US20060201199A1 - Optical element manufacturing method - Google Patents
Optical element manufacturing method Download PDFInfo
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- US20060201199A1 US20060201199A1 US11/374,117 US37411706A US2006201199A1 US 20060201199 A1 US20060201199 A1 US 20060201199A1 US 37411706 A US37411706 A US 37411706A US 2006201199 A1 US2006201199 A1 US 2006201199A1
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- lens elements
- lens
- optical element
- solder connection
- connection metal
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D11/00—Producing optical elements, e.g. lenses or prisms
- B29D11/00009—Production of simple or compound lenses
- B29D11/00365—Production of microlenses
Definitions
- the present invention relates to a method for manufacturing an optical element to be used as a device in a communication apparatus or a computer.
- Microlenses and micro-optical elements constituted with diffractive optical elements are used as optical components in optical disk player devices for playing CDs or the like and optical communication devices.
- Such diffractive optical elements assume a cylindrical shape or a semicylindrical shape and are manufactured by repeating a cycle made up of a photolithography process and an etching step a few times (see, for instance, Electronics Mounting Journal Vol. 5 No. 5 (2002) p.p. 466-472).
- the size of these microlenses and micro optical elements is in the range of 100 ⁇ m to several hundred ⁇ m ⁇ 100 ⁇ m to several hundred ⁇ m.
- the microlenses are manufactured by using a standard silicon wafer or an SOI (silicon-on-insulator) wafer often used in LSI production.
- SOI silicon-on-insulator
- the rear surface of the substrate is polished or in the case of an SOI wafer, the oxide film layer is removed through etching. Once the rear surface is removed, the aggregate is separated into bars of lenses detached from each other at a substantially middle area between the individual lenses. They are then used as microlenses (see, for instance, Japanese Laid Open Patent Publication No. 2003-161811).
- the lens elements When mounting such lens elements on a V-shaped groove in a silicon substrate (hereafter referred to as a silicon V-shaped groove substrate), the lens elements each need to be fixed onto the silicon V-shaped groove substrate with an adhesive or with solder. While it is necessary to deposit a metal having an affinity with solder at the lens side surface if the lens element is to be soldered onto the substrate, it is an extremely time consuming to form a metal film at one lens at a time, through vacuum deposition or the like at the lens side surfaces ranging over an extremely small area of approximately several hundred ⁇ m and, in reality, formation of such small metal areas at the lens side surface is not a viable proposition. In addition, while the lens elements are normally mounted on the silicon V-shaped groove substrate by using a flip chip bonder or the like, there is a great deal of interest in methods through which the lens element can be mounted with better accuracy at lower mounting cost.
- An object of the present invention which has been completed by addressing the problems of the related art discussed above, is to provide a new and improved optical element manufacturing method through which lens elements can be efficiently mounted onto a silicon V-shaped substrate while lowering the manufacturing costs.
- the present invention achieves the object described above by providing an optical element manufacturing method comprising a lens element forming step in which a first silicon oxide film is formed on a first silicon substrate and lens elements are formed at an upper surface of the first silicon oxide film, a coating step in which a solder connection metal film is coated onto side surfaces of the lens elements and a separating step in which the lens elements are separated by removing the first silicon oxide film.
- a solder connection metal film can easily be formed at the sidewall of each lens element.
- the lens element With the solder connection metal film formed at the sidewall of the lens element, the lens element can now be mounted onto a substrate through soldering. Namely, when fixing the lens element at the supporting substrate, it can be firmly set onto the supporting substrate through soldering with ease.
- the lens element forming step may include a step for forming a second silicon substrate on the first silicon oxide film, a step for forming lens portions at an upper surface of the second silicon substrate and a step for forming the lens elements by etching the second silicon substrate. By executing these steps, the lens elements (microlens array) can be formed with ease on the first silicon substrate.
- a step for forming a second silicon oxide film at upper surfaces of the lens element may be executed between the lens element forming step and the coating step and, in such a case, the first silicon oxide film and the second silicon oxide film should be removed through the separating step.
- the second silicon oxide film By forming the second silicon oxide film at the upper surface of the lens elements, i.e., at the surface where the lens portions are formed, it is ensured that the solder connection metal does not become adhered onto the lens portions. Then, as described above, the second silicon oxide film can be removed together with the first silicon oxide film through the separating step.
- the solder connection metal may be a metal that is not corroded by hydrofluoric acid. Such a solder connection metal will not be adversely affected even if hydrofluoric acid is used during the separating step.
- the coating step may be executed by adopting any of various methods including those described below.
- the solder connection metal may be applied through vapor deposition.
- the solder connection metal can be coated only onto a specific surface (side wall) of each lens element through vapor deposition such as ion coating.
- the solder connection metal deposited through vapor deposition may be, for instance, a metal material constituted of, for instance, Cu (0.2 ⁇ m)/Ni (0.1 ⁇ m) and Ni 80 Cr 20 (0.2 ⁇ m)/Ni (0.1 ⁇ m) (claim 6 ).
- the metal material constituted of Cu (0.2 ⁇ m)/Ni (0.1 ⁇ m) and Ni 80 Cr 20 (0.2 ⁇ m)/Ni (0.1 ⁇ m) demonstrates a sufficiently high level of resistance to a hydrofluoric acid solution (HF solution) and also assures a sufficient level of solder bonding strength.
- the coating step may be executed by electrolessly plating the solder connection metal.
- electroless plating a metal film can be formed evenly over the entire side wall and thus, even if the side walls of the lens elements having been formed are set next to each other, the solder connection metal can be formed at the side walls of the individual lens elements as long as the side walls are formed at a distance large enough to allow full penetration of the plating solution.
- lens elements can be formed at the silicon substrate at high density.
- the solder connection metal to be electrolessly plated may be a metal material constituted of Cu (0.5 ⁇ m)/Ni (0.1 ⁇ m).
- the metal material constituted of Cu (0.5 ⁇ m)/Ni (0.1 ⁇ m) demonstrates a sufficiently high level of resistance to a hydrofluoric acid solution (HF solution) and also assures a sufficiently high level of solder bonding strength.
- the coating step may be executed by electrolytically plating the solder connection metal.
- the solder connection metal can be formed evenly only over an area where an electrical current flows. This means that the extent to which the lens elements are affected by the presence of the solder connection metal is minimized.
- the solder connection metal can be formed at the sidewalls of the individual lens elements as long as the sidewalls are formed at a distance large enough to allow full penetration of the plating solution.
- lens elements can be formed at the silicon substrate at high density.
- the solder connection metal to be electrolytically plated may be a metal material constituted of Cu (0.5 ⁇ m)/Ni (0.2 ⁇ m).
- the metal material constituted of Cu (0.5 ⁇ m)/Ni (0.2 ⁇ m) demonstrates a sufficiently high level of resistance to a hydrofluoric acid solution (HF solution) and also assures a sufficiently high level of solder bonding strength.
- the method may further include a step for forming at a supporting substrate fixing grooves at which lens elements are to be fixed, a step for forming solder at the fixing grooves and a lens element fixing step for fixing the lens element at the fixing grooves.
- fix portions assuming a shape matching the shape of the fixing grooves may be formed at the lens elements during the lens element forming step.
- the lens elements formed through these steps can be mounted with ease at the supporting substrate via the solder.
- the fixing grooves may adopt any shape as long as its shape matches the shape of the fix portions at the lens elements, and it may assume, for instance, a recessed shape.
- the lens elements and the fixing grooves at the supporting substrate may be immersed in a solution so as to let the fix portions of the lens elements be fixed (otherwise referred to as “positioned”, “fitted”, “set” or “mounted”) at the fixing grooves through in-solution self alignment.
- a great number of lens elements can be fixed onto the supporting substrate all at once.
- the fix portions at each lens element may be formed asymmetrically relative to the center of the lens element.
- Such asymmetrical fix portions make it possible to accurately set and fix lenses in a batch by ensuring that the lens elements are not erroneously positioned back to front.
- the fix portions being asymmetrical relative to the center of the lens element assume shapes different from each other when viewed from the front or the rear of the lens element and such asymmetrical fix portions may be achieved by forming the left-side fix portion and the right-side fix portion of the lens element with different shapes by forming the left and right fix portions at unmatched positions or by forming a fix portion only on the left side or the right side.
- FIG. 1 illustrates the optical element manufacturing method achieved in a first embodiment
- FIG. 2 illustrates the optical element manufacturing method achieved in the First embodiment
- FIG. 3 shows a lens element
- FIG. 4 illustrates the optical element manufacturing method achieved in a second embodiment
- FIG. 5 illustrates the optical element manufacturing method achieved in the second embodiment
- FIG. 6 illustrates the optical element manufacturing method achieved in a third embodiment
- FIG. 7 shows the lens element with fix portions formed thereat.
- FIG. 8 illustrates a substrate with a V-shaped groove.
- the first embodiment of the optical element manufacturing method according to the present invention is explained.
- a specific method through which a metal film is formed at the side wall of each lens element is explained. It is to be noted that to facilitate the explanation, the thicknesses of the substrates, the layers or the films in the figures are exaggerated and that they do not necessarily match the actual thicknesses.
- an oxide layer 104 constituted with a silicon oxide film is formed on a supporting layer 102 constituted with a silicon substrate.
- the oxide layer 104 is used in a subsequent step as an etch stopper.
- a device-forming layer 106 constituted with a silicon substrate (an SOI substrate) is formed atop the oxide layer 104 .
- Lens elements are formed by using the device-forming layer 106 in a subsequent step.
- the device-forming layer 106 is formed so as to achieve a thickness substantially equal to the thickness of the lens elements along the optical axis to be ultimately achieved through the steps to be explained later.
- n ⁇ m lens portions 106 a are formed over regular intervals at the upper surface of the device-forming layer 106 . It is to be noted that only three lens portions 106 a are shown in the figure for purposes of simplifying the illustration.
- the lens portions 106 a can each be formed as a fresnel lens assuming a staged shape.
- a fresnel lens can be formed by alternately executing a photolithography step and an etching step several times.
- the lens elements are processed so as to achieve a specific external shape.
- a resist applied onto the device forming layer 106 through photolithography is patterned so as to match the lens element shape to be achieved and the resist pattern is transferred onto the device forming layer 106 by using the resist as a dry etching mask, thereby forming lens elements 120 with the external shape shown in FIG. 1 ( b ).
- the dry etching process may be executed by adopting the RIE method or the ICP-Bosch method (silicon deep-etching process).
- the device-forming layer 106 that is patterned through this process is constituted with an SOI substrate, and it is etched as far down as to the oxide layer 104 through, for instance, the ICP-Bosch method.
- a microlens array (only three lens elements 120 are shown in FIG. 1 ( b )) is formed on the supporting layer 102 , as shown in FIG. 1 ( b ).
- FIG. 2 ( a ) is a sectional view taken along A-A in FIG. 1 ( b ).
- TEOS tetraethoxysilane
- Such an oxide layer 108 may instead be formed as a silicon oxide film with a thickness of approximately 0.2 ⁇ m through sputtering, and the subsequent process is executed in exactly the same way in conjunction with the oxide layer formed through sputtering.
- solder metal film 110 is vapor-deposited through ion plating in a batch at the sidewalls of the plurality of lens elements 120 .
- the solder connection metal film 110 used in the embodiment adopts a two-layer structure detailed below.
- FIG. 3 illustrates the structure of a lens element 120 achieved in the embodiment.
- the lens element 120 has a thickness of approximately 100 ⁇ m.
- the solder connection metal film 110 is formed.
- the solder connection metal film 110 can be formed with ease at the sidewalls of the lens elements 120 by adopting the embodiment.
- the lens elements 120 with the solder connection metal film formed at the side walls thereof can be bonded through soldering. Namely, when fixing the lens elements 120 onto the supporting substrate, the lens elements can be firmly set on the supporting substrate via the solder.
- the solder connection metal film 110 needs to be constituted of a material that demonstrates a sufficiently high level of resistance to the hydrofluoric acid solution (HF solution) used when separating the individual lens elements 120 through the step shown in FIG. 2 ( c ) and also enables solder bonding.
- HF solution hydrofluoric acid solution
- lens elements 120 can be formed on the supporting layer 102 at high density. Namely, as shown in FIG. 4 ( a ), lens portions 106 a can be formed at the upper surface of the device forming layer 106 with smaller intervals compared to the intervals between the lens portions 106 in the first embodiment (see FIG. 1 ( a )). Then, as shown in FIG. 4 ( b ), lens elements 120 are formed so as to achieve a specific external shape through a method similar to that adopted in the first embodiment. The intervals between lens elements 120 formed next to each other are set so as to allow full penetration of the plating solution used for electroless plating.
- FIG. 5 ( a ) is a sectional view taken along B-B in FIG. 4 ( b ).
- An oxide layer 108 which is to be used to prevent any metal (solder connection metal) from becoming adhered to the lens portions 106 a during subsequent steps, is formed over a thickness of approximately 1 ⁇ m through the CVD method at the top surface of each lens element 120 .
- solder metal film 110 is formed through electroless plating in a batch at the sidewalls of the lens elements 120 .
- the solder connection metal film 110 used in the embodiment is constituted of the following metal material.
- the oxide layers 104 and 108 are removed from the silicon substrate by using a hydrofluoric acid solution (HF solution) and thus, the individual lens elements (microlenses) 120 are formed as shown in FIG. 5 ( c ).
- HF solution hydrofluoric acid solution
- the lens elements 120 with the solder connection metal film 110 formed at the sidewalls thereof in the embodiment can be bonded through soldering as in the first embodiment.
- the solder connection metal film 110 is constituted of a material that demonstrates a sufficiently high level of resistance to the hydrofluoric acid solution (HF solution) used when separating the individual lens elements 120 through the step shown in FIG. 5 ( c ) and the results of the solder bonding test we conducted indicate that the solder connection metal film 110 assures a sufficiently high level of bonding strength for reliable solder connection.
- HF solution hydrofluoric acid solution
- the embodiment in which the solder connection metal film 110 is formed through electroless plating is advantageous in that, the metal film can be formed evenly over the entire side walls and that, as shown in FIG. 4 ( b ), the solder connection metal film 110 can be formed at the side walls of lens elements 120 formed in close proximity to each other as long as the side walls are set over intervals that allow full penetration of the plating solution. Consequently, the lens elements 120 can be formed at the supporting layer 102 at high density.
- the supporting layer 102 in FIG. 5 ( a ) used in the embodiment needs to have electrically conductive characteristics so as to enable electrolytic plating.
- the device-forming layer 106 is constituted with a 0.1 ⁇ cm substrate in the embodiment.
- lens elements 120 can be formed with high density on the supporting layer 102 in the embodiment. Namely, as shown in FIG. 4 ( a ), lens portions 106 a can be formed at the upper surface of the device forming layer 106 with smaller intervals compared to the intervals between the lens portions 106 a in the first embodiment (see FIG. 1 ( a )). Then, as shown in FIG. 4 ( b ), lens elements 120 are formed so as to achieve a specific external shape through a method similar to that adopted in the first embodiment. The intervals between lens elements 120 formed next to each other are set so as to allow full penetration of the plating solution used for the electrolytic plating.
- FIG. 6 ( a ) is a sectional view taken along B-B in FIG. 4 ( b ).
- An oxide layer 108 which is to be used to prevent any metal (solder connection metal) from becoming adhered to the lens portions 106 a during subsequent steps, is formed over a thickness all of approximately 1 ⁇ m through the CVD method at the top surface of each lens element 120 .
- solder metal film 110 is formed through electroless plating in a batch at the sidewalls of the lens elements 120 . Since the sidewalls of the lens elements 120 in the embodiment are electrically conductive, the solder connection metal film 110 is formed only at the sidewalls of the lens elements, as shown in FIG. 6 ( c ).
- the solder connection metal film 110 used in the embodiment is constituted of the following metal material.
- the oxide layers 104 and 108 are removed from the silicon substrate by using a hydrofluoric acid solution (HF solution) and thus, the individual lens elements (microlenses) 120 are formed as shown in FIG. 6 ( c ).
- HF solution hydrofluoric acid solution
- the lens elements 120 with the solder connection metal film 110 formed at the sidewalls thereof in the embodiment can be bonded through soldering as in the first embodiment.
- the solder connection metal film 110 is constituted of a material that demonstrates a sufficiently high level of resistance to the hydrofluoric acid solution (HF solution) used when separating the individual lens elements 120 through the step shown in FIG. 6 ( c ), and the results of the solder bonding test we conducted indicate that the solder connection metal film 110 assures a sufficiently high level of bonding strength for reliable solder connection.
- HF solution hydrofluoric acid solution
- the embodiment in which the solder connection metal film 110 can be formed evenly only over the areas where a current flows as shown in FIG. 6 ( b ), achieves advantages in that the extent to which the lens elements 120 are affected by the presence of the solder connection metal film 110 is minimized and in that, as shown in FIG. 4 ( b ), the solder connection metal film 110 can be formed at the side walls of lens elements 120 formed in close proximity to each other as long as the side walls are set over intervals that allow penetration of the plating solution. Consequently, the lens elements 120 can be formed at the supporting layer 102 with high density.
- lens elements manufactured through a method adopted in any of the first through third embodiments are mounted on to a supporting substrate having a V-shaped groove formed thereupon (hereafter referred to as a V-shaped groove substrate) through post processing steps following the procedure executed as explained in reference to the first through third embodiments.
- lens elements are mounted in a batch at the V-shaped groove substrate which is an uncut 4-inch silicon wafer.
- FIG. 7 illustrates a lens element 220 to be mounted at the supporting substrate in the embodiment.
- the lens element 220 achieved in the embodiment includes fix portions 220 a and 220 b used to mount the lens element at a V-shaped groove substrate 300 in a post-processing step.
- the fix portions 220 a and 220 b assume shapes that make the lens element left/right asymmetrical, as shown in FIG. 7 .
- the fix portions 220 a and 220 b can be formed to assume such shapes during the step shown in FIG. 1 ( b ) for forming the lens element 120 to achieve a specific external shape by forming a specific pattern at the resist and executing the subsequent steps, as has been explained in reference to any of the first through third embodiments.
- solder connection metal film 110 is formed at the sidewall of the lens element 220 , as has been explained in reference to the first through third embodiments.
- a Cu (0.2 ⁇ m)/Ni (0.1 ⁇ m) film will have been formed.
- FIG. 8 illustrates the V-shaped groove substrate 300 at which the lens element 220 is to be mounted.
- a V-shaped groove 310 at which the lens portion of the lens element 220 is to be mounted and fixing grooves 320 a and 320 b at which the fix portions 220 a and 220 b of the lens element 220 are to be fitted are formed.
- the fixing grooves 320 a and 320 b at the V-shaped groove substrate 300 assume shapes that make them asymmetrical, so as to match the shapes of the fix portions 220 a and 220 b at the lens element 220 .
- Solder is formed through vacuum deposition at the fixing grooves 320 a and 320 b .
- solder constituted of a material containing Sn 95.5 Ag 4.0 Cu 0.5 may be formed through vacuum deposition at the fixing grooves 320 a and 320 b of the V-shaped groove substrate 300 .
- Lens elements 220 (e.g., approximately 2000 lens elements) having been separated from one another are scattered into ethanol (e.g., approximately 100 mL).
- This solution containing the lens elements 220 is poured onto the V-shaped groove substrate 300 in a tilted state (e.g., with an angle of inclination of approximately 20°).
- the solution circulates (e.g., for approximately 10 minutes) while the solution, together with the lens elements 220 in it flows continuously.
- the lens elements 220 can be disposed, each on a V-shaped groove 310 and the corresponding fixing grooves 320 a and 320 b at the V-shaped groove substrate 300 . Since the fixing grooves 320 a and 320 b at the V-shaped groove substrate 300 and the fix portions 220 a and 220 b of the lens elements 220 are formed to be left/right asymmetrical, the lens elements 220 can each be set accurately by preventing erroneous back-to-front placement of the lens elements 220 .
- the V-shaped groove substrate 300 with the lens elements 220 thus mounted is then held in a heating furnace sustaining a specific temperature over a predetermined length of time (e.g., 3 minutes in a heating furnace sustained at 275° C.). After the substrate is taken out of the furnace and allowed to cool down, it can be checked to ensure that the lens elements 220 have become firmly fixed. After the lens elements 220 have become completely fixed, the V-shaped groove substrate 300 is cut at specific positions, thereby completing the process of manufacturing an optical element module at which the lens elements 220 are mounted.
- fix portions 220 a and 220 b at the lens elements 220 as well as the fixing grooves 320 a and 320 b at the V-shaped groove substrate 300 , assume shapes which make them asymmetrical, achieves an advantage in that lens elements 220 can be disposed and fixed in a batch with accuracy through the in-solution self alignment effect by preventing an erroneous back-to-front placement of the individual lens elements.
- lens portions 106 a are each formed as a fresnel lens, assuming a staged shape in the embodiments described above, micro optical elements of different types including refractive optical elements may be formed through the LSI process.
- solder connection metal film 110 adopts a two-layer structure in an embodiment described earlier, the solder connection metal film may adopt a multiple layer structure with three or more metal layers or a single metal layer structure, as long as the metal film achieves a sufficiently high level of resistance to hydrofluoric acid processing.
- a silicon substrate is used as the base substrate when forming the microlens array in the embodiments, a substrate such as a GaAs substrate may be used instead, as long as it is optically transparent and is in a communication wavelength band.
- the lens elements are each connected to the lens supporting substrate at two positions along the horizontal direction, it may instead be mounted on a single side, i.e., at a single position, so as to allow easy distinction between the front side and the rear side of the lens element.
- the solder connection metal film can be formed with ease at the sidewalls of the lens elements by adopting the present invention.
- the lens elements with the solder connection metal film formed at the side walls thereof can be bonded through soldering. Namely, when fixing the lens elements onto the supporting substrate, the lens elements can be firmly set on the supporting substrate via the solder.
- the present invention may be adopted in a method for manufacturing optical elements to be used in communication devices or computers.
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Abstract
Description
- The disclosures of Japanese Patent Application No. JP 2005-71488, filed Mar. 14, 2005, entitled “Optical Element Manufacturing Method”. The contents of that application are herein incorporated by reference in their entirety.
- The present invention relates to a method for manufacturing an optical element to be used as a device in a communication apparatus or a computer.
- Microlenses and micro-optical elements constituted with diffractive optical elements are used as optical components in optical disk player devices for playing CDs or the like and optical communication devices. Such diffractive optical elements assume a cylindrical shape or a semicylindrical shape and are manufactured by repeating a cycle made up of a photolithography process and an etching step a few times (see, for instance, Electronics Mounting Journal Vol. 5 No. 5 (2002) p.p. 466-472). The size of these microlenses and micro optical elements is in the range of 100 μm to several hundred μm×100 μm to several hundred μm.
- The microlenses are manufactured by using a standard silicon wafer or an SOI (silicon-on-insulator) wafer often used in LSI production. Before the aggregate substrate is separated into individual lenses, the rear surface of the substrate is polished or in the case of an SOI wafer, the oxide film layer is removed through etching. Once the rear surface is removed, the aggregate is separated into bars of lenses detached from each other at a substantially middle area between the individual lenses. They are then used as microlenses (see, for instance, Japanese Laid Open Patent Publication No. 2003-161811).
- When mounting such lens elements on a V-shaped groove in a silicon substrate (hereafter referred to as a silicon V-shaped groove substrate), the lens elements each need to be fixed onto the silicon V-shaped groove substrate with an adhesive or with solder. While it is necessary to deposit a metal having an affinity with solder at the lens side surface if the lens element is to be soldered onto the substrate, it is an extremely time consuming to form a metal film at one lens at a time, through vacuum deposition or the like at the lens side surfaces ranging over an extremely small area of approximately several hundred μm and, in reality, formation of such small metal areas at the lens side surface is not a viable proposition. In addition, while the lens elements are normally mounted on the silicon V-shaped groove substrate by using a flip chip bonder or the like, there is a great deal of interest in methods through which the lens element can be mounted with better accuracy at lower mounting cost.
- An object of the present invention, which has been completed by addressing the problems of the related art discussed above, is to provide a new and improved optical element manufacturing method through which lens elements can be efficiently mounted onto a silicon V-shaped substrate while lowering the manufacturing costs.
- The present invention achieves the object described above by providing an optical element manufacturing method comprising a lens element forming step in which a first silicon oxide film is formed on a first silicon substrate and lens elements are formed at an upper surface of the first silicon oxide film, a coating step in which a solder connection metal film is coated onto side surfaces of the lens elements and a separating step in which the lens elements are separated by removing the first silicon oxide film.
- Through this manufacturing method, a solder connection metal film can easily be formed at the sidewall of each lens element. With the solder connection metal film formed at the sidewall of the lens element, the lens element can now be mounted onto a substrate through soldering. Namely, when fixing the lens element at the supporting substrate, it can be firmly set onto the supporting substrate through soldering with ease.
- The lens element forming step may include a step for forming a second silicon substrate on the first silicon oxide film, a step for forming lens portions at an upper surface of the second silicon substrate and a step for forming the lens elements by etching the second silicon substrate. By executing these steps, the lens elements (microlens array) can be formed with ease on the first silicon substrate.
- A step for forming a second silicon oxide film at upper surfaces of the lens element may be executed between the lens element forming step and the coating step and, in such a case, the first silicon oxide film and the second silicon oxide film should be removed through the separating step. By forming the second silicon oxide film at the upper surface of the lens elements, i.e., at the surface where the lens portions are formed, it is ensured that the solder connection metal does not become adhered onto the lens portions. Then, as described above, the second silicon oxide film can be removed together with the first silicon oxide film through the separating step.
- The solder connection metal may be a metal that is not corroded by hydrofluoric acid. Such a solder connection metal will not be adversely affected even if hydrofluoric acid is used during the separating step.
- The coating step may be executed by adopting any of various methods including those described below. In a first method, the solder connection metal may be applied through vapor deposition. In other words, the solder connection metal can be coated only onto a specific surface (side wall) of each lens element through vapor deposition such as ion coating.
- The solder connection metal deposited through vapor deposition may be, for instance, a metal material constituted of, for instance, Cu (0.2 μm)/Ni (0.1 μm) and Ni 80 Cr 20 (0.2 μm)/Ni (0.1 μm) (claim 6). The metal material constituted of Cu (0.2 μm)/Ni (0.1 μm) and Ni 80 Cr 20 (0.2 μm)/Ni (0.1 μm) demonstrates a sufficiently high level of resistance to a hydrofluoric acid solution (HF solution) and also assures a sufficient level of solder bonding strength.
- As a second method, the coating step may be executed by electrolessly plating the solder connection metal. Through electroless plating, a metal film can be formed evenly over the entire side wall and thus, even if the side walls of the lens elements having been formed are set next to each other, the solder connection metal can be formed at the side walls of the individual lens elements as long as the side walls are formed at a distance large enough to allow full penetration of the plating solution. Thus, lens elements can be formed at the silicon substrate at high density.
- The solder connection metal to be electrolessly plated may be a metal material constituted of Cu (0.5 μm)/Ni (0.1 μm). The metal material constituted of Cu (0.5 μm)/Ni (0.1 μm) demonstrates a sufficiently high level of resistance to a hydrofluoric acid solution (HF solution) and also assures a sufficiently high level of solder bonding strength.
- As a third method, the coating step may be executed by electrolytically plating the solder connection metal. Through electrolytic plating, the solder connection metal can be formed evenly only over an area where an electrical current flows. This means that the extent to which the lens elements are affected by the presence of the solder connection metal is minimized. In addition, even if the sidewalls of the lens elements having been formed are set next to each other, the solder connection metal can be formed at the sidewalls of the individual lens elements as long as the sidewalls are formed at a distance large enough to allow full penetration of the plating solution. Thus, lens elements can be formed at the silicon substrate at high density.
- The solder connection metal to be electrolytically plated may be a metal material constituted of Cu (0.5 μm)/Ni (0.2 μm). The metal material constituted of Cu (0.5 μm)/Ni (0.2 μm) demonstrates a sufficiently high level of resistance to a hydrofluoric acid solution (HF solution) and also assures a sufficiently high level of solder bonding strength.
- The method may further include a step for forming at a supporting substrate fixing grooves at which lens elements are to be fixed, a step for forming solder at the fixing grooves and a lens element fixing step for fixing the lens element at the fixing grooves. In this case, fix portions assuming a shape matching the shape of the fixing grooves may be formed at the lens elements during the lens element forming step. The lens elements formed through these steps can be mounted with ease at the supporting substrate via the solder. It is to be noted that the fixing grooves may adopt any shape as long as its shape matches the shape of the fix portions at the lens elements, and it may assume, for instance, a recessed shape.
- During the lens element fixing step, the lens elements and the fixing grooves at the supporting substrate may be immersed in a solution so as to let the fix portions of the lens elements be fixed (otherwise referred to as “positioned”, “fitted”, “set” or “mounted”) at the fixing grooves through in-solution self alignment. In this case, a great number of lens elements can be fixed onto the supporting substrate all at once.
- The fix portions at each lens element may be formed asymmetrically relative to the center of the lens element. Such asymmetrical fix portions make it possible to accurately set and fix lenses in a batch by ensuring that the lens elements are not erroneously positioned back to front. It is to be noted that the fix portions being asymmetrical relative to the center of the lens element assume shapes different from each other when viewed from the front or the rear of the lens element and such asymmetrical fix portions may be achieved by forming the left-side fix portion and the right-side fix portion of the lens element with different shapes by forming the left and right fix portions at unmatched positions or by forming a fix portion only on the left side or the right side.
-
FIG. 1 illustrates the optical element manufacturing method achieved in a first embodiment; -
FIG. 2 illustrates the optical element manufacturing method achieved in the First embodiment; -
FIG. 3 shows a lens element; -
FIG. 4 illustrates the optical element manufacturing method achieved in a second embodiment; -
FIG. 5 illustrates the optical element manufacturing method achieved in the second embodiment; -
FIG. 6 illustrates the optical element manufacturing method achieved in a third embodiment; -
FIG. 7 shows the lens element with fix portions formed thereat; and -
FIG. 8 illustrates a substrate with a V-shaped groove. - The following is a detailed explanation of the preferred embodiments of the optical element manufacturing method according to the present invention. It is to be noted that in the specification and the drawings, the same reference numerals are assigned to components having functions and structural features substantially identical to one another to preclude the necessity for a repeated explanation thereof.
- In reference to
FIGS. 1 through 3 , the first embodiment of the optical element manufacturing method according to the present invention is explained. In reference to the embodiment, a specific method through which a metal film is formed at the side wall of each lens element (microlens) is explained. It is to be noted that to facilitate the explanation, the thicknesses of the substrates, the layers or the films in the figures are exaggerated and that they do not necessarily match the actual thicknesses. - First, as shown in
FIG. 1 (a), anoxide layer 104 constituted with a silicon oxide film is formed on a supportinglayer 102 constituted with a silicon substrate. Theoxide layer 104 is used in a subsequent step as an etch stopper. Then, a device-forminglayer 106 constituted with a silicon substrate (an SOI substrate) is formed atop theoxide layer 104. Lens elements are formed by using the device-forminglayer 106 in a subsequent step. The device-forminglayer 106 is formed so as to achieve a thickness substantially equal to the thickness of the lens elements along the optical axis to be ultimately achieved through the steps to be explained later. - In addition, n×m
lens portions 106 a are formed over regular intervals at the upper surface of the device-forminglayer 106. It is to be noted that only threelens portions 106 a are shown in the figure for purposes of simplifying the illustration. Thelens portions 106 a can each be formed as a fresnel lens assuming a staged shape. A fresnel lens can be formed by alternately executing a photolithography step and an etching step several times. - Next, the lens elements are processed so as to achieve a specific external shape. A resist applied onto the
device forming layer 106 through photolithography is patterned so as to match the lens element shape to be achieved and the resist pattern is transferred onto thedevice forming layer 106 by using the resist as a dry etching mask, thereby forminglens elements 120 with the external shape shown inFIG. 1 (b). The dry etching process may be executed by adopting the RIE method or the ICP-Bosch method (silicon deep-etching process). The device-forminglayer 106 that is patterned through this process is constituted with an SOI substrate, and it is etched as far down as to theoxide layer 104 through, for instance, the ICP-Bosch method. - Through the steps described above, a microlens array (only three
lens elements 120 are shown inFIG. 1 (b)) is formed on the supportinglayer 102, as shown inFIG. 1 (b). -
FIG. 2 (a) is a sectional view taken along A-A inFIG. 1 (b). Anoxide layer 108 constituted with a silicon oxide film, which is to be used to prevent any metal (solder connection metal) from becoming adhered to thelens portions 106 a during subsequent steps, is formed over a thickness of approximately 1 μm through the CVD method by using tetraethoxysilane (TEOS) at the top surface of eachlens element 120. It is to be noted that such anoxide layer 108 may instead be formed as a silicon oxide film with a thickness of approximately 0.2 μm through sputtering, and the subsequent process is executed in exactly the same way in conjunction with the oxide layer formed through sputtering. - As shown in
FIG. 2 (b), asolder metal film 110 is vapor-deposited through ion plating in a batch at the sidewalls of the plurality oflens elements 120. The solderconnection metal film 110 used in the embodiment adopts a two-layer structure detailed below. - (1) Cu (0.2 μm)/Ni (0.1 μm)
- (2) Ni 80 Cr 20 (0.2 μm)/Ni (0.1 μm)
- Next, the oxide layers 104 and 108 are removed from the silicon substrate by using a hydrofluoric acid solution (HF solution) and thus, the individual lens elements (microlenses) 120 are formed as shown in
FIG. 2 (c).FIG. 3 illustrates the structure of alens element 120 achieved in the embodiment. Thelens element 120 has a thickness of approximately 100 μm. At a sidewall of thelens element 120, the solderconnection metal film 110 is formed. - As explained above, the solder
connection metal film 110 can be formed with ease at the sidewalls of thelens elements 120 by adopting the embodiment. Thelens elements 120 with the solder connection metal film formed at the side walls thereof can be bonded through soldering. Namely, when fixing thelens elements 120 onto the supporting substrate, the lens elements can be firmly set on the supporting substrate via the solder. - The solder
connection metal film 110 needs to be constituted of a material that demonstrates a sufficiently high level of resistance to the hydrofluoric acid solution (HF solution) used when separating theindividual lens elements 120 through the step shown inFIG. 2 (c) and also enables solder bonding. The results of the solder bonding test we conducted indicate that the solderconnection metal film 110 assures a sufficiently high level of bonding strength for reliable solder connection. - An explanation is given in reference to the second embodiment on a method for forming a solder connection metal film at the sidewalls of lens elements through electroless plating.
- By adopting this embodiment,
lens elements 120 can be formed on the supportinglayer 102 at high density. Namely, as shown inFIG. 4 (a),lens portions 106 a can be formed at the upper surface of thedevice forming layer 106 with smaller intervals compared to the intervals between thelens portions 106 in the first embodiment (seeFIG. 1 (a)). Then, as shown inFIG. 4 (b),lens elements 120 are formed so as to achieve a specific external shape through a method similar to that adopted in the first embodiment. The intervals betweenlens elements 120 formed next to each other are set so as to allow full penetration of the plating solution used for electroless plating. -
FIG. 5 (a) is a sectional view taken along B-B inFIG. 4 (b). Anoxide layer 108, which is to be used to prevent any metal (solder connection metal) from becoming adhered to thelens portions 106 a during subsequent steps, is formed over a thickness of approximately 1 μm through the CVD method at the top surface of eachlens element 120. - As shown in
FIG. 2 (b), asolder metal film 110 is formed through electroless plating in a batch at the sidewalls of thelens elements 120. The solderconnection metal film 110 used in the embodiment is constituted of the following metal material. - (1) Cu (0.5 μm)/Ni (0.1 μm)
- Next, the oxide layers 104 and 108 are removed from the silicon substrate by using a hydrofluoric acid solution (HF solution) and thus, the individual lens elements (microlenses) 120 are formed as shown in
FIG. 5 (c). - As explained above, the
lens elements 120 with the solderconnection metal film 110 formed at the sidewalls thereof in the embodiment can be bonded through soldering as in the first embodiment. The solderconnection metal film 110 is constituted of a material that demonstrates a sufficiently high level of resistance to the hydrofluoric acid solution (HF solution) used when separating theindividual lens elements 120 through the step shown inFIG. 5 (c) and the results of the solder bonding test we conducted indicate that the solderconnection metal film 110 assures a sufficiently high level of bonding strength for reliable solder connection. - In addition, the embodiment in which the solder
connection metal film 110 is formed through electroless plating is advantageous in that, the metal film can be formed evenly over the entire side walls and that, as shown inFIG. 4 (b), the solderconnection metal film 110 can be formed at the side walls oflens elements 120 formed in close proximity to each other as long as the side walls are set over intervals that allow full penetration of the plating solution. Consequently, thelens elements 120 can be formed at the supportinglayer 102 at high density. - An explanation is given in reference to the third embodiment on a method for forming a solder connection metal film at the sidewalls of lens elements through electrolytic plating.
- The supporting
layer 102 inFIG. 5 (a) used in the embodiment needs to have electrically conductive characteristics so as to enable electrolytic plating. The device-forminglayer 106 is constituted with a 0.1 Ω·cm substrate in the embodiment. - In addition, as in the second embodiment,
lens elements 120 can be formed with high density on the supportinglayer 102 in the embodiment. Namely, as shown inFIG. 4 (a),lens portions 106 a can be formed at the upper surface of thedevice forming layer 106 with smaller intervals compared to the intervals between thelens portions 106 a in the first embodiment (seeFIG. 1 (a)). Then, as shown inFIG. 4 (b),lens elements 120 are formed so as to achieve a specific external shape through a method similar to that adopted in the first embodiment. The intervals betweenlens elements 120 formed next to each other are set so as to allow full penetration of the plating solution used for the electrolytic plating. -
FIG. 6 (a) is a sectional view taken along B-B inFIG. 4 (b). Anoxide layer 108, which is to be used to prevent any metal (solder connection metal) from becoming adhered to thelens portions 106 a during subsequent steps, is formed over a thickness all of approximately 1 μm through the CVD method at the top surface of eachlens element 120. - As shown in
FIG. 6 (b), asolder metal film 110 is formed through electroless plating in a batch at the sidewalls of thelens elements 120. Since the sidewalls of thelens elements 120 in the embodiment are electrically conductive, the solderconnection metal film 110 is formed only at the sidewalls of the lens elements, as shown inFIG. 6 (c). The solderconnection metal film 110 used in the embodiment is constituted of the following metal material. - (1) Cu (0.5 μm)/Ni (0.2 μm)
- Next, the oxide layers 104 and 108 are removed from the silicon substrate by using a hydrofluoric acid solution (HF solution) and thus, the individual lens elements (microlenses) 120 are formed as shown in
FIG. 6 (c). - As explained above, the
lens elements 120 with the solderconnection metal film 110 formed at the sidewalls thereof in the embodiment can be bonded through soldering as in the first embodiment. The solderconnection metal film 110 is constituted of a material that demonstrates a sufficiently high level of resistance to the hydrofluoric acid solution (HF solution) used when separating theindividual lens elements 120 through the step shown inFIG. 6 (c), and the results of the solder bonding test we conducted indicate that the solderconnection metal film 110 assures a sufficiently high level of bonding strength for reliable solder connection. - In addition, the embodiment, in which the solder
connection metal film 110 can be formed evenly only over the areas where a current flows as shown inFIG. 6 (b), achieves advantages in that the extent to which thelens elements 120 are affected by the presence of the solderconnection metal film 110 is minimized and in that, as shown inFIG. 4 (b), the solderconnection metal film 110 can be formed at the side walls oflens elements 120 formed in close proximity to each other as long as the side walls are set over intervals that allow penetration of the plating solution. Consequently, thelens elements 120 can be formed at the supportinglayer 102 with high density. - In reference to the fourth embodiment, an explanation is given on a method through which lens elements manufactured through a method adopted in any of the first through third embodiments are mounted on to a supporting substrate having a V-shaped groove formed thereupon (hereafter referred to as a V-shaped groove substrate) through post processing steps following the procedure executed as explained in reference to the first through third embodiments. In the embodiment, lens elements are mounted in a batch at the V-shaped groove substrate which is an uncut 4-inch silicon wafer.
-
FIG. 7 illustrates alens element 220 to be mounted at the supporting substrate in the embodiment. - The
lens element 220 achieved in the embodiment includesfix portions groove substrate 300 in a post-processing step. Thefix portions FIG. 7 . Thefix portions FIG. 1 (b) for forming thelens element 120 to achieve a specific external shape by forming a specific pattern at the resist and executing the subsequent steps, as has been explained in reference to any of the first through third embodiments. - In addition, the solder
connection metal film 110 is formed at the sidewall of thelens element 220, as has been explained in reference to the first through third embodiments. For instance, at the sidewall of thelens element 220 having been formed by adopting the first embodiment, a Cu (0.2 μm)/Ni (0.1 μm) film will have been formed. -
FIG. 8 illustrates the V-shapedgroove substrate 300 at which thelens element 220 is to be mounted. - At the V-shaped
groove substrate 300, a V-shapedgroove 310 at which the lens portion of thelens element 220 is to be mounted and fixinggrooves fix portions lens element 220 are to be fitted are formed. - As shown in
FIG. 8 , the fixinggrooves groove substrate 300 assume shapes that make them asymmetrical, so as to match the shapes of thefix portions lens element 220. Solder is formed through vacuum deposition at the fixinggrooves lens element 220, solder constituted of a material containing Sn 95.5 Ag 4.0 Cu 0.5 may be formed through vacuum deposition at the fixinggrooves groove substrate 300. - Lens elements 220 (e.g., approximately 2000 lens elements) having been separated from one another are scattered into ethanol (e.g., approximately 100 mL). This solution containing the
lens elements 220 is poured onto the V-shapedgroove substrate 300 in a tilted state (e.g., with an angle of inclination of approximately 20°). The solution circulates (e.g., for approximately 10 minutes) while the solution, together with thelens elements 220 in it flows continuously. - Due to the in-solution self-alignment effect, the
lens elements 220 can be disposed, each on a V-shapedgroove 310 and the corresponding fixinggrooves groove substrate 300. Since the fixinggrooves groove substrate 300 and thefix portions lens elements 220 are formed to be left/right asymmetrical, thelens elements 220 can each be set accurately by preventing erroneous back-to-front placement of thelens elements 220. - The V-shaped
groove substrate 300 with thelens elements 220 thus mounted is then held in a heating furnace sustaining a specific temperature over a predetermined length of time (e.g., 3 minutes in a heating furnace sustained at 275° C.). After the substrate is taken out of the furnace and allowed to cool down, it can be checked to ensure that thelens elements 220 have become firmly fixed. After thelens elements 220 have become completely fixed, the V-shapedgroove substrate 300 is cut at specific positions, thereby completing the process of manufacturing an optical element module at which thelens elements 220 are mounted. - The embodiment described above, in which the
fix portions lens elements 220, as well as the fixinggrooves groove substrate 300, assume shapes which make them asymmetrical, achieves an advantage in thatlens elements 220 can be disposed and fixed in a batch with accuracy through the in-solution self alignment effect by preventing an erroneous back-to-front placement of the individual lens elements. - While the invention has been particularly shown and described with respect to preferred embodiments of the optical element manufacturing method according to the present invention by referring to the attached drawings, the present invention is not limited to these examples and it will be understood by those skilled in the art that various changes in form and detail may be made therein without departing from the spirit, scope and teaching of the invention.
- For instance, while the
lens portions 106 a are each formed as a fresnel lens, assuming a staged shape in the embodiments described above, micro optical elements of different types including refractive optical elements may be formed through the LSI process. - While the solder
connection metal film 110 adopts a two-layer structure in an embodiment described earlier, the solder connection metal film may adopt a multiple layer structure with three or more metal layers or a single metal layer structure, as long as the metal film achieves a sufficiently high level of resistance to hydrofluoric acid processing. While a silicon substrate is used as the base substrate when forming the microlens array in the embodiments, a substrate such as a GaAs substrate may be used instead, as long as it is optically transparent and is in a communication wavelength band. - While the lens elements are each connected to the lens supporting substrate at two positions along the horizontal direction, it may instead be mounted on a single side, i.e., at a single position, so as to allow easy distinction between the front side and the rear side of the lens element.
- As explained above, the solder connection metal film can be formed with ease at the sidewalls of the lens elements by adopting the present invention. The lens elements with the solder connection metal film formed at the side walls thereof can be bonded through soldering. Namely, when fixing the lens elements onto the supporting substrate, the lens elements can be firmly set on the supporting substrate via the solder.
- The present invention may be adopted in a method for manufacturing optical elements to be used in communication devices or computers.
Claims (13)
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JP2005071488A JP2006251691A (en) | 2005-03-14 | 2005-03-14 | Manufacturing method of optical element |
JP2005-071488 | 2005-03-14 |
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US3266057A (en) * | 1964-02-24 | 1966-08-16 | Elizabeth H Phelps | Wearing apparel |
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US7585422B2 (en) | 2009-09-08 |
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