US20050189228A1 - Electroplating apparatus - Google Patents
Electroplating apparatus Download PDFInfo
- Publication number
- US20050189228A1 US20050189228A1 US10/789,793 US78979304A US2005189228A1 US 20050189228 A1 US20050189228 A1 US 20050189228A1 US 78979304 A US78979304 A US 78979304A US 2005189228 A1 US2005189228 A1 US 2005189228A1
- Authority
- US
- United States
- Prior art keywords
- shield
- wafer
- electroplating
- anode
- cathode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
- H01L21/283—Deposition of conductive or insulating materials for electrodes conducting electric current
- H01L21/288—Deposition of conductive or insulating materials for electrodes conducting electric current from a liquid, e.g. electrolytic deposition
- H01L21/2885—Deposition of conductive or insulating materials for electrodes conducting electric current from a liquid, e.g. electrolytic deposition using an external electrical current, i.e. electro-deposition
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
- C25D17/001—Apparatus specially adapted for electrolytic coating of wafers, e.g. semiconductors or solar cells
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
- C25D17/007—Current directing devices
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
- C25D17/008—Current shielding devices
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
- C25D17/10—Electrodes, e.g. composition, counter electrode
- C25D17/12—Shape or form
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Electroplating Methods And Accessories (AREA)
- Electrodes Of Semiconductors (AREA)
Abstract
A electroplating apparatus which is suitable for depositing a metal layer of substantially uniform thickness across the center and edge regions of a semiconductor wafer substrate is disclosed. The apparatus includes a reservoir for containing an electrolytic fluid. A cathode, to which is mounted a wafer, and an anode in the electrolytic fluid are connected to an electroplating current source. A shield is provided between the cathode and anode to facilitate a more uniform deposit of the metal onto the wafer across the entire surface, including the center and edge regions, of the wafer.
Description
- The present invention relates to electrochemical plating (ECP) apparatuses and processes used to deposit metal layers on semiconductor wafer substrates in the fabrication of semiconductor integrated circuits. More particularly, the present invention relates to an elecroplating apparatus which includes a shield interposed between an anode and a cathode to reduce the electroplating deposition rate at the edge region of a substrate and facilitate deposition of a metal film having a substantially uniform thickness across the entire surface of a wafer.
- In the fabrication of semiconductor integrated circuits, metal conductor lines are used to interconnect the multiple components in device circuits on a semiconductor wafer. A general process used in the deposition of metal conductor line patterns on semiconductor wafers includes deposition of a conducting layer on the silicon wafer substrate; formation of a photoresist or other mask such as titanium oxide or silicon oxide, in the form of the desired metal conductor line pattern, using standard lithographic techniques; subjecting the wafer substrate to a dry etching process to remove the conducting layer from the areas not covered by the mask, thereby leaving the metal layer in the form of the masked conductor line pattern; and removing the mask layer typically using reactive plasma and chlorine gas, thereby exposing the top surface of the metal conductor lines. Typically, multiple alternating layers of electrically conductive and insulative materials are sequentially deposited on the wafer substrate, and conductive layers at different levels on the wafer may be electrically connected to each other by etching vias, or openings, in the insulative layers and filling the vias using aluminum, tungsten or other metal to establish electrical connection between the conductive layers.
- Deposition of conductive layers on the wafer substrate can be carried out using any of a variety of techniques. These include oxidation, LPCVD (low-pressure chemical vapor deposition), APCVD (atmospheric-pressure chemical vapor deposition), and PECVD (plasma-enhanced chemical vapor deposition). In general, chemical vapor deposition involves reacting vapor-phase chemicals that contain the required deposition constituents with each other to form a nonvolatile film on the wafer substrate. Chemical vapor deposition is the most widely-used method of depositing films on wafer substrates in the fabrication of integrated circuits on the substrates.
- Due to the ever-decreasing size of semiconductor components and the ever-increasing density of integrated circuits on a wafer, the complexity of interconnecting the components in the circuits requires that the fabrication processes used to define the metal conductor line interconnect patterns be subjected to precise dimensional control. Advances in lithography and masking techniques and dry etching processes, such as RIE (Reactive Ion Etching) and other plasma etching processes, allow production of conducting patterns with widths and spacings in the submicron range. Electrodeposition or electroplating of metals on wafer substrates has recently been identified as a promising technique for depositing conductive layers on the substrates in the manufacture of integrated circuits and flat panel displays. Such electrodeposition processes have been used to achieve deposition of the copper or other metal layer with a smooth, level or uniform top surface. Consequently, much effort is currently focused on the design of electroplating hardware and chemistry to achieve high-quality films or layers which are uniform across the entire surface of the substrates and which are capable of filling or conforming to very small device features. Copper has been found to be particularly advantageous as an electroplating metal.
- Electroplated copper provides several advantages over electroplated aluminum when used in integrated circuit (IC) applications. Copper is less electrically resistive than aluminum and is thus capable of higher frequencies of operation. Furthermore, copper is more resistant to electromigration (EM) than is aluminum. This provides an overall enhancement in the reliability of semiconductor devices because circuits which have higher current densities and/or lower resistance to EM have a tendency to develop voids or open circuits in their metallic interconnects. These voids or open circuits may cause device failure or burn-in.
- A typical standard or conventional
electroplating system 10 for depositing a metal such as copper onto a semiconductor wafer is shown inFIG. 1 . Theelectroplating system 10 includes a standard electroplating cell having an adjustablecurrent source 12, abath container 14 which holds an electrolyte electroplating bath solution (typically acid copper sulfate solution) 16, and acopper anode 18 and acathode 20 immersed in the electrolyte solution. Thecathode 20 includes asemiconductor wafer 22 that is to be electroplated with metal. Acontact ring 24 mounts thewafer 22 to thecathode 20. - Both the
anode 18 and thecathode 20 are connected to thecurrent source 12 typically by means ofsuitable wiring 26. Theelectroplating bath solution 16 may include an additive for filling of submicron features and leveling the surface of the copper electroplated on thewafer 22. An electrolyte holding tank (not shown) be may further be connected to thebath container 14 for the addition of extra electrolyte solution to thebath container 14, as needed. - In operation of the
electroplating system 10, thecurrent source 12 applies a selected voltage potential typically at room temperature between theanode 18 and thecathode 20. This potential creates a magnetic field around theanode 18 and thecathode 20, which magnetic field affects the distribution of the copper ions in thebath 16. In a typical copper electroplating application, a voltage potential of about 2 volts may be applied for about 2 minutes, and a current of about 4.5 amps flows between the anode and thecathode 20 andwafer 22. Consequently, copper is oxidized at theanode 18 as electrons from thecopper anode 18 reduce the ionic copper in the coppersulfate solution bath 16 to form a copper electroplate on thewafer 22, at the interface between thewafer 22 and thecopper sulfate bath 16. - The copper oxidation reaction which takes place at the
anode 18 is illustrated by the following reaction equation:
Cu---->Cu+++2 e − - The oxidized copper cation reaction product forms ionic copper sulfate in solution with the sulfate anion in the bath 16:
Cu+++SO4 −−---->Cu++SO4 −− - At the
wafer 22, the electrons harvested from the anode flowed through the wiring reduce copper cations in solution in thecopper sulfate bath 16 to electroplate the reduced copper onto the wafer 22:
Cu+++2 e −---->Cu - When a copper layer is deposited on the
wafer 22, such as by electrochemical plating, the copper layer must be deposited on ametal seed layer 23 such as copper which is deposited on thewafer 22 prior to the copper ECP process. Seed layers may be applied to the substrate using any of a variety of methods, such as by physical vapor deposition (PVD) and chemical vapor deposition (PVD). Typically, metal seed layers are thin (about 50-1500 angstroms thick) in comparison to conductive metal layers deposited on a semiconductor wafer substrate. - Conventional electrochemical plating techniques use copper sulfate (CuSO4) for the main electrolyte in the electroplating bath solution. The solution may further include additives such as chloride ion and levelers, as well as accelerators and suppressors which increase and decrease, respectively, the rate of the electroplating process. The rate of deposition of copper on the substrate, and the quality and resulting electrical and mechanical properties of the metallization, are largely dependent on the concentration of these organic additives in the electroplating bath solution.
- However, one of the drawbacks of the conventional
electroplating system 10 is that the current density at thecontact ring 24 is higher than the current density at the central region of thewafer 22. Therefore, the plating film is thicker at the edge region than at the center region of thewafer 22. Thus, the thickness of the plating film electroplated onto thewafer 22 is non-uniform. Accordingly, a novel electroplating device is needed to control the thickness of a metal electroplated onto the edge region of a substrate in order to facilitate a more uniform distribution of the metal across the edge and central regions of a wafer. - An object of the present invention is to provide a novel electroplating apparatus which is suitable for the electroplating of a metal on a wafer in the fabrication of integrated circuits.
- Another object of the present invention is to provide a novel electroplating apparatus which facilitates control in the thickness of a metal electroplated onto the edge region of a wafer.
- Another object of the present invention is to provide a novel electroplating apparatus which may include a mechanism to control the ion density of an electroplating solution in order to control the quantity of metal electroplated onto an edge region of a wafer.
- Still another object of the present invention is to provide a novel electroplating apparatus which may include a shield positioned between an anode and a cathode/wafer to alter the electric pathway between the wafer and the anode and improve the thickness uniformity of a metal layer electroplated onto the wafer.
- Yet another object of the present invention is to provide a novel electroplating apparatus which may include a shield positioned between an anode and a cathode/wafer and a current source electrically connected to the shield to apply a selected negative or positive voltage to the shield and adjust the concentration of metal ions in an electroplating bath for the uniform deposit of a metal layer on the wafer.
- Yet another object of the present invention is to provide a novel method for the uniform electroplating of a metal onto a wafer.
- In accordance with these and other objects and advantages, the present invention is generally directed to a novel electroplating apparatus which is suitable for depositing a metal layer of substantially uniform thickness across the center and edge regions of a semiconductor wafer substrate. The apparatus includes a reservoir for containing an electrolytic fluid. A cathode, to which is mounted a wafer, and an anode in the electrolytic fluid are connected to an electroplating current source. A shield is provided between the cathode and anode to facilitate a more uniform deposit of the metal onto the wafer across the entire surface, including the center and edge regions, of the wafer.
- The shield may have a ring-shaped configuration or a plate-shaped configuration and may be either electrically non-conductive or electrically-conductive. The electrically non-conductive shield alters the electric pathway between the anode and cathode in the electrolytic fluid. Consequently, the distribution of metal ions in the fluid, between the shield and wafer, is changed in such a manner that the thickness of a metal layer deposited onto the wafer is substantially uniform across the edge and center regions of the wafer.
- The electrically-conductive shield may be connected to a shield current source. A switch may be provided between the shield current source and the shield. The switch may be manipulated to apply a negative charge to the shield, in which case the shield acts as a cathode and reduces the quantity of metal cations in the electrolytic fluid in the area adjacent to the edge region as compared to the area adjacent to the center region of the wafer. Consequently, the electroplating metal deposition rate at the edge region is reduced to compensate for the normally lower metal deposition rate at the center region of the wafer, thus enhancing the overall thickness uniformity of the electroplated metal.
- The switch may be manipulated to apply a positive charge to the shield, in which case the shield acts as an anode. Accordingly, the concentration of metal cations in the electrolytic fluid in the area adjacent to the edge region relative to the center region of the wafer is increased, to increase the electroplating deposition rate of the metal onto the edge region of the wafer, as deemed necessary. By the alternating application of positive and negative charges to the wafer using the switch, the thickness of metal electroplated onto the edge region of the wafer can be precisely controlled to provide a layer of electroplated metal having a substantially uniform thickness across the entire surface of the wafer.
- The invention will now be described, by way of example, with reference to the accompanying drawings, in which:
-
FIG. 1 is a schematic of a typical conventional electroplating system; -
FIG. 2 is a schematic of an electroplating apparatus of the present invention; -
FIG. 3 is a top view of a ring-shaped shield element of the electroplating apparatus ofFIG. 2 ; -
FIG. 4 is a cross-section taken along section lines 4-4 inFIG. 3 ; -
FIG. 5 is a schematic of another embodiment of the electroplating apparatus of the present invention; -
FIG. 6 is a top view of a plate-shaped shield element of the electroplating apparatus ofFIG. 5 ; -
FIG. 7 is a cross-section taken along section lines 7-7 inFIG. 6 ; and -
FIG. 8 is a schematic of still another embodiment of the electroplating apparatus of the present invention. - The present invention has particularly beneficial utility in the electrochemical plating of copper or other metal onto a semiconductor wafer substrate in the fabrication of semiconductor integrated circuits. However, the invention is more generally applicable to the electrochemical plating of metals including but not limited to copper on substrates in a variety of industrial applications, including but not limited to semiconductor fabrication.
- The present invention is generally directed to a novel electroplating apparatus which enhances uniformity in the thickness of a metal layer deposited on a semiconductor wafer. The apparatus facilitates the electroplating of a metal layer having substantially uniform thickness across the entire wafer surface, particularly between the center and edge regions of the wafer. The apparatus includes a bath container having a reservoir for containing an electrolytic fluid. A cathode and an anode immersed in the electrolytic fluid are connected to an electroplating current source. The wafer is provided in electrical contact with the cathode, in the electrolytic fluid. A shield is provided between the cathode and anode to modify the electrical characteristics of the electrolytic fluid and provide a substantially uniform thickness of the metal electroplated onto the center and edge regions of the wafer.
- The shield may be ring-shaped or plate-shaped and may be electrically non-conductive or electrically-conductive. In one embodiment of the apparatus, the shield is either electrically conductive or non-conductive and alters the electric pathway between the anode and cathode in the electrolytic fluid. This alters the distribution of metal ions in the electrolytic fluid in such a manner that the thickness of a metal layer deposited onto the wafer is substantially the same across the edge region and center region on the wafer.
- In another embodiment of the apparatus, the shield is electrically-conductive and may be connected to a shield current source. A switch may be provided between the shield current source and the shield. When the switch is manipulated to apply a negative charge to the shield, the shield acts as a cathode and reduces metal cations in the electrolytic fluid in the area adjacent to the edge region of the wafer. This reduces the quantity of metal cations in the electrolytic fluid in the area adjacent to the edge region as compared to the area adjacent to the center region of the wafer. Consequently, the electroplating metal deposition rate at the edge region of the wafer is reduced to compensate for the normally lower metal deposition rate at the center region of the wafer. This enhances the overall thickness uniformity of the electroplated metal across the entire surface of the wafer.
- Upon application of a positive charge to the shield by manipulation of the switch, the shield acts as an anode. Accordingly, the concentration of metal cations in the electrolytic fluid in the area adjacent to the edge region of the wafer is increased, to increase the electroplating deposition rate of the metal onto the edge region of the wafer, as needed. By the alternating application of positive and negative charges to the wafer by manipulation of the switch, the thickness of metal electroplated onto the edge region of the wafer can be precisely controlled to provide a layer of electroplated metal having a substantially uniform thickness across the entire surface of the wafer.
- The electroplating apparatus may further include a mechanism to control the relative position of the shield with respect to the wafer in the electrolytic fluid. By movement of the negatively-charged cathode/shield toward the wafer, the deposition rate of the metal onto the edge region of the wafer is reduced correspondingly. By movement of the negatively-charged cathode/shield away from the wafer, the deposition rate of the metal onto the edge region of the wafer is increased. This mechanism can be used in combination with the switch to facilitate precise control of the relative thickness of metal electroplated onto the center and edge regions of the wafer.
- The electroplating apparatus of the present invention may be used with any formulation for the electrolytic fluid, such as copper, aluminum, nickel, chromium, zinc, tin, gold, silver, lead and cadmium electroplating baths. The present invention is also suitable for use with electroplating baths containing mixtures of metals to be plated onto a substrate. It is preferred that the electrolytic fluid be a copper alloy electroplating bath, and more preferably, a copper electroplating bath. Typical copper electroplating bath formulations are well known to those skilled in the art and include, but are not limited to, an electrolyte and one or more sources of copper ions.
- Suitable electrolytes include, but are not limited to, sulfuric acid, acetic acid, fluoroboric acid, methane sulfonic acid, ethane sulfonic acid, trifluormethane sulfonic acid, phenyl sulfonic acid, methyl sulfonic acid, p-toluenesulfonic acid, hydrochloric acid, phosphoric acid and the like. The acids are typically present in the bath in a concentration in the range of from about 1 to about 300 g/L. The acids may further include a source of halide ions such as chloride ions. Suitable sources of copper ions include, but are not limited to, copper sulfate, copper chloride, copper acetate, copper nitrate, copper fluoroborate, copper methane sulfonate, copper phenyl sulfonate and copper p-toluene sulfonate. Such copper ion sources are typically present in a concentration in the range of from about 10 to about 300 g/L of electroplating solution.
- Other electrochemical plating process conditions suitable for implementation of the present invention include a plating rpm of from typically about 0 rpm to about 500 rpm; a plating current of from typically about 0.2 mA/cm2 to about 20 mA/cm2; a plating voltage of typically about 2 volts and a bath temperature of from typically about 10 degrees C. to about 35 degrees C. In cases in which planarity of the electroplated metal through chemical mechanical planarization (CMP) is necessary, a leveling agent may be added to the electroplating bath solution at a concentration of from typically about 5 mmol/L to about 5 mol/L.
- Referring to
FIG. 2 , an illustrative embodiment of anelectroplating apparatus 30 of the present invention is shown. Theapparatus 30 may be conventional and includes a standard electroplating cell having an adjustable electroplatingcurrent source 32, abath container 34 having aninterior bath reservoir 35, a typicallycopper anode 36 and acathode 38. Acontact ring 40 holds asemiconductor wafer 42 that is to be electroplated with metal, against thecathode 38. - The
anode 36 andcathode 38 are connected to thecurrent source 32 by means ofsuitable wiring 33. Thebath container 34 holds an electrolytic fluid orelectroplating bath solution 44. Theapparatus 30 may further include a mechanism (not shown) for rotating thewafer 42 in theelectrolytic fluid 44 during the electroplating process, as is known by those skilled in the art. - A
shield 46 is mounted in thebath container 34, beneath thecontact ring 40, according to techniques known by those skilled in the art. In a preferred embodiment, theshield 46 is mounted on apositional adjustment arm 60 which is engaged by apositional adjustment motor 58. Thepositional adjustment motor 58 is operated to adjust the vertical position of theshield 46 in thebath container 34, and thus, the proximity of theshield 46 to thecontact ring 24. - As shown in
FIGS. 3 and 4 , theshield 46 typically includes a ring-shapedshield body 48 having acentral shield opening 50. Theshield body 48 may be an electrically-conductive metal or a non-conductive material such as plastic or ceramic, for example. In the case of anon-conductive shield body 48, an electrically-conductive material 51 covers the surfaces of theshield body 48. Preferably, the electrically-conductive material 51 is copper. - As shown in
FIGS. 3 and 4 , typical dimensions for the ring-shapedshield 46 include adiameter 64 of typically about 150˜200 mm; aring width 65 of typically about 3˜5 cm; and athickness 66 of typically about 30˜50 mm. These dimensions are compatible with anelectroplating apparatus 30 which is sized for the processing of 300 mm wafers. However, it is understood that these dimensions may vary depending on the diameter of wafers to be processed in theelectroplating apparatus 30. - An
electrical contact 52, such as suitable wiring, for example, is electrically connected to theshield 46. Aswitch 54 is connected to theelectrical contact 52. Theswitch 54 provides selective electrical connection between a positive terminal 56 a and anegative terminal 56 b of a shieldcurrent source 56. Accordingly, in operation of theapparatus 30 as hereinafter described, a positive charge is selectively applied to theshield 46 by establishing electrical communication between the positive terminal 56 a and theshield 46 through theswitch 54, as indicated by the phantom lines inFIG. 2 . Conversely, a negative charge is selectively applied to theshield 46 by establishing electrical communication between thenegative terminal 56 b and theshield 46 through theswitch 54. - Referring to
FIGS. 5-7 , an alternative embodiment of the present invention is shown wherein anelectroplating apparatus 70 includes ashield 72 having a plate-shapedshield body 74, as shown inFIGS. 6 and 7 . Theshield body 74 may be an electrically-conductive metal or a non-conductive material such as plastic or ceramic, for example. In the case of anon-conductive shield body 74, an electrically-conductive material 76 covers the surfaces of theshield body 74. Preferably, the electrically-conductive material 76 is copper. - Referring again to
FIG. 2 , in operation of theelectroplating apparatus 30, anelectrolytic fluid 44 is placed in thebath reservoir 35 of thebath container 34, with theanode 36 immersed in theelectrolytic fluid 44. Thewafer 42, having ametal seed layer 43 deposited thereon, is attached to thecathode 38, typically using thecontact ring 40, and immersed in theelectrolytic fluid 44. The electroplatingcurrent source 32 is energized to apply a negative voltage to thecathode 38 and a positive voltage to theanode 36. - At the
wafer 42, metal cations such as copper in theelectrolyte fluid 44 are reduced to form metal atoms, which are electroplated onto theseed layer 43. However, due to the presence of thecontact ring 40, the current density is higher in the area of theelectrolyte fluid 44 which is adjacent to the edge region of thewafer 42 than in the area of theelectrolyte fluid 44 which is adjacent to the center region of thewafer 42. Consequently, the metal deposition rate is typically higher at the edge region than at the center region of thewafer 42. - To reduce the electroplating rate at the edge of the
wafer 42, theswitch 54 is manipulated to establish electrical communication between theshield 46 and thenegative terminal 56 b of the shieldcurrent source 56. This imparts a negative charge to theshield 46, causing the shield to act as a cathode in theelectrolytic fluid 44. Accordingly, metal cations adjacent to theshield 46 are reduced, forming metal atoms that are electroplated onto theshield 46. The concentration of metal cations in theelectrolyte fluid 44 adjacent to the edge region of thewafer 42 is therefore reduced, thus lowering the electroplating deposition rate of the metal onto the edge region of thewafer 42. - In the event that it is deemed necessary to increase the electroplating rate at the edge region of the
wafer 42, theswitch 54 can be manipulated to establish electrical communication between theshield 46 and the positive terminal 56 a of the shieldcurrent source 56. This imparts a positive charge to theshield 46, causing theshield 46 to act as an anode. Accordingly, metal from the electrically-conductive material 51 (FIG. 4 ) of theshield 46 is oxidized, causing metal cations to enter theelectrolytic fluid 44. This increases the concentration of metal cations at the edge region of thewafer 42, thereby accelerating the electroplating deposition rate at the edge region of thewafer 42. - The electroplating deposition rate of metal onto the edge region of the
wafer 42 can be further controlled by adjusting the proximity of theshield 46 with respect to thewafer 42. Thus, when theswitch 54 applies a negative charge to the cathode/shield 46, the electroplating deposition rate at the edge region of thewafer 42 can be decreased, as needed, by moving theshield 46 into closer proximity to thecontact ring 40. Conversely, when theswitch 54 applies a positive charge to the anode/shield 46, the electroplating deposition rate at the edge region of thewafer 42 can be increased, as needed, by moving theshield 46 into closer proximity to thecontact ring 40. Positional adjustment of theshield 46 in theelectrolyte fluid 44 is accomplished by actuation of thepositional adjustment motor 58 andpositional adjustment arm 60. - Referring next to
FIG. 8 , in anelectroplating apparatus 80 of still another embodiment of the present invention, theelectrical contact 52,switch 54 and shieldcurrent source 56 of the embodiments ofFIGS. 2 and 5 are omitted. Theelectroplating apparatus 80 includes ashield 82 which is interposed between theanode 36 and thecathode 38. The position of theshield 82 may typically be adjusted in theelectrolyte fluid 44 by actuation of apositional adjustment motor 58 andpositional adjustment arm 60, as heretofore described with respect to the embodiments ofFIGS. 2 and 5 . - The
shield 82 may be an electrically non-conductive material such as plastic or ceramic, for example. Alternatively, theshield 82 may be an electrically-conductive material such as copper. Still further in the alternative, theshield 82 may include an electrically non-conductive shield body (not shown) which is covered with an electrically-conductive material, as heretofore described with respect to the embodiment ofFIGS. 2 and 5 . Furthermore, theshield 82 may have either a ring-shaped configuration or a plate-shaped configuration. - In operation of the
electroplating apparatus 80, theshield 82 changes the distribution of metal cations in theelectrolytic fluid 44, between theanode 36 and thewafer 42, in such a manner that the electroplating deposition rate at the edge region of thewafer 42 is slowed down to substantially equal the electroplating deposition rate at the center region of thewafer 42. Consequently, the thickness of a metal layer deposited onto theseed layer 43 on thewafer 42 is substantially uniform between the edge and center regions of thewafer 42. The electro deposition rate at the edge region of thewafer 42 can be increased, as needed, by moving theshield 82 into closer proximity to thewafer 42 by operation of thepositional adjustment motor 58. - While the preferred embodiments of the invention have been described above, it will be recognized and understood that various modifications can be made in the invention and the appended claims are intended to cover all such modifications which may fall within the spirit and scope of the invention.
Claims (24)
1. An electroplating apparatus comprising:
a reservoir for holding an electrolyte fluid;
an anode and a cathode for holding a wafer provided in said reservoir;
an electrical pathway provided between said cathode and said anode; and
a shield provided between said cathode and said anode.
2. The electroplating apparatus of claim 1 wherein said shield comprises a generally ring-shaped shield body.
3. The electroplating apparatus of claim 2 further comprising an electrically-conductive material provided on said shield body.
4. The electroplating apparatus of claim 3 wherein said electrically-conductive material comprises copper.
5. The electroplating apparatus of claim 3 further comprising a shield current source electrically connected to said shield for selectively applying a negative charge to said shield.
6. The electroplating apparatus of claim 2 wherein said shield body comprises an electrically non-conductive material.
7. An electroplating apparatus comprising:
a reservoir for holding an electrolyte fluid;
an anode and a cathode for holding a wafer provided in said reservoir;
an electrical pathway provided between said cathode and said anode; and
a shield comprising a generally plate-shaped shield body provided between said cathode and said anode.
8. The electroplating apparatus of claim 7 further comprising an electrically-conductive material provided on said shield body.
9. The electroplating apparatus of claim 8 wherein said electrically-conductive material comprises copper.
10. The electroplating apparatus of claim 8 further comprising a shield current source electrically connected to said shield for selectively applying a negative charge to said shield.
11. The electroplating apparatus of claim 7 wherein said shield body comprises an electrically non-conductive material.
12. A method of electroplating a metal on a wafer, comprising:
providing a reservoir containing an electrolyte fluid;
providing an anode and a cathode in said reservoir;
providing an electrical pathway between said cathode and said anode;
providing a shield in said electrolyte fluid between said cathode and said anode; and
applying a current to said cathode and said anode.
13. The method of claim 12 wherein said shield comprises a generally ring-shaped shield body.
14. The method of claim 13 further comprising an electrically-conductive material provided on said shield body.
15. The method of claim 14 wherein said electrically-conductive material comprises copper.
16. The method of claim 14 further comprising a shield current source electrically connected to said shield for selectively applying a negative charge to said shield.
17. The method of claim 16 further comprising selectively applying said negative charge to said shield for electroplating a metal onto said shield and applying a positive charge to said shield for releasing metal cations from said shield into said electrolyte fluid.
18. The method of claim 13 wherein said shield body comprises an electrically non-conductive material.
19. The method of claim 12 wherein said shield comprises a generally plate-shaped shield body.
20. The method of claim 19 further comprising an electrically-conductive material provided on said shield body.
21. The method of claim 20 wherein said electrically-conductive material comprises copper.
22. The method of claim 20 further comprising a shield current source electrically connected to said shield for selectively applying a negative charge to said shield.
23. The method of claim 19 wherein said shield body comprises an electrically non-conductive material.
24. The method of claim 22 further comprising selectively applying said negative charge to said shield for electroplating a metal onto said shield and applying a positive charge to said shield for releasing metal cations from said shield into said electrolyte fluid.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/789,793 US20050189228A1 (en) | 2004-02-27 | 2004-02-27 | Electroplating apparatus |
TW094105778A TWI260715B (en) | 2004-02-27 | 2005-02-25 | Electroplating apparatus |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/789,793 US20050189228A1 (en) | 2004-02-27 | 2004-02-27 | Electroplating apparatus |
Publications (1)
Publication Number | Publication Date |
---|---|
US20050189228A1 true US20050189228A1 (en) | 2005-09-01 |
Family
ID=34887380
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/789,793 Abandoned US20050189228A1 (en) | 2004-02-27 | 2004-02-27 | Electroplating apparatus |
Country Status (2)
Country | Link |
---|---|
US (1) | US20050189228A1 (en) |
TW (1) | TWI260715B (en) |
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20060081468A1 (en) * | 2004-10-19 | 2006-04-20 | Jds Uniphase Corporation | Magnetic latch for a vapour deposition system |
US20060137977A1 (en) * | 2004-12-29 | 2006-06-29 | Samsung Electronics Co., Ltd. | Wafer electroplating apparatus for improving process uniformity |
US20060237304A1 (en) * | 2005-04-22 | 2006-10-26 | Wataru Yamamoto | Electroplating apparatus |
US20080006529A1 (en) * | 2004-08-20 | 2008-01-10 | Jds Uniphase Corporation | Substrate Holder Assembly Device |
US20080022507A1 (en) * | 2006-07-26 | 2008-01-31 | Hanna Mark B | Manufacturing method for a septum polarizer |
EP1903603A2 (en) * | 2006-09-20 | 2008-03-26 | JDS Uniphase Corporation | Substrate holder assembly device |
US20090243051A1 (en) * | 2008-03-28 | 2009-10-01 | Micron Technology, Inc. | Integrated conductive shield for microelectronic device assemblies and associated methods |
US7790004B2 (en) | 2004-08-20 | 2010-09-07 | Jds Uniphase Corporation | Substrate holder for a vapour deposition system |
US20100275842A1 (en) * | 2009-04-30 | 2010-11-04 | Samsung Mobile Display Co., Ltd. | Evaporating apparatus |
US20120115328A1 (en) * | 2009-10-23 | 2012-05-10 | Semiconductor Manufacturing International (Shanghai) Corporation | Electroforming technique for mask formation |
CN102560612A (en) * | 2012-02-08 | 2012-07-11 | 南通富士通微电子股份有限公司 | Anode assembly for electroplating and electroplating device |
CN102560611A (en) * | 2012-02-08 | 2012-07-11 | 南通富士通微电子股份有限公司 | Anode assembly and electroplating device for electroplating |
CN103160906A (en) * | 2013-04-11 | 2013-06-19 | 蓝宁 | Method for improving electroplating and electroforming effects and electroplating and electroforming device |
US8575025B2 (en) | 2011-07-28 | 2013-11-05 | Hewlett-Packard Development Company, L.P. | Templated circuitry fabrication |
TWI471446B (en) * | 2013-08-22 | 2015-02-01 | ||
US11646259B2 (en) | 2020-10-27 | 2023-05-09 | Industrial Technology Research Institute | Redistribution structure and forming method thereof |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20090049957A (en) * | 2007-11-14 | 2009-05-19 | 삼성전기주식회사 | Plating apparatus |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6027631A (en) * | 1997-11-13 | 2000-02-22 | Novellus Systems, Inc. | Electroplating system with shields for varying thickness profile of deposited layer |
US6074544A (en) * | 1998-07-22 | 2000-06-13 | Novellus Systems, Inc. | Method of electroplating semiconductor wafer using variable currents and mass transfer to obtain uniform plated layer |
US6391168B1 (en) * | 1999-04-06 | 2002-05-21 | Nec Corporation | Plating apparatus utilizing an auxiliary electrode |
US6402923B1 (en) * | 2000-03-27 | 2002-06-11 | Novellus Systems Inc | Method and apparatus for uniform electroplating of integrated circuits using a variable field shaping element |
US6890413B2 (en) * | 2002-12-11 | 2005-05-10 | International Business Machines Corporation | Method and apparatus for controlling local current to achieve uniform plating thickness |
-
2004
- 2004-02-27 US US10/789,793 patent/US20050189228A1/en not_active Abandoned
-
2005
- 2005-02-25 TW TW094105778A patent/TWI260715B/en active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6027631A (en) * | 1997-11-13 | 2000-02-22 | Novellus Systems, Inc. | Electroplating system with shields for varying thickness profile of deposited layer |
US6074544A (en) * | 1998-07-22 | 2000-06-13 | Novellus Systems, Inc. | Method of electroplating semiconductor wafer using variable currents and mass transfer to obtain uniform plated layer |
US6391168B1 (en) * | 1999-04-06 | 2002-05-21 | Nec Corporation | Plating apparatus utilizing an auxiliary electrode |
US6402923B1 (en) * | 2000-03-27 | 2002-06-11 | Novellus Systems Inc | Method and apparatus for uniform electroplating of integrated circuits using a variable field shaping element |
US6890413B2 (en) * | 2002-12-11 | 2005-05-10 | International Business Machines Corporation | Method and apparatus for controlling local current to achieve uniform plating thickness |
Cited By (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7790004B2 (en) | 2004-08-20 | 2010-09-07 | Jds Uniphase Corporation | Substrate holder for a vapour deposition system |
US20080006529A1 (en) * | 2004-08-20 | 2008-01-10 | Jds Uniphase Corporation | Substrate Holder Assembly Device |
US7954219B2 (en) | 2004-08-20 | 2011-06-07 | Jds Uniphase Corporation | Substrate holder assembly device |
US20060081468A1 (en) * | 2004-10-19 | 2006-04-20 | Jds Uniphase Corporation | Magnetic latch for a vapour deposition system |
US7785456B2 (en) | 2004-10-19 | 2010-08-31 | Jds Uniphase Corporation | Magnetic latch for a vapour deposition system |
US20060137977A1 (en) * | 2004-12-29 | 2006-06-29 | Samsung Electronics Co., Ltd. | Wafer electroplating apparatus for improving process uniformity |
US20060237304A1 (en) * | 2005-04-22 | 2006-10-26 | Wataru Yamamoto | Electroplating apparatus |
US20080022507A1 (en) * | 2006-07-26 | 2008-01-31 | Hanna Mark B | Manufacturing method for a septum polarizer |
US7930814B2 (en) * | 2006-07-26 | 2011-04-26 | Raytheon Company | Manufacturing method for a septum polarizer |
EP1903603A3 (en) * | 2006-09-20 | 2009-09-16 | JDS Uniphase Corporation | Substrate holder assembly device |
EP1903603A2 (en) * | 2006-09-20 | 2008-03-26 | JDS Uniphase Corporation | Substrate holder assembly device |
US20090243051A1 (en) * | 2008-03-28 | 2009-10-01 | Micron Technology, Inc. | Integrated conductive shield for microelectronic device assemblies and associated methods |
US20100275842A1 (en) * | 2009-04-30 | 2010-11-04 | Samsung Mobile Display Co., Ltd. | Evaporating apparatus |
US8961692B2 (en) | 2009-04-30 | 2015-02-24 | Samsung Display Co., Ltd. | Evaporating apparatus |
US20120115328A1 (en) * | 2009-10-23 | 2012-05-10 | Semiconductor Manufacturing International (Shanghai) Corporation | Electroforming technique for mask formation |
US8748313B2 (en) * | 2009-10-23 | 2014-06-10 | Semiconductor Manufaturing International (Shanghai) Corporation | Electroforming technique for mask formation |
US8575025B2 (en) | 2011-07-28 | 2013-11-05 | Hewlett-Packard Development Company, L.P. | Templated circuitry fabrication |
CN102560611B (en) * | 2012-02-08 | 2015-03-18 | 南通富士通微电子股份有限公司 | Anode assembly and electroplating device for electroplating |
CN102560612A (en) * | 2012-02-08 | 2012-07-11 | 南通富士通微电子股份有限公司 | Anode assembly for electroplating and electroplating device |
CN102560611A (en) * | 2012-02-08 | 2012-07-11 | 南通富士通微电子股份有限公司 | Anode assembly and electroplating device for electroplating |
CN102560612B (en) * | 2012-02-08 | 2015-04-15 | 南通富士通微电子股份有限公司 | Anode assembly for electroplating and electroplating device |
CN103160906A (en) * | 2013-04-11 | 2013-06-19 | 蓝宁 | Method for improving electroplating and electroforming effects and electroplating and electroforming device |
TWI471446B (en) * | 2013-08-22 | 2015-02-01 | ||
US11646259B2 (en) | 2020-10-27 | 2023-05-09 | Industrial Technology Research Institute | Redistribution structure and forming method thereof |
Also Published As
Publication number | Publication date |
---|---|
TW200529328A (en) | 2005-09-01 |
TWI260715B (en) | 2006-08-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US20050189228A1 (en) | Electroplating apparatus | |
US7964506B1 (en) | Two step copper electroplating process with anneal for uniform across wafer deposition and void free filling on ruthenium coated wafers | |
US6562204B1 (en) | Apparatus for potential controlled electroplating of fine patterns on semiconductor wafers | |
TW593731B (en) | Apparatus for applying a metal structure to a workpiece | |
US20050145499A1 (en) | Plating of a thin metal seed layer | |
US7799684B1 (en) | Two step process for uniform across wafer deposition and void free filling on ruthenium coated wafers | |
US8513124B1 (en) | Copper electroplating process for uniform across wafer deposition and void free filling on semi-noble metal coated wafers | |
US7708875B2 (en) | Noncontact localized electrochemical deposition of metal thin films | |
US20060079085A1 (en) | Method for applying metal features onto metallized layers using electrochemical deposition | |
US8703615B1 (en) | Copper electroplating process for uniform across wafer deposition and void free filling on ruthenium coated wafers | |
US8926820B2 (en) | Working electrode design for electrochemical processing of electronic components | |
EP1680535A2 (en) | Electroplating compositions and methods for electroplating | |
US8099861B2 (en) | Current-leveling electroplating/electropolishing electrode | |
KR20070027753A (en) | Electrochemical plating cell with an auxiliary electrode in an isolated anolyte compartment | |
US7544281B2 (en) | Uniform current distribution for ECP loading of wafers | |
US20050199507A1 (en) | Chemical structures and compositions of ECP additives to reduce pit defects | |
US7182849B2 (en) | ECP polymer additives and method for reducing overburden and defects | |
US7014739B2 (en) | Convex profile anode for electroplating system | |
US20050211564A1 (en) | Method and composition to enhance wetting of ECP electrolyte to copper seed | |
US7481910B2 (en) | Method and apparatus for stabilizing plating film impurities | |
US7252750B2 (en) | Dual contact ring and method for metal ECP process | |
US7429401B2 (en) | Superconformal metal deposition using derivatized substrates | |
US20030188974A1 (en) | Homogeneous copper-tin alloy plating for enhancement of electro-migration resistance in interconnects | |
US20050245077A1 (en) | Reverse tone mask method for post-CMP elimination of copper overburden | |
CN112831821A (en) | Wafer electroplating device and electroplating method |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: TAIWAN SEMICONDUCTOR MANUFACTURING CO. LTD., TAIWA Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:HUANG, HUNG-YI;REEL/FRAME:015039/0811 Effective date: 20031208 |
|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |