US20060283566A1 - Method for producing coated paper with pearlescent effect - Google Patents
Method for producing coated paper with pearlescent effect Download PDFInfo
- Publication number
- US20060283566A1 US20060283566A1 US10/554,418 US55441805A US2006283566A1 US 20060283566 A1 US20060283566 A1 US 20060283566A1 US 55441805 A US55441805 A US 55441805A US 2006283566 A1 US2006283566 A1 US 2006283566A1
- Authority
- US
- United States
- Prior art keywords
- coating
- pearlescent effect
- deposition
- coated paper
- pearlescent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/66—Coatings characterised by a special visual effect, e.g. patterned, textured
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
- D21H23/22—Addition to the formed paper
- D21H23/52—Addition to the formed paper by contacting paper with a device carrying the material
- D21H23/56—Rolls
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/22—Structures being applied on the surface by special manufacturing processes, e.g. in presses
- D21H27/26—Structures being applied on the surface by special manufacturing processes, e.g. in presses characterised by the overlay sheet or the top layers of the structures
Definitions
- the present invention relates to a method for producing coated paper with pearlescent effect.
- so-called ivory or embossed coated papers are rather widespread and are produced by combining the traditional processes for producing coated papers with the methods for obtaining the so-called ivory or embossed effect.
- the pearlescent effect can in fact be obtained either by depositing, by means of a stiff blade, the pearlescent pigments on the paper medium on which the coating has been spread beforehand, or by mixing the pearlescent pigments with the coating and then spreading the resulting mixture onto the paper medium.
- the dimensions of the pearlescent pigments are in fact distinctly larger (by approximately ten times) than those of conventional coatings, and it is therefore practically impossible to obtain a uniform mixture.
- the pearlescent pigments are deposited by means of a stiff blade, since they are, as mentioned, considerably larger than the pigments that constitute the coating, they form streaks and/or lines.
- the aim of the present invention is to provide a method for producing coated paper with pearlescent effect that is capable of eliminating or in any case drastically reducing the drawbacks noted above of conventional methods.
- an object of the invention is to provide a method for producing coated paper with pearlescent effect that allows to obtain a paper with high printability.
- Another object of the present invention is to provide a technological solution that allows to provide a range of coated papers with pearlescent (or slightly pearlescent) effect while maintaining a high brightness, so as to allow their use in the most disparate sectors, from graphics to packaging and covering to advertising.
- Another object of the invention is to provide a method for producing coated paper with pearlescent effect that allows to obtain coated papers with pearlescent effect on one or both sides of the paper medium.
- the coating with pearlescent effect comprises at least nitrocellulose resins, mica-based pigments, and a solvent.
- the present invention provides a coated paper with pearlescent effect, which is characterized in that it comprises a paper medium that has, at at least one side, at least one first layer of coating and, over the first layer of coating, at least one layer of coating having a pearlescent effect.
- FIG. 1 is a perspective view of a coated paper with pearlescent effect according to the invention
- FIG. 2 is a perspective view of a deposition cylinder
- FIG. 3 is an enlarged-scale side elevation view of the outer surface of the deposition cylinder shown in FIG. 2 ;
- FIG. 4 is a sectional view, taken along the line IV-IV of FIG. 3 .
- the present invention relates to a method for producing coated paper having a pearlescent effect, generally designated by the reference numeral 1 .
- the production process according to the invention provides that at least one deposition of at least one layer 3 a of coating is performed at at least one side 2 a of a paper medium 2 , first of all, by way of per se known devices or systems.
- the method for producing coated paper with pearlescent effect provides for an additional deposition of a pearlescent coating 3 b over the coating layer 3 a.
- the additional deposition of pearlescent coating 3 b is performed by using rotogravure (or flexographic) devices (or systems), constituted for example by a deposition roller 4 , which has a plurality of deposition cells 5 at its outer side wall 4 a.
- a method for producing coated paper having a pearlescent effect can provide for a first deposition of a layer of conventional coating approximately 6-12 microns thick on both sides ( 2 a and 2 b ) of a paper medium 2 that has a thickness of approximately 100 microns.
- an additional layer of coating of approximately 1-8 microns per side is deposited on both sides.
- the thickness of the medium will be approximately 116-140 microns.
- a layer of pearlescent coating is then applied on one or both sides of the resulting medium by way of a system or device of the rotogravure/flexographic type, constituted for example by a deposition roller 4 .
- this deposition or these depositions of layers of pearlescent coating is(are) performed by placing the medium, or rather both faces of the medium, in contact with the outer side wall 4 a of the deposition roller 4 .
- the coating layer(s) containing the pearlescent pigments deposited by the deposition roller 4 has(have) a thickness of approximately 2-6 microns, which accordingly brings the total thickness of the resulting paper to 120-152 microns.
- the pearlescent coating comprises at least nitrocellulose resins, mica-based pigments, and a suitable solvent.
- the present invention provides a coated paper with pearlescent effect 1 , which is constituted by a paper medium 2 that has, at at least one side 2 a, at least one coating layer 3 a and, above the coating layer 3 a, at least one coating layer 3 b with pearlescent effect.
- the materials and the dimensions may be various according to requirements.
Abstract
A method for producing coated paper with pearlescent effect, sequentially comprising the following operating steps: a deposition, on at least one side of a paper medium, of at least one layer of coating; an additional deposition, over the at least one layer of coating, of a coating with pearlescent effect by a rotogravure/flexographic device.
Description
- The present invention relates to a method for producing coated paper with pearlescent effect.
- Currently, coated papers are increasingly important in the graphic sector.
- In particular, so-called ivory or embossed coated papers are rather widespread and are produced by combining the traditional processes for producing coated papers with the methods for obtaining the so-called ivory or embossed effect.
- However, currently it is not easy to obtain a coated paper with pearlescent effect by using conventional processes.
- The pearlescent effect, according to current knowledge, can in fact be obtained either by depositing, by means of a stiff blade, the pearlescent pigments on the paper medium on which the coating has been spread beforehand, or by mixing the pearlescent pigments with the coating and then spreading the resulting mixture onto the paper medium.
- However, it has been found that the products obtained with the methods described above are very poor.
- The dimensions of the pearlescent pigments are in fact distinctly larger (by approximately ten times) than those of conventional coatings, and it is therefore practically impossible to obtain a uniform mixture.
- Furthermore, in order to allow pearlescent pigments to express their characteristic effect, they must remain completely on the surface, whereas if they are mixed with the coating they also distribute proximate to the paper medium.
- Finally, it should be noted that if the pearlescent pigments are deposited by means of a stiff blade, since they are, as mentioned, considerably larger than the pigments that constitute the coating, they form streaks and/or lines.
- The aim of the present invention is to provide a method for producing coated paper with pearlescent effect that is capable of eliminating or in any case drastically reducing the drawbacks noted above of conventional methods.
- Within this aim, an object of the invention is to provide a method for producing coated paper with pearlescent effect that allows to obtain a paper with high printability.
- Another object of the present invention is to provide a technological solution that allows to provide a range of coated papers with pearlescent (or slightly pearlescent) effect while maintaining a high brightness, so as to allow their use in the most disparate sectors, from graphics to packaging and covering to advertising.
- Another object of the invention is to provide a method for producing coated paper with pearlescent effect that allows to obtain coated papers with pearlescent effect on one or both sides of the paper medium.
- This aim and these and other objects that will become better apparent hereinafter are achieved by a method for producing coated paper with pearlescent effect, characterized in that it sequentially comprises the steps of:
-
- performing a first deposition, on at least one side of a paper medium, of at least one first layer of coating;
- performing a second deposition, over the first layer of coating, of a coating with pearlescent effect by means of a rotogravure/flexographic device.
- Advantageously the coating with pearlescent effect comprises at least nitrocellulose resins, mica-based pigments, and a solvent.
- According to another aspect, the present invention provides a coated paper with pearlescent effect, which is characterized in that it comprises a paper medium that has, at at least one side, at least one first layer of coating and, over the first layer of coating, at least one layer of coating having a pearlescent effect.
- Further aspects and advantages of the invention will become better apparent from the present detailed description of some currently preferred examples of embodiments, given merely by way of non-limiting example with reference to the accompanying drawings, wherein:
-
FIG. 1 is a perspective view of a coated paper with pearlescent effect according to the invention; -
FIG. 2 is a perspective view of a deposition cylinder; -
FIG. 3 is an enlarged-scale side elevation view of the outer surface of the deposition cylinder shown inFIG. 2 ; and -
FIG. 4 is a sectional view, taken along the line IV-IV ofFIG. 3 . - In the examples of embodiments that follow, individual characteristics, given in relation to specific examples, may actually be interchanged with other different characteristics that exist in other examples of embodiments.
- Moreover, it is noted that anything found to be already known during the patenting process is understood not to be claimed and to be the subject of a disclaimer.
- As shown by the figures, the present invention relates to a method for producing coated paper having a pearlescent effect, generally designated by the reference numeral 1.
- In particular, the production process according to the invention provides that at least one deposition of at least one layer 3 a of coating is performed at at least one side 2 a of a
paper medium 2, first of all, by way of per se known devices or systems. - Also according to the invention, the method for producing coated paper with pearlescent effect provides for an additional deposition of a pearlescent coating 3 b over the coating layer 3 a.
- In particular, the additional deposition of pearlescent coating 3 b is performed by using rotogravure (or flexographic) devices (or systems), constituted for example by a
deposition roller 4, which has a plurality ofdeposition cells 5 at its outer side wall 4 a. - In greater detail, a method for producing coated paper having a pearlescent effect, merely by way of example, can provide for a first deposition of a layer of conventional coating approximately 6-12 microns thick on both sides (2 a and 2 b) of a
paper medium 2 that has a thickness of approximately 100 microns. - Then, according to a preferred embodiment, an additional layer of coating of approximately 1-8 microns per side is deposited on both sides.
- It is evident that after these depositions (of “conventional” coating), the thickness of the medium will be approximately 116-140 microns.
- According to the invention, a layer of pearlescent coating is then applied on one or both sides of the resulting medium by way of a system or device of the rotogravure/flexographic type, constituted for example by a
deposition roller 4. - By way of example, this deposition or these depositions of layers of pearlescent coating is(are) performed by placing the medium, or rather both faces of the medium, in contact with the outer side wall 4 a of the
deposition roller 4. - According to a preferred embodiment, the coating layer(s) containing the pearlescent pigments deposited by the
deposition roller 4 has(have) a thickness of approximately 2-6 microns, which accordingly brings the total thickness of the resulting paper to 120-152 microns. - Naturally, nothing forbids the use of initial paper media of different thickness, or the deposition of thicknesses of coating (or pearlescent coating) having thicknesses that differ from those indicated in the method described above.
- Advantageously, the pearlescent coating comprises at least nitrocellulose resins, mica-based pigments, and a suitable solvent.
- According to another aspect, the present invention provides a coated paper with pearlescent effect 1, which is constituted by a
paper medium 2 that has, at at least one side 2 a, at least one coating layer 3 a and, above the coating layer 3 a, at least one coating layer 3 b with pearlescent effect. - All the characteristics of the invention described above as being advantageous, convenient or the like may also be omitted or replaced with equivalents.
- All the details may further be replaced with other technically equivalent elements.
- The materials and the dimensions may be various according to requirements.
- The disclosures in Italian Patent Application No. VR2003A000054 from which this application claims priority are incorporated herein by reference.
Claims (11)
1-10. (canceled)
11. A method for producing coated paper with pearlescent effect, comprising sequentially the steps of:
performing a first deposition, on at least one side of a paper medium, of at least one layer of coating;
performing a second deposition, over said at least one layer of coating, of a coating with pearlescent effect by means of a rotogravure/flexographic device.
12. The method for producing coated paper with pearlescent effect according to claim 11 , wherein said coating with pearlescent effect comprises at least nitrocellulose resins, mica-based pigments, and a solvent.
13. The method for producing coated paper with pearlescent effect, according to claim 11 , wherein said rotogravure/flexographic device comprises at least one deposition roller.
14. The method for producing coated paper with pearlescent effect according to claim 13 , wherein said at least one deposition roller has a plurality of deposition cells at its outer side wall.
15. The method according to claim 11 , wherein said paper medium has a thickness comprised between 70 and 400 microns.
16. The method for producing coated paper with pearlescent effect according to claim 11 , wherein said first deposition step comprises deposition of a first and second layers of coating, said first layer of coating having a thickness comprised between 6 and 12 microns, and said second layer of coating having a thickness comprised between 1 and 8 microns.
17. The method for producing coated paper with pearlescent effect according to claim 16 , wherein said deposition of said first and second layers of coating is performed at both sides of said paper medium.
18. The method for producing coated paper with pearlescent effect according to claim 17 , wherein said second deposition of a coating with pearlescent effect is performed over both of said first depositions.
19. The method for producing coated paper with pearlescent effect according to claim 11 , wherein said second deposition of a coating with pearlescent effect has a thickness comprised between 2 and 6 microns per side.
20. A coated paper with pearlescent effect, comprising a paper medium that has, at at least one side, at least one layer of coating and, above said at least one layer of coating, at least one layer of coating with pearlescent effect.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITVR2003A000054 | 2003-05-07 | ||
IT000054A ITVR20030054A1 (en) | 2003-05-07 | 2003-05-07 | PROCESS FOR THE PRODUCTION OF COATED PAPER WITH A PEARLESCENT EFFECT |
PCT/EP2004/004222 WO2004099500A1 (en) | 2003-05-07 | 2004-04-21 | Method for producing coated paper with pearlescent effect |
Publications (1)
Publication Number | Publication Date |
---|---|
US20060283566A1 true US20060283566A1 (en) | 2006-12-21 |
Family
ID=33428333
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/554,418 Abandoned US20060283566A1 (en) | 2003-05-07 | 2004-04-21 | Method for producing coated paper with pearlescent effect |
Country Status (14)
Country | Link |
---|---|
US (1) | US20060283566A1 (en) |
EP (1) | EP1620604B1 (en) |
AT (1) | ATE455904T1 (en) |
CA (1) | CA2524042C (en) |
CY (1) | CY1109957T1 (en) |
DE (1) | DE602004025226D1 (en) |
DK (1) | DK1620604T3 (en) |
ES (1) | ES2338116T3 (en) |
HK (1) | HK1091522A1 (en) |
IT (1) | ITVR20030054A1 (en) |
PL (1) | PL1620604T3 (en) |
PT (1) | PT1620604E (en) |
SI (1) | SI1620604T1 (en) |
WO (1) | WO2004099500A1 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ITMI20130979A1 (en) * | 2013-06-13 | 2014-12-14 | Gruppo Cordenons Spa | PAPER MATERIAL WITH HOLOGRAPHIC AND METAL PERLESCENT EFFECT AND RELATIVE PROCESS OF MANUFACTURE |
ITUB20160512A1 (en) * | 2016-02-01 | 2017-08-01 | Gruppo Cordenons Spa | PAPER MATERIAL WITH A HIGH SOLID METAL PERLESCENT EFFECT IN LIGHT AND ITS MANUFACTURING PROCEDURE |
Citations (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2395992A (en) * | 1944-04-01 | 1946-03-05 | Warren S D Co | Mineral-coated printing paper |
US3053683A (en) * | 1958-09-19 | 1962-09-11 | Du Pont | Pigment, method of making same, and coating compositions containing same |
US4126727A (en) * | 1976-06-16 | 1978-11-21 | Congoleum Corporation | Resinous polymer sheet materials having selective, decorative effects |
US4409280A (en) * | 1981-09-21 | 1983-10-11 | Mannington Mills | Decorative surface coverings |
US4675212A (en) * | 1981-09-21 | 1987-06-23 | Mannington Mills, Inc. | Process for manufacturing decorative surface coverings |
US5466511A (en) * | 1991-07-18 | 1995-11-14 | Nevamar Corporation | Coated transfer sheet and laminate produced therefrom |
US5571557A (en) * | 1995-05-09 | 1996-11-05 | Chartpak, Inc. | Faux glass etch product and process of preparing same |
US5573584A (en) * | 1992-12-11 | 1996-11-12 | Basf Aktiengesellschaft | Interference pigments for preparing forgeryproof documents |
US5656331A (en) * | 1995-02-27 | 1997-08-12 | Union Camp Corporation | Printed substrate having a metallic finish and method for producing same |
US5670096A (en) * | 1990-11-15 | 1997-09-23 | Minnesota Mining And Manufacturing Company | Retroreflective article comprising a transparent base sheet and nacreous pigment coating, method for making such a base sheet, and method for making a forming master |
US5916416A (en) * | 1996-05-15 | 1999-06-29 | Cartiere Fedrigoni & C. S.P.A. | Method and apparatus for manufacturing papers with watermarks or patterns and paper thus manufactured |
US6251226B1 (en) * | 1997-05-12 | 2001-06-26 | Cartiere Fedrigoni & C. S.P.A. | Apparatus for manufacturing papers with watermarks or patterns |
US6332943B1 (en) * | 1997-06-30 | 2001-12-25 | Basf Aktiengesellschaft | Method of ink-jet printing with pigment preparations having a dispersant |
US20020192448A1 (en) * | 2001-04-24 | 2002-12-19 | Merck Patent Gmbh | Colored pigments |
US6544714B1 (en) * | 2001-08-16 | 2003-04-08 | Eastman Kodak Company | Nacreous photographic packaging materials |
US20030152715A1 (en) * | 2000-07-24 | 2003-08-14 | Erich Beck | Coating of substrates |
US20040096579A1 (en) * | 2000-10-14 | 2004-05-20 | Chang Kil-Wan | Method for preparing a pearlescent pigment by coating metal oxides on the synthesized mica |
US6866710B2 (en) * | 2002-12-17 | 2005-03-15 | Merck Patent Gmbh | Inorganic spherical absorption pigments |
US6989056B2 (en) * | 2003-09-26 | 2006-01-24 | Ciba Specialty Chemicals Corporation | IR reflective pigment compositions |
US20070029785A1 (en) * | 2003-06-20 | 2007-02-08 | Giuseppe Fedrigoni | Security paper, particularly for labels |
US20070212506A1 (en) * | 2006-03-13 | 2007-09-13 | Adair Paul C | Nonmetallic Label with metallic Appearance |
US7449287B1 (en) * | 2008-01-30 | 2008-11-11 | Eastman Kodak Company | Pearlescent textured imaging supports |
-
2003
- 2003-05-07 IT IT000054A patent/ITVR20030054A1/en unknown
-
2004
- 2004-04-21 ES ES04728543T patent/ES2338116T3/en active Active
- 2004-04-21 DK DK04728543.2T patent/DK1620604T3/en active
- 2004-04-21 DE DE602004025226T patent/DE602004025226D1/en active Active
- 2004-04-21 WO PCT/EP2004/004222 patent/WO2004099500A1/en active Application Filing
- 2004-04-21 AT AT04728543T patent/ATE455904T1/en active
- 2004-04-21 PL PL04728543T patent/PL1620604T3/en unknown
- 2004-04-21 US US10/554,418 patent/US20060283566A1/en not_active Abandoned
- 2004-04-21 CA CA2524042A patent/CA2524042C/en active Active
- 2004-04-21 EP EP04728543A patent/EP1620604B1/en active Active
- 2004-04-21 SI SI200431382T patent/SI1620604T1/en unknown
- 2004-04-21 PT PT04728543T patent/PT1620604E/en unknown
-
2006
- 2006-07-17 HK HK06107976.7A patent/HK1091522A1/en unknown
-
2010
- 2010-04-07 CY CY20101100317T patent/CY1109957T1/en unknown
Patent Citations (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2395992A (en) * | 1944-04-01 | 1946-03-05 | Warren S D Co | Mineral-coated printing paper |
US3053683A (en) * | 1958-09-19 | 1962-09-11 | Du Pont | Pigment, method of making same, and coating compositions containing same |
US4126727A (en) * | 1976-06-16 | 1978-11-21 | Congoleum Corporation | Resinous polymer sheet materials having selective, decorative effects |
US4409280A (en) * | 1981-09-21 | 1983-10-11 | Mannington Mills | Decorative surface coverings |
US4675212A (en) * | 1981-09-21 | 1987-06-23 | Mannington Mills, Inc. | Process for manufacturing decorative surface coverings |
US5670096A (en) * | 1990-11-15 | 1997-09-23 | Minnesota Mining And Manufacturing Company | Retroreflective article comprising a transparent base sheet and nacreous pigment coating, method for making such a base sheet, and method for making a forming master |
US5466511A (en) * | 1991-07-18 | 1995-11-14 | Nevamar Corporation | Coated transfer sheet and laminate produced therefrom |
US5573584A (en) * | 1992-12-11 | 1996-11-12 | Basf Aktiengesellschaft | Interference pigments for preparing forgeryproof documents |
US5656331A (en) * | 1995-02-27 | 1997-08-12 | Union Camp Corporation | Printed substrate having a metallic finish and method for producing same |
US5571557A (en) * | 1995-05-09 | 1996-11-05 | Chartpak, Inc. | Faux glass etch product and process of preparing same |
US5916416A (en) * | 1996-05-15 | 1999-06-29 | Cartiere Fedrigoni & C. S.P.A. | Method and apparatus for manufacturing papers with watermarks or patterns and paper thus manufactured |
US6251226B1 (en) * | 1997-05-12 | 2001-06-26 | Cartiere Fedrigoni & C. S.P.A. | Apparatus for manufacturing papers with watermarks or patterns |
US6332943B1 (en) * | 1997-06-30 | 2001-12-25 | Basf Aktiengesellschaft | Method of ink-jet printing with pigment preparations having a dispersant |
US20030152715A1 (en) * | 2000-07-24 | 2003-08-14 | Erich Beck | Coating of substrates |
US6737122B2 (en) * | 2000-07-24 | 2004-05-18 | Basf Aktiengesellschaft | Method for coating substrates |
US20040096579A1 (en) * | 2000-10-14 | 2004-05-20 | Chang Kil-Wan | Method for preparing a pearlescent pigment by coating metal oxides on the synthesized mica |
US20020192448A1 (en) * | 2001-04-24 | 2002-12-19 | Merck Patent Gmbh | Colored pigments |
US6544714B1 (en) * | 2001-08-16 | 2003-04-08 | Eastman Kodak Company | Nacreous photographic packaging materials |
US6866710B2 (en) * | 2002-12-17 | 2005-03-15 | Merck Patent Gmbh | Inorganic spherical absorption pigments |
US20070029785A1 (en) * | 2003-06-20 | 2007-02-08 | Giuseppe Fedrigoni | Security paper, particularly for labels |
US6989056B2 (en) * | 2003-09-26 | 2006-01-24 | Ciba Specialty Chemicals Corporation | IR reflective pigment compositions |
US20070212506A1 (en) * | 2006-03-13 | 2007-09-13 | Adair Paul C | Nonmetallic Label with metallic Appearance |
US7429413B2 (en) * | 2006-03-13 | 2008-09-30 | Brady Worldwide, Inc. | Nonmetallic label with metallic appearance |
US7449287B1 (en) * | 2008-01-30 | 2008-11-11 | Eastman Kodak Company | Pearlescent textured imaging supports |
Also Published As
Publication number | Publication date |
---|---|
PT1620604E (en) | 2010-04-09 |
EP1620604B1 (en) | 2010-01-20 |
SI1620604T1 (en) | 2010-05-31 |
ES2338116T3 (en) | 2010-05-04 |
WO2004099500A1 (en) | 2004-11-18 |
DE602004025226D1 (en) | 2010-03-11 |
EP1620604A1 (en) | 2006-02-01 |
CA2524042A1 (en) | 2004-11-18 |
CA2524042C (en) | 2012-11-27 |
ATE455904T1 (en) | 2010-02-15 |
PL1620604T3 (en) | 2010-06-30 |
CY1109957T1 (en) | 2014-09-10 |
ITVR20030054A1 (en) | 2004-11-08 |
HK1091522A1 (en) | 2007-01-19 |
DK1620604T3 (en) | 2010-03-15 |
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