US20060258545A1 - Well completion spacer fluids containing fibers - Google Patents

Well completion spacer fluids containing fibers Download PDF

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Publication number
US20060258545A1
US20060258545A1 US11/489,320 US48932006A US2006258545A1 US 20060258545 A1 US20060258545 A1 US 20060258545A1 US 48932006 A US48932006 A US 48932006A US 2006258545 A1 US2006258545 A1 US 2006258545A1
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United States
Prior art keywords
fibers
spacer fluid
fluid
foamed
spacer
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Abandoned
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US11/489,320
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Jiten Chatterji
Dennis Gray
Bobby King
John Dennis
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Individual
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Individual
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Priority claimed from US10/393,965 external-priority patent/US6668927B1/en
Application filed by Individual filed Critical Individual
Priority to US11/489,320 priority Critical patent/US20060258545A1/en
Publication of US20060258545A1 publication Critical patent/US20060258545A1/en
Abandoned legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/60Compositions for stimulating production by acting on the underground formation
    • C09K8/601Compositions for stimulating production by acting on the underground formation using spacer compositions
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/02Well-drilling compositions
    • C09K8/04Aqueous well-drilling compositions
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/40Spacer compositions, e.g. compositions used to separate well-drilling from cementing masses
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/42Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells
    • C09K8/424Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells using "spacer" compositions
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S507/00Earth boring, well treating, and oil field chemistry
    • Y10S507/927Well cleaning fluid
    • Y10S507/928Spacing slug or preflush fluid

Definitions

  • the present invention relates to spacer fluids containing fibers and methods of using the spacer fluids in well completions such as primary cementing.
  • Well bores are commonly drilled using the rotary drilling method.
  • a drill bit connected to a drill string is rotated while drilling fluid is circulated through the drill string, through the drill bit and upwardly to the surface through the annulus between the drill string and the walls of the well bore being drilled.
  • the drilling fluid functions to cool the drill bit, to remove cuttings from the well bore and to maintain hydrostatic pressure on the well bore.
  • the hydrostatic pressure prevents formation fluids from entering the well bore during drilling.
  • the drilling fluid also forms a filter cake on the walls of the well bore which prevents the drilling fluid from being lost into permeable subterranean zones.
  • the drilling fluid in the filter cake dehydrates and gels thereby forming a layer of solids and gelled drilling fluid on the walls of the well bore. While this filter cake is advantageous during drilling, it is detrimental to obtaining effective drilling fluid displacement and removal from the walls of the well bore.
  • a hydraulic cement slurry is pumped into the annular space between the walls of the well bore and the exterior surfaces of a pipe string disposed therein.
  • the cement slurry is allowed to set in the annular space thereby forming an annular sheath of hardened substantially impermeable cement therein.
  • the cement sheath physically supports and positions the pipe in the well bore and bonds the exterior surfaces of the pipe to the walls of the well bore whereby the undesirable migration of fluids between zones or formations penetrated by the well bore is prevented. If the drilling fluid filter cake is not adequately removed from the walls of the well bore or portions thereof, a competent seal between the hardened cement and the well bore does not result.
  • Spacer fluids are typically placed between two fluids contained or to be pumped within well bores.
  • fluids between which spacer fluids are utilized include between hydraulic cement slurries and drilling fluids, between different drilling fluids during drilling fluid changeouts and between drilling fluids and completion brines.
  • the spacers are also utilized to enhance drilling fluid and filter cake removal from the walls of well bores, to enhance displacement efficiency and to physically separate chemically incompatible fluids.
  • a hydraulic cement slurry and drilling fluid are separated by a spacer fluid when the cement slurry is placed in the annulus between a pipe string and the walls of a well bore.
  • the spacer fluid prevents intermixing of the cement slurry and the drilling fluid and facilitates the removal of filter cake and gelled drilling fluid from the walls of the well bore during displacement of the drilling fluid by the cement slurry. If intermixing of the cement slurry and the drilling fluid occurs, viscous masses are formed in the annulus that prevent continued displacement.
  • spacer fluids have achieved varying degrees of success in displacing fluids and removing filter cake, gelled drilling fluid and the like from the walls of the well bore.
  • spacer fluids that achieve greater removal of drilling fluid and filter cake from the walls of the well bore and prevent mixing of incompatible fluids.
  • the present invention provides improved water based well completion spacer fluids containing fibers and methods of using the spacer fluids which meet the need described above and overcome the deficiencies of the prior art.
  • the presence of fibers in the spacer fluids of this invention increases the drilling fluid and filter cake removal from the walls of a well bore as a result of the fibers imparting abrasive properties to the spacer fluids.
  • the spacer fluids are preferably foamed which increases the drilling fluid and filter cake removal. That is, the foamed spacer fluids of this invention exhibit better drilling fluid and drilling fluid filter cake removal as a result of the gas in the foamed spacer fluids energizing the fluids.
  • the gas bubbles are compressed as a foamed spacer fluid is pumped down the pipe string and the hydrostatic pressure increases. As the foamed spacer fluid enters the annulus and is pumped toward the surface, the hydrostatic pressure decreases which allows the gas bubbles to expand and cause the foamed spacer fluid to achieve highly efficient drilling fluid and filter cake removal from the annulus. The expansion of the gas bubbles also allows the foamed spacer fluid and fibers therein to enter irregular hole configurations and enlarged holes in the well bore and remove drilling fluid and filter cake therefrom. Finally, the increased viscosity of a foamed spacer fluid provides enhanced suspension of removed drilling fluid and filter cake.
  • the water-based spacer fluids of this invention are particularly well suited for displacing water-based drilling fluids and other water-based fluids, but they can also be used effectively in the removal of oil based drilling fluids and other oil based fluids.
  • a foamed spacer fluid of this invention contacts an oil based drilling fluid, the foamed spacer fluid will convert to a non-foamed spacer fluid.
  • the released gas enters the filter cake which in conjunction with the fibers in the spacer fluid facilitates the removal of the filter cake.
  • the spacer fluids of this invention basically comprise water, a weighting material, a dispersing agent, a suspending agent and friction reducer, and fibers.
  • the foamed spacer fluids comprise water, a weighting material, a dispersing agent, a suspending agent and friction reducer, fibers, a foaming and foam stabilizing surfactant or mixture of surfactants and a gas.
  • the methods of this invention basically comprise the following steps.
  • a spacer fluid is placed between first and second fluids in a well bore to separate the first and second fluids and to remove the first fluid from the walls of the well bore, the spacer fluid comprising water, a weighting material, a dispersing agent, a suspending agent and friction reducer, and fibers.
  • the first fluid and the spacer fluid are displaced from the well bore by the second fluid.
  • a preferred method of the invention comprises the following steps.
  • a foamed spacer fluid is placed between first and second fluids in a well bore to separate the first and second fluids and to remove the first fluid from the walls of the well bore, the spacer fluid comprising water, a weighting material, a dispersing agent, a suspending agent and friction reducer, fibers, a foaming and foam stabilizing surfactant or mixtures of surfactants and a gas.
  • the first fluid and the spacer fluid are displaced from the well bore by the second fluid.
  • FIG. 1 is a diagram of the spacer fluid efficiency test apparatus used in the examples outlined in the Description of Preferred Embodiments, with the results listed in Table I.
  • the spacer fluids of this invention basically comprise water, a weighting material, a dispersing agent, a suspending agent and friction reducer, and fibers.
  • a more preferred foamed spacer fluid comprises water, a weighting material, a dispersing agent, a suspending agent and friction reducer, fibers, a foaming and foam stabilizing surfactant or mixtures of surfactants and a gas.
  • the water in the spacer fluids of this invention can be fresh water or salt water.
  • salt water is used herein to mean unsaturated salt solutions and saturated salt solutions including brines and seawater.
  • weighting materials that can be utilized in the spacer fluids include, but are not limited to, barium sulfate, hematite, manganese tetraoxide and calcium carbonate. Of these, barium sulfate is preferred.
  • the weighting material is included in the spacer fluids in an amount in the range of from about 0 pounds to about 745 pounds per barrel of water therein.
  • the dispersing agent is included in the spacer fluids to disperse the solids and other materials in the water.
  • dispersing agents include, but are not limited to, naphthalene sulfonate condensed with formaldehyde, sodium polyacrylate, a terpolymer of acrylic acid, alkyloxybenzene sulfonate and methally sulfonate, formaldehyde, acetone, bisulfite condensate, melamine sulfonate formaldehyde condensate, and mixtures thereof.
  • the dispersing agent is included in the spacer fluid in an amount in the range of from about 0.5% to about 5% by weight of the water therein.
  • the suspending agent and friction reducer is included in the spacer fluid to suspend the weighting material and other solids therein as well as to reduce friction during pumping of the spacer fluid.
  • suspending agent and friction reducers include, but are not limited to, sepiolite, whelan gum, xanthan gum, hydroxyethylcellulose, bentonite, attapulgite, and mixtures thereof. Of these, xanthan gum is preferred.
  • the suspending agent and friction reducer is included in the spacer fluid in an amount in the range of from about 2 pounds to about 10 pounds per barrel of water therein.
  • fibers can be utilized in the present invention.
  • preferred such fibers include, but are not limited to, polyester fibers, polyamide fibers, polyethylene fibers, polypropylene fibers, and other polyolefin fibers.
  • the fibers can be made hydrophilic by treating them with a surface active agent. Of the foregoing, hydrophilic polypropylene fibers are most preferred.
  • the fibers are included in the spacer fluid in an amount in the range of from about 1/16 pound to about 1 ⁇ 4 pound per barrel of spacer fluid.
  • a foaming and foam stabilizing surfactant that functions to facilitate the formation of a foam and to stabilize the foam during its use is included in the spacer fluid.
  • surfactants include, but are not limited to, a mixture of an ethoxylated alcohol ether sulfate surfactant, an alkyl or alkene amidopropyl betaine surfactant and an alkyl or alkene amidopropyl dimethyl amine oxide surfactant or a mixture of an alpha-olefinic sulfonate surfactant and an alkyl or alkene amidopropyl betaine surfactant.
  • the mixture of an ethoxylated alcohol ether sulfate surfactant, an alkyl or alkene amidopropyl betaine surfactant and an alkyl or alkene amidopropyl dimethyl amine oxide surfactant is preferred.
  • This mixture and others are described in detail in U.S. Pat. Nos. 6,063,738; 6,210,476; 5,897,699; 5,875,845; and 5,820,670 issued to Chatterji, et al. which are incorporated herein by reference thereto.
  • the mixture of foaming and foam stabilizing surfactants is included in the foamed spacer fluid in an amount in the range of from about 0.5% to about 5% by weight of the water therein.
  • a gas such as air or nitrogen is included in the spacer fluid.
  • the gas is preferably nitrogen and the gas is present in the foamed spacer fluid in an amount in the range of from about 5% to about 80% by volume of the water therein.
  • the spacer fluids of this invention can also optionally include a well bore scouring material to facilitate the removal of filter cake and gelled drilling fluid from the walls of the well bore.
  • suitable scouring materials include, but are not limited to, diatomaceous earth, crystalline silica, amorphous silica, and mixtures thereof. Of these, crystalline silica scouring material is preferred.
  • the scouring material is present in the spacer fluid in an amount in the range of from about 10 pounds to about 80 pounds per barrel of water therein.
  • the spacer fluid when it is not foamed, it can optionally include a defoamer comprising oil and silica present in an amount in the range of from about 0.5% to about 2% by weight of the water therein.
  • a defoamer comprising oil and silica present in an amount in the range of from about 0.5% to about 2% by weight of the water therein.
  • the spacer fluids of this invention are particularly useful in primary cementing operations wherein the foamed spacer fluid is placed between a drilling fluid and a hydraulic cement slurry.
  • the drilling fluid can be a water-based drilling fluid, an oil based drilling fluid or a foamed water or oil based drilling fluid.
  • the hydraulic cement slurry can include various cements including Portland cements, slag cements, pozzolana cements, gypsum cements, aluminous cements, silica cements or high alkalinity cements. Of these, Portland cement is generally preferred.
  • the water in the hydraulic cement slurry can be fresh water or salt water.
  • a spacer mixing aid is added to the spacer fluid in a small amount to facilitate complete suspension of the heavy weight materials therein.
  • the spacer mixing aid is comprises 39.5% xanthan gum, 48.3% mineral oil, 2.7% oleophilic clay; 5.9% nonylphenol ethoxylated with 3 moles of ethylene oxide, and 3.9% naphthalene sulfonate condensed with formaldehyde (percents are by weight).
  • the spacer mixing aid is not required when the spacer fluid is mixed on-the-fly.
  • a preferred method of this invention for displacing a first fluid from a well bore with an incompatible second fluid comprises the steps of: (a) placing a spacer fluid between the first and second fluids to separate the first and second fluids and to remove the first fluid from the walls of the well bore, the spacer fluid comprising water, a weighting material, a dispersing agent, a suspending agent and friction reducer, and fibers; and (b) displacing the first fluid and the foamed spacer fluid from the well bore with the second fluid.
  • a preferred method of displacing drilling fluid from a well bore with a hydraulic cement slurry comprises the steps of: (a) placing a foamed spacer fluid between the drilling fluid and the hydraulic cement slurry to separate the drilling fluid from the hydraulic cement slurry and to remove the drilling fluid and filter cake from the walls of the well bore, the foamed spacer fluid comprising water, a weighting material, a dispersing agent, a suspending agent and friction reducer, fibers, a foaming and foam stabilizing surfactant and a gas; and (b) displacing the drilling fluid and the foamed spacer fluid from the well bore with the hydraulic cement slurry.
  • a preferred spacer fluid of this invention comprises: water; a weighting material; a dispersing agent; a suspending agent and friction reducer; and fibers.
  • a preferred foamed spacer fluid of this invention comprises: water; a weighting material; a dispersing agent; a suspending agent and friction reducer; fibers; a foaming and foam stabilizing surfactant; and a gas.
  • spacer fluid efficiency test apparatus designed to indicate how efficiently a spacer fluid will erode a filter cake from a formation core.
  • FIG. 1 is a diagram of spacer fluid efficiency test apparatus 10 .
  • Test apparatus 10 consists of reservoir 20 , variable speed pump 30 , test cell 40 containing core 45 with filter cake 50 deposited thereon, and flexible tubing 60 connection the components.
  • a drilling fluid is placed into a standard API high pressure fluid loss apparatus containing a core 45 as the filter medium.
  • filter cake 50 is deposited on core 45 using the fluid loss test apparatus.
  • Core 45 containing deposited filter cake 50 is removed from the fluid loss test apparatus, and the outside of core 45 is rinsed to remove any drilling fluid that is surrounding the core 45 .
  • the filter cake 50 is rinsed by pouring water over it gently. The weight of core 45 and filter cake 50 is the determined.
  • core 45 with filter cake 50 is mounted on test cell 40 shown in test apparatus 10 in FIG. 1 .
  • Spacer 25 to be tested is poured into reservoir 20 .
  • Pump speed controller 35 is adjusted to allow pump 30 to move spacer 25 through flexible tubing 60 and across filter cake 50 at a rate of 3.3 liters per minute.
  • the inlet and outlets for the flow of spacer 25 through test cell 40 is level with the top of core 45 .
  • the circulation of spacer 25 is continued for 40 minutes, and at the end of the 40 minutes, the circulation is stopped.
  • test cell 40 is disassembled by removing the bottom end holding core 45 with filter cake 50 on it.
  • the sides of core 45 are rinsed using the same procedure as at the start of the rest.
  • the top of filter cake 50 is rinsed by gently pouring water over it to remove loose spacer, the same as was done to remove loose drilling fluid at the beginning of the test.
  • the weight of core 45 and filter cake 50 is then determined. Filter cake 50 is then removed from core 45 and the weight of core 45 (without filter cake 50 ) is determined.
  • a first spacer fluid (Spacer 1 ) having a density of 16 pounds per gallon was prepared comprising water; 39.23% by weight of water of diatomaceous earth scouring material; 35.0% by weight of water of crystalline sand scouring material; 11.76% by weight of water of sepiolite suspending agent and friction reducer; 9.8% by weight of water of naphthalene sulfonate condensed with formaldehyde dispersing agent; 1.96% by weight of water of an oil and silica defoaming agent; and 1 gallon of spacer mixing aid blend per 10 barrels of mixing water.
  • 1 ⁇ 8 pound of hydrophilic polypropylene fibers per barrel of spacer fluid was added.
  • the spacer mixing aid blend is included in the spacer when it is batch mixed.
  • a 16 pound per gallon spacer fluid (Spacer 1 ) having the same composition as the first spacer fluid described above without the fibers was prepared and foamed with 2% by weight of a surfactant mixture comprising an ethoxylated alcohol either sulfate, an alkyl or alkene amidopropyl betaine and an alkyl or alkene amidopropyl dimethyl amine oxide to 10, 12 and 14 pound per gallon foamed spacer fluids.
  • 10, 12 and 14 pound per gallon foamed spacer fluids with hydrophilic polypropylene fibers were also prepared.
  • a second spacer fluid (Spacer 2 ) having a density of 16 pounds per gallon was prepared comprising water; 6.0% by weight of water of sodium polyacrylate dispersing agent; 3.75% by weight of water of a terpolymer of acrylic acid, alkoxybenzene sulfonate and methally sulfonate dispersing agent; 1.5% by weight of water of whelan gum suspending agent and friction reducer; 0.5% by weight of water of hydroxyethylcelluclose suspending agent and friction reducer; 22.5% by weight of water of sepiolite suspending agent and friction reducer; 66.0% by weight of water of amorphous silica.
  • To the second spacer fluid 1 ⁇ 8 pound of hydrophilic polypropylene fibers per barrel was added.
  • a 16 pound per gallon spacer fluid (Spacer 2 ) having the same composition as the second spacer fluid described above without the fibers was prepared and foamed with the same surfactant mixture described above to 10, 12 and 14 pound per gallon foamed spacer fluids. 10, 12 and 14 pound per gallon foamed spacer fluids with hydrophilic polypropylene fibers were also prepared.

Abstract

Well completion spacer fluids containing fibers and methods of using the spacer fluids are provided. A method of the invention for displacing a first fluid from a well bore with an incompatible second fluid comprises the following steps. A spacer fluid is placed between the first and second fluids to separate the first and second fluids and to remove the first fluid from the walls of the well bore. Thereafter, the first fluid and the spacer fluid are displaced from the well bore with the second fluid. The spacer fluid comprises water, a weighting material, a dispersing agent, a suspending agent and friction reducer and fibers. The spacer fluid containing the components mentioned above is preferably also foamed.

Description

    CROSS REFERENCE TO RELATED APPLICATIONS
  • This application is a divisional of U.S. application Ser. No. 10/740,189, filed Dec. 18, 2003, which is a continuation-in-part of U.S. application Ser. No. 10/393,965, now U.S. Pat. No. 5,668,927, filed on Mar. 21, 2003, the disclosures of which are hereby incorporated by reference.
  • BACKGROUND OF THE INVENTION
  • 1. Field of the Invention
  • The present invention relates to spacer fluids containing fibers and methods of using the spacer fluids in well completions such as primary cementing.
  • 2. Description of the Prior Art
  • Well bores are commonly drilled using the rotary drilling method. In that method, a drill bit connected to a drill string is rotated while drilling fluid is circulated through the drill string, through the drill bit and upwardly to the surface through the annulus between the drill string and the walls of the well bore being drilled. The drilling fluid functions to cool the drill bit, to remove cuttings from the well bore and to maintain hydrostatic pressure on the well bore. The hydrostatic pressure prevents formation fluids from entering the well bore during drilling.
  • The drilling fluid also forms a filter cake on the walls of the well bore which prevents the drilling fluid from being lost into permeable subterranean zones. However, the drilling fluid in the filter cake dehydrates and gels thereby forming a layer of solids and gelled drilling fluid on the walls of the well bore. While this filter cake is advantageous during drilling, it is detrimental to obtaining effective drilling fluid displacement and removal from the walls of the well bore.
  • In primary well cementing operations, a hydraulic cement slurry is pumped into the annular space between the walls of the well bore and the exterior surfaces of a pipe string disposed therein. The cement slurry is allowed to set in the annular space thereby forming an annular sheath of hardened substantially impermeable cement therein. The cement sheath physically supports and positions the pipe in the well bore and bonds the exterior surfaces of the pipe to the walls of the well bore whereby the undesirable migration of fluids between zones or formations penetrated by the well bore is prevented. If the drilling fluid filter cake is not adequately removed from the walls of the well bore or portions thereof, a competent seal between the hardened cement and the well bore does not result.
  • Spacer fluids are typically placed between two fluids contained or to be pumped within well bores. Examples of fluids between which spacer fluids are utilized include between hydraulic cement slurries and drilling fluids, between different drilling fluids during drilling fluid changeouts and between drilling fluids and completion brines. The spacers are also utilized to enhance drilling fluid and filter cake removal from the walls of well bores, to enhance displacement efficiency and to physically separate chemically incompatible fluids. For example, a hydraulic cement slurry and drilling fluid are separated by a spacer fluid when the cement slurry is placed in the annulus between a pipe string and the walls of a well bore. The spacer fluid prevents intermixing of the cement slurry and the drilling fluid and facilitates the removal of filter cake and gelled drilling fluid from the walls of the well bore during displacement of the drilling fluid by the cement slurry. If intermixing of the cement slurry and the drilling fluid occurs, viscous masses are formed in the annulus that prevent continued displacement.
  • The heretofore utilized spacer fluids have achieved varying degrees of success in displacing fluids and removing filter cake, gelled drilling fluid and the like from the walls of the well bore. However, there is a continuing need for improved spacer fluids that achieve greater removal of drilling fluid and filter cake from the walls of the well bore and prevent mixing of incompatible fluids.
  • SUMMARY OF THE INVENTION
  • The present invention provides improved water based well completion spacer fluids containing fibers and methods of using the spacer fluids which meet the need described above and overcome the deficiencies of the prior art. The presence of fibers in the spacer fluids of this invention increases the drilling fluid and filter cake removal from the walls of a well bore as a result of the fibers imparting abrasive properties to the spacer fluids. In addition, the spacer fluids are preferably foamed which increases the drilling fluid and filter cake removal. That is, the foamed spacer fluids of this invention exhibit better drilling fluid and drilling fluid filter cake removal as a result of the gas in the foamed spacer fluids energizing the fluids. The gas bubbles are compressed as a foamed spacer fluid is pumped down the pipe string and the hydrostatic pressure increases. As the foamed spacer fluid enters the annulus and is pumped toward the surface, the hydrostatic pressure decreases which allows the gas bubbles to expand and cause the foamed spacer fluid to achieve highly efficient drilling fluid and filter cake removal from the annulus. The expansion of the gas bubbles also allows the foamed spacer fluid and fibers therein to enter irregular hole configurations and enlarged holes in the well bore and remove drilling fluid and filter cake therefrom. Finally, the increased viscosity of a foamed spacer fluid provides enhanced suspension of removed drilling fluid and filter cake. The water-based spacer fluids of this invention are particularly well suited for displacing water-based drilling fluids and other water-based fluids, but they can also be used effectively in the removal of oil based drilling fluids and other oil based fluids. When a foamed spacer fluid of this invention contacts an oil based drilling fluid, the foamed spacer fluid will convert to a non-foamed spacer fluid. However, it is believed that the released gas enters the filter cake which in conjunction with the fibers in the spacer fluid facilitates the removal of the filter cake.
  • The spacer fluids of this invention basically comprise water, a weighting material, a dispersing agent, a suspending agent and friction reducer, and fibers. The foamed spacer fluids comprise water, a weighting material, a dispersing agent, a suspending agent and friction reducer, fibers, a foaming and foam stabilizing surfactant or mixture of surfactants and a gas.
  • The methods of this invention basically comprise the following steps. A spacer fluid is placed between first and second fluids in a well bore to separate the first and second fluids and to remove the first fluid from the walls of the well bore, the spacer fluid comprising water, a weighting material, a dispersing agent, a suspending agent and friction reducer, and fibers. Thereafter, the first fluid and the spacer fluid are displaced from the well bore by the second fluid.
  • A preferred method of the invention comprises the following steps. A foamed spacer fluid is placed between first and second fluids in a well bore to separate the first and second fluids and to remove the first fluid from the walls of the well bore, the spacer fluid comprising water, a weighting material, a dispersing agent, a suspending agent and friction reducer, fibers, a foaming and foam stabilizing surfactant or mixtures of surfactants and a gas. Thereafter, the first fluid and the spacer fluid are displaced from the well bore by the second fluid.
  • The objects, features and advantages of the present invention will be readily apparent to those skilled in the art upon a reading of the description of preferred embodiments which follows.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • A more complete understanding of the present disclosure and advantages thereof may be acquired by referring to the following description taken in conjunction with the accompanying drawings:
  • FIG. 1 is a diagram of the spacer fluid efficiency test apparatus used in the examples outlined in the Description of Preferred Embodiments, with the results listed in Table I.
  • DESCRIPTION OF PREFERRED EMBODIMENTS
  • As stated above, the spacer fluids of this invention basically comprise water, a weighting material, a dispersing agent, a suspending agent and friction reducer, and fibers. A more preferred foamed spacer fluid comprises water, a weighting material, a dispersing agent, a suspending agent and friction reducer, fibers, a foaming and foam stabilizing surfactant or mixtures of surfactants and a gas.
  • The water in the spacer fluids of this invention can be fresh water or salt water. The term “salt water” is used herein to mean unsaturated salt solutions and saturated salt solutions including brines and seawater.
  • Examples of weighting materials that can be utilized in the spacer fluids include, but are not limited to, barium sulfate, hematite, manganese tetraoxide and calcium carbonate. Of these, barium sulfate is preferred. The weighting material is included in the spacer fluids in an amount in the range of from about 0 pounds to about 745 pounds per barrel of water therein.
  • The dispersing agent is included in the spacer fluids to disperse the solids and other materials in the water. Examples of dispersing agents that can be utilized include, but are not limited to, naphthalene sulfonate condensed with formaldehyde, sodium polyacrylate, a terpolymer of acrylic acid, alkyloxybenzene sulfonate and methally sulfonate, formaldehyde, acetone, bisulfite condensate, melamine sulfonate formaldehyde condensate, and mixtures thereof. The dispersing agent is included in the spacer fluid in an amount in the range of from about 0.5% to about 5% by weight of the water therein.
  • The suspending agent and friction reducer is included in the spacer fluid to suspend the weighting material and other solids therein as well as to reduce friction during pumping of the spacer fluid. Examples of suspending agent and friction reducers that can be utilized include, but are not limited to, sepiolite, whelan gum, xanthan gum, hydroxyethylcellulose, bentonite, attapulgite, and mixtures thereof. Of these, xanthan gum is preferred. The suspending agent and friction reducer is included in the spacer fluid in an amount in the range of from about 2 pounds to about 10 pounds per barrel of water therein.
  • A variety of fibers can be utilized in the present invention. Examples of preferred such fibers include, but are not limited to, polyester fibers, polyamide fibers, polyethylene fibers, polypropylene fibers, and other polyolefin fibers. The fibers can be made hydrophilic by treating them with a surface active agent. Of the foregoing, hydrophilic polypropylene fibers are most preferred. The fibers are included in the spacer fluid in an amount in the range of from about 1/16 pound to about ¼ pound per barrel of spacer fluid.
  • When the spacer fluid is a foamed spacer fluid, a foaming and foam stabilizing surfactant that functions to facilitate the formation of a foam and to stabilize the foam during its use is included in the spacer fluid. While various such surfactants known to those skilled in the art can be used, presently preferred such surfactants include, but are not limited to, a mixture of an ethoxylated alcohol ether sulfate surfactant, an alkyl or alkene amidopropyl betaine surfactant and an alkyl or alkene amidopropyl dimethyl amine oxide surfactant or a mixture of an alpha-olefinic sulfonate surfactant and an alkyl or alkene amidopropyl betaine surfactant. Of these, the mixture of an ethoxylated alcohol ether sulfate surfactant, an alkyl or alkene amidopropyl betaine surfactant and an alkyl or alkene amidopropyl dimethyl amine oxide surfactant is preferred. This mixture and others are described in detail in U.S. Pat. Nos. 6,063,738; 6,210,476; 5,897,699; 5,875,845; and 5,820,670 issued to Chatterji, et al. which are incorporated herein by reference thereto. The mixture of foaming and foam stabilizing surfactants is included in the foamed spacer fluid in an amount in the range of from about 0.5% to about 5% by weight of the water therein.
  • Also, when the spacer fluid is foamed, a gas such as air or nitrogen is included in the spacer fluid. The gas is preferably nitrogen and the gas is present in the foamed spacer fluid in an amount in the range of from about 5% to about 80% by volume of the water therein.
  • The spacer fluids of this invention can also optionally include a well bore scouring material to facilitate the removal of filter cake and gelled drilling fluid from the walls of the well bore. Examples of suitable scouring materials include, but are not limited to, diatomaceous earth, crystalline silica, amorphous silica, and mixtures thereof. Of these, crystalline silica scouring material is preferred. When used, the scouring material is present in the spacer fluid in an amount in the range of from about 10 pounds to about 80 pounds per barrel of water therein.
  • Also, when the spacer fluid is not foamed, it can optionally include a defoamer comprising oil and silica present in an amount in the range of from about 0.5% to about 2% by weight of the water therein.
  • As mentioned above, the spacer fluids of this invention are particularly useful in primary cementing operations wherein the foamed spacer fluid is placed between a drilling fluid and a hydraulic cement slurry. The drilling fluid can be a water-based drilling fluid, an oil based drilling fluid or a foamed water or oil based drilling fluid.
  • The hydraulic cement slurry can include various cements including Portland cements, slag cements, pozzolana cements, gypsum cements, aluminous cements, silica cements or high alkalinity cements. Of these, Portland cement is generally preferred. The water in the hydraulic cement slurry can be fresh water or salt water.
  • When the spacer fluid of this invention is batch mixed on the surface, a spacer mixing aid is added to the spacer fluid in a small amount to facilitate complete suspension of the heavy weight materials therein. The spacer mixing aid is comprises 39.5% xanthan gum, 48.3% mineral oil, 2.7% oleophilic clay; 5.9% nonylphenol ethoxylated with 3 moles of ethylene oxide, and 3.9% naphthalene sulfonate condensed with formaldehyde (percents are by weight). The spacer mixing aid is not required when the spacer fluid is mixed on-the-fly.
  • A preferred method of this invention for displacing a first fluid from a well bore with an incompatible second fluid comprises the steps of: (a) placing a spacer fluid between the first and second fluids to separate the first and second fluids and to remove the first fluid from the walls of the well bore, the spacer fluid comprising water, a weighting material, a dispersing agent, a suspending agent and friction reducer, and fibers; and (b) displacing the first fluid and the foamed spacer fluid from the well bore with the second fluid.
  • A preferred method of displacing drilling fluid from a well bore with a hydraulic cement slurry comprises the steps of: (a) placing a foamed spacer fluid between the drilling fluid and the hydraulic cement slurry to separate the drilling fluid from the hydraulic cement slurry and to remove the drilling fluid and filter cake from the walls of the well bore, the foamed spacer fluid comprising water, a weighting material, a dispersing agent, a suspending agent and friction reducer, fibers, a foaming and foam stabilizing surfactant and a gas; and (b) displacing the drilling fluid and the foamed spacer fluid from the well bore with the hydraulic cement slurry.
  • A preferred spacer fluid of this invention comprises: water; a weighting material; a dispersing agent; a suspending agent and friction reducer; and fibers.
  • A preferred foamed spacer fluid of this invention comprises: water; a weighting material; a dispersing agent; a suspending agent and friction reducer; fibers; a foaming and foam stabilizing surfactant; and a gas.
  • In order to further illustrate the methods and foamed spacer fluids of this invention, the following examples are given.
  • EXAMPLE 1
  • Various spacer fluids were tested using a spacer fluid efficiency test apparatus designed to indicate how efficiently a spacer fluid will erode a filter cake from a formation core. A diagram of the test apparatus and the test procedure followed is set forth below.
  • FIG. 1 is a diagram of spacer fluid efficiency test apparatus 10. Test apparatus 10 consists of reservoir 20, variable speed pump 30, test cell 40 containing core 45 with filter cake 50 deposited thereon, and flexible tubing 60 connection the components.
  • A drilling fluid is placed into a standard API high pressure fluid loss apparatus containing a core 45 as the filter medium. Next, filter cake 50 is deposited on core 45 using the fluid loss test apparatus. Core 45 containing deposited filter cake 50 is removed from the fluid loss test apparatus, and the outside of core 45 is rinsed to remove any drilling fluid that is surrounding the core 45. The filter cake 50 is rinsed by pouring water over it gently. The weight of core 45 and filter cake 50 is the determined. Thereafter, core 45 with filter cake 50 is mounted on test cell 40 shown in test apparatus 10 in FIG. 1.
  • Spacer 25 to be tested is poured into reservoir 20. Pump speed controller 35 is adjusted to allow pump 30 to move spacer 25 through flexible tubing 60 and across filter cake 50 at a rate of 3.3 liters per minute. The inlet and outlets for the flow of spacer 25 through test cell 40 is level with the top of core 45. The circulation of spacer 25 is continued for 40 minutes, and at the end of the 40 minutes, the circulation is stopped.
  • Thereafter, test cell 40 is disassembled by removing the bottom end holding core 45 with filter cake 50 on it. The sides of core 45 are rinsed using the same procedure as at the start of the rest. The top of filter cake 50 is rinsed by gently pouring water over it to remove loose spacer, the same as was done to remove loose drilling fluid at the beginning of the test. The weight of core 45 and filter cake 50 is then determined. Filter cake 50 is then removed from core 45 and the weight of core 45 (without filter cake 50) is determined.
  • The percent of filter cake 50 removed is then determined by: % Rem = CW B - CW A CW B
    Where % Rem is the percent filter cake removed, CWB is the filter cake weight before exposure to spacer, and CWA is the filter cake weight after exposure to spacer.
  • A first spacer fluid (Spacer 1) having a density of 16 pounds per gallon was prepared comprising water; 39.23% by weight of water of diatomaceous earth scouring material; 35.0% by weight of water of crystalline sand scouring material; 11.76% by weight of water of sepiolite suspending agent and friction reducer; 9.8% by weight of water of naphthalene sulfonate condensed with formaldehyde dispersing agent; 1.96% by weight of water of an oil and silica defoaming agent; and 1 gallon of spacer mixing aid blend per 10 barrels of mixing water. To the first spacer fluid, ⅛ pound of hydrophilic polypropylene fibers per barrel of spacer fluid was added. The spacer mixing aid blend is included in the spacer when it is batch mixed.
  • A 16 pound per gallon spacer fluid (Spacer 1) having the same composition as the first spacer fluid described above without the fibers was prepared and foamed with 2% by weight of a surfactant mixture comprising an ethoxylated alcohol either sulfate, an alkyl or alkene amidopropyl betaine and an alkyl or alkene amidopropyl dimethyl amine oxide to 10, 12 and 14 pound per gallon foamed spacer fluids. 10, 12 and 14 pound per gallon foamed spacer fluids with hydrophilic polypropylene fibers were also prepared.
  • A second spacer fluid (Spacer 2) having a density of 16 pounds per gallon was prepared comprising water; 6.0% by weight of water of sodium polyacrylate dispersing agent; 3.75% by weight of water of a terpolymer of acrylic acid, alkoxybenzene sulfonate and methally sulfonate dispersing agent; 1.5% by weight of water of whelan gum suspending agent and friction reducer; 0.5% by weight of water of hydroxyethylcelluclose suspending agent and friction reducer; 22.5% by weight of water of sepiolite suspending agent and friction reducer; 66.0% by weight of water of amorphous silica. To the second spacer fluid, ⅛ pound of hydrophilic polypropylene fibers per barrel was added.
  • A 16 pound per gallon spacer fluid (Spacer 2) having the same composition as the second spacer fluid described above without the fibers was prepared and foamed with the same surfactant mixture described above to 10, 12 and 14 pound per gallon foamed spacer fluids. 10, 12 and 14 pound per gallon foamed spacer fluids with hydrophilic polypropylene fibers were also prepared.
  • The results of spacer fluid efficiency tests using the test apparatus described above are set forth in Table I below (Spacer 1 and 11 pound per gallon water based drilling fluid to deposit filter cake) and Table II below (Spacer 2 and 12.5 pound per gallon water based drilling fluid to deposit filter cake).
    TABLE I
    Filter Cake Erosion By Spacer 1 Fluids With and Without Fibers
    Weight of
    Drilling Percent of
    Fluid After Filter Cake
    Drilling Fluid Spacer 1 Spacer 1 Removal After
    Filter Cake Fluid Circulation, Spacer 1
    Weight, grams Tested grams Circulation
    24 14 lb/gal 24 0
    (No Fibers)
    22 14 lb/gal 20 10
    (With Fibers)
    19 14 lb/gal 15 21
    (Foamed, No Fibers)
    31 14 lb/gal 27 13
    (Foamed, With Fibers)
    28 12 lb/gal 26 7
    (Foamed, No Fibers)
    24 12 lb/gal 19 21
    (Foamed, With Fibers)
    29 10 lb/gal 27 7
    (Foamed, No Fibers)
    28.5 10 lb/gal 26.2 8
    (Foamed, With Fibers)
  • From Table I, it can be seen that the presence of fibers in the non-foamed and foamed spacer fluids provides greater efficiency in removing drilling fluid.
    TABLE II
    Filter Cake Erosion By Spacer 2 Fluids With and Without Fibers
    Weight of
    Drilling Percent of
    Fluid After Filter Cake
    Drilling Fluid Spacer 2 Spacer 2 Removal After
    Filter Cake Fluid Circulation, Spacer 2
    Weight, grams Tested grams Circulation
    18.5 16 lb/gal 17.7 4
    (No Fibers)
    19.8 16 lb/gal 18.0 9
    (With Fibers)
    12.8 14 lb/gal 12.7 1
    (Foamed, No Fibers)
    15.4 14 lb/gal 13.7 11
    (Foamed, With Fibers)
    16.9 12 lb/gal 14.7 13
    (Foamed, No Fibers)
    15.9 12 lb/gal 13.0 18
    (Foamed, With Fibers)
    23.5 10 lb/gal 20.8 11
    (Foamed, No Fibers)
    19.2 10 lb/gal 16.8 12.5
    (Foamed, With Fibers)
  • From Table II, it can again be seen that the presence of fibers in the non-foamed and foamed spacer fluids provides greater efficiency in removing drilling fluid.

Claims (23)

1. A spacer fluid comprising:
water;
a weighting material;
a dispersing agent;
a suspending agent and friction reducer; and
fibers selected from the group consisting of polyester fibers, polyamide fibers, polyethylene fibers, polypropylene fibers, and other polyolefin fibers.
2. The spacer fluid of claim 1 wherein the weighting material is selected from the group consisting of barium sulfate, hematite, manganese tetraoxide and calcium carbonate.
3. The spacer fluid of claim 1 wherein the dispersing agent is selected from the group consisting of naphthalene sulfonate condensed with formaldehyde, sodium polyacrylate, a terpolymer of acrylic acid, alkyloxybenzene sulfonate and methally sulfonate, formaldehyde, acetone, bisulfite condensate, melamine sulfonate formaldehyde condensate, and mixtures thereof.
4. The spacer fluid of claim 1 wherein the suspending agent and friction reducer is selected from the group consisting of sepiolite, whelan gum, xanthan gum, hydroxyethyl cellulose, bentonite, attapulgite, and mixtures thereof.
5. The spacer fluid of claim 1 wherein the fibers comprise hydrophilic fibers.
6. The spacer fluid of claim 1 wherein the fibers comprise hydrophilic polypropylene fibers.
7. The spacer fluid of claim 1 wherein the spacer fluid further comprises at least one additive selected from the group consisting of a well bore wall scouring material and a defoamer.
8. The spacer fluid of claim 1:
wherein the weighting material comprises barium sulfate;
wherein the dispersing agent comprises naphthalene sulfonate condensed with formaldehyde;
wherein the suspending agent and friction reducer comprises xanthan gum; and
wherein the fibers comprise hydrophilic fibers.
9. The spacer fluid of claim 1 wherein:
the weighting material is present in the spacer fluid in an amount up to about 745 pounds per barrel of the water present in the spacer fluid;
the dispersing agent is present in the spacer fluid in an amount up to about 5% by weight of the water present in the spacer fluid;
the suspending agent and friction reducer is present in the spacer fluid in an amount in the range of from about 2 pounds to about 10 pounds per barrel of the water present in the spacer fluid; and
the fibers are present in the spacer fluid in an amount in the range of from about 1/16 pound to about ¼ pound per barrel of the spacer fluid.
10. A well completion fluid comprising a foamed spacer fluid containing fibers.
11. The well completion fluid of claim 10 wherein the fibers are selected from the group consisting of polyester fibers, polyamide fibers, polyethylene fibers, polypropylene fibers, and other polyolefin fibers.
12. The well completion fluid of claim 10 wherein the fibers comprise hydrophilic fibers.
13. The well completion fluid of claim 10 wherein the fibers comprise hydrophilic polypropylene fibers.
14. The well completion fluid of claim 10 wherein the fibers are present in the foamed spacer fluid in an amount in the range of from about 1/16 pound to about ¼ pound per barrel of the foamed spacer fluid.
15. The well completion fluid of claim 10 wherein the foamed spacer fluid further comprises at least one additive selected from the group consisting of a weighting material, a dispersing agent, a suspending agent and friction reducer, and a well bore wall scouring material.
16. A foamed spacer fluid comprising:
water;
a weighting material;
a dispersing agent;
a suspending agent and friction reducer;
fibers;
a foaming and foam stabilizing surfactant; and
a gas.
17. The foamed spacer fluid of claim 16 wherein the fibers are selected from the group consisting of polyester fibers, polyamide fibers, polyethylene fibers, polypropylene fibers, and other polyolefin fibers.
18. The foamed spacer fluid of claim 16 wherein the fibers comprise hydrophilic fibers.
19. The foamed spacer fluid of claim 16 wherein the fibers comprise hydrophilic polypropylene fibers.
20. The foamed spacer fluid of claim 16 wherein the foamed spacer fluid further comprises a well bore wall scouring material.
21. The foamed spacer fluid of claim 16 wherein the foaming and foam stabilizing surfactant is selected from the group consisting of a mixture of an ethoxylated alcohol ether sulfate surfactant, an alkyl or alkene amidopropyl betaine surfactant and an alkyl or alkene amidopropyl dimethyl amine oxide surfactant, and a mixture of an alpha-olefmic sulfonate surfactant and an alkyl or alkene amidopropyl betaine surfactant.
22. The foamed spacer fluid of claim 16 wherein:
the weighting material comprises barium sulfate;
the dispersing agent comprises naphthalene sulfonate condensed with formaldehyde;
the suspending agent and friction reducer comprises xanthan gum;
the foaming and foam stabilizing surfactant comprises a mixture of an ethoxylated alcohol ether sulfate surfactant, an alkyl or alkene amidopropyl betaine surfactant and an alkyl or alkene amidopropyl dimethyl amine oxide surfactant; and
the fibers comprise hydrophilic fibers.
23. The foamed spacer fluid of claim 16 wherein:
the weighting material is present in the foamed spacer fluid in an amount up to about 745 pounds per barrel of the water present in the foamed spacer fluid;
the dispersing agent is present in the foamed spacer fluid in an amount up to about 5% by weight of the water present in the foamed spacer fluid;
the suspending agent and friction reducer is present in the foamed spacer fluid in an amount in the range of from about 2 pounds to about 10 pounds per barrel of the water present in the foamed spacer fluid; and
the fibers are present in the foamed spacer fluid in an amount in the range of from about 1/16 pound to about ¼ pound per barrel of the foamed spacer fluid.
US11/489,320 2003-03-21 2006-07-19 Well completion spacer fluids containing fibers Abandoned US20060258545A1 (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080168848A1 (en) * 2007-01-11 2008-07-17 Gary Funkhouser Measuring Cement Properties
US20130048285A1 (en) * 2011-08-31 2013-02-28 Stephane Boulard Compositions and Methods for Servicing Subterranean Wells
US8601882B2 (en) 2009-02-20 2013-12-10 Halliburton Energy Sevices, Inc. In situ testing of mechanical properties of cementitious materials
US8783091B2 (en) 2009-10-28 2014-07-22 Halliburton Energy Services, Inc. Cement testing
US8794078B2 (en) 2012-07-05 2014-08-05 Halliburton Energy Services, Inc. Cement testing
US8960013B2 (en) 2012-03-01 2015-02-24 Halliburton Energy Services, Inc. Cement testing
US20160122620A1 (en) * 2014-11-05 2016-05-05 Schlumberger Technology Corporation Compositions and Methods for Servicing Subterranean Wells
US20160122616A1 (en) * 2014-11-05 2016-05-05 Schlumberger Technology Corporation Compositions and Methods for Servicing Subterranean Wells
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Families Citing this family (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7124822B2 (en) * 2004-11-02 2006-10-24 Halliburton Energy Services, Inc. Foamed completion fluids and methods
US8609595B2 (en) 2005-09-09 2013-12-17 Halliburton Energy Services, Inc. Methods for determining reactive index for cement kiln dust, associated compositions, and methods of use
US8307899B2 (en) 2005-09-09 2012-11-13 Halliburton Energy Services, Inc. Methods of plugging and abandoning a well using compositions comprising cement kiln dust and pumicite
US8950486B2 (en) 2005-09-09 2015-02-10 Halliburton Energy Services, Inc. Acid-soluble cement compositions comprising cement kiln dust and methods of use
US9676989B2 (en) 2005-09-09 2017-06-13 Halliburton Energy Services, Inc. Sealant compositions comprising cement kiln dust and tire-rubber particles and method of use
US9051505B2 (en) 2005-09-09 2015-06-09 Halliburton Energy Services, Inc. Placing a fluid comprising kiln dust in a wellbore through a bottom hole assembly
US9023150B2 (en) 2005-09-09 2015-05-05 Halliburton Energy Services, Inc. Acid-soluble cement compositions comprising cement kiln dust and/or a natural pozzolan and methods of use
US9006155B2 (en) 2005-09-09 2015-04-14 Halliburton Energy Services, Inc. Placing a fluid comprising kiln dust in a wellbore through a bottom hole assembly
US8522873B2 (en) 2005-09-09 2013-09-03 Halliburton Energy Services, Inc. Spacer fluids containing cement kiln dust and methods of use
US9150773B2 (en) 2005-09-09 2015-10-06 Halliburton Energy Services, Inc. Compositions comprising kiln dust and wollastonite and methods of use in subterranean formations
US9809737B2 (en) 2005-09-09 2017-11-07 Halliburton Energy Services, Inc. Compositions containing kiln dust and/or biowaste ash and methods of use
US8281859B2 (en) 2005-09-09 2012-10-09 Halliburton Energy Services Inc. Methods and compositions comprising cement kiln dust having an altered particle size
US8505630B2 (en) 2005-09-09 2013-08-13 Halliburton Energy Services, Inc. Consolidating spacer fluids and methods of use
US8672028B2 (en) 2010-12-21 2014-03-18 Halliburton Energy Services, Inc. Settable compositions comprising interground perlite and hydraulic cement
US8505629B2 (en) * 2005-09-09 2013-08-13 Halliburton Energy Services, Inc. Foamed spacer fluids containing cement kiln dust and methods of use
US7407916B2 (en) * 2006-02-15 2008-08-05 Halliburton Energy Services, Inc. Foamed treatment fluids and associated methods
US7618924B2 (en) * 2006-04-10 2009-11-17 Saudi Arabian Oil Company Non-damaging manganese tetroxide water-based drilling fluids
US7861782B2 (en) * 2008-07-31 2011-01-04 Halliburton Energy Services Inc. Foamed cement compositions, additives, and associated methods
EP2175003A1 (en) * 2008-10-13 2010-04-14 Services Pétroliers Schlumberger Particle-loaded wash for well cleanup
EP2305767A1 (en) * 2009-10-02 2011-04-06 Services Pétroliers Schlumberger Method and compositon to prevent fluid mixing in pipe
EP2305450A1 (en) 2009-10-02 2011-04-06 Services Pétroliers Schlumberger Apparatus and methods for preparing curved fibers
US9708523B2 (en) * 2009-10-27 2017-07-18 Halliburton Energy Services, Inc. Swellable spacer fluids and associated methods
WO2011081546A1 (en) * 2009-12-30 2011-07-07 Schlumberger Canada Limited A method of fluid slug consolidation within a fluid system in downhole applications
EP2374860A1 (en) 2010-04-12 2011-10-12 Services Pétroliers Schlumberger Methods for treating fibers
EP2450416B1 (en) * 2010-10-13 2013-08-21 Services Pétroliers Schlumberger Methods and compositions for suspending fluids in a wellbore
US20120279707A1 (en) * 2011-05-05 2012-11-08 Halliburton Energy Services, Inc. Thermally-Activated, High-Temperature Cement Suspending Agent
CA3005388C (en) 2011-10-12 2019-01-29 Saudi Arabian Oil Company Cement oil-based mud spacer formulation
US8739871B2 (en) * 2012-09-18 2014-06-03 Halliburton Energy Services, Inc. Thermally-activated, high temperature particulate suspending agents and methods relating thereto
US20140131042A1 (en) * 2012-11-13 2014-05-15 Halliburton Energy Services, Inc. Methods for Generating Highly Conductive Channels in Propped Fractures
US10066146B2 (en) 2013-06-21 2018-09-04 Halliburton Energy Services, Inc. Wellbore servicing compositions and methods of making and using same
JP2015063669A (en) * 2013-08-27 2015-04-09 有限会社マグマ Composition for foundation digging/pouring material, foundation digging/pouring material, and operation method using the same
GB2557041B (en) * 2015-08-31 2022-02-23 Halliburton Energy Services Inc Use of crosslinked polymer system for mitigation of annular pressure buildup
CN110234728A (en) 2017-02-03 2019-09-13 沙特阿拉伯石油公司 The composition and application method for the water yl drilling fluid that thermal stability improves
US11732179B2 (en) 2018-04-03 2023-08-22 Schlumberger Technology Corporation Proppant-fiber schedule for far field diversion
JP7112242B2 (en) 2018-05-02 2022-08-03 学校法人早稲田大学 Impermeability and Permeability Restoration Method in the Ground
WO2020009918A1 (en) 2018-07-02 2020-01-09 Schlumberger Technology Corporation Cement compositions and methods
CA3122014C (en) 2019-02-01 2023-10-17 Halliburton Energy Services, Inc. Compatible low crystalline silica spacers
WO2020264288A1 (en) 2019-06-28 2020-12-30 Schlumberger Technology Corporation Cement compositions and methods
CN115637139A (en) * 2021-07-19 2023-01-24 中石化石油工程技术服务有限公司 Multi-edge quartz sand well cementation flushing fluid
US11939518B2 (en) * 2022-02-28 2024-03-26 Halliburton Energy Services, Inc. Wellbore treatment fluid

Citations (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3849316A (en) * 1971-08-16 1974-11-19 Dow Chemical Co Spacer composition
US3920559A (en) * 1974-02-19 1975-11-18 Milchem Inc Composition and process for defoaming aqueous drilling fluids
US4083407A (en) * 1977-02-07 1978-04-11 The Dow Chemical Company Spacer composition and method of use
US4093028A (en) * 1973-10-12 1978-06-06 Orpha B. Brandon Methods of use of cementitious materials and sonic or energy-carrying waves within subsurface formations
US4141843A (en) * 1976-09-20 1979-02-27 Halliburton Company Oil well spacer fluids
US4217229A (en) * 1976-09-20 1980-08-12 Halliburton Company Oil well spacer fluids
US4474240A (en) * 1983-01-24 1984-10-02 Oliver Jr John E Drilling fluid displacement process
US4530402A (en) * 1983-08-30 1985-07-23 Standard Oil Company Low density spacer fluid
US4646834A (en) * 1980-09-22 1987-03-03 Dowell Schlumberger Incorporated Aqueous treatment fluid and method of use
US4844164A (en) * 1988-05-27 1989-07-04 Union Oil Company Of California Process and composition for treating underground formations penetrated by a well borehole
US4869321A (en) * 1989-02-10 1989-09-26 Camco, Incorporated Method of plugging openings in well conduits
US4899819A (en) * 1986-07-30 1990-02-13 Mobil Oil Corporation Method for suspending wells
US5247995A (en) * 1992-02-26 1993-09-28 Bj Services Company Method of dissolving organic filter cake obtained from polysaccharide based fluids used in production operations and completions of oil and gas wells
US5284207A (en) * 1991-05-14 1994-02-08 Schlumberger Technology Corporation Method of cleaning a well bore prior to a cementing operation
US5358047A (en) * 1993-04-02 1994-10-25 Halliburton Company Fracturing with foamed cement
US5529123A (en) * 1995-04-10 1996-06-25 Atlantic Richfield Company Method for controlling fluid loss from wells into high conductivity earth formations
US5552377A (en) * 1993-04-20 1996-09-03 Kindred; Jack E. Mud sweep and spacer composition
US5716910A (en) * 1995-09-08 1998-02-10 Halliburton Company Foamable drilling fluid and methods of use in well drilling operations
US5789352A (en) * 1996-06-19 1998-08-04 Halliburton Company Well completion spacer fluids and methods
US5820670A (en) * 1996-07-01 1998-10-13 Halliburton Energy Services, Inc. Resilient well cement compositions and methods
US5829526A (en) * 1996-11-12 1998-11-03 Halliburton Energy Services, Inc. Method and apparatus for placing and cementing casing in horizontal wells
US5866517A (en) * 1996-06-19 1999-02-02 Atlantic Richfield Company Method and spacer fluid composition for displacing drilling fluid from a wellbore
US5875845A (en) * 1997-08-18 1999-03-02 Halliburton Energy Services, Inc. Methods and compositions for sealing pipe strings in well bores
US5897699A (en) * 1997-07-23 1999-04-27 Halliburton Energy Services, Inc. Foamed well cement compositions, additives and methods
US5909774A (en) * 1997-09-22 1999-06-08 Halliburton Energy Services, Inc. Synthetic oil-water emulsion drill-in fluid cleanup methods
US5945387A (en) * 1997-05-12 1999-08-31 Halliburton Energy Services, Inc. Polymeric well completion and remedial compositions and methods
US5977032A (en) * 1998-09-26 1999-11-02 Atlantic Richfield Company Acidic surfactant composition and method for cleaning wellbore and flowline surfaces using the surfactant composition
US6059035A (en) * 1998-07-20 2000-05-09 Halliburton Energy Services, Inc. Subterranean zone sealing methods and compositions
US6059036A (en) * 1997-11-26 2000-05-09 Halliburton Energy Services, Inc. Methods and compositions for sealing subterranean zones
US6063737A (en) * 1997-06-12 2000-05-16 Shell Oil Company Aqueous displacement fluid compositions for use in wellbores
US6063738A (en) * 1999-04-19 2000-05-16 Halliburton Energy Services, Inc. Foamed well cement slurries, additives and methods
US6090754A (en) * 1995-05-11 2000-07-18 Atlantic Richfield Company Surfactant blends for well operation
US6138760A (en) * 1998-12-07 2000-10-31 Bj Services Company Pre-treatment methods for polymer-containing fluids
US6145591A (en) * 1997-12-12 2000-11-14 Bj Services Company Method and compositions for use in cementing
US6148917A (en) * 1998-07-24 2000-11-21 Actisystems, Inc. Method of releasing stuck pipe or tools and spotting fluids therefor
US6164380A (en) * 1997-03-17 2000-12-26 Forta Corporation Method for clearing debris in a bore
US6210476B1 (en) * 1999-09-07 2001-04-03 Halliburton Energy Services, Inc. Foamed cement compositions and methods
US6213211B1 (en) * 1998-02-26 2001-04-10 John P. Haberman Using of stokes law cement slurries for improved well cementation
US6220354B1 (en) * 2000-10-24 2001-04-24 Halliburton Energy Services, Inc. High strength foamed well cement compositions and methods
US6221152B1 (en) * 1995-06-07 2001-04-24 Cp Kelco U.S., Inc. Stable suspension of hydrocolloids
US6270565B1 (en) * 1998-09-15 2001-08-07 Halliburton Energy Services, Inc. Methods and compositions for cementing pipe in well bores
US6283213B1 (en) * 1999-08-12 2001-09-04 Atlantic Richfield Company Tandem spacer fluid system and method for positioning a cement slurry in a wellbore annulus
US20010018973A1 (en) * 1999-10-13 2001-09-06 Jiten Chatterji Cementing wells with crack and shatter resistant cement
US20010022224A1 (en) * 1998-02-26 2001-09-20 Haberman John P. Cementing spacers for improved well cementation
US6297202B1 (en) * 1999-01-04 2001-10-02 Halliburton Energy Services, Inc. Defoaming compositions and methods
US6302209B1 (en) * 1997-09-10 2001-10-16 Bj Services Company Surfactant compositions and uses therefor
US20020147113A1 (en) * 1999-07-26 2002-10-10 Grinding & Sizing Co., Inc. Method for creating dense drilling fluid additive and composition therefor
US6554069B1 (en) * 2002-08-15 2003-04-29 Halliburton Energy Services, Inc. Methods of removing water-based drilling fluids and compositions
US6668927B1 (en) * 2003-03-21 2003-12-30 Halliburton Energy Services, Inc. Well completion foamed spacer fluids and methods
US6715553B2 (en) * 2002-05-31 2004-04-06 Halliburton Energy Services, Inc. Methods of generating gas in well fluids

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3846316A (en) 1968-12-03 1974-11-05 Phillips Petroleum Co Lubricants containing reaction products of petroleum sulfonic acids and organic nitrogen polymers
US5030366A (en) 1989-11-27 1991-07-09 Atlantic Richfield Company Spacer fluids

Patent Citations (55)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3849316A (en) * 1971-08-16 1974-11-19 Dow Chemical Co Spacer composition
US4093028A (en) * 1973-10-12 1978-06-06 Orpha B. Brandon Methods of use of cementitious materials and sonic or energy-carrying waves within subsurface formations
US3920559A (en) * 1974-02-19 1975-11-18 Milchem Inc Composition and process for defoaming aqueous drilling fluids
US4141843A (en) * 1976-09-20 1979-02-27 Halliburton Company Oil well spacer fluids
US4217229A (en) * 1976-09-20 1980-08-12 Halliburton Company Oil well spacer fluids
US4083407A (en) * 1977-02-07 1978-04-11 The Dow Chemical Company Spacer composition and method of use
US4646834A (en) * 1980-09-22 1987-03-03 Dowell Schlumberger Incorporated Aqueous treatment fluid and method of use
US4474240A (en) * 1983-01-24 1984-10-02 Oliver Jr John E Drilling fluid displacement process
US4530402A (en) * 1983-08-30 1985-07-23 Standard Oil Company Low density spacer fluid
US4899819A (en) * 1986-07-30 1990-02-13 Mobil Oil Corporation Method for suspending wells
US4844164A (en) * 1988-05-27 1989-07-04 Union Oil Company Of California Process and composition for treating underground formations penetrated by a well borehole
US4869321A (en) * 1989-02-10 1989-09-26 Camco, Incorporated Method of plugging openings in well conduits
US5284207A (en) * 1991-05-14 1994-02-08 Schlumberger Technology Corporation Method of cleaning a well bore prior to a cementing operation
US5247995A (en) * 1992-02-26 1993-09-28 Bj Services Company Method of dissolving organic filter cake obtained from polysaccharide based fluids used in production operations and completions of oil and gas wells
US5358047A (en) * 1993-04-02 1994-10-25 Halliburton Company Fracturing with foamed cement
US5552377A (en) * 1993-04-20 1996-09-03 Kindred; Jack E. Mud sweep and spacer composition
US5529123A (en) * 1995-04-10 1996-06-25 Atlantic Richfield Company Method for controlling fluid loss from wells into high conductivity earth formations
US6090754A (en) * 1995-05-11 2000-07-18 Atlantic Richfield Company Surfactant blends for well operation
US6221152B1 (en) * 1995-06-07 2001-04-24 Cp Kelco U.S., Inc. Stable suspension of hydrocolloids
US5716910A (en) * 1995-09-08 1998-02-10 Halliburton Company Foamable drilling fluid and methods of use in well drilling operations
US5851960A (en) * 1995-09-08 1998-12-22 Halliburton Company Method of performing well drilling operations with a foamable drilling fluid
US5789352A (en) * 1996-06-19 1998-08-04 Halliburton Company Well completion spacer fluids and methods
US5866517A (en) * 1996-06-19 1999-02-02 Atlantic Richfield Company Method and spacer fluid composition for displacing drilling fluid from a wellbore
US5820670A (en) * 1996-07-01 1998-10-13 Halliburton Energy Services, Inc. Resilient well cement compositions and methods
US5829526A (en) * 1996-11-12 1998-11-03 Halliburton Energy Services, Inc. Method and apparatus for placing and cementing casing in horizontal wells
US6164380A (en) * 1997-03-17 2000-12-26 Forta Corporation Method for clearing debris in a bore
US5968879A (en) * 1997-05-12 1999-10-19 Halliburton Energy Services, Inc. Polymeric well completion and remedial compositions and methods
US5945387A (en) * 1997-05-12 1999-08-31 Halliburton Energy Services, Inc. Polymeric well completion and remedial compositions and methods
US6063737A (en) * 1997-06-12 2000-05-16 Shell Oil Company Aqueous displacement fluid compositions for use in wellbores
US5897699A (en) * 1997-07-23 1999-04-27 Halliburton Energy Services, Inc. Foamed well cement compositions, additives and methods
US5875845A (en) * 1997-08-18 1999-03-02 Halliburton Energy Services, Inc. Methods and compositions for sealing pipe strings in well bores
US6302209B1 (en) * 1997-09-10 2001-10-16 Bj Services Company Surfactant compositions and uses therefor
US5909774A (en) * 1997-09-22 1999-06-08 Halliburton Energy Services, Inc. Synthetic oil-water emulsion drill-in fluid cleanup methods
US6059036A (en) * 1997-11-26 2000-05-09 Halliburton Energy Services, Inc. Methods and compositions for sealing subterranean zones
US6145591A (en) * 1997-12-12 2000-11-14 Bj Services Company Method and compositions for use in cementing
US20010022224A1 (en) * 1998-02-26 2001-09-20 Haberman John P. Cementing spacers for improved well cementation
US6213211B1 (en) * 1998-02-26 2001-04-10 John P. Haberman Using of stokes law cement slurries for improved well cementation
US6059035A (en) * 1998-07-20 2000-05-09 Halliburton Energy Services, Inc. Subterranean zone sealing methods and compositions
US6148917A (en) * 1998-07-24 2000-11-21 Actisystems, Inc. Method of releasing stuck pipe or tools and spotting fluids therefor
US6270565B1 (en) * 1998-09-15 2001-08-07 Halliburton Energy Services, Inc. Methods and compositions for cementing pipe in well bores
US5977032A (en) * 1998-09-26 1999-11-02 Atlantic Richfield Company Acidic surfactant composition and method for cleaning wellbore and flowline surfaces using the surfactant composition
US6138760A (en) * 1998-12-07 2000-10-31 Bj Services Company Pre-treatment methods for polymer-containing fluids
US6297202B1 (en) * 1999-01-04 2001-10-02 Halliburton Energy Services, Inc. Defoaming compositions and methods
US6063738A (en) * 1999-04-19 2000-05-16 Halliburton Energy Services, Inc. Foamed well cement slurries, additives and methods
US20020147113A1 (en) * 1999-07-26 2002-10-10 Grinding & Sizing Co., Inc. Method for creating dense drilling fluid additive and composition therefor
US6283213B1 (en) * 1999-08-12 2001-09-04 Atlantic Richfield Company Tandem spacer fluid system and method for positioning a cement slurry in a wellbore annulus
US6210476B1 (en) * 1999-09-07 2001-04-03 Halliburton Energy Services, Inc. Foamed cement compositions and methods
US6308777B2 (en) * 1999-10-13 2001-10-30 Halliburton Energy Services, Inc. Cementing wells with crack and shatter resistant cement
US20010018973A1 (en) * 1999-10-13 2001-09-06 Jiten Chatterji Cementing wells with crack and shatter resistant cement
US6220354B1 (en) * 2000-10-24 2001-04-24 Halliburton Energy Services, Inc. High strength foamed well cement compositions and methods
US6500252B1 (en) * 2000-10-24 2002-12-31 Halliburton Energy Services, Inc. High strength foamed well cement compositions and methods
US6715553B2 (en) * 2002-05-31 2004-04-06 Halliburton Energy Services, Inc. Methods of generating gas in well fluids
US6554069B1 (en) * 2002-08-15 2003-04-29 Halliburton Energy Services, Inc. Methods of removing water-based drilling fluids and compositions
US6668927B1 (en) * 2003-03-21 2003-12-30 Halliburton Energy Services, Inc. Well completion foamed spacer fluids and methods
US6852676B1 (en) * 2003-03-21 2005-02-08 Halliburton Energy Services, Inc. Well completion foamed spacer fluids and methods

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080168848A1 (en) * 2007-01-11 2008-07-17 Gary Funkhouser Measuring Cement Properties
US8601882B2 (en) 2009-02-20 2013-12-10 Halliburton Energy Sevices, Inc. In situ testing of mechanical properties of cementitious materials
US8783091B2 (en) 2009-10-28 2014-07-22 Halliburton Energy Services, Inc. Cement testing
US9594009B2 (en) 2009-10-28 2017-03-14 Halliburton Energy Services, Inc. Cement testing
US20130048285A1 (en) * 2011-08-31 2013-02-28 Stephane Boulard Compositions and Methods for Servicing Subterranean Wells
EP2594620A1 (en) * 2011-08-31 2013-05-22 Services Pétroliers Schlumberger Compositions and methods for servicing subterranean wells
US9790420B2 (en) * 2011-08-31 2017-10-17 Schlumberger Technology Corporation Compositions and methods for cleaning subterranean boreholes
US9500573B2 (en) 2012-03-01 2016-11-22 Halliburton Energy Services, Inc. Cement testing
US8960013B2 (en) 2012-03-01 2015-02-24 Halliburton Energy Services, Inc. Cement testing
US8794078B2 (en) 2012-07-05 2014-08-05 Halliburton Energy Services, Inc. Cement testing
US20160122616A1 (en) * 2014-11-05 2016-05-05 Schlumberger Technology Corporation Compositions and Methods for Servicing Subterranean Wells
WO2016073257A1 (en) * 2014-11-05 2016-05-12 Schlumberger Canada Limited Compositions and methods for servicing subterranean wells
US20160122620A1 (en) * 2014-11-05 2016-05-05 Schlumberger Technology Corporation Compositions and Methods for Servicing Subterranean Wells
US10161222B2 (en) * 2014-11-05 2018-12-25 Schlumberger Technology Corporation Compositions and methods for servicing subterranean wells
WO2017087263A1 (en) * 2015-11-17 2017-05-26 Schlumberger Technology Corporation Compositions and methods for servicing subterranean wells
WO2017091058A1 (en) * 2015-11-26 2017-06-01 Schlumberger Canada Limited Compositions and methods for servicing subterranean wells
US11186760B2 (en) 2015-11-26 2021-11-30 Schlumberger Technology Corporation Methods and compositions for cleaning interior of a casing string

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