageway 26, and anode 16 of fuel cell A faces and is electrically connected to an anodic current collector 34 by filaments 30 extending across but not blocking passageway 24. Current collectors 32,34 may be connected across a load 35 in order that the fuel cell stack 10 performs electrical work. Passageways 24 are formed by anode spacers 36 between the perimeter of anode 16 and either interconnect 28 or anodic current collector 34. Passageways 26 are formed by cathode spacers 38 between the perimeter of electrolyte 14 and either interconnect 28 or cathodic current collector 32.
  • [0017]
    Referring to FIGS. 2 and 3, a plurality of individual fuel cells may be stacked together to form a stack 12 similar to schematic stack 10 shown in FIG. 1. Stack 12 comprises five such cells. To form a complete working fuel cell assembly 13 (FIG. 3), stack 12 is sandwiched between an anodic current collector 34 and a cathodic current collector 32 which in turn are sandwiched between a top plate 15 and a gas-manifold base 17, the entire assembly being sealingly bound together by bolts 19 extending through bores in top plate 15 and threadedly received in bores in base 17.
  • [0018]
    Preferably, the interconnect and the current collectors are formed of an alloy, typically a “superalloy,” which is chemically and dimensionally stable at the elevated temperatures necessary for fuel cell operation, generally about 750° C. or higher, for example, Hastelloy, Haynes 230, or a stainless steel. The electrolyte is formed of a ceramic oxide and preferably includes zirconia stabilized with yttrium oxide (yttria), known in the art as YSZ. The cathode is formed of, for example, porous lanthanum strontium manganate or lanthanum strontium iron, and the anode is formed, for example, of a mixture of nickel and YSZ.
  • [0019]
    In operation (FIG. 1), reformate gas 21 is provided to passageways 24 at a first edge 25 of the anode free surface 20, flows parallel to the surface of the anode across the anode in a first direction, and is removed at a second and opposite edge 29 of anode surface 20. Hydrogen and CO diffuse into the anode to the interface with the electrolyte. Oxygen 31, typically in air, is provided to passageways 26 at a first edge 39 of the cathode free surface 22, flows parallel to the surface of the cathode in a second direction orthogonal to the first direction of the reformate (second direction omitted for clarity in FIG. 1), and is removed at a second and opposite edge 43 of cathode surface 22. Molecular oxygen gas (O2) diffuses into the cathode and is catalytically reduced to two O−2 ions by accepting four electrons from the cathode and the cathodic current collector 32 (cell B) or the interconnect 28 (cell A) via filaments 30. The electrolyte is permeable to the O−2 ions which pass by electric field through the electrolyte and combine with four hydrogen atoms to form two water molecules, giving up four electrons to the anode and the anodic current collector 34 (cell A) or the interconnect 28 (cell B) via filaments 30. Thus cells A and B are connected in series electrically between the two current collectors, and the total voltage and wattage between the current collectors is the sum of the voltage and wattage of the individual cells in a fuel cell stack.
  • [0020]
    FIG. 4 shows an improved two-cell stack 44 in accordance with the invention. Stack 44 is similar to prior art stack 10 shown in FIG. 1 but incorporates several improvements over the prior art.
  • [0021]
    First, prior art interconnect element 28 is relatively thick, heavy, and inflexible, having a typical thickness of about 3.5 mm or greater. Its thickness and weight contribute to the overall weight and size of a prior art stack, and its inflexibility contributes to the risk of cracking a non-planar electrolyte element or compromising the sealability between elements, as discussed above. Improved interconnect element 28 a is formed as a flexible foil having a thickness of less than about 0.5 mm and preferably about 0.127 mm (0.005 inch). Like the prior art interconnect 28, foil interconnect 28 a is preferably formed of an alloy which is chemically and dimensionally stable at the elevated temperatures necessary for fuel cell operation, for example, a superalloy such as Hastalloy, Haines 230, or a stainless steel.
  • [0022]
    Second, prior art anode spacer 36 and cathode spacer 38 are monolithic and formed from sheet stock having a thickness selected to yield the desired height of the anode passageways 24 and cathode passageways 26. Being inflexible, the prior art spacers also contribute to the risk of cracking a non-planar electrolyte element upon assembly of the stack as shown in FIG. 3, and/or compromising the sealability between the elements. As shown in FIG. 4, prior art spacers 36,38 are replaced by improved spacers 36 a,38 a, each comprising a plurality of thin elements 46, each preferably about 0.127 mm in thickness. Each element 46 is formed as a laminate comprising a superalloy and a soft and malleable material such as copper, nickel, or mica. Preferably, a foil of dielectric soft material, such as mica 48, is placed next to each of electrolyte elements 14 and anodes 16 to insulate the foil interconnect 28 a electrically from short-circuiting through the electrolyte elements, as shown in FIG. 4, and to seal against gas leakage. Phologopite or fluorophlogopite mica is especially effective at sealing against the irregular and porous surface of the electrolyte.
  • [0023]
    Using a plurality of thin spacers allows the height of the flow spaces to be varied as may be desired among different fuel cell stacks simply by varying the number of spacers included for each flow space. For example, in a currently preferred embodiment of a fuel cell stack, cathode flow space 26 is formed by five such spacers and anode flow space 24 is formed by three such spacers. Further, selection of spacer materials according to their thermal expansion properties allows the yield strength and thermal expansion of a stack to be specified, and thermal expansion of the spacers can provide sealing force for the seals against the electrolyte elements and the interconnect and current collectors. Further, forming thick spacers by assembling a plurality of thin laminated foil spacers, such that the foils may slide past one another as needed, results in a thick spacer which is nonetheless sufficiently flexible to conform to a non-planar electrolyte element without cracking it.
  • [0024]
    While the invention has been described by reference to various specific embodiments, it should be understood that numerous changes may be made within the spirit and scope of the inventive concepts described. Accordingly, it is intended that the invention not be limited to the described embodiments, but will have full scope defined by the language of the following claims.
Citas de patentes
Patente citada Fecha de presentación Fecha de publicación Solicitante Título
US3615838 *10 May 196826 Oct 1971Albert C EricksonFuel cell unit with novel fluid distribution drain and vent features
US3844920 *21 Nov 197329 Oct 1974Gen Motors CorpAir fuel ratio sensor
US5100740 *15 Oct 199131 Mar 1992General Electric CompanyDirect bonded symmetric-metallic-laminate/substrate structures
US5219673 *23 Ago 199115 Jun 1993Kaun Thomas DCell structure for electrochemical devices and method of making same
US5505498 *16 May 19949 Abr 1996Eg&G Pressure Science, Inc.Flexible pressure-energized joint
US5543239 *19 Abr 19956 Ago 1996Electric Power Research InstituteElectrode design for solid state devices, fuel cells and sensors
US5688610 *26 Jul 199618 Nov 1997Dornier GmbhDevice for generating energy
US6054231 *24 Jul 199825 Abr 2000Gas Research InstituteSolid oxide fuel cell interconnector
US6074771 *6 Feb 199813 Jun 2000Igr Enterprises, Inc.Ceramic composite electrolytic device and method for manufacture thereof
US6106966 *15 Jul 199822 Ago 2000The Arizona Board Of Regents On Behalf Of The University Of ArizonaSingle-crystal oxygen ion conductor
US6106967 *14 Jun 199922 Ago 2000Gas Research InstitutePlanar solid oxide fuel cell stack with metallic foil interconnect
US6321145 *29 Ene 200120 Nov 2001Delphi Technologies, Inc.Method and apparatus for a fuel cell propulsion system
US6326096 *4 Feb 19984 Dic 2001Gas Research InstituteSolid oxide fuel cell interconnector
US6423896 *28 Feb 200123 Jul 2002Delphi Technologies, Inc.Thermophotovoltaic insulation for a solid oxide fuel cell system
US6455185 *15 Dic 200024 Sep 2002Delphi Technologies, Inc.Reformate control valve assembly for a fuel cell
US6458477 *4 May 20001 Oct 2002Ztek CorporationFuel cell stacks for ultra-high efficiency power systems
US6485852 *7 Ene 200026 Nov 2002Delphi Technologies, Inc.Integrated fuel reformation and thermal management system for solid oxide fuel cell systems
US6492053 *10 Jun 199810 Dic 2002Ceramic Fuel Cells LimitedPlanar fuel cell assembly
US6509113 *15 Dic 200021 Ene 2003Delphi Technologies, Inc.Fluid distribution surface for solid oxide fuel cells
US6537629 *18 Ago 200025 Mar 2003Wilfried EnsingerSpacer
US6551734 *27 Oct 200022 Abr 2003Delphi Technologies, Inc.Solid oxide fuel cell having a monolithic heat exchanger and method for managing thermal energy flow of the fuel cell
US6562496 *30 Abr 200113 May 2003Delphi Technologies, Inc.Integrated solid oxide fuel cell mechanization and method of using for transportation industry applications
US6608463 *24 Jun 200219 Ago 2003Delphi Technologies, Inc.Solid-oxide fuel cell system having an integrated air supply system
US6613468 *22 Dic 20002 Sep 2003Delphi Technologies, Inc.Gas diffusion mat for fuel cells
US6613469 *22 Dic 20002 Sep 2003Delphi Technologies, Inc.Fluid distribution surface for solid oxide fuel cells
US6627339 *19 Abr 200130 Sep 2003Delphi Technologies, Inc.Fuel cell stack integrated with a waste energy recovery system
US6630264 *19 Abr 20017 Oct 2003Delphi Technologies, Inc.Solid oxide fuel cell process gas sampling for analysis
Citada por
Patente citante Fecha de presentación Fecha de publicación Solicitante Título
US826850422 Dic 200818 Sep 2012General Electric CompanyThermomechanical sealing of interconnect manifolds in fuel cell stacks
US20080032172 *4 Ago 20067 Feb 2008Subhasish MukerjeeConductive coating for solid oxide fuel cell
US20100159304 *22 Dic 200824 Jun 2010General Electric CompanyThermomechanical sealing of interconnect manifolds in fuel cell stacks
US20110159173 *3 Mar 201130 Jun 2011Delphi Technologies, Inc.Conductive coating for solid oxide fuel cells
EP2712012A217 Sep 201326 Mar 2014Delphi Technologies, Inc.A method of manufacturing a fuel cell stack having an electrically conductive interconnect.
Clasificaciones
Clasificación de EE.UU.429/468, 429/469
Clasificación internacionalH01M8/24, H01M8/02, F16J15/10
Clasificación cooperativaH01M8/0273, H01M8/0208, F16J15/102, H01M8/2425, H01M8/021
Clasificación europeaH01M8/02D2, H01M8/02C2A2, F16J15/10B, H01M8/24B2H, H01M8/02C2A2F