US20060135047A1 - Method and apparatus for clamping a substrate in a high pressure processing system - Google Patents
Method and apparatus for clamping a substrate in a high pressure processing system Download PDFInfo
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- US20060135047A1 US20060135047A1 US11/021,194 US2119404A US2006135047A1 US 20060135047 A1 US20060135047 A1 US 20060135047A1 US 2119404 A US2119404 A US 2119404A US 2006135047 A1 US2006135047 A1 US 2006135047A1
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- pressure
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/67005—Apparatus not specifically provided for elsewhere
- H01L21/67011—Apparatus for manufacture or treatment
- H01L21/67017—Apparatus for fluid treatment
- H01L21/67028—Apparatus for fluid treatment for cleaning followed by drying, rinsing, stripping, blasting or the like
- H01L21/6704—Apparatus for fluid treatment for cleaning followed by drying, rinsing, stripping, blasting or the like for wet cleaning or washing
- H01L21/67057—Apparatus for fluid treatment for cleaning followed by drying, rinsing, stripping, blasting or the like for wet cleaning or washing with the semiconductor substrates being dipped in baths or vessels
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/683—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping
- H01L21/6838—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping with gripping and holding devices using a vacuum; Bernoulli devices
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02041—Cleaning
- H01L21/02101—Cleaning only involving supercritical fluids
Definitions
- Results of this flexing can break wafers, because they are brittle and fragile and cannot elastically deform like stainless steel. It can also cause a grinding or fretting effect between the wafer and the platen, due to the high forces and small displacements which take place. This can create metal or silicon particles to be interspersed between the wafer and platen, which in turn can damage the current wafer, and be present on the platen to damage subsequent wafers that are processed.
- FIG. 1 is a simplified schematic representation of one embodiment of a processing system according to principles of the present invention
- process chemistry supply system 130 can be configured to introduce treating chemistry for curing, cleaning, healing (or restoring the dielectric constant of low-k materials), or sealing, or any combination thereof, or for applying low dielectric constant films (porous or non-porous).
- FIG. 1F shows the system 100 nearly completely depressurized. Only the residual pressure in the chamber 110 and fill line 124 remains at a level equal to the spring value setting of exit check valve 174 , or 100 psig in this example, as valve 176 remains open, but valve 184 can have been closed. At 100 psig in chamber 110 , no more fluid will flow out of exhaust port 108 as check valve 174 will close. Atmospheric pressure, or about 0 psig, can be indicated on gage 172 . At this time, the valve 195 can start to open to evacuate the line to the backside of the wafer 105 and to keep some wafer holding pressure differential on the wafer 105 to hold the wafer 105 to the platen 116 .
Abstract
Pressure biased wafer holding of a semiconductor wafer is provided for use in high pressure processing. The use of vacuum chucking for holding a semiconductor wafer during processing is applied to high pressure systems. Adverse effects of high pressure biases are prevented by a valve arrangement that reduces or limits the holding load on a wafer. Check valves and on-off valves connected to input and output lines to the chamber bias fluid applied to a wafer supporting platen to vary the backside pressure so that the excess of frontside pressure versus backside pressure on the wafer is kept within an effective clamping range without excessive force being applied to the wafer. Use of fluid-mechanical techniques is maximized in certain described embodiments to avoid disadvantages of electronic control systems.
Description
- The present invention relates to a method and system for clamping a substrate in a high pressure processing system and, more particularly, in a supercritical processing system.
- During the fabrication of semiconductor devices for integrated circuits (ICs), a sequence of material processing steps, including both pattern etching and deposition processes, are performed, whereby material is removed from or added to a substrate surface, respectively. During, for instance, pattern etching, a pattern formed in a mask layer of radiation-sensitive material, such as photoresist, using for example photolithography, is transferred to an underlying thin material film using a combination of physical and chemical processes to facilitate the selective removal of the underlying material film relative to the mask layer.
- Thereafter, the remaining radiation-sensitive material, or photoresist, and post-etch residue, such as hardened photoresist and other etch residues, are removed using one or more cleaning processes. Conventionally, these residues are removed by performing plasma ashing in an oxygen plasma, followed by wet cleaning through immersion of the substrate in a liquid bath of stripper chemicals.
- Until recently, dry plasma ashing and wet cleaning were found to be sufficient for removing residue and contaminants accumulated during semiconductor processing. However, recent advancements for ICs include a reduction in the critical dimension for etched features below a feature dimension acceptable for wet cleaning, such as a feature dimension below approximately 45 to 65 nanometers (nm). Moreover, the advent of new materials, such as low dielectric constant (low-k) materials, limits the use of plasma ashing due to their susceptibility to damage during plasma exposure.
- At present, interest has developed for the replacement of dry plasma ashing and wet cleaning. One interest includes the development of dry cleaning systems utilizing a supercritical fluid as a carrier for a solvent, or other residue removing composition. The use of supercritical carbon dioxide, for example, in processing semiconductor wafers has been shown in the art.
- Certain challenges occur when attempting to process silicon wafers under high pressure. One such issue is how to hold the wafer in place during processing. It has been shown that a wafer can be supported at discrete locations around its edge, with high pressure supercritical carbon dioxide (SCCO2) surrounding the entire wafer.
- A different approach is to hold the wafer down on a platen using vacuum or reduced pressure from the top surface of the wafer, which has also been shown. In such a case, bias in pressure keeps the wafer in place during processing, which may include violent events such as sudden decompressions, high surface velocity jets for cleaning, etc. One of the significant drawbacks of vacuum holding is the restraining of the wafer against the platen. With such a large surface area of 300 millimeter (mm) wafers, for example, the exposed area of the platen, is subjected to loads that can exceed half a million pounds. Even very thick steels platens will deflect under this kind of load. Typical pressures encountered in SCCO2 processing are a minimum of 1,031 psi, but 3,000 psi is not uncommon, and upwards of 10,000 psi has been reported in the literature.
- If a wafer is held against a platen, typically of stainless steel, the resulting static pressure load can force the wafer against the platen, which can cause damage to the backside of the wafer. Particulates that may be present can then get embedded into the platen or into the backside of the wafer. This can cause irreparable harm to the wafer for subsequent process steps.
- Another effect of these high forces is the flexing of the platen under the pressure load. As the pressure increases, the wafer becomes restrained against the platen. As pressure continues to increase, the platen can bow due to the load. The wafer may or may not be able to follow the new shape that the platen is forced into due to the pressure load. Once the pressure is released or reduced, the wafer must again readjust for the change in shape of the platen. If multiple pressure cycles are applied, this effect can be repeated many times on a single wafer.
- Results of this flexing can break wafers, because they are brittle and fragile and cannot elastically deform like stainless steel. It can also cause a grinding or fretting effect between the wafer and the platen, due to the high forces and small displacements which take place. This can create metal or silicon particles to be interspersed between the wafer and platen, which in turn can damage the current wafer, and be present on the platen to damage subsequent wafers that are processed.
- The magnitude of this flexing may be considered trivial under ordinary industrial circumstances. Unfortunately with semiconductor wafers, flexing of less than 0.0010 inches, or even as little as 0.0005 inches, have been shown to cause significant damage to wafers, or wafer breakage.
- At present, the inventors have recognized that if the force holding the wafer to the platen is reduced, the wafer can slip in relation to the platen, and the likelihood of breakage can be reduced. If the holding force is reduced even further in magnitude, then wear can also be eliminated because there would not be enough frictional force to create wear or particles.
- Misalignment of features on the wafer platen, or poor flatness of the platen surface can also result in wafer breakage if the holding load is high. If the wafer is required to span over holes or slots in the platen, then the wafer becomes a “bridge” with the entire pressure load bearing down on an unsupported region of thin silicon. It doesn't take a very large span to break a wafer when subjected to 3,000 psi or higher pressures.
- Accordingly, there is a need to overcome the above described problems.
- According to certain principles of the present invention, a processing system is provided which comprises a processing chamber configured to treat said substrate therein with a high pressure fluid; a platen coupled to said processing chamber and configured to support said substrate, a fluid supply system, a fluid flow system coupled to said fluid supply system and said chamber and configured to flow said fluid through said processing chamber over said substrate, and a chuck coupled to said platen and configured to hold said substrate against said platen by a pressure gradient between said high pressure fluid and said platen, wherein said chuck includes means responsive to the pressure of said fluid in said chamber for limiting the magnitude of said pressure gradient.
- According to other principles of the present invention, a vacuum chuck assembly is provided comprising a platen having a wafer supporting surface and configured to support said substrate on said surface for high pressure fluid processing, one or more fluid channels in said platen coupled to said wafer supporting surface, a clamping fluid control system including a clamping fluid line, a first pressure-limiting valve, a second pressure-limiting valve and a third pressure-limiting valve; said clamping fluid line being coupled to said channels, coupled to the outlet of a first pressure-limiting valve that is operable to maintain the pressure in said clamping fluid line to not less than a first maximum pressure gradient less than the pressure in said chamber, and coupled to the inlet of a second pressure-limiting valve that is operable to maintain the pressure in said clamping fluid line to not more than a second maximum pressure gradient more than the pressure to an exhaust line that is coupled to said chamber; said third pressure-limiting valve having an inlet coupled to said chamber, having an outlet coupled to said exhaust line, and being operable to maintain the pressure in said exhaust line at a pressure that is not less than a third maximum pressure gradient less than the pressure in said chamber; said third maximum pressure gradient being greater than said second maximum pressure gradient.
- According to other principles of the present invention, a method of controlling fluid clamping pressure to the backside of a substrate on a platen of a pressure biased wafer holder in a high pressure processing chamber is provided that comprises filling the processing chamber with processing fluid to a high processing pressure and applying a clamping fluid to a backside of a substrate on a platen in said processing chamber at a backside pressure that is responsive to the frontside pressure exerted by said fluid on said substrate, with the backside pressure being less than the frontside pressure by not more than a maximum clamping pressure gradient.
- These and other objectives and advantages of the present invention are set forth in the detailed description of the exemplary embodiments below.
- In the accompanying drawings:
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FIG. 1 is a simplified schematic representation of one embodiment of a processing system according to principles of the present invention; -
FIG. 1A is a diagram of a portion ofFIG. 1 representing the processing system at idle, prior to pressurization of the chamber, with the chamber at 0 psig (atmospheric pressure); -
FIG. 1B is a diagram similar toFIG. 1A but representing the processing system as the chamber is beginning to fill, with fluid therein at 100 psig; -
FIG. 1C is a diagram similar toFIG. 1B but representing the processing system as the chamber continues to fill, with fluid in the chamber at 300 psig; -
FIG. 1D is a diagram similar toFIG. 1C but representing the processing system with the chamber at a processing pressure of 3,000 psig; -
FIG. 1E is a diagram similar toFIG. 1D but representing the processing system as the chamber is beginning to vent, with fluid in the chamber at 1,500 psig; -
FIG. 1F is a diagram similar toFIG. 1E but representing the processing system as the chamber continues to vent, with fluid in the chamber at 100 psig; -
FIG. 1G is a diagram similar toFIG. 1F but representing the processing system as the chamber has been vented to atmospheric pressure, or 0 psig; and -
FIG. 1H is a diagram similar toFIG. 1G but representing the processing system after the chamber has been vented and the platen is back-pressurized for removal of the wafer. - In the following description, to facilitate a thorough understanding of the invention and for purposes of explanation and not limitation, specific details are set forth, such as a particular geometry of the processing system and various descriptions of the system components. However, it should be understood that the invention may be practiced with other embodiments that depart from these specific details.
- Referring now to the drawings, wherein like reference numerals designate identical or corresponding parts throughout the several views,
FIG. 1 illustrates aprocessing system 100 according to an embodiment of the invention. In the illustrated embodiment,processing system 100 is configured to treat asubstrate 105 with a high pressure fluid, such as a fluid in a supercritical state, with or without other additives, such as process chemistry. Theprocessing system 100 comprises processing elements that include aprocessing chamber 110, afluid flow system 120, a processchemistry supply system 130, a high pressurefluid supply system 140, and acontroller 150, all of which are configured to processsubstrate 105. Thecontroller 150 can be coupled to theprocessing chamber 110, thefluid flow system 120, the processchemistry supply system 130, and the high pressurefluid supply system 140. - Alternately, or in addition,
controller 150 can be coupled to a one or more additional controllers/computers (not shown), andcontroller 150 can obtain setup and/or configuration information from an additional controller/computer. - In
FIG. 1 , singular processing elements (110, 120, 130, 140, and 150) are shown, but this is not required for the invention. Theprocessing system 100 can comprise any number of processing elements having any number of controllers associated with them in addition to independent processing elements. - The
controller 150 can be used to configure any number of processing elements (110, 120, 130, and 140), and thecontroller 150 can collect, provide, process, store, and display data from processing elements. Thecontroller 150 can comprise a number of applications for controlling one or more of the processing elements. For example,controller 150 can include a graphic user interface (GUI) component (not shown) that can provide easy to use interfaces that enable a user to monitor and/or control one or more processing elements. - Referring still to
FIG. 1 , thefluid flow system 120 is configured to flow fluid and chemistry from thesupplies processing chamber 110. Thefluid flow system 120 is illustrated as a recirculation system through which the fluid and chemistry recirculate from, and back to, theprocessing chamber 110 viaprimary flow line 122. This recirculation is most likely to be the preferred configuration for many applications, but this is not necessary to the invention. Fluids, particularly inexpensive fluids, can be passed through theprocessing chamber 110 once and then discarded, which might be more efficient than reconditioning them for re-entry into the processing chamber. Accordingly, while the fluid flow system orrecirculation system 120 is described as a recirculating system in the exemplary embodiments, a non-recirculating system may, in some cases, be substituted. Thisfluid flow system 120 can include one or more valves (not shown) for regulating the flow of a processing solution through thefluid flow system 120 and through theprocessing chamber 110. Thefluid flow system 120 can comprise any number of back-flow valves, filters, pumps, and/or heaters (not shown) for maintaining a specified temperature, pressure or both for the processing solution and for flowing the process solution through thefluid flow system 120 and through theprocessing chamber 110. Furthermore, any one of the many components provided within thefluid flow system 120 may be heated to a temperature consistent with the specified process temperature. - Some components, such as a fluid flow or recirculation pump, may require cooling in order to permit proper functioning. For example, some commercially available pumps, having specifications required for processing performance at high pressure and cleanliness during supercritical processing, comprise components that are limited in temperature. Therefore, as the temperature of the fluid and structure are elevated, cooling of the pump is required to maintain its functionality.
Fluid flow system 120 for circulating or otherwise flowing the supercritical fluid throughprocessing chamber 110 can comprise theprimary flow line 122 coupled to highpressure processing system 100, and configured to supply the supercritical fluid at a fluid temperature equal to or greater than 40 degrees C. to the highpressure processing system 100, and a high temperature pump (not shown) coupled to theprimary flow line 122. The high temperature pump can be configured to move the supercritical fluid through theprimary flow line 122 to theprocessing chamber 110, wherein the high temperature pump comprises a coolant inlet configured to receive a coolant and a coolant outlet configured to discharge the coolant. A heat exchanger (not shown) coupled to the coolant inlet can be configured to lower a coolant temperature of the coolant to a temperature less than or equal to the fluid temperature of the supercritical fluid. Details regarding pump design are provided in co-pending U.S. patent application Ser. No. 10/987,066, entitled “Method and System for Cooling a Pump”; the entire content of which is herein incorporated by reference in its entirety. - Referring again to
FIG. 1 , theprocessing system 100 can comprise high pressurefluid supply system 140. The high pressurefluid supply system 140 can be coupled to thefluid flow system 120, but this is not required. In alternate embodiments, high pressurefluid supply system 140 can be configured differently and coupled differently. For example, thefluid supply system 140 can be coupled directly to theprocessing chamber 110. The high pressurefluid supply system 140 can include a supercritical fluid supply system. A supercritical fluid as referred to herein is a fluid that is in a supercritical state, which is that state that exists when the fluid is maintained at or above the critical pressure and at or above the critical temperature on its phase diagram. In such a supercritical state, the fluid possesses certain properties, one of which is the substantial absence of surface tension. Accordingly, a supercritical fluid supply system, as referred to herein, is one that delivers to a processing chamber a fluid that assumes a supercritical state at the pressure and temperature at which the processing chamber is being controlled. Furthermore, it is only necessary that at least at or near the critical point the fluid is in substantially a supercritical state at which its properties are sufficient, and exist long enough, to realize their advantages in the process being performed. Carbon dioxide, for example, is a supercritical fluid when maintained at or above a pressure of about 1,070 psi at a temperature of 31 degrees C. This state of the fluid in the processing chamber may be maintained by operating the processing chamber at 2,000 to 10,000 psi at a temperature of approximately 40 degrees C. or greater. - As described above, the
fluid supply system 140 can include a supercritical fluid supply system, which can be a carbon dioxide supply system. For example, thefluid supply system 140 can be configured to introduce a high pressure fluid having a pressure substantially near the critical pressure for the fluid. Additionally, thefluid supply system 140 can be configured to introduce a supercritical fluid, such as carbon dioxide in a supercritical state. Additionally, for example, thefluid supply system 140 can be configured to introduce a supercritical fluid, such as supercritical carbon dioxide, at a pressure ranging from approximately the critical pressure of carbon dioxide to 10,000 psi. Examples of other supercritical fluid species useful in the broad practice of the invention include, but are not limited to, carbon dioxide (as described above), oxygen, argon, krypton, xenon, ammonia, methane, methanol, dimethyl ketone, hydrogen, water, and sulfur hexafluoride. The fluid supply system can, for example, comprise a carbon dioxide source (not shown) and a plurality of flow control elements (not shown) for generating a supercritical fluid. For example, the carbon dioxide source can include a CO2 feed system, and the flow control elements can include supply lines, valves, filters, pumps, and heaters. Thefluid supply system 140 can comprise an inlet valve (not shown) that is configured to open and close to allow or prevent the stream of supercritical carbon dioxide from flowing into theprocessing chamber 110. For example,controller 150 can be used to determine fluid parameters such as pressure, temperature, process time, and flow rate. - Referring still to
FIG. 1 , the processchemistry supply system 130 is coupled to therecirculation system 120, but this is not required for the invention. In alternate embodiments, the processchemistry supply system 130 can be configured differently, and can be coupled to different elements in theprocessing system 100. The process chemistry is introduced by the processchemistry supply system 130 into the fluid introduced by thefluid supply system 140 at ratios that vary with the substrate properties, the chemistry being used and the process being performed in theprocessing chamber 110. Usually the ratio is roughly 1 to 15 percent by volume in systems where the chamber, recirculation system and associated plumbing have a volume of about one liter. This amounts to about 10 to 150 milliliters of additive in most cases. The ratio may be higher or lower. - The process
chemistry supply system 130 can be configured to introduce one or more of the following process compositions, but not limited to: cleaning compositions for removing contaminants, residues, hardened residues, photoresist, hardened photoresist, post-etch residue, post-ash residue, post chemical-mechanical polishing (CMP) residue, post-polishing residue, or post-implant residue, or any combination thereof; cleaning compositions for removing particulate; drying compositions for drying thin films, porous thin films, porous low dielectric constant materials, or air-gap dielectrics, or any combination thereof; film-forming compositions for preparing dielectric thin films, metal thin films, or any combination thereof; healing compositions for restoring the dielectric constant of low dielectric constant (low-k) films; sealing compositions for sealing porous films; or any combination thereof. Additionally, the processchemistry supply system 130 can be configured to introduce solvents, co-solvents, surfactants, etchants, acids, bases, chelators, oxidizers, film-forming precursors, or reducing agents, or any combination thereof. - The process
chemistry supply system 130 can be configured to introduce N-methyl pyrrolidone (NMP), diglycol amine, hydroxyl amine, di-isopropyl amine, tri-isoprpyl amine, tertiary amines, catechol, ammonium fluoride, ammonium bifluoride, methylacetoacetamide, ozone, propylene glycol monoethyl ether acetate, acetylacetone, dibasic esters, ethyl lactate, CHF3, BF3, HF, other fluorine containing chemicals, or any mixture thereof. Other chemicals such as organic solvents may be utilized independently or in conjunction with the above chemicals to remove organic materials. The organic solvents may include, for example, an alcohol, ether, and/or glycol, such as acetone, diacetone alcohol, dimethyl sulfoxide (DMSO), ethylene glycol, methanol, ethanol, propanol, or isopropanol (IPA). For further details, see U.S. Pat. No. 6,306,564, filed May 27, 1998, and titled “Removal of Resist or Residue from Semiconductors Using Supercritical Carbon Dioxide”, and U.S. Pat. No. 6,509,141, filed Sep. 3, 1999, and titled “Removal of Photoresist and Photoresist Residue from Semiconductors Using Supercritical Carbon dioxide Process,” both incorporated by reference herein. - Additionally, the process
chemistry supply system 130 can comprise a cleaning chemistry assembly (not shown) for providing cleaning chemistry for generating supercritical cleaning solutions within the processing chamber. The cleaning chemistry can include peroxides and a fluoride source. For example, the peroxides can include hydrogen peroxide, benzoyl peroxide, or any other suitable peroxide, and the fluoride sources can include fluoride salts (such as ammonium fluoride salts), hydrogen fluoride, fluoride adducts (such as organo-ammonium fluoride adducts), and combinations thereof. Further details of fluoride sources and methods of generating supercritical processing solutions with fluoride sources are described in U.S. patent application Ser. No. 10/442,557, filed May 20, 2003, and titled “Tetra-Organic Ammonium Fluoride and HF in Supercritical Fluid for Photoresist and Residue Removal”, and U.S. patent application Ser. No. 10/321,341, filed Dec. 16, 2002, and titled “Fluoride in Supercritical Fluid for Photoresist Polymer and Residue Removal,” both incorporated by reference herein. - Furthermore, the process
chemistry supply system 130 can be configured to introduce chelating agents, complexing agents and other oxidants, organic and inorganic acids that can be introduced into the supercritical fluid solution with one or more carrier solvents, such as N,N-dimethylacetamide (DMAc), gamma-butyrolactone (BLO), dimethyl sulfoxide (DMSO), ethylene carbonate (EC), N-methyl pyrrolidone (NMP), dimethylpiperidone, propylene carbonate, and alcohols (such a methanol, ethanol and 2-propanol). - Moreover, the process
chemistry supply system 130 can comprise a rinsing chemistry assembly (not shown) for providing rinsing chemistry for generating supercritical rinsing solutions within the processing chamber. The rinsing chemistry can include one or more organic solvents including, but not limited to, alcohols and ketone. In one embodiment, the rinsing chemistry can comprise sulfolane, also known as thiocyclopentane-1,1-dioxide, (cyclo)tetramethylene sulphone and 2,3,4,5-tetrahydrothiophene-1,1-dioxide, which can be purchased from a number of venders, such as Degussa Stanlow Limited, Lake Court, Hursley Winchester SO21 2LD UK. - Furthermore, the process
chemistry supply system 130 can be configured to introduce treating chemistry for curing, cleaning, healing (or restoring the dielectric constant of low-k materials), or sealing, or any combination thereof, or for applying low dielectric constant films (porous or non-porous). The chemistry can include hexamethyldisilazane (HMDS), chlorotrimethylsilane (TMCS), trichloromethylsilane (TCMS), dimethylsilyldiethylamine (DMSDEA), tetramethyldisilazane (TMDS), trimethylsilyldimethylamine (TMSDMA), dimethylsilyldimethylamine (DMSDMA), trimethylsilyldiethylamine (TMSDEA), bistrimethylsilyl urea (BTSU), bis(dimethylamino)methyl silane (B[DMA]MS), bis (dimethylamino)dimethyl silane (B [DMA]DS), HMCTS, dimethylaminopentamethyldisilane (DMAPMDS), dimethylaminodimethyldisilane (DMADMDS), disila-aza-cyclopentane (TDACP), disila-oza-cyclopentane (TDOCP), methyltrimethoxysilane (MTMOS), vinyltrimethoxysilane (VTMOS), or trimethylsilylimidazole (TMSI). Additionally, the chemistry may include N-tert-butyl-1,1-dimethyl-1-(2,3,4,5-tetramethyl-2,4-cyclopentadiene-1-yl)silanamine, 1,3-diphenyl-1,1,3,3-tetramethyldisilazane, or tert-butylchlorodiphenylsilane. For further details, see U.S. patent application Ser. No. 10/682,196, filed Oct. 10, 2003, and titled “Method and System for Treating a Dielectric Film,” and U.S. patent application Ser. No. 10/379,984, filed Mar. 4, 2003, and titled “Method of Passivating Low Dielectric Materials in Wafer Processing,” both incorporated by reference herein. - Additionally, the process
chemistry supply system 130 can be configured to introduce peroxides during, for instance, cleaning processes. The peroxides can include organic peroxides, or inorganic peroxides, or a combination thereof. For example, organic peroxides can include 2-butanone peroxide; 2,4-pentanedione peroxide; peracetic acid; t-butyl hydroperoxide; benzoyl peroxide; or m-chloroperbenzoic acid (mCPBA). Other peroxides can include hydrogen peroxide. - The
processing chamber 110 can be configured to processsubstrate 105 by exposing thesubstrate 105 to fluid from thefluid supply system 140, or process chemistry from the processchemistry supply system 130, or a combination thereof in aprocessing space 112. Additionally, processingchamber 110 can include anupper chamber assembly 114, and alower chamber assembly 115. - The
upper chamber assembly 114 can comprise a heater (not shown) for heating theprocessing chamber 110, thesubstrate 105, or the processing fluid, or a combination of two or more thereof. Alternately, a heater is not required. Additionally, theupper chamber assembly 114 can include flow components for flowing a processing fluid through theprocessing chamber 110. In one embodiment, the high pressure fluid is introduced to theprocessing chamber 110 through a ceiling formed in theupper chamber assembly 112 and located abovesubstrate 105 through one or more inlets located above a substantially center portion ofsubstrate 105. The high pressure fluid flows radially outward across an upper surface ofsubstrate 105 beyond a peripheral edge ofsubstrate 105, and discharges through one or more outlets, wherein the spacing between the upper surface ofsubstrate 105 and the ceiling decreases with radial position from proximate the substantially center portion ofsubstrate 105 to the peripheral edge ofsubstrate 105. - The
lower chamber assembly 115 can include aplaten 116 configured to supportsubstrate 105 and adrive mechanism 118 for translating theplaten 116 in order to load and unloadsubstrate 105, and sealinglower chamber assembly 115 withupper chamber assembly 114. Theplaten 116 can also be configured to heat or cool thesubstrate 105 before, during, and/or after processing thesubstrate 105. For example, theplaten 116 can include one or more heater rods configured to elevate the temperature of the platen to approximately 31 degrees C. or greater. Additionally, thelower assembly 115 can include a lift pin assembly for displacing thesubstrate 105 from the upper surface of theplaten 116 during substrate loading and unloading. - Additionally,
controller 150 includes a temperature control system coupled to one or more of theprocessing chamber 110, the fluid flow system 120 (or recirculation system), theplaten 116, the high pressurefluid supply system 140, or the processchemistry supply system 130. The temperature control system is coupled to heating elements embedded in one or more of these systems, and configured to elevate the temperature of the supercritical fluid to approximately 31 degrees C. or greater. The heating elements can, for example, include resistive heating elements. - A transfer system (not shown) can be used to move a substrate into and out of the
processing chamber 110 through a slot (not shown). In one example, the slot can be opened and closed by moving theplaten 116, and in another example, the slot can be controlled using an on-off valve (not shown). - The substrate can include semiconductor material, metallic material, dielectric material, ceramic material, or polymer material, or a combination of two or more thereof. The semiconductor material can include Si, Ge, Si/Ge, or GaAs. The metallic material can include Cu, Al, Ni, Pb, Ti, and/or Ta. The dielectric material can include silica, silicon dioxide, quartz, aluminum oxide, sapphire, low dielectric constant materials, TEFLON®, and/or polyimide. The ceramic material can include aluminum oxide, silicon carbide, etc.
- The
processing system 100 can further comprise an exhaust control system. The exhaust control system can be coupled to theprocessing chamber 110, but this is not required. In alternate embodiments, the exhaust control system can be configured differently and coupled differently. The exhaust control system can include an exhaust gas collection vessel (not shown) and can be used to remove contaminants from the processing fluid. Such exhaust control system can be used as an alternative to therecirculation system 120 that is provided to recycle the processing fluid. - The
processing system 100 can also comprise a pressure control system (not shown). The pressure control system can be coupled to theprocessing chamber 110, but this is not required. In alternate embodiments, the pressure control system can be configured differently and coupled differently. The pressure control system can include one or more pressure valves (not shown) for exhausting theprocessing chamber 110 and/or for regulating the pressure within theprocessing chamber 110. Alternately, the pressure control system can also include one or more pumps (not shown). For example, one pump may be used to increase the pressure within the processing chamber, and another pump may be used to evacuate theprocessing chamber 110. In another embodiment, the pressure control system can comprise seals for sealing the processing chamber. In addition, the pressure control system can comprise an elevator for raising and lowering thesubstrate 105 and/or theplaten 116. - The
platen 116 includes a vacuum chuck for clamping the wafer to the platen. The vacuum chuck is coupled to avacuum clamping system 160 which maintains a controlled clamping pressure differential for holding the wafer to theplaten 116. -
FIGS. 1A-1H are schematic diagrams showing thevacuum clamping system 160 in various stages of operation, including the valve and check valve scheme that creates a pressure bias across the wafer under all processing conditions. Thesystem 160 includes a chamberexit valve assembly 170 that controls flow of the processing fluid from theprocessing space 112 within thechamber 110 intoline 120, an entry valve assembly that controls the flow of processing fluid from theline 120 into theprocessing space 112 within thechamber 110, and a platenpressure regulating assembly 190 that controls the pressure of gas under thewafer 105 on theplaten 116 in relation to the pressure in theprocessing space 112 within thechamber 110. -
FIGS. 1A through 1H show the sequence, in order, of processing asingle wafer 105. The pressures picked are for illustration purposes, and can be of any range of pressures. The relationship of the opening values of the check valves produces the operation scheme of this invention. -
FIG. 1A shows thetool 100 in an idle configuration. Awafer 105 has been placed in theprocessing chamber 110.Gages tool 100 for illustrating pressures in each leg. Additional valving and components are anticipated, such as safety relief devices, but are not shown for simplicity of illustration. They are not critical to the basis of this invention, and have been omitted. - As shown in
FIG. 1A ,chamber 110 includes aninlet port 106 and anexhaust port 108 for flow of the processing fluid through thechamber 110. Clean, fresh processing fluid enters thechamber 110 through theinlet port 106 from a fluid entry line 124 and fluid carrying material cleaned or otherwise removed from thesubstrate 105 exits thechamber 110 throughexhaust port 108 into exhaust line 126. The fluid may or may not be recirculated from line 126 to line 124 throughsystem 120, via thefluid flow line 122, which cleans and reconditions the fluid. - The chamber
exit valve assembly 170 in line 126 includes acheck valve 174 and on-off valve 176 connected in series in line 126. Thevalve assembly 170 includes abypass valve 178 in parallel to the check and on-offvalves 174 and 176. A controlfluid vent tap 179 is located in line 126 between thecheck valve 174 and the on-off valve 176. The chamberinlet valve assembly 180 in line 124 includes an on-offvalve 184 in line 124. Theassembly 180 may optionally include an on-offvalve 186 connected in line 124 between thevalve 184 and thechamber inlet port 106. A controlfluid supply tap 189 is located in line 124 between the on-offvalves - The platen
pressure regulating assembly 190 includes a control fluid line 191 connected between thevent tap 179 and thesupply tap 189. In control fluid line 191 are connected anexit check valve 193 and aninlet check valve 194.Gage 172 is connected to a portion 177 of the line 191 between thetap 179 andvalve 193 to indicate the pressure out of the regulatingassembly 190, and thegage 182 is connected to line 191 between thevalve 194 and thesupply tap 189 to indicate the pressure into the regulatingassembly 190.Vacuum ports 117 in theplaten 116 beneath thewafer 105 are maintained at a clamping pressure that, while not necessarily at a vacuum relative to standard atmospheric pressure, are nonetheless at a pressure below the pressure of theprocessing space 112 within thechamber 110 during operation. Theports 117 are connected to acenter section 199 of control line 191 betweencheck valves gage 192 is connected to this line to indicate the platen clamping pressure. Gas into and out of the control line 191 at thiscentral portion 199 flows through on-offvalve 195, to which is avacuum pump 196. To the line between thevalve 195 and thepump 196 is connected a blow offgas supply 197 through an on-offvalve 198. -
FIG. 1A illustrates the system in the idle state in whichvalve 184 is closed. At this time, upstream pressure might be 3,000 psi, for example.Valve 186, which is open, is optional and can be used to isolate the chamber volume from the inlet line and to prevent backflow and contamination of the inlet line when the system is disconnected, for example to add an additional component to the process layout. At this time, thechamber 110 is at atmospheric (atm) pressure, as measured atgage 102. Thewafer 105 is depicted over thevacuum ports 117 of theplaten 116. Theports 117, while positioned to suck the wafer down against the platen, are nonetheless at atmospheric pressure at start up. - The
check valve 174 is a spring check valve having a spring pressure chosen at 100 psi for this example. It operates as a pressure relief valve that permits fluid to flow through it only in a forward direction and only when a pressure gradient of at least 100 psi is present across the valve in the forward direction. As such, the gas pressure in the chamber must build up to over 100 psi for any of it to flow past thecheck valve 174 and out to the open on-off vent valve 176. Vent on-offvalve 178 is employed to bleed off the chamber pressure that is retained by the spring rating of the check valve 174 (100 psi) to more fully depressurize thechamber 110. -
Exit check valve 193 is a low pressure check valve and controls clamping pressure during a decompression sequence. A small pressure value is chosen for this check valve (for example, 10 psi). It also operates as a pressure relief valve asvalve 174 described above. Thecheck valve 193 causes the pressure in lines connected to thewafer vacuum ports 117 in theplaten 116 to be, at most, slightly more than 10 psi above that at thereturn port 179, which is, at most, slightly more than 100 psi below that of the processing space within thechamber 10. -
Inlet check valve 194 and thevalve 195 isolate thevacuum pump 196.Valve 197 controls very low pressure gas, nitrogen in this example, to break any vacuum in the lines and allow thewafer 105 to release from the surface of theplaten 116. Thevacuum pump 196 generates vacuum on the backside of thewafer 105, when necessary. -
FIG. 1B shows thesystem 100 at the start of a chamber fill sequence. Thevacuum pump 196 is operating, andvalve 195 is open allowing vacuum, below atmospheric pressure, to be applied to the backside of thewafer 105 to hold it in place on theplaten 116.Valve 198 is closed.Check valve 193 andcheck valve 194 do not allow flow under this condition. A vacuum level of, for example, only −11 psig, which appears atline 199 and at theports 117 in theplaten 116, will be shown atgage 192. A higher vacuum is generally not required, although is possible up to approximately −14.7 psig. Thepump 196 andvalves controller 150, as are the other valves and components described below. The gas flowing through line 124 may be a neutral gas such as argon, or nitrogen if the chemistry allows, or may be a processing fluid in the gaseous state, for example carbon dioxide. -
Valve 195 is closed after vacuum has been established on the backside of thewafer 105. When pressure begins to increase in inlet line 124, for example with 100 psig being read atgage 182, and continues throughvalve 186 and into thechamber 110, the difference between topside and backside pressure on thewafer 105 might then be 100 psi+11 psi, or 111 psi for retaining thewafer 105 against the surface of theplaten 116. The fluid pressure does not yet flow past theexit check valve 174 and has not yet filled the line 177 to the lowpressure check valve 193.Vent valves 176 and 178 are closed at this time. -
FIG. 1C shows a further step during the fill sequence. When the pressure in inlet line 124 exceeds 200 psig,inlet check valve 194, which operates as a pressure relief valve, begins to open so that, when 300 psig of fill gas has built uppast valve 184 andvalve 186, as indicated ongage 182, and into thechamber 110, as indicated ongage 102,inlet check valve 194 has allowed 100 psig to reachline 199 toports 117 behind thewafer 105, as indicated ongage 192. The holding load on thewafer 105 would then be 300 psi−100 psi, or 200 psi.Exit check valve 174 will have allowed 200 psi to flow by, which forces lowpressure check valve 193 to stay closed, as the pressure on line 177 will be greater than that online 199, as indicated ongages -
FIG. 1D shows the filled state of thechamber 110 at maximum or operating pressure.Valve 184 can now be closed.Optional isolation valve 186 can also be closed at this time. When 3,000 psig is present in the fill line 124, as indicated ongage 182, 3,000 psig will also be present in thechamber 110, as indicated ongage 102. At this point, fluid from thechamber 110 will have filled the line 126 and filled past theexit check valve 174 and line 177 to the lowpressure check valve 193 to a pressure of 2,900 psig, as indicated atgage 172. Lowpressure check valve 193 will remain closed, as 2,800 psig will be present inline 199, as indicated ongage 192, which has been filled from line 124 through the 200 psi drop ofinlet check valve 194. This pressure of 2,800 psig is communicated toports 117 behind thewafer 105, so that the total clamping pressure on thewafer 105 is now 3,000 psi−2,800 psi, or 200 psi. This is the same as during the early filling stage when the chamber pressure was at only 300 psig. The value of theinlet check valve 194 regulates the pressure bias across thewafer 105 during chamber fill and filled conditions. -
FIG. 1E shows the state of thesystem 100 during the initial period when thechamber 110 is being vented and the pressure of the fluid therein is being reduced. The venting to half process pressure of 1,500 psig is shown, as indicated ongage 102 andgage 182. For the venting of thechamber 110, vent valve 176 is opened to allow flow through line 126 intoline 122 to depressurize theprocess chamber 110. The line after theexit check valve 174 will be at 100 psi less in pressure than thechamber 110, or 1,400 psig as indicated ongage 172, due to the value chosen for theexit check valve 174. The lowpressure check valve 193 will hold back that line pressure plus the differential pressure value determined by its spring or setting, which, in the example shown, is 10 psi. Therefore, the pressure in theline 199 and in theports 117 behind thewafer 105 is 1,400 psi+10 psi, or 1,410 psi, as indicated ongage 192. The holding load on the wafer is 1,500 psi−1,410 psi, or 90 psi. This value can be changed by changing the value of the spring ofexit check valve 174, or by changing the rating on the lowpressure check valve 193. Note that theinlet check valve 194 will not allow fluid to fill into theline 199 behind the wafer, because the pressure drop between line 124 andline 199 is less than the value of the 200 psi spring setting ofinlet check valve 194. -
FIG. 1F shows thesystem 100 nearly completely depressurized. Only the residual pressure in thechamber 110 and fill line 124 remains at a level equal to the spring value setting ofexit check valve valve 184 can have been closed. At 100 psig inchamber 110, no more fluid will flow out ofexhaust port 108 ascheck valve 174 will close. Atmospheric pressure, or about 0 psig, can be indicated ongage 172. At this time, thevalve 195 can start to open to evacuate the line to the backside of thewafer 105 and to keep some wafer holding pressure differential on thewafer 105 to hold thewafer 105 to theplaten 116. Openingvalve 195 when the chamber is at 100 psig, as indicated ongage 102, keeps the wafer holding pressure initially at 100 psi−10 psi, or still 90 psi, due to the setting ofcheck valve 193. This holding pressure can be increased by vacuum applied to the backside of the wafer (100 psi+11 psi=11 psi max) by operatingpump 196. -
FIG. 1G shows thesystem 100 with thechamber 110 in a fully vented state. This is achieved by openingvent valve 178 to bypassexit check valve 174 and allowing the pressure in thechamber 110 to drop to atmospheric pressure with the fluid flowing from thechamber 110 to line 126. Thevacuum pump 196 remains on during this final evacuation so that the backside pressure, as indicated ongage 192, remains negative relative to that of thechamber 110, as indicated ongage 102. The backside pressure will, for example, have decreased to −11 psig. The optionalchamber isolation valve 186, if provided, may or may not be open. If closed, it can trap the final 100 psig in the line 124; if open or absent, the line 124 will have bled down to atmospheric pressure along with thechamber 110. The wafer holding pressure will now be just the difference between atmospheric pressure and the level of vacuum produced by thevacuum pump 196. In this example, the holding pressure differential is 11 psi. -
FIG. 1H shows the status of thesystem 100 during wafer removal. Due to the high polish on thewafer 105 and the wafer holding surface of theplaten 116, awafer 105 might tend to stick to the surface of theplaten 116 and be difficult to lift off. A gentle flow of gas from theports 117 in theplaten 116 may be used to break the vacuum seal and allow thewafer 105 to be lifted off the surface of theplaten 116 by lift pins or other mechanisms (not shown). For this, thevacuum pump 196 is turned off and a blow off valve,valve 198 is opened, withvalve 195 remaining open. This provides a path applying gas, such as nitrogen or another gas compatible with the process, to flow from a supply at low pressure, for example 2 psig, to theports 117 at the backside of thewafer 105. - It is anticipated that the process implementing the pressure sequences described above for wafer backside pressure control can be attained by complex electronic pressure regulation with hardware/software interfaces. Use of the hardware features described above, however, provides advantages by eliminating drawbacks of an electronic system, which include the cost, which can easily be 10 times higher, the time and effort required for setup and calibration, as well as the reliability issues with electronic components and software, which may make such components impractical to implement such a system.
- While the mechanical embodiments described above include primarily vacuum chucking systems that apply the processing fluid itself behind the wafer on the platen, the processing fluid can instead be used as a pilot or control fluid that operates one or more pilot controlled fluid valves to communicate another fluid, for example an inert gas, behind the wafer.
- Further, the
processing chamber 110 can alternatively be configured as described in pending U.S. patent application Ser. No. 09/912,844 (U.S. Patent Application Publication No. 2002/0046707 A1), entitled “High pressure processing chamber for semiconductor substrates”, filed on Jul. 24, 2001, which is incorporated herein by reference in its entirety. - Pressure biased wafer holding of a semiconductor wafer has been described above for use in high pressure processing while preventing the adverse effects of high pressure biases. Controller controlled pressure to the backside of the supported substrate can be used to confine the pressure gradient that holds a wafer to the platen to a specified range between a maximum and minimum clamping pressure. A valve arrangement that reduces or limits the holding load on a wafer, as described in the illustrated embodiments, is particularly advantageous. Check valves and on-off valves, connected to input and output lines to the chamber, bias fluid applied to a wafer supporting platen to vary the backside pressure so that the excess of frontside pressure versus backside pressure on the wafer is kept within an effective clamping range without excessive force being applied across the wafer. Use of fluid-mechanical techniques is maximized in certain described embodiments to provide particular reliability and other advantages over electronic control systems.
- While the illustrated embodiments include valves located in fluid flow lines outside of the processing chamber, many of the advantages of a fluid mechanical system can be provided by substituting fluid flow paths in the platen itself or otherwise in the chamber that provide for attenuated flow of fluid from the chamber to behind substrate on the platen so as to develop a clamping pressure gradient within the desired pressure range.
- Although only certain exemplary embodiments of this invention have been described in detail above, those skilled in the art will readily appreciate that many modifications are possible in the exemplary embodiments without materially departing from the novel teachings and advantages of this invention. Accordingly, all such modifications are intended to be included within the scope of this invention.
Claims (20)
1. A processing system for treating a substrate comprising:
a processing chamber configured to treat said substrate therein with a high pressure fluid;
a platen coupled to said processing chamber and configured to support said substrate;
a fluid supply system;
a fluid flow system coupled to said fluid supply system and said chamber and configured to flow said fluid through said processing chamber over said substrate;
a chuck coupled to said platen and configured to hold said substrate against said platen by a pressure gradient between said high pressure fluid and said platen; and
said chuck including means responsive to the pressure of said fluid in said chamber for limiting the magnitude of said pressure gradient.
2. The processing system of claim 1 , wherein said means for limiting includes means for limiting said pressure gradient to less than the pressure difference between the pressure of said fluid in said chamber and atmosphere.
3. The processing system of claim 1 , wherein said means for limiting includes means for increasing the pressure of fluid between the substrate and the platen in accordance with increases of the pressure of fluid in the chamber.
4. The processing system of claim 1 , wherein said means for limiting includes one or more pressure regulated check valves connected between ports to the backside of the platen to processing fluid inlet or outlet ports of the chamber.
5. The processing system of claim 4 , wherein said one or more check valves have bias pressure settings corresponding to the magnitude of said pressure gradient.
6. The processing system of claim 4 , further comprising controller operated on-off valves having open and closed positions and coupled to said check valves and said chamber.
7. The processing system of claim 1 , wherein a temperature of said high pressure fluid ranges from approximately 31 degrees C. to 350 degrees C.
8. The processing system of claim 1 , wherein a pressure of said high pressure fluid ranges from approximately 1,070 psi to approximately 10,000 psi.
9. The processing system of claim 1 , wherein said supercritical fluid includes supercritical carbon dioxide (CO2).
10. The processing system of claim 1 , wherein said means includes a valve connected to the inlet of the chamber to regulate the pressure to a limited gradient below the chamber pressure during fill and filled conditions.
11. A vacuum chuck assembly for a high pressure fluid processing system for processing a substrate in a chamber, the assembly comprising:
a platen having a wafer supporting surface and configured to support said substrate on said surface for high pressure fluid processing;
one or more fluid channels in said platen coupled to said wafer supporting surface;
a clamping fluid control system including a clamping fluid line, a first pressure-limiting valve, a second pressure-limiting valve and a third pressure-limiting valve;
said clamping fluid line being:
coupled to said channels,
coupled to the outlet of a first pressure-limiting valve that is operable to maintain the pressure in said clamping fluid line to not less than a first maximum pressure gradient less than the pressure in said chamber, and
coupled to the inlet of a second pressure-limiting valve that is operable to maintain the pressure in said clamping fluid line to not more than a second maximum pressure gradient more than the pressure to an exhaust line that is coupled to said chamber; and
said third pressure-limiting valve:
having an inlet coupled to said chamber,
having an outlet coupled to said exhaust line, and
being operable to maintain the pressure in said exhaust line at a pressure that is not less than a third maximum pressure gradient less than the pressure in said chamber, said third maximum pressure gradient being greater than said second maximum pressure gradient.
12. The vacuum chuck assembly of claim 11 wherein:
said first maximum pressure gradient is greater than the difference between said third maximum pressure gradient and said second maximum pressure gradient.
13. The vacuum chuck assembly of claim 11 wherein:
said first maximum pressure gradient is not more than a maximum clamping pressure by which said chuck holds said substrate against said platen.
14. The vacuum chuck assembly of claim 11 wherein:
said third maximum pressure gradient is less than said second maximum pressure gradient by at least a minimum clamping pressure by which said chuck holds said substrate against said platen.
15. The vacuum chuck assembly of claim 11 further comprising:
a vacuum pump connected to said clamping fluid line to maintain a minimum clamping pressure by which said chuck holds said substrate against said platen.
16. The vacuum chuck assembly of claim 11 wherein:
said first maximum pressure gradient is greater than the difference between said third maximum pressure gradient and said second maximum pressure gradient;
said first maximum pressure gradient is not more than a maximum clamping pressure by which said chuck holds said substrate against said platen;
said third maximum pressure gradient is less than said second maximum pressure gradient by at least a minimum clamping pressure by which said chuck holds said substrate against said platen; and
said assembly further comprises a vacuum pump connected to said clamping fluid line to maintain said minimum clamping pressure.
17. A method of controlling fluid clamping pressure to the backside of a substrate on a platen of a pressure biased wafer holder in a high pressure processing chamber, the method comprising:
filling the processing chamber with processing fluid to a high processing pressure;
applying a clamping fluid to the backside of a substrate on a platen in said processing chamber at a backside pressure that is responsive to frontside pressure exerted by said fluid on said substrate, such that said backside pressure is less than the frontside pressure by not more than a maximum clamping pressure gradient.
18. The method of claim 17 further comprising:
maintaining said backside pressure at not less than a minimum clamping pressure gradient below said frontside pressure.
19. The method of claim 18 wherein:
said filling includes applying said clamping fluid to said platen from fluid being supplied to said processing chamber through a biased check valve that is set to establish said maximum clamping pressure gradient; and
said maintaining includes removing said fluid from said chamber and said clamping fluid from said platen through one or more biased check valves that are set to establish said minimum clamping pressure gradient.
20. The method of claim 17 wherein:
said filling includes applying said clamping fluid to said platen from fluid being supplied to said processing chamber through a biased check valve that is set to establish said maximum clamping pressure gradient.
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US20150162221A1 (en) * | 2006-08-07 | 2015-06-11 | Hyo-san Lee | Apparatus for treating wafers using supercritical fluid |
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US20150117135A1 (en) * | 2013-10-29 | 2015-04-30 | Taiwan Semiconductor Manufacturing Co., Ltd. | Slurry feed system and method of providing slurry to chemical mechanical planarization station |
US10814455B2 (en) | 2013-10-29 | 2020-10-27 | Taiwan Semiconductor Manufacturing Co., Ltd | Slurry feed system and method of providing slurry to chemical mechanical planarization station |
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Owner name: TOKYO ELECTRON LIMITED, JAPAN Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:SHEYDAYI, ALEXEI;REEL/FRAME:016184/0837 Effective date: 20041222 |
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