US20060292947A1 - Polyester fiber scrim and method for making same - Google Patents

Polyester fiber scrim and method for making same Download PDF

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Publication number
US20060292947A1
US20060292947A1 US11/288,860 US28886005A US2006292947A1 US 20060292947 A1 US20060292947 A1 US 20060292947A1 US 28886005 A US28886005 A US 28886005A US 2006292947 A1 US2006292947 A1 US 2006292947A1
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US
United States
Prior art keywords
scrim
polyester fibers
mechanically
layer
denier
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US11/288,860
Inventor
Daniel LaVietes
Darrell Heine
Kevin Bush
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Elk Premium Building Products Inc
Original Assignee
ELK PREMIUM PRODUCTS Inc
Elk Premium Building Products Inc
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Application filed by ELK PREMIUM PRODUCTS Inc, Elk Premium Building Products Inc filed Critical ELK PREMIUM PRODUCTS Inc
Priority to US11/288,860 priority Critical patent/US20060292947A1/en
Assigned to ELK PREMIUM PRODUCTS, INC. reassignment ELK PREMIUM PRODUCTS, INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: LAVIETES, DANIEL, BUSH, KEVIN J., HEINE, DARRELL
Priority to CA2550466A priority patent/CA2550466C/en
Priority to MXPA06007263A priority patent/MXPA06007263A/en
Assigned to ELK PREMIUM BUILDING PRODUCTS, INC reassignment ELK PREMIUM BUILDING PRODUCTS, INC CORRECTIVE ASSIGNMENT TO CORRECT THE ASSIGNEE'S NAME PREVIOUSLY RECORDED ON REEL 017558, FRAME 0608. ASSIGNOR HEREBY CONFIRMS THE ASSIGNMENT OF THE ENTIRE INTEREST. Assignors: LAVIETES, DANIEL, BUSH, KEVIN J., HEINE, DARRELL
Priority to US11/541,329 priority patent/US20070023958A1/en
Publication of US20060292947A1 publication Critical patent/US20060292947A1/en
Assigned to DEUTSCHE BANK AG NEW YORK BRANCH reassignment DEUTSCHE BANK AG NEW YORK BRANCH SECURITY AGREEMENT Assignors: CHROMIUM CORPORATION, ELK COMPOSITE BUILDING PRODUCTS, INC., ELK CORPORATION OF ALABAMA, ELK CORPORATION OF AMERICA, ELK CORPORATION OF ARKANSAS, ELK CORPORATION OF TEXAS, ELK GROUP, INC., ELK GROUP, LP, ELK PERFORMANCE NONWOVEN FABRICS, INC., ELK PREMIUM BUILDING PRODUCTS, INC., ELK SLATE PRODUCTS, INC., ELK TECHNOLOGIES, INC., ELK TECHNOLOGY GROUP, INC., ELK VERSASHIELD BUILDING SOLUTIONS, INC., ELKCORP, LUFKIN PATH FORWARD, INC., MIDLAND PATH FORWARD, INC., NELPA, INC., RGM PRODUCTS, INC., RIDGEMATE MANUFACTURING CO. INC.
Assigned to DEUTSCHE BANK TRUST COMPANY AMERICAS reassignment DEUTSCHE BANK TRUST COMPANY AMERICAS SECURITY AGREEMENT Assignors: CHROMIUM CORPORATION, ELK COMPOSITE BUILDING PRODUCTS, INC., ELK CORPORATION OF ALABAMA, ELK CORPORATION OF AMERICA, ELK CORPORATION OF ARKANSAS, ELK CORPORATION OF TEXAS, ELK GROUP, INC., ELK GROUP, LP, ELK PERFORMANCE NONWOVEN FABRICS, INC., ELK PREMIUM BUILDING PRODUCTS, INC., ELK SLATE PRODUCTS, INC., ELK TECHNOLOGIES, INC., ELK TECHNOLOGY GROUP, INC., ELK VERSASHIELD BUILDING SOLUTIONS, INC., ELKCORP, LUFKIN PATH FORWARD, INC., MIDLAND PATH FORWARD, INC., NELPA, INC., RGM PRODUCTS, INC., RIDGEMATE MANUFACTURING CO. INC.
Abandoned legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D39/00Filtering material for liquid or gaseous fluids
    • B01D39/14Other self-supporting filtering material ; Other filtering material
    • B01D39/16Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres
    • B01D39/1607Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous
    • B01D39/1623Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous of synthetic origin
    • B01D39/163Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous of synthetic origin sintered or bonded
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D39/00Filtering material for liquid or gaseous fluids
    • B01D39/14Other self-supporting filtering material ; Other filtering material
    • B01D39/20Other self-supporting filtering material ; Other filtering material of inorganic material, e.g. asbestos paper, metallic filtering material of non-woven wires
    • B01D39/2003Glass or glassy material
    • B01D39/2017Glass or glassy material the material being filamentary or fibrous
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/02Types of fibres, filaments or particles, self-supporting or supported materials
    • B01D2239/025Types of fibres, filaments or particles, self-supporting or supported materials comprising nanofibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/06Filter cloth, e.g. knitted, woven non-woven; self-supported material
    • B01D2239/065More than one layer present in the filtering material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/08Special characteristics of binders
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/20All layers being fibrous or filamentary
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02Composition of the impregnated, bonded or embedded layer
    • B32B2260/021Fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04Impregnation, embedding, or binder material
    • B32B2260/048Natural or synthetic rubber
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0207Elastomeric fibres
    • B32B2262/0215Thermoplastic elastomer fibers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0253Polyolefin fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0276Polyester fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/101Glass fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/724Permeability to gases, adsorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2459/00Nets, e.g. camouflage nets
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/10Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]
    • Y10T442/102Woven scrim
    • Y10T442/172Coated or impregnated
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/10Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]
    • Y10T442/102Woven scrim
    • Y10T442/183Synthetic polymeric fiber

Definitions

  • the present invention relates to filters, filter constructions, materials for use in filter constructions and methods of filtering.
  • the present invention in particular relates to construction materials utilized for supporting one or more layers of fine fibers in filter media.
  • Air filtration media used in application such as High Efficiency Particulate Air (HEPA) or Ultra Low Particulate Air (ULPA) filters require the use of very fine diameter fibers.
  • These fibers can be formed from synthetic polymers, such as polyethylene, polypropylene and polyester or from glass microfibers.
  • Webs or layers of these very fine diameter fibers are extremely fragile and must have some means of support when pleated and placed in the frame or cylindrical structure of the filter.
  • wire screen and plastic netting are used as media supports. These supports may be acceptable for glass microfiber webs, which contain very low percentages of synthetic latex binders providing limited strength for processing.
  • Melt blown and nanofiber webs and layers are pure polymers, which must be blown directly on to a blanket or carrier web. Synthetic scrims are used as these blankets.
  • the use of a scrim having low porosity results in increased airflow resistance of the filter media, which is undesirable. Higher porosity can be achieved by reducing the basis weight of the scrim, but then its ability to be self-supporting is correspondingly diminished.
  • a scrim which is designed for applications such as filters, may have the following desirable characteristics: (a) a sufficient basis weight to be self-supporting when pleated; (b) the ability to hold the shape of the pleats; and, (c) very high porosity (i.e., minimal, if any contribution to air flow resistance).
  • a self-supporting scrim or web structure is provided for use in filter applications.
  • the self-supporting scrim has very high porosity.
  • the scrim or web structure retains the shape of pleats and contributes minimally to airflow resistance.
  • An inventive wet-laid process with wet-web saturation is used for making the scrim or web structure.
  • the wet-laid process parameters are controlled so that the wet-laid web has greater uniformity than webs formed by other processes, for example, spun bond webs or dry-laid webs. Control of blending of fibers of different thickness can be both costly and difficult in spun bond processes.
  • the inventive wet-laid process allows blending of fibers of different thickness and lengths.
  • Synthetic fibers of one or more polymer types and a latex binder (e.g. a thermoplastic binder) of a different polymer type may be used in the make the scrim or web structure.
  • the scrim or web structure is thermally softened so that it can be shaped (e.g. pleated, corrugated) as desired for filter applications.
  • the synthetic fibers and the latex or thermoplastic binding polymers in the scrim or web structure are selected to have different softening or melting points.
  • the latex or thermoplastic binder is selected to soften or melt at relatively low temperatures so that the scrim or web structure can be shaped without damaging its fiber structure or losing its physical properties.
  • inventive scrims and web structures are readily thermopleated in comparison to conventional nylon fiber based scrims.
  • the polyester fibers and acrylic polymer latexes are much less expensive than nylon fibers.
  • inventive wet-laid scrims or web structures can have considerably higher porosity that conventional nylon continuous filament webs. Additionally, the wet-laid scrims or web structures have higher permeability at equal basis weight than conventional spun bonded polyester scrims.
  • Scrims are provided for filter applications.
  • the scrims are self-supporting when pleated or corrugated.
  • the scrims are fabricated suitable material compositions, which allow the scrim to hold the shape of the pleats and retain high porosity characteristics.
  • wet-laid processes for web forming such scrims with the suitable material compositions are provided. These wet-laid processes of web forming provide greater uniformity than spun-bond webs and dry-laid webs.
  • the wet-laid processes for scrim fabrication are more economical than conventional fabrication processes at least in part due to enhanced production speeds at which scrims can be formed by a wet-laid process.
  • the inventive wet-laid process allows fabrication of scrims composed of blends of fibers of different thicknesses and lengths, which are costly and difficult to control in conventional processes such as spun bond processes.
  • the wet-laid process with wet-web saturation allows the use of synthetic fibers of one or more polymer type and a latex binder of a different polymer type.
  • the softening or melting points of the fibers and polymer types are selected to be different.
  • the latex binder is a thermoplastic binder that can be softened without damaging the fiber structure. Webs fabricated using such latex binders can be shaped (e.g., pleated or corrugated) while maintaining or retaining their desirable physical properties.
  • High porosity is very important in fabrics used as scrims, supports or carrier webs.
  • inventive scrims may advantageously have considerably higher porosity that prior art fabrics or scrims. (See e.g., nylon continuous filament webs available from Cerex).
  • the inventive scrims may have permeability values, which are significantly higher than those of conventional spun bonded polyester scrims of equal basis weight (e.g. such as scrims available from Reemay).
  • the materials used for fabrication of the scrims can be substantially less expensive than nylon fibers, whose use in scrims has been previously suggested.
  • Nylon fibers are an “overkill” for most scrim applications (except, for example, for very high temperature applications). Further, nylon fibers are not readily thermo-pleated.
  • a web was formed on a Deltaformer® (Sandy Hill Corporation) and wet-web saturated with Rhoplex® GL-618 Acrylic Latex (Rohm and Haas Company) to a binder level of 25% of the total weight of the scrim and the web dried using conventional gas-fired ovens.
  • the basis weight of the dried scrim was 2.4 oz/yd 2 (81 g/m 2 ).
  • Scrims having basis weights of 2.0 oz/yd 2 (68 g/m 2 ), 1.8 oz/yd 2 (61 g/m 2 ) and 1.6 oz/yd 2 (54 g/m 2 ) were prepared in Examples II, III, and IV, respectively.
  • the method of preparation used in each instance was similar to that used in Example I described above.
  • This invention provides a wet-laid, high porosity, thermopleatable synthetic scrim, composed of polyester fibers and a thermoplastic synthetic latex binder.
  • polyester fibers may constitute 65% to 85% of the weight of the scrim.
  • the polyester fibers may have a thickness range of 6 denier (equivalent to 25 microns) to 15 denier (equivalent to 39 microns) and a cut length range of 0.5 inch to 1.5 inches.
  • the synthetic latex binder material which may constitute 15% to 35% of the weight of the scrim, may be a thermoplastic acrylic resin.
  • a suitable acrylic resin has a softening point between 200° F. and 300° F.
  • the basis weight of the exemplary scrims may be in the range of 1.4 oz/yd 2 (47 g/m 2 ) to 2.6 oz/yd 2 (88 g/m 2 ) and have a Frazier porosity in the range of 700 to 1050 cfm/ft 2 .
  • a particular scrim made from a polyester fiber and acrylic resin binder has a tensile strength of about 62 lbs/3′′ width, an elongation of about 10%, and Elmendorf tear value of about 972 grams.
  • the inventive scrims are suitable for use in filtering structures.
  • a dual layer filtration media formed by the application of melt-blown polypropylene fibers to one surface of the inventive scrim.
  • combining an additional scrim layer with the dual layer media may form a triple layer filtration media.
  • the additional scrim layer may be of any type including convention scrim types.
  • a dual layer filtration media may be formed by combining a glass microfiber mat with a scrim of the present invention.
  • a further layer of any type of scrim may be disposed on the open face of glass microfiber layer to form a three layer filtration media.
  • a dual layer filtration media is formed by the application of polypropylene nanofibers to one surface of a scrim of the present invention.
  • a further layer of any type of scrim may be disposed on the open face of polypropylene nanofiber layer to form a three layer filtration media.
  • the dual and triple-layer self-supporting scrims may be mechanically and thermally pleated in suitable geometrical configurations for use as filter elements.
  • a dual layer media is first mechanically pleated to form a pleated filtration media element. The pleat tips are then pushed or moved through a channel formed by top and bottom platens, which are heated to about 250° F. to 300° F. This heating softens the synthetic binder in the mechanically pleated scrim, which then retains the geometry of the pleats upon cooling.
  • a three layer media including the inventive scrim layer is first mechanically pleated and then its pleat tips are pushed through a channel of top and bottom heated platens. Again heating the platens to about 250° F. to about 300° F. can soften the synthetic binder of the scrim, which then retains the geometry of the pleats upon cooling.
  • the self-supporting scrims used in the two layer and three layer media elements may include a blend of polyester fibers of different thicknesses and cut lengths.
  • the polyester fibers are a blend of 6 denier 1 ⁇ 2′′ and 15 denier 11 ⁇ 2′′ polyester fibers.
  • the amounts of 6 denier to 15 denier polyester fibers may be selected to have a ratio of about 4:1 to about 19:1. In a preferred selection, the ratio may be from about 6:1 to about 12:1. A ratio of 9:1 of 6 denier to 15 denier polyester fibers may be most suitable.
  • the self-supporting scrims fabricated from synthetic latex binder using the inventive wet-laid processes may have basis weight in the range of 1.4 oz/yd 2 (47 g/m 2 ) to 2.6 oz/yd 2 (88 g/m 2 ), or preferably in the range of 1.6 oz/yd 2 (54 g/m 2 ) to 2.4 oz/yd 2 (81 g/m 2 ).
  • the synthetic latex binder used in the inventive scrim compositions may, for example, be a thermoplastic acrylic resin with a softening point between 200° F. and 300° F.
  • the latex binder may constitute 15% to 35% of the weight of the scrim. Preferably 20% to 30% of the weight of the scrim, and most preferably 25% of the weight of the scrim.
  • the inventive scrim may be characterized as having Frazier porosity in the range of 700 to 1050 cfm/ft 2 or preferably in the range of 750 to 970 cfm/ft 2 .
  • the inventive wet laid scrim or web structure may be utilized in filter constructions in any suitable configuration or combination with other filter materials or components (e.g., melt blown polypropylene fibers, glass microfiber mat and polypropylene nanofibers).
  • the Scrim may, for example, be configured as a layer in a dual or multiple layer filter media.
  • a dual layer filtration media is formed by the application of melt blown polypropylene fibers to one surface of the Scrim. Further, a three-layer filtration media is formed by sandwiching a layer of melt blown polypropylene fibers between the Scrim and another scrim. The latter scrim may be of any type.
  • a dual layer filtration media is formed by combining a glass microfiber mat with the Scrim. Further, a three layer filtration media is formed by sandwiching a layer of a glass microfiber mat between the Scrim and another scrim that may be of any type.
  • similar dual or three-layer filtration media are obtained by replacing the glass microfiber mat or melt blown polypropylene layer by polypropylene nanofibers.
  • the dual or multilayer media having the self-supporting Scrim may be mechanically shaped or pleated in the shape of the desired filter element. Portions of the mechanically shaped scrim then may be heated and cooled to form a self-supporting structure that preserves or retains the shape of the desired filter element.
  • the pleated media is pushed through a channel composed of two platens. One or both platens are heated to 250° F. to 300° F. to soften the thermoplastic latex binder of the Scrim at the pleat tips. Upon exiting the channel and cooling, the pleats retain their shape.

Abstract

Self-supporting scrim or web structure, which is readily thermopleated, is provided for use in filter applications. The self-supporting scrim has very high porosity. When pleated and deployed for filter applications, the scrim or web structure retains the shape of pleats and contributes minimally to airflow resistance. The scrim or web structure is fabricated from synthetic fibers and latex binders using a wet laid process.

Description

    CROSS REFERENCE TO RELATED APPLICATION
  • The present application claims priority from U.S. Provisional Patent Application No. 60/693,659 filed Jun. 24, 2005, the disclosure of which is incorporated herein by reference in its entirety.
  • FIELD OF THE INVENTION
  • The present invention relates to filters, filter constructions, materials for use in filter constructions and methods of filtering. The present invention in particular relates to construction materials utilized for supporting one or more layers of fine fibers in filter media.
  • BACKGROUND OF THE INVENTION
  • Air filtration media used in application such as High Efficiency Particulate Air (HEPA) or Ultra Low Particulate Air (ULPA) filters require the use of very fine diameter fibers. These fibers can be formed from synthetic polymers, such as polyethylene, polypropylene and polyester or from glass microfibers.
  • Webs or layers of these very fine diameter fibers are extremely fragile and must have some means of support when pleated and placed in the frame or cylindrical structure of the filter. Traditionally, wire screen and plastic netting are used as media supports. These supports may be acceptable for glass microfiber webs, which contain very low percentages of synthetic latex binders providing limited strength for processing.
  • Melt blown and nanofiber webs and layers are pure polymers, which must be blown directly on to a blanket or carrier web. Synthetic scrims are used as these blankets. The use of a scrim having low porosity results in increased airflow resistance of the filter media, which is undesirable. Higher porosity can be achieved by reducing the basis weight of the scrim, but then its ability to be self-supporting is correspondingly diminished.
  • Consideration is now being given improving the structural characteristics and other properties of scrims, and to methods for making such scrims. A scrim, which is designed for applications such as filters, may have the following desirable characteristics: (a) a sufficient basis weight to be self-supporting when pleated; (b) the ability to hold the shape of the pleats; and, (c) very high porosity (i.e., minimal, if any contribution to air flow resistance).
  • SUMMARY OF THE INVENTION
  • A self-supporting scrim or web structure is provided for use in filter applications. The self-supporting scrim has very high porosity. When pleated and deployed for filter applications, the scrim or web structure retains the shape of pleats and contributes minimally to airflow resistance.
  • An inventive wet-laid process with wet-web saturation is used for making the scrim or web structure. The wet-laid process parameters are controlled so that the wet-laid web has greater uniformity than webs formed by other processes, for example, spun bond webs or dry-laid webs. Control of blending of fibers of different thickness can be both costly and difficult in spun bond processes. In contrast, the inventive wet-laid process allows blending of fibers of different thickness and lengths.
  • Synthetic fibers of one or more polymer types and a latex binder (e.g. a thermoplastic binder) of a different polymer type may be used in the make the scrim or web structure. The scrim or web structure is thermally softened so that it can be shaped (e.g. pleated, corrugated) as desired for filter applications. The synthetic fibers and the latex or thermoplastic binding polymers in the scrim or web structure are selected to have different softening or melting points. The latex or thermoplastic binder is selected to soften or melt at relatively low temperatures so that the scrim or web structure can be shaped without damaging its fiber structure or losing its physical properties.
  • The inventive scrims and web structures are readily thermopleated in comparison to conventional nylon fiber based scrims. The polyester fibers and acrylic polymer latexes are much less expensive than nylon fibers. Further, the inventive wet-laid scrims or web structures can have considerably higher porosity that conventional nylon continuous filament webs. Additionally, the wet-laid scrims or web structures have higher permeability at equal basis weight than conventional spun bonded polyester scrims.
  • DESCRIPTION OF THE INVENTION
  • Scrims are provided for filter applications. The scrims are self-supporting when pleated or corrugated. The scrims are fabricated suitable material compositions, which allow the scrim to hold the shape of the pleats and retain high porosity characteristics. Further, wet-laid processes for web forming such scrims with the suitable material compositions are provided. These wet-laid processes of web forming provide greater uniformity than spun-bond webs and dry-laid webs. Advantageously, the wet-laid processes for scrim fabrication are more economical than conventional fabrication processes at least in part due to enhanced production speeds at which scrims can be formed by a wet-laid process.
  • The inventive wet-laid process allows fabrication of scrims composed of blends of fibers of different thicknesses and lengths, which are costly and difficult to control in conventional processes such as spun bond processes.
  • The wet-laid process with wet-web saturation allows the use of synthetic fibers of one or more polymer type and a latex binder of a different polymer type. In most instances, the softening or melting points of the fibers and polymer types are selected to be different. In preferable compositions, the latex binder is a thermoplastic binder that can be softened without damaging the fiber structure. Webs fabricated using such latex binders can be shaped (e.g., pleated or corrugated) while maintaining or retaining their desirable physical properties.
  • Such shaping properties are particularly remarkable when compared to spun bond polypropylene webs, since the entire structure softens and melts at relatively low temperatures.
  • High porosity is very important in fabrics used as scrims, supports or carrier webs. The inventive scrims may advantageously have considerably higher porosity that prior art fabrics or scrims. (See e.g., nylon continuous filament webs available from Cerex).
  • The inventive scrims may have permeability values, which are significantly higher than those of conventional spun bonded polyester scrims of equal basis weight (e.g. such as scrims available from Reemay).
  • The materials used for fabrication of the scrims (e.g. polyester fibers and acrylic polymer latexes) can be substantially less expensive than nylon fibers, whose use in scrims has been previously suggested. Nylon fibers are an “overkill” for most scrim applications (except, for example, for very high temperature applications). Further, nylon fibers are not readily thermo-pleated.
  • The methods and compositions of the present invention may be better understood or appreciated through the working Examples detailed below. These Examples are presented for purposes of illustration and should not be construed as limiting the invention in any way.
  • EXAMPLE I
  • A fiber furnish composed of 90% 6 denier ½″ length Type 103 polyester fiber and 10% 15 denier 1½″ Type 103 polyester fiber, both supplied by KoSa, were dispersed in a pulper, along with minor amounts of dispersant and viscosity modifier, commonly used in wet-laid mat manufacturing.
  • A web was formed on a Deltaformer® (Sandy Hill Corporation) and wet-web saturated with Rhoplex® GL-618 Acrylic Latex (Rohm and Haas Company) to a binder level of 25% of the total weight of the scrim and the web dried using conventional gas-fired ovens. The basis weight of the dried scrim was 2.4 oz/yd2 (81 g/m2).
  • EXAMPLES II TO IV
  • Scrims having basis weights of 2.0 oz/yd2 (68 g/m2), 1.8 oz/yd2 (61 g/m2) and 1.6 oz/yd2 (54 g/m2) were prepared in Examples II, III, and IV, respectively. The method of preparation used in each instance was similar to that used in Example I described above.
  • Properties of the samples of the scrims prepared in Examples I-IV were characterized using standardized physical tests. Table I shows several of the measured properties (i.e., basis weight, thickness, and Frazier porosity of these samples. Table I also references the corresponding standard test methods that were used to measure the individual properties.
    TABLE I
    PHYSICAL PROPERTIES OF EXAMPLE I-IV SCRIMS
    Property Reference Ex. I Ex. II Ex. III Ex. IV
    Basis Weight Tappi T-410 2.4 2.0 1.8 1.6
    (oz/yd2)
    Thickness (mil) Tappi T-411 26 24 22 21
    Frazier Porosity ASTM D-737 750 863 901 970
    (cfm/ft2)
  • It will be understood that the foregoing examples are only illustrative of the principles of the invention, and that various modifications can be made by those skilled in the art without departing from the scope and spirit of the invention. This invention provides a wet-laid, high porosity, thermopleatable synthetic scrim, composed of polyester fibers and a thermoplastic synthetic latex binder.
  • In exemplary scrims, polyester fibers may constitute 65% to 85% of the weight of the scrim. The polyester fibers may have a thickness range of 6 denier (equivalent to 25 microns) to 15 denier (equivalent to 39 microns) and a cut length range of 0.5 inch to 1.5 inches. The synthetic latex binder material, which may constitute 15% to 35% of the weight of the scrim, may be a thermoplastic acrylic resin. A suitable acrylic resin has a softening point between 200° F. and 300° F.
  • The basis weight of the exemplary scrims may be in the range of 1.4 oz/yd2 (47 g/m2) to 2.6 oz/yd2 (88 g/m2) and have a Frazier porosity in the range of 700 to 1050 cfm/ft2.
  • A particular scrim made from a polyester fiber and acrylic resin binder has a tensile strength of about 62 lbs/3″ width, an elongation of about 10%, and Elmendorf tear value of about 972 grams.
  • The inventive scrims are suitable for use in filtering structures. In one such structure, a dual layer filtration media formed by the application of melt-blown polypropylene fibers to one surface of the inventive scrim. Further, combining an additional scrim layer with the dual layer media may form a triple layer filtration media. The additional scrim layer may be of any type including convention scrim types. Alternatively, a dual layer filtration media may be formed by combining a glass microfiber mat with a scrim of the present invention. A further layer of any type of scrim may be disposed on the open face of glass microfiber layer to form a three layer filtration media.
  • In another application, a dual layer filtration media is formed by the application of polypropylene nanofibers to one surface of a scrim of the present invention. A further layer of any type of scrim may be disposed on the open face of polypropylene nanofiber layer to form a three layer filtration media.
  • The dual and triple-layer self-supporting scrims may be mechanically and thermally pleated in suitable geometrical configurations for use as filter elements. In one example, a dual layer media is first mechanically pleated to form a pleated filtration media element. The pleat tips are then pushed or moved through a channel formed by top and bottom platens, which are heated to about 250° F. to 300° F. This heating softens the synthetic binder in the mechanically pleated scrim, which then retains the geometry of the pleats upon cooling. In another example, a three layer media including the inventive scrim layer is first mechanically pleated and then its pleat tips are pushed through a channel of top and bottom heated platens. Again heating the platens to about 250° F. to about 300° F. can soften the synthetic binder of the scrim, which then retains the geometry of the pleats upon cooling.
  • The self-supporting scrims used in the two layer and three layer media elements may include a blend of polyester fibers of different thicknesses and cut lengths. In one exemplary scrim, the polyester fibers are a blend of 6 denier ½″ and 15 denier 1½″ polyester fibers. In a particular scrim fabrications, the amounts of 6 denier to 15 denier polyester fibers may be selected to have a ratio of about 4:1 to about 19:1. In a preferred selection, the ratio may be from about 6:1 to about 12:1. A ratio of 9:1 of 6 denier to 15 denier polyester fibers may be most suitable.
  • The self-supporting scrims fabricated from synthetic latex binder using the inventive wet-laid processes may have basis weight in the range of 1.4 oz/yd2 (47 g/m2) to 2.6 oz/yd2 (88 g/m2), or preferably in the range of 1.6 oz/yd2 (54 g/m2) to 2.4 oz/yd2 (81 g/m2).
  • The synthetic latex binder used in the inventive scrim compositions may, for example, be a thermoplastic acrylic resin with a softening point between 200° F. and 300° F. The latex binder may constitute 15% to 35% of the weight of the scrim. Preferably 20% to 30% of the weight of the scrim, and most preferably 25% of the weight of the scrim.
  • The inventive scrim may be characterized as having Frazier porosity in the range of 700 to 1050 cfm/ft2 or preferably in the range of 750 to 970 cfm/ft2.
  • The inventive wet laid scrim or web structure (hereinafter “Scrim”) may be utilized in filter constructions in any suitable configuration or combination with other filter materials or components (e.g., melt blown polypropylene fibers, glass microfiber mat and polypropylene nanofibers). The Scrim may, for example, be configured as a layer in a dual or multiple layer filter media.
  • In one exemplary filter construction, a dual layer filtration media is formed by the application of melt blown polypropylene fibers to one surface of the Scrim. Further, a three-layer filtration media is formed by sandwiching a layer of melt blown polypropylene fibers between the Scrim and another scrim. The latter scrim may be of any type. Similarly, in another exemplary filter construction, a dual layer filtration media is formed by combining a glass microfiber mat with the Scrim. Further, a three layer filtration media is formed by sandwiching a layer of a glass microfiber mat between the Scrim and another scrim that may be of any type. In yet another exemplary filter construction, similar dual or three-layer filtration media are obtained by replacing the glass microfiber mat or melt blown polypropylene layer by polypropylene nanofibers.
  • The dual or multilayer media having the self-supporting Scrim may be mechanically shaped or pleated in the shape of the desired filter element. Portions of the mechanically shaped scrim then may be heated and cooled to form a self-supporting structure that preserves or retains the shape of the desired filter element. In an exemplary implementation of a “pleat retention” process, the pleated media is pushed through a channel composed of two platens. One or both platens are heated to 250° F. to 300° F. to soften the thermoplastic latex binder of the Scrim at the pleat tips. Upon exiting the channel and cooling, the pleats retain their shape.
  • It will be understood that the foregoing is only illustrative of the principles of the invention and that various modifications can be made by those skilled in the art without departing from the scope and spirit of the invention, which is limited only by the claims that follow.

Claims (20)

1. A wet-laid, high porosity synthetic scrim composed of polyester fibers and a synthetic latex binder, wherein the synthetic latex binder has a softening temperature lower than the softening temperatures of the polyester fibers and wherein the synthetic scrim is mechanically shaped and then thermoplastically set in a self-supporting shape.
2. The scrim of claim 1 in which the polyester fibers comprise 65% to 85% of the weight of the scrim and the synthetic latex binder comprises 15% to 35% of the weight of the scrim.
3. The scrim of claim 2 in which the polyester fibers have a thickness in the range of about 6 denier to about 15 denier and a cut length of about 0.5 inch to 1.5 inches.
4. The scrim of claim 3 in which the synthetic latex binder is a thermoplastic acrylic resin with a softening point between 200° F. and 300° F.
5. The scrim of claim 4 in which the basis weight is in the range of 1.4 oz/yd2 (47 g/m2) to 2.6 oz/yd (88 g/m2).
6. The scrim of claim 5 that has a Frazier porosity in the range of 700 to 1050 cfm/ft2.
7. A multilayer layer filtration media formed by deposing one of a melt blown polypropylene fibers layer, a glass microfiber layer, and a polypropylene nanofibers layer on one surface of the scrim of claim 6, thereby forming a dual layer filtration media.
8. The multilayer layer filtration media of claim 7 wherein one of a melt blown polypropylene fibers layer, a glass microfiber layer, and a polypropylene nanofibers layer, is sandwiched between the scrim of claim 6 and another scrim, thereby forming a three layer filtration media.
9. The multilayer layer filtration media of claim 7 configured as a self-supporting, pleated filtration media element that is mechanically pleated and whose geometry is thermoplastically set by heating at least a portion of the mechanically pleated scrim to a temperature of about 250° F. to 300° F.
10. The multilayer layer filtration media of claim 7 configured as a self-supporting, pleated filtration media element that is mechanically pleated and whose geometry is thermoplastically set by heating at least a pleat tip of the mechanically pleated scrim to a temperature of about 250° F. to 300° F.
11. The scrim of claim 2 in which the polyester fibers comprise a blend of different thicknesses and cut lengths.
12. The scrim of claim 11 in which the polyester fibers are a blend of 6 denier ½″ and 15 denier 1½″ polyester fibers.
13. The scrim of claim 12 in which the amounts of 6 denier to 15 denier polyester fibers are in the ratio of about 4:1 to about 19:1.
14. The scrim of claim 12 in which the amounts of 6 denier to 15 denier polyester fibers are in the ratio of 9:1 and the thermoplastic binder content is about 25% by weight of the total weight of the scrim.
15. The scrim of claim 11 that has a Frazier porosity in the range of about 750 to 970 cfm/ft2.
16. A method for making a shaped filter media element that is self supporting, the method comprising:
obtaining a scrim comprising polyester fibers and a synthetic latex binder, wherein the latex binder has a softening temperature lower than the softening temperatures of the polyester fibers;
mechanically shaping the scrim to a desired shape; and
thermoplastically setting the mechanically shaped scrim to retain the desired shape
17. The method of claim 16, wherein obtaining a scrim comprising polyester fibers and a synthetic latex binder, comprises making the scrim by a wet-laid process.
18. The method of claim 16, wherein mechanically shaping the scrim to a desired shape comprises mechanically pleating the scrim.
19. The method of claim 18, wherein thermoplastically setting the scrim in the desired shape comprises heating at least a pleat tip of the mechanically pleated scrim to a temperature of between about 200° F. and about 300° F.
20. The method of claim 16, wherein thermoplastically setting the scrim in the desired shape comprises heating at least a portion of the mechanically shaped scrim to the softening temperature of the latex binder.
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US11684885B2 (en) 2014-12-19 2023-06-27 Hollingsworth & Vose Company Filter media comprising a pre-filter layer
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US11167232B2 (en) 2014-12-19 2021-11-09 Hollingsworth & Vose Company Filter media comprising a pre-filter layer
US10252200B2 (en) 2016-02-17 2019-04-09 Hollingsworth & Vose Company Filter media including a filtration layer comprising synthetic fibers
US11014030B2 (en) 2016-02-17 2021-05-25 Hollingsworth & Vose Company Filter media including flame retardant fibers
US11738295B2 (en) 2016-02-17 2023-08-29 Hollingsworth & Vose Company Filter media including flame retardant fibers
US11123668B2 (en) 2016-02-17 2021-09-21 Hollingsworth & Vose Company Filter media including a filtration layer comprising synthetic fibers
US10898838B2 (en) 2016-12-15 2021-01-26 Hollingsworth & Vose Company Filter media including adhesives
US11819790B2 (en) 2016-12-15 2023-11-21 Hollingsworth & Vose Company Filter media including adhesives and/or oleophobic properties
US11484821B2 (en) 2016-12-15 2022-11-01 Hollingsworth & Vose Company Filter media including adhesives
US11369904B2 (en) 2016-12-15 2022-06-28 Hollingsworth & Vose Company Filter media including adhesives and/or oleophobic properties
US10543441B2 (en) 2016-12-15 2020-01-28 Hollingsworth & Vose Company Filter media including adhesives and/or oleophobic properties
US10814261B2 (en) 2017-02-21 2020-10-27 Hollingsworth & Vose Company Electret-containing filter media
US11077394B2 (en) * 2017-02-21 2021-08-03 Hollingsworth & Vose Company Electret-containing filter media
US20210178304A1 (en) * 2017-02-21 2021-06-17 Hollingsworth & Vose Company Electret-containing filter media
US20180236384A1 (en) * 2017-02-21 2018-08-23 Hollingsworth & Vose Company Electret-containing filter media

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MXPA06007263A (en) 2007-01-26

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